JP2008039377A - Article with water repellent part and hydrophilic part, and its manufacturing method - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a suitable structure for applying a heat exchange element for forming a thin film with water repellent property on a thin film with hydrophilic property. <P>SOLUTION: This article has a thin film having a water repellent part and a hydrophilic part. The hydrophilic part is formed of a first thin film formed on a base material. The first thin film is formed by two-dimensional or three-dimensional contact of particles covered with hydrophilic members, and the water repellent part is formed of a second thin film formed on the first thin film. The particle diameter of particles in the first thin film is to be 0.5-50 μm, the thickness of the members with hydrophilic property is to be at least 0.01 times as large as the grain diameter, and the thickness of the members with hydrophilic property positioned in the lower part of the second thin film is to be 0.01 to 0.5 times as large as the particle diameter. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to an article having a water repellent part and a hydrophilic part, and more particularly to an article suitably used as an article used as a member of a heat exchanger having a shape such as a pipe-shaped body or a plate-shaped body.

  For an article having a shape such as a pipe-shaped body or a plate-shaped body used as a heat exchanger member such as a heat pipe or a fin, the effective heat transfer area when the liquid refrigerant evaporates is increased. In order to obtain a large heat transfer efficiency, the surface of the member is made a hydrophilic surface.

  On the other hand, the treatment that makes the surface of the member water-repellent surface reduces the contact area between the liquid refrigerant and the member, and the condensing liquid refrigerant is scattered in the vapor refrigerant, which is effective when the vapor refrigerant is condensed. It has also been attempted to increase the heat transfer area and improve the heat transfer efficiency between the refrigerant and the member.

  Patent Document 1 discloses a structure in which the upper part on the inner wall surface side of the heat pipe is a hydrophilic surface and the lower part is a water-repellent surface. In this structure, the liquid refrigerant is repelled by the water-repellent surface at the lower part on the inner wall surface side and easily supplied to the hydrophilic surface at the upper part. At the same time, liquid refrigerant flows under the inner surface due to gravity. By these two interactions, the liquid film is equalized, the effective heat transfer area when the liquid refrigerant evaporates increases, and a large heat transfer efficiency is obtained between the refrigerant and the heat pipe.

  Patent Document 2 discloses a structure in which the windward side of a fin used in an air conditioner or the like is a water-repellent surface and the leeward side is a hydrophilic surface. With this structure, it is possible to prevent the condensed water from moving to the windward side.

  As described above, an article having a water repellent part and a hydrophilic part in one article improves the performance of heat exchange elements such as heat pipes and fins due to the interaction of physical properties of water repellent and hydrophilic. In recent years, these heat exchange elements have been used to transmit heat generated from heat sources such as LSI packages used in precision equipment such as notebook computers and small game machines to the outside of the equipment.

In these precision instruments, since the members used therein are integrated, and the instruments themselves tend to be miniaturized, the heat exchange elements used therefor are also required to be miniaturized.
JP-A-6-147784 JP-A-10-96569

  In a miniaturized heat exchange element or the like, the region where the water repellent part and the hydrophilic part are formed is limited. In order to improve the performance of heat exchange elements such as heat pipes and fins by the interaction between the water repellent properties and the hydrophilic properties as described above in this element, the distance between the water repellent part and the hydrophilic part It is necessary to make the water repellent part and the hydrophilic part adjacent to each other as short as possible. However, since water repellency and hydrophilicity are contradictory properties, it is not technically easy to realize the above-described adjacency. An object of the present invention is to provide an article having this preferred form, and to provide a structure in which a thin film exhibiting water repellency is formed on a thin film exhibiting hydrophilicity.

  In the present invention, as a result of intensive studies to overcome the above-described problems, a hydrophilic thin film is formed on the surface of the substrate, and a partially water-repellent thin film is formed on the hydrophilic thin film. I was inspired by that. And if a hydrophilic thin film has a specific surface shape, even if the surface is excellent in hydrophilicity, it has been found that a thin film exhibiting water repellency can be formed with good adhesion. It was.

  That is, the article of the present invention is an article having a water repellent part and a hydrophilic part, and the article has a base material and a thin film having a part exhibiting water repellency and a part exhibiting hydrophilicity, and has the hydrophilicity. The presenting portion is composed of a first thin film formed on a substrate, the first thin film is composed of particles coated with a hydrophilic member, and the portion exhibiting water repellency is the first thin film. Consists of a second thin film partially formed on the first thin film so that the particle diameter of the particles in the first thin film is 0.5 to 50 μm, thereby forming an uneven shape due to the particles on the first thin film. The second thin film, which is a portion exhibiting water repellency, is adhered to the first thin film exhibiting hydrophilicity.

  The shape of the first thin film formed on the substrate is mainly formed of particles. Then, by forming a thin film with the particle diameter of the particle being 0.5 to 50 μm, a unique uneven shape due to the shape of the particle is formed on the thin film surface. Further, due to the uneven shape, the second thin film which is a portion exhibiting water repellency can be formed with good adhesion even if the surface thereof is hydrophilic.

  And in this invention, since the said particle | grains are coat | covered with the member which exhibits hydrophilic property, the part in which the 2nd thin film was formed shows water repellency, and the part which has not formed shows hydrophilic property. As a result, each part becomes adjacent.

  The water repellency and hydrophilicity in the present invention are defined from the contact angle of water droplets obtained according to JIS R 3257 (1999). In the present invention, the case of 30 ° or less is hydrophilic, Among the hydrophilic properties, the case of 10 ° or less is referred to as superhydrophilic, the case of 90 ° or more as water repellency, and the case of water repellency as 120 ° or more as super water repellency.

  When the particle diameter is less than 0.5 μm, it is difficult to overcome the hydrophilicity of the first thin film and form the second thin film exhibiting water repellency with good adhesion. On the other hand, if it exceeds 50 μm, the durability of the thin film and the adhesion of the thin film to the substrate are lowered. In order to improve the durability of the thin film, the adhesion of the thin film to the substrate, and the adhesion of the second thin film to the first thin film, the particle diameter is 1 to 30 μm, and further 2 to 2. The thickness is preferably 20 μm.

  The said particle diameter is defined as a value of the average particle diameter obtained by the method based on JIS H0554 (1995). And it measures by the method based on this method, and the particle | grains which have the above-mentioned particle diameter are applied to this invention.

  In addition, the particles used in the present invention are preferably inorganic particles having a particle size in the above range, and among them, porous inorganic particles having a rough particle surface may be used. preferable.

  It is preferable that the shortest distance between the second thin film and the particle is 0.01 to 0.5 times the particle diameter. A hydrophilic member is disposed between the second thin film and the particles. Therefore, the shortest distance between the second thin film and the particles corresponds to the thickness of the hydrophilic member being coated. When the ratio is less than 0.01 times, it is necessary to separately increase the thickness of the hydrophilic member in the portion where the second thin film is not formed in order to exhibit hydrophilicity. As a result, it becomes difficult to achieve the object of adjoining the hydrophilic part and the water-repellent part, which are the objectives of the present invention.

  On the other hand, in the case of more than 0.5 times, the difference between the top and bottom of the specific surface irregularities for adhering the second thin film exhibiting water repellency becomes small, and the second thin film exhibiting water repellency can be adhered. It becomes difficult. And from a viewpoint of making the adhesiveness of a 2nd thin film favorable, it is 0.3 times or less of the said ratio, More preferably, it is preferable to set it as 0.25 times or less.

  The shortest distance between the second thin film and the particles can be measured by observing the cross section of the article with a scanning electron microscope. In the present invention, the cross-sectional observation of the article is performed five times, and the value of the shortest distance is selected from these five observations. This operation is repeated 5 times, and the arithmetic average of the selected values is set as the shortest distance between the second thin film and the particles. Then, by comparing this shortest distance value with the particle diameter, the ratio between the shortest distance between the second thin film and the particles and the particle diameter is determined.

  In the present invention, it is preferable that the thickness of the thinnest part of the outermost hydrophilic member is 0.01 times or more the particle diameter of the particles. This is because if it is less than 0.01 times, it is difficult to exert the hydrophilicity of the hydrophilic member. In order to easily exhibit hydrophilicity, the ratio is more preferably 0.05 times or more. The thickness of the hydrophilic member tends to improve as the thickness increases. From the viewpoint of improving the hydrophilicity, it is preferable to increase the thickness. Hereinafter, it is good also as 1 times or less.

  The thinnest portion described above can be measured by observing a cross section of the article with a scanning electron microscope. In the present invention, the cross-sectional observation of the article is performed five times, and the value of the thinnest portion is selected from these five observations. This operation is repeated five times, and the arithmetic average of the selected values is set as the thickness of the thinnest portion of the hydrophilic member located at the outermost position. Then, by comparing the thickness value with the particle diameter, the ratio between the second thin film and the shortest distance between the particles and the particle diameter is determined.

  The thickness of the first thin film is preferably 0.6 μm to 150 μm, more preferably 3 to 100 μm, and more preferably 5 to 50 μm. The lower limit of the thickness is defined by the particle diameter of the particles described above, and the upper limit is defined as being preferable from the viewpoint of cost. In addition, this thickness is guide | induced by the distance between a base material and the top part of the surface uneven | corrugated shape of a 1st thin film.

  This thickness can be measured by observing a cross section of the article with a scanning electron microscope. In the present invention, the cross-sectional observation of the article is performed five times, and the longest value in the distance is selected from the five observations. This operation is repeated five times, and the arithmetic average of the selected values is used as the thickness value.

  The second thin film preferably has a thickness of at least the same thickness as the difference between the top and bottom of the surface irregularities formed in the first thin film. When it has this thickness, it becomes easy for the second thin film to adhere to the first thin film, which is preferable.

  In the present invention, by forming the second thin film on the first thin film, the surface shape having the irregularities of the first thin film can be reflected on the surface of the second thin film. When this surface shape is reflected in the surface shape of the second thin film, it tends to exhibit water repellency which can be called super water repellency. For that purpose, the thickness of the second thin film is preferably 3 times or less, more preferably 2 times or less of the particle.

  The thickness of the second thin film can be measured by observing the cross section of the article with a scanning electron microscope. In the present invention, the cross-sectional observation of the article is performed five times, and the value of the thickest portion is selected from these five observations. This operation is repeated five times, and the arithmetic average of the selected values is taken as the thickness of the second thin film.

  In the present invention, it is preferable that the first thin film has a structure in which the particles are in two-dimensional or three-dimensional contact with each other. By adopting such a structure, it becomes easy to form an uneven surface structure suitable for the adhesion of the second thin film within the range of the particle diameter described above. The structure can be formed, for example, by forming a thin film made of particles on a base material and then coating a hydrophilic member.

  Moreover, it is preferable that the member which exhibits hydrophilicity consists of alkali silicate. Alkali silicate is a material with excellent hydrophilicity, and can exhibit excellent hydrophilicity even with a relatively thin thickness. For example, excellent hydrophilicity can be said to be superhydrophilic with a contact angle of water droplets of 10 ° C. or less. Can be realized.

  Furthermore, the article of the present invention may have gradually different contact angles of water droplets in the hydrophilic portion by gradually changing the thickness of the hydrophilic member. In this case, the hydrophilic member is particularly preferably made of an alkali silicate. This is because the hydrophilicity of the substance can be easily controlled by changing the thickness.

  The article having a water repellent part and a hydrophilic part according to the present invention comprises a step of applying a coating liquid 1 in which the particles are dispersed to a substrate and heating to obtain a precursor film, a member exhibiting hydrophilicity after the step, or a hydrophilic property. The step of applying and heating the coating liquid 2 into which the precursor of the presenting member is introduced to the precursor film to obtain the first thin film, and the member exhibiting water repellency or the precursor of the member exhibiting water repellency were introduced It is efficient and preferable to form the coating liquid 3 by a manufacturing method including a step of obtaining a second thin film by partially applying and heating the coating liquid 3 on the first thin film.

  The article having a water-repellent part and a hydrophilic part of the present invention uses the interaction between water repellent and hydrophilic properties because the distance between the water-repellent part and the hydrophilic part is adjacent to each other. It is possible to reduce the size of heat exchange elements such as heat pipes and fins. In addition, the water repellency of the water repellent part can be made super water repellent, and the hydrophilic part can be made super hydrophilic, so that the above-mentioned interaction can be exhibited more efficiently. Also successful in performance.

  The article of the present invention will be described with reference to the drawings. FIG. 1 is a diagram illustrating a cross-sectional shape of an article of the present invention. The article (1) having a water-repellent part and a hydrophilic part according to the present invention has a base material (2) and a thin film having a part exhibiting water repellency and a part exhibiting hydrophilicity. The first thin film (3) is formed on a substrate, and the first thin film is composed of particles (5) covered with a hydrophilic member (6). The portion exhibiting is composed of a “second thin film (4)” partially formed on the first thin film.

  As the particles (5), zeolite, silica gel, silica, alumina, titania, calcium carbonate, calcium oxide, talc, diatomaceous earth, vermiculite, leechite, petal, shell calcined calcium and the like can be used. Among these particles, diatomaceous earth, zeolite, silica gel, and shell calcined calcium are suitable because they can exhibit water absorption, antibacterial properties, etc. due to their porous properties, and can increase the added value of the article of the present invention. In particular, it is preferable to use calcined shell calcium.

  The above-mentioned shell calcined calcium is obtained by calcining a shell whose main component before firing is calcium carbonate, and is obtained by gradually decarboxylation (removing carbon dioxide), calcium oxide (CaO) or calcium oxide. And calcium carbonate. By firing, 99% of calcium carbonate, which is the main component before firing, is gradually converted to calcium oxide, and at the same time, firing of 1% of organic substances contained in the shell before firing also proceeds simultaneously. Regarding the firing temperature, when the firing temperature is increased, all of the calcium carbonate is converted to calcium oxide, but when the firing temperature is low, part of the calcium carbonate is changed to calcium oxide, but the rest remains as calcium carbonate.

  The component of the calcined shell shell calcium to be used is not particularly limited as long as a part of the calcium carbonate can be converted to calcium oxide. In the present invention, specifically, calcium carbonate as the main component of the shell and the calcined product thereof. It is preferable to use calcium oxide obtained by doing this, a mixture of calcium oxide and calcium carbonate, or a mixed state thereof (mixed calcium oxide and calcium carbonate). The proportions of calcium carbonate and calcium oxide and the respective components vary depending on the firing temperature and firing time, and can be adjusted as appropriate.

  The calcination temperature in the case of producing shell-calcined calcium is usually 500 to 1200 ° C. The firing time is appropriately adjusted in consideration of the firing temperature and the like.

  Specific examples of the calcined calcium shells used in the present invention include, for example, scallop shells as shells and pulverized products of the high-temperature calcined products (trade name CAI, particle size 5 μm type and 15 μm type, Japanese natural materials) Co., Ltd.) and low-temperature fired scallops (trade name CAV, particle size 5 μm type and 15 μm type, manufactured by Nippon Natural Materials Co., Ltd.). There are other manufacturers of shell-calcined calcium such as Shell Powder Company, Step Company, and Chafroze Company, but are not limited to the above-described manufacturers.

  The particles (5) described above are mixed with water, methanol, ethanol, i-propanol, n-propanol, n-butanol, i-butanol, t-butanol, methoxyethanol, ethoxyethanol and other alcohols, ethylene glycol, acetate, The coating liquid 1 is prepared by suspending a general solvent such as carboxylic acid, lower hydrocarbon, aliphatic, aromatic, or a mixture of these using a solvent comprising a solvent, and preferably adding a surfactant or the like. Prepared.

  As the hydrophilic member (6), a sol-gel method, an inorganic paint, or the like can be used. The sol-gel method can be obtained by using a precursor of a metal oxide having a reactive group such as alkoxide, oxyhalide, halide, nitrate, etc. as a raw material, and hydrolyzing and polycondensing it. Examples of the metal in the metal oxide include Li, Na, K, Mg, Ca, St, Ba, In, Ge, Bi, fe, Cu, Y, Zr, Ta, and other widely used Si. Ti, Al, Zr, etc. can be used.

  As said inorganic coating material, alkali silicates, such as lithium silicate, sodium silicate, potassium silicate, ammonium silicate, etc. can be used. And these inorganic coating materials may have hardening agents, such as metals, such as zinc, a metal oxide, a metal hydroxide, and a phosphate. When compared with the sol-gel method and those with inorganic paints, those with inorganic paints that are easy to obtain highly hydrophilic ones are preferred, and those with alkali silicates, especially lithium silicates are preferred.

  Preferably, a precursor of a metal oxide having a reactive group such as alkoxide, oxyhalide, halide or nitrate, alkali silicate such as sodium silicate or potassium silicate, or hydrophilic member material such as ammonium silicate, Diluted in a solvent, more preferably acidic catalyst such as hydrochloric acid, nitric acid, sulfuric acid, acetic acid, trifluoroacetic acid, phosphoric acid, polycarboxylic acid, sodium hydroxide, potassium hydroxide, ammonium hydroxide, triethylamine, diethylamine, Basic catalysts such as triethanolamine, diethanolamine, alkoxysilanes having amino groups may be included, and more preferably water (liquid) is also added.

Examples of the solvent include alcohols such as methanol, ethanol, propanol, butanol and 3-methyl-3-methoxy-1-butanol; glycols such as ethylene glycol and propylene glycol; ethylene glycol monomethyl ether and propylene glycol monomethyl ether , Ethers such as propylene glycol monobutyl ether and diethyl ether; ketones such as methyl isobutyl ketone and diisobutyl ketone; amides such as dimethylformamide and dimethylacetamide; ethyl acetate, ethyl cellosolve acetate, 3-methyl-3-methoxy-1 -Acetates such as butanol acetate; aromatic or aliphatic hydrocarbons such as toluene, xylene, hexane, cyclohexane, and γ- Butyrolactone, it is preferable to use N- methyl-2-pyrrolidone, an organic solvent such as dimethyl sulfoxide.

  The coating liquid 2 is prepared by mixing the raw material of the hydrophilic member as described above and the solvent described above. The coating liquid 1 and the coating liquid 2 may be mixed, and this mixed liquid may be applied to the base material to form the first thin film. However, the coating liquid 1 is applied to the base material, heated, It is preferable to apply the coating liquid 2 and heat it. And it is preferable to perform these heating at 50-200 degreeC. When the latter method is employed, it is preferable that the shape of the particles is easily reflected in the surface shape of the “first thin film (3)”.

  As means for applying these coating solutions to the substrate, known means such as dip coating, flow coating, spin coating, roll coating, spray coating, screen printing, flexographic printing and the like can be used. When the substrate is in the shape of a pipe such as a heat pipe, dip coating is optimal as the means for applying. Moreover, when a base material is a heat pipe, it is preferable to form in the inner surface of a thin film pipe.

  For the “second thin film (4)” exhibiting water repellency, those obtained by hydrolysis and polycondensation of fluorine-containing resin, silicone, fluoroalkylsilane, and mixtures thereof are preferably used. The In particular, it is preferable to use a fluorine-containing resin that easily makes the thickness of the thin film of the second layer the thickness mentioned in the previous section.

  Examples of the fluorine-containing resin described above include tetrafluoroethylene resin (PTFE), tetrafluoroethylene-perfluoroalkoxy-ethylene copolymer resin (PFA), and tetrafluoroethylene-hexafluoropropylene copolymer resin (FEP). ), Ethylene-tetrafluoroethylene copolymer (ETFE), polychlorotrifluoroethylene (PCTFE), ethylene-chlorotrifluoroethylene copolymer (ECTFE), polyvinylidene fluoride (PVDF), polyvinyl fluoride (PVF) Etc. are typical examples.

  Moreover, as said silicone, organopolysiloxane is typically used, and it is used from dimethylpolysiloxane, methylphenylpolysiloxane, dimethyl-methylphenylpolysiloxane polymer, fluorinated polysiloxane and the like. Of these organopolysiloxanes, those having silanol groups or alkoxysilyl groups at both ends, particularly dimethylpolysiloxane having both ends are preferably used.

  The resin to be the second thin film is preferably in the form of a fine powder and dispersed in a water-soluble suspension suspended using a surfactant, a fluorine-based solvent or an organic solvent. The resulting suspension can preferably be the third coating solution. The aforementioned suspension is available from the market as a fluorine paint.

  And as means for applying the third coating liquid onto the “first thin film (3)”, known means such as dip coating, flow coating, spin coating, roll coating, spray coating, screen printing, flexographic printing, etc. Can be done by. When the substrate is in the shape of a pipe such as a heat pipe, dip coating is optimal as the means for applying. Moreover, when a base material is a heat pipe, it is preferable to form in the inner surface of a thin film pipe. Further, the third coating liquid is supplied in an island shape on the “first thin film (3)” using a mask material or the like, and the “second thin film (4) is formed on the“ first thin film (3) ”. ) "May be formed in an island shape.

  And a 2nd thin film can be formed by heating after application | coating. Since this heating temperature is preferably performed at +30 to + 100 ° C. of the softening temperature of the resin, the heating temperature in this step is preferably 230 to 500 ° C.

  The material of the base material forming the present invention is aluminum, stainless steel, copper, silver, gold, highly conductive ceramic, carbon material, or glass. The article of the present invention is preferably a heat pipe, fin, It is used for thermal conversion elements such as.

  For example, in the case of a heat pipe, the knowledge that efficient heat transfer efficiency can be obtained by controlling the water droplet contact angle of the surface of the heat pipe that is in contact with hydraulic fluid such as water has been obtained in the present invention. Specific examples of this will be described in Examples.

  The heat pipe preferably has a water repellent part and a hydrophilic part on its inner surface, that is, the surface in contact with the hydraulic fluid, and the difference in water droplet contact angle between the water repellent part and the hydrophilic part is preferably 115 ° or more. When a hydrophilic portion is provided on the inner surface of the heat pipe, the amount of evaporation per unit area can be increased. Furthermore, when it has a water-repellent part on the inner surface, it becomes difficult for water to stay inside the heat pipe.

  And by making the difference of the water droplet contact angle between the hydrophilic part and the water repellent part 115 ° or more, the circulation efficiency of the working fluid (for example, water) in the heat pipe is improved, and the heat transfer performance as the heat pipe is improved. Contribute. In particular, when the hydrophilic portion is a heating portion, this improvement in circulation efficiency is significant. And by making it the structure where the water-repellent part and hydrophilic part of the said heat pipe adjoined, the heat transfer efficiency of a heat pipe improves and it becomes easy to reduce a heat pipe.

Example 1
1. Preparation of base material As a base material, a copper pipe having an inner diameter of 4 mm, a thickness of 0.5 mm and a length of 200 mm was prepared.

2. Preparation of Coating Solution 1 Baked shellfish calcium (trade name CAV, manufactured by Japan Natural Materials Co., Ltd.) obtained by firing scallops at about 800 ° C. was used. After pulverizing the shell calcined calcium to a particle size of 3 μm, 10% by weight of calcined shell calcium, 3% by weight of a nonionic surfactant, and 87% by weight of isopropyl alcohol are mixed and dispersed and mixed in an alumina ball mill for 4 hours. A shell-calcined calcium suspension was prepared.

  This suspension solution was diluted with ethanol so that the solid content concentration became 2.5%, and this was used as coating solution 1.

3. Preparation of Coating Liquid 2 An aqueous solution having lithium silicate having a SiO ₂ / Li ₂ O molar ratio of 3.5 / 1 and having a silicate concentration of 2 wt% was designated as coating liquid 2.

4). Preparation of Coating Solution 3 An aqueous solution containing 10 wt% of a fluorine-containing resin [Cefal Lube I (manufactured by Central Glass, softening temperature: melting point 340 ° C.)] was prepared.

5. Preparation of Articles All of the above-mentioned base material 1 was immersed in a bath for immersion containing the coating liquid 1 at room temperature for 3 minutes and then pulled up. Then, it heated at 120 degreeC for 1 hour. After cooling, the entire base material was further immersed in an immersion bath containing the coating solution 2 for 5 minutes and then pulled up. The first thin film was formed by heating at 120 ° C. for 1 hour and cooling.

  Next, the base material on which the first thin film was formed in the immersion bath containing the coating liquid 3 was immersed from the end of the pipe by 1/3 of the total length for 5 minutes. Thereafter, heating was performed at 390 ° C. for 1 hour to obtain an article having a water repellent part and a hydrophilic part.

6). Evaluation of article The contact angle of the water droplets of the first thin film and the second thin film of the obtained article was measured according to JIS R 3257 (1999). The JIS relates to a method for measuring the contact angle of water droplets on a glass plate, but the measurement method was also applied to the substrate in this example. Note that the evaluation of the first thin film in this evaluation was performed in a portion where the second thin film was not formed.

  Moreover, evaluation of the adhesiveness to the base material of the thin film 1 and the thin film 2 was performed by the cross-cut peel test. Cut 10 vertical and horizontal cuts into the thin film and peel off with an acetate film (mending tape; Yamato Co., Ltd .; product number OP-3-18) coated with acrylic adhesive on one side as an adhesive. When they were removed, the presence or absence of peeling was observed, and the number of peeled pieces in 100 frames was measured. Note that the evaluation of the first thin film in this evaluation was performed in a portion where the second thin film was not formed.

  Furthermore, the obtained article was cut, the cross-sectional shape of the thin film was observed with an operation electron microscope, and the measurement of the thickness of the thin film and the like was determined based on the provisions of the present invention.

  The obtained results are shown in Table 1. In addition to the excellent hydrophilicity and water repellency obtained with this Example article, both the thin films 1 and 2 showed excellent adhesion.

Example 2
Articles were obtained in the same procedure as in Example 1, except that the particle diameter was 10 μm in the preparation process of the coating liquid 1 and the immersion time when coating the coating liquid 3 was 10 minutes. The evaluation of the article was also performed in the same manner as in Example 1. The results are shown in Table 1. In addition to the excellent hydrophilicity and water repellency obtained with this Example article, both the thin films 1 and 2 showed excellent adhesion.

Example 3
Articles were obtained in the same procedure as in Example 2 except that the particles were changed to silicon nitride having a particle size of 10 μm in the preparation process of the coating liquid 1. The evaluation of the article was also performed in the same manner as in Example 1. The results are shown in Table 1. In addition to the excellent hydrophilicity and water repellency obtained with this Example article, both the thin films 1 and 2 showed excellent adhesion.

Example 4
An article was obtained in the same procedure as in Example 2 except that the particle diameter was changed to 20 μm in the preparation process of the coating liquid 1. The evaluation of the article was also performed in the same manner as in Example 1. The results are shown in Table 1. In addition to the excellent hydrophilicity and water repellency obtained with this Example article, both the thin films 1 and 2 showed excellent adhesion.

Comparative Example 1
Articles were obtained in the same procedure as in Example 1 except that the particles were changed to silicon nitride having a particle size of 0.4 μm in the preparation process of the coating liquid 1. The evaluation of the article was also performed in the same manner as in Example 1. The results are shown in Table 1. The adhesion of the second thin film was inferior.

Comparative Example 2
An article was obtained in the same procedure as in Example 2 except that the particle diameter was changed to 60 μm in the preparation process of the coating liquid 1. The evaluation of the article was also performed in the same manner as in Example 1. The results are shown in Table 1. Both the first and second thin films had poor adhesion.

[Performance evaluation of the articles obtained in Examples 1 to 4 as a heat pipe]
Water was put into the obtained article as a working fluid, and both ends were sealed to form a heat pipe. For comparison, a heat pipe was obtained by the same procedure as described above even for an article obtained by the same procedure as in Example 1 except that the second thin film was not formed. This is a standard sample. Heat the part where only the first thin film is formed from the one side end of the heat pipe to the pipe length direction until the surface of the pipe reaches 80 ° C, and immediately after reaching 80 ° C The time until the temperature of the heated part reached 40 ° C. was measured. And the measurement time in the heat pipe obtained from each Example was divided by the time required for the standard data to evaluate the performance as a heat pipe.

  As a result, 0.75 from Example 1, 0.7 from Example 2, 0.72 from Example 3, and 0.65 from Example 4 As a heat pipe, excellent heat transfer efficiency was observed. These are considered to be caused by the difference in the contact angle of water droplets between the hydrophilic portion (first thin film) and the water repellent portion (second thin film) being not less than 115 °.

  In particular, in Examples 2 and 4, the difference in the contact angle of the above-described water droplets is significantly different from 125 ° or more, and it is considered that a significant improvement in the heat transfer coefficient was observed. It is assumed that the larger the difference in the contact angle between the water droplets, the better. However, in consideration of the manufacturing cost and the like, it may be 150 ° or less, more preferably 145 ° or less.

It is principal part sectional drawing for demonstrating the articles | goods of this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Article which has water repellent part and hydrophilic part 2 Base material 3 1st thin film 4 2nd thin film 5 Particle 6 Member which exhibits hydrophilicity

Claims (7)

An article having a water-repellent part and a hydrophilic part, the article having a substrate and a thin film having a part exhibiting water repellency and a part exhibiting hydrophilicity, and the part exhibiting hydrophilicity is on the substrate The first thin film is formed, the first thin film is formed of particles coated with a hydrophilic member, and the water repellent portion is partially formed on the first thin film. It consists of a second thin film, and by forming the particle diameter of the particles in the first thin film to 0.5 to 50 μm, an uneven shape due to the particles is formed on the first thin film, and the portion exhibiting water repellency An article having a water-repellent part and a hydrophilic part, characterized in that a second thin film is adhered to the first thin film exhibiting hydrophilicity. The article having a water-repellent part and a hydrophilic part according to claim 1, wherein the shortest distance between the second thin film and the particle is 0.01 to 0.5 times the particle diameter. The article having a water-repellent part and a hydrophilic part according to claim 1 or 2, wherein the particles in the first thin film are in two-dimensional or three-dimensional contact with each other when the particles are in contact with each other. . The article having a water-repellent part and a hydrophilic part according to any one of claims 1 to 3, wherein the member exhibiting hydrophilicity is made of alkali silicate. The water-repellent part and the hydrophilic part according to any one of claims 1 to 4, wherein the water-repellent part and the hydrophilic part are gradually different from each other in that the contact angle of water droplets in the part exhibiting hydrophilicity is gradually different. The article you have. The article having a water-repellent part and a hydrophilic part according to any one of claims 1 to 5, wherein the substrate is a pipe-shaped body or a plate-shaped body used as a heat exchange element. Applying and heating the coating liquid 1 in which the particles are dispersed on a substrate to obtain a precursor film, and applying the coating liquid 2 into which a hydrophilic member or a precursor of a hydrophilic member is introduced after the step Applying and heating the precursor film to obtain the first thin film, and partially applying the coating liquid 3 into which the member exhibiting water repellency or the precursor of the member exhibiting water repellency is introduced onto the first thin film An article having a water repellent part and a hydrophilic part according to any one of claims 1 to 6, further comprising a step of obtaining a second thin film by heating.

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