JP2006306857A - Cosmetic base and cosmetic formulated therewith - Google Patents
Cosmetic base and cosmetic formulated therewith Download PDFInfo
- Publication number
- JP2006306857A JP2006306857A JP2006095003A JP2006095003A JP2006306857A JP 2006306857 A JP2006306857 A JP 2006306857A JP 2006095003 A JP2006095003 A JP 2006095003A JP 2006095003 A JP2006095003 A JP 2006095003A JP 2006306857 A JP2006306857 A JP 2006306857A
- Authority
- JP
- Japan
- Prior art keywords
- cosmetic
- group
- feeling
- oxyalkylene
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、化粧料用基剤およびこれを配合する化粧料に関する。 The present invention relates to a cosmetic base and a cosmetic containing the same.
化粧料は、近年の消費者の傾向から、保湿感の高く、かつさっぱりした感触のものが好まれる傾向がある。このため、保湿剤は化粧料になくてはならないものとなっているが、このような要求に応じることのできる保湿剤および化粧料はまだ十分には得られていないのが現状である。
例えば、グリセリン、プロピレングリコール、１，３−ブチレングリコールなどに代表される水溶性多価アルコールは優れた保湿感はあるものの、高濃度に配合するとべたつき感が大きくなる。これにすべすべ感を付与しようとしてトリグリセリドやシリコーン油などを配合する場合には、両者の相溶性が劣るため多量の乳化剤を必要とし、すべすべ感や保湿感が低下してしまう。
Cosmetics tend to be preferred to have a high moisturizing feeling and a refreshing feel due to consumer trends in recent years. For this reason, moisturizers are indispensable for cosmetics, but the present situation is that sufficient moisturizers and cosmetics that can meet such requirements have not yet been obtained.
For example, water-soluble polyhydric alcohols typified by glycerin, propylene glycol, 1,3-butylene glycol and the like have an excellent moisturizing feeling, but when mixed at a high concentration, the sticky feeling increases. When a triglyceride or silicone oil is blended in order to give a smooth feeling to this, a large amount of emulsifier is required because the compatibility between the two is poor, and the smooth feeling and moisturizing feeling are lowered.
そこで水溶性の基剤で保湿感、すべすべ感両者の特性をだすために、Ｎ−アセチル塩基性アミノ酸（例えば特許公報１）、ポリ―γ―グルタミン酸架橋体（例えば特許公報２）、ポリエチレングリコールジアルキルエーテル（例えば特許公報３）などを配合した化粧料が報告されているが、いずれも十分な効果が得られていないのが現状である。
また、従来の保湿用化粧料は、塗布している部分を石鹸などで洗い流した場合かさかさしてしまい、肌のうるおい感を維持するにはクリームなど別の保湿用化粧料を再塗布するなどして補わなければならなかった。
Therefore, N-acetyl basic amino acid (for example, Patent Publication 1), poly-γ-glutamic acid cross-linked product (for example, Patent Publication 2), polyethylene glycol dialkyl, in order to bring out both moisturizing feeling and smooth feeling with a water-soluble base. Cosmetics formulated with ether (for example, Japanese Patent Publication No. 3) have been reported, but none of them are effective enough.
Also, conventional moisturizing cosmetics become bulky when the applied part is washed away with soap, etc., and another moisturizing cosmetic such as cream is reapplied to maintain the moist feeling of the skin. I had to make up for it.
本発明の目的は、べたつかない優れた感触と保湿性の双方を有し、洗浄後もうるおいを保つ化粧料用基剤およびこれを配合する化粧料を提供することである。 An object of the present invention is to provide a cosmetic base having both excellent non-sticky feel and moisturizing property and keeping moisture after washing, and a cosmetic containing the same.
すなわち本発明は、以下に示されるものである。
（１）下記の式（Ｉ）で示されるアルキレンオキシド誘導体からなる化粧料用基剤。
Ｚ−｛Ｏ（ＡＯ）l（ＥＯ）m−（ＢＯ）nＲ｝a （Ｉ）
（式中、Ｚは３〜９個の水酸基を有する化合物の水酸基を除いた残基、ａは３〜９、ＡＯは炭素数３〜４のオキシアルキレン基、ＥＯはオキシエチレン基、ｌおよびｍはそれぞれ炭素数３〜４のオキシアルキレン基、オキシエチレン基の平均付加モル数で、１≦ｌ≦５０、１≦ｍ≦５０であり、ＡＯとＥＯとの重量比（ＡＯ／ＥＯ）は１／５〜５／１であり、ＡＯとＥＯはランダム状に付加している。ＢＯは炭素数４のオキシアルキレン基、ｎはその平均付加モル数で、０．５≦ｎ≦５、Ｒは炭素数１〜４の炭化水素基である。）
（２） 前記の化粧料用基剤を配合してなる化粧料。
（３） 化粧料用基剤を０．０５〜５０重量％、水溶性多価アルコールを０．０５〜５０重量％含有する前記の化粧料。
That is, the present invention is as follows.
(1) A cosmetic base comprising an alkylene oxide derivative represented by the following formula (I).
Z- {O (AO) l (EO) m- (BO) n R} a (I)
(Wherein Z is a residue excluding the hydroxyl group of the compound having 3 to 9 hydroxyl groups, a is 3 to 9, AO is an oxyalkylene group having 3 to 4 carbon atoms, EO is an oxyethylene group, l and m Are the average added mole numbers of oxyalkylene groups having 3 to 4 carbon atoms and oxyethylene groups, 1 ≦ l ≦ 50, 1 ≦ m ≦ 50, and the weight ratio of AO to EO (AO / EO) is 1. AO and EO are randomly added, BO is an oxyalkylene group having 4 carbon atoms, n is the average number of moles added, 0.5 ≦ n ≦ 5, R is (It is a hydrocarbon group having 1 to 4 carbon atoms.)
(2) A cosmetic comprising the cosmetic base described above.
(3) The cosmetic described above containing 0.05 to 50% by weight of a cosmetic base and 0.05 to 50% by weight of a water-soluble polyhydric alcohol.
本発明の化粧料用基剤は優れたすべすべ感、保湿感の両方の性質を有し、洗浄後もうるおいを保つ、化粧料に配合したときに最も効果的な性能を発現する化粧料用基剤である。この化粧料用基剤を配合した化粧料は、優れたすべすべ感、保湿感の両方の性質を有し、洗浄後もうるおいを保つ、非常に優れた化粧料である。 The cosmetic base of the present invention has both excellent smoothness and moisturizing properties, keeps moisture after washing, and exhibits the most effective performance when formulated in cosmetics. It is an agent. A cosmetic containing this cosmetic base is an excellent cosmetic that has both excellent smoothness and moisturizing properties and maintains moisture after washing.
式（Ｉ）で示されるアルキレンオキシド誘導体において、Ｚは３〜９個の水酸基を有する化合物の水酸基を除いた残基であり、ａはＺの化合物の水酸基の数であり３〜９である。３〜９個の水酸基を有する化合物としては、ａ＝３であればグリセリン、トリメチロールプロパン、ヘキシレングリコール、ａ＝４であればエリスリトール、ペンタエリスリトール、ソルビタン、アルキルグリコシド、ａ＝５であればキシリトール、ａ＝６であればジペンタエリスリトール、ソルビトール、イノシトール、ａ＝８であればショ糖、トレハロース、ａ＝９であればマルチトールが挙げられる。また、これらの混合物を用いても良い。好ましくはＺは３〜６個の水酸基を有する化合物の水酸基を除いた残基であり、ａは３〜６である。ａが２以下では十分な保湿感が得られず、ａが１０以上ではべたつき感が生じてしまう。 In the alkylene oxide derivative represented by the formula (I), Z is a residue excluding the hydroxyl group of the compound having 3 to 9 hydroxyl groups, and a is the number of hydroxyl groups of the compound of Z and 3 to 9. Compounds having 3 to 9 hydroxyl groups include glycerin, trimethylolpropane, hexylene glycol if a = 3, erythritol, pentaerythritol, sorbitan, alkylglycoside if a = 4, and a = 5 Xylitol, if a = 6, dipentaerythritol, sorbitol, inositol, if a = 8, sucrose, trehalose, if a = 9, maltitol. Moreover, you may use these mixtures. Z is preferably a residue excluding the hydroxyl group of the compound having 3 to 6 hydroxyl groups, and a is 3 to 6. When a is 2 or less, a sufficient moisturizing feeling cannot be obtained, and when a is 10 or more, a sticky feeling is generated.
ＡＯは炭素数３〜４のオキシアルキレン基であり、例として、オキシプロピレン基、オキシブチレン基、オキシイソブチレン基、オキシトリメチレン基、オキシテトラメチレン基などが挙げられる。好ましくは、オキシプロピレン基、オキシブチレン基、さらに好ましくはオキシプロピレン基である。
ｌはＡＯの平均付加モル数であり、１≦ｌ≦５０、好ましくは２≦ｌ≦２０である。ｍはＥＯの平均付加モル数であり、１≦ｍ≦５０、好ましくは２≦ｍ≦２０である。ＡＯが１より少ないとべたつき感を生じてしまい、５０を越えると保湿感が低下する。またＥＯが１より少ないと保湿感が落ち、５０を越えるとべたつき感が生じてしまう。
ＡＯとＥＯとの重量比（ＡＯ／ＥＯ）は１／５〜５／１であり、好ましくは１／４〜４／１である。１／５より小さいとべたつき感が生じてしまい、５／１より大きいと保湿感が低下してしまう。
ＡＯとＥＯの付加する順序はランダム状に付加しているものである。
ＢＯは炭素数４のオキシアルキレン基であり、例としてオキシブチレン基、オキシイソブチレン基、オキシテトラメチレン基などが挙げられる。好ましくはオキシブチレン基である。
ｎはＢＯの平均付加モル数であり、０．５≦ｎ≦５、好ましくは１≦ｎ≦３である。０．５より少ないとべたつき感が生じてしまい、５を越えると保湿感が低下してしまう。
また本発明のＡＯの平均付加モル数ｌとＢＯの平均付加モル数ｎとの合計は、好ましくは１．５≦ｌ＋ｎ≦５０、さらに好ましくは３≦ｌ＋ｎ≦３０である。
Ｒは炭素数１〜４の炭化水素基で、炭化水素基としては、メチル基、エチル基、ｎ−プロピル基、イソプロピル基、ｎ−ブチル基、ｓｅｃ−ブチル基、ｔｅｒｔ−ブチル基およびこれらの混合物などが挙げられる。好ましくはメチル基、エチル基である。炭素数５以上の炭化水素基では親水性が低下し、保湿感が低下する。
AO is an oxyalkylene group having 3 to 4 carbon atoms, and examples thereof include an oxypropylene group, an oxybutylene group, an oxyisobutylene group, an oxytrimethylene group, and an oxytetramethylene group. An oxypropylene group, an oxybutylene group, and more preferably an oxypropylene group.
l is the average added mole number of AO, and 1 ≦ l ≦ 50, preferably 2 ≦ l ≦ 20. m is an average added mole number of EO, and 1 ≦ m ≦ 50, preferably 2 ≦ m ≦ 20. If AO is less than 1, a sticky feeling is produced, and if it exceeds 50, the moisturizing feeling is lowered. If EO is less than 1, the moisturizing feeling is lowered, and if it exceeds 50, a sticky feeling is produced.
The weight ratio (AO / EO) between AO and EO is 1/5 to 5/1, preferably 1/4 to 4/1. When it is less than 1/5, a sticky feeling is produced, and when it is greater than 5/1, the moisturizing feeling is lowered.
The order in which AO and EO are added is randomly added.
BO is an oxyalkylene group having 4 carbon atoms, and examples thereof include an oxybutylene group, an oxyisobutylene group, and an oxytetramethylene group. An oxybutylene group is preferred.
n is the average added mole number of BO, and 0.5 ≦ n ≦ 5, preferably 1 ≦ n ≦ 3. If it is less than 0.5, a sticky feeling is produced, and if it exceeds 5, the moisturizing feeling is lowered.
The sum of the average added mole number 1 of AO and the average added mole number BO of the present invention is preferably 1.5 ≦ l + n ≦ 50, more preferably 3 ≦ l + n ≦ 30.
R is a hydrocarbon group having 1 to 4 carbon atoms. Examples of the hydrocarbon group include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, sec-butyl group, tert-butyl group, and these. A mixture etc. are mentioned. A methyl group and an ethyl group are preferred. When the hydrocarbon group has 5 or more carbon atoms, the hydrophilicity is lowered and the moisturizing feeling is lowered.
本発明の式（Ｉ）で示されるアルキレンオキシド誘導体は、公知の方法で製造することができる。例えば、３個以上の水酸基を有している化合物にエチレンオキシドおよび炭素数３〜４のアルキレンオキシドを付加重合した後、炭素数４のアルキレンオキシドを反応させ、さらにその後ハロゲン化アルキルをアルカリ触媒の存在下にエーテル反応させることによって得られる。
また本発明の化粧料用基剤を配合してなる化粧料の形態は、特に限定されず、水性化粧料、油中水型または水中油型の乳化化粧料、油性化粧料のいずれでも良く、シャンプー、リンス、ボディソープ、洗顔剤、化粧水、乳液、クリーム、整髪料、口紅、育毛剤などさまざまな形態でも良い。
The alkylene oxide derivative represented by the formula (I) of the present invention can be produced by a known method. For example, after addition polymerization of ethylene oxide and a C3-4 alkylene oxide to a compound having 3 or more hydroxyl groups, the C4 alkylene oxide is reacted, and then an alkyl halide is present in the presence of an alkali catalyst. Obtained by ether reaction below.
Further, the form of the cosmetic comprising the cosmetic base of the present invention is not particularly limited, and may be any of a water-based cosmetic, a water-in-oil or oil-in-water emulsified cosmetic, and an oily cosmetic. Various forms such as shampoo, rinse, body soap, facial cleanser, lotion, milky lotion, cream, hair conditioner, lipstick, hair restorer may be used.
本発明の化粧料中への化粧料用基剤の配合量は特に限定されないが、通常０．０１〜７０重量％配合される。
また、化粧料として、水溶性多価アルコールを配合することによりさらに感触と保湿性の双方が良好なものとなる。好ましくは本発明の基剤０．０５〜５０重量％と水溶性多価アルコールを０．０５〜５０重量％、さらに好ましくは本発明の基剤０．１〜２５重量％と水溶性多価アルコールを０．１〜２５重量％、よりさらに好ましくは本発明の基剤１〜１０重量％と水溶性多価アルコールを１〜１０重量％配合する組み合わせがより効果的である。
水溶性多価アルコールとは分子内に水酸基を２個以上有する水溶性の化合物であり、例えば、プロピレングリコール、ジプロピレングリコール、イソプレングリコール、１，３−ブチレングリコール、グリセリン、ジグリセリン、ポリエチレングリコール、ソルビトール、マルチトール、メチルグルコシド、アルキルグルコシドおよびこれらのアルキレンオキシド付加物などが挙げられる。このうちジプロピレングリコール、イソプレングリコール、１，３−ブチレングリコール、グリセリン、ジグリセリン、ポリエチレングリコール、メチルグルコシド及びこれらのエチレンオキシド付加物が好ましい。
なお、本発明の化粧料には、他の成分を本発明の性能を損なわない範囲で含有することも可能である。例えば、低級アルコール、炭化水素系油、天然油脂、合成トリグリセライド、エステル油、ロウ類、シリコーン誘導体、油性基剤、陰イオン性界面活性剤、両性界面活性剤、非イオン性界面活性剤、陽イオン性界面活性剤、半極性界面活性剤、水溶性高分子、有機または無機塩類、ｐＨ調整剤、殺菌剤、キレート剤、抗酸化剤、紫外線吸収剤、ビタミン類、動植物由来の天然エキス、色素、顔料、香料などが挙げられる。
Although the compounding quantity of the base for cosmetics in the cosmetics of this invention is not specifically limited, 0.01-70 weight% is normally mix | blended.
In addition, by blending a water-soluble polyhydric alcohol as a cosmetic, both the feel and moisture retention are further improved. Preferably 0.05 to 50% by weight of the base of the present invention and 0.05 to 50% by weight of water-soluble polyhydric alcohol, more preferably 0.1 to 25% by weight of the base of the present invention and water-soluble polyhydric alcohol 0.1 to 25% by weight, more preferably 1 to 10% by weight of the base of the present invention and 1 to 10% by weight of a water-soluble polyhydric alcohol is more effective.
The water-soluble polyhydric alcohol is a water-soluble compound having two or more hydroxyl groups in the molecule. For example, propylene glycol, dipropylene glycol, isoprene glycol, 1,3-butylene glycol, glycerin, diglycerin, polyethylene glycol, Examples include sorbitol, maltitol, methyl glucoside, alkyl glucoside, and alkylene oxide adducts thereof. Of these, dipropylene glycol, isoprene glycol, 1,3-butylene glycol, glycerin, diglycerin, polyethylene glycol, methyl glucoside and ethylene oxide adducts thereof are preferred.
The cosmetic of the present invention can contain other components as long as the performance of the present invention is not impaired. For example, lower alcohols, hydrocarbon oils, natural fats and oils, synthetic triglycerides, ester oils, waxes, silicone derivatives, oily bases, anionic surfactants, amphoteric surfactants, nonionic surfactants, cations Surfactants, semipolar surfactants, water-soluble polymers, organic or inorganic salts, pH adjusters, fungicides, chelating agents, antioxidants, UV absorbers, vitamins, natural extracts derived from animals and plants, pigments, A pigment, a fragrance | flavor, etc. are mentioned.
合成例１ ポリオキシブチレン（５モル；ｎ＝１．７）ポリオキシエチレン（１０モル；ｎ＝１．７）ポリオキシプロピレン（１０モル；ｎ＝１．７）トリメチルグリセリンエーテルの合成
グリセリン９２ｇと触媒として水酸化カリウム６ｇをオートクレーブ中に仕込み、オートクレーブ中の空気を乾燥窒素で置換した後、攪拌しながら１４０℃で触媒を完全に溶解した。次に滴下装置によりエチレンオキシド４４０ｇとプロピレンオキシド５８０ｇの混合物を滴下させ、２時間攪拌した。さらに滴下装置によりブチレンオキシド３６０ｇを滴下させ、２時間攪拌し反応させた。次に、水酸化カリウム３３６ｇを仕込み、系内を乾燥窒素で置換した後、塩化メチル３００ｇを温度８０〜１３０℃で圧入し５時間反応させた。その後オートクレーブより反応組成物を取り出し、塩酸で中和してｐＨ６〜７とし、含有する水分を除去するため減圧−０．０９５ＭＰａ(ゲージ圧)、１００℃で１時間処理した。さらに処理後生成した塩を除去するため濾過を行い、化合物１の基剤を得た。
塩化メチルを反応させる前にサンプリングし、精製したものの水酸基価が１１９、化合物１の水酸基価が５であり、ほぼ水素原子がメチル基に変換されている。
合成例２〜９
合成例１と同様に、表１に示す化合物２〜９の合成を行った。
Synthesis Example 1 Synthesis of polyoxybutylene (5 mol; n = 1.7) polyoxyethylene (10 mol; n = 1.7) polyoxypropylene (10 mol; n = 1.7) trimethylglycerin ether As a catalyst, 6 g of potassium hydroxide was charged into an autoclave, the air in the autoclave was replaced with dry nitrogen, and the catalyst was completely dissolved at 140 ° C. with stirring. Next, a mixture of 440 g of ethylene oxide and 580 g of propylene oxide was dropped with a dropping device and stirred for 2 hours. Further, 360 g of butylene oxide was dropped with a dropping device, and the mixture was stirred for 2 hours to be reacted. Next, after charging 336 g of potassium hydroxide and replacing the system with dry nitrogen, 300 g of methyl chloride was injected at a temperature of 80 to 130 ° C. and reacted for 5 hours. Thereafter, the reaction composition was taken out from the autoclave, neutralized with hydrochloric acid to pH 6 to 7, and treated at a reduced pressure of -0.095 MPa (gauge pressure) at 100 ° C for 1 hour in order to remove the contained water. Further, filtration was performed to remove the salt produced after the treatment, and a base of Compound 1 was obtained.
Samples that were sampled and reacted before reacting with methyl chloride had a hydroxyl value of 119 and compound 1 had a hydroxyl value of 5, and almost all hydrogen atoms were converted to methyl groups.
Synthesis Examples 2-9
In the same manner as in Synthesis Example 1, compounds 2 to 9 shown in Table 1 were synthesized.
実施例１〜６および比較例１〜８
各化粧料用基剤を用いて下記に示す試験を行った。結果を表１に示す。各配合量は重量％である。
（官能評価）
化合物１０重量％水溶液を作成し、それを１０人の専門パネラーを用いてべたつき感のなさ（すべすべ感）と保湿感の評価を行った。評価方法は、上腕部を洗浄した後に試料を塗布し、塗布直後〜３０分後のべたつき感のなさと保湿感について５段階評価した合計値を採用した。３５点以上を良好と判断した。
べたつき感のなさ（すべすべ感）
５ ： のびが非常によく、肌をこすったとき、ひっかからずに非常に軽い感触
４ ： のびがよく、肌をこすったとき、ひっかからず軽い感触
３ ： のびがやや悪く、肌をこすったとき、少しひっかかる感触
２ ： のびが悪く、肌をこすったとき、ひっかかり重い感触
１ ： のびが非常に悪く、肌をこすったとき、ひっかかり非常に重い感触
保湿感
５ ： かさつきが全くなく、十分うるおっている感触
４ ： かさつきがなく、うるおっている感触
３ ： かさつきが若干あり、うるおいが少し足りない感触
２ ： かさつきがあり、うるおいが足りない感触
１ ： かさつきがひどく、うるおいが十分足りない感触
実施例１〜６より本発明の基剤は、べたつき感のなさ、保湿感の双方の点数を満たすものである。しかし比較例１〜８は、２つの性質を同時に満たすものはない。
Examples 1-6 and Comparative Examples 1-8
The following tests were conducted using each cosmetic base. The results are shown in Table 1. Each compounding amount is% by weight.
(sensory evaluation)
A 10% by weight aqueous solution of the compound was prepared, and the non-sticky feeling (smooth feeling) and the moisturizing feeling were evaluated using 10 professional panelists. As the evaluation method, a sample was applied after washing the upper arm, and a total value evaluated on a five-stage basis for the feeling of stickiness and moisturizing feeling immediately after application to 30 minutes was adopted. A score of 35 or more was judged good.
No stickiness (smooth feeling)
5: Very good spread, rubbed skin, very light feel without scratching 4: Good spread, rubbed skin, light touch without scratching 3: When slightly rubbed, rubbed skin Slightly squeezed feel 2: Slowly rubbed and rubbed skin, heavy squeaky feel 1: Slowly stretched, rubbed skin, squeezed and very heavy feel 5 Feeling 4 ： Feeling that it is not bulky and moist 3 ： Feeling that it is slightly moisturized and a little lacking in moisture 2 ： Feeling that it is bulky and lacking in moisture 1: Severely moisturized and enough moisture No feel From Examples 1 to 6, the base of the present invention satisfies both the points of no stickiness and moisturizing feeling. However, Comparative Examples 1 to 8 do not satisfy two properties at the same time.
実施例７〜１５および比較例９〜１５
化合物１〜９、グリセリン、ソルビトール、ポリエチレングリコール（分子量３００）、リジン塩酸塩のそれぞれを水相部に配合して、以下の組成からなる基剤のうち油相部を８０℃に加温し均一に溶解した後、攪拌しながら水相部を同温度で徐々に添加し撹拌後、４０℃まで冷却して乳液を作製し、実施例１と同様の評価を行った。結果を表２に示す。
油相部：
ベヘニルアルコール ２．０重量％
スクワラン ６．０重量％
ミリスチン酸イソプロピル ０．５重量％
モノステアリン酸ソルビタン １．０重量％
モノステアリン酸グリセリン １．０重量％
ポリオキシエチレン（２０モル）モノドデシルエーテル １．５重量％
香料 適量
防腐剤 適量
水相部：
保湿剤 表２参照
水溶性多価アルコール 表２参照
精製水 残部（全体が１００になるように）
Examples 7 to 15 and Comparative Examples 9 to 15
Each of compounds 1-9, glycerin, sorbitol, polyethylene glycol (molecular weight 300), and lysine hydrochloride are blended in the aqueous phase, and the oil phase of the base comprising the following composition is heated to 80 ° C to be uniform. Then, the aqueous phase portion was gradually added at the same temperature while stirring, and the mixture was stirred and then cooled to 40 ° C. to prepare an emulsion. The same evaluation as in Example 1 was performed. The results are shown in Table 2.
Oil phase:
Behenyl alcohol 2.0% by weight
Squalane 6.0% by weight
Isopropyl myristate 0.5% by weight
Sorbitan monostearate 1.0% by weight
1.0% by weight of glyceryl monostearate
Polyoxyethylene (20 mol) monododecyl ether 1.5% by weight
Perfume appropriate amount Preservative appropriate amount Aqueous part:
Moisturizer See Table 2 Water-soluble polyhydric alcohol See Table 2 Purified water The remainder (the whole is 100)
作製した乳液について、べたつき感のなさ（すべすべ感）、保湿感については前記の方法で評価を行い、洗浄後の評価は以下の方法で評価を行った。
（洗浄後評価）
１０人の専門パネラーを用いて上記処方品で官能評価をおこなった後、石鹸で上腕部を洗浄１５分後の感触について５段階評価した合計値を採用した。３５点以上を良好と判断した。
洗浄後の感触
５ ： 肌にかさつきがほとんどなく、うるおいがある感じ
４ ： 肌にかさつきがなく、若干うるおいがある感じ
３ ： 肌に若干かさつきがあるが、肌荒れまでにいたらない感じ
２ ： 肌に少しかさつきがあり、肌荒れしそうな感じ
１ ： 肌に非常にかさつきがあり、肌荒れしている感じ
About the produced emulsion, the non-sticky feeling (smooth feeling) and the moisturizing feeling were evaluated by the above methods, and the evaluation after washing was evaluated by the following methods.
(Evaluation after cleaning)
After performing sensory evaluation with the above-mentioned prescription product using 10 professional panelists, the total value evaluated for the feel after washing the upper arm with soap for 15 minutes was adopted. A score of 35 or more was judged good.
Feeling after washing 5: Feeling that there is almost no moisture on the skin 4: Feeling that there is no moisture on the skin and that it is slightly moisturized 3: Feeling that the skin is slightly moistened but not rough enough 2 : The skin feels somewhat rough and feels rough 1: The skin is very rough and feels rough
前記の基剤単品の評価結果と同様に、実施例７〜１５より本発明の化粧料は、べたつき感のなさ、保湿感、洗浄後の感触のすべてを満たすものである。しかし比較例９〜１５は、３つの性質を同時に満たすものはない。 Similar to the evaluation results of the above-mentioned base alone, the cosmetics of the present invention satisfy all of the non-sticky feeling, the moisturizing feeling and the feeling after washing from Examples 7 to 15. However, Comparative Examples 9 to 15 do not satisfy the three properties at the same time.
Claims (3)
Ｚ−｛Ｏ（ＡＯ）l（ＥＯ）m−（ＢＯ）nＲ｝a （Ｉ）
（式中、Ｚは３〜９個の水酸基を有する化合物の水酸基を除いた残基、ａは３〜９、ＡＯは炭素数３〜４のオキシアルキレン基、ＥＯはオキシエチレン基、ｌおよびｍはそれぞれ炭素数３〜４のオキシアルキレン基、オキシエチレン基の平均付加モル数で、１≦ｌ≦５０、１≦ｍ≦５０であり、ＡＯとＥＯとの重量比（ＡＯ／ＥＯ）は１／５〜５／１であり、ＡＯとＥＯはランダム状に付加している。ＢＯは炭素数４のオキシアルキレン基、ｎはその平均付加モル数で、０．５≦ｎ≦５、Ｒは炭素数１〜４の炭化水素基である。） A cosmetic base comprising an alkylene oxide derivative represented by the following formula (I):
Z- {O (AO) l (EO) m- (BO) n R} a (I)
(Wherein Z is a residue excluding the hydroxyl group of the compound having 3 to 9 hydroxyl groups, a is 3 to 9, AO is an oxyalkylene group having 3 to 4 carbon atoms, EO is an oxyethylene group, l and m Are the average added mole numbers of oxyalkylene groups having 3 to 4 carbon atoms and oxyethylene groups, 1 ≦ l ≦ 50, 1 ≦ m ≦ 50, and the weight ratio of AO to EO (AO / EO) is 1. AO and EO are randomly added, BO is an oxyalkylene group having 4 carbon atoms, n is the average number of moles added, 0.5 ≦ n ≦ 5, R is (It is a hydrocarbon group having 1 to 4 carbon atoms.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006095003A JP4760489B2 (en) | 2005-03-31 | 2006-03-30 | Cosmetic base and cosmetic comprising the same |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005101877 | 2005-03-31 | ||
| JP2005101877 | 2005-03-31 | ||
| JP2006095003A JP4760489B2 (en) | 2005-03-31 | 2006-03-30 | Cosmetic base and cosmetic comprising the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006306857A true JP2006306857A (en) | 2006-11-09 |
| JP4760489B2 JP4760489B2 (en) | 2011-08-31 |
Family
ID=37474149
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006095003A Active JP4760489B2 (en) | 2005-03-31 | 2006-03-30 | Cosmetic base and cosmetic comprising the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4760489B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007136067A1 (en) * | 2006-05-23 | 2007-11-29 | Shiseido Company Ltd. | External preparation for skin |
| WO2008041623A1 (en) * | 2006-09-29 | 2008-04-10 | Shiseido Company Ltd. | External preparation for skin and cleansing agent for skin |
| JP2008133216A (en) * | 2006-11-28 | 2008-06-12 | Shiseido Co Ltd | Hair conditioning composition |
| JP2008133214A (en) * | 2006-11-28 | 2008-06-12 | Shiseido Co Ltd | Hair-cleansing composition |
| JP2008303203A (en) * | 2007-05-08 | 2008-12-18 | Naris Cosmetics Co Ltd | Cosmetic |
| JP2009143816A (en) * | 2007-12-11 | 2009-07-02 | Shiseido Co Ltd | Skin care preparation |
| JP2013100241A (en) * | 2011-11-08 | 2013-05-23 | Nof Corp | Cosmetic |
| JP2013189392A (en) * | 2012-03-13 | 2013-09-26 | Nof Corp | Cosmetic |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5315435A (en) * | 1976-07-23 | 1978-02-13 | Nippon Oil & Fats Co Ltd | Hair dressing |
| JPS55118411A (en) * | 1979-03-07 | 1980-09-11 | Asahi Denka Kogyo Kk | Hairdressing composition |
| JPS5813685A (en) * | 1981-07-17 | 1983-01-26 | Nippon Oil & Fats Co Ltd | Anti-fogging agent |
| JPH01117813A (en) * | 1987-10-30 | 1989-05-10 | Nippon Oil & Fats Co Ltd | Cosmetic |
| JPH0859818A (en) * | 1994-08-23 | 1996-03-05 | Nippon Oil & Fats Co Ltd | Glycerol polyalkylene glycol ether derivative |
| JP2000154161A (en) * | 1998-11-19 | 2000-06-06 | Nof Corp | Oligoalkyloxirane derivative, its production and use |
| US6362233B1 (en) * | 2001-01-02 | 2002-03-26 | Phoenix Research Corporation | Methoxy capped alkoxylated glycerin compounds |
| JP2002179712A (en) * | 2000-12-15 | 2002-06-26 | Asahi Denka Kogyo Kk | Emulsifier for water-in-oil(w/o) type emulsion polymerization and dispersant for suspension polymerization |
-
2006
- 2006-03-30 JP JP2006095003A patent/JP4760489B2/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5315435A (en) * | 1976-07-23 | 1978-02-13 | Nippon Oil & Fats Co Ltd | Hair dressing |
| JPS55118411A (en) * | 1979-03-07 | 1980-09-11 | Asahi Denka Kogyo Kk | Hairdressing composition |
| JPS5813685A (en) * | 1981-07-17 | 1983-01-26 | Nippon Oil & Fats Co Ltd | Anti-fogging agent |
| JPH01117813A (en) * | 1987-10-30 | 1989-05-10 | Nippon Oil & Fats Co Ltd | Cosmetic |
| JPH0859818A (en) * | 1994-08-23 | 1996-03-05 | Nippon Oil & Fats Co Ltd | Glycerol polyalkylene glycol ether derivative |
| JP2000154161A (en) * | 1998-11-19 | 2000-06-06 | Nof Corp | Oligoalkyloxirane derivative, its production and use |
| JP2002179712A (en) * | 2000-12-15 | 2002-06-26 | Asahi Denka Kogyo Kk | Emulsifier for water-in-oil(w/o) type emulsion polymerization and dispersant for suspension polymerization |
| US6362233B1 (en) * | 2001-01-02 | 2002-03-26 | Phoenix Research Corporation | Methoxy capped alkoxylated glycerin compounds |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007136067A1 (en) * | 2006-05-23 | 2007-11-29 | Shiseido Company Ltd. | External preparation for skin |
| JP5461010B2 (en) * | 2006-05-23 | 2014-04-02 | 株式会社 資生堂 | Topical skin preparation |
| WO2008041623A1 (en) * | 2006-09-29 | 2008-04-10 | Shiseido Company Ltd. | External preparation for skin and cleansing agent for skin |
| JP2008133216A (en) * | 2006-11-28 | 2008-06-12 | Shiseido Co Ltd | Hair conditioning composition |
| JP2008133214A (en) * | 2006-11-28 | 2008-06-12 | Shiseido Co Ltd | Hair-cleansing composition |
| JP2008303203A (en) * | 2007-05-08 | 2008-12-18 | Naris Cosmetics Co Ltd | Cosmetic |
| JP2009143816A (en) * | 2007-12-11 | 2009-07-02 | Shiseido Co Ltd | Skin care preparation |
| JP2013100241A (en) * | 2011-11-08 | 2013-05-23 | Nof Corp | Cosmetic |
| JP2013189392A (en) * | 2012-03-13 | 2013-09-26 | Nof Corp | Cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4760489B2 (en) | 2011-08-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4736134B2 (en) | Cosmetic base and cosmetic comprising the same | |
| JP4736112B2 (en) | Cosmetic base material and cosmetic comprising the same | |
| JP4760489B2 (en) | Cosmetic base and cosmetic comprising the same | |
| JP4747075B2 (en) | Cosmetics and external preparations | |
| JP2003113023A (en) | Base for skin care preparation and cosmetic formulated with the same | |
| JP5850394B2 (en) | Cosmetics | |
| JP4985017B2 (en) | Nonionic surfactant and cosmetic comprising the same | |
| JP4736113B2 (en) | Cosmetic base and cosmetic comprising the same | |
| JP2012207000A (en) | Oil-in-water cosmetic | |
| JP2006315986A (en) | Hair cosmetic | |
| JP2008247859A (en) | Cosmetic composition | |
| WO2019188119A1 (en) | Hair cosmetic | |
| JP2002161020A (en) | Foamy cosmetic | |
| JP4005933B2 (en) | Cosmetics containing silicone | |
| JP4680799B2 (en) | Oil-based cleansing composition | |
| JPWO2019187703A1 (en) | Underwater oil drop type fine emulsion type cosmetics | |
| JP4400215B2 (en) | Cosmetics and hair cosmetics containing novel polymeric surfactants | |
| JP2022067636A (en) | Cosmetic base and cosmetics | |
| JP4045885B2 (en) | Novel cosmetic materials and cosmetics containing the same | |
| JP5807514B2 (en) | Hair cosmetics | |
| JP6784935B2 (en) | Oil-in-water UV protection cosmetic composition | |
| JPH11193214A (en) | Cleansing cosmetic | |
| JP4320191B2 (en) | Cleaning composition for applicator | |
| FR2639635A1 (en) | AMPHOTERIC SURFACTANTS CONTAINING ALKYLENE OXIDE | |
| JP2017148774A (en) | Silicone modifier, surface active agent, and emulsion composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20090311 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101026 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20101222 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110405 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110413 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110510 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110523 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140617 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4760489 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |