JP2008050280A - Aqueous hair cosmetic - Google Patents
Aqueous hair cosmetic Download PDFInfo
- Publication number
- JP2008050280A JP2008050280A JP2006226043A JP2006226043A JP2008050280A JP 2008050280 A JP2008050280 A JP 2008050280A JP 2006226043 A JP2006226043 A JP 2006226043A JP 2006226043 A JP2006226043 A JP 2006226043A JP 2008050280 A JP2008050280 A JP 2008050280A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- group
- hair
- alkyl
- hair cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000004209 hair Anatomy 0.000 title claims abstract description 81
- 239000002537 cosmetic Substances 0.000 title claims abstract description 31
- -1 fatty acid ester Chemical class 0.000 claims abstract description 43
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 34
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 26
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 15
- 239000000194 fatty acid Substances 0.000 claims abstract description 15
- 229930195729 fatty acid Natural products 0.000 claims abstract description 15
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 13
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 8
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 3
- 125000002091 cationic group Chemical group 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 22
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 19
- 229910052799 carbon Inorganic materials 0.000 description 19
- 150000001875 compounds Chemical class 0.000 description 19
- 239000003921 oil Substances 0.000 description 15
- 235000019198 oils Nutrition 0.000 description 15
- 239000002253 acid Substances 0.000 description 12
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 10
- 150000003512 tertiary amines Chemical class 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- JQMPJOXNMWUULP-UHFFFAOYSA-N 2-Methylhenicosane Chemical compound CCCCCCCCCCCCCCCCCCCC(C)C JQMPJOXNMWUULP-UHFFFAOYSA-N 0.000 description 6
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 5
- 239000001630 malic acid Substances 0.000 description 5
- 235000011090 malic acid Nutrition 0.000 description 5
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 4
- 235000019486 Sunflower oil Nutrition 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
- 125000005429 oxyalkyl group Chemical group 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- 239000002600 sunflower oil Substances 0.000 description 4
- DMBUODUULYCPAK-UHFFFAOYSA-N 1,3-bis(docosanoyloxy)propan-2-yl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCCCCCC DMBUODUULYCPAK-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229920006322 acrylamide copolymer Polymers 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 229960002154 guar gum Drugs 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 229920003169 water-soluble polymer Polymers 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 description 2
- RECMXJOGNNTEBG-UHFFFAOYSA-N 1-phenylmethoxyethanol Chemical compound CC(O)OCC1=CC=CC=C1 RECMXJOGNNTEBG-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229930182843 D-Lactic acid Natural products 0.000 description 2
- JVTAAEKCZFNVCJ-UWTATZPHSA-N D-lactic acid Chemical compound C[C@@H](O)C(O)=O JVTAAEKCZFNVCJ-UWTATZPHSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 229920006318 anionic polymer Polymers 0.000 description 2
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 2
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 235000019445 benzyl alcohol Nutrition 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 229940082500 cetostearyl alcohol Drugs 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 2
- 210000001520 comb Anatomy 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 125000006165 cyclic alkyl group Chemical group 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N ethyl trimethyl methane Natural products CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N gamma-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 description 2
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 2
- 230000037308 hair color Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 2
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- 235000000396 iron Nutrition 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
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- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 description 2
- KKBOOQDFOWZSDC-UHFFFAOYSA-N n-[2-(diethylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCN(CC)CC KKBOOQDFOWZSDC-UHFFFAOYSA-N 0.000 description 2
- MNAZHGAWPCLLGX-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C MNAZHGAWPCLLGX-UHFFFAOYSA-N 0.000 description 2
- WWVIUVHFPSALDO-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C WWVIUVHFPSALDO-UHFFFAOYSA-N 0.000 description 2
- 229920005615 natural polymer Polymers 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- PXDJXZJSCPSGGI-UHFFFAOYSA-N palmityl palmitate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 2
- 229960005323 phenoxyethanol Drugs 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
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- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
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- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
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- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 2
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- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
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- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
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- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- WCSBDRIEINNXNW-YPKPFQOOSA-N (z)-n-[2-(diethylamino)ethyl]octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCN(CC)CC WCSBDRIEINNXNW-YPKPFQOOSA-N 0.000 description 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N -2,3-Dihydroxypropanoic acid Natural products OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- FITTZNLMIFECNM-UHFFFAOYSA-N 1-(dimethylamino)-3-docosoxypropan-2-ol 1-[docosoxymethyl(methyl)amino]propan-2-ol Chemical compound C(CCCCCCCCCCCCCCCCCCCCC)OCN(C)CC(C)O.CN(C)CC(COCCCCCCCCCCCCCCCCCCCCCC)O FITTZNLMIFECNM-UHFFFAOYSA-N 0.000 description 1
- AUWQWFNAPOLLLV-UHFFFAOYSA-N 1-(dimethylamino)-3-hexadecoxypropan-2-ol 1-[hexadecoxymethyl(methyl)amino]propan-2-ol Chemical compound C(CCCCCCCCCCCCCCC)OCN(C)CC(C)O.CN(C)CC(COCCCCCCCCCCCCCCCC)O AUWQWFNAPOLLLV-UHFFFAOYSA-N 0.000 description 1
- OGGSSJKOBUVXRI-UHFFFAOYSA-N 1-(dimethylamino)-3-octadecoxypropan-2-ol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CN(C)C OGGSSJKOBUVXRI-UHFFFAOYSA-N 0.000 description 1
- ZTPOLRKNXOFBTE-UHFFFAOYSA-N 1-(dimethylamino)-3-octadecoxypropan-2-ol 1-[methyl(octadecoxymethyl)amino]propan-2-ol Chemical compound C(CCCCCCCCCCCCCCCCC)OCN(C)CC(C)O.CN(C)CC(COCCCCCCCCCCCCCCCCCC)O ZTPOLRKNXOFBTE-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
本発明は、アルキル変性シリコーンを含有する水性毛髪化粧料に関する。 The present invention relates to an aqueous hair cosmetic containing an alkyl-modified silicone.
毛髪は、常にドライヤー、ヘアアイロン、コテ等による熱、ブラッシング等の日常的なヘアケア行動による物理的刺激、及びパーマ、ヘアカラー、ブリーチ等による化学的刺激に曝されているため、その成分や構造体の部分的欠損を伴う損傷状態にある。このような状態を放置しておくと、枝毛や切れ毛の発生、パサついた手触り、まとまりのないヘアスタイル等の原因となり、ヘアケア的観点から好ましくない。 Since hair is always exposed to physical stimuli from daily hair care behavior such as heat, brushing, etc. by hair dryers, hair irons and irons, and chemical stimuli from perms, hair colors, bleaches, etc., its components and structure You are in a damaged state with partial body loss. If such a state is left as it is, it causes the generation of split ends and cut hairs, a dry touch, an uncoordinated hairstyle, etc., which is not preferable from the viewpoint of hair care.
従来、毛髪化粧料には、毛髪にパサつきをなくし、光沢やなめらかさを与える目的で、種々のシリコーン油、エステル油、炭化水素油などの油分が、可溶化、乳化又は溶解して用いられている。特にシリコーン油は、表面張力が低く毛髪へのなじみに優れ、良い光沢が得られるため、近年多用されている。例えば、ポリエーテル変性シリコーン、アルキル変性シリコーン及び尿素を含有する毛髪化粧料が、塗布時の使用性、乾燥後の感触に優れ、毛髪の損傷を防止するものとして提案されている（特許文献１）。 Conventionally, various cosmetic oils such as silicone oils, ester oils, hydrocarbon oils, etc. have been solubilized, emulsified or dissolved for the purpose of eliminating hairiness and giving gloss and smoothness to hair cosmetics. ing. In particular, silicone oil has been widely used in recent years because it has a low surface tension and is excellent in conformity to hair and provides a good gloss. For example, a hair cosmetic containing a polyether-modified silicone, an alkyl-modified silicone, and urea has been proposed as being excellent in usability during application and feeling after drying, and preventing hair damage (Patent Document 1). .
しかしながら、シリコーン油に代表される油分には、油分のもつ限界があり多量に用いたり、消費者が長期にわたり使用したりすると、毛髪のきしみ感が増加したり、脂ぎったりするという好ましくない欠点があった。 However, the oil content typified by silicone oil has a limitation that the oil content has, and when used in a large amount or used over a long period of time by consumers, there is an undesirable disadvantage that the squeaky feeling of hair increases or becomes greasy. there were.
本発明の目的は、髪のまとまり性やスタイル性を向上させる効果に優れ、特に乾燥後や翌日においてもパサついた手触りがなく、かつ髪のまとまり性やスタイル性を維持できる水性毛髪化粧料を提供することにある。 An object of the present invention is an aqueous hair cosmetic that has an excellent effect of improving the cohesiveness and style of hair, and that has no dry touch even after drying or the next day, and that can maintain the cohesiveness and style of hair. It is to provide.
本発明者らは、アルキル変性シリコーンをカチオン界面活性剤及び脂肪酸エステルと共に含有する水性毛髪化粧料が、上記要求を満たすものであることを見出した。 The present inventors have found that an aqueous hair cosmetic containing an alkyl-modified silicone together with a cationic surfactant and a fatty acid ester satisfies the above requirements.
すなわち本発明は、成分(A)、(B)及び(C)を含有する水性毛髪化粧料を提供するものである。 That is, the present invention provides an aqueous hair cosmetic containing components (A), (B) and (C).
(A)カチオン界面活性剤
(B)炭素数12〜40の直鎖又は分岐鎖のアルキル基又はアルケニル基を有する脂肪酸と多価アルコールから導かれる脂肪酸エステル
(C)アルキル変性シリコーン
(A) Cationic surfactant
(B) Fatty acid ester derived from a fatty acid having a linear or branched alkyl or alkenyl group having 12 to 40 carbon atoms and a polyhydric alcohol
(C) Alkyl modified silicone
本発明の水性毛髪化粧料は、乾燥後の髪のまとまり、しっとり感、パサつきのなさ、滑らかさ及びくし・ブラシや指の通りのよさに優れており、髪の束感が綺麗に揃いかつ傷んだ髪に効果がある。更に、翌日の洗髪時まで髪のまとまり／スタイルが持続し、しかも安定性にも優れる。 The water-based hair cosmetic composition of the present invention is excellent in hair unity, moist, dryness, smoothness and comb / brush / finger feel after drying. It has an effect on hair. Furthermore, the hair mass / style is maintained until the next day's hair washing, and the stability is also excellent.
成分(A)のカチオン界面活性剤としては、一級〜三級アミン型化合物と四級アンモニウム塩型化合物がある。なかでも好ましいものとして、一般式(1)で表される四級アンモニウム塩型化合物、並びに一般式(2)で表される三級アミン型化合物及びその塩が挙げられる。 Component (A) cationic surfactants include primary to tertiary amine type compounds and quaternary ammonium salt type compounds. Among them, preferred are a quaternary ammonium salt type compound represented by the general formula (1), a tertiary amine type compound represented by the general formula (2) and a salt thereof.
〔式中、Ａは水素原子、又は総炭素数12〜24の直鎖若しくは分岐鎖の飽和若しくは不飽和の、アミド基、N-炭化水素カルバモイル基、アシルオキシ基若しくは炭化水素オキシ基を示し、Ｂは炭素数１〜22の２価の直鎖又は分岐鎖の飽和又は不飽和のヒドロキシ基を有してもよい炭化水素基を示し、Ｒ1、Ｒ2及びＲ3は少なくとも１個が総炭素数１〜24の直鎖又は分岐鎖のアルキル基又はアルケニル基を示し、残りは炭素数１〜３のアルキル基を示し、Ｘ-はハロゲン化物イオン又は有機アニオンを示す。〕 [In the formula, A represents a hydrogen atom or a linear or branched saturated or unsaturated amide group, N-hydrocarbon carbamoyl group, acyloxy group or hydrocarbon oxy group having a total carbon number of 12 to 24; Represents a hydrocarbon group which may have a divalent linear or branched saturated or unsaturated hydroxy group having 1 to 22 carbon atoms, and at least one of R 1 , R 2 and R 3 is a total carbon. A linear or branched alkyl group or alkenyl group having 1 to 24 carbon atoms, the remaining alkyl group having 1 to 3 carbon atoms, and X - represents a halide ion or an organic anion. ]
〔式中、Ａ及びＢは前記と同じ意味を示し、Ｙ1及びＹ2は独立して炭素数１〜４のアルキル基を示す。〕 Wherein, A and B have the same meanings as described above, Y 1 and Y 2 represents an alkyl group having 1 to 4 carbon atoms independently. ]
このうち、一般式(1)で表される四級アンモニウム塩（四級アンモニウム塩(1)という）としては、モノ長鎖アルキル（炭素数12〜22）四級アンモニウム塩、ジ長鎖アルキル又はアルケニル（炭素数12〜22）四級アンモニウム塩、分岐鎖アルキル（炭素数12〜22）四級アンモニウム塩、アルキルアミド（炭素数12〜24）アルキル（炭素数１〜５）四級アンモニウム塩、N-炭化水素カルバモイル（炭素数12〜24）アルキル（炭素数１〜５）四級アンモニウム塩、アシル（炭素数12〜24）オキシアルキル（炭素数１〜５）四級アンモニウム塩、アルキル又はアルケニル（炭素数12〜24）オキシアルキル（炭素数１〜５）四級アンモニウム塩が挙げられる。 Among these, as the quaternary ammonium salt represented by the general formula (1) (referred to as quaternary ammonium salt (1)), a mono long chain alkyl (carbon number 12 to 22) quaternary ammonium salt, di long chain alkyl or Alkenyl (carbon number 12-22) quaternary ammonium salt, branched chain alkyl (carbon number 12-22) quaternary ammonium salt, alkylamide (carbon number 12-24) alkyl (carbon number 1-5) quaternary ammonium salt, N-hydrocarbon carbamoyl (carbon number 12-24) alkyl (carbon number 1-5) quaternary ammonium salt, acyl (carbon number 12-24) oxyalkyl (carbon number 1-5) quaternary ammonium salt, alkyl or alkenyl (C12-C24) oxyalkyl (C1-C5) quaternary ammonium salt is mentioned.
モノ長鎖アルキル（炭素数12〜22）四級アンモニウム塩としては、ステアリルトリメチルアンモニウムクロライド、ミリスチルトリメチルアンモニウムクロライド、セチルトリメチルアンモニウムクロライド、アラキルトリメチルアンモニウムクロライド、ベヘニルトリメチルアンモニウムクロライド、ラウリルトリメチルアンモニウムクロライド等が挙げられる。 Mono long chain alkyl (C12-22) quaternary ammonium salts include stearyl trimethylammonium chloride, myristyltrimethylammonium chloride, cetyltrimethylammonium chloride, aralkyltrimethylammonium chloride, behenyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc. Can be mentioned.
ジ長鎖アルキル又はアルケニル（炭素数12〜22）四級アンモニウム塩としては、ジステアリルジメチルアンモニウムクロライド、ジオレイルジメチルアンモニウムクロライド、ジイソステアリルジメチルアンモニウムメトサルフェート、ジ[(2-ドデカノイルアミノ)エチル]ジメチルアンモニウムクロライド、ジ[(2-ステアロイルアミノ)プロピル]ジメチルアンモニウムエトサルフェート等が挙げられる。 Di long-chain alkyl or alkenyl (C12-22) quaternary ammonium salts include distearyldimethylammonium chloride, dioleyldimethylammonium chloride, diisostearyldimethylammonium methosulfate, di [(2-dodecanoylamino) ethyl ] Dimethylammonium chloride, di [(2-stearoylamino) propyl] dimethylammonium etosulphate and the like.
分岐鎖アルキル（炭素数12〜22）四級アンモニウム塩としては、2-デシルテトラデシルトリメチルアンモニウムクロライド、2-ドデシルヘキサデシルトリメチルアンモニウムクロライド、ジ-2-ヘキシルデシルジメチルアンモニウムクロライド、ジ-2-オクチルドデシルジメチルアンモニウムクロライド等が挙げられる。 Examples of branched alkyl (C12-22) quaternary ammonium salts include 2-decyltetradecyltrimethylammonium chloride, 2-dodecylhexadecyltrimethylammonium chloride, di-2-hexyldecyldimethylammonium chloride, di-2-octyl And dodecyldimethylammonium chloride.
アルキルアミド（炭素数12〜24）アルキル（炭素数１〜５）四級アンモニウム塩としては、ステアラミドプロピル四級アンモニウム塩が挙げられる。N-炭化水素カルバモイル（炭素数12〜24）アルキル（炭素数１〜５）四級アンモニウム塩としては、N-ステアリルカルバモイルプロピル四級アンモニウム塩が挙げられる。アシル（炭素数12〜24）オキシアルキル（炭素数１〜５）四級アンモニウム塩としては、ステアロキシプロピル四級アンモニウム塩が挙げられる。炭化水素（炭素数12〜24）オキシアルキル（炭素数１〜５）四級アンモニウム塩としては、オクタデシロキシプロピルトリメチルアンモニウムクロライドが挙げられる。 Examples of the alkylamide (carbon number 12-24) alkyl (carbon number 1-5) quaternary ammonium salt include stearamide propyl quaternary ammonium salt. Examples of the N-hydrocarbon carbamoyl (carbon number 12-24) alkyl (carbon number 1-5) quaternary ammonium salt include N-stearylcarbamoylpropyl quaternary ammonium salt. Examples of acyl (C12-24) oxyalkyl (C1-5) quaternary ammonium salts include stearoxypropyl quaternary ammonium salts. Examples of the hydrocarbon (carbon number 12-24) oxyalkyl (carbon number 1-5) quaternary ammonium salt include octadecyloxypropyltrimethylammonium chloride.
一般式(2)で表される三級アミン型化合物（三級アミン型化合物(2)という）において、Ａが水素原子以外の場合、Ａは総炭素数14〜22、更には総炭素数18〜22のアミド基又は炭化水素オキシ基であることが好ましく、またその炭化水素部分が飽和であるもの、更には直鎖であるものが好ましい。この場合におけるＢは、トリメチレン基、2-ヒドロキシトリメチレン基が好ましい。Ａが水素原子の場合、Ｂとしては、炭素数18〜22の基が好ましく、また飽和の基、更には直鎖の基が好ましく、ヒドロキシ基を有することが好ましい。Ｙ1及びＹ2としては、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、t-ブチル基等が挙げられ、なかでもメチル基、エチル基が好ましく、更にはメチル基が好ましい。 In the tertiary amine type compound represented by the general formula (2) (referred to as tertiary amine type compound (2)), when A is other than a hydrogen atom, A is a total carbon number of 14 to 22, and further a total carbon number of 18 It is preferably an amide group or a hydrocarbon oxy group of ˜22, and those in which the hydrocarbon portion is saturated, and further those in which they are linear are preferred. In this case, B is preferably a trimethylene group or a 2-hydroxytrimethylene group. When A is a hydrogen atom, B is preferably a group having 18 to 22 carbon atoms, is preferably a saturated group, more preferably a linear group, and preferably has a hydroxy group. Examples of Y 1 and Y 2 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, and a t-butyl group. Among them, a methyl group and an ethyl group are preferable, and a methyl group is more preferable.
三級アミン型化合物(2)の好ましい態様として、一般式(2a)で表されるエーテルアミン化合物及び一般式(2b)で表されるアミドアミン化合物が挙げられる。 Preferred embodiments of the tertiary amine type compound (2) include an ether amine compound represented by the general formula (2a) and an amidoamine compound represented by the general formula (2b).
〔式中、Ｙ1及びＹ2は前記と同じ意味を示し、Ａ1は炭素数12〜24の直鎖又は分岐鎖の飽和又は不飽和の炭化水素基を示し、Ｘは水素原子又はヒドロキシ基を示し、Ａ2は炭素数11〜23の直鎖又は分岐鎖の飽和又は不飽和の炭化水素基を示し、ｍは２〜４の数を示す。〕 [Wherein Y 1 and Y 2 have the same meaning as described above, A 1 represents a linear or branched saturated or unsaturated hydrocarbon group having 12 to 24 carbon atoms, and X represents a hydrogen atom or a hydroxy group. A 2 represents a linear or branched saturated or unsaturated hydrocarbon group having 11 to 23 carbon atoms, and m represents a number of 2 to 4. ]
一般式(2a)で表されるエーテルアミン化合物の具体例としては、N,N-ジメチル-3-ヘキサデシルオキシプロピルアミン〔ヘキサデシルオキシプロピルジメチルアミン〕、N,N-ジメチル-3-オクタデシルオキシプロピルアミン〔オクタデシルオキシプロピルジメチルアミン〕、N,N-ジメチル-3-ヘキサデシルオキシ-2-ヒドロキシプロピルアミン〔ヘキサデシルオキシ(2-ヒドロキシプロピル)ジメチルアミン〕、N,N-ジメチル-3-オクタデシルオキシ-2-ヒドロキシプロピルアミン〔オクタデシルオキシ(2-ヒドロキシプロピル)ジメチルアミン〕、N,N-ジメチル-3-ベヘニルオキシ-2-ヒドロキシプロピルアミン〔ベヘニルオキシ(2-ヒドロキシプロピル)ジメチルアミン〕等が挙げられる。市販品の一例として、カチナールSHPA（東邦化学社；N,N-ジメチル-3-オクタデシルオキシ-2-ヒドロキシプロピルアミン，INCI名 ステアリルPG-ジメチルアミン）が挙げられる。 Specific examples of the ether amine compound represented by the general formula (2a) include N, N-dimethyl-3-hexadecyloxypropylamine [hexadecyloxypropyldimethylamine], N, N-dimethyl-3-octadecyloxy. Propylamine [octadecyloxypropyldimethylamine], N, N-dimethyl-3-hexadecyloxy-2-hydroxypropylamine [hexadecyloxy (2-hydroxypropyl) dimethylamine], N, N-dimethyl-3-octadecyl Oxy-2-hydroxypropylamine [octadecyloxy (2-hydroxypropyl) dimethylamine], N, N-dimethyl-3-behenyloxy-2-hydroxypropylamine [behenyloxy (2-hydroxypropyl) dimethylamine], etc. Can be mentioned. An example of a commercially available product is Katchinal SHPA (Toho Chemical Co., Ltd .; N, N-dimethyl-3-octadecyloxy-2-hydroxypropylamine, INCI name stearyl PG-dimethylamine).
一般式(2b)で表されるアミドアミン化合物は、毛髪への吸着性が高く、毛髪の濯ぎ時、乾燥時における滑らかさを付与する。また、他の成分の分散安定性にも寄与するものである。アミドアミン化合物の具体例としては、イソステアリン酸ジエチルアミノエチルアミド、オレイン酸ジエチルアミノエチルアミド、ステアリン酸ジエチルアミノエチルアミド、ステアリン酸ジエチルアミノプロピルアミド、ステアリン酸ジブチルアミノエチルアミド、ステアリン酸ジブチルアミノプロピルアミド、ステアリン酸ジプロピルアミノプロピルアミド、ステアリン酸ジプロピルアミノエチルアミド、ステアリン酸ジメチルアミノエチルアミド、ステアリン酸ジメチルアミノプロピルアミド、パルミチン酸ジエチルアミノエチルアミド、パルミチン酸ジエチルアミノプロピルアミド、パルミチン酸ジメチルアミノエチルアミド、パルミチン酸ジメチルアミノプロピルアミド、ミリスチン酸ジメチルアミノエチルアミド、ミリスチン酸ジメチルアミノプロピルアミド、ベヘニン酸ジエチルアミノエチルアミド、ベヘニン酸ジエチルアミノプロピルアミド、ベヘニン酸ジメチルアミノエチルアミド、ベヘニン酸ジメチルアミノプロピルアミド、アラキン酸ジメチルアミノエチルアミド、アラキン酸ジメチルアミノプロピルアミド等が挙げられ、なかでも、性能、安定性、入手容易性等の面で、ステアリン酸ジエチルアミノエチルアミド、ステアリン酸ジメチルアミノプロピルアミド、ベヘニン酸ジメチルアミノプロピルアミド等が特に好ましい。 The amidoamine compound represented by the general formula (2b) has high adsorptivity to hair and imparts smoothness during rinsing and drying of the hair. It also contributes to the dispersion stability of other components. Specific examples of amidoamine compounds include diethylstearic acid diethylaminoethylamide, oleic acid diethylaminoethylamide, stearic acid diethylaminoethylamide, stearic acid diethylaminopropylamide, stearic acid dibutylaminoethylamide, stearic acid dibutylaminopropylamide, stearic acid dipropyl. Aminopropylamide, stearic acid dipropylaminoethylamide, stearic acid dimethylaminoethylamide, stearic acid dimethylaminopropylamide, palmitic acid diethylaminoethylamide, palmitic acid diethylaminopropylamide, palmitic acid dimethylaminoethylamide, palmitic acid dimethylaminopropyl Amides, myristic acid dimethylaminoethylamide, myristic acid Examples include methylaminopropylamide, behenic acid diethylaminoethylamide, behenic acid diethylaminopropylamide, behenic acid dimethylaminoethylamide, behenic acid dimethylaminopropylamide, arachidic acid dimethylaminoethylamide, and arachidic acid dimethylaminopropylamide. However, stearic acid diethylaminoethylamide, stearic acid dimethylaminopropylamide, behenic acid dimethylaminopropylamide, and the like are particularly preferable in terms of performance, stability, availability, and the like.
三級アミン型化合物(2)は、等モル以上の酸の添加によって酸付加塩を形成させて酸性に調整し、アミンを解離状態にして用いることが好ましい。ここで酸付加塩を形成させる酸としては、後述の水性毛髪化粧料のpH調整に用いられるものと同様のものが用いられ、pHの調整と兼用してもよい。 The tertiary amine type compound (2) is preferably used in the dissociated state by adjusting the acidity by forming an acid addition salt by adding an equimolar or more acid. Here, as the acid for forming the acid addition salt, the same acid as used for adjusting the pH of the aqueous hair cosmetic described later may be used, and it may be used for adjusting the pH.
成分(A)の四級アンモニウム塩型化合物(1)及び三級アミン型化合物(2)は、２種以上を併用してもよく、またその含有量は、濯ぎや乾燥後に髪をなめらかにするという観点から、本発明の水性毛髪化粧料中の0.1〜20重量％が好ましく、更には0.05〜15重量％、特に0.5〜10重量％が好ましい。なお、この含有量は、成分(A)が三級アミン型化合物の塩である場合、三級アミン型化合物に換算した量をいう。 The component (A) quaternary ammonium salt type compound (1) and tertiary amine type compound (2) may be used in combination of two or more, and the content thereof makes the hair smooth after rinsing and drying. In view of the above, it is preferably 0.1 to 20% by weight, more preferably 0.05 to 15% by weight, and particularly preferably 0.5 to 10% by weight in the aqueous hair cosmetic composition of the present invention. In addition, this content means the quantity converted into the tertiary amine type compound, when a component (A) is the salt of a tertiary amine type compound.
成分(B)の脂肪酸エステルは、炭素数12〜40の直鎖又は分岐鎖のアルキル基又はアルケニル基を有する脂肪酸と多価アルコールから導かれるものである。 The fatty acid ester of component (B) is derived from a fatty acid having a linear or branched alkyl group or alkenyl group having 12 to 40 carbon atoms and a polyhydric alcohol.
炭素数12〜40の直鎖又は分岐鎖のアルキル基又はアルケニル基を有する脂肪酸としては、炭素数18〜22の飽和脂肪酸、例えばステアリン酸、ベヘニン酸が好ましいものとして挙げられる。また、多価アルコールとしては、グリセリン、ポリグリセリンが好ましいものとして挙げられる。このような脂肪酸と多価アルコールから導かれる脂肪酸エステルとしては、トリステアリン酸グリセリル、トリベヘン酸グリセリル、ペンタステアリン酸テトラグリセリル、ペンタステアリン酸ヘキサグリセリル、ペンタステアリン酸デカグリセリル、デカステアリン酸デカグリセリル等が挙げられる。 Preferred examples of the fatty acid having a linear or branched alkyl group or alkenyl group having 12 to 40 carbon atoms include saturated fatty acids having 18 to 22 carbon atoms such as stearic acid and behenic acid. Moreover, as a polyhydric alcohol, glycerol and polyglycerol are mentioned as a preferable thing. Examples of fatty acid esters derived from such fatty acids and polyhydric alcohols include glyceryl tristearate, glyceryl tribehenate, tetraglyceryl pentastearate, hexaglyceryl pentastearate, decaglyceryl pentastearate, decaglyceryl decastearate, and the like. Can be mentioned.
成分(B)の脂肪酸エステルは、２種以上を併用してもよく、またその含有量は、本発明の毛髪化粧料中の0.01〜10重量％、特に0.05〜５重量％が好ましい。 The fatty acid ester of component (B) may be used in combination of two or more, and the content thereof is preferably 0.01 to 10% by weight, particularly 0.05 to 5% by weight in the hair cosmetic composition of the present invention.
成分(C)のアルキル変性シリコーンとしては、分子中に単位(a)及び単位(b)を有するもの（アルキル変性シリコーン(ab)という）が挙げられる。 Examples of the alkyl-modified silicone of component (C) include those having units (a) and units (b) in the molecule (referred to as alkyl-modified silicone (ab)).
〔式中、Ｒ4及びＲ5は独立して炭素数１〜４のアルキル基を示し、Ｒ6は炭素数１〜40の直鎖、分岐鎖又は環状のアルキル基又はアルケニル基を示し、Ｒ7は炭素数７〜40の直鎖、分岐鎖又は環状のアルキル基又はアルケニル基を示し、ａは２以上、ｂは３以上であって、ａ＋ｂ＝５〜6000となる数を示す。〕 [Wherein, R 4 and R 5 independently represent an alkyl group having 1 to 4 carbon atoms, R 6 represents a linear, branched or cyclic alkyl group or alkenyl group having 1 to 40 carbon atoms; 7 represents a linear, branched or cyclic alkyl group or alkenyl group having 7 to 40 carbon atoms, a represents 2 or more, b represents 3 or more, and a + b = 5 to 6000. ]
アルキル変性シリコーン(ab)は、１分子中に少なくとも３個の炭素数７〜40の炭化水素基を有するものであり、分岐鎖状でも環状であってもよい。 The alkyl-modified silicone (ab) has at least three hydrocarbon groups having 7 to 40 carbon atoms in one molecule, and may be branched or cyclic.
成分(C)のアルキル変性シリコーン(ab)が有するＲ4及びＲ5で示されるアルキル基としては、メチル基、エチル基、n-プロピル基、イソプロピル基、n-ブチル基等が挙げられるが、なかでもメチル基が好ましい。また、Ｒ6及びＲ7で示されるアルキル基又はアルケニル基は、直鎖状、分岐鎖状及び環状のいずれであってもよいが、Ｒ6が炭素数１〜４のアルキル基であり、かつＲ7が炭素数７〜40（より好ましくは12〜22、特に好ましくは16〜18）のアルキル基又はアルケニル基であることが好ましい。Ｒ7の具体例としては、オクチル基、ノニル基、デシル基、ウンデシル基、ドデシル基、トリデシル基、テトラデシル基、ペンタデシル基、ヘキサデシル基、ヘプタデシル基、オクタデシル基、ノナデシル基、エイコシル基、ヘンエイコシル基、ドコシル基、テトラコシル基、ペンタコシル基、ヘキサコシル基、ヘプタコシル基、オクタコシル基、トリアコンチル基、テトラトリアコンチル基、オクタトリアコンチル基、テトラコンチル基、2-ヘプチルウンデシル基、2-ウンデシルペンタデシル基、2-デシルテトラデシル基、2-デシルペンタデシル基、2-エチルヘキシル基、2-オクチルドデシル基、2-ウンデシルテトラデシル基、メチル分岐イソステアリル基、メチル分岐ドデシル基（プロピレンテトラマー）、メチル分岐ノニル基（プロピレントリマー）等が挙げられる。また、ａ＋ｂは５〜6000であるが、200〜3000であることが好ましく、更には、ａ及びｂが150〜750でａ＋ｂが300〜1500であることが好ましい。ここでａ、ｂは重量平均分子量から算出した平均重合度として求められる。 Examples of the alkyl group represented by R 4 and R 5 of the component (C) alkyl-modified silicone (ab) include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, and an n-butyl group. Of these, a methyl group is preferable. The alkyl group or alkenyl group represented by R 6 and R 7 may be any of linear, branched, and cyclic, but R 6 is an alkyl group having 1 to 4 carbon atoms, and R 7 is preferably an alkyl group or an alkenyl group having 7 to 40 carbon atoms (more preferably 12 to 22, particularly preferably 16 to 18). Specific examples of R 7 include octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, heneicosyl, Docosyl group, tetracosyl group, pentacosyl group, hexacosyl group, heptacosyl group, octacosyl group, triacontyl group, tetratriacontyl group, octatriacontyl group, tetracontyl group, 2-heptylundecyl group, 2-undecylpentadecyl group 2-decyltetradecyl group, 2-decylpentadecyl group, 2-ethylhexyl group, 2-octyldodecyl group, 2-undecyltetradecyl group, methyl-branched isostearyl group, methyl-branched dodecyl group (propylene tetramer), methyl Branched nonyl group (propyleneto Limer). Moreover, although a + b is 5-6000, it is preferable that it is 200-3000, Furthermore, it is preferable that a and b are 150-750 and a + b is 300-1500. Here, a and b are obtained as an average degree of polymerization calculated from the weight average molecular weight.
また、成分(C)のアルキル変性シリコーンは、その融点が10〜60℃、特に20〜50℃であるものが好ましい。なお、当該オルガノポリシロキサンの融点は、示差走査熱量計（DSC）を用いて測定した場合の値である。 The alkyl-modified silicone as component (C) preferably has a melting point of 10 to 60 ° C, particularly 20 to 50 ° C. The melting point of the organopolysiloxane is a value when measured using a differential scanning calorimeter (DSC).
アルキル変性シリコーン(ab)は、前記ポリシロキサン単位(a)及び(b)を、分子中のいずれの位置に有している構造であってもよいが、製造の容易性の観点からは、両単位１ブロックずつが直接に結合しており、これに両末端残基が結合した単純な構造であるのが好ましい。また、この両末端残基は−ＯＳｉＲ8Ｒ9Ｒ10（Ｒ8〜Ｒ10は炭素数１〜４のアルキル基を示す）であることが好ましい。成分(C)のオルガノポリシロキサンの具体例としては、次の一般式(3)で表わされるものが挙げられる。 The alkyl-modified silicone (ab) may have a structure having the polysiloxane units (a) and (b) at any position in the molecule, but from the viewpoint of ease of production, both Each unit block is directly bonded, and a simple structure in which both terminal residues are bonded to this is preferable. Further, it is preferable that the both-terminal residue that is -OSiR 8 R 9 R 10 (R 8 ~R 10 is an alkyl group having 1 to 4 carbon atoms). Specific examples of the component (C) organopolysiloxane include those represented by the following general formula (3).
〔式中、ａ、ｂ及びＲ7は前記と同じ意味を示す。〕 [Wherein, a, b and R 7 have the same meaning as described above. ]
この一般式(3)で表わされるオルガノシロキサンの市販品としては、東芝シリコーン社のXF42-A7154、XF42-A5048、XF42-A5047等が挙げられる。 Commercially available products of the organosiloxane represented by the general formula (3) include XF42-A7154, XF42-A5048, and XF42-A5047 manufactured by Toshiba Silicone.
成分(C)のアルキル変性シリコーンは、単独で又は２種以上を組み合わせて使用することができ、またその含有量は髪のまとまり性やスタイル性を向上させ、乾燥後のパサつきを抑え、毛先まで滑らかなものとするという観点から、本発明の水性毛髪化粧料の0.01〜20重量％、更には0.01〜10重量％、特に0.01〜５重量％が好ましい。 The component (C) alkyl-modified silicone can be used alone or in combination of two or more thereof, and its content improves the cohesiveness and style of the hair, suppresses dryness after drying, and the hair From the viewpoint of achieving smoothness, 0.01 to 20% by weight, more preferably 0.01 to 10% by weight, and particularly preferably 0.01 to 5% by weight of the aqueous hair cosmetic composition of the present invention.
本発明の水性毛髪化粧料には、すすぎ時の感触、乾燥後の仕上がり感の向上を目的として、成分(C)以外のシリコーン類を含有させてもよい。シリコーン類としては、ジメチルポリシロキサン、アミノ変性ポリシロキサン、フッ素変性ポリシロキサン、ポリオキシアルキレン変性ポリシロキサン、カルボン酸変性ポリシロキサン、アルコール変性ポリシロキサン、エポキシ変性ポリシロキサン等が挙げられる。これらシリコーン類は２種以上を併用してもよく、その含有量は本発明の水性毛髪化粧料の0.1〜20重量％、特に0.5〜10重量％が好ましい。 The aqueous hair cosmetic composition of the present invention may contain silicones other than the component (C) for the purpose of improving the feel during rinsing and the finished feeling after drying. Examples of silicones include dimethylpolysiloxane, amino-modified polysiloxane, fluorine-modified polysiloxane, polyoxyalkylene-modified polysiloxane, carboxylic acid-modified polysiloxane, alcohol-modified polysiloxane, and epoxy-modified polysiloxane. Two or more kinds of these silicones may be used in combination, and the content thereof is preferably 0.1 to 20% by weight, particularly 0.5 to 10% by weight of the aqueous hair cosmetic composition of the present invention.
本発明の水性毛髪化粧料には、乾燥後の仕上がり感（サラサラ感しっとり感など）を向上する目的で、油剤類を含有させることができる。かかる油剤類としてはアマニ油、ツバキ油、マカデミアナッツ油、トウモロコシ油、ミンク油、オリーブ油、アボガド油、サザンカ油、ヒマシ油、サフラワー油、ホホバ油、ヒマワリ油、アーモンド油、ナタネ油、ゴマ油、大豆油、落花生油、メドウフォーム油、トリグリセリン、トリオクタン酸グリセリン、トリイソパルミチン酸グリセリン等の液体油脂；オクタン酸セチル、ラウリン酸ヘキシル、ミリスチン酸イソプロピル、ミリスチン酸ミリスチル、パルミチン酸イソプロピル、パルミチン酸オクチル、パルミチン酸ヘキサデシル、ステアリン酸イソセチル、ステアリン酸硬化ヒマシ油、モノヒドロキシステアリン酸硬化ヒマシ油、イソステアリン酸イソプロピル、イソパルミチン酸オクチル、オレイン酸イソデシル、トリ2-エチルヘキサン酸グリセリル、テトラ2-エチルヘキサン酸ペンタエリスリット、コハク酸2-エチルヘキシル、セバシン酸ジエチル等のエステル油；流動パラフィン、スクワラン、スクワレン、パラフィン、セレシン等の炭化水素類;ラウリン酸、ミリスチン酸、パルミチン酸、オレイン酸、ステアリン酸等の脂肪酸などが挙げられる。これら油剤は、２種以上を併用してもよく、その含有量は本発明の水性毛髪化粧料の0.01〜20重量％、特に0.1〜10重量％が好ましい。 The aqueous hair cosmetic composition of the present invention can contain oils for the purpose of improving the finished feeling after drying (such as a smooth and moist feeling). Such oils include linseed oil, camellia oil, macadamia nut oil, corn oil, mink oil, olive oil, avocado oil, sasanqua oil, castor oil, safflower oil, jojoba oil, sunflower oil, almond oil, rapeseed oil, sesame oil, large Liquid oils such as bean oil, peanut oil, meadowfoam oil, triglycerin, glyceryl trioctanoate, glycerin triisopalmitate; cetyl octanoate, hexyl laurate, isopropyl myristate, myristyl myristate, isopropyl palmitate, octyl palmitate, Hexadecyl palmitate, isocetyl stearate, stearic acid hydrogenated castor oil, monohydroxystearic acid hydrogenated castor oil, isopropyl isostearate, octyl isopalmitate, isodecyl oleate, tri-2-ethyl Ester oil such as glyceryl sanrate, pentaerythritol tetra-2-ethylhexanoate, 2-ethylhexyl succinate, diethyl sebacate; hydrocarbons such as liquid paraffin, squalane, squalene, paraffin, ceresin; lauric acid, myristic acid, Examples thereof include fatty acids such as palmitic acid, oleic acid, and stearic acid. Two or more of these oil agents may be used in combination, and the content thereof is preferably 0.01 to 20% by weight, particularly preferably 0.1 to 10% by weight, based on the aqueous hair cosmetic composition of the present invention.
本発明の水性毛髪化粧料には、高級アルコールを含有させることができる。高級アルコールとしては、セチルアルコール、セトステアリルアルコール、ステアリルアルコール、ペヘニルアルコール等が挙げられるが、なかでも炭素数18〜24の直鎖アルカノール、特にステアリルアルコール、べへニルアルコールが好ましい。これらは２種以上を併用してもよく、その含有量は、塗布からすすぎ、及び乾燥後の平滑性の点、並びに系の安定性や使いやすい粘度に調整する点から、成分(A)の使用量に対して、0.5〜20倍モルが好ましく、更には1〜10倍モル、特に２〜８倍モルが好ましい。 The aqueous hair cosmetic composition of the present invention can contain a higher alcohol. Examples of higher alcohols include cetyl alcohol, cetostearyl alcohol, stearyl alcohol, and penyl alcohol. Among these, linear alkanols having 18 to 24 carbon atoms, particularly stearyl alcohol and behenyl alcohol are preferred. Two or more of these may be used in combination. The content of component (A) is from the point of rinsing from application and smoothness after drying, and adjusting the system stability and viscosity to be easy to use. 0.5-20 times mole is preferable with respect to the usage-amount, Furthermore, 1-10 times mole, and especially 2-8 times mole are preferable.
本発明の水性毛髪化粧料には、有機溶剤を含有させることができる。有機溶剤としては、ベンジルアルコール、ベンジルオキシエタノール、フェノキシエタノール等の芳香族アルコール；N-メチルピロリドン、N-オクチルピロリドン、ルラウリルピロリドン；エチレンカーボネート、プロピレンカーボネート等のアルキレンカーボネート；γ-ブチロラクトン、γ-カプロラクトン等のラクトン類が挙げられる。これらは２種以上を併用してもよく、またその含有量は、使用感、ツヤ及び柔軟性の向上の点から、本発明の水性毛髪化粧料中の0.01〜50重量％が好ましく、更には0.1〜35重量％、特に0.5〜10重量％が好ましい。 The aqueous hair cosmetic composition of the present invention can contain an organic solvent. Organic solvents include aromatic alcohols such as benzyl alcohol, benzyloxyethanol, phenoxyethanol; N-methylpyrrolidone, N-octylpyrrolidone, lulaurylpyrrolidone; alkylene carbonates such as ethylene carbonate and propylene carbonate; γ-butyrolactone, γ-caprolactone And lactones. Two or more of these may be used in combination, and the content thereof is preferably 0.01 to 50% by weight in the aqueous hair cosmetic composition of the present invention, from the viewpoint of improvement in feeling of use, gloss and flexibility. 0.1 to 35% by weight, particularly 0.5 to 10% by weight is preferred.
本発明の水性毛髪化粧料には、多価アルコールを含有させることができる。多価アルコールとしては、プロピレングリコール、1,3-ブタンジオール、ジプロピレングリコール、ポリプロピレングリコール（特に分子量200〜700のもの）、グリセリン、ジグリセリン、トリグリセリン等のポリグリセリン、トリメチロールエタン、トリメチルプロパン、エリスリトール、ペンタエリスリトール、ソルビタン、グルコース、ソルビトール、マルチトール、シュクロース、ラフィノース、トレハロース、ポリオキシエチレンメチルグルコシド、ポリオキシプロピレンメチルグルコシド等が挙げられる。これらは２種以上を併用してもよく、またその含有量は、塗布時の液ののばしやすさや濯ぎ時の滑らかさの向上の点から、本発明の水性毛髪化粧料中の0.01〜20重量％が好ましく、更には0.01〜15重量％、特に0.01〜10重量％が好ましい。 The aqueous hair cosmetic composition of the present invention can contain a polyhydric alcohol. Polyhydric alcohols include propylene glycol, 1,3-butanediol, dipropylene glycol, polypropylene glycol (especially those having a molecular weight of 200 to 700), polyglycerin such as glycerin, diglycerin, and triglycerin, trimethylolethane, and trimethylpropane. Erythritol, pentaerythritol, sorbitan, glucose, sorbitol, maltitol, sucrose, raffinose, trehalose, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside and the like. Two or more of these may be used in combination, and the content thereof is 0.01 to 20% by weight in the aqueous hair cosmetic composition of the present invention from the viewpoint of ease of spreading of the liquid during application and improvement of smoothness during rinsing. %, More preferably 0.01 to 15% by weight, and particularly preferably 0.01 to 10% by weight.
本発明の水性毛髪化粧料には、組成物の安定性向上の目的で、水溶性ポリマーを含有させることができる。水溶性ポリマーとしては、カチオン性ポリマー、両性ポリマー、アニオン性ポリマー、ノニオン性ポリマー、天然高分子又はその誘導体が挙げられる。 The aqueous hair cosmetic composition of the present invention can contain a water-soluble polymer for the purpose of improving the stability of the composition. Examples of the water-soluble polymer include a cationic polymer, an amphoteric polymer, an anionic polymer, a nonionic polymer, a natural polymer, or a derivative thereof.
カチオン性ポリマーとしては、例えばカチオン化セルロース誘導体、カチオン性澱粉、カチオン化グアーガム誘導体、ジアリル第四級アンモニウム塩／アクリルアミド共重合物、第四級化ポリビニルピロリドン誘導体等が挙げられ、なかでもカチオン化セルロース及びカチオン化グアーガム、特にカチオン化セルロースが好ましい。市販品としては、カチナールシリーズ（東邦化学社）、UCAREPOLYMERJRシリーズ、同LRシリーズ（Amercho1社）を用いることができる。 Examples of the cationic polymer include cationized cellulose derivatives, cationic starch, cationized guar gum derivatives, diallyl quaternary ammonium salts / acrylamide copolymers, quaternized polyvinylpyrrolidone derivatives, and the like. And cationized guar gum, particularly cationized cellulose. As commercial products, the Kachinar series (Toho Chemical Co., Ltd.), the UCAREPOLYMERJR series, and the LR series (Amercho1 company) can be used.
両性ポリマーとしては、例えば、プラサイズL401（互応化学社）、ユカフォーマーAM-75、同AM75S/SM（以上、三菱化学社）等のカルボキシベタイン型モノマーの重合体又は共重合体；マーコートプラス3330（カルゴン社）、アンフォマー28-4910、同LV-71（以上、ナショナル・スターチ社）等のアクリル酸／ジアリル第四級アンモニウム塩／アクリルアミド共重合体が挙げられ、特にマーコートプラス3330、ユカフォーマーAM-75が好ましい。 Examples of the amphoteric polymer include polymers or copolymers of carboxybetaine type monomers such as Plasize L401 (Kohaku Chemical Co., Ltd.), Yuka Former AM-75, and AM75S / SM (Mitsubishi Chemical Co., Ltd.); Acrylic acid / diallyl quaternary ammonium salt / acrylamide copolymers such as Calgon), Amphomer 28-4910, LV-71 (National Starch), especially Marquat Plus 3330, Yucaformer AM-75 Is preferred.
アニオン性ポリマーとしては、アクリル酸エステル／メタクリル酸エステル共重合体（プラスサイズ；互応化学社）、ビニルピロリドン／ビニルアセテート／ビニルプロピオネート共重合体（ルビスコールVAP；BASF社）、ビニルピロリドン／アクリレート共重合体（ルビフレックス；BASF社）、アクリレート／アクリルアミド共重合体（ウルトラホールド；BASF社）等が挙げられ、特にカルボキシ基含有ポリマーが好ましい。 Examples of anionic polymers include acrylic acid ester / methacrylic acid ester copolymer (plus size; Kyodo Chemical Co.), vinyl pyrrolidone / vinyl acetate / vinyl propionate copolymer (rubiscol VAP; BASF), vinyl pyrrolidone / Examples include acrylate copolymers (rubyflex; BASF), acrylate / acrylamide copolymers (Ultrahold; BASF), and carboxy group-containing polymers are particularly preferable.
ノニオン性ポリマーとしては、例えばルビスコールK12、同17、同30、同60、同80、同90（以上、BASF社）、PVPKI5、同30、同60、同90（以上、ISP社）等のポリビニルピロリドン；ルビスコールVA28E、同37E、同55E、同64E、同73E（以上、BASF社）等が挙げられ、特にルビスコールKl7、30、PVPK30が好ましい。 Nonionic polymers include, for example, Rubiscol K12, 17, 30, 60, 80, 90 (above, BASF), PVPKI5, 30, 60, 90 (above, ISP), etc. Polyvinyl pyrrolidone; rubiscol VA28E, 37E, 55E, 64E, 73E (above, BASF), and the like. Rubiscol Kl7, 30, and PVPK30 are particularly preferable.
天然高分子又はその誘導体としては、例えばグアーガム、キサンタンガム等の天然多糖類；ヒドロキシプロピルキトサン等のキチン誘導体；メチルヒドロキシプロピルデンプン等、デンプン系高分子化合物；メチルヒドロキシプロピルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、カルボキシメチルセルロースナトリウム等のセルロース系高分子化合物；アルギン酸ナトリウム、アルギン酸プロピレングリコールエステル等のアルギン酸系高分子化合物などが挙げられ、特にヒドロキシプロピルセルロース、ヒドロキシエチルセルロースが好ましい。 Examples of natural polymers or derivatives thereof include natural polysaccharides such as guar gum and xanthan gum; chitin derivatives such as hydroxypropyl chitosan; starch-based polymer compounds such as methylhydroxypropyl starch; methylhydroxypropylcellulose, hydroxyethylcellulose, and hydroxypropylcellulose. And cellulose polymer compounds such as sodium carboxymethyl cellulose; and alginic acid polymer compounds such as sodium alginate and propylene glycol alginate, and hydroxypropyl cellulose and hydroxyethyl cellulose are particularly preferable.
以上のような水溶性ポリマーは、１種以上を用いることができ、その含有量は、本発明の水性毛髪化粧料中に0.01〜10重量％が好ましく、更には0.05〜５重量％、特に0.05〜２重量％が好ましい。 One or more water-soluble polymers as described above can be used, and the content thereof is preferably 0.01 to 10% by weight, more preferably 0.05 to 5% by weight, particularly 0.05 in the aqueous hair cosmetic composition of the present invention. ~ 2 wt% is preferred.
本発明の水性毛髪化粧料のpHは、水で20重量倍に希釈したときの25℃におけるpHとして、２〜６に調整されることが好ましく、更には2.5〜５、特に2.8〜4.7に調整されるのが好ましい。pHの調整には、有機酸又は無機酸が使用され、前述した、成分(A)の三級アミン型化合物の中和に用いるものと同様のものを使用することができ、有機酸としてはヒドロキシ酸、モノカルボン酸、ジカルボン酸、トリカルボン酸、ポリカルボン酸、アルキル硫酸、アルキルリン酸等が挙げられる。ヒドロキシ酸としては、グリコール酸、乳酸、オキシ酪酸、グリセリン酸、リンゴ酸、酒石酸等が、モノカルボン酸としては、酢酸等が、ジカルボン酸としては、マロン酸、コハク酸、グルタミン酸、アジピン酸、マレイン酸、フマル酸、フタル酸等が、トリカルボン酸としては、クエン酸等が挙げられる。無機酸としては、塩酸、硫酸、リン酸等が挙げられる。これらのうち、有機酸が好ましく、なかでもα-ヒドロキシカルボン酸、特に乳酸、リンゴ酸が、つや、毛髪の柔軟性、まとまり性のうえで優れている。有機酸又は無機酸の含有量は、本発明の水性毛髪化粧料中の0.05〜10重量％が好ましく、特に0.1〜５重量％が好ましい。 The pH of the aqueous hair cosmetic composition of the present invention is preferably adjusted to 2 to 6, more preferably 2.5 to 5, particularly 2.8 to 4.7 as the pH at 25 ° C. when diluted 20 times by weight with water. Preferably it is done. For adjusting the pH, an organic acid or an inorganic acid is used, and the same one as used for neutralization of the tertiary amine type compound of the component (A) described above can be used. Examples include acids, monocarboxylic acids, dicarboxylic acids, tricarboxylic acids, polycarboxylic acids, alkyl sulfuric acids, and alkyl phosphoric acids. Hydroxy acids include glycolic acid, lactic acid, oxybutyric acid, glyceric acid, malic acid, tartaric acid, etc., monocarboxylic acids include acetic acid, etc., and dicarboxylic acids include malonic acid, succinic acid, glutamic acid, adipic acid, maleic acid. Acid, fumaric acid, phthalic acid and the like, and tricarboxylic acid include citric acid and the like. Examples of inorganic acids include hydrochloric acid, sulfuric acid, phosphoric acid and the like. Of these, organic acids are preferable, and α-hydroxycarboxylic acids, particularly lactic acid and malic acid are excellent in terms of gloss, flexibility and cohesiveness of hair. The content of the organic acid or inorganic acid is preferably 0.05 to 10% by weight, particularly preferably 0.1 to 5% by weight in the aqueous hair cosmetic composition of the present invention.
本発明の水性毛髪化粧料は、水を媒体とするものであり、上記成分以外に、成分(A)以外の界面活性剤；水酸化ナトリウム、水酸化カリウム等のpH調整剤；エチレンジアミン四酢酸（EDTA）等のキレート剤；アミノ酸及びその誘導体；ポリエチレン、ポリスチレン、ポリメチルメタクリレート、ナイロン、シリコーン等のポリマー微粉末及びそれらの疎水化処理物；その他、保湿剤、動植物由来の抽出エキス、薬効成分、タンパク質、抗菌剤、紫外線吸収剤、パール化剤、防腐剤、殺菌剤、抗フケ剤、色素、香料などを、目的に応じて配合することができる。 The aqueous hair cosmetic composition of the present invention uses water as a medium. Besides the above components, surfactants other than the component (A); pH adjusting agents such as sodium hydroxide and potassium hydroxide; ethylenediaminetetraacetic acid ( Chelating agents such as EDTA; amino acids and derivatives thereof; polymer fine powders such as polyethylene, polystyrene, polymethyl methacrylate, nylon, silicone, and their hydrophobized products; other humectants, extracts derived from animals and plants, medicinal components, Proteins, antibacterial agents, ultraviolet absorbers, pearlizing agents, preservatives, bactericides, antidandruff agents, pigments, fragrances and the like can be blended according to the purpose.
本発明の水性毛髪化粧料は、成分(A)、(B)及び(C)、並びに目的に応じ適宜使用されるその他の成分と水を配合することにより製造される。また本発明の水性毛髪化粧料の形態としては、ヘアコンディショナー、ヘアトリートメント等の浴室内で使用されるものなどが挙げられる。 The aqueous hair cosmetic composition of the present invention is produced by blending water with components (A), (B) and (C), and other components used as appropriate according to the purpose. Examples of the form of the aqueous hair cosmetic of the present invention include those used in bathrooms such as hair conditioners and hair treatments.
以下の実施例及び比較例において、pHは、すべて水で20重量倍に希釈したときの25℃における測定値である。 In the following Examples and Comparative Examples, pH is a value measured at 25 ° C. when diluted 20 times by weight with water.
実施例１〜６並びに比較例１及び２
下記方法により、表１に示す組成のヘアコンディショナーの製造及び評価を行った。
Examples 1-6 and Comparative Examples 1 and 2
The hair conditioner having the composition shown in Table 1 was produced and evaluated by the following method.
（製造法）
精製水を80℃に加熱し、酸及びノニオン性ポリマー（ヒドロキシエチルセルロース）を添加する（水相）。一方、成分(A)、高級アルコール（ステアリルアルコール）、油剤及び溶剤を80℃で混合溶解する（油相）。水相をプロペラ攪拌（１Ｌ程度の製造で約250rpm）しながら油相を添加し、約30分攪拌・乳化させる。60℃に冷却し、残りの酸を添加し、更に約30分攪拌する。成分(B)及び成分(C)を添加し、他のシリコーン類を添加する。その後45℃に冷却した後、その他の成分を添加し、30℃まで攪拌冷却し配合を終了する。
(Production method)
Purified water is heated to 80 ° C., and acid and nonionic polymer (hydroxyethylcellulose) are added (aqueous phase). On the other hand, component (A), higher alcohol (stearyl alcohol), oil agent and solvent are mixed and dissolved at 80 ° C. (oil phase). The oil phase is added while stirring the water phase with a propeller (about 250 rpm in the production of about 1 L), and stirred and emulsified for about 30 minutes. Cool to 60 ° C., add remaining acid and stir for about 30 minutes more. Component (B) and component (C) are added, and other silicones are added. Then, after cooling to 45 ° C., other components are added, and the mixture is stirred and cooled to 30 ° C. to finish blending.
（評価法）
未だパーマ、ヘアカラー等の化学処理をしたことのない20名の日本人女性の毛髪それぞれ約20ｇ（約15〜20cm）に対し、プリティアハイブリーチ（花王社）により、40℃、20分処理（浴比１：１）を２回繰り返した。シャンプーで洗浄後、表１のヘアコンディショナー２ｇを均一に塗布し、次いで30秒間流水ですすぎ流した後、ドライヤーにて乾燥した。
ヘアコンディショナーを使用した後、乾燥状態の「髪のまとまりやすさ」、「髪のしっとり感」、「パサつきのなさ」、「滑らかさ」、「髪の束感が綺麗に揃う」、「くし、ブラシや指の通りのよさ」、「傷んだ髪に効果がある」及び「翌日の洗髪時まで髪のまとまり／スタイルが持続」を、以下の基準に従って官能評価した。表１に20名の総得点スコアを示す。（最高点100点，最低点20点）
(Evaluation method)
About 20 g (about 15 to 20 cm) of hair of 20 Japanese women who have not yet been chemically treated with perm, hair color, etc., treated at 40 ° C. for 20 minutes with Prettyia Hybrid (Kao) The bath ratio 1: 1) was repeated twice. After washing with shampoo, 2 g of the hair conditioner shown in Table 1 was uniformly applied, then rinsed with running water for 30 seconds and then dried with a drier.
After using the hair conditioner, dry “easy to bundle hair”, “moist feeling of hair”, “no lump”, “smoothness”, “a feeling of bundled hair”, “comb, Sensory evaluation was performed according to the following criteria for “goodness of brush and finger passage”, “effective on damaged hair” and “maintenance of hair mass / style until the next day's hair wash”. Table 1 shows the total score score of 20 people. (Maximum 100 points, Minimum 20 points)
５：非常に効果がある。
４：やや効果がある。
３：どちらともいえない。
２：やや効果がない。
１：効果がない。
5: Very effective.
4: Slightly effective.
3: Neither can be said.
2: Slightly ineffective.
1: Not effective.
１)：単位(a)はＲ4＝Ｒ5＝ＣＨ3、ａ＝750、単位(b)はＲ6＝ＣＨ3、Ｒ7＝Ｃ18Ｈ37、ｂ＝750
２)：単位(a)はＲ4＝Ｒ5＝ＣＨ3、ａ＝500、単位(b)はＲ6＝ＣＨ3、Ｒ7＝Ｃ18Ｈ37、ｂ＝500
３)：単位(a)はＲ4＝Ｒ5＝ＣＨ3、ａ＝50、単位(b)はＲ6＝ＣＨ3、Ｒ7＝Ｃ18Ｈ37、ｂ＝50
４)：単位(a)はＲ4＝Ｒ5＝ＣＨ3、ａ＝500、単位(b)はＲ6＝ＣＨ3、Ｒ7＝Ｃ16Ｈ33、ｂ＝500
５)：単位(a)はＲ4＝Ｒ5＝ＣＨ3、ａ＝75、単位(b)はＲ6＝ＣＨ3、Ｒ7＝Ｃ16Ｈ33、ｂ＝75
６)：単位(a)はＲ4＝Ｒ5＝ＣＨ3、ａ＝500、単位(b)はＲ6＝ＣＨ3、Ｒ7＝Ｃ22Ｈ45、ｂ＝500
1): Unit (a) is R 4 = R 5 = CH 3 , a = 750, Unit (b) is R 6 = CH 3 , R 7 = C 18 H 37 , b = 750
2): Unit (a) is R 4 = R 5 = CH 3 , a = 500, unit (b) is R 6 = CH 3 , R 7 = C 18 H 37 , b = 500
3): Unit (a) is R 4 = R 5 = CH 3 , a = 50, Unit (b) is R 6 = CH 3 , R 7 = C 18 H 37 , b = 50
4): Unit (a) is R 4 = R 5 = CH 3 , a = 500, unit (b) is R 6 = CH 3 , R 7 = C 16 H 33 , b = 500
5): Unit (a) is R 4 = R 5 = CH 3 , a = 75, Unit (b) is R 6 = CH 3 , R 7 = C 16 H 33 , b = 75
6): Unit (a) is R 4 = R 5 = CH 3 , a = 500, unit (b) is R 6 = CH 3 , R 7 = C 22 H 45 , b = 500
実施例７ ヘアコンディショナー
（重量％）
ベヘニルトリメチルアンモニウムクロライド 1.5
ステアリルアルコール 3
セチルアルコール 2
ジプロピレングリコール 5
グリセリン 1
ドコシル変性シリコーン6) 0.3
トリステアリン酸グリセリル 0.3
ビスメトキシプロピルアミドイソドコサン 0.2
ジメチコーン含有エマルジョン
（東レ・ダウコーニング社，CF-2460） 2.5
リンゴ酸 0.1
乳酸 0.7
ハイブリッドヒマワリ油 0.3
加水分解シルク液 0.1
椿油 0.1
ベンジルオキシエタノール 0.3
ベンジルアルコール 0.2
ジペンタエリトリット脂肪酸エステル
（日清製油社、コスモール168AR） 0.3
フェノキシエタノール 0.1
イオン交換水 残量
Example 7 Hair Conditioner
(weight%)
Behenyltrimethylammonium chloride 1.5
Stearyl alcohol 3
Cetyl alcohol 2
Dipropylene glycol 5
Glycerin 1
Docosyl modified silicone 6) 0.3
Glyceryl tristearate0.3
Bismethoxypropylamide isodocosane 0.2
Dimethicone-containing emulsion (Toray Dow Corning, CF-2460) 2.5
Malic acid 0.1
Lactic acid 0.7
Hybrid sunflower oil 0.3
Hydrolyzed silk solution 0.1
Kerosene 0.1
Benzyloxyethanol 0.3
Benzyl alcohol 0.2
Dipentaerythritol fatty acid ester (Nisshin Oil Co., Cosmall 168AR) 0.3
Phenoxyethanol 0.1
Ion exchange water
上記ヘアコンディショナー（pH3.2）は、乾燥後の髪のまとまり、しっとり感、パサつきのなさ、滑らかさ及びくし・ブラシや指の通りのよさに優れており、髪の束感が綺麗に揃い、かつ傷んだ髪に効果がある。更に、翌日の洗髪時まで髪のまとまり／スタイルが持続し、しかも安定性にも優れるものであった。 The above hair conditioner (pH3.2) is excellent in the texture of the hair after drying, moist feeling, dryness, smoothness and the comfort of combs, brushes and fingers. Also effective for damaged hair. Furthermore, the hair mass / style was maintained until the next day's hair washes, and the stability was excellent.
実施例８ ヘアトリートメント
（重量％）
オクタデシロキシプロピルジメチルアミン 2.3
ステアリルアルコール 8
ジプロピレングリコール 3
オクタデシル変性シリコーン2) 0.1
トリベヘン酸グリセリル 0.1
ビスメトキシプロピルアミドイソドコサン 0.5
アミノ変性シリコーン 0.6
高重合メチルポリシロキサン（平均重合度2500） 1.0
ジメチルポリシロキサン（重合度600） 2.5
リンゴ酸 0.2
ベンジルアルコール 0.5
乳酸 1.8
ハイブリッドヒマワリ油 0.2
モノヒドロキシステアリン酸硬化ヒマシ油 0.3
イオン交換水 残量
Example 8 Hair Treatment
(weight%)
Octadecyloxypropyldimethylamine 2.3
Stearyl alcohol 8
Dipropylene glycol 3
Octadecyl-modified silicone 2) 0.1
Glyceryl tribehenate 0.1
Bismethoxypropylamide isodocosane 0.5
Amino-modified silicone 0.6
Highly polymerized methylpolysiloxane (average degree of polymerization 2500) 1.0
Dimethylpolysiloxane (degree of polymerization 600) 2.5
Malic acid 0.2
Benzyl alcohol 0.5
Lactic acid 1.8
Hybrid sunflower oil 0.2
Monohydroxystearic acid hydrogenated castor oil 0.3
Ion exchange water
上記のヘアトリートメント（pH3.3）は、乾燥後の髪のまとまり、しっとり感、パサつきのなさ、滑らかさ及びくし・ブラシや指の通りのよさに優れており、髪の束感が綺麗に揃い、かつ傷んだ髪に効果がある。更に、翌日の洗髪時まで髪のまとまり／スタイルが持続し、しかも安定性にも優れるものであった。 The above hair treatment (pH3.3) has excellent hair texture, bunch, dryness, smoothness, smoothness, combing, brushing and fingering. Also effective for damaged hair. Furthermore, the hair mass / style was maintained until the next day's hair washes, and the stability was excellent.
実施例９ ヘアトリートメント
（重量％）
セチルトリメチルアンモニウムクロライド 0.5
セトステアリルアルコール 1.6
高重合メチルポリシロキサンエマルション
（東レ・ダウコーニング社，シリコーンBY22-060） 1.0
パルミチン酸イソプロピル 2.0
オクタデシル変性シリコーン2) 0.2
トリベヘン酸グリセリル 0.1
ビスメトキシプロピルアミドイソドコサン 0.3
アミノ変性シリコーン 0.05
リンゴ酸 0.1
乳酸 0.05
ハイブリッドヒマワリ油 0.5
椿油 0.1
加水分解シルク液 0.1
香料 0.03
イオン交換水 残量
Example 9 Hair Treatment
(weight%)
Cetyltrimethylammonium chloride 0.5
Cetostearyl alcohol 1.6
Highly polymerized methylpolysiloxane emulsion (Toray Dow Corning, Silicone BY22-060) 1.0
Isopropyl palmitate 2.0
Octadecyl-modified silicone 2) 0.2
Glyceryl tribehenate 0.1
Bismethoxypropylamide isodocosane 0.3
Amino-modified silicone 0.05
Malic acid 0.1
Lactic acid 0.05
Hybrid sunflower oil 0.5
Kerosene 0.1
Hydrolyzed silk solution 0.1
Perfume 0.03
Ion exchange water
上記ヘアトリートメント（pH3.3）は、乾燥後の髪のまとまり、しっとり感、パサつきのなさ、滑らかさ及びくし・ブラシや指の通りのよさに優れており、髪の束感が綺麗に揃い、かつ傷んだ髪に効果がある。更に、翌日の洗髪時まで髪のまとまり／スタイルが持続し、しかも安定性にも優れるものであった。 The above hair treatment (pH3.3) is excellent in the unity of hair after drying, moist feeling, dryness, smoothness and the comfort of combs, brushes and fingers. Also effective for damaged hair. Furthermore, the hair mass / style was maintained until the next day's hair washes, and the stability was excellent.
Claims (1)
(A)カチオン界面活性剤
(B)炭素数12〜40の直鎖又は分岐鎖のアルキル基又はアルケニル基を有する脂肪酸と多価アルコールから導かれる脂肪酸エステル
(C)アルキル変性シリコーン An aqueous hair cosmetic containing components (A), (B) and (C).
(A) Cationic surfactant
(B) Fatty acid ester derived from a fatty acid having a linear or branched alkyl or alkenyl group having 12 to 40 carbon atoms and a polyhydric alcohol
(C) Alkyl modified silicone
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010254583A (en) * | 2009-04-21 | 2010-11-11 | Arimino Kagaku Kk | Hair cosmetic |
| JP2018104358A (en) * | 2016-12-27 | 2018-07-05 | 旭化成ワッカーシリコーン株式会社 | Oil-in-water type silicone emulsion composition |
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| JPH09175981A (en) * | 1995-12-27 | 1997-07-08 | Pola Chem Ind Inc | Cosmetic containing alpha-alkylphenethyl-modified silicone |
| JPH1036230A (en) * | 1996-07-17 | 1998-02-10 | Nikko Kemikaruzu Kk | Composition for hair cosmetic and hair cosmetic |
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| JPS63230620A (en) * | 1987-03-18 | 1988-09-27 | Asahi Denka Kogyo Kk | Hair rinse composition |
| JPH06298625A (en) * | 1993-04-20 | 1994-10-25 | Kao Corp | Hair treating agent composition |
| JPH09175981A (en) * | 1995-12-27 | 1997-07-08 | Pola Chem Ind Inc | Cosmetic containing alpha-alkylphenethyl-modified silicone |
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| JP2010254583A (en) * | 2009-04-21 | 2010-11-11 | Arimino Kagaku Kk | Hair cosmetic |
| JP2018104358A (en) * | 2016-12-27 | 2018-07-05 | 旭化成ワッカーシリコーン株式会社 | Oil-in-water type silicone emulsion composition |
| WO2018121966A1 (en) | 2016-12-27 | 2018-07-05 | Wacker Chemie Ag | Oil-in-water type silicone emulsion composition |
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