JP2008255497A - Steel cord for reinforcing rubber product and method for producing the same - Google Patents

Steel cord for reinforcing rubber product and method for producing the same Download PDF

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JP2008255497A
JP2008255497A JP2007095527A JP2007095527A JP2008255497A JP 2008255497 A JP2008255497 A JP 2008255497A JP 2007095527 A JP2007095527 A JP 2007095527A JP 2007095527 A JP2007095527 A JP 2007095527A JP 2008255497 A JP2008255497 A JP 2008255497A
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strands
strand
cord
layer
strand group
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Akitaka Morioka
哲隆 森岡
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Tokusen Kogyo Co Ltd
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Tokusen Kogyo Co Ltd
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    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B1/00Constructional features of ropes or cables
    • D07B1/06Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
    • D07B1/0606Reinforcing cords for rubber or plastic articles
    • D07B1/062Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration
    • D07B1/0633Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration having a multiple-layer configuration
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B1/00Constructional features of ropes or cables
    • D07B1/06Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
    • D07B1/0606Reinforcing cords for rubber or plastic articles
    • D07B1/0646Reinforcing cords for rubber or plastic articles comprising longitudinally preformed wires
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2001Wires or filaments
    • D07B2201/2007Wires or filaments characterised by their longitudinal shape
    • D07B2201/2008Wires or filaments characterised by their longitudinal shape wavy or undulated
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2015Strands
    • D07B2201/2019Strands pressed to shape
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2015Strands
    • D07B2201/2023Strands with core
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2015Strands
    • D07B2201/2024Strands twisted
    • D07B2201/2029Open winding
    • D07B2201/2031Different twist pitch
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2015Strands
    • D07B2201/2024Strands twisted
    • D07B2201/2029Open winding
    • D07B2201/2031Different twist pitch
    • D07B2201/2032Different twist pitch compared with the core
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2015Strands
    • D07B2201/2038Strands characterised by the number of wires or filaments
    • D07B2201/204Strands characterised by the number of wires or filaments nine or more wires or filaments respectively forming multiple layers
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2401/00Aspects related to the problem to be solved or advantage
    • D07B2401/20Aspects related to the problem to be solved or advantage related to ropes or cables
    • D07B2401/208Enabling filler penetration
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2501/00Application field
    • D07B2501/20Application field related to ropes or cables
    • D07B2501/2046Tire cords

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  • Ropes Or Cables (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a steel cord which is used for reinforcing rubber products, has good rubber material invasiveness, is free from the slip of a core strand group and an intermediate strand group, has a stable twist structure, is little extended with low loads, and has a three-layered structure. <P>SOLUTION: The cord 10 having an L+M+N structure is produced by twisting intermediate strands 12 each having smaller pitch approximately sine wave-like curls than the pitches of curls for twisting all strands, around a core strand 11, further twisting side strands 13, and then pressing in the direction crossing the longitudinal direction of the cord. A steel cord having a 1×P structure is produced by simultaneously twisting all intermediate strands each having a smaller pitch approximately sine wave-like curls than the pitches of curls for twisting the strands with other strands, and then pressing the twisted product. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、自動車用タイヤ、コンベアベルト等のゴム製品補強材として使用されるゴム製品補強用スチールコード(以下、単に「コード」ということもある。)に関するものである。   TECHNICAL FIELD The present invention relates to a steel cord for reinforcing rubber products (hereinafter sometimes simply referred to as “cord”) used as a reinforcing material for rubber products such as automobile tires and conveyor belts.

自動車用タイヤ、コンベアベルト等のゴム製品補強材として使用される1+6+12構造、3+9+15構造、あるいは1×19構造、1×27構造等の3層構造のゴム製品補強用スチールコードとしては、従来、複数本の素線を堅く撚り合わせて密着させた、いわゆるクローズド撚り構造のコードが一般的である。しかし、このクローズド撚りコードは、隣接する素線間に閉じられた空洞部が存在しており、コードを2枚のゴムシートの間に挟んで加熱圧縮して複合体シートを形成した時に、ゴム材が素線間の空洞部に侵入することはなくて、単にコードをゴムシートによって包み込んだだけの複合体となり、ゴム材がコード素線間の空洞部に完全に入り込んでゴムシートとコードとが一体化されたいわゆる完全な複合体にはならない。そのため、従来のクローズド撚りコードをゴムシートで挟んで圧縮した複合体シートを例えば自動車のタイヤに組み込むと、ゴム材とコードとの接着が不十分で、自動車の走行時にゴム材がコードから剥離する、いわゆるセパレーション現象を起こす可能性が大きく、また、ゴム材中に侵入した水分がコードの空洞部に達すると、その水分は空洞部を伝ってたちまちコードの長手方向に伝播してコードを腐食させ、その結果、そのコードの機械的強度を著しく低下させることになる。   Conventionally, steel cords for reinforcing rubber products such as 1 + 6 + 12 structure, 3 + 9 + 15 structure, 1 × 19 structure, 1 × 27 structure, etc. used as a rubber product reinforcing material for automobile tires, conveyor belts, etc. A so-called closed twisted cord in which the strands of the book are tightly twisted and brought into close contact is generally used. However, this closed twisted cord has a closed cavity between adjacent strands, and when a composite sheet is formed by sandwiching the cord between two rubber sheets and heat-compressing the rubber, The material does not invade the cavity between the strands, and it is a composite that simply wraps the cord with the rubber sheet, and the rubber material completely penetrates into the cavity between the cord strands. Does not become a so-called perfect composite. Therefore, when a composite sheet obtained by compressing a conventional closed twisted cord sandwiched between rubber sheets is incorporated into, for example, an automobile tire, the adhesion between the rubber material and the cord is insufficient, and the rubber material peels off from the cord when the automobile is running. In other words, there is a high possibility of causing a so-called separation phenomenon, and when the moisture that has penetrated into the rubber material reaches the cavity of the cord, the moisture propagates along the cavity and in the longitudinal direction of the cord and corrodes the cord. As a result, the mechanical strength of the cord is significantly reduced.

また、図6に示すように、3層構造のコード60の中心層を構成する素線群(「芯素線群」といい、素線1本の場合も含む。)、中間層を構成する素線群(「中間素線群」という。)および外層を構成する素線群(「側素線群」という。)の各素線61,62,63に施す撚り合わせのためのくせ付けを過大なものとすることで、素線61,62,63同士の間に外側に連通する隙間64を設けてゴム材が侵入し易くなるようにしたオープン撚り構造のコードも知られている。しかし、オープン撚り構造のコードは、芯素線群と中間素線群とが非接触であり、また、中間素線群と側素線群とが非接触であるため、芯素線群および中間素線群がずれ動きやすくて、撚りの安定度が低い。   Also, as shown in FIG. 6, a group of strands (referred to as “core strand group”, including the case of a single strand) constituting the central layer of the three-layer structure cord 60, and an intermediate layer. The caulking for twisting applied to the strands 61, 62, 63 of the strand group (referred to as “intermediate strand group”) and the strand group constituting the outer layer (referred to as “side strand group”). A cord having an open twist structure in which a rubber material is easily invaded by providing a gap 64 communicating with the outside between the strands 61, 62, 63 by making it excessive is also known. However, the cord of the open stranded structure has no contact between the core strand group and the intermediate strand group, and the intermediate strand group and the side strand group do not contact each other. The strand group is easy to move and the twist stability is low.

また、図7に示すように、3層構造のコード70で、芯素線群、中間素線群および側素線群がそれぞれ所定数の素線71,72,73から成り、中心素線群あるいは中間素線群の一部素線に撚り合わせのためのくせとは異なる小さな螺旋状のくせを有する(図示の例は、中間素線群の9本の素線72の内の3本に螺旋状のくせを設けた場合を示している。)ものとしたものが提案されている(例えば、特許文献1参照)。このコード70は、螺旋状のくせを設けた素線72(「螺旋素線」という)と螺旋状のくせを設けていない素線(「非螺旋素線」という)との間に外側に連通する隙間74ができてゴム材が侵入する。そして、芯素線群の素線71が中間素線群のいずれかの素線72と係合し、中間素線群の素線72が側素線群のいずれかの素線73と係合するため、芯素線群および中間素線群のコード長手方向に対する自由度がなくなり、コード長手方向へのずれ動きが生じない。   In addition, as shown in FIG. 7, in the cord 70 having a three-layer structure, the core strand group, the intermediate strand group, and the side strand group are each composed of a predetermined number of strands 71, 72, 73, and the central strand group Alternatively, it has a small helical comb different from the twist for twisting a part of the intermediate strands (in the illustrated example, three of the nine strands 72 of the intermediate strands are included in three strands). A case in which a helical habit is provided is shown.) A proposal has been proposed (for example, see Patent Document 1). The cord 70 communicates with the outside between a strand 72 having a spiral bend (referred to as “spiral strand”) and a strand not provided with a spiral bevel (referred to as “non-spiral strand”). A gap 74 is formed and the rubber material enters. The strand 71 of the core strand group engages with any strand 72 of the intermediate strand group, and the strand 72 of the intermediate strand group engages with any strand 73 of the side strand group. Therefore, there is no degree of freedom in the cord longitudinal direction of the core strand group and the intermediate strand group, and no shift movement in the cord longitudinal direction occurs.

しかし、このように芯素線群あるいは中間素線群の素線に螺旋状のくせを設けた従来のコードは、一部素線だけを螺旋素線としたものであって、非螺旋素線同士によって囲まれる箇所は閉じた空洞部となり、そこにはゴム材が侵入しない。   However, the conventional cords in which the spiral strands are provided on the strands of the core strand group or the intermediate strand group in this way are those in which only some strands are spiral strands, and non-spiral strands A portion surrounded by each other becomes a closed cavity, and the rubber material does not enter there.

そこで、図8に示すように、3層構造のコード80で、芯素線群、中間素線群および側素線群がそれぞれ所定数の素線81,82,83から成るものにおいて、中間素線群の全ての素線82を螺旋素線とすることが考えられる。こうすることで、外側に連通する隙間84が拡大し、閉じた空洞部がなくなる。しかし、このように中間素線群の全ての素線82を螺旋素線とすると、コードの伸びが大きくなり、それが新たな問題となる。コードには、柔軟性を得るためにある程度の伸びは必要であるが、必要以上に伸びが大きいとタイヤの剛性を低下させてしまう。特に、近年スチール化がすすむタイヤのカーカス部に使用するコードでは、タイヤの走行安定性を低下させるため低荷重伸びの大きいコードは不適である。   Therefore, as shown in FIG. 8, in the cord 80 having a three-layer structure, the core strand group, the intermediate strand group, and the side strand group each include a predetermined number of strands 81, 82, and 83. It is conceivable that all the strands 82 of the line group are spiral strands. By doing so, the gap 84 communicating with the outside is enlarged, and the closed cavity is eliminated. However, if all the strands 82 of the intermediate strand group are spiral strands as described above, the elongation of the cord becomes large, which becomes a new problem. The cord needs to be stretched to some extent in order to obtain flexibility. However, if the cord is stretched more than necessary, the rigidity of the tire is lowered. In particular, a cord used for a carcass portion of a tire that is becoming steel in recent years is not suitable for a cord having a large low load elongation because the running stability of the tire is lowered.

特開2000−80578号公報JP 2000-80578 A

したがって、ゴム材侵入性が良好で、且つ、芯素線群や中間素線群のずれ動きがなくて撚り構造が安定し、低荷重伸びが小さい3層構造のゴム製品補強用スチールコードを得ることが課題である。   Accordingly, a rubber cord for reinforcing a rubber product having a three-layer structure having a good rubber material penetration property, no twist movement of the core strand group and intermediate strand group, a stable twisted structure, and a small low load elongation is obtained. This is a problem.

上記課題は、L+M+N(L=1〜4、M=4〜9、N=8〜15)の3層撚り構造、または1×P(P=13〜27)の束撚り3層構造のスチールコードを、外層を構成する素線群の少なくとも一部の素線同士の間に隙間が存在するとともに、中間層を構成する素線群の全ての素線が、撚り合わせのためのくせとは別に撚り合わせのためのくせよりピッチの小さいくせを有し、かつ、コード長手方向の略全ての箇所において、前記中間層を構成する素線群の少なくともいずれか1本の素線が、中心層を構成する素線群の少なくともいずれか1本の素線に接触しているよう構成することにより解決することができる。   The above-mentioned problem is a steel cord having a three-layer structure of L + M + N (L = 1 to 4, M = 4 to 9, N = 8 to 15) or a bundle twist three-layer structure of 1 × P (P = 13 to 27). There is a gap between at least some of the strands of the strand group constituting the outer layer, and all the strands of the strand group constituting the intermediate layer are separated from the habit for twisting. At least one strand of the strand group constituting the intermediate layer has a central layer in almost all locations in the longitudinal direction of the cord having a pitch smaller than the twist for twisting. The problem can be solved by making contact with at least one strand of the strand group to be configured.

このコードは、外層を構成する素線群(側素線群)の素線同士の隙間から侵入したゴム材が、中間層を構成する素線群(中間素線群)の撚り合わせのためのくせよりピッチの小さいくせを有する素線同士の間に形成される隙間から中間素線群と中心層を構成する素線群(芯素線群)の間に入り込む。しかも、このコードは、中間素線群の全ての素線が撚り合わせのためのくせよりピッチの小さいくせを有することにより、中間素線群と側素線群との間、および中間素線群と芯素線群との間に閉じた空洞部は存在しないものとなる。そのため、ゴム材が容易に侵入する。   This cord is used for twisting the strands of the strands constituting the intermediate layer (intermediate strands) by the rubber material that has entered through the gaps between the strands of the strands constituting the outer layer (side strands). The intermediate strand group and the strand group constituting the central layer (core strand group) enter from a gap formed between strands having a pitch smaller than the comb. In addition, this cord has a structure in which all the strands of the intermediate strand group have a pitch smaller than the pitch for twisting, so that the intermediate strand group is located between the intermediate strand group and the side strand group. There is no closed cavity between the core wire group and the core wire group. Therefore, the rubber material easily enters.

そして、このコードは、コード長手方向の略全ての箇所において、中間素線群の少なくともいずれか1本の素線が、芯素線群の少なくともいずれか1本の素線に接触しているため、中間素線群と芯素線群とがコード長手方向に連続して係合し、また、中間素線群の素線は側素線群の素線とも部分的に係合する。そのため、中間素線群のコード長手方向へのずれ動きが生じず、撚りが安定する。   In this cord, since at least any one strand of the intermediate strand group is in contact with at least one strand of the core strand group in almost all locations in the cord longitudinal direction. The intermediate strand group and the core strand group are continuously engaged in the cord longitudinal direction, and the strands of the intermediate strand group are also partially engaged with the strands of the side strand group. Therefore, the intermediate strand group does not shift in the longitudinal direction of the cord, and the twist is stabilized.

さらに、このコードは、コード長手方向の略全ての箇所において、中間素線群の少なくともいずれか1本の素線が、芯素線群の少なくともいずれか1本の素線に接触しているため、クローズド撚りコードと同様にコードの伸びが小さく、低荷重伸びを抑制できる。   Further, in this cord, since at least any one strand of the intermediate strand group is in contact with at least any one strand of the core strand group at almost all locations in the cord longitudinal direction. Like the closed twisted cord, the elongation of the cord is small and low load elongation can be suppressed.

また、上記課題は、L+M+N(L=1〜4、M=4〜9、N=8〜15)の3層撚り構造、または1×P(P=13〜27)の束撚り3層構造のスチールコードを、外層を構成する素線群の少なくとも一部の素線同士の間に隙間が存在するとともに、中間層を構成する素線群の全ての素線が、撚り合わせのためのくせとは別に撚り合わせのためのくせよりピッチの小さいくせを有し、かつ、前記中間層を構成する素線群の素線同士がコード中心軸に略平行となるよう略パラレルに接触して該中間層を構成する素線群の素線の撚り角と外層を構成する素線群の素線の撚り角との差が大きくなる箇所が、コード長手方向に不連続な配置で部分的に存在するよう構成することにより解決することができる。   In addition, the above-mentioned problem is that a three-layer twist structure of L + M + N (L = 1 to 4, M = 4 to 9, N = 8 to 15) or a bundle twist three-layer structure of 1 × P (P = 13 to 27). The steel cord has a gap between at least some of the strands of the strand group constituting the outer layer, and all strands of the strand group constituting the intermediate layer are twisted for twisting together. In addition, there is a pitch smaller than the twist for twisting, and the wires of the wire group constituting the intermediate layer come into contact with each other in substantially parallel so that the wires are substantially parallel to the cord central axis. The part where the difference between the strand angle of the strands of the strand group constituting the layer and the strand angle of the strand group constituting the outer layer is partially present in a discontinuous arrangement in the cord longitudinal direction This configuration can solve the problem.

このコードは、外層を構成する素線群(側素線群)の素線同士の隙間から侵入したゴム材が、中間層を構成する素線群(中間素線群)の撚り合わせのためのくせよりピッチの小さいくせを有する素線同士の間に形成される隙間から中間素線群と中心層を構成する素線群(芯素線群)の間に入り込む。しかも、このコードは、中間素線群の全ての素線が撚り合わせのためのくせよりピッチの小さいくせを有することにより、中間素線群と側素線群との間、および中間素線群と芯素線群との間に閉じた空洞部は存在しないものとなる。そのため、ゴム材が容易に侵入する。   This cord is used for twisting the strands of the strands constituting the intermediate layer (intermediate strands) by the rubber material that has entered through the gaps between the strands of the strands constituting the outer layer (side strands). The intermediate strand group and the strand group constituting the central layer (core strand group) enter from a gap formed between strands having a pitch smaller than the comb. In addition, this cord has a structure in which all the strands of the intermediate strand group have a pitch smaller than the pitch for twisting, so that the intermediate strand group is located between the intermediate strand group and the side strand group. There is no closed cavity between the core wire group and the core wire group. Therefore, the rubber material easily enters.

そして、このコードは、中間素線群の素線同士がコード中心軸に略平行となるよう略パラレルに接触して該中間素線群の素線の撚り角と側素線群の素線の撚り角との差が大きくなる箇所が、コード長手方向に不連続な配置で部分的に存在するため、撚り角が揃うことによる側素線群の素線の落ち込みが防止されて、ゴム材侵入路が確保される。   And this cord is contacted in approximately parallel so that the strands of the intermediate strand group are substantially parallel to the cord central axis, and the strand angle of the strand of the intermediate strand group and the strand of the side strand group The part where the difference from the twist angle becomes larger is partly discontinuously arranged in the longitudinal direction of the cord, preventing the strands of the side strands from falling due to the uniform twist angle and intruding the rubber material A road is secured.

さらに、このコードは、中間素線群の素線は側素線群の素線と部分的に係合するとともに、芯素線群の素線とは、コード長手方向の略全ての箇所において、中間素線群の少なくともいずれか1本の素線が、芯素線群の少なくともいずれか1本の素線に接触しているため、中間素線群と芯素線群とがコード長手方向に連続して係合することになり、そのため、中間素線群のコード長手方向へのずれ動きが生じず、撚りが安定する。また、このコードは、中間素線群の素線が芯素線群の素線に接触することになるため、コードの伸びが小さく、低荷重伸びを抑制できる。   Further, in this cord, the strands of the intermediate strand group are partially engaged with the strands of the side strand group, and the strands of the core strand group are substantially the same in the longitudinal direction of the cord. Since at least one strand of the intermediate strand group is in contact with at least one strand of the core strand group, the intermediate strand group and the core strand group are arranged in the longitudinal direction of the cord. As a result, the intermediate strand group is not displaced in the longitudinal direction of the cord, and the twist is stabilized. Further, in this cord, since the strands of the intermediate strand group come into contact with the strands of the core strand group, the cord has a small elongation and can suppress a low load elongation.

また、上記課題は、L+M+N(L=1〜4、M=4〜9、N=8〜15)の3層撚り構造、または1×P(P=13〜27)の束撚り3層構造のスチールコードを、外層を構成する素線群の少なくとも一部の素線同士の間に隙間が存在するとともに、中間層を構成する素線群の全ての素線が、撚り合わせのためのくせとは別に撚り合わせのためのくせよりピッチの小さいくせを有し、かつ、コード長手方向の略全ての箇所において、前記中間層を構成する素線群の少なくともいずれか1本の素線が、中心層を構成する素線群の少なくともいずれか1本の素線に接触しているとともに、前記中間層を構成する素線群の素線同士がコード中心軸に略平行となるよう略パラレルに接触して該中間層を構成する素線群の素線の撚り角と外層を構成する素線群の素線の撚り角との差が大きくなる箇所が、コード長手方向に不連続な配置で部分的に存在するよう構成することにより解決することができる。   In addition, the above-mentioned problem is that a three-layer twist structure of L + M + N (L = 1 to 4, M = 4 to 9, N = 8 to 15) or a bundle twist three-layer structure of 1 × P (P = 13 to 27). The steel cord has a gap between at least some of the strands of the strand group constituting the outer layer, and all strands of the strand group constituting the intermediate layer are twisted for twisting together. In addition, at least one strand of the strand group constituting the intermediate layer has a pitch smaller than the twist for twisting, and at almost all locations in the longitudinal direction of the cord, The wires in contact with at least one of the wires constituting the layer are in contact with each other so that the wires in the wires constituting the intermediate layer are substantially parallel to the cord central axis. The strands of the strands of the strands constituting the intermediate layer and the outer layer Point the difference between the twist angle of the strands of the strand group is large, it can be solved by constructing so that partially present in the code longitudinally discontinuous arrangement.

このコードは、外層を構成する素線群(側素線群)の素線同士の隙間から侵入したゴム材が、中間層を構成する素線群(中間素線群)の撚り合わせのためのくせよりピッチの小さいくせを有する素線同士の間に形成される隙間から中間素線群と中心層を構成する素線群(芯素線群)の間に入り込む。しかも、このコードは、中間素線群の全ての素線が撚り合わせのためのくせよりピッチの小さいくせを有することにより、中間素線群と側素線群との間、および中間素線群と芯素線群との間に閉じた空洞部は存在しないものとなる。そのため、ゴム材が容易に侵入する。   This cord is used for twisting the strands of the strands constituting the intermediate layer (intermediate strands) by the rubber material that has entered through the gaps between the strands of the strands constituting the outer layer (side strands). The intermediate strand group and the strand group constituting the central layer (core strand group) enter from a gap formed between strands having a pitch smaller than the comb. In addition, this cord has a structure in which all the strands of the intermediate strand group have a pitch smaller than the pitch for twisting, so that the intermediate strand group is located between the intermediate strand group and the side strand group. There is no closed cavity between the core wire group and the core wire group. Therefore, the rubber material easily enters.

そして、このコードは、中間素線群の素線同士がコード中心軸に略平行となるよう略パラレルに接触して該中間素線群の素線の撚り角と外層を構成する素線群の素線の撚り角との差が大きくなる箇所が、コード長手方向に不連続な配置で部分的に存在するため、撚り角が揃うことによる側素線群の素線の落ち込みが防止されて、ゴム材侵入路が確保される。   And this cord is contacted in approximately parallel so that the strands of the intermediate strand group are substantially parallel to the cord central axis, and the strand angle of the strand of the intermediate strand group and the strand group constituting the outer layer Since the part where the difference with the strand angle of the strand is large is partially present in a discontinuous arrangement in the cord longitudinal direction, the falling of the strands of the side strand group due to the uniform twist angle is prevented, A rubber entry path is secured.

さらに、このコードは、コード長手方向のいずれの箇所においても、中間素線群の少なくとも1本の素線が芯素線群の素線のいずれかに常に接触し、また、中間素線群の素線は側素線群の素線とも部分的に係合する。そのため、中間素線群のコード長手方向へのずれ動きが生じず、撚りが安定する。   Furthermore, in this cord, at any location in the longitudinal direction of the cord, at least one strand of the intermediate strand group always contacts one of the strands of the core strand group. The strands partially engage with the strands of the side strand group. Therefore, the intermediate strand group does not shift in the longitudinal direction of the cord, and the twist is stabilized.

また、このコードは、コード長手方向の略全ての箇所において、中間素線群の少なくともいずれか1本の素線が、中心層を構成する素線群の少なくともいずれか1本の素線に接触しているため、クローズド撚りコードと同様にコードの伸びが小さく、低荷重伸びを抑制できる。   In addition, in this cord, at almost all locations in the longitudinal direction of the cord, at least one strand of the intermediate strand group contacts at least one strand of the strand group constituting the center layer. Therefore, the elongation of the cord is small as in the case of the closed twist cord, and the low load elongation can be suppressed.

上記構成のコードにおいて、撚り合わせのためのくせよりピッチの小さいくせは、素線に螺旋状のくせを付けた後押圧加工したことより得られたくせであるのが好ましい。所望のくせ形状に歯型を加工した一対の歯車間に素線を通してもジグザク状に折り曲げられて成る小さなくせが得られるが、そうした手段でくせ付けした素線は、折り曲げられた箇所が折り曲げられない箇所より加工度が大きくなり、この加工度が大きい折り曲げ箇所に応力が残留し、これに外力による応力が加わることで折り曲げ箇所の応力が過大になって耐疲労性が低下する。それに対し、螺旋状のくせを施した後、押圧加工したことにより得られたくせは、どの箇所においても加工度が均等になるので、過大な応力が作用せず、耐疲労性に優れたものとなる。   In the cord having the above-described configuration, the habit having a smaller pitch than the habit for twisting is preferably a habit obtained by pressing a strand after forming a helical habit on the strand. Even if a wire is passed between a pair of gears whose teeth have been processed into a desired shape, a small wrinkle can be obtained by bending the wire into a zigzag shape. The degree of work becomes greater than the part where there is not, stress remains in the bent part where the degree of work is large, and stress due to external force is added to this, so that the stress at the bent part becomes excessive and the fatigue resistance decreases. On the other hand, the wrinkle obtained by applying a pressurizing process after applying a helical wrinkle has an even degree of processing at any location, so that excessive stress does not act and it has excellent fatigue resistance. Become.

また、撚り合わせのためのくせよりピッチの小さいくせは、ピッチP1が、P1=0.2Pc〜0.5Pc(但し、Pcは撚り合わせのピッチ)で、波高hが、h=0.2d〜1.2d(但し、dは素線径)であるのが好ましい。ピッチP1が0.2Pcより小さいと、くせ付け時に過大な応力が作用する無理な塑性変形を伴うこととなって、素線が折れやすくなるとともに生産性が低下し、ピッチP1が0.5Pcより大きいと、引張力が均等に負荷されなくなって、中間素線群の撚りの安定性が悪くなると共に、耐疲労性が悪くなる。また、波高hが0.2dよりも小さいと、各素線間の隙間が小さくなりすぎて、流動性の良いゴム材を使用しても加圧加硫時にゴム材が内部へ充分に侵入できず、波高hが1.2dmmより大きいと、撚りの安定性が悪くなり耐疲労性が悪化する。なお、これら撚り合わせのためのくせよりピッチの小さいくせのピッチP1および波高hの値は、コードから撚りをほぐして取り出した素線のものと一致する。   Further, the pitch P1 is P1 = 0.2Pc to 0.5Pc (where Pc is the pitch of twisting) and the wave height h is h = 0.2d to It is preferably 1.2d (where d is the wire diameter). If the pitch P1 is smaller than 0.2 Pc, excessive plastic deformation is applied to cause excessive stress at the time of soldering, so that the strands are easily broken and the productivity is lowered, and the pitch P1 is less than 0.5 Pc. If it is large, the tensile force is not evenly applied, and the twist stability of the intermediate strand group is deteriorated and the fatigue resistance is deteriorated. Also, if the wave height h is less than 0.2d, the gap between the wires becomes too small, and even if a rubber material with good fluidity is used, the rubber material can sufficiently penetrate into the interior during pressure vulcanization. If the wave height h is greater than 1.2 dmm, the twist stability is deteriorated and the fatigue resistance is deteriorated. Note that the values of the pitch P1 and the wave height h, which have a smaller pitch than the twists for twisting, coincide with those of the strands obtained by untwisting the cord.

本発明のゴム製品補強用スチールコードは以下の方法で製造することができる。
すなわち、L+M+N(L=1〜4本、M=4〜9、N=8〜15)の3層撚り構造のスチールコードの場合、L本の素線を撚り合わせて中心層を構成する素線群とし、該中心層を構成する素線群の上に、螺旋状のくせを付けた後押圧加工して得られた略二次元波状で撚り合わせのためのくせよりピッチの小さいくせを有するM本の素線を撚り合わせて中間層を構成する素線群とし、該中間層を構成する素線群の上に少なくとも一部の素線同士の間に隙間が存在するようN本の素線を撚り合わせて外層を構成する素線群とし、こうして形成した3層撚り構造のスチールコードにコード長手方向に直交する方向から押圧加工を施すことで本発明のスチールコードを製造することができる。
The steel cord for reinforcing rubber products of the present invention can be manufactured by the following method.
That is, in the case of a steel cord having a three-layer twisted structure of L + M + N (L = 1 to 4, M = 4 to 9, N = 8 to 15), a strand constituting the central layer by twisting L strands M, which is a two-dimensional wave shape obtained by pressing a strand after forming a spiral bevel on the strands constituting the central layer and having a pitch smaller than the twist for twisting The strands of the strands constituting the intermediate layer by twisting the strands of the strands, and the strands of N wires so that a gap exists between at least some strands on the strands of the strand constituting the intermediate layer The steel cord of the present invention can be manufactured by applying a pressing process from the direction orthogonal to the cord longitudinal direction to the steel cord having the three-layer twist structure formed in this manner.

また、1×P(P=13〜27)の束撚り3層構造のスチールコードの場合、中間層を構成する素線群の全ての素線を、螺旋状のくせを付けた後押圧加工して得られた略二次元波状で撚り合わせのためのくせよりピッチの小さいくせを有するものとし、該略二次元波状のくせを有する素線からなる中間層の素線群と中心層の素線群と外層の素線群の各素線を同一方向および同一ピッチで一度に撚り合わせて前記外層の少なくとも一部の素線同士の間に隙間が存在する束撚り3層構造のスチールコードを形成し、該スチールコードにコード長手方向に直交する方向から押圧加工を施すことで本発明のスチールコードを製造することができる。   In addition, in the case of a steel cord having a 1 × P (P = 13 to 27) bundle-twisted three-layer structure, all the strands of the strand group constituting the intermediate layer are subjected to a pressing process after adding a helical comb. An intermediate layer group consisting of strands having a substantially two-dimensional corrugated shape and a pitch smaller than the twist for twisting, and a core layer strand The strands of the strands of the group and the outer layer are twisted at once in the same direction and at the same pitch to form a bundle-twisted three-layer steel cord in which a gap exists between at least some of the strands of the outer layer And the steel cord of this invention can be manufactured by giving a pressing process to this steel cord from the direction orthogonal to a cord longitudinal direction.

このように芯素線群の上に略二次元波状のくせを有する中間素線群の素線を撚り合わせ、さらに側素線群の素線を撚り合わせてなる3層撚り構造のスチールコードにコード長手方向に直交する方向から押圧加工を施すことにより、また、略二次元波状のくせを有する素線からなる中間素線群と芯素線群および側素線群の素線を一度に撚り合わせてなる束撚り3層構造のスチールコードにコード長手方向に直交する方向から押圧加工を施すことにより、コード長手方向の略全ての箇所において、中間素線群の少なくともいずれか1本の素線が、芯素線群の少なくともいずれか1本の素線に常に接触しているコードとなり、また、中間素線群の素線同士がコード中心軸に略平行となるよう略パラレルに接触して中間素線群の素線の撚り角と外層を構成する素線群の素線の撚り角との差が大きくなる箇所が、コード長手方向に不連続な配置で部分的に存在するコードとなる。   In this way, a steel cord having a three-layer twist structure is formed by twisting the strands of the intermediate strand group having a substantially two-dimensional wavy habit on the core strand group and further twisting the strands of the side strand group. By pressing from the direction orthogonal to the longitudinal direction of the cord, the strands of the intermediate strand group consisting of strands having a substantially two-dimensional undulation, the core strand group and the side strand group are twisted at once. By applying a pressing process to the steel cord having a bundle-twisted three-layer structure formed in a direction orthogonal to the longitudinal direction of the cord, at least any one strand of the intermediate strand group in almost all the locations in the longitudinal direction of the cord Is a cord that is always in contact with at least one strand of the core strand group, and in parallel so that the strands of the intermediate strand group are substantially parallel to the cord center axis. The strand angle and outer layer of the strands of the intermediate strand group Point the difference between the twist angle of the strand of the strand group to be formed becomes large, the code present partially in discontinuous located in code longitudinally.

これらの製造方法において、中間素線群の素線は、螺旋状のくせを付けた後押圧加工して略二次元波状のくせを付けたものを一旦リール等に巻き取り、撚線機の繰り出し装置に所定本数分をセットして撚り合わせてもよいし、撚線機の繰り出し装置から撚り口までの間でくせ付け加工を行うようにしてもよい。   In these manufacturing methods, the strands of the intermediate strand group are wound with a helical wrinkle, then pressed and wound into a reel, etc., and then rolled out by a twisting machine. A predetermined number of wires may be set and twisted together in the device, or the kneading process may be performed between the twisting device and the twisting port.

本発明によれば、ゴム材侵入性が良好で、且つ、芯素線群や中間素線群のずれ動きがなくて撚り構造が安定すると共に低荷重伸びが小さい3層構造のゴム製品補強用スチールコードを得ることができ、このコードを例えば自動車用タイヤの補強材として使用することにより、タイヤの寿命を大幅に延長することができる。また、このコードは、低荷重伸びが小さいため、近年スチール化が進むタイヤのカーカス部に使用することができる。   According to the present invention, for rubber product reinforcement with a three-layer structure that has good rubber material penetration, no twist movement of the core strand group and intermediate strand group, stable twist structure, and low low load elongation A steel cord can be obtained, and the life of the tire can be greatly extended by using this cord as a reinforcing material for an automobile tire, for example. In addition, since the low load elongation is small, this cord can be used for a carcass portion of a tire that is becoming steel.

また、このコードは、中間素線群の素線の撚り合わせのためのくせよりピッチの小さいくせを、素線に螺旋状のくせを付けた後押圧加工したことより得られたくせとすることで、加工度が均等となり、過大な応力が作用せず、耐疲労性に優れたものとなるようにすることができる。   In addition, this cord is made by making a habit with a smaller pitch than the habit for twisting the strands of the intermediate strand group, and a habit obtained by pressing the strand after adding a helical habit to the strand. Further, the degree of processing becomes uniform, excessive stress does not act, and excellent fatigue resistance can be achieved.

また、このコードは、撚りをほぐした後の素線の状態で、撚り合わせのためのくせよりピッチの小さいくせのピッチP1が、P1=0.2Pc〜0.5Pc(但し、Pcは撚り合わせのピッチ)であるようにすることで、無理な塑性変形を避けるとともに生産性を高めることができ、また、中間素線群の撚りの安定性並びに耐疲労性が悪化しないようにすることができる。また、撚りをほぐした後の素線の状態で、撚り合わせのためのくせよりピッチの小さいくせの波高hが、h=0.2d〜1.2d(但し、dは素線径)とあるようすることで、ゴム材が内部へ充分に侵入できるとともに、撚りの安定性並びに耐疲労性が悪化しないようにすることができる。   Also, this cord is in the state of the strand after untwisting, and the pitch P1, which is smaller than the twist for twisting, is P1 = 0.2Pc to 0.5Pc (where Pc is twisted) In this case, it is possible to avoid excessive plastic deformation and increase productivity, and to prevent the twist stability and fatigue resistance of the intermediate strand group from being deteriorated. . Further, in the state of the strands after untwisting the strands, the wave height h of the pitch having a smaller pitch than the strand for twisting is h = 0.2d to 1.2d (where d is the strand diameter). By doing so, the rubber material can sufficiently penetrate into the inside, and the stability of twisting and fatigue resistance can be prevented from deteriorating.

以下、本発明の実施形態のゴム製品補強用スチールコード(以下、「スチールコード」あるいは、単に「コード」という。)を図面を参照して説明する。   Hereinafter, a steel cord for reinforcing rubber products according to an embodiment of the present invention (hereinafter referred to as “steel cord” or simply “cord”) will be described with reference to the drawings.

図1はL+M+N(L=1〜4、M=4〜9、N=8〜15)の3層撚り構造のスチールコードの場合の実施形態の一例として、1+5+11構造のスチールコードの断面構造を示している。   FIG. 1 shows a cross-sectional structure of a steel cord having a 1 + 5 + 11 structure as an example of an embodiment of a steel cord having a three-layer twist structure of L + M + N (L = 1 to 4, M = 4 to 9, N = 8 to 15). ing.

図1に示すコード(スチールコード)10は、1+5+11の3層撚り構造で、1本の素線(芯素線11)の周りに略正弦波状の小さなくせ(撚り合わせのためのくせよりピッチの小さいくせ)を有する5本の素線(中間素線12)を撚り合わせ、外側(最外)に、撚り合わせのためのくせのみを有する11本の素線(側素線13)を撚り合わせ、こうして形成した3層撚り構造のコードにコード長手方向に直交する方向から押圧加工を施したものである。   The cord (steel cord) 10 shown in FIG. 1 has a 1 + 5 + 11 three-layer twisted structure, and has a small sine wave around a single strand (core strand 11) (pitch more than the strand for twisting). 5 strands (intermediate strands 12) having small habits are twisted, and 11 strands (side strands 13) having only a habit for twisting are twisted outside (outermost). The cord having the three-layer twisted structure thus formed is pressed from the direction orthogonal to the cord longitudinal direction.

このコード10は、外層を構成する素線群の少なくとも一部の素線(側素線13)同士の間に隙間14が存在するとともに、中間層を構成する素線群(中間素線群)の素線(中間素線12)の全てが、撚り合わせのためのくせとは別に略二次元波状で撚り合わせのためのくせよりピッチおよび波高の小さいくせを有している。この略二次元波状のくせは、素線(中間素線12)に螺旋状のくせを付けた後押圧加工したことにより得られたくせであり、撚り合わせ前の素線の状態では略正弦波状である。   The cord 10 includes a gap 14 between at least some of the strands (side strands 13) of the strand group constituting the outer layer, and a strand group (intermediate strand group) constituting the intermediate layer. All of the strands (intermediate strands 12) are substantially two-dimensional wavy apart from the twist for twisting, and have a pitch and a pitch smaller than the twist for twisting. This substantially two-dimensional wave-like habit is a habit obtained by applying a helical wrinkle to an element wire (intermediate element wire 12) and then pressing it. In the state of the element wire before twisting, it is substantially sinusoidal. is there.

撚り合わせ前の素線の略正弦波状のくせは、図3に示すとおり波の谷から谷までまたは山から山までの長さ(周期)P1を意味し、波高とは、波の谷から山までの高さ(振幅)hを意味する。中間素線12の略二次元波状のくせは、ピッチP1が、P1=0.2Pc〜0.5Pc(但し、Pcは撚り合わせのピッチ)で、波高hが、h=0.2d〜1.2d(但し、dは素線径)である。なお、素線径dは、0.15〜0.40mmであるのが好ましい。0.15mm未満であるとスチールコードの強度が低下し、0.40mmを越えると柔軟性が悪化する。   The substantially sinusoidal habit of the strands before twisting means the length (period) P1 from the wave valley to the valley or from the mountain to the mountain as shown in FIG. 3, and the wave height is from the wave valley to the mountain. Means the height (amplitude) h. The intermediate wire 12 has a substantially two-dimensional wavy pitch P1 of P1 = 0.2Pc to 0.5Pc (where Pc is a twisted pitch) and a wave height h of h = 0.2d to 1.d. 2d (where d is the wire diameter). In addition, it is preferable that the strand diameter d is 0.15-0.40 mm. If it is less than 0.15 mm, the strength of the steel cord is lowered, and if it exceeds 0.40 mm, the flexibility is deteriorated.

そして、このコード10は、コード長手方向の略全ての箇所において、中間素線群の素線(中間素線12)の少なくともいずれか1本の素線が、図1に示すように中心層を構成する素線群(芯素線群)の素線(芯素線11)に接触(芯素線群の芯素線11が複数本の場合は、少なくともいずれか一本の芯素線11に接触)している。   The cord 10 has at least one strand of the strands of the intermediate strand group (intermediate strand 12) in the central portion of the cord longitudinal direction as shown in FIG. Contact with the strands (core strands 11) of the strand group (core strand group) to be configured (when there are a plurality of core strands 11 of the core strand group), contact with at least one of the core strands 11 Contact).

また、このコード10は、図4に示すように、中間素線群の素線(中間素線12)同士がコード長手方向に不連続な配置で部分的に略パラレルに接触し、その略パラレルに接触する箇所(範囲)Aで、中間素線12の撚り角αが0(ゼロ)で、図示しない外層を構成する素線群(側素線群)の素線(側素線13)の撚り角(中間素線12の非パラレル部分での撚り角αと同じ)との差が大きくなっている。   In addition, as shown in FIG. 4, the cord 10 includes a group of intermediate strands (intermediate strands 12) which are in contact with each other in a discontinuous arrangement in the longitudinal direction of the cord and partially in parallel. Of the strand (side strand 13) of the strand group (side strand group) constituting the outer layer (not shown), where the twist angle α of the intermediate strand 12 is 0 (zero). The difference from the twist angle (same as the twist angle α in the non-parallel portion of the intermediate strand 12) is large.

芯素線11(芯素線群)の上に、略正弦波状の小さなくせを有する複数本(図の例では5本)の中間素線12を、コード長手方向の略全ての箇所において、中間素線12の少なくともいずれか1本の素線が芯素線11に接触するように撚り合わせると、それら複数本の中間素線12は、コード長手方向に間隔をおいて周期的になじんで所定の撚り角αとなる部分と、押し潰れた格好で略パラレルに接触し合う部分とができ、図4に示すような撚り構造となるのである。   On the core strand 11 (core strand group), a plurality of intermediate strands 12 (five in the example shown in the figure) having a small sine wave shape are placed at almost all locations in the longitudinal direction of the cord. When the strands 12 are twisted so that at least one of the strands 12 comes into contact with the core strand 11, the plurality of intermediate strands 12 are periodically blended at predetermined intervals in the longitudinal direction of the cord. The portion having the twist angle α and the portion in contact with each other in a substantially parallel fashion are formed, and a twisted structure as shown in FIG. 4 is obtained.

このコード10は、側素線群の素線(側素線13)同士の隙間14から侵入したゴム材が、中間素線群の略二次元波状の小さなくせを有する素線(中間素線12)同士の間に形成される隙間15から中間素線群と芯素線群の間に入り込む。しかも、このコード10は、中間素線群の全ての素線(中間素線12)が略二次元波状の小さなくせを有することにより、中間素線群と側素線群との間、および中間素線群と芯素線群との間に閉じた空洞部は存在しないものとなる。そのため、ゴム材が容易に侵入する。   In the cord 10, a rubber material that has entered from a gap 14 between the strands of the side strand group (side strand 13) has a strand (intermediate strand 12) having a small two-dimensional wavy shape of the intermediate strand group. ) It enters between the intermediate strand group and the core strand group from the gap 15 formed between them. In addition, the cord 10 has an intermediate wire group between the intermediate wire group and the side wire group because all the wires (intermediate wire 12) of the intermediate wire group have a small two-dimensional wavy shape. There is no closed cavity between the strand group and the core strand group. Therefore, the rubber material easily enters.

そして、このコード10は、中間素線群の素線(中間素線12)同士がコード中心軸に略平行となるよう略パラレルに接触して該中間素線群の素線(中間素線12)の撚り角と外層を構成する素線群の素線の撚り角との差が大きくなる箇所が、コード長手方向に不連続な配置で部分的に存在するため、撚り角が揃うことによる側素線群の素線(側素線13)の落ち込みが防止されて、ゴム材侵入路が確保される。   The cord 10 is brought into contact with each other in a substantially parallel manner so that the strands of the intermediate strand group (intermediate strands 12) are substantially parallel to the cord central axis. ) And the strand angle of the strands of the strands constituting the outer layer are partially discontinuously arranged in the longitudinal direction of the cord. The strands of the strand group (side strands 13) are prevented from dropping, and a rubber material intrusion path is secured.

さらに、このコード10は、コード長手方向の略全ての箇所において、中間素線群の少なくともいずれか1本の素線(中間素線12)が芯素線群の少なくともいずれか1本の素線(芯素線11)に常に接触し、また、中間素線群の素線(中間素線12)は側素線群の素線(側素線13)とも部分的に係合する。そのため、中間素線群のコード長手方向へのずれ動きが生じず、撚りが安定する。   Further, the cord 10 includes at least any one strand of the intermediate strand group (intermediate strand 12) at least any one strand of the core strand group at almost all locations in the cord longitudinal direction. The core wires 11 are always in contact with each other, and the strands of the intermediate strand group (intermediate strands 12) are also partially engaged with the strands of the side strand group (side strand 13). Therefore, the intermediate strand group does not shift in the longitudinal direction of the cord, and the twist is stabilized.

また、図2は1×P(P=13〜27)の束撚り3層構造のスチールコードの場合の実施形態の一例として、1×16の束撚り3層構造のスチールコードの断面構造を示している。   FIG. 2 shows a cross-sectional structure of a 1 × 16 bundle-twisted three-layer steel cord as an example of an embodiment in the case of a 1 × P (P = 13-27) bundle-twisted three-layer steel cord. ing.

図2に示すコード(スチールコード)20は、1×16の束撚り3層構造で、1本の素線(芯素線21)を中心とし、その周りに略正弦波状の小さなくせ(撚り合わせのためのくせよりピッチの小さいくせ)を有する5本の素線(中間素線22)を配置し、外側(最外)に10本の素線(側素線23)を配置して一度に撚り合わせ、こうして形成した束撚り3層構造のコードにコード長手方向に直交する方向から押圧加工を施したものである。   The cord (steel cord) 20 shown in FIG. 2 has a 1 × 16 bundle-twisted three-layer structure, with a single strand (core strand 21) as the center and a small sinusoidal twist (twisting together) around it. 5 strands (intermediate strands 22) having a pitch smaller than that of the forehead are disposed, and 10 strands (side strands 23) are disposed on the outside (outermost) at a time. The cords of the bundle-twisted three-layer structure formed by twisting are subjected to pressing from the direction orthogonal to the cord longitudinal direction.

このコード20は、外層を構成する素線群の少なくとも一部の素線(側素線23)同士の間に隙間24が存在するとともに、中間層を構成する素線群(中間素線群)の素線(中間素線22)の全てが、撚り合わせのためのくせとは別に略二次元波状で撚り合わせのためのくせよりピッチおよび波高の小さいくせを有している。この略二次元波状のくせは、素線(中間素線22)に螺旋状のくせを付けた後押圧加工したことにより得られたくせであり、撚り合わせ前の素線の状態では略正弦波状である。   The cord 20 includes a gap 24 between at least some of the strands (side strands 23) of the strand group constituting the outer layer, and a strand group (intermediate strand group) constituting the intermediate layer. All of the strands (intermediate strands 22) are substantially two-dimensional wavy apart from the twist for twisting, and have a pitch and a wave height smaller than the twist for twisting. This substantially two-dimensional wave-like wrinkle is a habit obtained by adding a helical wrinkle to an element wire (intermediate element wire 22) and then pressing it. In the state of the element wire before twisting, it is substantially sinusoidal. is there.

このコード20の場合も、撚り合わせ前の中間素線22の略正弦波状のくせは、図3に示すようにピッチP1が、P1=0.2Pc〜0.5Pc(但し、Pcは撚り合わせのピッチ)で、波高hが、h=0.2d〜1.2d(但し、dは素線径)である。なお、素線径dは、0.15〜0.40mmであるのが好ましい。0.15mm未満であるとスチールコードの強度が低下し、0.40mmを越えると柔軟性が悪化する。   In the case of this cord 20 as well, the substantially sinusoidal habit of the intermediate strand 22 before twisting is such that the pitch P1 is P1 = 0.2 Pc to 0.5 Pc (where Pc is twisted) as shown in FIG. Pitch) and the wave height h is h = 0.2d to 1.2d (where d is the wire diameter). In addition, it is preferable that the strand diameter d is 0.15-0.40 mm. If it is less than 0.15 mm, the strength of the steel cord is lowered, and if it exceeds 0.40 mm, the flexibility is deteriorated.

そして、このコード20も、コード長手方向の略全ての箇所において、中間素線群の素線(中間素線22)の少なくともいずれか1本の素線が、図2に示すように中心層を構成する素線群(芯素線群)の素線(芯素線21)に接触(芯素線群の芯素線21が複数本の場合は、少なくともいずれか一本の芯素線21に接触)している。   The cord 20 also has at least one strand of the strand of the intermediate strand group (intermediate strand 22) in the central portion of the cord longitudinal direction as shown in FIG. Contact with the strands (core strands 21) of the constituent strand group (core strand group) (in the case where there are a plurality of core strands 21 of the core strand group), at least one of the core strands 21 Contact).

そして、このコード20も、図4に示すように、中間素線群の素線(中間素線22)同士がコード長手方向に不連続な配置で部分的に略パラレルに接触し、その略パラレルに接触する箇所(範囲)Aで、中間素線22の撚り角αが0(ゼロ)で、図示しない外層を構成する素線群(側素線群)の素線(側素線23)の撚り角(中間素線22の非パラレル部分での撚り角αと同じ)との差が大きくなっている。   As shown in FIG. 4, the cord 20 is also configured such that the strands of the intermediate strand group (intermediate strands 22) are in contact with each other in a partially discontinuous arrangement in the longitudinal direction of the cord, and are substantially parallel. Of the strand (side strand 23) of the strand group (side strand group) constituting the outer layer (not shown) when the twist angle α of the intermediate strand 22 is 0 (zero). The difference from the twist angle (same as the twist angle α in the non-parallel portion of the intermediate strand 22) is large.

芯素線21(芯素線群)の周りに、略正弦波状の小さなくせを有する複数本(図の例では5本)の中間素線22を配置し、外側(最外)に側素線23を配置して、コード長手方向の略全ての箇所において、中間素線22の少なくともいずれか1本が芯素線21に接触するように一度で撚り合わせると、複数本の中間素線22は、コード長手方向に間隔をおいて周期的になじんで所定の撚り角αとなる部分と、押し潰れた格好で略パラレルに接触し合う部分とができ、図4に示すような撚り構造となるのである。   Around the core strand 21 (core strand group), a plurality of intermediate strands 22 (five in the example shown in the figure) having a small sine wave shape are arranged, and the side strands are arranged outside (outermost). 23, and twisting at a time so that at least one of the intermediate strands 22 is in contact with the core strand 21 at almost all locations in the longitudinal direction of the cord, the plurality of intermediate strands 22 are In addition, a portion having a predetermined twist angle α that is adapted to periodically in the longitudinal direction of the cord to a predetermined twist angle α and a portion in contact with each other in a substantially parallel manner can be formed, resulting in a twist structure as shown in FIG. It is.

このコード20は、側素線群の素線(側素線23)同士の隙間24から侵入したゴム材が、中間素線群の略二次元波状の小さなくせを有する素線(中間素線22)同士の間に形成される隙間25から中間素線群と芯素線群の間に入り込む。しかも、このコード20は、中間素線群の全ての素線(中間素線22)が略二次元波状の小さなくせを有することにより、中間素線群と側素線群との間、および中間素線群と芯素線群との間に閉じた空洞部は存在しないものとなる。そのため、ゴム材が容易に侵入する。   In the cord 20, a rubber material that has entered through a gap 24 between the strands of the side strand group (side strands 23) has a substantially two-dimensional wave-like strand of the intermediate strand group (intermediate strand 22). ) It enters between the intermediate strand group and the core strand group from the gap 25 formed between them. In addition, since all the strands (intermediate strands 22) of the intermediate strand group have a small two-dimensional wavy shape, this code 20 is provided between the intermediate strand group and the side strand group and between There is no closed cavity between the strand group and the core strand group. Therefore, the rubber material easily enters.

そして、このコード20は、中間素線群の素線(中間素線22)同士がコード中心軸に略平行となるよう略パラレルに接触して該中間素線群の素線(中間素線22)の撚り角と外層を構成する素線群の素線の撚り角との差が大きくなる箇所が、コード長手方向に不連続な配置で部分的に存在するため、撚り角が揃うことによる側素線群の素線(側素線23)の落ち込みが防止されて、ゴム材侵入路が確保される。   The cord 20 is brought into contact with each other in a substantially parallel manner so that the strands of the intermediate strand group (intermediate strands 22) are substantially parallel to the cord central axis. ) And the strand angle of the strands of the strands constituting the outer layer are partially discontinuously arranged in the longitudinal direction of the cord. The strands of the strand group (side strands 23) are prevented from dropping, and a rubber material entry path is secured.

さらに、このコード20は、コード長手方向の略全ての箇所において、中間素線群の少なくともいずれか1本の素線(中間素線22)が芯素線群の少なくともいずれか1本の素線(芯素線21)に常に接触し、また、中間素線群の素線(中間素線22)は側素線群の素線(側素線23)とも部分的に係合する。そのため、中間素線群のコード長手方向へのずれ動きが生じず、撚りが安定する。   Further, the cord 20 is configured such that at almost any position in the longitudinal direction of the cord, at least one strand of the intermediate strand group (intermediate strand 22) is at least one strand of the core strand group. The core wires 21 are always in contact with each other, and the strands of the intermediate strand group (intermediate strands 22) are also partially engaged with the strands of the side strand group (side strands 23). Therefore, the intermediate strand group does not shift in the longitudinal direction of the cord, and the twist is stabilized.

実施例として、直径5.5mmのスチール線材を、パテンティングおよび伸線加工を繰り返した後、表面にブラスメッキを施して、線径0.25mmの素線とし、この素線を用いて、1+5+11の3層撚り構造、1×16の束撚り3層構造の2種類のコードを製造した。   As an example, a steel wire having a diameter of 5.5 mm was repeatedly subjected to patenting and wire drawing, and then the surface was subjected to brass plating to form a strand having a wire diameter of 0.25 mm. Using this strand, 1 + 5 + 11 Two types of cords having a three-layer twisted structure and a 1 × 16 bundle-twisted three-layer structure were manufactured.

1+5+11構造の実施例のコードは、中間素線群とする5本の素線を、それぞれ螺旋状のくせを付けた後、押圧加工によって略正弦波状の小さなくせ(撚り合わせのためのくせよりピッチの小さいくせ)を有する素線に加工し、その5本の素線を1本の芯素線の周りに撚り合わせて中間素線群とし、その外側(最外)に11本の素線(側素線)を撚り合わせて3層撚り構造のコードを形成し、こうして形成したコードにコード長手方向に直交する方向から押圧加工を施して製造したものである。   In the cord of the embodiment of the 1 + 5 + 11 structure, the five strands as the intermediate strand group are each formed with a helical wrinkle and then subjected to pressing to form a small sinusoidal wrinkle (pitch from a twist for twisting). The strands are processed into strands, and the 5 strands are twisted around one core strand to form an intermediate strand group, and 11 strands (outermost) Side cords) are twisted together to form a cord with a three-layer twist structure, and the cord thus formed is manufactured by pressing from the direction perpendicular to the longitudinal direction of the cord.

また、1×16構造の実施例のコードは、中間素線群となる5本の素線を、それぞれ螺旋状のくせを付けた後、押圧加工によって略正弦波状の小さなくせ(撚り合わせのためのくせよりピッチの小さいくせ)を有する素線に加工し、1本の素線(芯素線)の周りにそれら略正弦波状の小さなくせを有する5本の素線(中間素線)を配置し、外側(最外)に10本の素線(側素線)を配置して一度に撚り合わせ、こうして形成した束撚り3層構造のコードにコード長手方向に直交する方向から押圧加工を施して製造したものである。   In addition, the cord of the embodiment of the 1 × 16 structure is formed by attaching a spiral bead to each of the five strands that are the intermediate strand group, and then pressing the press-work to form a small sinusoidal warp (for twisting). 5 strands (intermediate strands) having small sine wave-like small bends around one strand (core strand). Then, ten strands (side strands) are arranged on the outside (outermost) and twisted at once, and the cord of the bundle-twisted three-layer structure thus formed is pressed from the direction orthogonal to the cord longitudinal direction. Manufactured.

いずれの場合も、螺旋状のくせは、供給される素線を軸芯として回転するくせ付け装置(特公昭63−63293号公報等記載のくせ付け装置)を用いて付与した。くせ形状は、くせ付けピンの間隔、くせ付けピンの寸法および、素線を軸芯として回転する回転数で調整した。   In any case, the helical wrinkle was applied using a wrinkle device (a wrinkle device described in Japanese Patent Publication No. 63-63293, etc.) that rotates using the supplied strand as an axis. The comb shape was adjusted by the spacing of the tacking pins, the dimension of the tacking pins, and the number of rotations rotating around the element wire.

また、螺旋状のくせを略二次元波状のくせに加工する押圧加工および、撚り線加工後の押圧加工は、複数個の自由回転するローラーを千鳥状に配置した周知の押圧加工装置で行った。ただし、押圧加工の手段はこれに限られるものではない。   In addition, the pressing process for processing the helical wrinkle into a substantially two-dimensional waved wrinkle and the pressing process after the stranded wire processing were performed by a known press processing device in which a plurality of freely rotating rollers were arranged in a staggered manner. . However, the pressing means is not limited to this.

こうして製造した実施例のコードのゴム侵入性、低荷重伸びおよび撚り構造の安定性を従来例のコードと比較して評価した。   The rubber penetration, low load elongation and stability of the twisted structure of the cords of the examples manufactured in this way were evaluated in comparison with the cords of the conventional examples.

ゴム侵入性は、各コードを2kgの引張荷重をかけた状態でゴム材中に埋め込み、加圧加硫した後コードを取り出し、そのコードを分解して一定長さを観察し、観察した長さに対するゴムと接触した形跡のある長さの比をパーセント表示して評価した。   For rubber penetration, each cord is embedded in a rubber material under a tensile load of 2 kg, and after pressure vulcanization, the cord is taken out, the cord is disassembled and a certain length is observed, and the observed length The ratio of the length of traces in contact with rubber to the percentage was evaluated as a percentage.

低荷重伸びは、5kg荷重負荷時の伸びをパーセント表示して評価した。   The low load elongation was evaluated by expressing the elongation at the time of 5 kg load as a percentage.

また、撚り構造の安定性は、図5に示すように、コードCの半径とほぼ同等の深さの断面半円形の溝を設けた1対の挟み具31,32を上下に合わせてコードCを挟み、上側の挟み具31の上に錘33を載せて、その状態でコードCを一方向(矢印の方向)に連続的に引き抜いたときに、コードCの側素線が余って挟み具31,32の溝の入口側に素線がたまっていく量(余り量)がどれくらいあるかで評価した。余り量が無ければ、各層の素線群間同士が密接していることを意味する。   Further, as shown in FIG. 5, the stability of the twisted structure is such that a pair of sandwiching tools 31 and 32 provided with semicircular grooves having a depth substantially equal to the radius of the cord C are aligned vertically. When the cord 33 is placed on the upper pinching tool 31 and the cord C is continuously pulled out in one direction (in the direction of the arrow), the side wire of the cord C is excessively pinched. Evaluation was made as to how much amount (extra amount) the strands accumulated on the entrance sides of the grooves 31 and 32. If there is no excess amount, it means that the wire groups of each layer are in close contact with each other.

従来例は、直径5.5mmのスチール線材を、パテンティングおよび伸線加工を繰り返した後、表面にプラスメッキを施して、線径0.25mmの素線とし、この素線を用いて、従来の1+5+11のクローズド構造のコード、1+5+11のオープン構造のコード、1+5+11で螺旋状のくせを有する素線を中間層に配置したコード、1×16のオープン構造のコード、1×16のクローズド構造のコード、1×16で螺旋状のくせを有する素線を中間層に配置したコードの6種類のコードを製造した。螺旋状のくせを設ける素線の数は、1+5+11構造のコード、1×16構造のコード共に、中間層に位置する5本の素線のうちの3本とした。   In a conventional example, a steel wire having a diameter of 5.5 mm is subjected to patenting and wire drawing, and then subjected to plus plating on the surface to obtain a strand having a wire diameter of 0.25 mm. 1 + 5 + 11 closed structure cord, 1 + 5 + 11 open structure cord, 1 + 5 + 11 cord with a spiral wrinkle arranged in the middle layer, 1 × 16 open structure cord, 1 × 16 closed structure cord Six types of cords were manufactured, in which 1 × 16 strands having a helical wrinkle were arranged in the intermediate layer. The number of strands on which the spiral combs are provided is three of the five strands located in the intermediate layer for both the 1 + 5 + 11 structure cord and the 1 × 16 cord.

評価の結果を表1に示す。

Figure 2008255497
表1から、実施例のコードは全ての評価で従来コードより優れていることが明らかである。 The evaluation results are shown in Table 1.
Figure 2008255497
From Table 1, it is clear that the code of the example is superior to the conventional code in all evaluations.

本発明の実施形態の1+5+11の3層撚り構造のスチールコードの断面図である。It is sectional drawing of the steel cord of the 1 + 5 + 11 3 layer twist structure of embodiment of this invention. 本発明の実施形態の1×16の束撚り3層構造のスチールコードの断面図である。It is sectional drawing of the steel cord of 1 * 16 bundle twist 3 layer structure of embodiment of this invention. 本発明の実施形態における略正弦波状のくせのピッチおよび波高の説明図である。It is explanatory drawing of the pitch and wave height of the substantially sinusoidal habit in embodiment of this invention. 本発明の実施形態における中間素線群の撚り構造の説明図である。It is explanatory drawing of the twist structure of the intermediate | middle strand group in embodiment of this invention. 実施例のスチールコードの撚り構造の安定性を評価する方法の説明図である。It is explanatory drawing of the method of evaluating the stability of the twist structure of the steel cord of an Example. 従来の1+6+12の3層オープン撚り構造のスチールコードの断面図である。It is sectional drawing of the steel cord of the conventional 1 + 6 + 12 3 layer open twist structure. 従来の1×24の束撚り構造で中間層の一部の素線が撚り合わせのためのくせとは異なる螺旋状のくせを有しているスチールコードの断面図である。FIG. 6 is a cross-sectional view of a steel cord having a conventional 1 × 24 bundle-twisted structure in which some strands of an intermediate layer have a spiral bend different from the bend for twisting. 従来の1×24の束撚り構造で中間層の全ての素線が撚り合わせのためのくせとは異なる螺旋状のくせを有しているコードの断面図である。It is sectional drawing of the code | cord | chord which has the helical habit different from the habit for twisting all the strands of the intermediate | middle layer by the conventional 1x24 bundle twist structure.

符号の説明Explanation of symbols

10、20 コード(スチールコード)
11、21 芯素線
12、22 中間素線
13、23 側素線
14、24 隙間
10, 20 cord (steel cord)
11, 21 Core strands 12, 22 Intermediate strands 13, 23 Side strands 14, 24 Gap

Claims (7)

L+M+N(L=1〜4、M=4〜9、N=8〜15)の3層撚り構造、または1×P(P=13〜27)の束撚り3層構造のスチールコードであって、外層を構成する素線群の少なくとも一部の素線同士の間に隙間が存在するとともに、中間層を構成する素線群の全ての素線が、撚り合わせのためのくせとは別に撚り合わせのためのくせよりピッチの小さいくせを有し、かつ、コード長手方向の略全ての箇所において、前記中間層を構成する素線群の少なくともいずれか1本の素線が、中心層を構成する素線群の少なくともいずれか1本の素線に接触していることを特徴とするゴム製品補強用スチールコード。 A steel cord of L + M + N (L = 1 to 4, M = 4 to 9, N = 8 to 15) or a three-layer twist structure of 1 × P (P = 13 to 27), There is a gap between at least some of the strands of the strands that make up the outer layer, and all strands of the strands that make up the intermediate layer are twisted separately from the twist for twisting And at least one strand of the strand group constituting the intermediate layer constitutes the central layer at almost all locations in the longitudinal direction of the cord. A steel cord for reinforcing rubber products, wherein the steel cord is in contact with at least one of the strands. L+M+N(L=1〜4、M=4〜9、N=8〜15)の3層撚り構造、または1×P(P=13〜27)の束撚り3層構造のスチールコードであって、外層を構成する素線群の少なくとも一部の素線同士の間に隙間が存在するとともに、中間層を構成する素線群の全ての素線が、撚り合わせのためのくせとは別に撚り合わせのためのくせよりピッチの小さいくせを有し、かつ、前記中間層を構成する素線群の素線同士がコード中心軸に略平行となるよう略パラレルに接触して該中間層を構成する素線群の素線の撚り角と外層を構成する素線群の素線の撚り角との差が大きくなる箇所が、コード長手方向に不連続な配置で部分的に存在することを特徴とするゴム製品補強用スチールコード。 A steel cord of L + M + N (L = 1 to 4, M = 4 to 9, N = 8 to 15) or a three-layer twist structure of 1 × P (P = 13 to 27), A gap exists between at least some of the strands of the strands that make up the outer layer, and all strands of the strands that make up the intermediate layer are twisted separately from the twist for twisting The intermediate layer is formed by contacting the wires in the group of wires constituting the intermediate layer substantially in parallel with each other so as to be substantially parallel to the cord central axis. The location where the difference between the strand angle of the strands of the strand group and the strand angle of the strands of the strand group constituting the outer layer is partially present in a discontinuous arrangement in the cord longitudinal direction Steel cord for reinforcing rubber products. L+M+N(L=1〜4、M=4〜9、N=8〜15)の3層撚り構造、または1×P(P=13〜27)の束撚り3層構造のスチールコードであって、外層を構成する素線群の少なくとも一部の素線同士の間に隙間が存在するとともに、中間層を構成する素線群の全ての素線が、撚り合わせのためのくせとは別に撚り合わせのためのくせよりピッチの小さいくせを有し、かつ、コード長手方向の略全ての箇所において、前記中間層を構成する素線群の少なくともいずれか1本の素線が、中心層を構成する素線群の少なくともいずれか1本の素線に接触しているとともに、前記中間層を構成する素線群の素線同士がコード中心軸に略平行となるよう略パラレルに接触して該中間層を構成する素線群の素線の撚り角と外層を構成する素線群の素線の撚り角との差が大きくなる箇所が、コード長手方向に不連続な配置で部分的に存在することを特徴とするゴム製品補強用スチールコード。 A steel cord of L + M + N (L = 1 to 4, M = 4 to 9, N = 8 to 15) or a three-layer twist structure of 1 × P (P = 13 to 27), There is a gap between at least some of the strands of the strands that make up the outer layer, and all strands of the strands that make up the intermediate layer are twisted separately from the twist for twisting And at least one strand of the strand group constituting the intermediate layer constitutes the central layer at almost all locations in the longitudinal direction of the cord. While contacting at least one of the strands of the strand group, the strands of the strand group constituting the intermediate layer are substantially parallel to each other so that the strands are substantially parallel to the cord center axis. Strand angle of the strands constituting the layer and the strands of the strands constituting the outer layer Rubber products reinforcing steel cord for the difference between the twist angle is larger portion, characterized in that the partially present in discrete located in code longitudinal. 前記撚り合わせのためのくせよりピッチの小さいくせは、素線に螺旋状のくせを付けた後押圧加工したことより得られたくせである請求項1、2または3記載のゴム製品補強用スチールコード。 The steel cord for reinforcing a rubber product according to claim 1, 2 or 3, wherein the habit having a smaller pitch than the habit for twisting is a habit obtained by pressing a strand after forming a helical habit on the strands. . 前記撚り合わせのためのくせよりピッチの小さいくせは、ピッチP1が、P1=0.2Pc〜0.5Pc(但し、Pcは撚り合わせのピッチ)で、波高hが、h=0.2d〜1.2d(但し、dは素線径)である請求項1、2、3または4記載のゴム製品補強用スチールコード。 The pitch smaller than the twist for twisting is such that the pitch P1 is P1 = 0.2 Pc to 0.5 Pc (where Pc is the twisting pitch), and the wave height h is h = 0.2 d to 1. The steel cord for reinforcing rubber products according to claim 1, 2 or 3, wherein d is 2d (where d is a wire diameter). L+M+N(L=1〜4本、M=4〜9、N=8〜15)の3層撚り構造のスチールコードの製造方法であって、L本の素線を撚り合わせて中心層を構成する素線群とし、該中心層を構成する素線群の上に、螺旋状のくせを付けた後押圧加工して得られた略二次元波状で撚り合わせのためのくせよりピッチの小さいくせを有するM本の素線を撚り合わせて中間層を構成する素線群とし、該中間層を構成する素線群の上に少なくとも一部の素線同士の間に隙間が存在するようN本の素線を撚り合わせて外層を構成する素線群とし、こうして形成した3層撚り構造のスチールコードにコード長手方向に直交する方向から押圧加工を施すことを特徴とするゴム製品補強用スチールコードの製造方法。 L + M + N (L = 1-4, M = 4-9, N = 8-15) manufacturing method of a steel cord having a three-layer twisted structure, in which a core layer is formed by twisting L strands A strand group is formed, and on the strand group constituting the center layer, a helical pitch is applied, and then a substantially two-dimensional wave shape obtained by pressing, and a pitch having a smaller pitch than the twist for twisting. The strands of the M wires are twisted together to form a strand group that constitutes the intermediate layer, and N strands are formed so that a gap exists between at least some strands on the strand group that constitutes the intermediate layer. A steel cord for reinforcing rubber products, characterized in that strands are twisted to form a strand constituting an outer layer, and the steel cord having the three-layer twist structure thus formed is pressed from a direction perpendicular to the longitudinal direction of the cord. Production method. 1×P(P=13〜27)の束撚り3層構造のスチールコードの製造方法であって、中間層を構成する素線群の全ての素線を、螺旋状のくせを付けた後押圧加工して得られた略二次元波状で撚り合わせのためのくせよりピッチの小さいくせを有するものとし、該略二次元波状のくせを有する素線からなる中間層の素線群と中心層の素線群と外層の素線群の各素線を同一方向および同一ピッチで一度に撚り合わせて前記外層の少なくとも一部の素線同士の間に隙間が存在する束撚り3層構造のスチールコードを形成し、該スチールコードにコード長手方向に直交する方向から押圧加工を施すことを特徴とするゴム製品補強用スチールコードの製造方法。 1 × P (P = 13 to 27) of a method of manufacturing a steel cord having a three-layer structure of bundle twist, and pressing all the strands of the strand group constituting the intermediate layer after forming a helical habit It is a substantially two-dimensional wave obtained by processing and has a smaller pitch than the twist for twisting. A steel cord having a bundle-twisted three-layer structure in which the strands of the strand group and the strands of the outer layer are twisted at the same time in the same direction and at the same pitch, and a gap exists between at least some of the strands of the outer layer A method of manufacturing a steel cord for reinforcing rubber products, characterized in that the steel cord is pressed from a direction orthogonal to the longitudinal direction of the cord.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103485216A (en) * 2013-08-30 2014-01-01 江苏兴达钢帘线股份有限公司 Three-layer steel cord with 4+10+16 structure

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103485216A (en) * 2013-08-30 2014-01-01 江苏兴达钢帘线股份有限公司 Three-layer steel cord with 4+10+16 structure

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