JP2008133214A - Hair-cleansing composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a hair-cleansing composition which gives excellent hair smoothness and excellent non-stiffness, after used and when dried, and has excellent bubbling and cleansing effects also for hair coated with styling agents. <P>SOLUTION: This hair-cleansing composition comprises 0.01 to 15 mass% of a block type alkylene oxide derivative, 0.1 to 20 mass% of sodium cocoylmethyltaurine, and 0.1 to 15 mass% of a specific amideamine type amphoteric surfactant. The block type alkylene oxide derivative includes POB(30)POE(30) trimethylglyceryl ether. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a hair cleaning composition, and more particularly to an improvement of a hair cleaning composition containing a block-type alkylene oxide derivative as an active ingredient.

  A hair shampoo, which is a typical embodiment of a hair cleaning composition, generally contains a large amount of an anionic surfactant, and when the hair is washed, sebum and other oils on the surface of the hair are washed away in addition to dirt. End up. For this reason, the hair feels badly, and there is an adverse effect such as rustling and poor combing properties. Moreover, since the oil content of the scalp is also removed, there is a tendency that dandruff tends to occur.

In order to eliminate these drawbacks, conventionally, a method of blending an oil or the like with a hair shampoo base and replenishing the oil during hair washing has been conventionally employed. As the oil to be blended, for example, lanolin derivatives, fatty acid esters, proteins, silicones and the like are employed.
However, when trying to add a sufficient amount of oil to eliminate the above-mentioned drawbacks, there may be a problem that the stability of the base is lowered. Moreover, even when a large amount of oil was stably blended by some method, there was a problem that the foaming effect and the cleaning effect, which are the original functions of a hair shampoo, were inferior. Furthermore, further improvements have been demanded in the feeling of use such as smoothness after use.

On the other hand, it is known to add a quaternary nitrogen-containing water-soluble polymer for the purpose of imparting conditioning properties (see, for example, Patent Document 1).
However, when a quaternary nitrogen-containing water-soluble polymer is blended, the smoothness during rinsing can be improved, but the effect of improving the smoothness and suppleness of the hair is sufficiently obtained after towel drying and drying. On the contrary, when these were blended in a large amount, there was a tendency to lead to hair fraying, hair frying (drying), etc. at the time of drying, and the improvement was desired.

In recent years, hair styling agents containing silicone oil, alcohol, resin, and the like are commercially available, and there are various types such as gel, mousse, liquid, spray, and solid. For this reason, if the hair is washed after the hair styling agent is applied, the foaming or cleaning effect inherent in the hair cleaning agent tends to be hindered due to silicone oil, alcohol or the like. As countermeasures thereof, blending of polyoxyethylene dicarboxylic acid ester (see, for example, Patent Document 2), a method of blending an alkylene oxide derivative (see, for example, Patent Document 3), and the like are known.
However, by any of these methods, it cannot be said that the hair feels dry after washing and drying and the combing is sufficient, and further improvement has been desired.

JP 55-38813 A JP 2001-226234 A JP 2003-160449 A

  The present invention has been made in view of the above-mentioned circumstances, and the problem is that the hair feels when dried after use, particularly smoothness and excellent smoothness, and even for hair coated with a styling agent, An object of the present invention is to provide a hair cleaning composition having excellent foaming and cleaning effects.

  As a result of intensive studies by the present inventors in order to solve the above problems, a block type alkylene oxide derivative having a specific structure, cocoyl methyl taurine sodium, and a specific amidoamine type amphoteric surfactant are incorporated into a hair washing composition. By doing so, it has been found that the hair feels at the time of drying after use, in particular, smoothness and smoothness, and it is possible to obtain excellent foaming and cleaning effects even for hair coated with a styling agent. It came to complete.

（式中、Ｙは３〜６個の水酸基を有する多価アルコールの水酸基を除いた残基、ｋは前記多価アルコールの水酸基数、ＥＯはオキシエチレン基、ＡＯは炭素数３〜６のオキシアルキレン基でそれぞれブロック状に付加されている。ａ×ｋ、ｂ×ｋおよびｃ×ｋはそれぞれオキシエチレン基、炭素数３〜６のオキシアルキレン基、オキシエチレン基の平均付加モル数であり、０≦ａ×ｋ≦１００、１≦ｂ×ｋ≦１００、０≦ｃ×ｋ≦１００、ただし（ａ＋ｃ）×ｋ＞１である。式（Ｉ）中の全オキシエチレン基と炭素数３〜６のオキシアルキレン基の合計に対する、式（Ｉ）中の全オキシエチレン基の割合は、１０〜８０質量％である。Ｒは炭素数１〜４の炭化水素基である。）

（式中、Ｒ^２は平均炭素原子数７〜１９の飽和または不飽和の炭化水素基を表わし；Ｚ^１は水素原子または（ＣＨ_２）_ｌＣＯＯＹ^１（ここで、Ｙ^１はアルカリ金属類、アルカリ土類金属類または有機アミン類を表わし；ｌは１〜３の整数を表わす）を表し；Ｍ^２はアルカリ金属類、アルカリ土類金属類または有機アミン類を表わし；ｍ及びｎは各々１〜３の整数を表す。）

（式中、Ｒ^３は平均炭素原子数７〜１９の飽和または不飽和の炭化水素基を表わし；Ｚ^２は水素原子または（ＣＨ_２）_ｒＣＯＯＹ^２（ここで、Ｙ^２はアルカリ金属類、アルカリ土類金属類または有機アミン類を表わし；ｒは１〜３の整数を表わす）を表わし；Ｒ^４は水素原子または（ＣＨ_２）_ｓＣＯＯＹ^３（ここでＹ^３はアルカリ金属類、アルカリ土類金属類または有機アミン類を表わし；ｓは１〜３の整数を表わす）を表わし；Ｍ^３はアルカリ金属類、アルカリ土類金属類または有機アミン類を表わし；ｐ、ｑは１〜３の整数を表わす。） That is, the hair cleaning composition of the present invention comprises 0.01 to 15% by mass of a block-type alkylene oxide derivative represented by the following formula (I), 0.1 to 20% by mass of sodium cocoylmethyl taurine, and the following formula ( II) or an amidoamine type amphoteric surfactant represented by (III) in an amount of 0.1 to 15% by mass.

(In the formula, Y is a residue obtained by removing a hydroxyl group of a polyhydric alcohol having 3 to 6 hydroxyl groups, k is the number of hydroxyl groups of the polyhydric alcohol, EO is an oxyethylene group, and AO is an oxy of 3 to 6 carbon atoms. Each of which is added in the form of a block with an alkylene group, wherein a × k, b × k and c × k are the average number of moles of oxyethylene group, oxyalkylene group having 3 to 6 carbon atoms, and oxyethylene group, 0 ≦ a × k ≦ 100, 1 ≦ b × k ≦ 100, 0 ≦ c × k ≦ 100, where (a + c) × k> 1 In the formula (I), all oxyethylene groups and 3 to 3 carbon atoms The ratio of all oxyethylene groups in formula (I) to the total of 6 oxyalkylene groups is 10 to 80% by mass, and R is a hydrocarbon group having 1 to 4 carbon atoms.

(Wherein R ² represents a saturated or unsaturated hydrocarbon group having an average carbon number of 7 to 19; Z ¹ represents a hydrogen atom or (CH ₂ ) ₁ COOY ¹ (where Y ¹ represents an alkali metal, Represents an alkaline earth metal or an organic amine; l represents an integer of 1 to 3; M ² represents an alkali metal, an alkaline earth metal, or an organic amine; Represents an integer of ~ 3)

(Wherein R ³ represents a saturated or unsaturated hydrocarbon group having an average carbon number of 7 to 19; Z ² is a hydrogen atom or (CH ₂ ) _r COOY ² (where Y ² is an alkali metal, Represents an alkaline earth metal or an organic amine; r represents an integer of 1 to 3; R ⁴ represents a hydrogen atom or (CH ₂ ) _s COOY ³ (where Y ³ represents an alkali metal, an alkaline earth) It represents a kind metals or organic amines; s represents an an integer of 1 to 3); M ³ represents an alkali metal, an alkaline earth metal or organic amines; p, q is 1 to 3 Represents an integer.)

In the hair cleaning composition, it is preferable that the AO group of the block-type alkylene oxide derivative represented by the formula (I) is an oxybutylene group.
In the hair cleaning composition, a in the block type alkylene oxide derivative represented by the above formula (I) is 0, and the addition order of AO and EO is (AO)-( EO) is preferred.

  The hair cleaning composition is a hair shampoo.

  According to the present invention, 0.01 to 15% by mass of a block-type alkylene oxide derivative having a specific structure, 0.1 to 20% by mass of sodium cocoylmethyl taurate, and 0.1 to 15% by mass of a specific amidoamine type amphoteric surfactant. % Is incorporated into the hair cleaning composition to provide excellent hair feel during drying after use, especially smoothness and smoothness, as well as excellent foaming and cleaning effects for hair coated with a styling agent. The hair-cleaning composition which has can be obtained.

Hereinafter, preferred embodiments of the present invention will be described.
In the present invention, the term “hair cleaning composition” means a composition that is used for scalp and hair and has a cleaning effect, and has no hair cleaning action, such as mere hair rinse, hair treatment, hair conditioner, etc. Shall be excluded. However, the range of the “hair cleaning composition” of the present invention is distinguished by whether or not the hair cleaning composition has a cleaning effect, and is not distinguished by the trade name. For example, a rinse-in shampoo or the like in which a cleaning action is recognized is also included in the “hair cleaning composition” of the present invention.
<Block-type alkylene oxide derivative>
The hair washing composition according to the present invention contains a block-type alkylene oxide derivative represented by the following formula (I).

In the alkylene oxide derivative represented by the above formula (I), Y is a residue excluding the hydroxyl group of the polyhydric alcohol having 3 to 6 hydroxyl groups, k is the number of hydroxyl groups of the polyhydric alcohol, and 3 to 6 It is. Examples of the compound having 3 to 6 hydroxyl groups include glycerin with k = 3, trimethylolpropane, hexylene glycol, erythritol with k = 4, pentaerythritol, xylitol with k = 5, sorbitol with k = 6 And inositol. The block-type alkylene oxide derivative to be blended in the hair washing composition according to the present invention is basically based on a residue excluding the hydroxyl group of one or a mixture of two or more polyhydric alcohols having 3 to 6 hydroxyl groups. The skeleton.
In the present invention, Y is more preferably a residue obtained by removing a hydroxyl group of a polyhydric alcohol having 3 to 4 hydroxyl groups, that is, it is preferable that 3 ≦ k ≦ 4 is satisfied. When k is 2 or less, when blended in the hair washing composition, the smoothness during drying after use tends to be inferior, and when k is 7 or more, a sticky feeling tends to occur.

  EO is an oxyethylene group having 2 carbon atoms. AO is an oxyalkylene group having 3 to 6 carbon atoms, and specific examples include an oxypropylene group, an oxybutylene group, an oxyisobutylene group, an oxy t-butylene group, an oxypentylene group, and an oxyhexylene group. . Preferred are an oxypropylene group and an oxybutylene group, and more preferred is an oxybutylene group.

  b × k is the average added mole number of AO, and 1 ≦ b × k ≦ 100, preferably 3 ≦ b × k ≦ 70. a × k and c × k are average added moles of EO, 0 ≦ a × k ≦ 100, 0 ≦ c × k ≦ 100, preferably 3 ≦ a × k ≦ 70, 3 ≦ c × k ≦ 70. Moreover, the preferable range of the average addition mole number of all the oxyethylene groups in the said formula (I) is 1 <(a + c) * k <= 200, More preferably, it is 6 <= (a + c) * k <= 140. AO becomes a hydrophobic site in the block-type alkylene oxide derivative according to the present invention, and when b × k is 0, it tends to be inferior in stability when blended in a hair washing composition. There is a tendency to be inferior in smoothness when dried. Further, when a × k or c × k is 0, the stability tends to be inferior when blended into the hair washing composition, and when it exceeds 100, a sticky feeling tends to occur.

The ratio of the total EO in the said formula (I) with respect to the sum total of AO and EO in the said formula (I) is 10-80 mass%, More preferably, it is 20-70 mass%. If it is less than 10% by mass, it tends to be inferior in smoothness when dried after use, and if it is more than 80% by mass, it tends to cause stickiness.
The addition form of AO and EO is block-like, and the addition order is (AO)-(EO) order, (EO)-(AO) order, (EO)-( Any of the order of AO)-(EO) may be sufficient. In the present invention, the order of (AO)-(EO) with respect to Y in the formula is particularly preferable. In the order of (AO)-(EO) with respect to Y in the formula, it corresponds to a in the formula being 0.

  R is a hydrocarbon group having 1 to 4 carbon atoms. Examples of the hydrocarbon group include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, and a tert-butyl group. It is done. In the present invention, a methyl group and an ethyl group are preferable. If the carbon number is greater than 5, the smoothness tends to be inferior when drying after use. Further, in the block-type alkylene oxide derivative blended in the hair washing composition according to the present invention, R may be the same or different in one molecule, and is a block type having the same R in one molecule. One kind of alkylene oxide derivative or a mixture of two or more kinds having different Rs may be used.

Specific examples of the alkylene oxide derivative blended in the hair cleaning composition according to the present invention include POB (30) POE (30) glyceryl trimethyl ether, POB (30) POE (35) glyceryl trimethyl ether, and POB (17). POE (28) glyceryl trimethyl ether, POB (27) POE (45) glyceryl trimethyl ether, POB (14) POE (34) glyceryl trimethyl ether, POB (22) POE (55) glyceryl trimethyl ether, POB (19) POE ( 55) Glyceryl trimethyl ether, POB (40) POE (80) glyceryl trimethyl ether, POB (80) POE (40) glyceryl trimethyl ether, POB (30) POE (30) glyceryl triethyl ether, P B (30) POE (35) glyceryl triethyl ether, POB (14) POE (34) glyceryl triethyl ether, POB (30) POE (30) glyceryl tripropyl ether, POE (30) POP (30) glyceryl triethyl ether, POE (35) POP (40) glyceryl trimethyl ether, POE (41) POP (48) glyceryl trimethyl ether, etc. are mentioned.
The POE, POP, and POB are abbreviations for polyoxyethylene, polyoxypropylene, and polyoxybutylene, respectively, and may be abbreviated as follows.

  The alkylene oxide derivative blended in the hair washing composition according to the present invention can be produced by a known method. For example, it is obtained by subjecting a polyhydric alcohol having a hydroxyl group to addition polymerization of ethylene oxide and an alkylene oxide having 3 to 6 carbon atoms, and then subjecting an alkyl halide to an ether reaction in the presence of an alkali catalyst.

  In the hair washing composition according to the present invention, the blending amount of the alkylene oxide derivative having the above-mentioned specific structure is preferably 0.01 to 15% by mass, more preferably 0.1 to 10% by mass in the total amount of the composition. %. If it is less than 0.01% by mass, the effect of the blending may not be sufficiently exhibited, and if it exceeds 15% by mass, a feeling of stiffness may occur during drying after use.

<Cocoyl methyl taurine sodium>
The hair cleaning composition according to the present invention preferably contains sodium cocoylmethyl taurine as a surfactant. The amount of cocoyl methyl taurine sodium is preferably 0.1 to 20% by mass, more preferably 1 to 15% by mass, based on the total amount of the hair cleaning composition. If it is less than 0.1% by mass, foaming tends to be inferior when the hair on which the styling agent is applied is washed, and if it exceeds 20% by mass, a squeaky or slimy sensation may occur during drying after use. is there.

（式中、Ｒ^２は平均炭素原子数７〜１９の飽和または不飽和の炭化水素基を表わし；Ｚ^１は水素原子または（ＣＨ_２）_ｌＣＯＯＹ^１（ここで、Ｙ^１はアルカリ金属類、アルカリ土類金属類または有機アミン類を表わし；ｌは１〜３の整数を表わす）を表し；Ｍ^２はアルカリ金属類、アルカリ土類金属類または有機アミン類を表わし；ｍ及びｎは各々１〜３の整数を表す。）

（式中、Ｒ^３は平均炭素原子数７〜１９の飽和または不飽和の炭化水素基を表わし；Ｚ^２は水素原子または（ＣＨ_２）_ｒＣＯＯＹ^２（ここで、Ｙ^２はアルカリ金属類、アルカリ土類金属類または有機アミン類を表わし；ｒは１〜３の整数を表わす）を表わし；Ｒ^４は水素原子または（ＣＨ_２）_ｓＣＯＯＹ^３（ここでＹ^３はアルカリ金属類、アルカリ土類金属類または有機アミン類を表わし；ｓは１〜３の整数を表わす）を表わし；Ｍ^３はアルカリ金属類、アルカリ土類金属類または有機アミン類を表わし；ｐ、ｑは１〜３の整数を表わす。） <Amidoamine type amphoteric surfactant>
In the hair cleaning composition according to the present invention, it is preferable to further contain an amidoamine type amphoteric surfactant as a surfactant. The amidoamine type amphoteric surfactant used in the present invention is represented by the following general formulas (II) and (III).

(Wherein R ² represents a saturated or unsaturated hydrocarbon group having an average carbon number of 7 to 19; Z ¹ represents a hydrogen atom or (CH ₂ ) ₁ COOY ¹ (where Y ¹ represents an alkali metal, Represents an alkaline earth metal or an organic amine; l represents an integer of 1 to 3; M ² represents an alkali metal, an alkaline earth metal, or an organic amine; Represents an integer of ~ 3)

(Wherein R ³ represents a saturated or unsaturated hydrocarbon group having an average carbon number of 7 to 19; Z ² is a hydrogen atom or (CH ₂ ) _r COOY ² (where Y ² is an alkali metal, Represents an alkaline earth metal or an organic amine; r represents an integer of 1 to 3; R ⁴ represents a hydrogen atom or (CH ₂ ) _s COOY ³ (where Y ³ represents an alkali metal, an alkaline earth) It represents a kind metals or organic amines; s represents an an integer of 1 to 3); M ³ represents an alkali metal, an alkaline earth metal or organic amines; p, q is 1 to 3 Represents an integer.)

In the amidoamine type amphoteric surfactant represented by the above formula (II), R ² represents a saturated or unsaturated hydrocarbon group having an average carbon number of 7 to 19, and examples of R ² CO include C ₉ H ₁₉ CO C ₁₁ H ₂₃ CO, C ₁₃ H ₂₇ CO, C ₁₅ H ₃₁ CO, C ₁₇ H ₃₅ CO, C ₁₃ H ₂₅ CO, C ₁₅ H ₂₉ CO, coconut fatty acid residue, palm palm fatty acid residue, etc. . Z ¹ is a hydrogen atom or (CH ₂ ) ₁ COOY ¹ . When Z ¹ is (CH ₂ ) ₁ COOY ¹ , Y ¹ represents an alkali metal, alkaline earth metal or organic amine, specifically lithium, potassium, sodium, calcium, magnesium, ammonium, monoethanol Examples include amine, diethanolamine, triethanolamine and the like. L is an integer of 1 to 3.
Further, M ² represents an alkali metal, an alkaline earth metal or an organic amine, and specifically, lithium, potassium, sodium, calcium, magnesium, ammonium, monoethanolamine, diethanolamine, triethanolamine and the like are exemplified. Is done. M and n are each an integer of 1 to 3.

  As the amidoamine type amphoteric surfactant represented by the above formula (II), specifically, N-lauroyl-N′-carboxymethyl-N ′-(2-hydroxyethyl) ethylenediamine sodium, N-myristoyl-N′-carboxy Methyl-N ′-(2-hydroxyethyl) ethylenediamine sodium, N-palmitoyl-N′-carboxymethyl-N ′-(2-hydroxyethyl) ethylenediamine sodium, N-lauroyl-N′-carboxymethyl-N ′-( 2-hydroxyethyl) ethylenediamine potassium, N-lauroyl-N′-carboxymethyl-N ′-(2-hydroxyethyl) ethylenediamine magnesium, and the like.

In the amidoamine type amphoteric surfactant represented by the above formula (III), in the above formula, R ³ represents a saturated or unsaturated hydrocarbon group having an average carbon number of 7 to 19, and R ³ CO is For example, C ₉ H ₁₉ CO, C ₁₁ H ₂₃ CO, C ₁₃ H ₂₇ CO, C ₁₅ H ₃₁ CO, C ₁₇ H ₃₅ CO, C ₁₃ H ₂₅ CO, C ₁₅ H ₂₉ CO, coconut fatty acid residue, palm palm fatty acid Examples include residues. Z ² is a hydrogen atom or (CH ₂ ) _r COOY ² . R ⁴ is a hydrogen atom or (CH ₂ ) _s COOY ³ .
When Z ² is (CH ₂ ) _r COOY ² or R ⁴ is (CH ₂ ) _s COOY ³ , Y ² and Y ³ each represent an alkali metal, an alkaline earth metal or an organic amine, Specifically, lithium, potassium, sodium, calcium, magnesium, ammonium, monoethanolamine, diethanolamine, triethanolamine and the like are exemplified. r and s are each an integer of 1 to 3.
Further, M ³ represents an alkali metal, an alkaline earth metal or an organic amine, and specific examples include lithium, potassium, sodium, calcium, magnesium, ammonium, monoethanolamine, diethanolamine, triethanolamine and the like. The p and q are integers of 1 to 3, respectively.

  As the amidoamine type amphoteric surfactant represented by the above formula (III), specifically, N-lauroyl-N- (2-hydroxyethyl) -N ′, N′-bis (carboxymethyl) ethylenediamine sodium, N-myristoyl -N- (2-hydroxyethyl) -N ', N'-bis (carboxymethyl) ethylenediamine sodium, N-palmitoyl-N- (2-hydroxyethyl) -N', N'-bis (carboxymethyl) ethylenediamine sodium N-stearoyl-N- (2-hydroxyethyl) -N ′, N′-bis (carboxymethyl) ethylenediamine sodium, N-lauroyl-N- (2-hydroxyethyl) -N ′, N′-bis (carboxy Methyl) ethylenediamine calcium, N-lauroyl-N- (2-hydroxyethyl) -N ', N'-bis (carboxymethyl) ethylenediamine magnesium, N- lauroyl-N-(2-hydroxyethyl) -N', N'-bis (carboxymethyl) ethylenediamine and triethanolamine.

  In the hair washing composition according to the present invention, the amount of the amidoamine type amphoteric surfactant represented by the above formulas (II) and (III) is preferably 0.1 to 20% by mass in the total amount of the hair composition. More preferably, it is 1-10 mass%. If it is less than 0.1% by mass, the washing effect may not be sufficiently exerted when the hair on which the styling agent is applied is washed, and if it exceeds 20% by mass, a slimy sensation is produced when drying after use. There is a case.

  In the hair cleaning composition according to the present invention, ingredients usually used in cosmetics and quasi-drug hair cleaning compositions can be appropriately blended within the range not impairing the effects of the present invention. Specific ingredients that can be blended are listed below. A composition containing the block type alkylene oxide derivative having the above specific structure, sodium cocoylmethyl taurate and a specific amidoamine type amphoteric surfactant within a suitable blending amount range, and further containing one or more of the following components: Thus, the hair cleaning composition of the present invention can be prepared.

  Examples of the humectant include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-hydroxystearate. Sodium lactate, bile salt, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, Izayoi rose extract, yarrow extract, merirot extract and the like.

  Examples of the powder component include inorganic powders (for example, talc, kaolin, mica, sericite, muscovite, phlogopite, synthetic mica, saucite, biotite, permiculite, magnesium carbonate, calcium carbonate, silicic acid. Aluminum, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (baked gypsum), calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder , Metal soap (eg, zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc .; organic powder (eg, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene Powder of styrene and acrylic acid copolymer resin, benzoguanamine resin powder, polytetrafluoroethylene powder, cellulose powder, etc .; inorganic white pigment (eg, zinc oxide); inorganic red pigment (eg, iron titanate) Inorganic purple pigments (eg, mango violet, cobalt violet, etc.); inorganic green pigments (eg, chromium oxide, chromium hydroxide, cobalt titanate, etc.); inorganic blue pigments (eg, ultramarine blue, bitumen, etc.) Pearl pigments (eg, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil); metal powder pigments (eg, aluminum powder, copper powder, etc.) ); Such as zirconium, barium or aluminum lakes Organic pigments (for example, red 201, red 202, red 204, red 205, red 220, red 226, red 228, red 405, orange 203, orange 204, yellow 205, yellow Organic pigments such as No. 401 and Blue No. 404, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5 No., Yellow No. 202, Yellow No. 203, Green No. 3 and Blue No. 1); natural pigments (for example, chlorophyll, β-carotene and the like) and the like.

  Examples of liquid oils include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern castor oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin and the like.

  Examples of the solid fat include cacao butter, palm oil, horse fat, hydrogenated palm oil, palm oil, beef tallow, sheep fat, hydrogenated beef tallow, palm kernel oil, pork fat, beef bone fat, owl kernel oil, hydrogenated oil, cattle Leg fats, moles, hydrogenated castor oil and the like.

  Examples of waxes include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, and reduced lanolin. Jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, and the like.

Examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax, and the like.
Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, toluic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid ( DHA) and the like.

  Examples of higher alcohols include linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol); branched chain alcohols (eg, monostearyl glycerin ether (batyl alcohol) ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyl decanol, isostearyl alcohol, octyldodecanol and the like.

  Ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate, Lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, monoisostearic acid-N-alkyl glycol, neopentyl glycol dicaprate, apple Acid diisostearyl, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid trimethylolpropane, triisostearate Trimethylolpropane phosphate, pentaerythritol tetra-2-ethylhexanoate, glycerin tri-2-ethylhexanoate, glycerin trioctanoate, glyceryl triisopalmitate, trimethylolpropane triisostearate, cetyl-2-ethylhexanoate 2-ethylhexyl palmitate, glyceryl trimyristate, tri-2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl -L-glutamic acid-2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, myristic acid-2-hexyl Rudeshiru, palmitic acid-2-hexyl decyl adipate 2-hexyl decyl, diisopropyl sebacate, succinic acid-2-ethylhexyl, and triethyl citrate.

  Examples of the silicone oil include linear polysiloxanes (for example, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (for example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexyl). Silicone resins, silicone rubber, various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, etc.), acrylic silicone And the like.

Moreover, you may mix | blend various surfactant other than the above in the range which does not impair the effect of this invention to the hair washing composition concerning this invention.
Anionic surfactants include, for example, fatty acid soaps (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (eg, sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfates (eg, POE lauryl sulfate triethanolamine, POE sodium lauryl sulfate, etc.); Phosphate ester salts (POE oleyl ether sodium phosphate, POE stearyl ether phosphate, etc.); Sulfosuccinate (eg, sodium di-2-ethylhexyl sulfosuccinate, mono Lauroyl monoethanolamide polyoxyethylene sodium sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, etc.); alkylbenzene sulfonates (eg linear dode) Sodium rubenzene sulfonate, linear dodecyl benzene sulfonate triethanolamine, linear dodecyl benzene sulfonic acid, etc.); higher fatty acid ester sulfates (for example, hydrogenated coconut oil fatty acid sodium glycerin sulfate, etc.); N-acyl glutamate (for example, N-lauroyl glutamate monosodium, N-stearoyl glutamate disodium, N-myristoyl-L-glutamate monosodium, etc.); sulfated oil (eg funnel oil etc.); POE alkyl ether carboxylic acid; POE alkyl allyl ether carboxylate Α-olefin sulfonates; higher fatty acid ester sulfonates; secondary alcohol sulfates; higher fatty acid alkylolamide sulfates; lauroyl monoethanolamide sodium succinate Beam; N- palmitoyl aspartate ditriethanolamine; sodium caseinate, and the like.

  Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (eg, cetylpyridinium chloride, etc.); distearyldimethylammonium dialkyldimethylammonium chloride; Poly (N, N'-dimethyl-3,5-methylenepiperidinium chloride); alkyl quaternary ammonium salt; alkyldimethylbenzylammonium salt; alkylisoquinolinium salt; dialkyl morpholinium salt; POE alkylamine; Examples include amine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride and the like.

  Examples of the lipophilic nonionic surfactant include sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, Sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexyl); glycerin polyglycerin fatty acids (for example, mono-cotton oil fatty acid glycerin, mono-erucic acid glycerin, sesquioleate glycerin, monostearin) Glycerin acid, α, α′-oleic acid pyroglutamate glycerin, monostearate glycerin malate, etc.); propylene glycol fatty acid esters (eg, Propylene glycol stearate); hydrogenated castor oil derivatives; glycerol alkyl ethers, and the like.

  Examples of hydrophilic nonionic surfactants include POE sorbitan fatty acid esters (for example, POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan monooleate, POE sorbitan tetraoleate, etc.); POE sorbite fatty acid ester (Eg POE sorbite monolaurate, POE sorbite monooleate, POE sorbite pentaoleate, POE sorbite monostearate, etc.); POE glycerin fatty acid esters (eg POE glycerin monostearate, POE glycerin monoisostearate) POE monooleate such as POE glycerin triisostearate); POE fatty acid esters (for example, POE distearate, POE monodiolate, distearies) POE alkyl ethers (for example, POE lauryl ether, POE oleyl ether, POE stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE cholestanol ether, etc.); Pluronic type (for example, POE / POP alkyl ethers (for example, POE / POP cetyl ether, POE / POP-2-decyltetradecyl ether, POE / POP monobutyl ether, POE / POP hydrogenated lanolin, POE / POP glycerin ether, etc.) ); Tetra POE / tetra-POP ethylenediamine condensates (for example, Tetronic, etc.); POE castor oil hydrogenated castor oil derivatives (for example, POE castor oil, POE hydrogenated castor oil, POE hydrogenated castor oil monoisostearate, P) OE hydrogenated castor oil triisostearate, POE hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, POE hydrogenated castor oil maleic acid, etc .; POE beeswax lanolin derivatives (eg POE sorbite beeswax etc.); Oil fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE propylene glycol fatty acid ester; POE alkylamine; POE fatty acid amide; sucrose fatty acid ester; alkylethoxydimethylamine oxide; Reyl phosphoric acid and the like can be mentioned.

  Examples of natural water-soluble polymers include plant-based polymers (for example, gum arabic, gum tragacanth, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (guckweed extract), starch (Rice, corn, potato, wheat), glycyrrhizic acid); microbial polymers (eg, xanthan gum, dextran, succinoglucan, bullulan, etc.); animal polymers (eg, collagen, casein, albumin, gelatin, etc.), etc. Is mentioned.

  Semi-synthetic water-soluble polymers include, for example, starch polymers (eg, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate) Hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder and the like); alginic acid polymers (for example, sodium alginate, propylene glycol alginate, etc.) and the like.

  Synthetic water-soluble polymers include, for example, vinyl polymers (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer); polyoxyethylene polymers (eg, polyethylene glycol 20,000, 40,000, 60,000). Etc.); acrylic polymers (for example, sodium polyacrylate, polyethyl acrylate, polyacrylamide and the like); polyethyleneimine; cationic polymers and the like.

  Examples of the thickener include gum arabic, carrageenan, caraya gum, gum tragacanth, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, CMC, hydroxyethylcellulose, hydroxypropyl Cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, cellulose dialkyldimethylammonium sulfate, xanthan gum, magnesium aluminum silicate, bentonite, hectorite, AlMg silicate (Beegum), Examples thereof include laponite and silicic anhydride.

  Examples of the ultraviolet absorber include benzoic acid-based ultraviolet absorbers (for example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester. N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester, etc.); anthranilic acid ultraviolet absorbers (for example, homomenthyl-N-acetyl anthranilate etc.); Salicylic acid-based UV absorbers (eg, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate); For example, octylcinnamate, ethyl-4-isopropylcinnamate, methyl-2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p-methoxycinnamate Mate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl- p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate, etc.); benzophenone UV absorbers (for example, 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4 ′ -Tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2- Ethylhexyl-4′-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc.); 3- (4′-methylbenzylidene) -d, l -Camphor, 3-benzylidene-d, l-camphor; 2 -Phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-methylphenylbenzotriazole; 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy Dibenzalazine; dianisoylmethane; 2-methoxy-2'-t-butyldibenzoylmethane; 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one Etc.

  Examples of the lower alcohol include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

  Examples of the polyhydric alcohol include divalent alcohols (for example, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, Pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trivalent alcohol (eg, glycerin, trimethylolpropane, etc.); tetravalent alcohol (eg, 1, 2, 6) Pentaerythritol such as hexanetriol, etc .; pentavalent alcohol (eg, xylitol, etc.); hexavalent alcohol (eg, sorbitol, mannitol, etc.); polyhydric alcohol polymer (eg, diethylene glycol, dipropylene glycol, Tylene glycol, polypropylene glycol, tetraethylene glycol, diglycerin, polyethylene glycol, triglycerin, tetraglycerin, polyglycerin, etc.); divalent alcohol alkyl ethers (for example, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol) Monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol mono 2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol Dibutyl Dihydric alcohol alkyl ethers (for example, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol) Monoethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether, dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol Dibutyl alcohol ether ester (for example, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl ether acetate, ethylene glycol diazebate, ethylene glycol disuccine) Diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, propylene glycol monophenyl ether acetate, etc.); glycerin monoalkyl ether (example) Xyl alcohol, ceralkyl alcohol, batyl alcohol, etc.); sugar alcohols (eg, sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, amylolytic sugar, maltose, xylitol, amylolytic sugar) Reduced alcohol, etc.); Glysolid; Tetrahydrofurfuryl alcohol; POE Tetrahydrofurfuryl alcohol; POP butyl ether; POP / POE butyl ether; Tripolyoxypropylene glycerin ether; POP glycerin ether; POP glycerin ether phosphate; POP / POE pentane erythritol Examples include ether and polyglycerin.

  Examples of monosaccharides include tricarbon sugars (eg, D-glyceryl aldehyde, dihydroxyacetone, etc.); tetracarbon sugars (eg, D-erythrose, D-erythrulose, D-treose, erythritol, etc.); pentose sugars (eg, L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc .; hexose (eg, D-glucose, D-talose, D) -Bucicose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc.); pentose sugar (eg, aldheptose, heproose, etc.); octose sugar (eg, octulose, etc.); For example, 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L Mannose, etc.]; amino sugars (eg, D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, muramic acid, etc.); uronic acids (eg, D-glucuronic acid, D-mannuronic acid, L-guluronic acid, D- Galacturonic acid, L-iduronic acid, etc.).

Examples of the oligosaccharides include sucrose, gnocyanose, umbelliferose, lactose, planteose, isoliquinoses, α, α-trehalose, raffinose, lycnose, umbilicin, stachyose verbusose and the like.
Examples of amino acids include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.) and the like. Examples of the amino acid derivative include acyl sarcosine sodium (lauroyl sarcosine sodium), acyl glutamate, acyl β-alanine sodium, glutathione, and pyrrolidone carboxylic acid.

  Examples of the organic amine include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-methyl-1-propanol, and the like. Is mentioned.

  Examples of the sequestering agent include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, and tetrasodium edetate. Sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, trisodium ethylenediaminehydroxyethyl triacetate and the like.

  Examples of the antioxidant assistant include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid.

  Other ingredients that can be added include, for example, preservatives (ethyl paraben, butyl paraben, etc.); whitening agents (eg, placenta extract, yukinoshita extract, arbutin, etc.); blood circulation promoters (nicotinic acid, benzyl nicotinate, nicotine) Acid tocopherol, nicotinic acid β-butoxy ester, minoxidil or its analog, vitamin Es, γ-oryzanol, alkoxycarbonylpyridine N-oxide, carpronium chloride, acetylcholine or a derivative thereof, and the like (for example, ginger, (Ubakaku, Auren, Shikon, Birch, Loquat, Carrot, Aloe, Zeniaoi, Iris, Grape, Loofah, Lily, Saffron, Senkyu, Pepper, Hypericum, Onionis, Garlic, Pepper, Chimpi, Toki, Button, Seaweed, etc.), Activation Agent (eg Panthenyl ethyl ether, nicotinamide, biotin, pantothenic acid, royal jelly, cholesterol derivatives and the like); antiseborrheic agents (for example, pyridoxines, thianthol and the like).

  The hair cleaning composition of the present invention means that applied to scalp and hair for the purpose of cleaning the hair, and the dosage form can take a wide variety of forms such as an aqueous solution system, an emulsion system, and a gel system.

The present invention will be described more specifically with reference to the following examples. In addition, this invention is not limited by this. The blending amount is expressed in mass% unless otherwise specified.
First, a method for evaluating the hair cleaning composition used in the following examples will be described. The hair cleaning composition comprises a hair styling agent (N-methacryloyl N, N-dimethylammonium / α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer (trade name: Yucaformer SM); 20%, ethanol; 30% , Propylene glycol; 5%, purified water; 45%) and applied to the hair after 2 hours.
The composition of the hair cleaning composition (shampoo) used as a control is as follows.
Composition of control shampoo (mass%)
(1) Polyoxyethylene (3 mol) sodium lauryl ether sulfate 10.0
(2) Palm fatty acid monotaenolamide 2.0
(3) Sodium benzoate 0.5
(4) Lauryldimethylaminoacetic acid betaine 5.0
(5) Perfume appropriate amount (6) Purified water remaining

Evaluation (1): Smoothness of hair after hair washing and drying After hair washing, the hair washing composition of the following test examples and the above-described control shampoo were performed by 10 professional panelists on the smoothness of hair after hair washing. Have it used, and have it scored as follows. Here, the score determination is performed with the control shampoo set to zero. In addition, the average value which divided the sum total of the score by each panel by the panel number of persons was calculated, and it was set as the evaluation result according to the following evaluation criteria.
Scoring criteria +3: I feel very smooth compared to the control shampoo.
+2: Feels smoother than control shampoo.
+1: Feels slightly smoother than control shampoo.
0: Neither can be said.
-1: Does not feel much smoother than control shampoo.
-2: Does not feel smoother than control shampoo.
-3: Does not feel smoother than control shampoo.
Evaluation criteria A: The average value of 10 panel members is +1.5 points or more B: The average value of 10 panel members is 0 points or more and less than 1.5 points C: The average value of 10 panel members is −1.5 More than 0 points and less than 0 points D: The average value of 10 panelists is less than -1.5 points

Evaluation (2): No hair stiffness after hair washing and drying The hair washing composition of the following test example and the above control shampoo were dried by hair after hair washing and then the hair was not stiff by 10 professional panelists. And have the following score determination performed. Here, the score determination is performed with the control shampoo set to zero. In addition, the average value which divided the sum total of the score by each panel by the panel number of persons was calculated, and it was set as the evaluation result according to the following evaluation criteria.
Scoring standard +3: Compared to control shampoo, it does not feel stiff at all.
+2: Does not feel stiff compared to control shampoo.
+1: Does not feel much stiff compared to control shampoo.
0: Neither can be said.
-1: Compared with control shampoo, it feels a little stiff.
-2: Feels stiff compared to control shampoo.
-3: Feels very stiff compared to control shampoo.
Evaluation criteria A: The average value of 10 panel members is +1.5 points or more B: The average value of 10 panel members is 0 points or more and less than 1.5 points C: The average value of 10 panel members is −1.5 More than 0 points and less than 0 points D: The average value of 10 panelists is less than -1.5 points

Evaluation (3): Goodness of combing after hair washing and drying After hair washing, the hair washing composition of the following test examples and the above control shampoo were dried by 10 professional panelists on the goodness of combing hair after that. And have the following score determination performed. Here, the score determination is performed with the control shampoo set to zero. In addition, the average value which divided the sum total of the score by each panel by the panel number of persons was calculated, and it was set as the evaluation result according to the following evaluation criteria.
Scoring criteria +3: Compared to control shampoo, I feel that the comb is very good.
+2: I feel that combing is better than control shampoo.
+1: I feel that the comb is slightly better than the control shampoo.
0: Neither can be said.
-1: Compared to control shampoo, feel that combing is not good.
-2: I feel that the comb is not good compared to the control shampoo.
-3: I feel that the comb is not very good compared to the control shampoo.
Evaluation criteria A: The average value of 10 panel members is +1.5 points or more B: The average value of 10 panel members is 0 points or more and less than 1.5 points C: The average value of 10 panel members is −1.5 More than 0 points and less than 0 points D: The average value of 10 panelists is less than -1.5 points

Evaluation (4): Foaming power test In a 70 ppm calcium chloride aqueous solution, 2% of each formulation of the following test example was dissolved, 400 mL of each of these solutions was stirred with a mixer, and the height of the foam after 60 seconds was measured. This was defined as foaming power. The evaluation criteria are as follows.
Evaluation criteria A: 2400 mL or more B: 2000 mL or more, less than 2400 mL C: 1500 mL or more, less than 2000 mL D: less than 1500 mL

Evaluation (5): Foaming during hair washing With regard to foaming during hair washing, 10 professional panelists actually used the hair cleaning compositions of the test examples shown below and the above control shampoo, and received the following score determination. . Here, the score determination is performed with the control shampoo set to zero. In addition, the average value which divided the sum total of the score by each panel by the panel number of persons was calculated, and it was set as the evaluation result according to the following evaluation criteria.
Scoring criteria +3: I feel that foaming is very good compared to the control shampoo.
+2: Feels foaming better than control shampoo.
+1: Feels slightly bubbling compared to control shampoo.
0: Neither can be said.
-1: I feel that foaming is not good compared to the control shampoo.
-2: Feels less foaming than control shampoo.
-3: I feel that foaming is not very good compared to the control shampoo.
Evaluation criteria A: The average value of 10 panel members is +1.5 points or more B: The average value of 10 panel members is 0 points or more and less than 1.5 points C: The average value of 10 panel members is −1.5 More than 0 points and less than 0 points D: The average value of 10 panelists is less than -1.5 points

Evaluation (6): Washing effect After washing the hair, the hair cleaning composition of the test examples shown below and the above control shampoo were actually used by 10 expert panelists, and the following score determination was performed. . Here, the score determination is performed with the control shampoo set to zero. In addition, the average value which divided the sum total of the score by each panel by the panel number of persons was calculated, and it was set as the evaluation result according to the following evaluation criteria.
Scoring criteria +3: I feel that there is a very good cleaning effect compared to the control shampoo.
+2: I feel that there is a cleaning effect compared to the control shampoo.
+1: I feel that there is a little cleaning effect compared to the control shampoo.
0: Neither can be said.
-1: I feel that the cleaning effect is slightly inferior to the control shampoo.
-2: I feel that the cleaning effect is inferior to that of the control shampoo.
-3: I feel that the cleaning effect is very inferior compared to the control shampoo.
Evaluation criteria A: The average value of 10 panel members is +1.5 points or more B: The average value of 10 panel members is 0 points or more and less than 1.5 points C: The average value of 10 panel members is −1.5 More than 0 points and less than 0 points D: The average value of 10 panelists is less than -1.5 points

In the blending composition shown in the following table, a hair washing composition was prepared by a conventional method, and an evaluation test was performed on the evaluation items (1) to (6).
First, Table 1 below shows the results of a comparative test between a composition containing a specific component compounded in a conventional shampoo and a hair washing composition containing a block type alkylene oxide derivative having a specific structure.
In addition, the block type alkylene oxide derivative in the following table | surface shall have a structure of the following formula | equation (IV). For example, when a + c + e = 30 and b + d + f = 30, they are expressed as (BO) ₃₀ (EO) ₃₀ .

As is clear from the results of Table 1 above, Test Examples 1 to 3 containing diethoxyethyl succinate and succinoglucan blended in a conventional shampoo product to improve the smoothness of hair after use are as follows: Although it has better usability than control shampoo, it is not fully satisfactory. In addition, the cleaning effect was found to be improved.
Moreover, in Test Examples 4 and 5 in which an alkylene oxide derivative represented by CH ₃ O — [(EO) ₁₀ / (PO) ₁₀ ] CH ₃ was blended, an evaluation result was generally obtained. However, even better evaluation results were obtained in Test Example 6 in which a specific block-type alkylene oxide derivative having a different structure was blended.

From the above results, it has been clarified that when an alkylene oxide derivative having a specific structure is blended, extremely excellent results can be obtained particularly in the feeling of use such as smoothness and no firmness after washing the hair.
Therefore, the present inventors examined the alkylene oxide derivative to be blended. The results are shown in Table 2 below.

As is apparent from the results of Table 2 above, Test Example 13 containing an alkylene oxide derivative containing only an oxyethylene part is inferior in smoothness, stiffness, foaming and washing effect after washing the hair, and only in the oxybutylene part. A certain alkylene oxide derivative combination test example 14 was inferior in terms of stiffness and foaming.
Further, in Test Example 15 in which the terminal of the alkylene oxide derivative is hydrogen, the smoothness, stiffness and combing points after washing the hair are not sufficient. In addition, when a random type alkylene oxide derivative was blended (Test Example 16), hair stiffness after shampooing was observed.

On the other hand, in the test example which mix | blended various block type alkylene oxide derivatives mix | blended with Test Examples 7-12, it was what was excellent in any evaluation of (1)-(6). In particular, Test Examples 7 to 10 were extremely excellent in smoothness after hair washing and no stiffness.
Next, the effect of the type of surfactant in the hair cleaning composition was examined. The results are shown in Table 3 below.

As is clear from the results of Table 3 above, when a specific block type alkylene oxide derivative and various anionic surfactants are combined (Test Examples 17 to 20), the result is inferior in the feeling of stiffness particularly after washing and drying the hair. It was. However, when cocoyl methyl taurine sodium is used as an anionic surfactant, it is clear from the results in Tables 1 and 2 that the feeling of use is excellent.
As in Test Example 22, even when cocoyl methyl taurine sodium was blended, when the amphoteric surfactant was not blended, the feeling of stickiness was not improved. Further, when cocoyl methyl taurine sodium and an amphoteric surfactant were blended and no specific block type alkylene oxide derivative was blended (Test Example 21), the overall evaluation was inferior.

Based on the above results, when a block type alkylene oxide derivative with a specific structure, cocoyl methyl taurine, and an amphoteric surfactant are blended, the hair feels when drying after use, especially smoothness and smoothness, and a styling agent It was found that the foaming and cleaning effects were also good for the hair coated with.
Next, Table 4 below shows the results of studying suitable blending amounts of the block-type alkylene oxide derivative having a specific structure in the hair washing composition.

  From the results of Table 4 above, the blending amount of the block-type alkylene oxide derivative having a specific structure is recognized from about 0.01% by mass, but particularly noticeable is 0.1% by mass or more. However, when it becomes 20.0% by mass or more, a slight wrinkle starts to occur after hair washing and drying. Therefore, the blending amount of the block-type alkylene oxide derivative having a specific structure is preferably 0.01 to 15.0% by mass, and more preferably 0.1 to 10.0% by mass.

Hereinafter, some synthesis examples of various alkylene oxide derivatives blended in the hair washing composition of the above-described test examples will be shown.
<Synthesis Example 1>
Synthesis of polyoxybutylene (30 mol) polyoxyethylene (30 mol) trimethylglyceryl ether (block type alkylene oxide derivative) 92 g of glycerin and 18 g of potassium hydroxide as a catalyst were charged into the autoclave, and the air in the autoclave was replaced with dry nitrogen. Then, the catalyst was completely dissolved at 140 ° C. with stirring. Next, 2160 g of butylene oxide was dropped with a dropping device and stirred for 2 hours. Subsequently, 1320 g of ethylene oxide was dropped with a dropping device and stirred for 2 hours. Next, 400 g of potassium hydroxide was charged and the inside of the system was replaced with dry nitrogen, and then 300 g of methyl chloride was injected at a temperature of 80 to 130 ° C. and reacted for 5 hours. Thereafter, the reaction composition was taken out from the autoclave, neutralized with hydrochloric acid and adjusted to pH 6 to 7, and treated at a reduced pressure of -0.088 MPa (gauge pressure) at 100 ° C. for 1 hour in order to remove the contained water. Further, filtration was performed to remove the salt generated after the treatment, and a block-type alkylene oxide derivative was obtained.
Samples that were sampled and reacted before reacting with methyl chloride had a hydroxyl value of 49, the alkylene oxide derivative 1 had a hydroxyl value of 0.4, and the ratio of the number of hydrogen atoms to the number of terminal methyl groups was 0.008. An atom is converted to a methyl group.

<Synthesis Example 2>
Synthesis of polyoxyethylene (57 mol) trimethylglyceryl ether (alkylene oxide derivative) 92 g of glycerin and 18 g of potassium hydroxide as a catalyst were charged into an autoclave, and the air in the autoclave was replaced with dry nitrogen, and then stirred at 140 ° C. The catalyst was completely dissolved. Next, 2508 g of ethylene oxide was dropped with a dropping device and stirred for 2 hours. Next, 400 g of potassium hydroxide was charged and the inside of the system was replaced with dry nitrogen, and then 300 g of methyl chloride was injected at a temperature of 80 to 130 ° C. and reacted for 5 hours. Thereafter, the reaction composition was taken out from the autoclave, neutralized with hydrochloric acid and adjusted to pH 6 to 7, and treated at a reduced pressure of -0.088 MPa (gauge pressure) at 100 ° C. for 1 hour in order to remove the contained water. Further, filtration was performed to remove the salt generated after the treatment, and an alkylene oxide derivative was obtained.
Samples which were sampled and reacted before reacting with methyl chloride had a hydroxyl value of 66, and the alkylene oxide derivative 1 had a hydroxyl value of 0.60.009, and the ratio of the number of hydrogen atoms to the number of terminal methyl groups was almost completely hydrogen atoms. Has been converted to a methyl group.

<Synthesis Example 3>
Synthesis of polyoxybutylene (30 mol) polyoxyethylene (30 mol) glyceryl ether (block type alkylene oxide derivative) 92 g of glycerol and 18 g of potassium hydroxide as a catalyst were charged into the autoclave, and the air in the autoclave was replaced with dry nitrogen. Thereafter, the catalyst was completely dissolved at 140 ° C. with stirring. Next, 2160 g of butylene oxide was dropped with a dropping device and stirred for 2 hours. Subsequently, 1320 g of ethylene oxide was dropped with a dropping device and stirred for 2 hours. Thereafter, the reaction composition was taken out from the autoclave, neutralized with hydrochloric acid and adjusted to pH 6 to 7, and treated at a reduced pressure of -0.088 MPa (gauge pressure) at 100 ° C. for 1 hour in order to remove the contained water. Further, filtration was performed to remove the salt generated after the treatment, and a block-type alkylene oxide derivative was obtained.

<Synthesis Example 4>
Synthesis of polyoxybutylene (30 mol) polyoxyethylene (30 mol) tributyl glyceryl ether (block-type alkylene oxide derivative) 92 g of glycerol and 18 g of potassium hydroxide as a catalyst were charged into the autoclave, and the air in the autoclave was replaced with dry nitrogen. Then, the catalyst was completely dissolved at 140 ° C. with stirring. Next, 2160 g of butylene oxide was dropped with a dropping device and stirred for 2 hours. Subsequently, 1320 g of ethylene oxide was dropped with a dropping device and stirred for 2 hours. Next, after charging 800 g of potassium hydroxide and replacing the inside with dry nitrogen, 1200 g of butyl chloride was injected at a temperature of 80 to 130 ° C. and reacted for 5 hours. Thereafter, the reaction composition was taken out from the autoclave, neutralized with hydrochloric acid and adjusted to pH 6 to 7, and treated at a reduced pressure of -0.088 MPa (gauge pressure) at 100 ° C. for 1 hour in order to remove the contained water. Further, filtration was performed to remove the salt generated after the treatment, and a block-type alkylene oxide derivative was obtained.
Samples which were sampled and reacted before reacting with methyl chloride had a hydroxyl value of 50, the alkylene oxide derivative 1 had a hydroxyl value of 1.5, and the ratio of the number of hydrogen atoms to the number of terminal butyl groups was 0.03, indicating that hydrogen was almost completely removed. Atoms are converted to butyl groups.

<Synthesis Example 5>
Synthesis of polyoxybutylene (30 mol) polyoxyethylene (30 mol) glyceryl ether (random alkylene oxide derivative) 92 g of glycerin and 18 g of potassium hydroxide as a catalyst were charged into the autoclave, and the air in the autoclave was replaced with dry nitrogen. Thereafter, the catalyst was completely dissolved at 140 ° C. with stirring. Next, a mixture of 2160 g of butylene oxide and 1320 g of ethylene oxide was dropped with a dropping device and stirred for 2 hours. Next, 400 g of potassium hydroxide was charged and the inside of the system was replaced with dry nitrogen, and then 300 g of methyl chloride was injected at a temperature of 80 to 130 ° C. and reacted for 5 hours. Thereafter, the reaction composition was taken out from the autoclave, neutralized with hydrochloric acid to adjust to pH 6 to 7, and treated at a reduced pressure of -0.088 MPa (gauge pressure) at 100 ° C for 1 hour in order to remove the contained water. Further, filtration was performed to remove the salt generated after the treatment, and a random alkylene oxide derivative was obtained.
Samples which were sampled and reacted before reacting with methyl chloride had a hydroxyl value of 47, the resulting random alkylene oxide derivative 5 compound had a hydroxyl value of 0.5, and the ratio of the number of hydrogen atoms to the number of terminal methyl groups was 0.011. The hydrogen atom is almost completely converted to a methyl group.

    Although the formulation example of the hair washing composition of this invention is given to the following, the technical scope of this invention is not limited by these. The following hair cleansing composition prepared by a conventional method is excellent in the feel of hair when dried after use, in particular smoothness and non-stiffness, and also has a foaming and cleaning effect on hair coated with a styling agent. It was good.

（上記式（ＩＶ）中、ａ＋ｃ＋ｅ＝３０、ｂ＋ｄ＋ｆ＝３０、Ｒ^１，Ｒ^２，Ｒ^３はＣ_４Ｈ_９であり、ＢＯはオキシブチレン基、ＥＯはオキシエチレン基を示す。）
ココイルメチルタウリンナトリウム ２０．０
ラウリン酸ジエタノールアミド ３．０
ラウリルジメチルアミノ酢酸ベタイン ４．０
エチレングリコールジステアレート ２．５
１，３−ブチレングリコール １．０
安息香酸ナトリウム ０．５
色剤 適 量
香料 適 量
精製水 残 余 Formulation Example 1: Hair Shampoo (Compounding ingredients) (mass%)
POB (30) POE (30) tributyl glyceryl ether 3.0

(In the above formula (IV), a + c + e = 30, b + d + f = 30, R ¹ , R ² and R ³ are C ₄ H ₉ , BO is an oxybutylene group, and EO is an oxyethylene group.)
Cocoyl methyl taurine sodium 20.0
Lauric acid diethanolamide 3.0
Lauryldimethylaminoacetic acid betaine 4.0
Ethylene glycol distearate 2.5
1,3-butylene glycol 1.0
Sodium benzoate 0.5
Colorant appropriate amount Fragrance appropriate amount Purified water residue

Formulation Example 2: Hair Shampoo (Compounding ingredients) (mass%)
POB (30) POE (30) Trimethyl glyceryl ether 8.0
(In the above formula (IV), a + c + e = 30, b + d + f = 30, R ¹ , R ² , and R ³ are CH ₃ , BO represents an oxybutylene group, and EO represents an oxyethylene group.)
Cocoyl methyl taurine sodium 12.0
Palm fatty acid amidopropyldimethylaminoacetic acid sodium betaine 7.0
Cationized cellulose ether 2.0
Colorant appropriate amount Fragrance appropriate amount Purified water residue

Formulation Example 3: Hair Shampoo (Compounding ingredients) (mass%)
POB (30) POE (35) triethyl glyceryl ether 7.0
(In the above formula (IV), a + c + e = 30, b + d + f = 30, R ¹ , R ² , and R ³ are C ₂ H ₅ , BO represents an oxybutylene group, and EO represents an oxyethylene group.)
Cocoyl Methyl Taurine Sodium 8.0
N-lauroyl-N'-carboxymethyl-N'-
(2-Hydroxyethyl) ethylenediamine sodium 8.0
Ethylene glycol distearate 2.5
Dipropylene glycol 3.0
Sodium benzoate 0.5
Perfume appropriate amount Purified water residue

Claims (4)

0.01 to 15% by mass of a block-type alkylene oxide derivative represented by the following formula (I), 0.1 to 20% by mass of sodium cocoylmethyl taurate, and an amidoamine represented by the following formula (II) or (IIII) A hair washing composition comprising 0.1 to 15% by mass of an amphoteric surfactant.

(In the formula, Y is a residue obtained by removing a hydroxyl group of a polyhydric alcohol having 3 to 6 hydroxyl groups, k is the number of hydroxyl groups of the polyhydric alcohol, EO is an oxyethylene group, and AO is an oxy of 3 to 6 carbon atoms. Each of which is added in the form of a block with an alkylene group, wherein a × k, b × k and c × k are the average number of moles of oxyethylene group, oxyalkylene group having 3 to 6 carbon atoms, and oxyethylene group, 0 ≦ a × k ≦ 100, 1 ≦ b × k ≦ 100, 0 ≦ c × k ≦ 100, where (a + c) × k> 1 In the formula (I), all oxyethylene groups and 3 to 3 carbon atoms The ratio of all oxyethylene groups in formula (I) to the total of 6 oxyalkylene groups is 10 to 80% by mass, and R is a hydrocarbon group having 1 to 4 carbon atoms.

(Wherein R ² represents a saturated or unsaturated hydrocarbon group having an average carbon number of 7 to 19; Z ¹ represents a hydrogen atom or (CH ₂ ) ₁ COOY ¹ (where Y ¹ represents an alkali metal, Represents an alkaline earth metal or an organic amine; l represents an integer of 1 to 3; M ² represents an alkali metal, an alkaline earth metal, or an organic amine; Represents an integer of ~ 3)

(Wherein R ³ represents a saturated or unsaturated hydrocarbon group having an average carbon number of 7 to 19; Z ² is a hydrogen atom or (CH ₂ ) _r COOY ² (where Y ² is an alkali metal, Represents an alkaline earth metal or an organic amine; r represents an integer of 1 to 3; R ⁴ represents a hydrogen atom or (CH ₂ ) _s COOY ³ (where Y ³ represents an alkali metal, an alkaline earth) It represents a kind metals or organic amines; s represents an an integer of 1 to 3); M ³ represents an alkali metal, an alkaline earth metal or organic amines; p, q is 1 to 3 Represents an integer.)   The hair washing composition according to claim 1, wherein the AO group of the block-type alkylene oxide derivative represented by the formula (I) is an oxybutylene group.   The hair washing composition according to claim 1 or 2, wherein a of the block-type alkylene oxide derivative represented by the formula (I) is 0, and the addition order of AO and EO is relative to Y in the formula. A hair washing composition characterized by being (AO)-(EO).   The hair washing composition according to any one of claims 1 to 3, wherein the hair washing composition is a hair shampoo.