JP2008527191A5 - - Google Patents

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JP2008527191A5
JP2008527191A5 JP2007550442A JP2007550442A JP2008527191A5 JP 2008527191 A5 JP2008527191 A5 JP 2008527191A5 JP 2007550442 A JP2007550442 A JP 2007550442A JP 2007550442 A JP2007550442 A JP 2007550442A JP 2008527191 A5 JP2008527191 A5 JP 2008527191A5
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Japan
Prior art keywords
sheet
paper
antibacterial
hydrophobic
fixing agent
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JP2007550442A
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JP2008527191A (en
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Priority claimed from PCT/US2006/000233 external-priority patent/WO2006074255A1/en
Publication of JP2008527191A publication Critical patent/JP2008527191A/en
Publication of JP2008527191A5 publication Critical patent/JP2008527191A5/ja
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Claims (26)

紙又は板紙の製造の際に、25℃において0.3g/L未満の水溶解度を有する疎水性の殺菌剤と、カチオン性固定剤とを、紙スラリーに添加する段階;
抄紙機内の前記紙スラリーを処理してシートを作成する段階:
を含む、建築材料に用いるための抗菌性紙シートの製造方法。
Adding a hydrophobic disinfectant having a water solubility of less than 0.3 g / L at 25 ° C. and a cationic fixative to the paper slurry during paper or board manufacture;
Processing the paper slurry in a paper machine to create a sheet:
A method for producing an antibacterial paper sheet for use in building materials.
前記疎水性の殺菌剤が、ジヨードメチル−p−トリルスルホン(DIMTS)、亜鉛ピリチオン、チアベンダゾール、3−ヨード−2−プロピニルブチルカルバメート、ジクロロオクチルイソチアゾリノン、o−フェニルフェノール、ブロモニトロスチレン、及び2−(チオシアノメチルチオ)ベンゾチアゾールからなる群から選択される、請求項1に記載の方法。   The hydrophobic fungicide is diiodomethyl-p-tolylsulfone (DIMTS), zinc pyrithione, thiabendazole, 3-iodo-2-propynylbutylcarbamate, dichlorooctylisothiazolinone, o-phenylphenol, bromonitrostyrene, and 2 2. The method of claim 1, wherein the method is selected from the group consisting of-(thiocyanomethylthio) benzothiazole. 前記疎水性の殺菌剤が、ジヨードメチル−p−トリルスルホンである、請求項1又は2に記載の方法。 The method according to claim 1 or 2 , wherein the hydrophobic bactericidal agent is diiodomethyl-p-tolylsulfone. 前記シートをプレスした紙に処理する段階をさらに含む、請求項1〜3のいずれか一項に記載の方法。 Further comprising the step of treating the paper was pressed the sheet process towards according to any one of claims 1-3. 前記シートを複層の板紙に処理する段階をさらに含む、請求項1〜3のいずれか一項に記載の方法。 Further comprising the step of treating the sheet paperboard multilayer, Method person according to any one of claims 1-3. 前記疎水性の殺菌剤が、前記カチオン性固定剤をパルプスラリーに添加する前に、当該パルプスラリーにウェットエンド適用することによって添加される、請求項1〜5のいずれか一項に記載の方法。 The hydrophobic fungicide, the cationic fixing agent prior to addition to the pulp slurry is added by applying wet end, the pulp slurry, who claimed in any one of claims 1-5 Law. 前記疎水性の殺菌剤が、前記カチオン性固定剤をパルプスラリーに添加した後に、当該パルプスラリーにウェットエンド適用することによって添加される、請求項1〜5のいずれか一項に記載の方法。 The hydrophobic fungicide, the cationic fixing agent after adding to the pulp slurry is added by applying wet end, the pulp slurry, how according to any one of claims 1-5 . 前記疎水性の殺菌剤が、前記カチオン性固定剤を前記パルプスラリーに添加すると同時に、前記パルプスラリーにウェットエンド適用することによって添加される、請求項1〜5のいずれか一項に記載の方法。 The hydrophobic fungicide, simultaneously with the addition of the cationic fixing agent to the pulp slurry, the added by applying wet end to the pulp slurry, who claimed in any one of claims 1-5 Law. 前記疎水性の殺菌剤及びカチオン性固定剤を、共に混合してプレミックスを形成させ、そして当該プレミックスが、前記パルプスラリーにウェットエンド適用することによって添加される、請求項1〜5のいずれか一項に記載の方法。 Said hydrophobic disinfectant and cationic fixing agent, to form a premix by mixing together, and the premix is added by applying wet end in the pulp slurry, either of claims 1 to 5 the method according to one paragraph or. 前記カチオン性固定剤が、ポリアクリルアミド、ポリアミン、ポリDADMAC、ポリグアニジン、ポリエチレンイミン、セルロースエーテル、でん粉、アルミニウム系凝固剤、鉄系凝固剤、改質粘土、改質タルク、シリカ微粒子系及びそれらの組み合わせから選択される、請求項1〜のいずれか一項に記載の方法。 The cationic fixing agent, polyacrylamide, polyamine, poly DADMAC, polyguanidines, polyethyleneimines, cellulosic ethers, starch, aluminum-based coagulants, iron-based coagulants, modified clays, modified talc, silica fine particles based and its Re It is selected from a combination of al, method person according to any one of claims 1-9. 前記カチオン性固定剤がポリアミンである、請求項1〜10のいずれか一項に記載の方法。 The cationic fixing agent is a polyamine, Method person according to any one of claims 1-10. 前記カチオン性固定剤:前記殺菌剤の重量比が、1:35〜15:1である、請求項1〜11のいずれか一項に記載の方法。 The cationic fixing agent weight ratio of the fungicide, 1: 35-15: 1 is, methods who claimed in any one of claims 1 to 11. 前記カチオン性固定剤:前記殺菌剤の重量比が、1:35〜2.5:1である、請求項1〜12のいずれか一項に記載の方法。 The cationic fixing agent weight ratio of the fungicide, 1: 35 to 2.5: 1 is, methods who claimed in any one of claims 1 to 12. 前記シートを処理して防湿性を付与するか、そして/又は強度を強化する段階をさらに含む、請求項1〜13のいずれか一項に記載の方法。 Said sheet processes by either imparting moisture resistance, and further comprising the step of enhancing the / or intensity, methods who claimed in any one of claims 1 to 13. 第二の抗菌剤材料を、純粋な生成物又は配合物としてコーティングすることにより、前記紙スラリー又は完成品のシートに添加する段階をさらに含む、請求項1〜14のいずれか一項に記載の方法。 By coating a second antimicrobial agent material, as pure product or formulation, further comprising the step of adding to paper slurry or PVC sheet, according to any one of claims 1-14 mETHODS. 前記疎水性の殺菌剤が、前記シート中に存在する乾燥繊維1トンあたり、少なくとも0.02ポンドに等しい量で存在する、請求項1〜15のいずれか一項に記載の方法に従って製造された紙又は板紙の抗菌性シート。 16. The process of any one of claims 1 to 15 , wherein the hydrophobic bactericide is present in an amount equal to at least 0.02 pounds per ton of dry fiber present in the sheet. Antibacterial sheet of paper or paperboard. 前記ジヨードメチル−p−トリルスルホンが、前記シート中に存在する乾燥繊維1トンあたり、約2.0〜10.0ポンドの量で存在する、請求項1〜15のいずれか一項に記載の方法に従って製造された、紙又は板紙の抗菌性シート。 16. The method of any one of claims 1-15, wherein the diiodomethyl-p-tolylsulfone is present in an amount of about 2.0-10.0 pounds per ton of dry fiber present in the sheet. Paper or paperboard antibacterial sheet manufactured according to the above. 前記ジヨードメチル−p−トリルスルホンが、前記シート中に存在する乾燥繊維1トンあたり、約2.0〜3.2ポンドの量で存在する、請求項1〜15のいずれか一項に記載の方法に従って製造された、紙又は板紙の抗菌性シート。 16. A method according to any one of the preceding claims, wherein the diiodomethyl-p-tolylsulfone is present in an amount of about 2.0 to 3.2 pounds per ton of dry fiber present in the sheet. Paper or paperboard antibacterial sheet manufactured according to the above. 前記カチオン性固定剤及び殺菌剤の両方が、前記紙の機械的性質又は品質を実質的に変化させない、請求項1〜15のいずれか一項に記載の方法で製造された抗菌性シート。 The antimicrobial sheet manufactured by the method according to any one of claims 1 to 15 , wherein both the cationic fixative and the bactericidal agent do not substantially change the mechanical properties or quality of the paper. 紙及び板紙に関するTAPPI法T−487に従って、試験2週間後に、少なくとも「適度な抗菌性」として判定される、請求項1〜15のいずれか一項に記載の方法で製造された抗菌性シート。 The antibacterial sheet produced by the method according to any one of claims 1 to 15 , which is determined as at least "moderate antibacterial" after 2 weeks of testing according to TAPPI method T-487 for paper and paperboard. 紙及び板紙に関するTAPPI法T−487に従って、試験3週間後に「抗菌性」として判定される、請求項1〜15のいずれか一項に記載の方法で製造された、抗菌性シート。 The antibacterial sheet manufactured by the method according to any one of claims 1 to 15 , which is determined as "antibacterial" after 3 weeks of testing according to TAPPI method T-487 for paper and paperboard. ASTM法G−21の条件下の試験の7日後に、30%以下の菌類の増殖を有する、請求項1〜15のいずれか一項に記載の方法で製造された抗菌性シート。 The antibacterial sheet manufactured by the method according to any one of claims 1 to 15 , which has a fungal growth of 30% or less after 7 days of the test under the condition of ASTM method G-21. ASTM法G−21の条件下の試験の4週間後に、30%以下の菌類の増殖を有する、請求項1〜15のいずれか一項に記載の方法で製造された抗菌性シート。 The antibacterial sheet produced by the method according to any one of claims 1 to 15 , which has a fungal growth of 30% or less after 4 weeks of the test under the conditions of ASTM method G-21. ASTM D 3273において7〜10の評価を受ける、請求項1〜15のいずれか一項に記載の方法で製造された抗菌性シート。 The antibacterial sheet manufactured by the method according to any one of claims 1 to 15 , which receives an evaluation of 7 to 10 in ASTM D 3273. 抗菌剤表面処理をさらに含む、請求項1〜15のいずれか一項に記載の方法で製造された抗菌性シート。 The antibacterial sheet manufactured by the method according to any one of claims 1 to 15 , further comprising an antibacterial agent surface treatment. ASTM D3273を7〜10の評価で合格する、請求項1〜15のいずれか一項に記載の方法で製造された抗菌性のシートを含む完成した石こうボード。 A finished gypsum board comprising an antibacterial sheet produced by the method of any one of claims 1 to 15 , which passes ASTM D3273 with a rating of 7-10.
JP2007550442A 2005-01-05 2006-01-05 Enhanced fungicide efficacy in paper and paperboard Pending JP2008527191A (en)

Applications Claiming Priority (2)

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US64161805P 2005-01-05 2005-01-05
PCT/US2006/000233 WO2006074255A1 (en) 2005-01-05 2006-01-05 Enhanced efficacy of fungicides in paper and paperboard

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JP2008527191A JP2008527191A (en) 2008-07-24
JP2008527191A5 true JP2008527191A5 (en) 2009-02-12

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US (1) US20060169431A1 (en)
EP (1) EP1859103B1 (en)
JP (1) JP2008527191A (en)
KR (1) KR101276386B1 (en)
CN (1) CN101098999B (en)
CA (1) CA2594189A1 (en)
MX (1) MX2007008240A (en)
PL (1) PL1859103T3 (en)
WO (1) WO2006074255A1 (en)

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