JP2008012471A - Prevention of scattering of scatterable dust of asbestos, or fixing liquid thereof - Google Patents

Prevention of scattering of scatterable dust of asbestos, or fixing liquid thereof Download PDF

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JP2008012471A
JP2008012471A JP2006187831A JP2006187831A JP2008012471A JP 2008012471 A JP2008012471 A JP 2008012471A JP 2006187831 A JP2006187831 A JP 2006187831A JP 2006187831 A JP2006187831 A JP 2006187831A JP 2008012471 A JP2008012471 A JP 2008012471A
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dust
asbestos
scattering
fixing liquid
thickener
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JP4373416B2 (en
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Akitaka Furuya
晃敬 古矢
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Abstract

<P>PROBLEM TO BE SOLVED: To surely and economically suppress or prevent scattering of dust (asbestos dust) caused by weathering of sprayed material of asbestos or demolition. <P>SOLUTION: An appropriate amount of fixing liquid formed by homogeneously blending a surfactant and a thickener to a solution of polysaccharide like gum arabic, is sprayed to the sprayed material of asbestos to moisturize/fix dust of weathered sprayed material, to suppress or prevent scattering of dust caused by demolition. Even if the fixing liquid is dried, scattering of dust caused by demolition of the treating object can be suppressed or prevented, by re-moisturizing with water and recovering viscosity of the fixing liquid. Inclusion of water into the thickener swells the volume thereof to facilitate exfoliation of the treating object. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、アスベスト等を含む断熱・耐火又は結露防止・保温・吸音用吹き付け材等の風化又はアスベスト等を含む建材及び焼却炉の解体工事又は微生物濾過フィルター(HEPAフィルター)の交換・撤去工事等に伴い発生する粉塵(アスベスト粉末、ダイオキシンを含む灰、ウィルス等微生物を含む塵埃等)の固定又は飛散防止及び殺菌を目的とする粉塵の飛散防止又は固定(着)液に関する。   The present invention includes insulation, fire resistance or anti-condensation including asbestos, etc., weathering of spraying materials for heat insulation and sound absorption, etc., construction materials including asbestos, etc., and dismantling of incinerators, replacement / removal of microbial filtration filters (HEPA filters), etc. The present invention relates to a dust scattering preventive or fixing (fixing) liquid for the purpose of fixing or preventing dust and dust (asbestos powder, ash containing dioxin, dust containing microorganisms such as viruses) and the like, and sterilization.

アスベスト等を含む吹き付け材の風化又は解体工事に伴い発生する粉塵(アスベスト粉末)は風に載って広く空間に飛散して、近接する広範囲の住民の健康に悪影響を及ぼす事が、近来問題視されている。
そこで、既設のアスベスト等の風化吹き付け材の撤去又は風化アスベストを含む建材の解体・撤去が急がれている現状であるが、従来、吹き付け材の風化アスベスト又はアスベストを含む建材の解体・撤去工事に伴い発生する粉塵の飛散防止方法としては、事前に工事対象物を幕で蔽って外界と遮断するとか、既設の吹き付け材に界面活性剤を含む水を散布して充分に湿潤させ工事中の粉塵の発生を抑制し、吹き付け材等を除去後、さらに表面に有機高分子樹脂剤を含む液を塗布して残存する粉塵を固定すると言った方法が一般的に採られていた。
Dust (asbestos powder) generated during the weathering or demolition work of spray materials containing asbestos, etc., has been seen as a problem in the near future, as it spreads in the wind and spreads widely into the space, adversely affecting the health of a wide range of nearby residents. ing.
Therefore, there is an urgent need for the removal of existing weathered spray materials such as asbestos or the dismantling / removal of building materials containing weathered asbestos. In order to prevent dust from being scattered, the construction object should be covered with a curtain in advance to shut it off from the outside, or the existing spraying material may be sprayed with water containing a surfactant and thoroughly wetted. In general, after the removal of the spraying material and the like is suppressed, the liquid containing the organic polymer resin agent is applied to the surface to fix the remaining dust.

しかしながら、単に幕を用いて施工対象物を外界と遮断するだけでは、粉塵の飛散を防止する目的を充分に果たすことが困難で、これは補助的な手段に過ぎない。
水を散布して粉塵の発生を抑制する方法は、単に被処理材に水を浸透させて湿潤し粉塵の発生を抑制する操作であるから、工事中、対象物が乾燥しないようするために大量の水を必要とする。従って、施工前に排水処理の設備を整える必要がある事や、それにより生じた汚泥についても、乾燥後であれば粉塵が再発生して了う事になるので、別途、飛散防止処理が必要になる等の問題がある。
However, it is difficult to sufficiently achieve the purpose of preventing dust scattering simply by using a curtain to block the construction object from the outside world, and this is only an auxiliary means.
The method of suppressing the generation of dust by spraying water is simply an operation that suppresses the generation of dust by infiltrating water into the material to be treated to prevent the generation of dust during construction. Need water. Therefore, it is necessary to prepare wastewater treatment facilities before construction, and the resulting sludge will be regenerated after drying. There are problems such as becoming.

また、有機高分子樹脂剤等を含む液を塗布した場合は、樹脂に含まれる揮発性溶剤の蒸発により、施工時の閉鎖空間における当該揮発性溶剤の濃度管理及び有毒発生ガスの処理が必要になって来る事。更には、乾燥すると被処理材とコンクリート面や鉄骨の表面等の部材との接着性が向上するため、解体時の処理が難しくなる、等の問題がある。
即ち、時間が経つと剥離・解体時に粉塵が発生し易くなる。
In addition, when a liquid containing an organic polymer resin agent or the like is applied, the concentration of the volatile solvent in the closed space at the time of construction and treatment of the toxic gas is required due to evaporation of the volatile solvent contained in the resin. What will come. Furthermore, since the adhesion between the material to be treated and a member such as a concrete surface or the surface of a steel frame improves when dried, there is a problem that it becomes difficult to dispose of the material during disassembly.
That is, when time passes, dust tends to be generated during peeling and dismantling.

建築物の解体等工事における「石綿粉じんへのばく露防止マニュアル」 建設業労働災害防止協会企画開発課 平成17年8月9日 初版発行“Exposure Prevention Manual for Asbestos Dust” in the Demolition of Buildings Construction and Industrial Accident Prevention Association Planning and Development Division August 9, 2005 First edition issued

解決しようとする問題点は、上記従来法に内在する欠陥を除去し、簡単、経済的な手段で風化又は解体に伴い、吹き付け材等から発生する粉塵(アスベスト粉末)が広く空間に飛散するのを効果的に固定若しくは抑制する湿潤・固定液を提供し、以って、アスベストを含む吹き付け材の処理/解体環境を衛生的にし、且つ、処理工事を促進する事を目的とする。   The problem to be solved is that the defects inherent in the above-mentioned conventional method are removed, and dust (asbestos powder) generated from the spraying material etc. is widely scattered in the space with weathering or dismantling by simple and economical means. The purpose of the present invention is to provide a moistening / fixing solution that effectively fixes or suppresses the above, thereby sanitizing the treatment / disassembly environment of the spray material containing asbestos and promoting the treatment work.

本発明は、アラビア・ゴムなどの多糖類水溶液に界面活性剤と増粘剤とを均質に配合したアスベスト等の飛散性粉塵の湿潤・固定液を用意して、これを吹き付け材などの被処理物に噴霧・自然浸透させ湿潤し、粉塵を固定する事を特徴とする。   The present invention provides a wet / fixing solution for scattering dust such as asbestos, in which a surfactant and a thickener are uniformly mixed in an aqueous polysaccharide solution such as gum arabic and gum, and this is treated with a spraying material or the like. It is characterized by fixing the dust by spraying and spontaneously penetrating objects.

(a)本液は、界面活性剤を適量配合する事により、被処理物に対し自然浸透し易くして湿潤効果を奏する事及び殺菌効果を生じる事を可能にする。
(b)対象物を湿潤後は、アラビア・ゴムなどの粘性によって粉塵(アスベスト粉末)を固着して飛散を抑制し、乾燥後は、固定する。
(c)増粘剤は、湿潤状態では粘性向上による固定に相乗するが、接着性に劣るので、乾燥後の再湿潤により、剥離し易くなる。
(A) By mixing an appropriate amount of a surfactant, the present liquid can easily permeate into an object to be treated, thereby exerting a wetting effect and producing a bactericidal effect.
(B) After wetting the object, dust (asbestos powder) is fixed by viscosity such as gum arabic and rubber to suppress scattering, and fixed after drying.
(C) Although the thickener synergizes with the fixation by improving the viscosity in a wet state, it is poor in adhesiveness, so that it is easily peeled off by re-wetting after drying.

(d)液が乾燥した後であっても、再び水分を補給するだけで液の粘性が復活して粉塵の発生を抑制する事が出来る。つまり、一端、固定液を施工した対象物は粉塵が固着され、粉塵の飛散を抑制(防止)する。又、乾燥後であっても水分を再補給する事によって、簡単に液(固化部位)が粘性を復活し、粉塵の飛散を抑制できる。かつ、増粘剤等の効果により剥離し易くなる。
(e)本液の使用によって、一度の噴霧で対象物の湿潤・固定が可能である。
(f)更に、本液は単に溶液である事から、施工に当たり有害ガスの発生の恐れが無い。
(D) Even after the liquid has dried, the viscosity of the liquid can be restored and the generation of dust can be suppressed by replenishing the water again. In other words, dust is fixed to the object to which the fixing liquid has been applied at one end, thereby suppressing (preventing) dust scattering. Moreover, even after drying, by replenishing the water, the liquid (solidified part) can easily recover its viscosity and suppress dust scattering. And it becomes easy to peel by the effect of a thickener or the like.
(E) By using this liquid, it is possible to wet and fix the object with a single spray.
(F) Furthermore, since this liquid is simply a solution, there is no risk of generation of harmful gases during construction.

(g)即ち、アラビア・ゴムなどの多糖類水溶液に界面活性剤と増粘剤とを均質に配合した固定液を、風化したアスベスト等の吹き付け材に対して噴霧し自然浸透させ、当該液の粘着性により吹き付け材に内在する粉塵となり得る物質を固着し、粉塵が風化又は解体処理時に外界に飛散する事を防止する効果を得るものである。 (G) That is, a fixative solution in which a surfactant and a thickener are homogeneously blended in an aqueous solution of polysaccharides such as gum arabic and rubber is sprayed onto a spraying material such as weathered asbestos to allow natural penetration. A substance that can become dust existing in the spraying material is fixed due to adhesiveness, and the effect of preventing dust from scattering to the outside during weathering or dismantling treatment is obtained.

本液の噴霧処理後に吹き付け材等が乾燥しても、水分を再補給する事により、固定液の粘性が容易に復活するため、処理後、長時間経っても、剥離・解体作業時の粉塵発生を抑制することが出来る。又、増粘剤は水分を含む事により、体積が膨張し、接着性が劣る状態を発揮できるので処理済み吹き付け材が基材から剥離し易くなる。処理済み吹き付け材等は固定液に滑沢性がが生じるので、綺麗に剥離し易く剥離後も粉塵が発生しない。   Even if the spraying material is dried after spraying this liquid, the viscosity of the fixative is easily restored by replenishing the water. Generation can be suppressed. Further, since the thickener contains moisture, the volume expands and the adhesiveness is inferior, so that the treated spraying material is easily peeled off from the substrate. Since the treated spraying material has lubricity in the fixing solution, it is easy to peel off cleanly and does not generate dust after peeling.

ダイオキシンを含む灰が付着した焼却炉の解体工事や、バイオハザード施設等の微生物汚染防止用高精度除菌フィルター(HEPAフィルター)の交換作業や解体工事により飛散するウィルス・細菌等の微生物群のフィルターへの固定と殺菌処理を同時に行うことが可能である事、又、界面活性剤を適量加える事により、油塵等、水を弾じく塵埃であっても、固定が可能である。   Dismantling of incinerators with ash containing dioxins, and replacement of high-accuracy sanitizing filters (HEPA filters) to prevent microbial contamination in biohazard facilities, etc. Filters for microorganisms such as viruses and bacteria scattered by dismantling work It is possible to carry out the fixation and the sterilization treatment at the same time, and by adding an appropriate amount of a surfactant, it is possible to fix even dust that repels water, such as oil dust.

風化アスベストの固定又は解体除去のために費やされる費用は、経験によれば、専ら、その準備工程の粉塵飛散防止処理作業に費やされる割合が大きいので、粉塵飛散防止又は固定液の特徴及びその使い易さは、経済的且つ適確に作業を進める得るか否かに、大きく影響する。本液の上記特徴は、健康・経済的に風化アスベストの固定又は解体除去作業を施行するのに適切であると信じられる。   The cost spent for fixing or dismantling and removing weathered asbestos is, according to experience, a large percentage of the dust-spreading prevention work in the preparation process. Ease is greatly influenced by whether the work can be proceeded economically and accurately. It is believed that the above characteristics of this liquid are suitable for carrying out the work of fixing or dismantling weathered asbestos in a healthy and economical manner.

本液を組成する各成分は、粘着剤、界面活性剤及び増粘剤として業界に流通している剤であれば、必ずしも実施例に例示した名称(商品名)のものに限られない。なお、その組成比は、各剤に期待される特性の発揮が相互に損なわれない範囲とする。   Each component composing the present liquid is not necessarily limited to the names (trade names) exemplified in the examples as long as it is an agent distributed in the industry as an adhesive, a surfactant and a thickener. In addition, the composition ratio shall be a range in which the performance of the properties expected for each agent is not impaired.

配合(重量比)
アラビア・ゴム粉末 5% (粘着剤)
ポリエチレングリコール(PG4000) 1% (界面活性剤)
カルボキシメチルセルロース(CMC) 1% (増粘剤)
水 93%
固定液の調整
Formulation (weight ratio)
Arabic rubber powder 5% (adhesive)
Polyethylene glycol (PG4000) 1% (surfactant)
Carboxymethylcellulose (CMC) 1% (Thickener)
93% water
Fixing solution adjustment

60〜80℃の湯で均質に溶かす。
散布方法
Dissolve homogeneously in hot water at 60-80 ° C.
Spraying method

プランジャーポンプで低圧ミスト散布する。噴霧器の噴霧ノズルを被処理面より30cm程度離し、散布面積が直径30cm〜50cm程度になるように調節して、処理対象面に45°〜90°の角度で満遍なく静かに散布する。この時、吹き付け材料が飛散しないような噴射圧に調節する。散布面に固定液の表面張力が発生していない事を確認する事。
散布量:非処理物の厚み・体積の20%〜30%程度の容量とする。
(厚み1〜3cmの場合)実体積の5倍以下で充分湿潤するに足りる量
実施例:1リットル/m
但し、水分量による重さで吹き付け材が剥離・崩壊しない範囲とする。
効果の確認
Spray low pressure mist with plunger pump. The spray nozzle of the sprayer is separated from the surface to be processed by about 30 cm, and the spraying area is adjusted so as to have a diameter of about 30 cm to 50 cm, and sprayed uniformly and uniformly on the processing target surface at an angle of 45 ° to 90 °. At this time, the spray pressure is adjusted so that the spray material does not scatter. Make sure that there is no surface tension of the fixative on the spray surface.
Application amount: 20% to 30% of the thickness / volume of the non-treated material.
(In the case of a thickness of 1 to 3 cm) An amount sufficient for sufficient wetting at 5 times or less of the actual volume Example: 1 liter / m 2
However, the spraying material does not peel or collapse due to the weight of moisture.
Confirmation of effect

作業中の粉塵測定を行い、以下の成果を得た。
(1)粉塵濃度測定値
作業前粉塵濃度 0.03 mg/m
作業中粉塵濃度 0.016mg/m
作業後粉塵濃度 0.018mg/m
(2)アスベスト分析
During the work, dust was measured and the following results were obtained.
(1) Dust concentration measurement value Dust concentration before work 0.03 mg / m 3
Dust concentration during work 0.016mg / m 3
Dust concentration after work 0.018mg / m 3
(2) Asbestos analysis

作業前 有 (50%含有)
作業中空気濃度 0.06f/m
作業後空気濃度 不検出
処理後の耐火性 変化無し
Before work Yes (50% contained)
Air concentration during work 0.06f / m 3
No air concentration after operation No change in fire resistance after treatment

アスベスト等を含む耐火・耐熱等吹き付け材の施工個所は、都市内又はその周辺に立地する公共用建物、工場その他個人用住宅等、枚挙に暇が無い。これらの建築材は、経年変化を経て、アスベストの風化の時期を経過している事例が多く、アスベスト等に対する健康被害が判明した後には、可及的短時期間に撤去又は分解工事を施すことが望ましい場合が少なくない。
然し乍ら、その多くは都市内に立地して、工事中、隣接周辺域に風に載ってアスベスト粉塵が飛散し、付近住民の健康に影響を及ぼす恐れが在る。本液の特徴は、風化アスベスト等を含む建材の粉塵の固定又は解体工事の際に広く発揮されるものと信じられる。
Construction sites for fire and heat resistant spray materials including asbestos, etc. have no spare time for public buildings, factories and other private houses located in or around the city. Many of these building materials have undergone a period of weathering of asbestos after aging, and after the health damage to asbestos, etc. has been found, they should be removed or disassembled as soon as possible. Is often desirable.
However, most of them are located in the city, and during construction, asbestos dust may be scattered on the adjacent surrounding area and affect the health of nearby residents. It is believed that the characteristics of this liquid are widely exhibited during the fixing or dismantling of building materials including weathered asbestos.

Claims (1)

アラビア・ゴム等の多糖類水溶液に界面活性剤と増粘剤とを均質配合して成るアスベスト等飛散性粉塵の飛散防止又は固定液。
An anti-scattering or fixing solution for asbestos and other dusts, which is a mixture of a surfactant and a thickener in an aqueous solution of polysaccharides such as gum arabic and gum.
JP2006187831A 2006-07-07 2006-07-07 Prevention of scattering of asbestos and other dust particles or fixative Expired - Fee Related JP4373416B2 (en)

Priority Applications (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120119001A1 (en) * 2010-11-11 2012-05-17 Empire Technology Development Llc Environmental contamination inhibition
JP2012236888A (en) * 2011-05-11 2012-12-06 Eco First:Kk Asbestos scattering preventing agent and asbestos material treatment method
JP2014000735A (en) * 2012-06-19 2014-01-09 Ohbayashi Corp Method for decomposing structure

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120119001A1 (en) * 2010-11-11 2012-05-17 Empire Technology Development Llc Environmental contamination inhibition
WO2012064328A1 (en) * 2010-11-11 2012-05-18 Empire Technology Development Llc Environmental contamination inhibition
JP2012236888A (en) * 2011-05-11 2012-12-06 Eco First:Kk Asbestos scattering preventing agent and asbestos material treatment method
JP2014000735A (en) * 2012-06-19 2014-01-09 Ohbayashi Corp Method for decomposing structure

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