JP2008013243A - Packaging process for hollow fiber cartridge - Google Patents

Packaging process for hollow fiber cartridge Download PDF

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JP2008013243A
JP2008013243A JP2006189061A JP2006189061A JP2008013243A JP 2008013243 A JP2008013243 A JP 2008013243A JP 2006189061 A JP2006189061 A JP 2006189061A JP 2006189061 A JP2006189061 A JP 2006189061A JP 2008013243 A JP2008013243 A JP 2008013243A
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hollow fiber
fiber membrane
bag
water
cartridge
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JP4919718B2 (en
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Akihiro Watanabe
昭広 渡辺
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Asahi Kasei Chemicals Corp
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Abstract

【課題】本発明は、複数本の中空糸膜からなり両端部が接着固定層で接着固定され、中空糸膜が露出し、水及び各種水溶液で処理された中空糸膜カートリッジにおいて、保管時及び輸送機における中空糸膜の乾燥及び中空糸膜の糸切れを防止するための包装方法を提供する。
【解決手段】複数本の中空糸膜からなり両端部が接着固定層4、5で接着固定され、中空糸膜が露出し、水及び各種水溶液で処理された中空糸膜カートリッジAを水蒸気遮断性の袋7に収め、更に、水蒸気遮断性の袋7に収めた中空糸膜カートリッジAをポリエチレンの袋8に収め、夫々の袋7、8を減圧して包装する。
【選択図】 図2
The present invention relates to a hollow fiber membrane cartridge comprising a plurality of hollow fiber membranes, both ends of which are adhesively fixed with an adhesive fixing layer, the hollow fiber membranes exposed, and treated with water and various aqueous solutions. Provided is a packaging method for preventing hollow fiber membrane drying and hollow fiber membrane breakage in a transport machine.
SOLUTION: A hollow fiber membrane cartridge A comprising a plurality of hollow fiber membranes, both ends of which are adhered and fixed by adhesive fixing layers 4 and 5 to expose the hollow fiber membranes and treated with water and various aqueous solutions, is water-blocking. Further, the hollow fiber membrane cartridge A contained in the water vapor blocking bag 7 is placed in a polyethylene bag 8, and each bag 7, 8 is decompressed and packaged.
[Selection] Figure 2

Description

本発明は複数本の中空糸膜からなり両端部が接着固定層で接着固定され、中空糸膜が露出し、水及び各種水溶液で処理された中空糸膜カートリッジの包装方法に関する。   The present invention relates to a packaging method for a hollow fiber membrane cartridge comprising a plurality of hollow fiber membranes, both ends of which are bonded and fixed by an adhesive fixing layer, the hollow fiber membrane is exposed, and treated with water and various aqueous solutions.

中空糸膜カートリッジは、中空糸膜がケースに収められて接着されたタイプと、ケースがなく両端部が接着剤で接着固定されて中空糸膜が露出したタイプと、が存在する(例えば特許文献1参照)。また、通常、中空糸膜カートリッジは中空糸膜束が現場で直ぐに使用できるように水又は各種水溶液で処理されている。   There are two types of hollow fiber membrane cartridges: a type in which a hollow fiber membrane is accommodated in a case and a type in which there is no case and both ends are bonded and fixed with an adhesive and the hollow fiber membrane is exposed (for example, Patent Documents) 1). In general, the hollow fiber membrane cartridge is treated with water or various aqueous solutions so that the hollow fiber membrane bundle can be used immediately on site.

特開平11−033366号公報Japanese Patent Laid-Open No. 11-033366

中空糸膜がケースに収められたタイプの中空糸膜カートリッジは、中空糸膜がケースに収められ接着されているために、保管中及び輸送中の中空糸膜の乾燥及び糸切れの発生はほとんどないが、中空糸膜が露出したタイプの中空糸膜カートリッジは、ケースがなく中空糸膜が露出しているため、保管中及び輸送中に中空糸膜の乾燥や、糸切れの発生等の問題がある。   Hollow fiber membrane cartridges that contain hollow fiber membranes in a case are almost free of drying and breakage of the hollow fiber membranes during storage and transportation because the hollow fiber membranes are contained in a case and bonded. However, hollow fiber membrane cartridges with exposed hollow fiber membranes do not have a case and the hollow fiber membranes are exposed, so problems such as drying of the hollow fiber membranes and occurrence of thread breakage during storage and transportation There is.

本発明は、中空糸膜が露出し、水又は各種水溶液で処理された中空糸膜カートリッジを保管及び輸送時における糸の乾燥及び糸切れを防止するための包装方法に関するものである。   The present invention relates to a packaging method for preventing drying and breakage of yarns during storage and transportation of a hollow fiber membrane cartridge in which a hollow fiber membrane is exposed and treated with water or various aqueous solutions.

本発明者らは、鋭意検討の結果、中空糸膜が露出し、水又は各種水溶液で処理された中空糸膜カートリッジの保管及び輸送時の中空糸膜の乾燥及び糸切れを防止する包装形態として、中空糸膜カートリッジを水蒸気遮断性の袋及びポリエチレン製の袋に挿入して減圧包装することにより保管及び輸送時の中空糸膜の乾燥及び糸切れを防止出来ることを見出し、本発明に至った。   As a packaging form for preventing hollow fiber membranes from drying and thread breakage during storage and transportation of hollow fiber membrane cartridges exposed to water or various aqueous solutions as a result of intensive studies. The present inventors have found that the hollow fiber membrane cartridge can be prevented from drying and breaking of the hollow fiber membrane during storage and transportation by inserting the hollow fiber membrane cartridge into a water vapor blocking bag and a polyethylene bag and packaging under reduced pressure. .

即ち、本発明は以下の通りである。   That is, the present invention is as follows.

複数本の中空糸膜からなり両端部が接着固定層で接着固定され、中空糸膜が露出し、水及び各種水溶液で処理された中空糸膜カートリッジを水蒸気遮断性の袋に収め、更に、水蒸気遮断性の袋に収めた中空糸膜カートリッジをポリエチレンの袋に収め、夫々の袋を減圧して包装することを特徴とする中空糸膜カートリッジの包装方法。   The hollow fiber membrane is composed of a plurality of hollow fiber membranes, and both ends thereof are bonded and fixed with an adhesive fixing layer, the hollow fiber membranes are exposed, and a hollow fiber membrane cartridge treated with water and various aqueous solutions is placed in a water vapor blocking bag. A packaging method for a hollow fiber membrane cartridge, wherein the hollow fiber membrane cartridge housed in a barrier bag is placed in a polyethylene bag, and each bag is decompressed and packaged.

本発明により、中空糸膜が露出し、水及び各種水溶液で処理されたカートリッジの保管及び輸送において中空糸膜の乾燥及び糸切れを防止することが出来る。   According to the present invention, the hollow fiber membrane is exposed, and drying and breakage of the hollow fiber membrane can be prevented in storage and transportation of cartridges treated with water and various aqueous solutions.

本発明の中空糸膜カートリッジの包装方法に適用される中空糸膜カートリッジの構造の一例を図1により説明する。本中空糸膜カートリッジAは、複数本の中空糸膜からなる中空糸膜束1と、中空糸膜束1の両端にカートリッジヘッド2と下部リング3とを有し、カートリッジヘッド側接着固定層4、及び下部リング側接着固定層5で中空糸膜を固定している。カートリッジヘッド2と下部リング3は側芯棒6により連結されている。   An example of the structure of the hollow fiber membrane cartridge applied to the hollow fiber membrane cartridge packaging method of the present invention will be described with reference to FIG. This hollow fiber membrane cartridge A has a hollow fiber membrane bundle 1 composed of a plurality of hollow fiber membranes, a cartridge head 2 and a lower ring 3 at both ends of the hollow fiber membrane bundle 1, and a cartridge head side adhesive fixing layer 4 The hollow fiber membrane is fixed by the lower ring side adhesive fixing layer 5. The cartridge head 2 and the lower ring 3 are connected by a side core rod 6.

この中空糸膜カートリッジAは、水及び各種水溶液(例えば塩化カルシウム水溶液、グリセリン水溶液等が掲げられる)によって濡れた状態に処理されている。   The hollow fiber membrane cartridge A is treated in a wet state with water and various aqueous solutions (for example, calcium chloride aqueous solution, glycerin aqueous solution, etc.).

本発明の包装方法は、図2に示すように、上記の如く構成された中空糸膜カートリッジAを、水蒸気遮断性の袋7に挿入して収める。さらに、中空糸膜カートリッジAを挿入した水蒸気遮断性の袋7をポリエチレン製の袋8に挿入して収めた後、水蒸気遮断性の袋7及びポリエチレン製の袋8それぞれを、上部より減圧した後、ヒートシーラーでシールして減圧包装を行う。減圧包装により中空糸膜束1が袋7、8でしっかり固定され、袋内で中空糸膜が揺れることがなくなる。   In the packaging method of the present invention, as shown in FIG. 2, the hollow fiber membrane cartridge A configured as described above is inserted and stored in a water vapor blocking bag 7. Further, after the water vapor blocking bag 7 having the hollow fiber membrane cartridge A inserted therein is inserted and stored in the polyethylene bag 8, each of the water vapor blocking bag 7 and the polyethylene bag 8 is depressurized from above. Then, seal with a heat sealer and pack under reduced pressure. The hollow fiber membrane bundle 1 is firmly fixed by the bags 7 and 8 by the decompression packaging, and the hollow fiber membrane is not shaken in the bag.

特に、水蒸気遮断性の袋7により水の外部への蒸発が防止される。水蒸気遮断性の袋7としては、厚みが0.03〜0.1mm程度で水蒸気透過性がASTM−F1249(38℃ 90%)の測定で10g/m2 ・day以下であり、例えば塩化ビニリデン、真空蒸着フィルム等の袋が掲げられるが、これらに限定されるものではない。 In particular, the water vapor blocking bag 7 prevents evaporation of water to the outside. The water vapor barrier bag 7 has a thickness of about 0.03 to 0.1 mm and a water vapor permeability of 10 g / m 2 · day or less as measured by ASTM-F1249 (38 ° C. 90%). For example, vinylidene chloride, Although bags, such as a vacuum evaporation film, are hung up, it is not limited to these.

水蒸気遮断性の袋7だけではカートリッジ取り扱い中に傷、こすれ等により破れが発生した場合、中空糸膜カートリッジAの中空糸膜の乾燥、糸切れを防止が困難である。そのため、水蒸気遮断性の袋7の外側に破れ防止のための厚めの袋を必要とする。   If the water vapor barrier bag 7 alone is broken due to scratches, rubbing or the like during handling of the cartridge, it is difficult to prevent the hollow fiber membrane of the hollow fiber membrane cartridge A from being dried and from being broken. Therefore, a thick bag for preventing tearing is required outside the water vapor blocking bag 7.

厚めで減圧により中空糸膜カートリッジAを固定するためには柔軟性が必要で、素材としてはポリエチレン製の袋8が好適である。ポリエチレン製の袋8の厚みは0.1〜0.3mmが好ましく、減圧包装されることにより、より強固に中空糸膜が固定され、水蒸気遮断性の袋7の傷、破れを防止し、中空糸膜の乾燥及び糸切れを防止できる。   In order to fix the hollow fiber membrane cartridge A with a thick and reduced pressure, flexibility is required, and a polyethylene bag 8 is suitable as a material. The thickness of the polyethylene bag 8 is preferably 0.1 to 0.3 mm, and by packing under reduced pressure, the hollow fiber membrane is more firmly fixed, and the water-blocking bag 7 is prevented from being scratched or broken. It is possible to prevent the yarn film from drying and breaking.

カートリッジヘッド2及び、下部リング3端部による中空糸膜の糸切れを更に防止する為に、カートリッジヘッド2、下部リング3部分に発泡ポリエチレンシート9を巻いて、水蒸気遮断性の袋7、ポリエチレンの袋8を減圧包装することも出来る。   In order to further prevent thread breakage of the hollow fiber membrane due to the cartridge head 2 and the lower ring 3 end, a polyethylene foam sheet 9 is wound around the cartridge head 2 and the lower ring 3 to form a water vapor blocking bag 7 and polyethylene. The bag 8 can be packaged under reduced pressure.

[実施例]
本発明の実施例を以下に説明するが、それによって本発明が限定されることはない。
[Example]
Examples of the present invention will be described below, but the present invention is not limited thereby.

複数の中空糸膜の両端をウレタン樹脂で接着固定し、一方の端部外周に液密に接着固定されたカートリッジヘッド2と他方端部外周に液密に接着固定された下部リング3とを有し、膜面積25m2 の円筒形の中空糸膜カートリッジAを作成した。 Both ends of a plurality of hollow fiber membranes are bonded and fixed with urethane resin, and a cartridge head 2 that is liquid-tightly bonded and fixed to the outer periphery of one end and a lower ring 3 that is bonded and fixed to the outer periphery of the other end are liquid-tight. A cylindrical hollow fiber membrane cartridge A having a membrane area of 25 m 2 was prepared.

接着はウレタン樹脂(サンユレック社製)を使用し、遠心接着を行った。遠心接着の際、カートリッジヘッド側接着固定層4と下部リング側接着固定層5とをSUS304製の外径13mmのパイプを2本用いて連結固定化した。   Adhesion was performed using a urethane resin (manufactured by Sanyu Rec) and centrifugal adhesion was performed. At the time of centrifugal bonding, the cartridge head side adhesive fixing layer 4 and the lower ring side adhesive fixing layer 5 were connected and fixed using two pipes made of SUS304 having an outer diameter of 13 mm.

この中空糸膜カートリッジAを水で処理し、下部リング3及びその上部にある中空糸膜束1に発泡ポリエチレンシート9を巻いた後、この中空糸膜カートリッジAを水蒸気遮断性を有するバリアロンS(旭化成製)製の袋7、及びポリエチレンの袋8に入れ、上部より減圧してヒートシールを行い包装した。   This hollow fiber membrane cartridge A is treated with water, and after the foamed polyethylene sheet 9 is wound around the lower ring 3 and the hollow fiber membrane bundle 1 at the upper part thereof, the hollow fiber membrane cartridge A is removed from the water barrier barrier S ( Asahi Kasei Co., Ltd.) bag 7 and polyethylene bag 8 were depressurized from above and sealed by heat sealing.

このようにして包装された中空糸膜カートリッジAをダンボールに箱詰し、トラックにて2000km走行後、漏れ検査を実施したところ漏れはなかった。また、6ヶ月放置後漏れ検査を実施したが、漏れはなかった。   The hollow fiber membrane cartridge A thus packaged was boxed in cardboard, and after running 2000 km on a truck, a leak test was conducted, and there was no leak. In addition, leakage inspection was conducted after 6 months of standing, but there was no leakage.

[比較例1]
複数の中空糸膜の両端をウレタン樹脂で接着固定し、一方の端部外周に液密に接着固定されたカートリッジヘッド2と他方端部外周に液密に接着固定された下部リング3とを有し、膜面積25m2 の円筒形の中空糸膜カートリッジAを作成した。
[Comparative Example 1]
Both ends of a plurality of hollow fiber membranes are bonded and fixed with urethane resin, and a cartridge head 2 that is liquid-tightly bonded and fixed to the outer periphery of one end and a lower ring 3 that is bonded and fixed to the outer periphery of the other end are liquid-tight. A cylindrical hollow fiber membrane cartridge A having a membrane area of 25 m 2 was prepared.

接着はウレタン樹脂(サンユレック社製)を使用し、遠心接着を行った。遠心接着の際、カートリッジヘッド側接着固定層4と下部リング側接着固定層5とをSUS304製の外径13mmのパイプを2本用いて連結固定化した。   Adhesion was performed using a urethane resin (manufactured by Sanyu Rec) and centrifugal adhesion was performed. At the time of centrifugal bonding, the cartridge head side adhesive fixing layer 4 and the lower ring side adhesive fixing layer 5 were connected and fixed using two pipes made of SUS304 having an outer diameter of 13 mm.

この中空糸膜カートリッジAを水で処理し、ポリエチレンの袋に入れ、ヒートシールを行い包装した。   This hollow fiber membrane cartridge A was treated with water, placed in a polyethylene bag, heat sealed and packaged.

この包装された中空糸膜カートリッジAをダンボールに箱詰し、トラックにて2000km走行後、漏れ検査を実施したところ3本の漏れが発生し、漏れ個所を確認したところ、下部リング3上部での糸切れが確認された。また、6ヶ月放置後漏れ検査を実施したが、5本の漏れが発生し、漏れ個所を確認したところ、糸が乾燥している部位が確認され、その部位から漏れが発生していた。   The packaged hollow fiber membrane cartridge A is packaged in cardboard, and after running 2000 km on a truck, leak inspection is performed. When three leaks are detected, the leak location is confirmed. Thread breakage was confirmed. In addition, a leak inspection was conducted after being left for 6 months, but 5 leaks occurred, and when the leak location was confirmed, a portion where the yarn was dry was confirmed, and a leak occurred from that portion.

本発明の中空糸膜カートリッジの包装方法は、中空糸膜が露出し、且つ水及び各種水溶液で処理された中空糸膜カートリッジを包装する際に利用して有利である。   The method for packaging a hollow fiber membrane cartridge of the present invention is advantageous when packaging a hollow fiber membrane cartridge in which the hollow fiber membrane is exposed and treated with water and various aqueous solutions.

中空糸膜カートリッジの構造の一例を説明する図である。It is a figure explaining an example of the structure of a hollow fiber membrane cartridge. 水蒸気遮断性の袋と、ポリエチレンの袋とによって包装した中空糸膜カートリッジを説明する図である。It is a figure explaining the hollow fiber membrane cartridge packaged with the water-vapor-shielding bag and the polyethylene bag.

符号の説明Explanation of symbols

A 中空糸膜カートリッジ
1 中空糸膜束
2 カートリッジヘッド
3 下部リング
4 カートリッジヘッド側接着固定層
5 下部リング側接着固定層
6 側芯棒
7 水蒸気遮断性の袋
8 ポリエチレン製の袋
9 発泡ポリエチレンシート
A hollow fiber membrane cartridge 1 hollow fiber membrane bundle 2 cartridge head 3 lower ring 4 cartridge head side adhesive fixing layer 5 lower ring side adhesive fixing layer 6 side core rod 7 water vapor blocking bag 8 polyethylene bag 9 foamed polyethylene sheet

Claims (1)

複数本の中空糸膜からなり両端部が接着固定層で接着固定され、中空糸膜が露出し、水及び各種水溶液で処理された中空糸膜カートリッジを水蒸気遮断性の袋に収め、更に、水蒸気遮断性の袋に収めた中空糸膜カートリッジをポリエチレンの袋に収め、夫々の袋を減圧して包装することを特徴とする中空糸膜カートリッジの包装方法。 The hollow fiber membrane is composed of a plurality of hollow fiber membranes, and both ends thereof are bonded and fixed with an adhesive fixing layer, the hollow fiber membranes are exposed, and a hollow fiber membrane cartridge treated with water and various aqueous solutions is placed in a water vapor blocking bag. A packaging method for a hollow fiber membrane cartridge, wherein the hollow fiber membrane cartridge housed in a barrier bag is placed in a polyethylene bag, and each bag is decompressed and packaged.
JP2006189061A 2006-07-10 2006-07-10 Packaging method for hollow fiber membrane cartridge Active JP4919718B2 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014201346A (en) * 2013-04-05 2014-10-27 旭化成メディカル株式会社 Packaging material of membrane module
JP2016040026A (en) * 2014-08-12 2016-03-24 オルガノ株式会社 Reverse osmosis membrane module and method for storage of reverse osmosis membrane

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05221461A (en) * 1992-02-04 1993-08-31 Teijin Ltd Packaging bag
JP2004195380A (en) * 2002-12-19 2004-07-15 Toray Ind Inc Package of liquid separation membrane module, method for manufacturing the package and method for preserving the module
JP2005066389A (en) * 2003-08-25 2005-03-17 Toyobo Co Ltd Preservation pack and preservation method of selectively permeable separation membrane
JP2006143235A (en) * 2004-11-17 2006-06-08 Daicen Membrane Systems Ltd Packing method of hollow fiber membrane bundle

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05221461A (en) * 1992-02-04 1993-08-31 Teijin Ltd Packaging bag
JP2004195380A (en) * 2002-12-19 2004-07-15 Toray Ind Inc Package of liquid separation membrane module, method for manufacturing the package and method for preserving the module
JP2005066389A (en) * 2003-08-25 2005-03-17 Toyobo Co Ltd Preservation pack and preservation method of selectively permeable separation membrane
JP2006143235A (en) * 2004-11-17 2006-06-08 Daicen Membrane Systems Ltd Packing method of hollow fiber membrane bundle

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014201346A (en) * 2013-04-05 2014-10-27 旭化成メディカル株式会社 Packaging material of membrane module
JP2016040026A (en) * 2014-08-12 2016-03-24 オルガノ株式会社 Reverse osmosis membrane module and method for storage of reverse osmosis membrane

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