JP2008520426A - 水素分離のためのイオンおよび電子伝導性の酸化物混合複合体 - Google Patents

水素分離のためのイオンおよび電子伝導性の酸化物混合複合体 Download PDF

Info

Publication number
JP2008520426A
JP2008520426A JP2007543065A JP2007543065A JP2008520426A JP 2008520426 A JP2008520426 A JP 2008520426A JP 2007543065 A JP2007543065 A JP 2007543065A JP 2007543065 A JP2007543065 A JP 2007543065A JP 2008520426 A JP2008520426 A JP 2008520426A
Authority
JP
Japan
Prior art keywords
membrane
phase
doped
oxide
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2007543065A
Other languages
English (en)
Japanese (ja)
Other versions
JP2008520426A5 (https=
Inventor
ゴーパラン，スリカンス
パル，ユーデイ，ビー．
カースキーヤン，アンナマレー
ヘンドン，キュイ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boston University
Original Assignee
Boston University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boston University filed Critical Boston University
Publication of JP2008520426A publication Critical patent/JP2008520426A/ja
Publication of JP2008520426A5 publication Critical patent/JP2008520426A5/ja
Withdrawn legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0041—Inorganic membrane manufacture by agglomeration of particles in the dry state
    • B01D67/00411—Inorganic membrane manufacture by agglomeration of particles in the dry state by sintering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B01D71/0271—Perovskites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0073—Sealings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02—Preparation of oxygen
    • C01B13/0229—Purification or separation processes
    • C01B13/0248—Physical processing only
    • C01B13/0251—Physical processing only by making use of membranes
    • C01B13/0255—Physical processing only by making use of membranes characterised by the type of membrane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion characterised by membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0681—Reactant purification by the use of electrochemical cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0687—Reactant purification by the use of membranes or filters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/22—Thermal or heat-resistance properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/26—Electrical properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C01B2203/041—In-situ membrane purification during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00—Purification or separation of specific gases
    • C01B2210/0043—Impurity removed
    • C01B2210/0053—Hydrogen
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Analytical Chemistry (AREA)
  • Sustainable Development (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Conductive Materials (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Non-Insulated Conductors (AREA)
JP2007543065A 2004-11-23 2005-10-21 水素分離のためのイオンおよび電子伝導性の酸化物混合複合体 Withdrawn JP2008520426A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US63036804P 2004-11-23 2004-11-23
PCT/US2005/038081 WO2007011401A2 (en) 2004-11-23 2005-10-21 Composite mixed oxide ionic and electronic conductors for hydrogen separation

Publications (2)

Publication Number Publication Date
JP2008520426A true JP2008520426A (ja) 2008-06-19
JP2008520426A5 JP2008520426A5 (https=) 2008-12-11

Family

ID=37546907

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2007543065A Withdrawn JP2008520426A (ja) 2004-11-23 2005-10-21 水素分離のためのイオンおよび電子伝導性の酸化物混合複合体

Country Status (4)

Country Link
US (1) US7588626B2 (https=)
EP (1) EP1814646A2 (https=)
JP (1) JP2008520426A (https=)
WO (1) WO2007011401A2 (https=)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008251266A (ja) * 2007-03-29 2008-10-16 Tdk Corp 複合型混合導電体
JP2009143792A (ja) * 2007-11-07 2009-07-02 Air Products & Chemicals Inc 混合伝導性イオン輸送膜における動的分解の制御
KR101096058B1 (ko) 2009-02-05 2011-12-19 전남대학교산학협력단 복합 기능성 수소 분리막, 이를 포함하는 수소 생산 시스템 및 이들을 이용한 수소 생산방법
JP2014050776A (ja) * 2012-09-05 2014-03-20 Ngk Spark Plug Co Ltd 酸素透過膜
JP2018002558A (ja) * 2016-07-05 2018-01-11 日本特殊陶業株式会社 改質装置
JP2024518222A (ja) * 2021-05-03 2024-05-01 ユティリティ・グローバル・インコーポレイテッド 電気化学水性ガスシフト反応器及び使用方法

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8012380B2 (en) * 2004-03-05 2011-09-06 Ceramatec, Inc. Proton conducting ceramic membranes for hydrogen separation
US20070245897A1 (en) * 2006-04-20 2007-10-25 Innovene Usa Electron, hydrogen and oxygen conveying membranes
US20100234650A1 (en) * 2006-06-21 2010-09-16 Bp P.L.C. Oxygen separation membrane
JP5228353B2 (ja) * 2007-03-29 2013-07-03 Ｔｄｋ株式会社 複合型混合導電体
US20080248363A1 (en) * 2007-04-06 2008-10-09 Alfred University Composite electrolyte material having high ionic conductivity and depleted electronic conductivity and method for producing same
DE102007037203B4 (de) * 2007-07-30 2009-06-10 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Bestimmung von Diffusions- und/oder Austauschkoeffizienten eines Werkstoffs
US8652947B2 (en) * 2007-09-26 2014-02-18 Wang Nang Wang Non-polar III-V nitride semiconductor and growth method
US8118934B2 (en) * 2007-09-26 2012-02-21 Wang Nang Wang Non-polar III-V nitride material and production method
WO2009072127A2 (en) * 2007-12-06 2009-06-11 Technion Research & Development Foundation Ltd. Self-heated dense ceramic tubes for separating gases
JP2011519114A (ja) * 2007-12-21 2011-06-30 サン−ゴバン セラミックス アンド プラスティクス，インコーポレイティド 燃料電池スタックのためのセラミックインターコネクト
US8323463B2 (en) * 2010-01-22 2012-12-04 Praxair Technology, Inc. Catalyst containing oxygen transport membrane
SE535245C2 (sv) * 2010-08-02 2012-06-05 Gett Fuel Cells Internat Ab Bränsleceller utan ektrolyter
US9561476B2 (en) 2010-12-15 2017-02-07 Praxair Technology, Inc. Catalyst containing oxygen transport membrane
US9486735B2 (en) 2011-12-15 2016-11-08 Praxair Technology, Inc. Composite oxygen transport membrane
EP2791082B1 (en) 2011-12-15 2021-01-20 Praxair Technology, Inc. Method of producing composite oxygen transport membrane
EP2935155B1 (en) 2012-12-19 2019-02-13 Praxair Technology Inc. Method for sealing an oxygen transport membrane assembly
US9453644B2 (en) 2012-12-28 2016-09-27 Praxair Technology, Inc. Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream
US9296671B2 (en) 2013-04-26 2016-03-29 Praxair Technology, Inc. Method and system for producing methanol using an integrated oxygen transport membrane based reforming system
US9938145B2 (en) 2013-04-26 2018-04-10 Praxair Technology, Inc. Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system
US9611144B2 (en) 2013-04-26 2017-04-04 Praxair Technology, Inc. Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion
US9212113B2 (en) 2013-04-26 2015-12-15 Praxair Technology, Inc. Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source
WO2014201274A1 (en) 2013-06-12 2014-12-18 Adam Clayton Powell Improved liquid metal electrodes for gas separation
EP3055054A2 (en) 2013-10-07 2016-08-17 Praxair Technology Inc. Ceramic oxygen transport membrane array reactor and reforming method
RU2661581C2 (ru) 2013-10-08 2018-07-17 Праксайр Текнолоджи, Инк. Система и способ регулирования температуры в реакторе на основе кислородпроводящих мембран
US20160362805A1 (en) * 2013-11-01 2016-12-15 Adam Clayton Powell, IV Methods and apparatuses for increasing energy efficiency and improving membrane robustness in primary metal production
CA2926757C (en) 2013-12-02 2020-02-25 Praxair Technology, Inc. Method and system for producing hydrogen using an oxygen transport membrane based reforming system with secondary reforming
CA2937943A1 (en) 2014-02-12 2015-08-20 Praxair Technology, Inc. Oxygen transport membrane reactor based method and system for generating electric power
US10822234B2 (en) 2014-04-16 2020-11-03 Praxair Technology, Inc. Method and system for oxygen transport membrane enhanced integrated gasifier combined cycle (IGCC)
WO2016057164A1 (en) 2014-10-07 2016-04-14 Praxair Technology, Inc Composite oxygen ion transport membrane
US10441922B2 (en) 2015-06-29 2019-10-15 Praxair Technology, Inc. Dual function composite oxygen transport membrane
US10118823B2 (en) 2015-12-15 2018-11-06 Praxair Technology, Inc. Method of thermally-stabilizing an oxygen transport membrane-based reforming system
US9938146B2 (en) 2015-12-28 2018-04-10 Praxair Technology, Inc. High aspect ratio catalytic reactor and catalyst inserts therefor
CN109070014A (zh) 2016-04-01 2018-12-21 普莱克斯技术有限公司 含催化剂的氧气传送膜
US11136238B2 (en) 2018-05-21 2021-10-05 Praxair Technology, Inc. OTM syngas panel with gas heated reformer
US11761096B2 (en) * 2018-11-06 2023-09-19 Utility Global, Inc. Method of producing hydrogen
US11289650B2 (en) * 2019-03-04 2022-03-29 International Business Machines Corporation Stacked access device and resistive memory
WO2023278252A1 (en) 2021-07-02 2023-01-05 Utility Global, Inc. Production of hydrogen via electrochemical reforming

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH441776A (de) 1966-05-17 1967-08-15 Marincek Borut Verfahren zur Herstellung von Metallen durch Schmelzflusselektrolyse von Oxiden
US4108743A (en) 1977-05-02 1978-08-22 Ford Motor Company Method and apparatus for separating a metal from a salt thereof
CA1203950A (en) 1982-12-23 1986-04-29 Harold S. Cox Anti-static articles
US5714091A (en) 1987-03-13 1998-02-03 The Standard Oil Company Process for the partial oxydation of hydrocarbons
US6287432B1 (en) 1987-03-13 2001-09-11 The Standard Oil Company Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions
US5306411A (en) 1989-05-25 1994-04-26 The Standard Oil Company Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions
US4804448A (en) 1987-06-24 1989-02-14 Eltron Research, Inc. Apparatus for simultaneous generation of alkali metal species and oxygen gas
US4908113A (en) 1987-09-01 1990-03-13 Institute Of Gas Technology Apparatus for the electrochemical separation of oxygen
US4865925A (en) 1987-12-14 1989-09-12 Hughes Aircraft Company Gas permeable electrode for electrochemical system
CA2012009C (en) 1989-03-16 1999-01-19 Tadashi Ogasawara Process for the electrolytic production of magnesium
JP2882104B2 (ja) * 1991-07-17 1999-04-12 松下電器産業株式会社 プロトン伝導体およびその製造方法
US5380467A (en) 1992-03-19 1995-01-10 Westinghouse Electric Company Composition for extracting oxygen from fluid streams
US5273628A (en) 1992-05-11 1993-12-28 Gas Research Institute Mixed ionic-electronic conductors for oxygen separation and electrocatalysis
US5478444A (en) * 1992-05-11 1995-12-26 Gas Research Institute Composite mixed ionic-electronic conductors for oxygen separation and electrocatalysis
US5616223A (en) * 1992-05-11 1997-04-01 Gas Research Institute Mixed ionic-electronic conducting composites for oxygen separation and electrocatalysis
US5509362A (en) 1992-12-11 1996-04-23 Energy And Environmental Research Corporation Method and apparatus for unmixed combustion as an alternative to fire
US5312525A (en) 1993-01-06 1994-05-17 Massachusetts Institute Of Technology Method for refining molten metals and recovering metals from slags
US6033632A (en) 1993-12-08 2000-03-07 Eltron Research, Inc. Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them
US5447555A (en) 1994-01-12 1995-09-05 Air Products And Chemicals, Inc. Oxygen production by staged mixed conductor membranes
US5520799A (en) 1994-09-20 1996-05-28 Mobil Oil Corporation Distillate upgrading process
AU5524296A (en) 1995-04-25 1996-11-18 Energy And Environmental Research Corporation Methods and systems for heat transfer by unmixed combustion
US5962122A (en) 1995-11-28 1999-10-05 Hoechst Celanese Corporation Liquid crystalline polymer composites having high dielectric constant
US5976345A (en) 1997-01-06 1999-11-02 Boston University Method and apparatus for metal extraction and sensor device related thereto
US6162334A (en) 1997-06-26 2000-12-19 Alcoa Inc. Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum
US6165553A (en) 1998-08-26 2000-12-26 Praxair Technology, Inc. Method of fabricating ceramic membranes
US6153163A (en) * 1998-06-03 2000-11-28 Praxair Technology, Inc. Ceramic membrane reformer
US6296687B2 (en) * 1999-04-30 2001-10-02 Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Natural Resources Hydrogen permeation through mixed protonic-electronic conducting materials
US6235417B1 (en) * 1999-04-30 2001-05-22 Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Natural Resources Two-phase hydrogen permeation membrane
US6471921B1 (en) * 1999-05-19 2002-10-29 Eltron Research, Inc. Mixed ionic and electronic conducting ceramic membranes for hydrocarbon processing
US6146549A (en) 1999-08-04 2000-11-14 Eltron Research, Inc. Ceramic membranes for catalytic membrane reactors with high ionic conductivities and low expansion properties
US6541159B1 (en) 1999-08-12 2003-04-01 Reveo, Inc. Oxygen separation through hydroxide-conductive membrane
US20040157075A1 (en) * 2000-06-09 2004-08-12 Building Materials Investment Corporation Single ply thermoplastic polyolefin (TPO) roofing membranes having superior heat seam peel strengths and low temperature flexibility
US6677070B2 (en) 2001-04-19 2004-01-13 Hewlett-Packard Development Company, L.P. Hybrid thin film/thick film solid oxide fuel cell and method of manufacturing the same
US7393384B2 (en) * 2002-04-18 2008-07-01 The Trustees Of Boston University Hydrogen separation using oxygen ion-electron mixed conduction membranes
US6726893B2 (en) * 2002-09-17 2004-04-27 The University Of Chicago Hydrogen production by high-temperature water splitting using electron-conducting membranes
CN100575063C (zh) * 2003-07-10 2009-12-30 普莱克斯技术有限公司 复合氧离子传导元件
US7258820B2 (en) * 2004-03-05 2007-08-21 Ceramatec, Inc. Ceramic mixed protonic/electronic conducting membranes for hydrogen separation
JP2008516399A (ja) 2004-10-05 2008-05-15 シーティーピー ハイドロジェン コーポレイション 電気化学システム用の伝導性セラミック
US20060234098A1 (en) 2005-04-18 2006-10-19 Clean Coal Energy, Llc Direct carbon fuel cell with molten anode
US20070245897A1 (en) * 2006-04-20 2007-10-25 Innovene Usa Electron, hydrogen and oxygen conveying membranes

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008251266A (ja) * 2007-03-29 2008-10-16 Tdk Corp 複合型混合導電体
JP2009143792A (ja) * 2007-11-07 2009-07-02 Air Products & Chemicals Inc 混合伝導性イオン輸送膜における動的分解の制御
KR101096058B1 (ko) 2009-02-05 2011-12-19 전남대학교산학협력단 복합 기능성 수소 분리막, 이를 포함하는 수소 생산 시스템 및 이들을 이용한 수소 생산방법
JP2014050776A (ja) * 2012-09-05 2014-03-20 Ngk Spark Plug Co Ltd 酸素透過膜
JP2018002558A (ja) * 2016-07-05 2018-01-11 日本特殊陶業株式会社 改質装置
JP2024518222A (ja) * 2021-05-03 2024-05-01 ユティリティ・グローバル・インコーポレイテッド 電気化学水性ガスシフト反応器及び使用方法
JP7776518B2 (ja) 2021-05-03 2025-11-26 ユティリティ・グローバル・インコーポレイテッド 電気化学水性ガスシフト反応器及び使用方法

Also Published As

Publication number Publication date
EP1814646A2 (en) 2007-08-08
US20060191408A1 (en) 2006-08-31
US7588626B2 (en) 2009-09-15
WO2007011401A3 (en) 2007-04-12
WO2007011401A2 (en) 2007-01-25

Similar Documents

Publication Publication Date Title
US7588626B2 (en) Composite mixed oxide ionic and electronic conductors for hydrogen separation
Liu et al. Structure, sinterability, chemical stability and conductivity of proton-conducting BaZr0. 6M0. 2Y0. 2O3− δ electrolyte membranes: the effect of the M dopant
CA2307005C (en) Hydrogen permeation through mixed protonic-electronic conducting materials
US7479242B2 (en) Complex mixed conductor containing Pr-doped cerium oxide and spinel-type ferrite and its preparation method
Liu et al. High-performance Ni–BaZr0. 1Ce0. 7Y0. 1Yb0. 1O3− δ (BZCYYb) membranes for hydrogen separation
US7393384B2 (en) Hydrogen separation using oxygen ion-electron mixed conduction membranes
JP5509077B2 (ja) 水素分離のための水素イオン伝導セラミック膜
US20100015014A1 (en) Mixed Ionic and Electronic Conducting Membrane
US6056807A (en) Fluid separation devices capable of operating under high carbon dioxide partial pressures which utilize creep-resistant solid-state membranes formed from a mixed conducting multicomponent metallic oxide
Escolástico et al. Improvement of transport properties and hydrogen permeation of chemically-stable proton-conducting oxides based on the system BaZr 1-xy Y x M y O 3-δ
Garcia-Fayos et al. Dual-phase membrane based on LaCo0. 2Ni0. 4Fe0. 4O3− x-Ce0. 8Gd0. 2O2− x composition for oxygen permeation under CO2/SO2-rich gas environments
Partovi et al. Enhanced oxygen permeability of novel Cu-containing CO2-tolerant dual-phase membranes
Montaleone et al. On the compatibility of dual phase BaCe0. 65Zr0. 2Y0. 15O3-based membrane for hydrogen separation application
Chen et al. Effect of the La/W ratio in lanthanum tungstate on the structure, stability and hydrogen permeation properties
Dong et al. CO2-tolerant mixed conducting oxide for catalytic membrane reactor
Yoon et al. Highly stable dual-phase Y0. 8Ca0. 2Cr0. 8Co0. 2O3–Sm0. 2Ce0. 8O1. 9 ceramic composite membrane for oxygen separation
CA2654364A1 (en) Oxygen separation membrane
Son et al. Exceptional performance of water splitting coupled with methane partial oxidation by oxygen-permeable membrane reactor
Li et al. SDC‐SCFZ dual‐phase ceramics: structure, electrical conductivity, thermal expansion, and O2 permeability
US20130216938A1 (en) Co2 tolerant, mixed conductive oxide and uses thereof for hydrogen separation
Ramasamy et al. Oxygen permeability of mixed-conducting Ce0. 8Tb0. 2O2− δ membranes: Effects of ceramic microstructure and sintering temperature
Dong et al. SrAl2O4-improved SrCo0. 8Fe0. 2O3− δ mixed-conducting membrane for effective production of hydrogen from methane
Vivet et al. La (1− x) SrxFe (1− y) GayO3− δ perovskite membrane: Oxygen semi-permeation, thermal expansion coefficient and chemical stability under reducing conditions
Gopalan Using ceramic mixed ionic and electronic conductors for gas separation
Gohar et al. Revolutionizing energy systems with perovskite proton-conducting materials: advances and applications in solid oxide fuel cells

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20081021

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20081021

RD02 Notification of acceptance of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7422

Effective date: 20081021

A761 Written withdrawal of application

Free format text: JAPANESE INTERMEDIATE CODE: A761

Effective date: 20090908