JP2008143829A - Kit for hair-treating agent - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a kit for use in hair-treating agents, easily mixing each of agents uniformly even a second agent is in a liquid state, also having an optimal viscosity after the mixing for preventing the dripping down from the hair, excellent in extension property on the hair and further capable of reducing an irritating smell of such as an alkaline agent, etc. <P>SOLUTION: This kit for the hair-treating agents for use in hair-bleaching or oxidative hair-dyeing, and containing a first agent containing an alkaline agent and a second agent containing an oxidant comprises (A) dialkyl phosphate, (B) a nonionic surfactant, and (C) a polyhydric alcohol. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a hair treatment kit for hair bleaching or oxidative hair coloring, which contains a first agent and a liquid second agent. More specifically, each agent is easy to mix, and after mixing, it has an optimal viscosity to prevent dripping from the hair, and also has excellent extensibility on the hair, reducing irritating odors The present invention relates to a kit for treating hair.

  In the case of multi-component depigmenting agents or hair dyes such as two-component, three-component, etc., it improves the storage stability of each agent and is easy to apply to hair (prevents dripping) on the hair From the standpoint of spreadability (uniform coating), it is most important to set the viscosity at the time of use to an optimum viscosity. It is also important to reduce irritating odors derived from raw materials such as alkaline agents during use.

  Conventionally, an attempt to add a thickening compound has been made as a means for making the viscosity in use optimum. For example, in patent document 1, viscosity stability is improved by mix | blending xanthan gum. In Patent Document 2, viscosity is imparted by adjusting pH by mixing a first agent and a second agent using a carboxyvinyl polymer whose viscosity depends on pH. In patent document 3, the viscosity is provided by mix | blending the thickening copolymer thickened by addition of an alkaline substance with the 2nd agent, and mixing with the 1st agent containing an alkaline substance. In patent document 4, favorable viscosity stability is obtained by mix | blending hydroxypropyl starch acid and an aqueous thickener.

Moreover, the mixing | blending of a specific oil agent is proposed as a means to reduce irritating odors, such as an alkaline agent. For example, in Patent Document 5, an irritating odor is reduced by blending isoparaffin, a nonionic surfactant, and a polymer compound. In patent document 6, the irritating odor is reduced by mix | blending the oil agent which uses triglyceride as a structural component, a higher alcohol, and ester type nonionic surfactant. In Patent Document 7, the irritating odor is reduced by blending a higher alcohol having 20 to 25 carbon atoms, a higher alcohol having 10 to 19 carbon atoms and a surfactant.
JP-A-9-67235 JP-A-11-286421 JP 11-349454 A JP-A-2005-336126 JP 2003-221319 A JP 2003-73243 A JP 2004-189638 A

  However, although it is possible to reduce the irritating odor and the optimum viscosity at the time of use based on these attempts, in the case where the second agent is liquid, the properties, viscosity and specific gravity of the first agent and the second agent are Because of the great difference, both the two agents cannot be easily mixed uniformly, making it difficult to achieve an optimal viscosity during use, and it is difficult to exert the effect of reducing irritating odors. . Moreover, since the viscosity stability after mixing is inferior, there are also problems such as dripping from the hair during use and poor spreadability on the hair.

  As a result of intensive studies to solve the above problems, the present inventors have found that the multi-agent hair treatment agent kit contains dialkyl phosphate, so that each agent can be used even if the second agent is liquid. It becomes easy to mix evenly, and after mixing, it has optimal viscosity, prevents dripping from the hair and has excellent spreadability on the hair, and further reduces irritating odors such as alkaline agents And the present invention has been completed.

  That is, this invention is a kit for hair treatment agents containing the 1st agent containing an alkaline agent and the liquid 2nd agent containing an oxidizing agent, Comprising: (A) Dialkyl phosphate, (B) Nonionic The present invention relates to a kit for a hair treatment agent for hair bleaching or oxidative hair dyeing comprising an ionic surfactant and (C) a polyhydric alcohol.

  The kit for hair treatment agent of the present invention can easily mix each agent evenly in the applicator at the time of use even when the second agent is liquid, and can achieve an optimum viscosity at the time of mixing. At the same time, it has an excellent effect on viscosity stability after mixing. Moreover, since it is excellent in the spreadability on hair by preventing the dripping from hair by setting it as the optimal viscosity, decoloring property and dyeing | staining property can be improved. Furthermore, the outstanding effect that the pungent odor derived from raw materials, such as an alkaline agent, can be reduced is also show | played.

  The kit for hair treatment agent of the present invention is a kit comprising a first agent containing an alkaline agent and a liquid second agent containing an oxidizing agent, wherein (A) a dialkyl phosphate and (B) a non-ion. It has a great feature in containing a functional surfactant and (C) a polyhydric alcohol. Usually, when agents having different properties are mixed, a large amount of labor is required for uniform mixing. However, in the present invention, the first agent and the liquid second agent can be easily mixed by containing the dialkyl phosphate component, and further, by containing the nonionic surfactant component, It was found that the quality after mixing can be maintained well. In this specification, the liquid state means that the viscosity measured with a B-type viscometer (25 ° C., No. 3, rotor, 30 r / min) is 2,000 mpa · s or less.

  (A) As dialkyl phosphate, the formula (I):

(Wherein R ¹ and R ² each independently represents a saturated or unsaturated linear alkyl group having 12 to 22 carbon atoms)
The compound represented by these is mentioned. These components can be used individually or in combination of 2 or more types as appropriate.

In the present invention, among the compounds represented by the formula (I), it is preferable to use a dialkyl phosphate in which R ¹ and R ² are a saturated or unsaturated linear alkyl group having 14 to 18 carbon atoms. ^It is more preferable to use dicetyl phosphate in which ¹ and R ² are saturated alkyl groups having 16 carbon atoms.

As a commercial item of the compound represented by the formula (I), for example, “DP-10” (dicetyl phosphate, manufactured by Nikko Chemicals Co., Ltd.) in which R ¹ and R ² are a saturated alkyl group having 16 carbon atoms may be mentioned. .

  The content of the component (A) is not particularly limited as long as a desired effect is imparted, but usually the mixing of each agent is facilitated, and the viewpoint of obtaining an optimum viscosity, suppressing dripping from the hair, From the viewpoint of improving spreadability and reducing the irritating odor derived from raw materials such as alkaline agents, 0.01 to 4% by weight is preferable and 0.1 to 2% by weight is more preferable in the kit for hair treatment agent. .

  (B) The nonionic surfactant is not particularly limited, and examples thereof include polyoxyalkylene alkyl ether, glycerin fatty acid ester, polyalkylene glycol fatty acid ester, sorbitan fatty acid ester, ethylene oxide condensate of sorbitan fatty acid ester, and the like. , Polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene lanolin and the like.

  Examples of the polyoxyalkylene alkyl ether include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxypropylene cetyl ether, Examples thereof include oxypropylene isocetyl ether, polyoxypropylene stearyl ether, and polyoxypropylene oleyl ether.

  Examples of glyceryl fatty acid esters include glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, and glyceryl monooleate. Monoglyceryl fatty acid esters such as glyceryl monoerucate; diglyceryl monocaprylate, decaglyceryl monocaprylate, hexaglyceryl monocaprate, tetraglyceryl monolaurate, hexaglyceryl monolaurate, decaglyceryl monolaurate, poly (4- 10) Glyceryl, decaglyceryl monomyristate, decaglyceryl monostearate, poly (2-10) monostearate Riseriru, monooleate diglyceryl monooleate hexaglyceryl, monobehenate decaglyceryl include polyglycerol fatty acid esters such as Monoeruka decaglyceryl.

  Examples of polyalkylene glycol fatty acid esters include polyethylene glycol monoesters such as polyethylene glycol monooleate, polyethylene glycol monostearate, and polyethylene glycol monolaurate, propylene glycol monostearate, propylene glycol monolaurate, propylene glycol monooleate, and the like. Is mentioned.

  Examples of the ethylene oxide condensate of sorbitan fatty acid ester and sorbitan fatty acid ester include sorbitan trioleate, sorbitan monooleate, sorbitan monostearate, sorbitan monopalmitate, sorbitan monolaurate, polyoxyethylene sorbitan monooleate, mono Examples thereof include polyoxyethylene sorbitan stearate, polyoxyethylene sorbitan monolaurate, and polyoxyethylene sorbitan trioleate.

  The said component can be used individually or in combination of 2 or more types as appropriate.

  The content of the component (B) is not particularly limited as long as the desired effect is imparted, but usually, from the viewpoint of imparting optimum viscosity and viscosity stability after mixing, in the hair treatment agent kit, 0.1 to 5 weight% is preferable and 0.5 to 4 weight% is more preferable.

  (C) Examples of the polyhydric alcohol include glycols and glycerins. Glycols include ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, 1,3-butylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexane. Examples include diol, 1,2-octanediol, and 1,2-decanediol. Examples of glycerin include glycerin, diglycerin, polyglycerin, and concentrated glycerin. These components can be used alone or in combination of two or more.

  Although content of (C) component will not be specifically limited if a desired effect is provided, Usually, 0.1-8 in the kit for hair treatment agents from a viewpoint of improving the viscosity stability after mixing. % By weight is preferable, and 1 to 6% by weight is more preferable.

  The component (A), the component (B), and the component (C) are independently contained in the first agent and the second agent, but the first agent and the liquid second agent are easily uniform. From the viewpoint of mixing and obtaining an optimum viscosity, the first agent preferably contains all the components (A) to (C).

  In addition, in the kit for hair treatment agent of the present invention, in addition to the components (A) to (C), in addition to the components (A) to (C), (D) from the viewpoint of achieving an optimum viscosity, suppressing dripping from the hair, and improving spreadability. It is preferable to contain a water-soluble polysaccharide.

  Examples of (D) water-soluble polysaccharides include seed mucilage, sap mucilage, production mucilage, and cellulosic components.

  Examples of seed mucilage include guar gum, quince seed, konjac mannan, tamarind gum, tara gum, dextrin, starch, locust bean gum and the like. Examples of the sap mucilage include gum arabic, gati gum, karaya gum, and tongan cant gum.

  Examples of the product mucilage include curdlan, xanthan gum, gellan gum, cyclodextrin, dextran, pullulan and the like. Examples of the cellulose component include crystalline cellulose, methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, carboxymethyl cellulose, and cationized cellulose.

  The above compounds can be used alone or in combination of two or more, but among these, xanthan gum is preferred in the present invention. Further, derivatives of xanthan gum are also preferable, and specific examples include acetylated xanthan gum and oxyalkylenated xanthan gum (such as hydroxypropyl xanthan gum).

  The content of the component (D) is not particularly limited as long as a desired effect is imparted, but usually 0.01 to 2% by weight in the hair treatment kit from the viewpoint of obtaining an optimum viscosity at the time of mixing. Is preferable, and 0.05 to 1 weight% is more preferable.

  The component (D) may be contained in the first agent and / or the second agent, but is preferably contained in the first agent from the viewpoint of obtaining an optimum viscosity at the time of mixing.

  Examples of the alkaline agent in the first agent include ammonia, monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, 2-amino-2-methyl-1-propanol, ammonium carbonate, ammonium bicarbonate, sodium carbonate and the like. These can be used alone or in appropriate combination of two or more.

  The content of the alkali agent in the first agent is not particularly limited as long as a desired effect is imparted, but is usually preferably 0.1 to 15% by weight from the viewpoint of improving the decolorization / hair dyeing effect, and 0 More preferably, it is 5 to 10% by weight.

  The first agent may contain an oxidative dye. Examples of the oxidative dye include a dye intermediate and a coupler, and these can be used alone or in combination of two or more.

  Representative examples of the dye intermediate include phenylenediamines, aminophenols, diaminopyridines and salts thereof, and specific examples thereof include paraphenylenediamine, N, N-bis (2-hydroxyethyl). -P-phenylenediamine, orthochloroparaphenylenediamine sulfate, 4,4'-diaminodiphenylamine sulfate, toluene-2,5-diamine sulfate, paramethylaminophenol sulfate, paraaminophenol, orthoaminophenol and the like. These may be used alone or in appropriate combination of two or more.

  Specific examples of couplers include resorcin, metaaminophenol, 2,6-diaminopyridine, metaphenylenediamine, metaphenylenediamine sulfate, metaphenylenediamine hydrochloride, 5-aminoorthocresol, 2,4-diaminophenoxyethanol hydrochloride, 5- (2-Hydroxyethylamino) -2-methylphenol, β-naphthol, catechol and the like can be mentioned, and these can be used alone or in combination of two or more.

  Further, in order to adjust the color tone, the first agent can further contain a dye directly. Specific examples of direct dyes include paranitroorthophenylenediamine, nitroparaphenylenediamine, paranitrometaphenylenediamine sulfate, 2-amino-5-nitrophenol, and picramic acid, as well as pharmaceuticals, quasi drugs, and cosmetics. Acid dyes described in “Ministerial Ordinance for Determining Tar Colors that can be Used for Pharmaceuticals” (Ministry of Health and Welfare, Showa 41) permitted to be used for coloring, for example, yellow 403 (1), etc. Nitro-based dyes, azo dyes such as orange No. 205, yellow No. 4 and black No. 401, nitroso dyes such as green No. 401, triphenylmethane dyes such as blue No. 205, red No. 106 and yellow No. 202 (1 ), Xanthene dyes such as yellow No. 203, quinoline dyes such as yellow No. 203, anthrax such as purple No. 401 and green No. 201 Non dyes, indigo dyes, such as Blue No. 2, pyrene tar dyes such as green No. 204, and these may be used alone or in combination of two or more appropriately.

  In the present invention, for example, basic dyes such as Basic Blue 99, Basic Yellow 57, Basic Brown 16, Basic Brown 17, Basic Red 76, and HC Blue No. 2, HC Yellow No. 2, HC Yellow No. 4, HC Yellow No. 4 5, HC Red No. 5 1, HC Red No. 1 3, HC Orange No. HC dyes such as 1 and disperse dyes such as DISPERSE BLACK 9, DISPERSE VIOLET 1 can be appropriately blended with the first agent within the range in which the object of the present invention is not inhibited.

  It is preferable to adjust the kind of each dye and the blending ratio thereof so that the first agent has a desired color. The content of the oxidation dye in the first agent is preferably 0.001 to 10% by weight, more preferably 0.01 to 5% by weight, from the viewpoint of expressing a sufficient hair dyeing effect.

  Examples of the oxidizing agent in the second agent include hydrogen peroxide, urea peroxide, persulfate, perborate, percarbonate, bromate, periodate, and the like. Two or more kinds can be used in appropriate combination.

  The content of the oxidizing agent in the second agent is preferably 0.1 to 20% by weight, more preferably 1 to 16% by weight, from the viewpoint of obtaining sufficient oxidizing power.

  As long as the effects of the present invention are not impaired, the first agent and the second agent include oily components, surfactants other than nonionic surfactants, lower alcohols, higher alcohols, metal sequestering agents. , PH adjusters, animal and plant extracts, and the like can be appropriately blended. In each agent, the components (A) to (D) and the remainder of the components are water such as purified water.

  A conventionally well-known method is mentioned as a manufacturing method of a 1st agent and a 2nd agent. For example, the oil phase containing the component (A) dissolved by heating is mixed and stirred in the same manner as the aqueous phase containing the components (B) and (C) heated, and emulsified. After emulsification, the first agent can be produced by cooling and adding an alkali agent. The second agent can be produced by mixing and stirring an oxidizing agent and other components in the aqueous phase.

  The weight ratio of the first agent to the second agent (first agent / second agent) is preferably 3/1 to 1/4, more preferably 2/1 to 1/3, from the viewpoint of easy mixing. It is adjusted to become.

  The hair treatment kit of the present invention can be easily and uniformly mixed by simply adding the first agent into the applicator filled with the second agent, sealing and shaking at the time of use. it can. Therefore, the kit for a hair treatment agent of the present invention is a three-component hair treatment agent used by mixing the first agent and the second agent as they are, or mixed with a third agent such as persulfate. It can be used as a formula hair treatment agent.

Examples 1-4 and Comparative Examples 1-6
The 1st agent and 2nd agent of the composition shown in Table 1 or Table 2 were manufactured by the following method, and each kit for hair treatment agents of Examples 1-4 and Comparative Examples 1-6 was obtained.

<First agent production method>
When the oil phase is heated to 80 ° C. and sufficiently dissolved, the water phase similarly heated to 80 ° C. is gradually added. The mixture is stirred with a homomixer at 3000 r / min for 10 minutes to emulsify. After emulsification, it is cooled to 35 ° C. and an alkali agent is added. After the addition, stir sufficiently uniformly.

<Second agent production method>
Add the oxidizer to the water phase and stir it thoroughly.

  Next, the following test examples 1-4 were evaluated about the obtained kit for hair treatment agents. The results are shown in Tables 1 and 2.

Test Example 1 (Ease of mixing)
The training was conducted by 20 specialist panels. About the kit for hair treatment agents of each Example and each comparative example, the 1st agent and the 2nd agent were shaken and mixed in the applicator by the ratio (weight ratio) of 1: 2, and the hair treatment agent was prepared. The ease of mixing at that time was evaluated, and the ease of mixing was evaluated according to the following evaluation criteria.

[Evaluation criteria for ease of mixing]
◎: Reply when 16 or more of 20 people mix easily and uniformly ○: Reply when 11-15 of 20 people mix easily and even △: Reply if 6-10 of 20 people mix easily and uniformly ×: Answers that 5 or less of 20 people can easily mix evenly

Test example 2 (optimum viscosity during mixing)
The training was conducted by 20 specialist panels. About 2 g of each hair treatment agent prepared in Test Example 1 was applied to a test hair bundle (length 10 cm, weight 1 g) which was left overnight at 23 ° C. and a humidity of 60%. Evaluation was performed according to the following evaluation criteria.

[Evaluation criteria for dripping]
◎: 16 or more of 20 people answered that there was no dripping from the hair bundle ○: 11-15 of 20 people answered that there was no dripping from the hair bundle Δ: 6-10 of 20 people answered Answer that there is no dripping from the hair bundle ×: 5 or less of 20 people answered that there is no dripping from the hair bundle

[Evaluation criteria for extensibility]
◎: More than 16 out of 20 responded that extensibility on hair was excellent ○: 11-15 out of 20 responded that extensibility on hair was excellent Δ: 6-10 out of 20 responded to hair Answer that extensibility on the top is excellent ×: 5 or less of 20 responded that extensibility on the hair is excellent

Test Example 3 (Viscosity stability)
For each hair treatment agent obtained in Test Example 1, by shaking the applicator, the viscosity immediately after mixing and the viscosity after standing for 1 hour at room temperature are compared, and the variation in viscosity is evaluated according to the following evaluation criteria. did.

[Viscosity stability evaluation criteria]
◎: No change in viscosity immediately after mixing ○: Slight increase or decrease in viscosity is observed compared to immediately after mixing Δ: Clear increase or decrease in viscosity is observed compared to immediately after mixing ×: Significant increase in viscosity compared to immediately after mixing Or a decline is observed

Test Example 4 (Suppression of irritating odor and evaluation of decolorization / dyeability)
The training was conducted by 20 specialist panels. The hair bundle to which each hair treatment agent was applied in Test Example 2 was allowed to stand at 30 ° C. for 30 minutes after application, then washed with tap water, and the hair bundle was dried using a dryer. The pungent odor during the treatment and the decolorization / hair dyeing property of the hair bundle after drying were evaluated according to the following evaluation criteria.

[Evaluation criteria for pungent odors]
◎: 16 or more of 20 respondents do not feel any irritating odor such as alkaline agent ○: 11-15 of 20 respondents do not feel any irritating odor such as alkaline agent Δ: 6 to 20 of 20 respondents 10 respondents who do not feel any irritating odors such as alkaline agents x: 5 or less of 20 respondents who do not feel any irritating odors such as alkaline agents

[Evaluation criteria for decolorization / dyeability]
◎: More than 16 out of 20 people answered that the hair bundles were uniformly decolored and dyed ○: 11 to 15 out of 20 people were uniformly decolored and dyed without uneven hair bundles Answer △: 6 to 10 out of 20 hair bundles have no unevenness and are uniformly decolored and dyed x: 5 out of 20 people have uniform hair colors and are uniformly decolored and dyed Answer

  From the above results, it can be seen that the hair treatment agent kits of the examples are excellent in all characteristics such as ease of mixing and dripping. On the other hand, Comparative Examples 1 and 4 are excellent in ease of mixing, decolorization, and hair dyeing due to the effect of dicetyl phosphate, but since they do not contain the component (B), the components after mixing can be maintained uniformly. It cannot be done and is considered to be inferior to dripping or viscosity stability. Comparative Examples 2 and 5 are obtained by removing only the component (A) from Examples 2 and 4, respectively. However, since they do not contain the component (A), they are inferior in ease of mixing and the physical properties thereafter are also poor. Moreover, although Comparative Examples 3 and 6 were able to forcibly impart viscosity with a nonionic surfactant or the like and suppress dripping from the hair, they were excellent in other evaluations including ease of mixing. The effect could not be obtained. From this, it is suggested that by containing the component (A) and the component (B), the first agent and the liquid second agent can be easily mixed and the quality after mixing can be maintained well. It was done.

  Hereinafter, Formulation Examples 1 to 4 of the kit for hair treatment agent of the present invention are shown. The content is% by weight.

(Formulation Example 1: Two-component hair dye)
(First agent: cream)
Paraphenylenediamine 0.15
Resorcinol 0.1
Metaaminophenol 0.05
Dicetyl phosphate 1.0
Polyoxyethylene cetyl ether (40E.O.) 1.0
Polyoxyethylene cetyl ether (20E.O.) 1.0
Cetyl alcohol 5.0
Dipropylene glycol 7.0
Xanthan gum 0.2
Glutamic acid 0.3
Arginine 0.3
Proline 0.3
Methylpolysiloxane 2.0
Perfume appropriate amount Ammonia water (28%) 5.0
Monoethanolamine 2.0
Ammonium carbonate 0.5
Purified water balance
Total 100.0
(Second agent: liquid)
Hydrogen peroxide (35%) 16.0
Dicetyl phosphate 0.5
Cetyl alcohol 0.5
Hydroxyethanediphosphonic acid 0.5
Tetrasodium pyrophosphate 0.5
Purified water balance
Total 100.0

(Prescription Example 2: Two-component hair dye)
(First agent: cream)
Paraphenylenediamine 0.15
Resorcinol 0.1
Metaaminophenol 0.05
Dicetyl phosphate 1.0
Polyoxyethylene cetyl ether (40E.O.) 3.0
Stearyl alcohol 7.0
Dipropylene glycol 3.0
Concentrated glycerin 3.0
Xanthan gum 0.5
Glutamic acid 0.3
Arginine 0.3
Methylphenylpolysiloxane 1.0
Perfume appropriate amount Ammonia water (28%) 5.0
Monoethanolamine 2.0
Ammonium carbonate 0.5
Purified water balance
Total 100.0
(Second agent: liquid)
Hydrogen peroxide (35%) 16.0
Hydroxyethanediphosphonic acid 0.5
Tetrasodium pyrophosphate 0.5
Purified water balance
Total 100.0

(Prescription Example 3: Two-component hair dye)
(First agent: cream)
Paraphenylenediamine 0.15
Resorcinol 0.1
Metaaminophenol 0.05
Dicetyl phosphate 2.0
Polyoxyethylene cetyl ether (20E.O.) 1.5
Cetyl alcohol 3.0
Stearyl alcohol 2.0
Concentrated glycerin 10.0
Xanthan gum 0.15
Glutamic acid 0.3
Proline 0.3
Amino-modified silicone 0.5
Perfume appropriate amount Ammonia water (28%) 5.0
Monoethanolamine 2.0
Ammonium carbonate 0.5
Purified water balance
Total 100.0
(Second agent: liquid)
Hydrogen peroxide (35%) 16.0
Polyoxyethylene lauryl ether 0.5
Cetyl alcohol 0.5
Hydroxyethanediphosphonic acid 0.5
Tetrasodium pyrophosphate 0.5
Purified water balance
Total 100.0

(Prescription Example 4: Three-part bleaching agent)
(First agent: cream)
Dicetyl phosphate 0.5
Polyoxyethylene cetyl ether (40E.O.) 0.3
Polyoxyethylene cetyl ether (20E.O.) 2.0
Cetyl alcohol 4.0
Stearyl alcohol 4.0
Dipropylene glycol 4.0
Concentrated glycerin 3.0
Xanthan gum 0.3
Glutamic acid 0.3
Methylphenylpolysiloxane 1.0
Amino-modified silicone 1.0
Perfume appropriate amount Ammonia water (28%) 5.0
Monoethanolamine 2.0
Ammonium carbonate 0.5
Purified water balance
Total 100.0
(Second agent: liquid)
Hydrogen peroxide (35%) 16.0
Hydroxyethanediphosphonic acid 0.5
Tetrasodium pyrophosphate 0.5
Purified water balance
Total 100.0
(Third agent: powder)
Potassium persulfate 25.0
Ammonium persulfate 20.0
Sodium metasilicate 20.0
Magnesium stearate 10.0
Sodium carboxymethyl cellulose 10.0
Silica anhydride 13.5
EDTA 1.0
Chromium oxide 0.5
Total 100.0

  The kit for hair treatment agent of the present invention is suitable for use as a decoloring agent or a hair dye because it is easy to mix the first agent and the liquid second agent.

Claims (5)

  A kit for a hair treatment agent comprising a first agent containing an alkaline agent and a liquid second agent containing an oxidizing agent, wherein (A) a dialkyl phosphate, (B) a nonionic surfactant, and (C) A hair treatment agent kit for hair decolorization or oxidative hair coloring, comprising a polyhydric alcohol.   The kit for hair treatment agents according to claim 1, wherein the first agent contains components (A) to (C).   (A) The kit for hair treatment agents of Claim 1 or 2 whose component is a dicetyl phosphate.   Furthermore, the kit for hair treatment agents in any one of Claims 1-3 formed by containing (D) water-soluble polysaccharide. (D) The kit for hair treatment agents of Claim 4 whose component is a xanthan gum and / or a xanthan gum derivative.