JP2008504986A - 被覆シート、その形成方法及びその物品 - Google Patents
被覆シート、その形成方法及びその物品 Download PDFInfo
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- JP2008504986A JP2008504986A JP2007519363A JP2007519363A JP2008504986A JP 2008504986 A JP2008504986 A JP 2008504986A JP 2007519363 A JP2007519363 A JP 2007519363A JP 2007519363 A JP2007519363 A JP 2007519363A JP 2008504986 A JP2008504986 A JP 2008504986A
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- 238000000034 method Methods 0.000 title claims description 9
- -1 polyol compound Chemical class 0.000 claims abstract description 103
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 42
- 239000004417 polycarbonate Substances 0.000 claims abstract description 42
- 229920005862 polyol Polymers 0.000 claims abstract description 33
- 229920003180 amino resin Polymers 0.000 claims abstract description 27
- 229920005989 resin Polymers 0.000 claims abstract description 23
- 239000011347 resin Substances 0.000 claims abstract description 23
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 78
- 239000010410 layer Substances 0.000 claims description 67
- 150000002009 diols Chemical class 0.000 claims description 49
- 238000000576 coating method Methods 0.000 claims description 36
- 239000011248 coating agent Substances 0.000 claims description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 28
- 229920003232 aliphatic polyester Polymers 0.000 claims description 27
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 26
- 125000001931 aliphatic group Chemical group 0.000 claims description 22
- 239000001257 hydrogen Substances 0.000 claims description 22
- 229910052739 hydrogen Inorganic materials 0.000 claims description 22
- 150000001412 amines Chemical class 0.000 claims description 19
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 17
- 239000004611 light stabiliser Substances 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 14
- 229920005668 polycarbonate resin Polymers 0.000 claims description 13
- 239000004431 polycarbonate resin Substances 0.000 claims description 13
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 10
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 229920000877 Melamine resin Polymers 0.000 claims description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 9
- 238000010521 absorption reaction Methods 0.000 claims description 8
- 150000001298 alcohols Chemical class 0.000 claims description 8
- 150000002431 hydrogen Chemical class 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 8
- 239000003381 stabilizer Substances 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 239000003086 colorant Substances 0.000 claims description 7
- 125000001424 substituent group Chemical group 0.000 claims description 7
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 5
- 229920005992 thermoplastic resin Polymers 0.000 claims description 5
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 3
- 150000001491 aromatic compounds Chemical class 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- 238000003475 lamination Methods 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 2
- ZQHJVIHCDHJVII-OWOJBTEDSA-N (e)-2-chlorobut-2-enedioic acid Chemical compound OC(=O)\C=C(\Cl)C(O)=O ZQHJVIHCDHJVII-OWOJBTEDSA-N 0.000 claims description 2
- CXJAFLQWMOMYOW-UHFFFAOYSA-N 3-chlorofuran-2,5-dione Chemical compound ClC1=CC(=O)OC1=O CXJAFLQWMOMYOW-UHFFFAOYSA-N 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 239000002518 antifoaming agent Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- 238000000748 compression moulding Methods 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 238000013003 hot bending Methods 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- 150000007974 melamines Chemical class 0.000 claims description 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 2
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 2
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 2
- 238000007639 printing Methods 0.000 claims description 2
- 239000011241 protective layer Substances 0.000 claims description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 238000003856 thermoforming Methods 0.000 claims description 2
- 238000007666 vacuum forming Methods 0.000 claims description 2
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 2
- 239000004609 Impact Modifier Substances 0.000 claims 1
- 238000003618 dip coating Methods 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid group Chemical class S(N)(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 claims 1
- 239000011253 protective coating Substances 0.000 abstract description 11
- 239000007795 chemical reaction product Substances 0.000 abstract description 9
- 239000000758 substrate Substances 0.000 abstract description 3
- 239000006096 absorbing agent Substances 0.000 description 30
- 238000001723 curing Methods 0.000 description 20
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 11
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 10
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 235000021317 phosphate Nutrition 0.000 description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 7
- 238000002835 absorbance Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- 239000012965 benzophenone Substances 0.000 description 6
- 239000008199 coating composition Substances 0.000 description 6
- 150000002989 phenols Chemical class 0.000 description 6
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 5
- 229930185605 Bisphenol Natural products 0.000 description 5
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 5
- 239000012964 benzotriazole Substances 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 4
- 229920003270 Cymel® Polymers 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 125000005842 heteroatom Chemical group 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 230000000717 retained effect Effects 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical group OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000008034 disappearance Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 125000000743 hydrocarbylene group Chemical group 0.000 description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920001610 polycaprolactone Polymers 0.000 description 3
- 238000012667 polymer degradation Methods 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 229910052724 xenon Inorganic materials 0.000 description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 2
- 0 *N(*)c1nc(N(*)*)nc(N(*)*)n1 Chemical compound *N(*)c1nc(N(*)*)nc(N(*)*)n1 0.000 description 2
- MQCPOLNSJCWPGT-UHFFFAOYSA-N 2,2'-Bisphenol F Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1O MQCPOLNSJCWPGT-UHFFFAOYSA-N 0.000 description 2
- SITYOOWCYAYOKL-UHFFFAOYSA-N 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(3-dodecoxy-2-hydroxypropoxy)phenol Chemical compound OC1=CC(OCC(O)COCCCCCCCCCCCC)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(C)=CC=2)C)=N1 SITYOOWCYAYOKL-UHFFFAOYSA-N 0.000 description 2
- ZSSVCEUEVMALRD-UHFFFAOYSA-N 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)phenol Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(C)=CC=2)C)=N1 ZSSVCEUEVMALRD-UHFFFAOYSA-N 0.000 description 2
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical group NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical group NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 125000002619 bicyclic group Chemical group 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 2
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
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- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- PYXKIBGUDPZSBQ-UHFFFAOYSA-N phenol;3,5,5-trimethylcyclohex-2-en-1-one Chemical compound OC1=CC=CC=C1.OC1=CC=CC=C1.CC1=CC(=O)CC(C)(C)C1 PYXKIBGUDPZSBQ-UHFFFAOYSA-N 0.000 description 2
- 238000001782 photodegradation Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920006289 polycarbonate film Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- HQEPZWYPQQKFLU-UHFFFAOYSA-N (2,6-dihydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC(O)=C1C(=O)C1=CC=CC=C1 HQEPZWYPQQKFLU-UHFFFAOYSA-N 0.000 description 1
- UXUFTKZYJYGMGO-CMCWBKRRSA-N (2s,3s,4r,5r)-5-[6-amino-2-[2-[4-[3-(2-aminoethylamino)-3-oxopropyl]phenyl]ethylamino]purin-9-yl]-n-ethyl-3,4-dihydroxyoxolane-2-carboxamide Chemical compound O[C@@H]1[C@H](O)[C@@H](C(=O)NCC)O[C@H]1N1C2=NC(NCCC=3C=CC(CCC(=O)NCCN)=CC=3)=NC(N)=C2N=C1 UXUFTKZYJYGMGO-CMCWBKRRSA-N 0.000 description 1
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 description 1
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical group NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C09D161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
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- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J7/04—Coating
- C08J7/054—Forming anti-misting or drip-proofing coatings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C—CHEMISTRY; METALLURGY
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Abstract
【選択図】 なし
Description
式中、R3は、所望に応じて1個以上のヘテロ原子で置換されていてもよいC2−C24ヒドロカルビレン基である。適当なポリオール化合物には、二価フェノール化合物、例えばレゾルシノール、2,2’−メチレンジフェノール、2,4’−メチレンジフェノール、4,4’−メチレンジフェノール、4,4’−イソプロピリデンジフェノール、4,4’−ジヒドロキシジフェニルスルホンなど;二価脂肪族アルコール、例えばエチレングリコール、ジエチレングリコール、トリエチレングリコール、テトラエチレングリコール、プロピレングリコール、1,3−プロパンジオール、1,4−ブタンジオール、1,5−ペンタンジオール、1,2,3−プロパントリオール、ペンタエリスリトール、ソルビトールなど;アルキド樹脂、例えばヒドロキシ官能性エポキシ樹脂;可溶性セルロール誘導体;遊離ヒドロキシ基を有するビニル重合体、例えばビニルアルコールの単独重合体及び共重合体、酢酸ビニルの単独重合体及び共重合体の部分加水分解物;オリゴマー状脂肪族ポリエステルジオール;オリゴマー状脂肪族ポリカーボネートジオール;オリゴマー状脂肪族ポリエステルカーボネートジオール;オリゴマー状脂肪族ポリウレタンジオールなど;及びこれらのポリオール化合物の混合物がある。一実施形態では、ポリオール化合物はヒドロキシ基に加えてカルボキシルもしくはアミノ基を含んでいてもよい。
式中、nは4〜約12である。具体的な脂肪族ジオールには、例えば、1,6−ヘキサンジオール、3−メチル−1,5−ペンタンジオール、2,2,4−トリメチル−1,5−ペンタンジオールなどがある。残りのジオールとして用いるのに適当なものには、例えば、短鎖脂肪族ジオール、具体的には1,3−ブタンジオール、1,3−プロピレングリコール、2,2−ジエチル−1,3−プロパンジオール、エチレングリコール、ネオペンチルグリコールなど;脂環式ジオール、具体的には4,4’−メチレンビス(シクロヘキサノール)、4,4’−イソプロピリデンビス(シクロヘキサノール)、シクロヘキサンジメタノールなど;芳香族ジオール、具体的にはフェニレンジプロパノールなど、並びにこれらの混合物がある。一実施形態では、オリゴマー状脂肪族ポリエステルジオールは、2つの酸基の間に4個以上の炭素原子が介在する脂肪族二酸と、2つのヒドロキシル基の間に4個以上の炭素原子が介在する脂肪族ジオールとの反応生成物である。オリゴマー状脂肪族ポリエステルジオールは、カプロラクトンのような脂肪族ラクトンと脂肪族ジオールとの反応で合成することもできる。一実施形態では、オリゴマー状脂肪族ポリエステルジオールは、数平均分子量が約200〜約4000AMUである。この範囲内で、分子量を特定すると約500AMU以上とすることができる。またこの範囲内で、分子量を特定すると約3000AMU以下、さらに特定すると約2500AMU以下とすることができる。オリゴマー状ポリエステルジオールを製造する方法としては、通常、当技術分野で公知のポリエステル製造方法が適当である。適当なオリゴマー状脂肪族ポリエステルジオールが、例えばBayer社からDESMOPHEN(登録商標)S1015−120(以前はRUCOFLEX(登録商標)S1015−120として販売)、Dow社からTone210として市販されている。
式中、R6はC2−C12アルキレン基である。オリゴマー状脂肪族ポリウレタンジオールは、当技術分野で公知のポリウレタン製造方法で製造することができる。適当なオリゴマー状脂肪族ポリウレタンジオールが、例えばKing Industries社からK−FLEX(登録商標)UD−320として市販されている。
式中、R12は各々独立にC1−C6ヒドロカルビルであるか、又は2つのR12基が結合してC2−C12ヒドロカルビレン基を形成してもよい。一実施形態では、3つのR12基中の炭素原子の和が約4〜約10、さらに特定すると約5〜約8である。代表的な三級アミンはトリエチルアミンである。適当な触媒安定剤にはさらに、芳香族複素環式アミン類、例えばピリジン、アミノアルカノール類、例えば2−メチルアミノエタノールなどもある。これらの触媒安定剤の混合物を使用してもよい。
被覆組成物処方
ポリオール化合物及びUV吸収剤の種類の異なる多数の硬化性被覆組成物を製造した。硬化性組成物は、5.3gのCYMEL(登録商標)303(ヘキサメトキシメチルメラミン、Cytec社製)、0.15gのp−トルエンスルホン酸、6.16gの1−メトキシ−2−プロパノール、6.16gの1−ブトキシ−2−プロパノール、0.59gのメタノール、0.75gの1−ブタノール、0.59gの2−プロパノール、0.05gのEFKA(登録商標)30、及び0.56g(固形分として)のUV吸収剤を含有した。したがって、UV吸収剤は被覆固形分に基づいて5%存在した。ポリオール化合物は、DESMOPHEN(登録商標)VP LS2391(脂肪族ポリエステルカーボネートジオール、Bayer社製)、DESMOPHEN(登録商標)S1015−120(脂肪族ポリエステルジオール、Bayer社製)、及びK−FLEX(登録商標)UD−320(脂肪族ポリウレタンジオール、Bayer社製)から選んだ。UV吸収剤は、CYASORB(登録商標)UV−531(ベンゾフェノン化合物、Cytec社製)、TINUVIN(登録商標)384(ベンゾトリアゾール化合物、Ciba Specialty Chemicals社製)、TINUVIN(登録商標)400(トリアジン化合物、Ciba Specialty Chemicals社製)及び2,6−ジヒドロキシベンゾフェノン(DHBP)から選んだ。いくつかのサンプルはさらに、ヒンダードアミン光安定剤TINUVIN(登録商標)152(Ciba Specialty Chemicals社製)を含有した。
サンプルを、2インチ×6インチ(5.08cm×15.24cm)、厚さ10ミル(250μm)の安定剤未添加ポリカーボネートフィルムに流し塗りした。被覆層を約30分間ドレインし、次いで125℃の強制通風炉に5分間入れ、フィルムを完全に乾燥した。初期吸光度(UV吸収剤のλmaxでの)をUnicamUV−3分光光度計にて、約1.5〜2.0吸光度単位となる位置でとり、そのスポットをマークした。次にサンプルを125℃で75分間硬化し、吸光度を再度測定した。次にコーティングを濃硫酸でエッチング除去し、3度目の吸光度を測定した。これらの測定値から、揮発したUV吸収剤の量とポリカーボネートに移行したUV吸収剤の量を、またその差から被膜に残っている量を計算できる。
上記フィルムの小片(約1cm×2cm)を鋼フレームに取り付け、配列とした。基準ビームに未被覆ポリカーボネートフィルムを用いて、325、328、340及び345nmにて各フィルムから吸光度読取値を得た。各UV吸収剤についての適切な吸光度(表1参照)をlog(10A−1)対露光量としてプロットした。露光量は340nmで測定したキロジュール/(平方メートル−ナノメータ)(kJ/m2・nm)として表示した。勾配は、340nmでの1000kJ/m2・nm当たりの吸光単位として表示した、UV吸収剤の光分解速度である。
光期間:100%オン
暗/ドライ:なし
暗/スプレイ:週30分
光/スプレイ:なし
ブラックパネル:55℃
ドライバルブ:35℃
相対湿度:30%
内部フィルタ:CIRA
外部フィルタ:ソーダライム
表1に示した結果から分かるように、トリアジンUV吸収剤TINUVIN400は、硬化中よく保持され、3種のジオールすべてで形成した被膜中での消失速度が一般に低かった。ベンゾトリアゾールTINUVIN384は硬化中余りよく保持されず、消失速度がはるかに高かった。ベンゾフェノンDHBPは硬化中よく保持されたが、耐候試験中早くに失われた。一方、ベンゾフェノンCYASORB531は硬化中よく保持されず、耐候試験中すぐに失われた。ヒンダードアミン光安定剤はVU吸収剤の消失にほとんど影響しなかった。
表1の例2の配合を建てなおし、TINUVIN400の含量をコーティング固形分に基づいて2.2重量%だけとして例36を製造した。5%のCYASORB531を含有する例36及び例28を、4インチ×12インチ×1/8インチ(10.16cm×30.48cm×0.3175cm)のポリカーボネートパネルに流し塗りし、30分間空気乾燥し、次いで強制通風炉にて130℃で60分間ベークした。パネルのフローライン(フローラインとはコーティングを塗工する鉛直位置である)の下3インチからサンプルをとり、下記条件にて、Atlas Ci35aキセノンアークウエザロメータでのキセノンアーク耐候試験に供した。
光期間:160分
暗/ドライ:5分
暗/スプレイ:15分
光/スプレイ:なし
ブラックパネル:70℃
ドライバルブ:45℃
相対湿度:50%
内部フィルタ:タイプSホウケイ酸塩
外部フィルタ:タイプSホウケイ酸塩
340nmで測定して6950kJ/m2・nmの露光後、トリアジンUV吸収剤を含有する例36のサンプルは黄色度指数YI(ASTM D1925)の変化−0.14を示し、一方ベンゾフェノンUV吸収剤で製造した例28のサンプルは黄色度指数YIの変化+8.3を示し、層剥離した。
例38〜42は、厚さ4.5mmの平坦なポリカーボネートパネルに表2に示す被覆組成物を流し塗りし、被覆パネルを20分間空気乾燥させ、130℃で60分間硬化することにより作製した。サンプルは主として、ポリオール化合物の種類と量、p−トルエンスルホン酸の量、トリエチルアミンの量、溶剤組成、及びトリアジン及びヒンダードアミン光安定剤の量が異なる。ほとんどの原料は例1〜35で用いたのと同じであった。Tone210はDow社製のオリゴマー状脂肪族ジオールである。PTSAはp−トルエンスルホン酸である。量はすべて重量部で表示する。
例43〜45は、幅600mm、高さ2000mm、厚さ5mmの平坦なポリカーボネートパネルに表4に示す被覆組成物を流し塗りし、被覆パネルを20分間空気乾燥させ、130℃で60分間硬化することにより作製した。CYMEL301はCytec社製のヘキサメトキシメチルメラミンである。
表6に示す処方(量はすべて重量部で表示する)の被覆溶液を製造した。Tone301、Tone305及びTone310はDow社製の三官能性オリゴマー状ポリカプロラクトンである。DESMOPHENE(登録商標)F2037−420はBayer社製の脂肪族ポリエステルトリオールである。ポリカーボネートシートを被覆溶液に浸漬し、室温で20分間空気乾燥し、130℃で60分間硬化することにより被覆した。
Claims (32)
- ポリカーボネート樹脂を含んでなる第一の層と第一の層の表面に設けられた第二の層とを備えるシートであって、第二の層が、アミノプラスト樹脂とポリオール化合物とUV吸収量のトリアジン化合物とを含んでなる硬化性組成物を硬化してなる硬化物を含んでなる、シート。
- 第一の層がさらに、ポリ(ブチレンテレフタレート)、ポリ(エチレンテレフタレート)、脂肪族ポリエステル、ポリ(スチレン−コ−アクリロニトリル)及びゴム含有耐衝撃性改良剤から選択される熱可塑性樹脂を含む、請求項1記載のシート。
- 第一の層が着色剤を実質的に含まない、請求項1記載のシート。
- 第一の層が着色剤を含む、請求項1記載のシート。
- 第一の層の厚さが約0.05〜約25mmである、請求項1記載のシート。
- 前記硬化性組成物が、硬化性固形分の全重量に基づいて約20〜約80重量%のアミノプラスト樹脂を含む、請求項1記載のシート。
- 前記ポリオール化合物が200原子質量単位超の数平均分子量を有し、オリゴマー状脂肪族ポリエステルジオール、オリゴマー状脂肪族ポリカーボネートジオール、オリゴマー状脂肪族ポリエステルカーボネートジオール、オリゴマー状脂肪族ポリウレタンジオール又はこれらの混合物を含む、請求項1記載のシート。
- 前記ポリオール化合物がジオール及びトリオールを含む、請求項1記載のシート。
- 前記硬化性組成物が、硬化性固形分の全重量に基づいて約20〜約80重量%のポリオール化合物を含む、請求項1記載のシート。
- 前記硬化性組成物が硬化性固形分の全重量に基づいて約0.1〜約10重量%のトリアジン化合物を含む、請求項1記載のシート。
- 前記硬化性組成物がさらにヒンダードアミン光安定剤を含む、請求項1記載のシート。
- 前記硬化性組成物がさらに、C1−C12アルコール、C3−C12ケトン、C3−C12エステル、C4−C12エーテル、C3−C12アルコキシアルカノール、C1−C12ハロゲン化炭化水素、C2−C12カルボン酸、C6−C18芳香族化合物及びこれらの混合物から選択される溶剤を含む、請求項1記載のシート。
- 前記溶剤が1−メトキシ−2−プロパノール、1−ブトキシー2−プロパノール又はこれらの混合物を含む、請求項15記載のシート。
- 前記硬化性組成物がさらに酸性リン酸アルキル、酸性リン酸ジアルキル、リン酸、マレイン酸、無水マレイン酸、フマル酸、クロロマレイン酸、無水クロロマレイン酸、酸性フタル酸アルキル、モノアルキルコハク酸エステル、モノアルキルマレイン酸エステル、アルキルスルホン酸、アリールスルホン酸、スルファミン酸及びこれらの混合物から選択される硬化触媒を含む、請求項1記載のシート。
- 前記硬化性組成物がさらに触媒安定剤を含む、請求項17記載のシート。
- 前記触媒安定剤がトリエチルアミン、ピリジン、2−メチルアミノエタノール及びこれらの混合物から選択される触媒安定剤を含む、請求項18記載のシート。
- 前記硬化性組成物がさらに流れ制御剤、界面活性剤、粘度調整剤、消泡剤及びこれらの混合物から選択される添加剤を含む、請求項1記載のシート。
- 第二の層の厚さが約1〜約50μmである、請求項1記載のシート。
- ポリカーボネート樹脂を含んでなる第一の層と、第一の層の表面に設けられた第二の層とを備えるシートであって、
第二の層が、メラミン−ホルムアルデヒド樹脂と、オリゴマー状脂肪族ポリエステルジオール、オリゴマー状脂肪族ポリカーボネートジオール、オリゴマー状脂肪族ポリエステルカーボネートジオール、オリゴマー状脂肪族ポリウレタンジオール又はこれらの混合物と、UV吸収量の以下の構造のトリアジン化合物とを含んでなる硬化性組成物を硬化してなる硬化物を含む、シート。
- ポリカーボネート樹脂を含んでなる厚さ約0.1〜約20mmの第一の層と、第一の層の表面に設けられた厚さ約2〜約40μmの第二の層とを備えるシートであって、
第二の層が、硬化性固形分の全重量に基づいて、約40〜約60重量%のメラミン−ホルムアルデヒド樹脂と、約40〜約60重量%のオリゴマー状ポリエステルジオール、オリゴマー状ポリカーボネートジオール、オリゴマー状ポリエステルカーボネートジオール又はこれらの混合物と、約0.1〜約5重量%のp−トルエンスルホン酸と、約0.1〜約5重量%のUV吸収量の以下の構造のトリアジン化合物とを含んでなる硬化性組成物を硬化してなる硬化物を含む、シート。
- 前記硬化性組成物がさらに1−メトキシ−2−プロパノール、1−ブトキシー2−プロパノール又はこれらの混合物を含有する溶剤を含む、請求項23記載のシート。
- 前記硬化性組成物がさらに約0.01〜約1重量%のヒンダードアミン光安定剤を含む、請求項23記載のシート。
- シートの製造方法であって、
ポリカーボネートシートの表面に、アミノプラスト樹脂とポリオール化合物とUV吸収量のトリアジン化合物とを含んでなる硬化性組成物を塗工する工程、
前記硬化性組成物を硬化して保護層を形成する工程
を含んでなる方法。 - 前記塗工工程が流れ塗りを含む、請求項26記載の方法。
- 前記塗工工程が浸漬塗布を含む、請求項26記載の方法。
- 請求項1記載のシートから形成した物品。
- 物品の形成が、ドレープ成形、熱成形、真空成形、加圧成形、圧縮成形、冷間カービング、熱間曲げ、積層、絵付け成形、印刷又はこれらの組合せによる、請求項29記載の物品。
- 請求項22記載のシートから形成した物品。
- 請求項23記載のシートから形成した物品。
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US10/882,530 US7960031B2 (en) | 2004-06-30 | 2004-06-30 | Coated sheet, method of formation thereof, and articles derived therefrom |
PCT/US2005/022949 WO2006004765A1 (en) | 2004-06-30 | 2005-06-28 | Coated sheet, method of formation thereof, and articles derived therefrom |
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EP (1) | EP1791895B1 (ja) |
JP (1) | JP4892476B2 (ja) |
KR (1) | KR20070041454A (ja) |
CN (1) | CN1976982B (ja) |
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HK (1) | HK1107363A1 (ja) |
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KR102522984B1 (ko) * | 2017-06-16 | 2023-04-18 | 사빅 글로벌 테크놀러지스 비.브이. | 폴리카르보네이트에서 안정화제로서의 설폰산의 용도 |
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TW200615315A (en) | 2006-05-16 |
WO2006004765A1 (en) | 2006-01-12 |
HK1107363A1 (en) | 2008-04-03 |
EP1791895A1 (en) | 2007-06-06 |
US20110081498A1 (en) | 2011-04-07 |
KR20070041454A (ko) | 2007-04-18 |
EP1791895B1 (en) | 2015-07-22 |
AU2005259919A1 (en) | 2006-01-12 |
US7960031B2 (en) | 2011-06-14 |
TWI385201B (zh) | 2013-02-11 |
US8329300B2 (en) | 2012-12-11 |
US20080032054A1 (en) | 2008-02-07 |
US20060003164A1 (en) | 2006-01-05 |
US7854983B2 (en) | 2010-12-21 |
JP4892476B2 (ja) | 2012-03-07 |
CN1976982A (zh) | 2007-06-06 |
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