JP2009023242A - Transfer paper - Google Patents
Transfer paper Download PDFInfo
- Publication number
- JP2009023242A JP2009023242A JP2007189424A JP2007189424A JP2009023242A JP 2009023242 A JP2009023242 A JP 2009023242A JP 2007189424 A JP2007189424 A JP 2007189424A JP 2007189424 A JP2007189424 A JP 2007189424A JP 2009023242 A JP2009023242 A JP 2009023242A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- lame
- agent
- adhesive
- transfer paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000012546 transfer Methods 0.000 title claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- 239000000853 adhesive Substances 0.000 claims abstract description 28
- 239000000843 powder Substances 0.000 claims abstract description 27
- 239000012943 hotmelt Substances 0.000 claims abstract description 26
- 239000010410 layer Substances 0.000 claims description 72
- 230000001070 adhesive effect Effects 0.000 claims description 27
- 238000002156 mixing Methods 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 239000002344 surface layer Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 abstract description 8
- 238000010030 laminating Methods 0.000 abstract 2
- 229920003002 synthetic resin Polymers 0.000 description 9
- 239000000057 synthetic resin Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 238000004132 cross linking Methods 0.000 description 5
- 239000010408 film Substances 0.000 description 5
- 230000001771 impaired effect Effects 0.000 description 5
- 238000005562 fading Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Images
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
Abstract
Description
本発明は、転写紙の技術分野に属する。 The present invention belongs to the technical field of transfer paper.
転写紙は、表面に画像を印刷し、その印刷した面を衣類などの被転写体に押し当ててアイロン等で加熱することで、画像を被転写体へ熱転写するために使用される。このため、熱転写紙、熱転写シート等とも呼ばれる。 The transfer paper is used for printing an image on the surface, pressing the printed surface against a transfer medium such as clothing and heating it with an iron or the like, thereby transferring the image to the transfer medium. For this reason, it is also called a thermal transfer paper, a thermal transfer sheet, or the like.
転写された衣類などは洗濯を繰り返されるのが普通であるが、洗濯による色落ちという問題がある。特に、インクジェット式で印刷すると色落ちする傾向が大きかった。このため、耐洗濯性を高めるために各種の提案がなされている。例えば特開２０００−１６８２５０号公報には、インク受容層を少なくとも熱硬化性樹脂とホットメルト接着性樹脂とで構成して、耐洗濯性を高める技術が開示されている。
しかしながら、特許文献１のインク受容層を採用しても洗濯の繰り返しによる色落ちを完全に防止することはできないし、インク自体が紫外線などで劣化することもあった。
本発明は、従来の手法では防ぎきれない色落ちや劣化に対して、従来とは異なる手法での対策技術を提供するものである。
However, even if the ink receiving layer of Patent Document 1 is employed, color fading due to repeated washing cannot be completely prevented, and the ink itself may be deteriorated by ultraviolet rays or the like.
The present invention provides a countermeasure technique using a method different from the conventional one against color loss and deterioration that cannot be prevented by the conventional method.
請求項１記載の転写紙（１）は、図１に示すとおり、ベースシート（２）の片面にラメ入りカバー層（３）を積層し、該ラメ入りカバー層（３）の上に接着剤含有インク受容層（４）を積層してなる。 The transfer paper (1) according to claim 1, as shown in FIG. 1, a lamellar cover layer (3) is laminated on one side of a base sheet (2), and an adhesive is formed on the lamellar cover layer (3). The ink-receiving layer (4) is laminated.
ベースシート（２）は、公知の転写紙と同様に離型処理紙又は合成樹脂フィルムを使用する。ベースシート（２）として使用する合成樹脂フィルムは、転写時の加熱に十分耐えうる耐熱性を有するものであればよいが、機械的強度、耐熱性、作業性などの点からＰＥＴフィルム（厚みは３０μｍ〜３００μｍ）が好ましい。なお、合成樹脂フィルムの表面を離型処理してもよい。 As the base sheet (2), a release treated paper or a synthetic resin film is used in the same manner as a known transfer paper. The synthetic resin film used as the base sheet (2) is not particularly limited as long as it has sufficient heat resistance to withstand the heating during transfer. However, in terms of mechanical strength, heat resistance, workability, etc., the PET film (thickness is 30 μm to 300 μm) is preferable. Note that the surface of the synthetic resin film may be released.
ラメ入りカバー層（３）は、透明な合成樹脂中にラメ剤を分散させた透明フィルムを用いる。なお、「透明」とは可視光の透過度が１００％のことを言うわけではなく、ここでは可視光の透過度が５０％以上のことをいう（以下同様）。 For the cover layer (3) with a glitter, a transparent film in which a glitter agent is dispersed in a transparent synthetic resin is used. Note that “transparent” does not mean that the transmittance of visible light is 100%, but here it means that the transmittance of visible light is 50% or more (the same applies hereinafter).
一般的なラメ剤は、異なった２種類以上の合成樹脂の薄膜を多層に積層した構造の薄片であり、薄膜の界面における光の反射により発色するので、合成樹脂の薄膜それ自体は透明である。このラメ剤の反射光の色は観察者が見る角度や光の入射、屈折等の加減で様々に変化する。市販品としては、堀金箔粉（株）のニューレインボー、ダイヤ工業（株）のクリスタルレインボー等がある。 A general lamellar agent is a thin piece having a structure in which two or more different types of synthetic resin thin films are laminated in multiple layers, and colors are generated by reflection of light at the thin film interface, so the synthetic resin thin film itself is transparent. . The color of the reflected light of this lame agent changes variously depending on the angle seen by the observer, the incidence of light, the refraction, and the like. Commercially available products include New Rainbow from Horikin Foil Powder Co., Ltd. and Crystal Rainbow from Dia Kogyo Co., Ltd.
また、合成樹脂のフィルムに蒸着やめっきにて金属を付着させた構造のラメ剤もあり、金属粉をラメ剤として用いることもあり、本発明にてもこれらを使用できる。但し、これらのラメ剤は不透明であるので、上記の透明なラメ剤と比べればラメ入りカバー層（３）の可視光の透過度が低下する。 There is also a lamellar agent having a structure in which a metal is attached to a synthetic resin film by vapor deposition or plating, and metal powder may be used as the lamellar agent, and these can also be used in the present invention. However, since these lamellar agents are opaque, the visible light transmittance of the lamellar cover layer (3) is lower than that of the transparent lamellar agent.
ラメ入りカバー層（３）中でラメ剤が占める割合が小さ過ぎてはラメ感が乏しくなり、大き過ぎると画像の鮮明さを損なう（画像感が乏しくなる）おそれがある。また、著しく大きいと転写加工時の剥離性が低下して転写機能が損なわれる。こうしたことから、ラメ入りカバー層（３）中でラメ剤が４〜１０重量％を占める配合比が好ましい。 If the ratio of the lame agent in the cover layer (3) containing the glitter is too small, the feeling of glitter is poor, and if it is too large, the sharpness of the image may be impaired (the feeling of image becomes poor). On the other hand, if it is extremely large, the peelability at the time of transfer processing is lowered and the transfer function is impaired. For these reasons, a blending ratio in which the lame agent occupies 4 to 10% by weight in the lame-containing cover layer (3) is preferable.
なお、不透明なラメ剤を用いる場合には、ラメ入りカバー層（３）の透明性を確保するために、上記範囲内でも少なめの（４重量％に近い）配合比にするのが好ましい。
ラメ剤が分散される合成樹脂は、透明という条件以外に特段の制限はないが、熱架橋タイプのウレタン樹脂が適している。
In addition, when using an opaque lame agent, in order to ensure the transparency of the cover layer (3) containing a lame, it is preferable to make it a mixture ratio (a value close to 4% by weight) even within the above range.
The synthetic resin in which the lame agent is dispersed is not particularly limited except for the condition of being transparent, but a heat-crosslinking type urethane resin is suitable.
ラメ入りカバー層（３）は、熱架橋タイプのウレタン樹脂エマルジョン（市販品として大日精化（株）のセイカプレンＵＤ７１０、林化学工業（株）のバインダーＣＢ８０２Ｕ、同ＣＬ１０９がある。）、消泡剤、可塑剤（例えばエチレングリコール）、ラメ剤、水からなる組成物をベースシート（２）上に塗着してから、ウレタン樹脂を架橋反応させることで形成される。ラメ入りカバー層（３）の厚みは、１０〜１５μｍが好ましく、１２〜１５μｍがより好ましい。 The lame-containing cover layer (3) is a heat-crosslinking type urethane resin emulsion (Seikaprene UD710 from Dainichi Seika Co., Ltd., Binder CB802U from Hayashi Chemical Industry Co., Ltd., CL109), and an antifoaming agent. It is formed by applying a composition comprising a plasticizer (for example, ethylene glycol), a lame agent, and water on the base sheet (2) and then crosslinking the urethane resin. The thickness of the lamellar cover layer (3) is preferably 10 to 15 μm, and more preferably 12 to 15 μm.
ラメ入りカバー層（３）の上に積層される接着剤含有インク受容層（４）は、インクジェット式のカラープリンタ（又はコピー機）用のインクを定着させる目的（インク受容層）と、被転写体（衣類など）の表面に接着させる目的（接着剤含有〜層）とで設けてあり、透明な合成樹脂中にカチオン化剤とホットメルトパウダーとを添加して構成される。 The adhesive-containing ink receiving layer (4) laminated on the lamellar cover layer (3) has the purpose of fixing ink for an ink-jet color printer (or copier) (ink receiving layer) and the transferred object. It is provided for the purpose of adhering to the surface of a body (clothing, etc.) (adhesive-containing layer), and is constituted by adding a cationizing agent and hot melt powder into a transparent synthetic resin.
接着剤含有インク受容層（４）にカチオン化剤を添加するのは、上記インクの定着性を良好にするためである。カチオン化剤は公知のものを使用できるが、カチオン化剤の種類や配合量によってインクの定着性が大きく左右されることがあるので、実験などを行って選択するとよい。なお、推奨される市販品としては、センカ（株）のＨＰ−２０７Ａ、ＨＰ−２３０Ａ、ＨＰ−２６０Ａや出光ファインケミカル（株）のカチオン化剤がある。 The reason why the cationizing agent is added to the adhesive-containing ink receiving layer (4) is to improve the fixability of the ink. As the cationizing agent, known ones can be used. However, since the fixability of the ink may be greatly influenced by the kind and blending amount of the cationizing agent, it may be selected by performing an experiment or the like. In addition, as a commercially available product recommended, there are HP-207A, HP-230A, HP-260A of Senka Co., Ltd. and a cationizing agent of Idemitsu Fine Chemical Co., Ltd.
一方、ホットメルトパウダーは転写時に接着剤として機能する。このホットメルトパウダーは公知のものを使用すればよい。但し、家庭用アイロンは１６０℃〜１８０℃の温度範囲で使用されるのが普通であるから、この温度で溶融するホットメルトパウダーが望ましい。 On the other hand, the hot melt powder functions as an adhesive during transfer. A known hot melt powder may be used. However, since a household iron is usually used in a temperature range of 160 ° C. to 180 ° C., a hot melt powder that melts at this temperature is desirable.
接着剤含有インク受容層（４）は、熱架橋タイプのアクリル樹脂エマルジョン（市販品として大日精化（株）のセイカプレン＃３００、林化学工業（株）のバインダーＣＢ１０１ｈがある。）、消泡剤（例えば共栄社化学（株）のアクアレン３０６２、サンノプコの７７７）、カチオン化剤、ホットメルトパウダー、分散剤（例えば共栄社化学（株）のフローレンＧ ７００ＡＭＰ）、水からなる組成物をラメ入りカバー層（３）の上に塗着してから、アクリル樹脂を架橋反応させることで形成される。なお、分散剤は、ホットメルトパウダーが疎水性であるため二次凝集対策、沈降分離対策として添加している。 The adhesive-containing ink receiving layer (4) is a heat-crosslinking acrylic resin emulsion (commercially available products include Seikapren # 300 manufactured by Dainichi Seika Co., Ltd. and binder CB101h manufactured by Hayashi Chemical Industry Co., Ltd.), an antifoaming agent. (For example, Kyoeisha Chemical Co., Ltd. Aqualen 3062, Sannopco's 777), cationizing agent, hot melt powder, dispersant (for example, Kyoeisha Chemical Co., Ltd. Floren G 700AMP), water composition containing lame ( It is formed by applying an acrylic resin to a cross-linking reaction after coating on 3). The dispersant is added as a countermeasure against secondary agglomeration and sedimentation separation because the hot melt powder is hydrophobic.
ところで、ホットメルトパウダーの配合比を大きくすれば転写時の接着力が強くなるがインクの定着性が損なわれる傾向がある。つまり、インクの定着性を優先するならカチオン化剤を多めに、転写時の接着力を優先するならホットメルトパウダー多めにするとよいことになる。 By the way, if the blending ratio of the hot melt powder is increased, the adhesive force at the time of transfer is increased, but the ink fixing property tends to be impaired. In other words, if priority is given to the fixing property of the ink, more cationizing agent should be used, and if priority is given to the adhesive force during transfer, more hot melt powder should be used.
しかし、インクの定着性も転写時の接着力も重要であるから、請求項２に記載のように、接着剤含有インク受容層（４）を表層となる第１層（４ａ）とラメ入りカバー層（３）側になる第２層（４ｂ）との２層で構成し、一方をインクの定着性を優先する層、他方を転写時の接着力を優先する層にすれば、定着性と接着力とを両立できる。 However, since the fixing property of the ink and the adhesive strength at the time of transfer are important, the adhesive-containing ink receiving layer (4) and the lamellar cover layer are used as the surface layer of the adhesive-containing ink receiving layer (4) as described in claim 2. (3) It is composed of two layers, the second layer (4b) on the side, and one is a layer that prioritizes ink fixability, and the other is a layer that prioritizes adhesive strength during transfer. Can balance power.
より具体的には、請求項３に記載のように、接着剤含有インク受容層（４）は、アクリル樹脂中に少なくともカチオン化剤とホットメルトパウダーとを添加してなり、カチオン化剤（質量）／ホットメルトパウダー（質量）で表されるカチオン化剤とホットメルトパウダーの配合比を第１層（４ａ）の方が第２層（４ｂ）よりも大きくすればよい。こうすれば、表面部分（第１層（４ａ））はインクの定着性に優れたものになり、転写時には第１層（４ａ）と第２層（４ｂ）に含まれたホットメルトパウダーにより強力な接着効果が得られる。 More specifically, as described in claim 3, the adhesive-containing ink receiving layer (4) is formed by adding at least a cationizing agent and hot melt powder to an acrylic resin, and the cationizing agent (mass). ) / Hot melt powder (mass) and the mixing ratio of the cationizing agent and the hot melt powder may be larger in the first layer (4a) than in the second layer (4b). By doing so, the surface portion (the first layer (4a)) becomes excellent in the fixing property of the ink, and at the time of transfer, the hot melt powder contained in the first layer (4a) and the second layer (4b) is stronger. Adhesive effect can be obtained.
また、第１層（４ａ）においては、ホットメルトパウダーの添加割合が小さいと接着力が弱くなり、堅牢性が低下して洗濯によって脱落するおそれがある。一方、ホットメルトパウダーの添加割合が大きいと印刷された画像がぼけたり滲んだりするおそれがある。 In addition, in the first layer (4a), when the addition ratio of the hot melt powder is small, the adhesive strength is weakened, and the fastness may be lowered and may be dropped by washing. On the other hand, if the ratio of hot melt powder added is large, the printed image may be blurred or blurred.
第２層（４ｂ）においては、ホットメルトパウダーの添加割合が小さいと、第１層（４ａ）と同様に、接着力が弱くなり堅牢性が低下して洗濯によって脱落するおそれがある。一方、ホットメルトパウダーの添加割合を大きくすれば堅牢性は向上するが、硬くなって風合いが損なわれ、また伸縮性が低下するために転写面が割れるおそれがある。 In the second layer (4b), if the addition ratio of the hot melt powder is small, the adhesive strength is weakened and the fastness is lowered, and there is a possibility that the second layer (4b) may fall off by washing. On the other hand, if the addition ratio of the hot melt powder is increased, the fastness is improved, but it becomes hard and the texture is impaired, and the transfer surface may be cracked because the stretchability is lowered.
上記のことから、ホットメルトパウダーの添加割合は、第１層（４ａ）については、該層中でホットメルトパウダーが１３〜１５重量％を占める配合比が好ましく、第２層（４ｂ）については、該層中でホットメルトパウダーが１５〜２０重量％を占める配合比が好ましい。なお、第１層（４ａ）、第２層（４ｂ）ともに、ホットメルトパウダーの配合比を１３〜１５重量％としてもよい。 From the above, for the first layer (4a), the addition ratio of the hot melt powder is preferably a blending ratio in which the hot melt powder accounts for 13 to 15% by weight, and for the second layer (4b). A blending ratio in which the hot melt powder accounts for 15 to 20% by weight in the layer is preferable. In addition, the blending ratio of the hot melt powder may be 13 to 15% by weight in both the first layer (4a) and the second layer (4b).
接着剤含有インク受容層（４）の厚みは、第１層（４ａ）、第２層（４ｂ）とも５〜２５μｍ、全体として１０〜５０μｍ程度が好ましい。これは、第１層（４ａ）、第２層（４ｂ）とも厚みが５μｍを下回ると強度が不足するおそれがあり、一方２５μｍを上回ると硬くなって風合いが損なわれるおそれがあることによる。そうしたことから、第１層（４ａ）、第２層（４ｂ）とも厚みを１２〜１５μｍとするのが好ましい。 The thickness of the adhesive-containing ink receiving layer (4) is preferably about 5 to 25 μm for the first layer (4a) and the second layer (4b), and about 10 to 50 μm as a whole. This is because the strength of both the first layer (4a) and the second layer (4b) may be insufficient if the thickness is less than 5 μm, and on the other hand, if the thickness is greater than 25 μm, the texture may be impaired. For this reason, the thickness of both the first layer (4a) and the second layer (4b) is preferably 12 to 15 μm.
本発明の転写紙（１）を用いて衣類などに転写するには、まずインクジェット式プリンタにて第１層（４ａ）に画像を印刷する。言うまでもないが、画像は逆像とされる。接着剤含有インク受容層（４）が上記のように構成されているため、インクの定着性に優れており、鮮明に印刷できる。 In order to transfer to a garment or the like using the transfer paper (1) of the present invention, an image is first printed on the first layer (4a) with an ink jet printer. Needless to say, the image is a reverse image. Since the adhesive-containing ink receiving layer (4) is configured as described above, it has excellent ink fixability and can be printed clearly.
印刷後、インクの乾燥を待つ。通常は、室温で６０分程度で十分である。
次に、図２に示すように、Ｔシャツ、トレーナー等の衣類（被転写体）の表面に転写紙（１）の印刷面すなわち第１層（４ａ）を対面させて、転写紙（１）を被転写体に重ね合わせる。そして、ベースシート（２）に家庭用アイロン（１６０℃〜１８０℃）を押し当てて、加熱する。これにより、接着剤含有インク受容層（４）のホットメルトパウダーが溶融して、接着剤含有インク受容層（４）すなわち転写紙（１）を被転写体に接着する。
Wait for ink to dry after printing. Usually, about 60 minutes at room temperature is sufficient.
Next, as shown in FIG. 2, the printing surface of the transfer paper (1), that is, the first layer (4a) is faced to the surface of a garment (transfer object) such as a T-shirt or a trainer, so that the transfer paper (1) Is superimposed on the transfer medium. And a household iron (160 degreeC-180 degreeC) is pressed against a base sheet (2), and it heats. Thereby, the hot-melt powder of the adhesive-containing ink receiving layer (4) is melted, and the adhesive-containing ink receiving layer (4), that is, the transfer paper (1) is bonded to the transfer target.
アイロンを外すと短時間のうちに溶融していた接着剤（ホットメルトパウダー）が固化するから、そこでベースシート（２）を引き剥がす。これにより、接着剤含有インク受容層（４）と、その上のラメ入りカバー層（３）とが被転写体に接着したまま残留し、転写が完了する。 When the iron is removed, the adhesive (hot melt powder) melted in a short time solidifies, and the base sheet (2) is peeled off there. As a result, the adhesive-containing ink receiving layer (4) and the lamellar cover layer (3) thereon remain adhered to the transfer medium, and transfer is completed.
本発明の転写紙（１）を用いて衣類などに転写すると、印刷面（接着剤含有インク受容層（４））が衣類側になり、その上をラメ入りカバー層（３）で被覆した構造になる。つまり、ラメ入りカバー層（３）がインクを保護するので、洗濯による色落ちを抑制できる。 When transferred to clothing or the like using the transfer paper (1) of the present invention, the printed surface (adhesive-containing ink receiving layer (4)) is on the clothing side and is covered with a lamellar cover layer (3). become. That is, since the lame cover layer (3) protects the ink, color fading due to washing can be suppressed.
また、ラメ剤による反射光は、見る角度に応じて色が変化して印刷された画像の美観を向上させるが、それのみではなく、画像（インクの色）を鮮明に感じさせる効果がある。このため、多少の色落ちがあっても、これをラメ剤の反射光が補って色落ちを実感させない。これにより、転写画像の実用上での長寿命化が可能になる。 Further, the reflected light from the lame agent improves the aesthetics of the printed image by changing the color according to the viewing angle, but it has the effect of making the image (ink color) clear. For this reason, even if there is some color fading, the reflected light of the lame agent compensates for this so that the color fading is not realized. This makes it possible to extend the practical life of the transferred image.
１・・・転写紙、２・・・ベースシート、３・・・ラメ入りカバー層、４・・・接着剤含有インク受容層、４ａ・・・第１層、４ｂ・・・第２層。 DESCRIPTION OF SYMBOLS 1 ... Transfer paper, 2 ... Base sheet, 3 ... Lame cover layer, 4 ... Adhesive containing ink receiving layer, 4a ... 1st layer, 4b ... 2nd layer.
Claims (3)
ことを特徴とする請求項１記載の転写紙。 2. The transfer paper according to claim 1, wherein the adhesive-containing ink receiving layer is composed of two layers, a first layer that is a surface layer and a second layer that is on the lamellar cover layer side.
カチオン化剤（質量）／ホットメルトパウダー（質量）で表されるカチオン化剤とホットメルトパウダーの配合比は、第１層の方が第２層よりも大きい
ことを特徴とする請求項２記載の転写紙。 The adhesive-containing ink receiving layer is formed by adding at least a cationizing agent and hot melt powder to an acrylic resin.
The mixing ratio of the cationizing agent and the hot melt powder expressed by cationizing agent (mass) / hot melt powder (mass) is larger in the first layer than in the second layer. Transfer paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007189424A JP5230973B2 (en) | 2007-07-20 | 2007-07-20 | Transfer paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007189424A JP5230973B2 (en) | 2007-07-20 | 2007-07-20 | Transfer paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009023242A true JP2009023242A (en) | 2009-02-05 |
| JP5230973B2 JP5230973B2 (en) | 2013-07-10 |
Family
ID=40395545
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007189424A Active JP5230973B2 (en) | 2007-07-20 | 2007-07-20 | Transfer paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5230973B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013075002A (en) * | 2011-09-30 | 2013-04-25 | Olympia:Kk | Display unit, and game machine |
| WO2022030537A1 (en) * | 2020-08-05 | 2022-02-10 | 大日本印刷株式会社 | Thermal transfer sheet and combination of thermal transfer sheet and intermediate transfer medium |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09169157A (en) * | 1995-10-20 | 1997-06-30 | Keiwa Shoko Kk | Transfer image receiving material for ink jet printer |
| JPH10315695A (en) * | 1997-05-21 | 1998-12-02 | Canon Inc | Thermal transfer medium for ink-jet, thermal transfer method and thermally transferred item |
| JPH10329415A (en) * | 1997-05-30 | 1998-12-15 | Canon Inc | Ink jet recording transfer medium |
| JP2002219863A (en) * | 2001-01-26 | 2002-08-06 | Mitsubishi Paper Mills Ltd | Transfer sheet for ink jet recording |
| JP2004361622A (en) * | 2003-06-04 | 2004-12-24 | Dainippon Printing Co Ltd | Hologram transfer sheet and intermediate transfer recording medium |
| JP2006124826A (en) * | 2004-09-29 | 2006-05-18 | Mitsubishi Materials Corp | Metal colloid particle, metal colloid, and use of metal colloid |
-
2007
- 2007-07-20 JP JP2007189424A patent/JP5230973B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09169157A (en) * | 1995-10-20 | 1997-06-30 | Keiwa Shoko Kk | Transfer image receiving material for ink jet printer |
| JPH10315695A (en) * | 1997-05-21 | 1998-12-02 | Canon Inc | Thermal transfer medium for ink-jet, thermal transfer method and thermally transferred item |
| JPH10329415A (en) * | 1997-05-30 | 1998-12-15 | Canon Inc | Ink jet recording transfer medium |
| JP2002219863A (en) * | 2001-01-26 | 2002-08-06 | Mitsubishi Paper Mills Ltd | Transfer sheet for ink jet recording |
| JP2004361622A (en) * | 2003-06-04 | 2004-12-24 | Dainippon Printing Co Ltd | Hologram transfer sheet and intermediate transfer recording medium |
| JP2006124826A (en) * | 2004-09-29 | 2006-05-18 | Mitsubishi Materials Corp | Metal colloid particle, metal colloid, and use of metal colloid |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013075002A (en) * | 2011-09-30 | 2013-04-25 | Olympia:Kk | Display unit, and game machine |
| WO2022030537A1 (en) * | 2020-08-05 | 2022-02-10 | 大日本印刷株式会社 | Thermal transfer sheet and combination of thermal transfer sheet and intermediate transfer medium |
| JP7044214B1 (en) * | 2020-08-05 | 2022-03-30 | 大日本印刷株式会社 | Thermal transfer sheet, and combination of thermal transfer sheet and intermediate transfer medium |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5230973B2 (en) | 2013-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6211718B2 (en) | Label writer tape | |
| US20090176039A1 (en) | Image Transfer Sheet and Method Utilizing a Rubber Based Hot Melt Adhesive | |
| WO2020203861A1 (en) | Intermediate transfer medium, recording medium, decorative sheet, and decorative product | |
| US20070042140A1 (en) | Image Transfer Sheet and Method Utilizing a Rubber Based Hot Melt Adhesive | |
| JP5230973B2 (en) | Transfer paper | |
| JP2017065234A5 (en) | ||
| JP4827096B2 (en) | Image-receiving layer transfer sheet for inkjet | |
| JP2005231368A (en) | Durable printing composite material and related method | |
| JP6361917B2 (en) | Thermal transfer media | |
| KR101340976B1 (en) | Waterslide Decal Paper for Dye Sublimation Thermal Transfer Printing | |
| JP6651700B2 (en) | Thermal transfer sheet | |
| JP5092090B2 (en) | Water transfer sheet and water transfer release sheet | |
| WO2007049513A1 (en) | Peeping preventive film for information display, and process for producing the same | |
| KR100962513B1 (en) | Transfer medium having light storage function | |
| TW580456B (en) | Thermo-sensitive recording medium and printed object | |
| JP6680429B1 (en) | Thermal transfer sheet and printed matter | |
| JP2004205827A (en) | Heat transfer type image protecting sheet | |
| JP2018171860A (en) | Recording sheet for inkjet | |
| JP2009154504A (en) | Water transfer sheet | |
| JP6714055B2 (en) | Cool feeling decorative sheet for heat transfer | |
| JPH0445981A (en) | Printing method | |
| JP7067007B2 (en) | Transfer sheet | |
| JP2010083129A (en) | Sublimation type thermal transfer ribbon | |
| JP5483327B2 (en) | Thermal melt transfer image forming method | |
| JP2002067504A (en) | Method for forming image, laminated sheet used therefor, and its matter |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20100521 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20120221 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120327 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120522 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20121218 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130206 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130226 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130321 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20160329 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5230973 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |