JP2008263793A - Grain processed food product, agent for improving grain processing, and method for reducing acid smell - Google Patents

Grain processed food product, agent for improving grain processing, and method for reducing acid smell Download PDF

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JP2008263793A
JP2008263793A JP2007107187A JP2007107187A JP2008263793A JP 2008263793 A JP2008263793 A JP 2008263793A JP 2007107187 A JP2007107187 A JP 2007107187A JP 2007107187 A JP2007107187 A JP 2007107187A JP 2008263793 A JP2008263793 A JP 2008263793A
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grain
acetic acid
processed
food
rice
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JP4355007B2 (en
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Yukihiro Takahashi
幸裕 高橋
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Mizkan Group Corp
Mizkan Nakanos Co Ltd
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Mizkan Nakanos Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B9/00Preservation of edible seeds, e.g. cereals
    • A23B9/16Preserving with chemicals
    • A23B9/24Preserving with chemicals in the form of liquids or solids
    • A23B9/26Organic compounds; Microorganisms; Enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/109Types of pasta, e.g. macaroni or noodles
    • A23L7/113Parboiled or instant pasta
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/196Products in which the original granular shape is maintained, e.g. parboiled rice

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
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  • Cereal-Derived Products (AREA)
  • Noodles (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a grain processed food product as a grain processed product (such as boiled rice, boiled noodles and rice cake) excellent in antiseptic force (preservability), and reduced in acid smell; to provide an agent for improving grain processing to be used for producing the grain processed food; and to provide a method for reducing acid smell of the grain processed food. <P>SOLUTION: This grain processed food product contains 0.01-0.06 mass% of acetic acid, and 0.00001-0.001 mass% of α-ethylglucoside. The agent for improving grain processing, which contains acetic acid and α-ethylglucoside, is used for producing the grain processed food product. The method for reducing acid smell of the acetic acid of the grain processed food product includes the step of adding to the grain processed food product which contains 0.01-0.06 mass% of acetic acid, α-ethylglucoside so as to include 0.00001-0.001 mass% per the grain processed food product. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、防腐等のために酢酸など揮発性有機酸を含有させた穀物加工食品(炊飯米、餅等)の酸臭を低減させる技術に関し、さらに詳細には、該酸臭低減のためにα−エチルグルコシドを含有させた穀物加工食品、穀物加工改良剤及び酸臭低減方法に関する。   The present invention relates to a technique for reducing the acid odor of processed cereal foods (rice cooked rice, rice bran, etc.) containing a volatile organic acid such as acetic acid for preserving, and more specifically, for reducing the acid odor. The present invention relates to a processed grain food containing α-ethyl glucoside, a grain processing improver, and a method for reducing acid odor.

昨今、スーパーマーケットやコンビニエンスストアー等で販売される弁当や惣菜等を購入して持ち帰って食する、いわゆる「中食」と呼ばれる食習慣が普及してきている。
これらの食品は、製造されてから比較的長時間経過後に食膳に供されることになるものである。よって、微生物増殖による腐敗の防止などの保存性の付与が必要であり、種々の加工方法や加工改良剤が開発されている。
中食に用いられる穀物加工食品の代表的なものとして炊飯米がある。その炊飯米の防腐のための炊飯改良剤として有機酸又はその塩類がよく用いられている(例えば、特許文献1参照)。グルコン酸やクエン酸などのいわゆる不揮発性の有機酸及びその塩類が使われる場合もあるが、防腐力の点からいえば、酢酸又はその塩類の方が効果が大きい。
In recent years, a so-called “meal” dietary habit has been widespread, where people buy lunch boxes and side dishes sold at supermarkets and convenience stores and take home.
These foods are to be used as a food after a relatively long time since they were manufactured. Therefore, it is necessary to impart storage stability such as prevention of spoilage due to microbial growth, and various processing methods and processing improvers have been developed.
Cooked rice is a typical processed grain food used for meals. An organic acid or a salt thereof is often used as a rice cooking improver for preserving the cooked rice (for example, see Patent Document 1). So-called non-volatile organic acids such as gluconic acid and citric acid and salts thereof may be used, but acetic acid or salts thereof are more effective in terms of antiseptic power.

しかしながら、酢酸は、炊飯米に独特の刺激のある酸臭を付与してしまう傾向がある。特に、酢酸を含有する炊飯改良剤を添加した炊飯米を食する際に電子レンジ等で再加熱等すると、強い酸臭が発生して風味を著しく低下させるという欠点があった。
通常、酢酸等の有機酸含有炊飯改良剤は、生米当たりの酢酸濃度を0.01〜0.1重量%程度とし、炊き上がり後の炊飯米のpHがおよそ5〜6になるようにして用いられる。
しかしながら、このような状態の炊飯米は、電子レンジ等による再加熱前であっても酢酸臭が感じられ、さらに再加熱をすることで酢酸が揮発しやすい状態となるので、刺激のある酢酸臭がより一層強くなってしまうという欠点があった。
However, acetic acid tends to impart a unique and pungent acid odor to cooked rice. In particular, when the cooked rice to which the rice cooking improver containing acetic acid is added is reheated with a microwave oven or the like, a strong acid odor is generated and the flavor is significantly reduced.
Usually, an organic acid containing rice cooking improver such as acetic acid has an acetic acid concentration per raw rice of about 0.01 to 0.1% by weight so that the cooked rice has a pH of about 5 to 6 after cooking. Used.
However, the cooked rice in such a state feels acetic acid odor even before being reheated by a microwave oven or the like, and the acetic acid is likely to volatilize by reheating. Has the disadvantage of becoming even stronger.

従って、防腐力(保存性)に優れており、且つ、炊飯直後はもとより、炊飯米の再加熱の際にも酢酸臭のような刺激のある酸臭の発生を低減する方法、炊飯改良剤、及び酸臭の発生を低減した炊飯米の開発が強く望まれていた。
また、上記課題は、炊飯米に限った問題ではない。例えば、餅や茹で麺などの穀物加工食品においても防腐のために酢酸を用いることがあるが、これらの穀物加工食品は、味や香りが淡白であるため、酢酸の酸臭が発生すると風味を損ねてしまい易いという欠点がある。そこで、防腐力(保存性)に優れており、且つ、加工直後はもとより、穀物加工食品の再加熱の際にも酢酸臭のような刺激のある酸臭の発生を低減する方法、穀物加工改良剤、及び酸臭の発生を低減した穀物加工食品の開発が強く望まれていた。
Therefore, it is excellent in preservative power (preservability), and a method for reducing the generation of an acid odor that is irritating such as acetic acid odor not only immediately after cooking, but also during reheating of cooked rice, a rice cooking improver, Development of cooked rice with reduced generation of acid odor has been strongly desired.
Moreover, the said subject is not a problem only for cooked rice. For example, acetic acid is sometimes used for preservatives in processed foods such as rice bran and boiled noodles, but these processed foods have a pale taste and aroma. There is a drawback that it is easy to damage. Therefore, it has excellent antiseptic power (storability) and improves the processing of grains, a method for reducing the generation of irritating acid odors such as acetic acid odor not only immediately after processing but also when reheating processed cereal foods. There has been a strong demand for development of cereals and processed cereals with reduced acid odor.

特開平5−176693号公報Japanese Patent Laid-Open No. 5-176693

本発明は、上記従来の問題点を解消し、防腐力と酸臭の低減の両方を達成する穀物加工食品を提供すること、さらには、該穀物加工食品の製造に供する穀物加工改良剤を提供することを目的とするものである。
また、防腐のために酢酸を含有した穀物加工食品の酸臭を低減させる方法を提供することを目的とするものである。
The present invention provides a processed grain food that solves the above-mentioned conventional problems, achieves both antiseptic power and reduced acid odor, and further provides a grain processing improver for use in the production of the processed grain food. It is intended to do.
It is another object of the present invention to provide a method for reducing the acid odor of a processed grain food containing acetic acid for preserving.

本発明者らは、上記課題を解決すべく、鋭意検討を重ねた結果、防腐のために酢酸を含有した穀物加工食品にα−エチルグルコシドを極微量含有することにより、穀物の加工直後はもとより、穀物加工食品の再加熱の際にも酢酸の酸臭発生を低減し、風味に優れた穀物加工食品を製造することができることを見出した。
さらに、穀物加工食品に、酒粕や酒粕抽出物、酒粕酢等を添加することで、結果として極微量のα−エチルグルコシドを穀物加工物に含有することができることも見出した。特に、酒粕酢は、穀物加工物に防腐のための酢酸を含有させると同時にα−エチルグルコシドを極微量含有させることができる点で有効に用いることができることをも見出した。
As a result of intensive studies to solve the above-mentioned problems, the present inventors have included a very small amount of α-ethyl glucoside in the processed cereal food containing acetic acid for preserving, so as to immediately after processing the cereal. The present inventors have found that it is possible to reduce the generation of acid odor of acetic acid during reheating of processed cereals and to produce processed cereals with excellent flavor.
Furthermore, the present inventors also found that by adding sake lees, sake lees extract, sake lees vinegar and the like to processed grain foods, it is possible to contain a trace amount of α-ethyl glucoside in the processed grain products as a result. In particular, it has also been found that sake lees vinegar can be effectively used in that a processed grain product can contain acetic acid for preserving and at the same time contain a trace amount of α-ethylglucoside.

すなわち、本発明は以下のものである。
請求項1に係る本発明は、酢酸を0.01〜0.06質量%含有し、且つ、α−エチルグルコシドを0.00001〜0.001質量%含有することを特徴とする穀物加工食品に関するものである。
請求項2に係る本発明は、穀物加工食品が、炊飯米、蒸し米、餅、茹で麺のいずれか1種又は2種以上を組み合わせた食品である、請求項1に記載の穀物加工食品に関するものである。
請求項3に係る本発明は、前記α−エチルグルコシドが、添加された酒粕及び/又は酒粕酢に由来するものである、請求項1又は2に記載の穀物加工食品に関するものである。
請求項4に係る本発明は、酢酸とα−エチルグルコシドの含有質量比が、100対0.03〜100対9である、請求項1〜3のいずれか1項に記載の穀物加工食品に関するものである。
請求項5に係る本発明は、穀物加工食品の熱加工直後及び/又は再加熱時に発生する酢酸の酸臭が低減された、請求項1〜4のいずれか1項に記載の穀物加工食品に関するものである。
請求項6に係る本発明は、請求項1〜5のいずれかに記載の穀物加工食品を製造するために用いる、酢酸及びα−エチルグルコシドを含有した穀物加工改良剤に関するものである。
請求項7に係る本発明は、酢酸を0.01〜0.06質量%含有する穀物加工食品に、α−エチルグルコシドを該穀物加工食品当り0.00001〜0.001質量%含有するように添加することにより、穀物加工食品の酢酸の酸臭を低減させる方法に関するものである。
That is, the present invention is as follows.
This invention which concerns on Claim 1 contains 0.01-0.06 mass% of acetic acid, and contains 0.00001-0.001 mass% of alpha-ethyl glucoside, It is related with the grain processed food characterized by the above-mentioned. Is.
The present invention according to claim 2 relates to the processed grain food according to claim 1, wherein the processed grain food is a food obtained by combining any one or more of cooked rice, steamed rice, rice bran, and boiled noodles. Is.
The present invention according to claim 3 relates to the processed grain food according to claim 1 or 2, wherein the α-ethylglucoside is derived from added sake lees and / or sake lees vinegar.
The present invention according to claim 4 relates to the processed cereal food according to any one of claims 1 to 3, wherein the mass ratio of acetic acid to α-ethylglucoside is 100 to 0.03 to 100 to 9. Is.
The present invention according to claim 5 relates to the processed cereal food according to any one of claims 1 to 4, wherein the acid odor of acetic acid generated immediately after heat processing and / or reheating of the processed cereal food is reduced. Is.
The present invention according to claim 6 relates to a grain processing improver containing acetic acid and α-ethyl glucoside, which is used for producing the grain processed food according to any one of claims 1 to 5.
The present invention according to claim 7 is such that the processed cereal food containing 0.01 to 0.06% by mass of acetic acid contains 0.00001 to 0.001% by mass of α-ethyl glucoside per cereal processed food. It is related with the method of reducing the acid smell of the acetic acid of a grain processed food by adding.

なお、α−エチルグルコシド(以降、エチル−α−グルコシドと表現する場合もある。)は、「調理食品の旨味や濃厚味に関与する呈味成分」であることは知られている(特開平2−291293号公報参照)。
また、β−D−エチルグルコシドは、「飲食品に添加した際に、その飲食品のもつ刺激的かつストレートな香味を和らげ、全体として質量感を賦与する結果、コクのある香味が増強される」ことが知られている(特開平7−250644号公報参照)。つまり、「エチルグルコシド」が香味に影響を与える性質を有する成分であることは知られていたことになる。
In addition, it is known that α-ethyl glucoside (hereinafter sometimes referred to as ethyl-α-glucoside) is a “flavoring component related to the umami and richness of cooked food” (Japanese Patent Laid-Open No. Hei. No. 2-291293).
In addition, β-D-ethyl glucoside is “when added to a food or drink, the stimulating and straight flavor of the food or drink is alleviated, and as a result, a mass feeling is given as a whole, and a rich flavor is enhanced. Is known (see Japanese Patent Application Laid-Open No. 7-250644). That is, it has been known that “ethyl glucoside” is a component having a property of affecting the flavor.

一方、本発明は、上記特許文献で述べられているような飲食品(本発明では穀物加工食品)の「味」や「香味」を変化、改善することを目的とするものではない。さらに詳しく言うと、本発明では、上記特許文献とは逆に「味」には殆ど影響を与えることをせずに、穀物加工食品の酸臭、特に低温や常温にて流通した後の喫食時に電子レンジなどで再加熱した際に発生するムッとくる酸臭という特異的な酸臭に対しての低減を目的とするものであって、その目的達成のための手段としてα−エチルグルコシドを用いるものである。つまり、本発明は、上記特許文献には全く記載も示唆もされておらず、思想を異にする発明であると言える。   On the other hand, the present invention is not intended to change or improve the “taste” or “flavor” of a food or drink (in the present invention, processed cereal food) as described in the above-mentioned patent documents. More specifically, in the present invention, contrary to the above-mentioned patent document, it hardly affects the “taste”, and at the time of eating after having been circulated at low temperature or normal temperature, the acid odor of the processed grain food. The purpose is to reduce the peculiar acid odor generated when reheated in a microwave oven or the like, and α-ethyl glucoside is used as a means for achieving the purpose. Is. That is, the present invention is neither described nor suggested at all in the above patent document, and can be said to be an invention having a different idea.

さらには、特開平7−250644号公報には、エチルグリコシドの添加量として、「飲食品に対して、0.01〜10重量%、好ましくは0.05〜5重量%の添加量を例示することができる。」と記載されており、また、「0.01重量%よりも少ないと、効果が得られず」と記載されていることから、従来、飲食品の香味に影響を与えうる量のエチルグリコシドは飲食品に対して0.01重量%は必要であると解釈することが妥当と言える。   Furthermore, in JP-A-7-250644, the addition amount of ethyl glycoside is exemplified as “addition amount of 0.01 to 10% by weight, preferably 0.05 to 5% by weight with respect to food and drink. In addition, since it is described that “the effect is not obtained when the amount is less than 0.01% by weight”, the amount that can affect the flavor of foods and drinks conventionally. It can be said that it is reasonable to interpret that 0.01% by weight of ethylglycoside is required for food and drink.

これに対し、本発明は、特開平7−250644号公報に記載の量よりはるかに少ない量、すなわち、飲食品(本発明では穀物加工物)に対して0.00001〜0.001質量%という予想もつかない極めて少ない量を含有するものである。この量は、特開平7−250644号公報で開示された、香味に影響を与えうるとされる最少量のさらに1/10〜1/1000に過ぎない。本発明は、この極微量のα−エチルグルコシドによって、従来のような飲食品の香味の増強や改善、苦味、渋味その他の不快臭の除去(特開平7−250644号公報)ではなく、酢酸の酸臭、特に、穀物加工物を再加熱した際の酸臭を特異的に低減するという発明である。
特開平2−291293号公報や特開平7−250644号公報には、「味」には殆ど影響を与えることない極微量のエチルグルコシドが、酢酸を含有する穀物加工食品の酸臭、特に低温や常温にて流通した後の喫食時に電子レンジなどで再加熱した際に発生するムッとくる酸臭を顕著に低減できることについては、何ら開示もしくは示唆されていなかった。
すなわち、本発明は、上記の特許文献に記載の発明とは全く思想を異にする発明であり、これら公知の発明から容易に想到し得る発明でないことは言うまでもない。
On the other hand, the present invention is much less than the amount described in JP-A-7-250644, that is, 0.00001 to 0.001% by mass with respect to food and drink (grain processed product in the present invention). It contains a very small amount that is not expected. This amount is only 1/10 to 1/1000 of the minimum amount disclosed in JP-A-7-250644, which can affect the flavor. According to the present invention, acetic acid is not used to enhance or improve the flavor of conventional foods and beverages, to remove bitterness, astringency and other unpleasant odors (JP-A-7-250644). It is an invention that specifically reduces the acid odor, particularly when the processed grain product is reheated.
In JP-A-2-291293 and JP-A-7-250644, an extremely small amount of ethyl glucoside that hardly affects the “taste” is an acid odor of a grain processed food containing acetic acid, particularly at low temperatures. There has been no disclosure or suggestion that the acid odor generated when reheated in a microwave oven or the like during eating after being distributed at room temperature can be significantly reduced.
That is, the present invention is an invention that is completely different from the invention described in the above-mentioned patent documents, and needless to say, the invention is not easily conceivable from these known inventions.

本発明によれば、防腐力(保存性)に優れた穀物加工物(炊飯米、蒸し米、餅、茹で麺等)であって、加工直後はもとより、低温や常温にて流通した後の喫食時、特に電子レンジ等による再加熱の際に感じる酸臭を低減した穀物加工物を提供することができる。
また、前記穀物加工物を製造することが可能となる穀物加工改良剤を提供することができる。
さらには、防腐のために酢酸を含有した穀物加工食品の酸臭を低減させる方法を提供することができる。
According to the present invention, processed grain products (cooked rice, steamed rice, boiled rice, boiled noodles, etc.) with excellent antiseptic power (preservability), which are not only immediately after processing but also after being distributed at low or normal temperature In particular, it is possible to provide a processed grain product with reduced acid odor that is felt during reheating, particularly with a microwave oven or the like.
Moreover, the grain processing improving agent which becomes possible to manufacture the said grain processed material can be provided.
Furthermore, the method of reducing the acid odor of the processed grain food containing acetic acid for preserving can be provided.

本発明における穀物加工食品とは、米、大麦、小麦、豆、とうもろこし等の穀物を加工することによって人が食するように加工したものを言う。例えば、米に炊飯という加工を施した炊飯米や、小麦粉を水で練った生麺や乾麺に茹で加工を施した茹で麺などである。他には、蒸し米、餅、パン等、味や香りが淡白な穀物加工食品が該当する。本発明においては、これらの中でも炊飯米、蒸し米、餅、茹で麺のいずれか1種又は2種以上であることが好ましく、特に炊飯米が最も好ましい。
本発明における穀物加工食品の商品形態としては特に限定されないが、常温もしくは低温にて流通販売され、喫食時に電子レンジ等の加温調理器具にて常温もしくは高温に加熱される、すなわちコンビニエンスストア、スーパーマーケットやテイクアウト惣菜店等で販売される弁当、おにぎり、調理麺等が主に該当するが、特には、弁当、おにぎりを挙げることができる。
The grain processed food in the present invention refers to food processed by humans by processing grains such as rice, barley, wheat, beans, corn and the like. For example, cooked rice obtained by processing rice to cooked rice, raw noodles obtained by kneading wheat flour with water, or boiled noodles obtained by subjecting dried noodles to boiled rice. Others include processed cereal foods that are pale in taste and aroma, such as steamed rice, rice bran, and bread. In this invention, it is preferable that it is any 1 type or 2 or more types of cooked rice, steamed rice, rice bran, and boiled noodles among these, and especially cooked rice is the most preferable.
The product form of the processed grain food in the present invention is not particularly limited, but is distributed and sold at normal temperature or low temperature, and is heated to normal temperature or high temperature with a heating cooker such as a microwave oven when eating, that is, a convenience store, a supermarket Lunch boxes, rice balls, cooked noodles, etc. sold mainly at sushi and take-out side dishes stores, etc., mainly include lunch boxes and rice balls.

本発明における酢酸の含有方法としては、酢酸を単体の物質として添加することにより含有させてもよいし、酢酸を含有する食品を添加して含有させることによって、結果として酢酸を含有させてもよい。例えば、食酢を穀物加工食品に含有させるなどの手段によって穀物加工食品に酢酸を含有することができる。
また、酢酸は、穀物加工段階で含有させてもよいし、穀物加工後、喫食時までの間に含有させてもよい。例えば、炊飯米においては、炊飯時に食酢等を適量添加して含有させてもよいし、炊飯後に食酢含有水等を振りかけて含有させてもよい。なお、防腐効果を炊飯米に均一に持たせるには炊飯時に添加した方が好ましい。なお、これは茹で麺など、他の穀物加工食品においても同様のことが言える。
As a method for containing acetic acid in the present invention, acetic acid may be contained as a single substance, or acetic acid may be contained as a result by adding and containing a food containing acetic acid. . For example, acetic acid can be contained in the processed cereal food by means such as adding vinegar to the processed cereal food.
Acetic acid may be contained in the grain processing stage, or after the grain is processed and before eating. For example, in cooked rice, an appropriate amount of vinegar or the like may be added and contained at the time of cooking, or vinegar-containing water or the like may be sprinkled and contained after cooking. In addition, it is more preferable to add at the time of rice cooking so that the cooked rice may have a preservative effect uniformly. The same applies to other processed grain foods such as boiled noodles.

酢酸の含有量としては、穀物加工食品当り0.01〜0.06質量%であることが必要であるが、好ましくは0.02〜0.05質量%がよい。0.06%より多いと酸味及び酸臭が強く出てしまい、味や香りが淡白な穀物加工食品の本来の香味を損なってしまう。また、0.01%より少ないと防腐効果を十分に得られない。   The acetic acid content needs to be 0.01 to 0.06% by mass, preferably 0.02 to 0.05% by mass, based on the processed cereal food. If it is more than 0.06%, the acidity and acid odor will be strong, and the original flavor of the processed cereal food will be impaired. On the other hand, if it is less than 0.01%, the antiseptic effect cannot be sufficiently obtained.

また、穀物加工食品のpHとしては、求める味や防腐効果によって範囲は決められるものであり一概には規定できないが、両者を兼ね備えることを考えるとpHが5.0〜6.2であることが適当であり、さらには5.2〜5.8が好ましい。pHが5.0より低いと酸味が強く出てしまう可能性があり、味が淡白な穀物加工食品の本来の味を損なってしまう。また、pHが6.2より高いと防腐効果を十分に得られない可能性がある。
なお、酸味や酸臭が気にならないような穀物加工食品、例えば、寿司に用いる酢飯などは、本来、酸臭があることが普通であるため、本発明を用いる必要はなく、本発明における穀物加工食品とは区別する必要がある。そのため、本発明においては酢酸の含有量を所定範囲に限定したのである。
Moreover, as the pH of the processed grain food, the range is determined by the desired taste and antiseptic effect and cannot be defined unconditionally, but considering that it has both, the pH may be 5.0 to 6.2. It is suitable, and more preferably 5.2 to 5.8. If the pH is lower than 5.0, there is a possibility that the acidity will be strong, and the original taste of the processed cereal food will be impaired. On the other hand, if the pH is higher than 6.2, the antiseptic effect may not be sufficiently obtained.
It should be noted that processed cereal foods that do not bother the sourness and acid odor, such as vinegared rice used for sushi, normally have an acid odor, so it is not necessary to use the present invention. It must be distinguished from processed grain foods. Therefore, in the present invention, the acetic acid content is limited to a predetermined range.

本発明において用いるα−エチルグルコシドとは、グルコピラノシドにエチル基がα結合したものであり、化学合成による製造だけでなく、清酒やみりんをはじめとする酒類中や酒粕にも微量に含まれることが知られている。
穀物加工食品にα−エチルグルコシドを含有させる方法としては、α−エチルグルコシドを単体の物質として添加することにより含有させてもよいし、α−エチルグルコシドを含有する食品や添加物を含有させることによって、結果としてα−エチルグルコシドを含有させてもよい。例えば、α−エチルグルコシドを含有する食品として、清酒、酒粕、酒粕酢などを穀物加工食品に含有させるなどの手段を用いることができる。α−エチルグルコシドを含有する食品としては、特に、酒粕及び酒粕酢のいずれか1種又は2種以上であることが好ましい。
The α-ethyl glucoside used in the present invention is a product in which an ethyl group is α-bonded to glucopyranoside, and is not only produced by chemical synthesis but also contained in a small amount in alcoholic beverages and sake lees such as sake and mirin. Are known.
As a method of adding α-ethyl glucoside to processed grain foods, α-ethyl glucoside may be added as a single substance, or food or additives containing α-ethyl glucoside may be included. As a result, α-ethylglucoside may be contained. For example, as a food containing α-ethyl glucoside, means such as adding sake, sake lees, sake lees vinegar and the like to the processed grain food can be used. In particular, the food containing α-ethyl glucoside is preferably one or more of sake lees and sake lees vinegar.

また、α−エチルグルコシドは、穀物加工段階で含有させてもよいし、穀物加工後、喫食時までの間に含有させてもよい。例えば、炊飯米においては、炊飯時に食酢等の酢酸含有食品と一緒に清酒や酒粕などを適量添加して含有させてもよい。もちろん、炊飯後にα−エチルグルコシドを含有した液体を混ぜても良いが、酸臭低減効果を炊飯米に均一に持たせるには炊飯時に添加した方が好ましい。   Moreover, (alpha) -ethyl glucoside may be contained in a grain processing stage, and may be contained after the grain processing until it eats. For example, in cooked rice, a proper amount of sake or sake lees may be added together with acetic acid-containing foods such as vinegar during cooking. Of course, a liquid containing α-ethyl glucoside may be mixed after cooking, but it is preferable to add it at the time of cooking rice so that the cooked rice has an acid odor reducing effect uniformly.

また、α−エチルグルコシドと酢酸の両方を含有する酒粕酢を穀物加工食品に添加することで両物質を含有させることによっても本発明の穀物加工食品を製造することができ、作業の効率もよく好ましい。例えば、炊飯米において、炊飯時に酒粕酢を適量添加することによってα−エチルグルコシドと酢酸の両方を含有させることができる。もちろん、α−エチルグルコシド又は酢酸が本発明の効果を発揮させる量に満たない場合は、別途の方法によりα−エチルグルコシド又は酢酸を追加で添加しても良い。   Moreover, the processed grain food of the present invention can also be produced by adding both substances by adding sake vinegar containing both α-ethylglucoside and acetic acid to the processed grain food. preferable. For example, in cooked rice, both α-ethyl glucoside and acetic acid can be contained by adding an appropriate amount of sake vinegar during cooking. Of course, if the amount of α-ethyl glucoside or acetic acid is less than the amount that exerts the effect of the present invention, α-ethyl glucoside or acetic acid may be additionally added by a separate method.

α−エチルグルコシドの含有量としては、「味」に殆ど影響を与えない極微量を含有させるが、具体的には、穀物加工食品当り0.00001〜0.001質量%であることが好ましく、さらに好ましくは0.0001〜0.001質量%がよい。0.001質量%より多いとα−エチルグルコシド特有の味を感じ易くなり、味や香りが淡白な穀物加工食品の本来の香味を損なう傾向となる。また、0.00001質量%より少ないと酸臭を低減する効果を十分に得られにくくなる。   As the content of α-ethyl glucoside, a trace amount that hardly affects the “taste” is contained, and specifically, it is preferably 0.00001 to 0.001% by mass per processed grain food, More preferably, 0.0001-0.001 mass% is good. When it is more than 0.001% by mass, it becomes easy to feel the taste peculiar to α-ethyl glucoside, and the taste and aroma tend to deteriorate the original flavor of the processed cereal food. On the other hand, when the amount is less than 0.00001% by mass, it is difficult to sufficiently obtain the effect of reducing the acid odor.

また、酢酸とα−エチルグルコシドの含有量の質量比としては、前者対後者が、100対0.003〜100対9の範囲であることが好ましく、さらに好ましくは、100対0.3〜100対9である。α−エチルグルコシドの比率が上記比率より多いと、α−エチルグルコシド特有の味を感じ易く、また、少ないと酸臭を低減する効果を十分に得られにくいためである。   The mass ratio of acetic acid and α-ethyl glucoside content is preferably such that the former vs. latter is in the range of 100 to 0.003 to 100 to 9, more preferably 100 to 0.3 to 100. Pair 9. This is because if the ratio of α-ethyl glucoside is larger than the above ratio, it is easy to feel the taste peculiar to α-ethyl glucoside, and if it is small, the effect of reducing the acid odor is not sufficiently obtained.

本発明は、穀物加工食品の酸臭を低減することを目的とするものであるが、特に、熱加工直後及び/又は再加熱された際に酢酸の揮発によって生じる酸臭を低減することにより効果を発揮する。例えば、防腐のために食酢を炊飯米に含有した炊飯米を用いた白米、おにぎり、弁当などの商品を、低温や常温で流通された後の喫食時に電子レンジ等で再加熱すると、包装や蓋を開けた瞬間ムッとするような酸臭が鼻をつくことがある。これは、再加熱によって食酢に含まれている酢酸が揮発したためであり、低温や常温では感じにくい酸臭である。   The present invention aims to reduce the acid odor of processed cereal foods, and is particularly effective by reducing the acid odor caused by volatilization of acetic acid immediately after heat processing and / or when reheated. Demonstrate. For example, if products such as white rice, rice balls, lunch boxes, etc., using cooked rice containing vinegar in the cooked rice for preservatives are reheated in a microwave oven, etc. after being distributed at low or normal temperature, An acid odor that makes you stuffy the moment you open your mouth may make your nose. This is because acetic acid contained in vinegar is volatilized by reheating, and it is an acid odor that is difficult to feel at low and normal temperatures.

また、本発明は、最終製品としての穀物加工食品だけでなく、穀物加工食品の酸臭を低減するために、加工の際に用いられる穀物加工改良剤も含むものである。例えば、α−エチルグルコシドを適量水と混合したものであってもよい。さらに、酢酸をα−エチルグルコシドと前記所定の割合になるように一緒に含有したものであってもよいし、クエン酸や酢酸ナトリウムなどの有機酸や有機酸塩、また還元水あめなどの糖類などを一緒に含有し、複数の機能を持たせた炊飯改良剤としてもよい。
特に、酒粕酢を穀物加工の際(炊飯前など)に添加することは、防腐効果を有する揮発性有機酸である酢酸と、酸臭の低減効果を有するα−エチルグルコシドを前記所定の割合で含有することができる点で有効である。従って、酒粕酢は、穀物加工改良剤として有効に用いることができる。また、例えば酢酸を0.01〜0.06質量%含有させ、且つ、α−エチルグルコシドを0.00001〜0.001質量%含有させたものを、穀物加工改良剤することもできる。この場合、公知の賦形剤を用いてもよいし、さらには前記したように、クエン酸や酢酸ナトリウムなどの有機酸や有機酸塩、また還元水あめなどの糖類などを一緒に含有し、複数の機能を持たせたものとしてもよい。
The present invention also includes a grain processing improver used in processing to reduce the acid odor of the processed grain food as well as the processed grain food as the final product. For example, α-ethyl glucoside may be mixed with an appropriate amount of water. Furthermore, acetic acid may be contained together with α-ethyl glucoside so as to have the predetermined ratio, organic acids such as citric acid and sodium acetate, organic acid salts, saccharides such as reduced syrup, etc. It is good also as a rice cooking improver which contains together and gave a plurality of functions.
In particular, adding sake lees vinegar during grain processing (before cooking rice, etc.) means that acetic acid, which is a volatile organic acid having an antiseptic effect, and α-ethyl glucoside, which has an acid odor reducing effect, in the predetermined ratio. It is effective in that it can be contained. Therefore, sake lees vinegar can be used effectively as a grain processing improver. Further, for example, what contains 0.01 to 0.06% by mass of acetic acid and 0.00001 to 0.001% by mass of α-ethyl glucoside can be used as a grain processing improver. In this case, a known excipient may be used, and as described above, it contains an organic acid such as citric acid or sodium acetate, an organic acid salt, or a saccharide such as reduced syrup, It is good also as what gave the function of.

本発明においては、酢酸を0.01〜0.06質量%含有する穀物加工食品に、α−エチルグルコシドを該穀物加工食品当り0.00001〜0.001質量%含有するように添加することにより、穀物加工食品の酢酸の酸臭を有効に低減させることができ、酢酸の酸臭の低減された穀物加工食品を製造することができる。   In the present invention, α-ethyl glucoside is added to a processed cereal food containing 0.01 to 0.06% by mass of acetic acid so as to contain 0.00001 to 0.001% by mass of the processed cereal food. Thus, the acid odor of acetic acid in the processed grain food can be effectively reduced, and the processed grain food with reduced acid odor of acetic acid can be produced.

以下、本発明を実施例により具体的に説明するが、本発明はこれにより何ら制限されるものではない。   EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited thereto.

実施例1(酢酸含有白飯におけるα−エチルグルコシドの酸臭低減効果)
(1)酢酸ならびにα−エチルグルコシドを含有する白飯の炊飯
生米(滋賀県産こしひかり)300gを洗米し、約2時間水に浸漬した。次いで、水切りしたのち、5合釜の家庭用炊飯機に投入し、水340gを加えたところへ、氷酢酸0.2gならびに表1に示す所定量のα−エチルグルコシド(表1に示す量:0〜0.007g)を溶解した液をそれぞれ投入し、攪拌した後、常法により加熱して炊飯した。その後、加熱を止め、30分間の蒸らし工程を経て、炊飯を完了した。
このようにして調製した炊飯米は、冷却後重量が660gとなり、150g入りのパック容器に充填し白飯とした。
Example 1 (Acid odor reduction effect of α-ethyl glucoside in acetic acid-containing cooked rice)
(1) Cooked white rice containing acetic acid and α-ethylglucoside 300 g of raw rice (Koshihikari from Shiga Prefecture) was washed and immersed in water for about 2 hours. Next, after draining, the mixture was put into a 5 rice kettle household rice cooker and 340 g of water was added to 0.2 g of glacial acetic acid and a predetermined amount of α-ethyl glucoside shown in Table 1 (amount shown in Table 1: The liquid in which 0 to 0.007 g) was dissolved was added and stirred, and then heated and cooked by a conventional method. Then, heating was stopped and the cooking of rice was completed through a steaming process for 30 minutes.
The cooked rice thus prepared had a weight of 660 g after cooling and was filled in a 150 g packed container to obtain white rice.

(2)熟練官能検査員による再加熱時の酸臭評価
以上の工程にて作成した白飯を20℃で24時間保存したのちに電子レンジで500W、1分間加熱し、90℃以上の状態で、弊社熟練官能検査員により各々の酸臭の程度を下記の基準にて評価した。結果を表1中に示した。
なお、表1において、調製した炊飯米に含有される酢酸及びα−エチルグルコシドの濃度は、調製した炊飯米の冷却後重量(g)に対する、酢酸及びα−エチルグルコシドの添加量(g)による質量%により示した。
(2) Evaluation of acid odor at the time of reheating by a skilled sensory inspector After storing the white rice prepared in the above process at 20 ° C. for 24 hours, it is heated in a microwave oven at 500 W for 1 minute, and in a state of 90 ° C. or higher, The degree of each acid odor was evaluated according to the following criteria by our expert sensory inspector. The results are shown in Table 1.
In Table 1, the concentration of acetic acid and α-ethyl glucoside contained in the prepared cooked rice depends on the added amount (g) of acetic acid and α-ethyl glucoside relative to the weight (g) after cooling of the prepared cooked rice. Indicated by mass%.

〔酸臭の評価基準〕
○:酢酸臭が少ない
△:酢酸臭がわずかに少ない
×:酢酸臭が強い
[Evaluation criteria for acid odor]
○: Little acetic acid odor △: Little acetic acid odor ×: Strong acetic acid odor

Figure 2008263793
Figure 2008263793

表1から明らかなように、α−エチルグルコシドを添加した酢酸含有白飯は、無添加のものに比べて明確に酸臭が低減していることが確認された。
このような酸臭の低減効果は、α−エチルグルコシドの含有量が0.00001質量%のときでも認められるが、特に0.0001〜0.001質量%のときに顕著であることが明らかになった。
As apparent from Table 1, it was confirmed that the acid odor was clearly reduced in the acetic acid-containing cooked rice to which α-ethylglucoside was added as compared with the additive-free one.
Such an effect of reducing the acid odor is recognized even when the content of α-ethyl glucoside is 0.00001% by mass, but it is clearly remarkable particularly when the content is 0.0001 to 0.001% by mass. became.

実施例2(α−エチルグルコシドを含有する食品による酸臭低減効果の比較)
実施例1の結果を踏まえて、α−エチルグルコシドを含有する食品による酸臭低減効果について検証した。
(1)酢酸ならびにα−エチルグルコシドを含有する食品を添加した白飯の炊飯
生米(滋賀県産こしひかり)300gを洗米し、約2時間水に浸漬した。次いで、水切りしたのち、5合釜の家庭用炊飯機に投入し、水340gを加えたところへ、表2に示す通り、酢酸または酢酸を含む食品ならびにα−エチルグルコシドを含む食品をそれぞれ投入し、攪拌した後、常法により加熱して炊飯した。その後、加熱を止め、30分間の蒸らし工程を経て、炊飯を完了した。このようにして調製した炊飯米は、冷却後重量が660gとなり、150g入りのパック容器に充填し白飯とした。
尚、本実験においては、酒粕は(株)小林晴吉商店製の「酒粕」を使用し、酒粕酢は(株)ミツカンナカノス製の「優撰」を使用した。
Example 2 (Comparison of acid odor reduction effect by food containing α-ethyl glucoside)
Based on the results of Example 1, the acid odor reduction effect of the food containing α-ethyl glucoside was verified.
(1) Cooked white rice to which food containing acetic acid and α-ethyl glucoside was added 300 g of raw rice (Koshihikari produced in Shiga Prefecture) was washed and immersed in water for about 2 hours. Next, after draining, the mixture is put into a 5 rice kettle household rice cooker, and after adding 340 g of water, as shown in Table 2, acetic acid or a food containing acetic acid and a food containing α-ethyl glucoside are added. After stirring, the rice was heated and cooked by a conventional method. Then, heating was stopped and the cooking of rice was completed through a steaming process for 30 minutes. The cooked rice thus prepared had a weight of 660 g after cooling and was filled in a 150 g packed container to obtain white rice.
In this experiment, “Sake lees” made by Haruyoshi Kobayashi Co., Ltd. was used as the sake lees, and “Yuyasu” made by Mitsukannakanos was used as the sake lees vinegar.

(2)熟練官能検査員による再加熱時の酸臭評価
実施例1と同様に、以上の工程にて作成した白飯を20℃で24時間保存したのちに電子レンジで500W、1分間加熱し、90℃以上の状態で、弊社熟練官能検査員にて各々の酸臭の程度を評価した。結果を表2中に示した。
なお、表2において、酒粕添加区は、「酒粕」0.04g添加にて、調製した炊飯米に対してα−エチルグルコシド0.0001質量%を添加したことになる。酒粕酢添加区は、「優撰」4.8ml添加にて、調製した炊飯米に対して酢酸0.03質量%とα−エチルグルコシド0.0002質量%の双方を同時に添加したことになる。
(2) Evaluation of acid odor at the time of reheating by a skilled sensory inspector As in Example 1, after storing the white rice prepared in the above steps at 20 ° C. for 24 hours, it was heated in a microwave oven at 500 W for 1 minute, In a state of 90 ° C. or higher, our skilled sensory inspector evaluated the degree of each acid odor. The results are shown in Table 2.
In Table 2, the sake lees added section was obtained by adding 0.0001% by mass of α-ethylglucoside to the prepared cooked rice by adding 0.04 g of “Sake lees”. In the sake vinegar addition group, 4.8 ml of “Yuyi” was added, and 0.03% by mass of acetic acid and 0.0002% by mass of α-ethyl glucoside were simultaneously added to the prepared cooked rice.

Figure 2008263793
Figure 2008263793

表2から明らかなように、α−エチルグルコシドを含有した食品を添加した場合においても、無添加のものに比べて明確に酸臭が低減していることが確認された。   As is apparent from Table 2, it was confirmed that the acid odor was clearly reduced compared to the non-added food when the food containing α-ethyl glucoside was added.

本発明によれば、防腐力(保存性)に優れた穀物加工物(炊飯米、蒸し米、餅、茹で麺等)であり、且つ、加工直後はもとより、低温や常温にて流通した後の喫食時、特に電子レンジ等による再加熱の際に感じる酸臭を低減した穀物加工物という従来になかった食品を提供することが可能となる。
また、前記穀物加工物を製造することが可能となる、従来になかった穀物加工改良剤を提供することが可能となる。
さらには、防腐のために酢酸を含有した穀物加工食品の酸臭を低減させる方法を提供することが可能となる。
従って、本発明は食品産業において有効に利用することができる。
According to the present invention, it is a processed grain product (cooked rice, steamed rice, boiled rice, boiled noodles, etc.) excellent in antiseptic power (preservative), and not only immediately after processing but also after being distributed at low temperature or normal temperature. It is possible to provide an unprecedented food, such as a processed grain product, which has reduced acid odor when eaten, particularly when reheated by a microwave oven or the like.
In addition, it is possible to provide an unprecedented grain processing improver capable of producing the processed grain product.
Furthermore, it is possible to provide a method for reducing the acid odor of a processed grain food containing acetic acid for preserving.
Therefore, the present invention can be effectively used in the food industry.

Claims (7)

酢酸を0.01〜0.06質量%含有し、且つ、α−エチルグルコシドを0.00001〜0.001質量%含有することを特徴とする穀物加工食品。   A processed grain food comprising 0.01 to 0.06% by mass of acetic acid and 0.00001 to 0.001% by mass of α-ethylglucoside. 穀物加工食品が、炊飯米、蒸し米、餅、茹で麺のいずれか1種又は2種以上を組み合わせた食品である、請求項1に記載の穀物加工食品。   The processed cereal food according to claim 1, wherein the processed cereal food is a food obtained by combining one or more of cooked rice, steamed rice, rice bran, and boiled noodles. 前記α−エチルグルコシドが、添加された酒粕及び/又は酒粕酢に由来するものである、請求項1又は2に記載の穀物加工食品。   The grain processed food according to claim 1 or 2, wherein the α-ethylglucoside is derived from added sake lees and / or sake lees vinegar. 酢酸とα−エチルグルコシドの含有質量比が、100対0.03〜100対9である、請求項1〜3のいずれか1項に記載の穀物加工食品。   The processed grain food according to any one of claims 1 to 3, wherein the mass ratio of acetic acid to α-ethylglucoside is 100 to 0.03 to 100 to 9. 穀物加工食品の熱加工直後及び/又は再加熱時に発生する酢酸の酸臭が低減された、請求項1〜4のいずれか1項に記載の穀物加工食品。   The processed cereal food according to any one of claims 1 to 4, wherein the acid odor of acetic acid generated immediately after heat processing and / or reheating of the processed cereal food is reduced. 請求項1〜5のいずれかに記載の穀物加工食品を製造するために用いる、酢酸及びα−エチルグルコシドを含有した穀物加工改良剤。   A grain processing improver containing acetic acid and α-ethyl glucoside, which is used to produce the processed grain food according to claim 1. 酢酸を0.01〜0.06質量%含有する穀物加工食品に、α−エチルグルコシドを該穀物加工食品当り0.00001〜0.001質量%含有するように添加することにより、穀物加工食品の酢酸の酸臭を低減させる方法。   By adding α-ethyl glucoside to the processed cereal food containing 0.01 to 0.06% by mass of acetic acid so as to contain 0.00001 to 0.001% by mass of the processed cereal food, A method for reducing the acid odor of acetic acid.
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