JP2008504714A5 - - Google Patents

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Publication number
JP2008504714A5
JP2008504714A5 JP2007519288A JP2007519288A JP2008504714A5 JP 2008504714 A5 JP2008504714 A5 JP 2008504714A5 JP 2007519288 A JP2007519288 A JP 2007519288A JP 2007519288 A JP2007519288 A JP 2007519288A JP 2008504714 A5 JP2008504714 A5 JP 2008504714A5
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JP
Japan
Prior art keywords
substrate
solution
energy source
layer
light source
Prior art date
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JP2007519288A
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Japanese (ja)
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JP2008504714A (en
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Priority claimed from PCT/US2005/022172 external-priority patent/WO2006012174A2/en
Publication of JP2008504714A publication Critical patent/JP2008504714A/en
Publication of JP2008504714A5 publication Critical patent/JP2008504714A5/ja
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Claims (21)

基板を処理する方法であって、
光を照射することによる解離により少なくとも一つの反応化学種が生成される溶液層を、溶液分注ノズルによって基板の表面に供給するステップと、
反応化学種を生成するために前記溶液を解離可能なエネルギ源を利用するステップであって、前記エネルギ源は、エネルギが前記基板の前記表面に衝突するのを遮断するバッフルを備えたエンクロージャに含まれ、エネルギは、前記基板の前記表面上の前記溶液層の少なくとも第1の部分に向けられ、前記バッフルは、前記基板の前記表面からの再結合長未満であるステップと、
前記基板上の第一の材料を反応させステップと、
前記反応させた第一の材料を前記基板から除去するステップと
を備える方法。
A method of processing a substrate, comprising:
The solvent liquid layer at least one reactive species Ru generated by dissociation by irradiation with light, and supplying to the surface of the substrate by solution injecting nozzle,
Using an energy source capable of dissociating the solution to generate reactive species, the energy source included in an enclosure with a baffle that blocks energy from colliding with the surface of the substrate. Energy is directed to at least a first portion of the solution layer on the surface of the substrate, and the baffle is less than a recombination length from the surface of the substrate;
A step of Ru reacting the first material on the substrate,
Removing the reacted first material from the substrate.
溶液は、H22又はH2Oで構成される集合のうち少なくとも一つを含む請求項1記載の方法。 The method of claim 1, wherein the solution comprises at least one of a group consisting of H 2 O 2 or H 2 O. 前記反応化学種は、O3、O2、OH、O、又はOOHで構成される集合のうち少なくとも一つを含む請求項1記載の方法。 The method of claim 1, wherein the reactive species comprises at least one of a set consisting of O 3 , O 2 , OH, O, or OOH. 前記エネルギ源は、紫外線光である請求項1記載の方法。 The method of claim 1, wherein the energy source is ultraviolet light. 前記エネルギ源は、前記溶液が前記基板の前記表面に接触する前に、前記溶液に照射する請求項1記載の方法。 The method of claim 1, wherein the energy source irradiates the solution before the solution contacts the surface of the substrate. 前記エネルギ源は、前記溶液が前記基板の前記表面に接触する時間の少なくとも一部に渡って前記溶液に照射する請求項1記載の方法。 The method of claim 1, wherein the energy source irradiates the solution over at least a portion of the time that the solution contacts the surface of the substrate. 前記エネルギ源は、約300nm以下の波長を有する光源である請求項1記載の方法。 The method of claim 1, wherein the energy source is a light source having a wavelength of about 300 nm or less. 前記エネルギ源は、約180nm乃至約220nmの波長を有する光源である請求項1記載の方法。 The method of claim 1, wherein the energy source is a light source having a wavelength of about 180 nm to about 220 nm. 前記エネルギ源は、コリメートされた光源である請求項1記載の方法。 The method of claim 1, wherein the energy source is a collimated light source . 前記エネルギ源は、パルス化されたエネルギ源である請求項1記載の方法。 The method of claim 1, wherein the energy source is a pulsed energy source . 前記エネルギ源に晒される前記第一の材料の実質的に一部のみを反応させる請求項1記載の方法。 The method of claim 1, wherein only a substantial portion of the first material exposed to the energy source is reacted. 前記溶液は、少なくとも濃度10パーセントのH22を含む請求項1記載の方法。 The method of claim 1, wherein the solution layer comprises at least a 10 percent concentration of H 2 O 2 . 記第一の材料は、有機材料である請求項1記載の方法。 Before SL first material The method of claim 1 wherein the organic material. 記第一の材料は、マスク層のパターンを介して露出させる請求項13記載の方法。 Before SL first material The method of claim 13, wherein exposing through a pattern of the mask layer. 記基板の前記表面に前記溶液を供給するステップは、動的液体メニスカスを介して前記溶液を供給するステップを含む請求項1記載の方法。 Supplying the solution layer on the surface before Symbol substrate The method of claim 1 including the step of supplying said solution through a dynamic liquid meniscus. に、前記基板の前記表面を濯ぐステップを備える請求項1記載の方法。 Further, the method according to claim 1, further comprising a step of rinsing the surface of the substrate. 板を処理するシステムであって
基板支持部と、その上に支持された基板と、
溶液分注ノズルと、
前記基板の表面上で支持された溶液の層であって、前記溶液分注ノズルによって前記基板の前記表面に供給される溶液の層と、
反応化学種を生成するために前記溶液を解離可能なエネルギ源であって、前記エネルギ源は、エネルギが前記基板の前記表面に衝突するのを遮断するバッフルを備えた容器に収容され、前記基板の前記表面上の前記溶液の前記層の少なくとも第1の部分に向けられ、前記バッフルは、前記基板の前記表面からの再結合長未満であるエネルギ源
前記基板支持部と、前記溶液分注ノズルと、前記エネルギ源とに結合され、前記溶液と、前記基板支持部と、前記エネルギ源との動作パラメータを制御可能な制御システムと
を備えるシステム。
A substrate support to a system for treating a base plate, a substrate supported thereon,
A solution dispensing nozzle;
A layer of solution supported on the surface of the substrate, the layer of solution being supplied to the surface of the substrate by the solution dispensing nozzle ;
An energy source capable of dissociating the solution to generate reactive species, the energy source housed in a container having a baffle that blocks energy from colliding with the surface of the substrate; An energy source directed to at least a first portion of the layer of the solution on the surface of the substrate, wherein the baffle is less than a recombination length from the surface of the substrate ;
A system comprising a control system coupled to the substrate support, the solution dispensing nozzle, and the energy source and capable of controlling operating parameters of the solution, the substrate support, and the energy source .
記エネルギ源は、光源である請求項17記載のシステム。 Prior Symbol energy source, the system of claim 17 wherein the light source. 記エネルギ源は、紫外光源である請求項17記載のシステム。 Prior Symbol energy source, the system of claim 17 wherein the ultraviolet light source. 記エネルギ源は、近接ヘッドに含まれ、前記溶液の前記層は、前記近接ヘッドと前記基板の前記表面との間に支持された動的液体メニスカス内の前記基板の前記表面で支持でき、前記近接ヘッドは、
複数のポートであって、
近接ヘッド表面
前記近接ヘッドに結合された真空源
前記近接ヘッドに結合された第2の溶液源
を含む請求項17記載のシステム。
Before SL energy source is included in the proximity head, the layer of the solution, can be supported by the supported said surface of the substrate in the dynamic liquid meniscus between the proximity head and the surface of the substrate, The proximity head is
Multiple ports,
Proximity head surface ,
A vacuum source coupled to the proximity head ;
The system of claim 17 , comprising a second solution source coupled to the proximity head .
板内の有機層をエッチングするシステムであって、
基板支持部と、その上に支持され、有機層上に形成されたパターン化マスク層を有し、前記有機層の第一の部分が前記マスク層内のパターンの第一の部分により露出される基板と
溶液分注ノズルと
前記基板の上面において支持される溶液の層であって、前記分注ノズルによって前記基板の前記上面に供給される溶液層と
少なくとも一つの反応化学種を生成するために前記溶液の解離が可能な光源であって、前記光源は、光が前記基板の前記上面に衝突するのを遮断するバッフルを備えたエンクロージャに含まれ、前記基板の前記上面上の前記溶液の前記層の少なくとも第1の部分に向けられ、前記バッフルは、前記基板の前記上面からの再結合長未満である光源
前記基板支持部と、前記溶液分注ノズルと、前記光源とに結合され、前記溶液と、前記基板支持部と、前記光源との動作パラメータを制御可能な制御システムと
を備えるシステム。
A system for etching an organic layer of the base inner plate,
A substrate support and a patterned mask layer supported on and formed on the organic layer, the first portion of the organic layer being exposed by the first portion of the pattern in the mask layer With substrate
A solution dispensing nozzle and a layer of solution supported on the upper surface of the substrate, wherein the solution layer is supplied to the upper surface of the substrate by the dispensing nozzle and the solution to generate at least one reactive chemical species A light source capable of dissociating , wherein the light source is included in an enclosure with a baffle that blocks light from impinging on the top surface of the substrate, and wherein the layer of the solution on the top surface of the substrate A light source directed to at least a first portion, wherein the baffle is less than a recombination length from the top surface of the substrate ;
A system comprising a control system coupled to the substrate support, the solution dispensing nozzle, and the light source and capable of controlling operating parameters of the solution, the substrate support, and the light source .
JP2007519288A 2004-06-28 2005-06-23 System and method for cleaning and etching a substrate Withdrawn JP2008504714A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US88000704A 2004-06-28 2004-06-28
PCT/US2005/022172 WO2006012174A2 (en) 2004-06-28 2005-06-23 System and method of cleaning and etching a substrate

Publications (2)

Publication Number Publication Date
JP2008504714A JP2008504714A (en) 2008-02-14
JP2008504714A5 true JP2008504714A5 (en) 2008-08-07

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JP2007519288A Withdrawn JP2008504714A (en) 2004-06-28 2005-06-23 System and method for cleaning and etching a substrate

Country Status (6)

Country Link
EP (1) EP1782461A4 (en)
JP (1) JP2008504714A (en)
KR (1) KR20070026687A (en)
CN (1) CN101006571A (en)
TW (1) TWI271793B (en)
WO (1) WO2006012174A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010236088A (en) * 2009-03-09 2010-10-21 Hitachi High-Technologies Corp Cleaning device and cleaning method of mask member and organic el display
US20130068264A1 (en) * 2011-09-21 2013-03-21 Nanya Technology Corporation Wafer scrubber apparatus
KR101992422B1 (en) * 2012-08-14 2019-06-24 주식회사 동진쎄미켐 Apparatus and method for polishing metal layer using photolysis advanced oxidation process
US10347503B2 (en) * 2013-11-11 2019-07-09 Tokyo Electron Limited Method and hardware for enhanced removal of post etch polymer and hardmask removal
TWI570806B (en) 2013-11-11 2017-02-11 東京威力科創股份有限公司 System and method for enhanced removal of metal hardmask using ultra violet treatment
US10867815B2 (en) 2018-09-04 2020-12-15 Tokyo Electron Limited Photonically tuned etchant reactivity for wet etching
US10896824B2 (en) * 2018-12-14 2021-01-19 Tokyo Electron Limited Roughness reduction methods for materials using illuminated etch solutions

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5512123A (en) * 1992-05-19 1996-04-30 Maxwell Laboratories Method for using pulsed optical energy to increase the bondability of a surface
US5782986A (en) * 1996-01-11 1998-07-21 Fsi International Process for metals removal using beta-diketone or beta-ketoimine ligand forming compounds
US6631726B1 (en) * 1999-08-05 2003-10-14 Hitachi Electronics Engineering Co., Ltd. Apparatus and method for processing a substrate
US6503464B1 (en) * 1999-08-12 2003-01-07 Sipec Corporation Ultraviolet processing apparatus and ultraviolet processing method
JP3961240B2 (en) * 2001-06-28 2007-08-22 株式会社半導体エネルギー研究所 Method for manufacturing semiconductor device

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