JP2008521161A5 - - Google Patents

Download PDF

Info

Publication number
JP2008521161A5
JP2008521161A5 JP2007524926A JP2007524926A JP2008521161A5 JP 2008521161 A5 JP2008521161 A5 JP 2008521161A5 JP 2007524926 A JP2007524926 A JP 2007524926A JP 2007524926 A JP2007524926 A JP 2007524926A JP 2008521161 A5 JP2008521161 A5 JP 2008521161A5
Authority
JP
Japan
Prior art keywords
carbon atoms
general formula
group
branched
fluorinated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2007524926A
Other languages
Japanese (ja)
Other versions
JP2008521161A (en
Filing date
Publication date
Priority claimed from JP2004227046A external-priority patent/JP2006049037A/en
Application filed filed Critical
Publication of JP2008521161A publication Critical patent/JP2008521161A/en
Publication of JP2008521161A5 publication Critical patent/JP2008521161A5/ja
Withdrawn legal-status Critical Current

Links

Claims (6)

少なくとも１種の非プロトン性溶剤と、
一般式、
Ｒ１−Ｏ−Ｒｆ１（式１）
（上式中、Ｒ１は炭素数１〜４の分岐していてもよいアルキル基であり、Ｒｆ１は炭素数５〜１０の分岐していてもよいフッ素化アルキル基である）、
一般式、
Ｒ２−Ｏ−（Ｒｆ２−Ｏ）ｎ−Ｒ３（式２）
（上式中、Ｒ２及びＲ３は各々独立して、炭素数１〜４の分岐していてもよいアルキル基であり、Ｒｆ２は炭素数３〜１０の分岐していてもよいフッ素化アルキレン基であり、ｎは１〜３の整数である）、または、
一般式、
Ｒｆｈ１−Ｏ−Ａ−Ｏ−Ｒｆｈ２（式３）
（上式中、Ｒｆｈ１は及びＲｆｈ２は各々独立して、少なくとも１つの水素を持つ炭素数３〜９の分岐していてもよいフッ素化アルキル基であって、さらにエーテル酸素を含んでいてもよく、Ａは炭素数１〜８の分岐していてもよいアルキレン基である）、
により示される、沸点が８０℃以上の少なくとも１種のフッ素化エーテルと、
を含む、電気化学エネルギーデバイス用非水電解液のための非水混合溶媒。 At least one aprotic solvent; and
General formula,
R 1 —O—R f1 (Formula 1)
(Wherein R 1 is an optionally branched alkyl group having 1 to 4 carbon atoms, and R f1 is an optionally fluorinated alkyl group having 5 to 10 carbon atoms),
General formula,
R 2 —O— (R f2 —O) n —R 3 (Formula 2)
(In the above formula, R 2 and R 3 are each independently an alkyl group having 1 to 4 carbon atoms which may be branched, and R f2 is a fluorinated group having 3 to 10 carbon atoms which may be branched. An alkylene group and n is an integer of 1 to 3), or
General formula,
R fh1 —O—A—O—R fh2 (Formula 3)
( Wherein R fh1 and R fh2 are each independently a fluorinated alkyl group having 3 to 9 carbon atoms and having at least one hydrogen atom, and further containing ether oxygen. A is an optionally branched alkylene group having 1 to 8 carbon atoms),
At least one fluorinated ether having a boiling point of 80 ° C. or higher represented by
A non-aqueous mixed solvent for a non-aqueous electrolyte for an electrochemical energy device. 前記非プロトン性溶媒は、炭酸エチレン、炭酸プロピレン、炭酸ブチレン、一般式ＲｘＯＣＯＯＲｙ（Ｒｘ及びＲｙは各々同じであるかまたは異なり、直鎖または分岐した炭素数１〜３のアルキル基である）で表される炭酸エステル、γ−ブチロラクトン、１，２−ジメトキシエタン、ジグライム、トリグライム、テトラグライム、テトラヒドロフラン、アルキル置換テトラヒドロフラン、１，３−ジオキソラン、アルキル置換１，３−ジオキソラン、テトラヒドロピラン及びアルキル置換ヒドロピランの群から選ばれる少なくとも一つである、請求項１記載の非水混合溶媒。 The aprotic solvent is ethylene carbonate, propylene carbonate, butylene carbonate, general formula R x OCOOR y (R x and R y are the same or different, and each is a linear or branched alkyl group having 1 to 3 carbon atoms. Carbonate ester, γ-butyrolactone, 1,2-dimethoxyethane, diglyme, triglyme, tetraglyme, tetrahydrofuran, alkyl-substituted tetrahydrofuran, 1,3-dioxolane, alkyl-substituted 1,3-dioxolane, tetrahydropyran And the non-aqueous mixed solvent according to claim 1, which is at least one selected from the group consisting of alkyl-substituted hydropyrans. 少なくとも一つのフッ素原子を有する有機化合物であって、炭素原子の他にＢ，Ｎ，Ｏ，Ｓｉ，Ｐ，Ｓのいずれかの原子を含んでいてもよい有機化合物をさらに含む、請求項１又は２記載の非水混合溶媒。 An organic compound having at least one fluorine atom, B in addition to carbon atoms, further comprising N, O, Si, P, a good organic compound also include any atom of S, claim 1 or non-aqueous solvent mixture of 2, wherein. 請求項１〜３のいずれか１項記載の非水混合溶媒に、イオン解離可能な支持電解質が溶解している、電気化学エネルギーデバイス用非水電解液。 A nonaqueous electrolytic solution for electrochemical energy devices, wherein a supporting electrolyte capable of ion dissociation is dissolved in the nonaqueous mixed solvent according to any one of claims 1 to 3 . 前記イオン解離可能な支持電解質は一般式ＸＹ、
（式中、Ｘは一般式（ＲｆaＳＯ2）（ＲｆbＳＯ2）Ｎ-（ここで、Ｒｆa及びＲｆｂは各々同じまたは異なる直鎖または分岐した炭素数１〜４のフッ素化アルキル基である）で表される化合物、一般式（ＲｆｃＳＯ2）（ＲｆｄＳＯ2）（ＲｆｅＳＯ2）Ｃ-（ここで、Ｒｆｃ、Ｒｆｄ及びＲｆｅは各々同じまたは異なる直鎖または分岐した炭素数１〜４のフッ素化アルキル基である）で表される化合物、一般式ＲｆｆＳＯ3 -（ここで、Ｒｆｆは直鎖または分岐した炭素数１〜４のフッ素化アルキル基である）で表される化合物、ＰＦ6 -，ＣｌＯ4 -，ＢＦ4 -及びＡｓＦ6 -からなる群より選ばれる一つまたは複数であり、Ｙは１種類または複数種の陽イオンである）である塩である、請求項４記載の非水電解液。 The ion dissociable supporting electrolyte has the general formula XY,
(Wherein X is a general formula (Rf a SO 2 ) (Rf b SO 2 ) N − (where Rf a and Rf b are the same or different linear or branched fluorinated alkyl having 1 to 4 carbon atoms, respectively) A compound represented by the general formula (Rf c SO 2 ) (Rf d SO 2 ) (Rf e SO 2 ) C − (where Rf c , Rf d and Rf e are the same or different A compound represented by the general formula Rf f SO 3 − (wherein Rf f is a linear or branched fluorinated group having 1 to 4 carbon atoms). An alkyl group), one or more selected from the group consisting of PF 6 − , ClO 4 − , BF 4 − and AsF 6 − , and Y is one or more cations. The nonaqueous electrolytic solution according to claim 4 , which is a salt. 請求項４又は５記載の非水電解液と接触しているアノードとエレクトロードとを含む電気化学エネルギーデバイス。 An electrochemical energy device comprising an anode and an electrode in contact with the non-aqueous electrolyte according to claim 4 or 5 .
JP2007524926A 2004-08-03 2005-08-03 Non-aqueous electrolyte for electrochemical energy devices Withdrawn JP2008521161A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2004227046A JP2006049037A (en) 2004-08-03 2004-08-03 Nonaqueous electrolyte for electrochemical energy device
PCT/US2005/027482 WO2006017533A2 (en) 2004-08-03 2005-08-03 Nonaqueous electrolytic solution for electrochemical energy devices

Publications (2)

Publication Number Publication Date
JP2008521161A JP2008521161A (en) 2008-06-19
JP2008521161A5 true JP2008521161A5 (en) 2008-09-04

Family

ID=35134353

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2004227046A Pending JP2006049037A (en) 2004-08-03 2004-08-03 Nonaqueous electrolyte for electrochemical energy device
JP2007524926A Withdrawn JP2008521161A (en) 2004-08-03 2005-08-03 Non-aqueous electrolyte for electrochemical energy devices

Family Applications Before (1)

Application Number Title Priority Date Filing Date
JP2004227046A Pending JP2006049037A (en) 2004-08-03 2004-08-03 Nonaqueous electrolyte for electrochemical energy device

Country Status (6)

Country Link
US (1) US20090130567A1 (en)
EP (3) EP2068388A1 (en)
JP (2) JP2006049037A (en)
KR (1) KR20070059080A (en)
CN (1) CN1993848B (en)
WO (1) WO2006017533A2 (en)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006216361A (en) * 2005-02-03 2006-08-17 Three M Innovative Properties Co Electrolytic solution for lithium battery
JP4822265B2 (en) * 2006-03-13 2011-11-24 独立行政法人産業技術総合研究所 Fluorine-containing polyether compound and method for producing the same
DE102006016185A1 (en) * 2006-04-06 2007-10-11 Bayerische Motoren Werke Ag Control device for motor vehicles for learning the autonomous driving of a given ideal line
JP5206408B2 (en) * 2006-07-13 2013-06-12 ダイキン工業株式会社 Electrochemical devices
US7737307B2 (en) 2007-08-06 2010-06-15 E. I. Du Pont De Nemours And Company Fluorinated nonionic surfactants
CA2719405A1 (en) 2008-04-28 2009-11-05 Asahi Glass Company, Limited Nonaqueous electrolyte for secondary cell, and secondary cell
JP5253905B2 (en) * 2008-06-30 2013-07-31 パナソニック株式会社 Non-aqueous electrolyte and non-aqueous electrolyte secondary battery
CN102365781B (en) * 2009-03-27 2013-05-08 旭硝子株式会社 Electrolyte solution for electrical energy storage devices, and electrical energy storage device
EP2442397B1 (en) * 2009-06-10 2016-10-05 Asahi Kasei Kabushiki Kaisha Electrolytic solution and lithium-ion secondary battery utilizing the same
CN102498606A (en) 2009-09-11 2012-06-13 旭硝子株式会社 Non-aqueous electrolytic solution for power storage device, and power storage device
JP5704633B2 (en) 2009-09-29 2015-04-22 Ｎｅｃエナジーデバイス株式会社 Secondary battery
CN102598390A (en) * 2009-10-27 2012-07-18 旭硝子株式会社 Nonaqueous electrolyte solution for secondary battery, and secondary battery
KR101117699B1 (en) * 2009-11-19 2012-02-24 삼성에스디아이 주식회사 Electrolytic solution for lithium battery and lithium battery employing the same
US20120321940A1 (en) * 2010-03-26 2012-12-20 Daisuke Kawasaki Nonaqueous electrolyte secondary battery
JP5848545B2 (en) * 2011-08-08 2016-01-27 三星エスディアイ株式会社Ｓａｍｓｕｎｇ ＳＤＩ Ｃｏ．，Ｌｔｄ． Secondary battery separator layer and secondary battery
JP6123682B2 (en) * 2012-02-03 2017-05-10 日本電気株式会社 Lithium secondary battery
US8778077B2 (en) * 2012-02-29 2014-07-15 Skc Inc. Solvent for heat-shrinkable polyester-based labels
CN103367806A (en) * 2012-03-27 2013-10-23 中国科学院宁波材料技术与工程研究所 Novel electrolyte system of lithium ion battery
EP2833468B1 (en) 2012-03-27 2017-11-29 Asahi Glass Company, Limited Non-aqueous electrolyte solution for secondary batteries, and lithium-ion secondary battery
US9847551B2 (en) * 2012-06-08 2017-12-19 Nec Corporation Lithium-ion secondary battery
US9040203B2 (en) * 2013-01-16 2015-05-26 Samsung Sdi Co., Ltd. Lithium battery
JP6304876B2 (en) * 2013-03-28 2018-04-04 本田技研工業株式会社 Lithium air battery
WO2015046175A1 (en) * 2013-09-24 2015-04-02 旭硝子株式会社 Nonaqueous liquid electrolyte for use in secondary battery, and lithium-ion secondary battery
US9853323B2 (en) 2013-10-31 2017-12-26 Samsung Electronics Co., Ltd. Positive electrode for lithium-ion secondary battery, and lithium-ion secondary battery
WO2015078791A1 (en) 2013-11-28 2015-06-04 Solvay Specialty Polymers Italy S.P.A. Electrolyte compositions for lithium batteries
CN103972587A (en) * 2014-05-15 2014-08-06 上海空间电源研究所 Electrolyte with high flame retardant property and electrochemical property and lithium ion battery
EP2950380B1 (en) 2014-05-27 2017-04-12 Samsung Electronics Co., Ltd Electrolyte for lithium air battery and lithium air battery including the same
WO2016152425A1 (en) 2015-03-25 2016-09-29 日本電気株式会社 Hydrofluoroether compound, nonaqueous electrolyte solution and lithium ion secondary battery
US10707526B2 (en) 2015-03-27 2020-07-07 New Dominion Enterprises Inc. All-inorganic solvents for electrolytes
CN105070528B (en) * 2015-07-16 2017-12-22 湖南中大新能源科技有限公司 A kind of ultracapacitor electrolyte
CN106252723B (en) * 2016-08-29 2019-03-19 宁德市凯欣电池材料有限公司 The method for producing lithium-ion battery electrolytes
US10707531B1 (en) 2016-09-27 2020-07-07 New Dominion Enterprises Inc. All-inorganic solvents for electrolytes
CN110637388B (en) * 2017-05-18 2023-03-24 日本电气株式会社 Electrolyte for lithium ion secondary battery and lithium ion secondary battery using same
JP7287252B2 (en) * 2019-04-25 2023-06-06 株式会社豊田自動織機 Electrolyte and lithium ion secondary battery
WO2021124958A1 (en) * 2019-12-16 2021-06-24 株式会社村田製作所 Electrochemical capacitor
GB202014633D0 (en) * 2020-09-17 2020-11-04 Mexichem Fluor Sa De Cv Composition
WO2023100767A1 (en) * 2021-11-30 2023-06-08 パナソニックＩｐマネジメント株式会社 Lithium secondary battery

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2555378B2 (en) * 1987-10-30 1996-11-20 株式会社ネオス Synthetic Fluoroalkoxyethanes
JPH06290809A (en) 1993-03-31 1994-10-18 Matsushita Electric Ind Co Ltd Non-aqueous electrolyte secondary battery
JPH0837024A (en) * 1994-07-26 1996-02-06 Asahi Chem Ind Co Ltd Nonaqueous electrolytic secondary battery
JPH0864240A (en) 1994-08-25 1996-03-08 Sanyo Electric Co Ltd Nonaqueous electrolyte battery
TW360987B (en) * 1995-07-25 1999-06-11 Sumitomo Chemical Co Non-aqueous electrolyte and lithium secondary battery
JPH09293533A (en) 1996-04-26 1997-11-11 Mitsubishi Chem Corp Nonaqueous electrolyte secondary battery
DE19619233A1 (en) * 1996-05-13 1997-11-20 Hoechst Ag Fluorine-containing solvents for lithium batteries with increased security
TW434923B (en) * 1998-02-20 2001-05-16 Hitachi Ltd Lithium secondary battery and liquid electrolyte for the battery
JP3726533B2 (en) 1998-02-20 2005-12-14 株式会社日立製作所 Lithium secondary battery, its electrolyte and electrical equipment
KR100605344B1 (en) * 1998-09-11 2006-07-28 미쓰이 가가쿠 가부시키가이샤 Nonaqueous electrolytic liquid and secondary battery with nonaqueous electrolytic liquid
JP2000294281A (en) 1999-04-08 2000-10-20 Hitachi Maxell Ltd Nonaqueous electrolyte secondary battery
JP2001085058A (en) 1999-09-20 2001-03-30 Hitachi Ltd Nonaqueous electrolyte and lithium primary battery, lithium secondary battery and electrochemical capacitor using this and high polymer electrolyte and polymer secondary battery using this
US7229718B2 (en) * 2002-08-22 2007-06-12 Samsung Sdi Co., Ltd. Electrolyte for rechargeable lithium battery and rechargeable lithium battery comprising same
JP4204281B2 (en) * 2002-09-04 2009-01-07 三洋電機株式会社 Nonaqueous electrolyte secondary battery

Similar Documents

Publication Publication Date Title
JP2008521161A5 (en)
CN105474452B (en) Nonaqueous electrolyte for battery and lithium secondary battery
JP7005587B2 (en) Non-aqueous electrolyte composition
US10316006B2 (en) Heterocyclic ionic liquids
CN107949948B (en) Non-aqueous electrolyte composition containing lithium oxalate phosphate
CN104022310B (en) Lithium rechargeable battery and the lithium ion battery containing this electrolyte
EP3050872B1 (en) Fluorinated sulfonamide as electrolyte (co-)solvent for lithium-ion batteries
CN108270035B (en) Battery electrolyte containing high-concentration lithium salt
WO2006106657A1 (en) Electrolyte solution
Roy et al. Lithium Borate Ester Salts for Electrolyte Application in Next‐Generation High Voltage Lithium Batteries
EP3025389A1 (en) Oxiranyl derivatives as additives for electrolytes in lithium-ion batteries
JP2008069102A (en) Lithium salt
CN106486696A (en) A kind of non-aqueous electrolyte for lithium ion cell and lithium ion battery
CN106816633A (en) A kind of pseudo- high concentration esters lithium-sulfur cell electrolyte and lithium-sulfur cell
JP5509627B2 (en) Power storage device
JP5074817B2 (en) BF3 complex and method for producing BF3 complex
JP4929766B2 (en) Electrolyte
JP5526491B2 (en) Non-aqueous electrolyte for primary battery and non-aqueous electrolyte primary battery using the same
JP2006196390A (en) Ionic liquid composition and electrochemical device using it
CN109473721A (en) A kind of high-voltage electrolyte additive, high-voltage electrolyte and lithium ion battery
JPWO2005123656A1 (en) NOVEL METHYL CARBONATES, PROCESS FOR PRODUCING THE SAME, NON-AQUEOUS ELECTROLYTE SOLUTION
JP2015115221A (en) Electrolyte for sodium ion batteries and sodium ion battery
Su et al. Terminally fluorinated glycol ether electrolyte for lithium metal batteries
EP2163537B1 (en) Liquid electrolyte for an electrochemical device
CN108539268B (en) High specific energy non-aqueous electrolyte for lithium cell