JP2008079328A5 - - Google Patents

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JP2008079328A5
JP2008079328A5 JP2007265981A JP2007265981A JP2008079328A5 JP 2008079328 A5 JP2008079328 A5 JP 2008079328A5 JP 2007265981 A JP2007265981 A JP 2007265981A JP 2007265981 A JP2007265981 A JP 2007265981A JP 2008079328 A5 JP2008079328 A5 JP 2008079328A5
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thin film
piezoelectric thin
layer
ruthenium
aluminum
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JP2007265981A
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JP2008079328A (en
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Priority to JP2007265981A priority Critical patent/JP2008079328A/en
Priority claimed from JP2007265981A external-priority patent/JP2008079328A/en
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Claims (9)

基板の第1の面上に形成された圧電薄膜と、該圧電薄膜を挟むように形成された下部電極及び上部電極とを有する圧電薄膜共振子であって、
前記圧電薄膜が窒化アルミニウムで形成され、
前記上部電極及び下部電極はそれぞれルテニウム又はルテニウム合金の層を含み、
前記下部電極には、その下に形成された空隙に全体が露出しているとともに、アルミニウム(Al),銅(Cu)若しくはクロム(Cr)の純金属、又はアルミニウム(Al),銅(Cu)若しくはクロム(Cr)の合金、又はアルミニウム(Al),銅(Cu)若しくはクロム(Cr)の酸化物、又はアルミニウム(Al),銅(Cu)若しくはクロム(Cr)の窒化物による薄膜層が形成されており、前記下部電極は前記空隙に露出していないことを特徴とする圧電薄膜共振子。
A piezoelectric thin film resonator having a piezoelectric thin film formed on a first surface of a substrate, and a lower electrode and an upper electrode formed so as to sandwich the piezoelectric thin film,
The piezoelectric thin film is formed of aluminum nitride;
Each of the upper and lower electrodes includes a layer of ruthenium or ruthenium alloy,
The lower electrode is entirely exposed in the gap formed thereunder, and is pure metal of aluminum (Al), copper (Cu) or chromium (Cr), or aluminum (Al), copper (Cu). Alternatively, a thin film layer is formed of an alloy of chromium (Cr), an oxide of aluminum (Al), copper (Cu) or chromium (Cr), or a nitride of aluminum (Al), copper (Cu) or chromium (Cr). The piezoelectric thin film resonator is characterized in that the lower electrode is not exposed to the gap .
前記上部電極と下部電極はそれぞれルテニウム合金の層を含むことを特徴とする請求項記載の圧電薄膜共振子。 The piezoelectric thin-film resonator as claimed in claim 1, wherein the upper electrode and the lower electrode comprising a layer of each ruthenium alloy. 前記圧電薄膜を形成する窒化アルミニウムが(002)方向を主軸とする配向性を有することを特徴とする請求項1又は2記載の圧電薄膜共振子。 3. The piezoelectric thin film resonator according to claim 1, wherein the aluminum nitride forming the piezoelectric thin film has an orientation with a (002) direction as a main axis. 前記ルテニウム又はルテニウム合金の層が(002)方向を主軸とする配向性を有することを特徴とする請求項1又は2項記載の圧電薄膜共振子。 The ruthenium or piezoelectric thin-film resonator as claimed in claim 1 or 2, wherein, wherein the having orientation layer of ruthenium alloy has a main axis (002) direction. 前記下部電極及び上部電極の膜厚の和d1と前記圧電薄膜の膜厚d2との比d1/d2が1/12以上1以下であることを特徴とする請求項1又は2記載の圧電薄膜共振子。 3. The piezoelectric thin film resonance according to claim 1, wherein a ratio d1 / d2 between a sum d1 of film thicknesses of the lower electrode and the upper electrode and a film thickness d2 of the piezoelectric thin film is 1/12 or more and 1 or less. Child. 基板上に下部電極を形成する第1の工程と、前記下部電極を覆うように前記基板上に窒化アルミニウムの圧電薄膜を形成する第2の工程と、前記圧電薄膜上に上部電極を形成する第3の工程とを有する圧電薄膜共振子の製造方法であって、
前記第1の工程は、アルミニウム(Al),銅(Cu)若しくはクロム(Cr)の純金属、又はアルミニウム(Al),銅(Cu)若しくはクロム(Cr)の合金、又はアルミニウム(Al),銅(Cu)若しくはクロム(Cr)の酸化物、又はアルミニウム(Al),銅(Cu)若しくはクロム(Cr)の窒化物による薄膜層と、該薄膜層上にルテニウム又はルテニウム合金の層を含む前記下部電極を形成する工程を含み、
前記第3の工程は、ルテニウム又はルテニウム合金の層を含む前記上部電極を形成する工程を含み、
前記製造方法は更に、前記下部電極の下に設けられた前記薄膜層全体が露出する空隙を形成する工程を含むことを特徴とする圧電薄膜共振子の製造方法。
A first step of forming a lower electrode on the substrate; a second step of forming a piezoelectric thin film of aluminum nitride on the substrate so as to cover the lower electrode; and a second step of forming an upper electrode on the piezoelectric thin film. A method of manufacturing a piezoelectric thin film resonator having three steps,
The first step is a pure metal of aluminum (Al), copper (Cu) or chromium (Cr), an alloy of aluminum (Al), copper (Cu) or chromium (Cr), or aluminum (Al), copper The lower part including a thin film layer made of an oxide of (Cu) or chromium (Cr) or a nitride of aluminum (Al), copper (Cu) or chromium (Cr), and a layer of ruthenium or a ruthenium alloy on the thin film layer Forming an electrode,
The third step includes forming the upper electrode including a layer of ruthenium or a ruthenium alloy,
The method for manufacturing a piezoelectric thin film resonator further includes a step of forming a void in which the entire thin film layer provided under the lower electrode is exposed.
前記第1の工程は、(002)方向を主軸とする配向性を有する前記ルテニウム又はルテニウム合金の層を形成する工程を含み、
前記第2の工程は、(002)方向を主軸とする配向性を有する前記窒化アルミニウムの層を形成する工程を含むことを特徴とする請求項記載の圧電薄膜共振子の製造方法。
The first step includes a step of forming a layer of the ruthenium or ruthenium alloy having orientation with a (002) direction as a main axis,
7. The method of manufacturing a piezoelectric thin film resonator according to claim 6, wherein the second step includes a step of forming the aluminum nitride layer having an orientation with a (002) direction as a main axis.
前記第1の工程は、スパッタ圧力が0.5Pa以上のスパッタリング方法を用いて前記ルテニウム又はルテニウム合金の層を形成することを特徴とする請求項6又は7記載の圧電薄膜共振子の製造方法。 8. The method of manufacturing a piezoelectric thin film resonator according to claim 6, wherein the first step forms the ruthenium or ruthenium alloy layer by using a sputtering method having a sputtering pressure of 0.5 Pa or more. 前記空隙を形成する工程は、前記下部電極の全体が前記空隙に露出するように前記下部電極を形成することを特徴とする請求項6から8のいずれか一項記載の圧電薄膜共振子の製造方法。 9. The method of manufacturing a piezoelectric thin film resonator according to claim 6 , wherein the step of forming the gap forms the lower electrode so that the entire lower electrode is exposed to the gap. Method.
JP2007265981A 2007-10-12 2007-10-12 Piezoelectric thin film resonator and its manufacturing method Pending JP2008079328A (en)

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JP2008079328A5 true JP2008079328A5 (en) 2009-07-09

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JP5322597B2 (en) * 2008-11-13 2013-10-23 太陽誘電株式会社 Resonator, filter, duplexer and electronic device

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JP3672115B2 (en) * 1995-09-19 2005-07-13 富士通株式会社 Thin film forming method and semiconductor device manufacturing method
JP3489343B2 (en) * 1996-07-30 2004-01-19 松下電工株式会社 Method for manufacturing semiconductor device
KR100765682B1 (en) * 1998-06-19 2007-10-11 가부시키가이샤 히타치세이사쿠쇼 Semiconductor device and production method thereof
JP2000357931A (en) * 1999-06-16 2000-12-26 Victor Co Of Japan Ltd Manufacture of composite piezoelectric oscillator
JP2001111136A (en) * 1999-10-08 2001-04-20 Fujitsu Ltd Direction-of-magnetization controlled film and magnetoresistance effect-type sensor using the same
JP2001168675A (en) * 1999-12-08 2001-06-22 Mitsubishi Electric Corp Piezoelectric resonator, piezoelectric oscillator using this and method for manufacturing piezoelectric resonator
JP2001250995A (en) * 2000-03-07 2001-09-14 Mitsubishi Electric Corp Piezoelectric thin-film element
JP2001251159A (en) * 2000-03-08 2001-09-14 Mitsubishi Electric Corp Thin film piezoelectric element and its manufacturing method
US6472954B1 (en) * 2001-04-23 2002-10-29 Agilent Technologies, Inc. Controlled effective coupling coefficients for film bulk acoustic resonators
JP2003046160A (en) * 2001-04-26 2003-02-14 Matsushita Electric Ind Co Ltd Piezoelectric element, actuator, and ink jet head
JP3953315B2 (en) * 2001-12-26 2007-08-08 宇部興産株式会社 Aluminum nitride thin film-metal electrode laminate and thin film piezoelectric resonator using the same
JP3954395B2 (en) * 2001-10-26 2007-08-08 富士通株式会社 Piezoelectric thin film resonator, filter, and method of manufacturing piezoelectric thin film resonator
JP2005073175A (en) * 2003-08-27 2005-03-17 Fujitsu Media Device Kk Piezoelectric thin film resonator, and its manufacturing method

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