JP2008007109A - Presser member for accelerator operation resistance generator - Google Patents

Presser member for accelerator operation resistance generator Download PDF

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JP2008007109A
JP2008007109A JP2007197814A JP2007197814A JP2008007109A JP 2008007109 A JP2008007109 A JP 2008007109A JP 2007197814 A JP2007197814 A JP 2007197814A JP 2007197814 A JP2007197814 A JP 2007197814A JP 2008007109 A JP2008007109 A JP 2008007109A
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accelerator
pressing member
resistance
resistance generator
friction member
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JP4767229B2 (en
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Akihiko Matsuoka
晃彦 松岡
Seiji Sato
誠二 佐藤
Satoru Fukuzawa
覚 福澤
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NTN Corp
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NTN Corp
NTN Toyo Bearing Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a presser member for an accelerator operation resistance generator with appropriate frictional force and sliding property, and having a sheet-like friction member with significantly improved resistance to abrasion and creep deformation. <P>SOLUTION: In the presser member for an accelerator operation resistance generator, friction resistance is given to a rotational shaft 4 directly or indirectly driving equipment for engine output control, to apply a resistance force to accelerator operation. The pressor member is constituted of the sheet-like friction member 2 and a metal plate-like member 3, and the friction member 2 is formed of fluororesin composition of fluororesin mixed with at least one compounding agent selected from whisker having Mohs hardness of 5 or less, carbon fiber, and hard resin powder. In the accelerator operation, the friction member 2 is relatively rotated with respect to the metal disc 5 normally or reversely to generate difference between a depression force and a returning force of an accelerator pedal, while being brought into press-contact with the metal disc 5 fixed to the rotational shaft 4. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は運転者のアクセル操作量に応じてエンジンの出力制御用機器、例えば吸気絞り弁を直接または間接に駆動するシステムにおけるアクセル操作抵抗発生装置用押し当て部材に関する。   The present invention relates to a pressing member for an accelerator operation resistance generator in a system for directly or indirectly driving an engine output control device, for example, an intake throttle valve, in accordance with a driver's accelerator operation amount.

自動車エンジンの出力制御は、ガソリンエンジン車では吸気絞り弁を開閉することで行ない、ディーゼルエンジン車では噴射ポンプのプランジャを回転させることで行なっている。
この出力制御は、アクセルペダルと吸気絞り弁あるいは噴射ポンプのプランジャ等の出力制御機器をワイヤーケーブルで連結しており、運転者のアクセル操作に応じて出力制御機器を駆動する。
近年、ガソリンエンジン車の出力制御は、アクセル操作量を電気信号に変換してアクチュエータを動作させ、このアクチュエータにより吸気絞り弁を開閉させるアクチュエータ方式が実用化されている(特許文献1)。
アクチュエータ方式では従来と比較してワイヤーケーブルが極端に短くなるため、ワイヤーケーブルによる抵抗が小さくなり、運転者はアクセル操作がしづらくなる。このアクセル操作のし難さは、運転者を必要以上に疲れさせ、また事故を引き起こす要因ともなり得る場合がある。
このことは、ディーゼルエンジン車においてワイヤーケーブルを短縮した場合でも発生する。
このため、アクセル操作に抵抗力を加えるアクセル操作抵抗発生装置が知られている(特許文献2、特許文献3)。
The output control of an automobile engine is performed by opening and closing an intake throttle valve in a gasoline engine vehicle, and by rotating a plunger of an injection pump in a diesel engine vehicle.
In this output control, an output control device such as an accelerator pedal and an intake throttle valve or a plunger of an injection pump is connected by a wire cable, and the output control device is driven according to the driver's accelerator operation.
In recent years, the output control of a gasoline engine vehicle has been put to practical use as an actuator system in which an accelerator operation amount is converted into an electric signal to operate an actuator and an intake throttle valve is opened and closed by this actuator (Patent Document 1).
In the actuator system, the wire cable is extremely short as compared with the conventional one, so that the resistance by the wire cable is reduced, and the driver does not easily operate the accelerator. This difficulty in operating the accelerator may cause the driver to become tired more than necessary and may cause an accident.
This occurs even when the wire cable is shortened in a diesel engine vehicle.
For this reason, accelerator operation resistance generators that apply resistance to accelerator operation are known (Patent Documents 2 and 3).

例えば、特許文献3には、エンジンの出力制御用機器を間接または直接に駆動させる回転軸とアクセルペダルとがワイヤーケーブルで連結され、アクセル操作量に応じて回転する出力制御用機器駆動機構の回転軸に抵抗力を加える装置であって、回転軸に固定された円板に、フッ素系樹脂からなる摩擦部材をばね部材を用いて常時弾性的に押当てることによって運転者が違和感なくアクセル操作できる手段を開示している。
ここで摩擦部材を用いるのは、アクセルペダル踏み込み力と戻り力に差を発生させるためである。この差が小さいと、運転者がアクセルペダルを任意に踏み込んで速度を一定に保つ場合、意識しないほどのわずかな踏み込み力の変化によってもペダルが動作するため、ペダル操作が困難になる。また、差が大きいと、運転者がアクセルペダルを任意に踏み込んで速度を一定に保つ場合ではペダル操作が容易になるが、速度を加減速する場合にペダル操作に不快感を生じる。これは、踏み込み時にペダルが重く感じられたり、戻し時にペダルが戻り難いと感じるようになるためである。
実開昭59−41708号公報 特開平9−280076号公報 特開平9−236030号公報
For example, in Patent Document 3, a rotation shaft for driving an output control device of an engine indirectly or directly and an accelerator pedal are connected by a wire cable, and rotation of an output control device drive mechanism that rotates according to an accelerator operation amount. A device that applies a resistance force to the shaft, and the driver can operate the accelerator without feeling a sense of incongruity by constantly pressing a friction member made of a fluorine resin against a disc fixed to the rotating shaft using a spring member. Means are disclosed.
The reason why the friction member is used is to generate a difference between the accelerator pedal depression force and the return force. If this difference is small, when the driver depresses the accelerator pedal arbitrarily to keep the speed constant, the pedal operates even with a slight change in the depressing force that is not conscious, so that the pedal operation becomes difficult. If the difference is large, pedal operation becomes easy when the driver arbitrarily depresses the accelerator pedal to keep the speed constant, but uncomfortable pedal operation occurs when the speed is increased or decreased. This is because the pedal feels heavier when depressing or it is difficult to return when returning.
Japanese Utility Model Publication No.59-41708 JP-A-9-280076 JP-A-9-236030

しかしながら、フッ素系樹脂で形成された摩擦部材は、適度な摩擦力と摺動性を兼ね備えるが、アクセル操作抵抗発生装置の摩擦部材に必要とされる耐クリープ性や自己摩耗性に劣るという問題がある。すなわち、従来の摩擦部材に用いられているフッ素系樹脂はクリープ変形が大きく、また自己摩耗量が大きい。
その結果、クリープ変形や自己摩耗によって、摩擦部材の押付け荷重の変動によりアクセルフィーリングが変化する。さらに摩擦部材の回転びびりやアクセル戻りが悪化するという問題がある。
However, the friction member formed of a fluorine-based resin has an appropriate frictional force and slidability, but has a problem that it is inferior in creep resistance and self-abrasion required for the friction member of the accelerator operation resistance generator. is there. That is, the fluororesin used for the conventional friction member has a large creep deformation and a large amount of self-wear.
As a result, the accelerator feeling changes due to the variation of the pressing load of the friction member due to creep deformation or self-wear. Furthermore, there is a problem that the rotational chatter of the friction member and the accelerator return deteriorate.

本発明は、このような問題に対処するためになされたもので、適度な摩擦力と摺動性を兼ね備え、さらに耐摩耗性と耐クリープ変形を大幅に向上させたシート状の摩擦部材を備えたアクセル操作抵抗発生装置用押し当て部材を提供することを目的とする。   The present invention has been made in order to cope with such a problem, and has a sheet-like friction member that has both appropriate frictional force and sliding property, and further greatly improved wear resistance and creep deformation resistance. Another object of the present invention is to provide a pressing member for an accelerator operating resistance generator.

本発明のアクセル操作抵抗発生装置用押し当て部材は、エンジンの出力制御用機器を直接または間接に駆動する回転軸に摩擦抵抗を付与してアクセル操作に抵抗力を加える押し当て部材であって、該押し当て部材はシート状の摩擦部材と金属製板状部材とから構成され、上記摩擦部材はフッ素樹脂にモース硬度 5以下のウィスカ、炭素繊維および硬質樹脂粉末から選ばれた少なくとも一つの配合剤を配合したフッ素樹脂組成物で形成されてなり、アクセル操作時において、該摩擦部材が上記回転軸に固定された金属製相手部材に圧接されつつ、該金属製相手部材に対して正逆に相対回転することによりアクセルペダル踏み込み力と戻り力に差を発生させることを特徴とする。   The pressing member for the accelerator operation resistance generator of the present invention is a pressing member that applies a frictional resistance to a rotating shaft that directly or indirectly drives an engine output control device and applies a resistance force to an accelerator operation, The pressing member is composed of a sheet-like friction member and a metal plate-like member, and the friction member is at least one compounding agent selected from fluororesin, whisker having a Mohs hardness of 5 or less, carbon fiber, and hard resin powder. In the accelerator operation, the friction member is pressed against the metal mating member fixed to the rotating shaft and is relative to the metal mating member in the forward and reverse directions. By rotating, a difference is generated between the accelerator pedal depression force and the return force.

上記押し当て部材はシート状の摩擦部材と金属製板状部材とが接着されていることを特徴とする。
また、上記押し当て部材の金属製板状部材の外径には突起が形成され、ハウジング内の凹部に嵌合することによって回転不可能となっていることを特徴とする。
The pressing member is characterized in that a sheet-like friction member and a metal plate-like member are bonded to each other.
In addition, a protrusion is formed on the outer diameter of the metal plate-like member of the pressing member, and it is impossible to rotate by fitting into a recess in the housing.

上記フッ素樹脂が四フッ化エチレン樹脂(以下、PTFEと略称する)および変性四フッ化エチレン樹脂(以下、変性PTFEと略称する)から選ばれた少なくとも一つの樹脂であることを特徴とする。
また、上記ウィスカは、アスペクト比が 10 以上の単結晶であることを特徴とする。
また、上記硬質樹脂粉末が、ポリイミド樹脂粉末またはポリアミドイミド樹脂粉末であり、上記フッ素樹脂 100 体積部に対して 5〜25 体積部配合してなることを特徴とする。
The fluororesin is at least one resin selected from a tetrafluoroethylene resin (hereinafter abbreviated as PTFE) and a modified tetrafluoroethylene resin (hereinafter abbreviated as modified PTFE).
The whisker is a single crystal having an aspect ratio of 10 or more.
Further, the hard resin powder is a polyimide resin powder or a polyamideimide resin powder, and is characterized by blending 5 to 25 parts by volume with respect to 100 parts by volume of the fluororesin.

フッ素樹脂組成物を上記配合とすることにより、本発明のアクセル操作抵抗発生装置用押し当て部材の摩擦部材は、配合剤の作用によりフッ素樹脂組成物の耐摩耗性と耐クリープ変形性が大幅に向上する。   When the fluororesin composition is blended as described above, the friction member of the pressing member for the accelerator operating resistance generator according to the present invention significantly increases the wear resistance and creep deformation resistance of the fluororesin composition by the action of the compounding agent. improves.

本発明は、エンジンの出力制御用機器を直接または間接に駆動する回転軸に摩擦抵抗を付与して、アクセル操作に抵抗力を付与するアクセル操作抵抗発生装置用押し当て部材において、該押し当て部材がシート状の摩擦部材と金属製板状部材とから構成され、この摩擦部材がフッ素樹脂にモース硬度 5以下のウィスカ、炭素繊維および硬質樹脂粉末から選ばれた少なくとも一つの配合剤を配合したフッ素樹脂組成物で形成されてなるので、また、上記フッ素樹脂が四フッ化エチレン樹脂および変性四フッ化エチレン樹脂から選ばれた少なくとも一つの樹脂であるので、適度な摩擦力と摺動性を兼ね備え、さらに耐摩耗性とクリープ変形とを大幅に改善できた。その結果、アクセル操作のフィーリングが良好になるとともに、従来品より長寿命のアクセル操作抵抗発生装置が得られる。   The present invention relates to a pressing member for an accelerator operating resistance generator that applies a frictional resistance to a rotating shaft that directly or indirectly drives an engine output control device and applies a resistance force to an accelerator operation. Is composed of a sheet-like friction member and a metal plate-like member, and the friction member is a fluorine resin containing at least one compounding agent selected from whisker having a Mohs hardness of 5 or less, carbon fiber, and hard resin powder. Since it is formed of a resin composition, the fluororesin is at least one resin selected from a tetrafluoroethylene resin and a modified tetrafluoroethylene resin. In addition, the wear resistance and creep deformation were greatly improved. As a result, the accelerator operation feeling is improved and an accelerator operation resistance generator having a longer life than that of the conventional product can be obtained.

本発明の一実施態様として、アクセルセンサユニットから延びる回転軸の軸端部に設置されたアクセル操作抵抗発生装置の一例を図1に示す。
アクセル操作抵抗発生装置1は、アクセルセンサユニット10から延び転がり軸受7で支持される回転軸4の軸端部に設置され、ハウジング内に収容される。
ハウジング内には、ハウジング底部から順に転がり軸受7、スペーサ8、スプリングワッシャ9、押し当て部材が回転軸4の軸方向に設けられている。
押し当て部材は、適度な摩擦力と摺動性を兼ね備えるシート状のアクセル操作抵抗発生装置用摩擦部材2と、たわみ等の変形を防止するため金属製円板からなる板状部材3とから構成され、板状部材3に摩擦部材2を接着して形成する。なお、板状部材3の外径部には突起3aが形成され、ハウジング内の凹部6に嵌合することによって板状部材3は回転不可能となっている。
回転軸4の端部には摩擦部材2の相手部材となる金属製円板5が、ボルトによって強固に固定され、回転軸4の回転にともない回転する。
回転軸4はアクセルを踏み込んだ時にワイヤーケーブル11と結束されたアクセルレバー12の動作によって回転し、アクセルを戻した時にリターンスプリング14の戻り力で逆回転する。
摩擦部材2に形成された凸状接触部2aが金属製円板5にスプリングワッシャ9によって圧接し、回転軸4はリターンスプリングの戻り力で逆回転する時にこの圧接で生じる摩擦抵抗によって摩擦力が発生する。この回転軸4に生じる摩擦力がアクセル操作の抵抗となる。なお、13は出力用端子である。
As an embodiment of the present invention, FIG. 1 shows an example of an accelerator operating resistance generator installed at the shaft end of a rotating shaft extending from an accelerator sensor unit.
The accelerator operation resistance generator 1 is installed at the shaft end portion of the rotating shaft 4 that extends from the accelerator sensor unit 10 and is supported by the rolling bearing 7, and is accommodated in the housing.
In the housing, a rolling bearing 7, a spacer 8, a spring washer 9, and a pressing member are provided in the axial direction of the rotary shaft 4 in order from the bottom of the housing.
The pressing member is composed of a sheet-like friction member 2 for an accelerator operation resistance generator having both an appropriate frictional force and slidability, and a plate-like member 3 made of a metal disk to prevent deformation such as deflection. Then, the friction member 2 is bonded to the plate-like member 3. In addition, the protrusion 3a is formed in the outer-diameter part of the plate-shaped member 3, and the plate-shaped member 3 cannot be rotated by fitting in the recessed part 6 in a housing.
A metal disk 5 which is a counterpart member of the friction member 2 is firmly fixed to the end of the rotating shaft 4 by a bolt, and rotates as the rotating shaft 4 rotates.
The rotating shaft 4 is rotated by the operation of the accelerator lever 12 bound to the wire cable 11 when the accelerator is stepped on, and reversely rotated by the return force of the return spring 14 when the accelerator is returned.
The convex contact portion 2a formed on the friction member 2 is brought into pressure contact with the metal disk 5 by a spring washer 9, and when the rotary shaft 4 rotates in reverse by the return force of the return spring, friction force is generated by the friction resistance generated by this pressure contact. appear. The frictional force generated on the rotating shaft 4 becomes the resistance of the accelerator operation. Reference numeral 13 denotes an output terminal.

摩擦部材は、適度な摩擦力と摺動性を兼ね備えるとともに、耐摩耗性とクリープ変形に対して十分に耐用可能なように、マトリクス樹脂となるフッ素樹脂にモース硬度 5以下のウィスカ、炭素繊維または硬質樹脂粉末をそれぞれ単独で、あるいは混合物として配合する。
モース硬度 5以下のウィスカを配合する場合、適度な摩擦力と摺動性を維持しつつ、耐摩耗性と耐クリープ性が両立できる摩擦部材が得られる。
モース硬度 5以下のウィスカは、アスペクト比が 10 以上の単結晶であることが好ましい。
具体的には、チタン酸カリウムウィスカ(モース硬度 3〜4)、硫酸カルシウムウィスカ(モース硬度 3)、硫酸マグネシウムウィスカ(モース硬度 2〜3)、ウォラストナイト(モース硬度 4〜5)、酸化亜鉛ウィスカ(モース硬度 4)、炭酸カルシウムウィスカ(モース硬度 3〜4)等が例示できる。
The friction member has an appropriate frictional force and sliding property, and has a whisker having a Mohs hardness of 5 or less, a carbon fiber, or a fluororesin as a matrix resin so that it can sufficiently withstand abrasion resistance and creep deformation. The hard resin powders are blended individually or as a mixture.
When a whisker having a Mohs hardness of 5 or less is blended, a friction member capable of achieving both wear resistance and creep resistance while maintaining an appropriate frictional force and slidability can be obtained.
The whisker having a Mohs hardness of 5 or less is preferably a single crystal having an aspect ratio of 10 or more.
Specifically, potassium titanate whiskers (Mohs hardness 3-4), calcium sulfate whiskers (Mohs hardness 3), magnesium sulfate whiskers (Mohs hardness 2-3), wollastonite (Mohs hardness 4-5), zinc oxide Examples include whiskers (Mohs hardness 4) and calcium carbonate whiskers (Mohs hardness 3-4).

これらのウィスカはフッ素樹脂組成物においてミクロ補強の役割を果たすので、摩擦部材の耐クリープ性、耐摩耗性が著しく向上する。ウィスカは短繊維であるため摩擦面での存在割合が大きくほとんどの摩擦せん断を受け持つために、相手材を損傷しない。
しかし、ウィスカの繊維長が短すぎると十分な耐クリープ性、耐摩耗性が得られなくなるため、繊維長は 50μm 前後であることが好ましい。これに該当するウィスカとしては、硫酸カルシウムウィスカの無水塩型、半水塩型が挙げられ、好ましくは無水塩型である。
Since these whiskers play a role of micro reinforcement in the fluororesin composition, the creep resistance and wear resistance of the friction member are remarkably improved. Whisker is a short fiber and has a large proportion of friction on the friction surface.
However, if the whisker fiber length is too short, sufficient creep resistance and wear resistance cannot be obtained. Therefore, the fiber length is preferably around 50 μm. The whisker corresponding to this includes anhydrous salt type and hemihydrate type of calcium sulfate whisker, preferably anhydrous salt type.

上市されているウィスカを具体的に例示すると、硫酸カルシウムウィスカとしてフランクリンファイバーA−30(無水塩型)、フランクリンファイバーH−30(半水塩型)(繊維長 50〜60μm 、大日精化工業社製)、チタン酸カリウムウィスカとしてティスモN(繊維長 10〜20μm 、大塚化学社製)、酸化亜鉛ウィスカとしてパナテトラ(繊維長 2〜50μm 、松下電器産業社製)、硫酸マグネシウムウィスカとしてモスハイジ(繊維長 10〜30μm 、宇部興産社製)等を挙げることができる。   Specific examples of commercially available whiskers include Franklin fiber A-30 (anhydrous salt type) and Franklin fiber H-30 (hemihydrate type) as calcium sulfate whiskers (fiber length 50-60 μm, Dainichi Seika Kogyo Co., Ltd.) ) Tismo N (fiber length 10-20 μm, manufactured by Otsuka Chemical Co.) as potassium titanate whisker, Panatetra (fiber length 2-50 μm, manufactured by Matsushita Electric Industrial Co., Ltd.) as zinc oxide whisker, Mosheidi (fiber length) as magnesium sulfate whisker 10-30 μm, manufactured by Ube Industries, Ltd.).

また、モース硬度 5以下のウィスカに代えて、炭素繊維を配合しても、適度な摩擦力と摺動性を維持しつつ、耐摩耗性と耐クリープ性が両立できる摩擦部材が得られる。
炭素繊維はピッチ系あるいはパン系炭素繊維のいずれでもよく、その繊維長は 0.05mm〜0.1mm の範囲のミルド繊維であることが好ましい。繊維種は特に限定しないが、2,000 ℃焼成あるいはそれ以上の温度での処理品(黒鉛化品)より 1,000℃焼成品(炭化品)の方が好ましい。また、低弾性を狙った低温焼成品あるいは高弾性を狙った高温焼成品いずれも使用することができる。繊維径はφ 20μm 以下、好ましくは、φ 5μm 〜φ15μm であり、アスペクト比は 5〜80、好ましくは 20〜50 である。
上市されている炭素繊維を具体的には例示すると、ピッチ系炭素繊維としてクレカミルドM101S(呉羽化学工業社製)、ドナカーボンS241(大阪ガスケミカル社製)、パン系炭素繊維としてべスファイトHTA−CMFO160−0H(東邦レーヨン社製)等を挙げることができる。
In addition, even if carbon fiber is blended in place of whisker having a Mohs hardness of 5 or less, a friction member capable of achieving both wear resistance and creep resistance while maintaining appropriate frictional force and slidability can be obtained.
The carbon fiber may be either pitch-based or bread-based carbon fiber, and the fiber length is preferably a milled fiber having a range of 0.05 mm to 0.1 mm. The fiber type is not particularly limited, but a 1000 ° C. baked product (carbonized product) is preferable to a 2,000 ° C. baked product or a processed product (graphitized product) at a higher temperature. Moreover, either a low-temperature fired product aiming at low elasticity or a high-temperature fired product aiming at high elasticity can be used. The fiber diameter is φ20 μm or less, preferably φ5 μm to φ15 μm, and the aspect ratio is 5 to 80, preferably 20 to 50.
Specific examples of commercially available carbon fibers include Crecamilde M101S (manufactured by Kureha Chemical Co., Ltd.) and Donacarbon S241 (manufactured by Osaka Gas Chemical Co., Ltd.) as pitch-based carbon fibers, and Besfight HTA-CMFO160 as bread-based carbon fibers. -0H (manufactured by Toho Rayon Co., Ltd.).

また、モース硬度 5以下のウィスカに代えて、硬質樹脂粉末を配合しても同様の効果が得られる。ここで、硬質樹脂粉末とは、マトリクス樹脂であるPTFEまたは変性PTFEの成形温度 380℃にて変形しない樹脂の粉末であり、かつPTFE等の耐クリープ性、耐摩耗性を改善することのできる合成樹脂の粉末である。具体的には、熱可塑性ポリイミド樹脂(三井化学社製)、熱硬化性ポリイミド樹脂(Furon社製、宇部興産社製)、ポリエーテルエーテルケトン樹脂(VictrexMC社製)、全芳香族ポリエステル樹脂(住友化学工業社製)、芳香族ポリアミド樹脂(住友化学工業社製)、ポリアミドイミド樹脂(三菱化成社製)、エポキシ樹脂、フェノール樹脂等を挙げることができる。   The same effect can be obtained by blending hard resin powder in place of whisker having a Mohs hardness of 5 or less. Here, the hard resin powder is a resin powder that does not deform at a molding temperature of 380 ° C. of PTFE or modified PTFE as a matrix resin, and can be improved in creep resistance and wear resistance such as PTFE. Resin powder. Specifically, thermoplastic polyimide resin (manufactured by Mitsui Chemicals), thermosetting polyimide resin (manufactured by Furon, Ube Industries, Ltd.), polyether ether ketone resin (manufactured by Victrex MC), wholly aromatic polyester resin (Sumitomo) Chemical Industry Co., Ltd.), aromatic polyamide resin (Sumitomo Chemical Co., Ltd.), polyamideimide resin (Mitsubishi Kasei Co., Ltd.), epoxy resin, phenol resin and the like.

また、成形性などを考慮すれば、熱硬化性樹脂を硬化後、500℃以上の高温で熱処理、粉砕した硬質樹脂粉末が好ましい。さらに1,000℃以上で炭化処理したもの、2,000℃以上で黒鉛化処理したものが好ましい。熱硬化性樹脂の例は、エポキシ樹脂、ポリイミド樹脂、フェノール樹脂などがある。粉砕後の平均粒径は 50μm 以下、好ましくは 25μm 以下であり、形状は球状が好ましい。特にフェノールをパラフォルムアルデヒド溶液中で反応硬化後、500 ℃以上の高温で熱処理、粉砕した球状の粉末が好ましい。
市販されている球状の黒鉛化処理された粉末を例示すると、メソカーボンビーズ(大阪ガスケミカル社製)、べルパール(鐘紡社製)、ユニベックス(ユニチカ社製)、マイクロカーボンビーズ(日本カーボン社製)等を挙げることができる。
In consideration of moldability and the like, a hard resin powder obtained by heat-curing and grinding at a high temperature of 500 ° C. or higher after curing the thermosetting resin is preferable. Further, carbonized at 1,000 ° C. or higher and graphitized at 2,000 ° C. or higher are preferable. Examples of the thermosetting resin include an epoxy resin, a polyimide resin, and a phenol resin. The average particle size after pulverization is 50 μm or less, preferably 25 μm or less, and the shape is preferably spherical. In particular, a spherical powder obtained by reacting and curing phenol in a paraformaldehyde solution and then heat-treating and pulverizing at a high temperature of 500 ° C. or higher is preferable.
Examples of commercially available spherical graphitized powder include mesocarbon beads (manufactured by Osaka Gas Chemical Co., Ltd.), bel pearl (manufactured by Kanebo Co., Ltd.), unibex (manufactured by Unitika Ltd.), and microcarbon beads (manufactured by Nippon Carbon Co., Ltd.). And the like.

上記モース硬度 5以下のウィスカ、炭素繊維、硬質樹脂粉末は、それぞれ単独でも、あるいは混合物としても使用できる。また、例えばウィスカを複数種類混合して使用することができる。   The whisker, carbon fiber, and hard resin powder having a Mohs hardness of 5 or less can be used alone or as a mixture. Further, for example, a plurality of types of whiskers can be mixed and used.

摩擦部材のマトリクス材であるフッ素樹脂の中でPTFEおよび/または変性PTFEを使用することができる。
PTFEは、四フッ化エチレン(テトラフルオロエチレン)の単独重合体であって、アルゴフロン(Ausimont社製)、テフロン(登録商標、DuPont社製)、フルオン(ICI社製)、ポリフロン(ダイキン工業社製)等の商標名で市販されているフッ素樹脂である。このようなPTFEは、310〜390℃で軟化して圧縮成形および押出成形は可能であるが通常の射出成形は不可能な樹脂である。
PTFE and / or modified PTFE can be used in the fluororesin that is the matrix material of the friction member.
PTFE is a homopolymer of tetrafluoroethylene (tetrafluoroethylene), and Algoflon (manufactured by Ausimmont), Teflon (registered trademark, manufactured by DuPont), Fluon (manufactured by ICI), Polyflon (Daikin Industries, Ltd.) It is a fluororesin marketed under a trade name such as Such PTFE is a resin that is softened at 310 to 390 ° C. and can be compression-molded and extruded, but cannot be normally injection-molded.

本発明に好適な変性PTFEは、四フッ化エチレン単位と、四フッ化エチレンのフッ素が他の有機基(−X)で置換された置換四フッ化エチレン単位とから構成される変性PTFEである。その一般式を化1に示す。有機基(−X)は特に限定するものではないが、パーフルオロアルキルエーテル基あるいはフルオロアルキル基などが好ましい。化1に示す変性PTFEを用いた場合、耐クリープ特性が向上する。
(化1)
−[−CF2−CF2−]m−[−CFX−CF2−]n
PTFE、変性PTFEの重合方法は一般的なモールディングパウダーを重合する懸濁重合法、ファインパウダーを重合する乳化重合法のいずれも採用できるが、分子量は約 50 万から約 1,000万が好ましく、さらに限定すれば 100万から 700万が好ましい。
上市されている変性PTFEを具体的に例示すると、テフロンTG70J(三井・デュポンフロロケミカル社製)、ポリフロンM111(ダイキン工業社製)、ホスタフロンTFM1600(Hoechst社製)等を挙げることができる。
The modified PTFE suitable for the present invention is a modified PTFE composed of a tetrafluoroethylene unit and a substituted tetrafluoroethylene unit in which the fluorine of tetrafluoroethylene is substituted with another organic group (-X). . The general formula is shown in Chemical Formula 1. The organic group (-X) is not particularly limited, but is preferably a perfluoroalkyl ether group or a fluoroalkyl group. When the modified PTFE shown in Chemical Formula 1 is used, the creep resistance is improved.
(Chemical formula 1)
-[-CF 2 -CF 2- ] m -[-CFX-CF 2- ] n-
As a polymerization method of PTFE and modified PTFE, either a suspension polymerization method for polymerizing a general molding powder or an emulsion polymerization method for polymerizing a fine powder can be adopted, but the molecular weight is preferably about 500,000 to about 10 million, and further limited. From 1 million to 7 million is preferable.
Specific examples of the modified PTFE on the market include Teflon TG70J (Mitsui / DuPont Fluorochemical), Polyflon M111 (Daikin Industries), Hostaflon TFM1600 (Hoechst), and the like.

モース硬度 5以下のウィスカ、炭素繊維および硬質樹脂粉末から選ばれた少なくとも一つの配合剤の配合量はPTFE 100体積部に対して 5〜40 体積部であることが好ましい。配合剤の配合量が 40 体積部を越えると成形が困難となる。また、 5体積部未満であれば、耐摩耗性および耐クリープ性に顕著な効果が現れない。   The blending amount of at least one compounding agent selected from whisker having a Mohs hardness of 5 or less, carbon fiber, and hard resin powder is preferably 5 to 40 parts by volume with respect to 100 parts by volume of PTFE. Molding becomes difficult when the compounding amount exceeds 40 parts by volume. In addition, if it is less than 5 parts by volume, there is no significant effect on wear resistance and creep resistance.

実施例、比較例に用いた材料を以下に示す。
フッ素樹脂
PTFE;テフロン7J(三井・デュポンフロロケミカル社製)
変性PTFE;テフロンTG70J(三井・デュポンフロロケミカル社製)
配合剤
硫酸カルシウムウィスカ(無水塩型、モース硬度 3);フランクリンファイバーA30(大日精化工業社製)
ウォラストナイトウィスカ(モース硬度 4.5);ケモリット(丸和バイオケミカル社製)
ホウ酸アルミニウムウィスカ(モース硬度 7);アルボレックス−Y(四国化成社製)
酸化アルミニウムウィスカ(モース硬度 9)
炭素繊維(ピッチ系);クレカミルドM101S(呉羽化学工業社製)
ガラス繊維;MF−KAC(旭ファイバーグラス社製)
ポリイミド樹脂粉末(熱硬化性);(Furon社製)
ポリアミドイミド樹脂粉末;(三菱化成社製)
The materials used in Examples and Comparative Examples are shown below.
Fluororesin PTFE; Teflon 7J (Mitsui / DuPont Fluorochemicals)
Modified PTFE; Teflon TG70J (Mitsui / DuPont Fluorochemicals)
Formulation Calcium sulfate whisker (anhydrous salt type, Mohs hardness 3); Franklin fiber A30 (manufactured by Dainichi Seika Kogyo Co., Ltd.)
Wollastonite whisker (Mohs hardness 4.5); Chemolit (Maruwa Biochemical Co., Ltd.)
Aluminum borate whisker (Mohs hardness 7); Arborex-Y (manufactured by Shikoku Chemicals)
Aluminum oxide whisker (Mohs hardness 9)
Carbon fiber (pitch type); Crecamill M101S (manufactured by Kureha Chemical Industry Co., Ltd.)
Glass fiber: MF-KAC (Asahi Fiber Glass)
Polyimide resin powder (thermosetting); (Furon)
Polyamideimide resin powder; (Mitsubishi Kasei Co., Ltd.)

実施例1〜実施例6、比較例1〜比較例3
上記材料を用い、表1に示す組成をヘンシェル乾式混合機を使用してドライブレンドし、プレス機でφ124mm×φ64mm× 100mmの円筒素形材を予備成形し、370 ℃× 4時間、フリーベーキング法にて焼成した。さらに 2mm厚にスカイビング加工しφ50mm×φ40mm× 2mmのリング状のシート試験片を得た。そしてリングシートの片面をアルカリ処理によりエッチングして接着可能とし、ステンレス製治具(φ50mm×φ15mm× 4mm)の一面にエポキシ系接着剤を用いて接合し、評価試験片とした。
この評価試験片を用いて、アクセル操作抵抗発生装置用押し当て部材の摩擦部材として必要とされる以下の評価試験を行なった。
Examples 1 to 6 and Comparative Examples 1 to 3
Using the above materials, dry blending the composition shown in Table 1 using a Henschel dry mixer, pre-molding a cylindrical shape of φ124mm x φ64mm x 100mm with a press machine, 370 ° C x 4 hours, free baking method Baked in. Further, it was skived to a thickness of 2 mm to obtain a ring-shaped sheet test piece of φ50 mm × φ40 mm × 2 mm. Then, one side of the ring sheet was etched by alkali treatment so that it could be bonded, and bonded to one side of a stainless steel jig (φ50 mm × φ15 mm × 4 mm) using an epoxy adhesive to obtain an evaluation test piece.
Using this evaluation test piece, the following evaluation test required as a friction member of the pressing member for the accelerator operating resistance generator was performed.

1)摩擦試験:回転数 2.0m/min.、荷重 8kgf、雰囲気温度 80℃の条件で相手材をステンレス鋼とし空気中で、初期(耐久試験前)および以下に述べる耐久試験後に摩擦係数を測定した。
2)耐久試験:揺動角±75度、速度 1Hz、荷重 8kgf、雰囲気温度 80℃、空気中の条件で 300万サイクルの耐久試験を行なった。評価は、耐久試験前と後との摩耗量の変化を耐摩耗性として、厚みの変化を耐クリープ性として、目視で観察した相手材の摺動面の変化を相手材攻撃性として、ほとんど変化がなかったのを○で、わずかに変化が認められたのを△で、大きな変化があったものを×でそれぞれ評価した。測定結果を表1に示す。
1) Friction test: Friction coefficient measured at initial (before endurance test) and after endurance test described below in stainless steel as the mating material under conditions of rotation speed 2.0m / min., Load 8kgf, ambient temperature 80 ℃ did.
2) Endurance test: An endurance test of 3 million cycles was performed under conditions of rocking angle ± 75 degrees, speed 1 Hz, load 8 kgf, ambient temperature 80 ° C, and air. Evaluation is almost the same as the wear resistance before and after the endurance test as wear resistance, the change in thickness as creep resistance, and the change in the sliding surface of the other material visually observed as the other material aggression. The case where there was no change was evaluated by ○, the case where slight change was observed was evaluated by Δ, and the case where there was a large change was evaluated by ×. The measurement results are shown in Table 1.

Figure 2008007109
Figure 2008007109

表1の結果から明らかなように、本発明のアクセル操作抵抗発生装置用押し当て部材の摩擦部材は、摩擦係数が耐久試験後も初期値とほとんど変化なかった。また、耐摩耗性および耐クリープ性でも優れていることがわかった。さらに相手材に対しても攻撃性のないことが認められた。
このことから本発明の摩擦部材は、アクセル操作抵抗発生装置の摩擦部材として好適であるといえる。
実施例に対して、比較例の組成からなる摩擦部材は、耐久性が劣り(比較例1)、またはモース硬度が 5を越えているため相手攻撃性が大きかった(比較例2、比較例3)。配合剤を含まない比較例1は 100万サイクルまでに摩擦部材が摩耗したため試験を中止した。
As is clear from the results in Table 1, the friction coefficient of the pressing member for an accelerator operating resistance generator according to the present invention was almost the same as the initial value even after the durability test. It was also found to be excellent in wear resistance and creep resistance. Furthermore, it was recognized that it was not aggressive against the opponent.
From this, it can be said that the friction member of the present invention is suitable as a friction member of the accelerator operation resistance generator.
The friction member having the composition of the comparative example was inferior in durability to the example (Comparative Example 1), or because the Mohs hardness exceeded 5, the opponent attack was large (Comparative Example 2 and Comparative Example 3). ). In Comparative Example 1 containing no compounding agent, the test was stopped because the friction member was worn by 1 million cycles.

本発明の押し当て部材は、適度な摩擦力と摺動性を兼ね備え、さらに耐摩耗性と耐クリープ変形を大幅に向上させたシート状の摩擦部材を備えるので、アクセル操作抵抗発生装置用の押し当て部材として好適に利用できる。   The pressing member of the present invention has a sheet-like friction member that has both an appropriate frictional force and sliding property, and has greatly improved wear resistance and creep deformation. It can be suitably used as a contact member.

アクセル操作抵抗発生装置の一例を示す図である。It is a figure which shows an example of an accelerator operation resistance generator.

符号の説明Explanation of symbols

1 アクセル操作抵抗発生装置
2 摩擦部材
3 板状部材
4 回転軸
5 円板
6 凹部
7 転がり軸受
8 スペーサ
9 スプリングワッシャ
10 アクセルセンサユニット
11 ワイヤーケーブル
12 アクセルレバー
13 出力用端子
14 リターンスプリング
DESCRIPTION OF SYMBOLS 1 Accelerator operation resistance generator 2 Friction member 3 Plate-shaped member 4 Rotating shaft 5 Disc 6 Recessed part 7 Rolling bearing 8 Spacer 9 Spring washer 10 Accelerator sensor unit 11 Wire cable 12 Accelerator lever 13 Output terminal 14 Return spring

Claims (6)

エンジンの出力制御用機器を直接または間接に駆動する回転軸に摩擦抵抗を付与してアクセル操作に抵抗力を加えるアクセル操作抵抗発生装置用押し当て部材において、
前記押し当て部材はシート状の摩擦部材と金属製板状部材とから構成され、
前記摩擦部材はフッ素樹脂にモース硬度 5以下のウィスカ、炭素繊維および硬質樹脂粉末から選ばれた少なくとも一つの配合剤を配合したフッ素樹脂組成物で形成されてなり、
アクセル操作時において、該摩擦部材が前記回転軸に固定された金属製相手部材に圧接されつつ、該金属製相手部材に対して正逆に相対回転することによりアクセルペダル踏み込み力と戻り力に差を発生させることを特徴とするアクセル操作抵抗発生装置用押し当て部材。
In the pressing member for the accelerator operating resistance generator that applies frictional resistance to the rotating shaft that directly or indirectly drives the engine output control device and applies resistance to the accelerator operation,
The pressing member is composed of a sheet-like friction member and a metal plate-like member,
The friction member is formed of a fluororesin composition in which at least one compounding agent selected from whisker having a Mohs hardness of 5 or less, carbon fiber, and hard resin powder is blended with fluororesin,
When the accelerator is operated, the friction member is pressed against the metal mating member fixed to the rotating shaft, and is rotated relative to the metal mating member in the forward and reverse directions, thereby causing a difference between the accelerator pedal depression force and the return force. A pressing member for an accelerator operating resistance generator.
前記押し当て部材はシート状の摩擦部材と金属製板状部材とが接着されていることを特徴とする請求項1記載のアクセル操作抵抗発生装置用押し当て部材。   2. The pressing member for an accelerator operating resistance generator according to claim 1, wherein the pressing member is formed by bonding a sheet-like friction member and a metal plate-like member. 前記押し当て部材の金属製板状部材の外径には突起が形成され、ハウジング内の凹部に嵌合することによって回転不可能となっていることを特徴とする請求項1または請求項2記載のアクセル操作抵抗発生装置用押し当て部材。   The protrusion is formed in the outer diameter of the metal plate-shaped member of the said pressing member, and it cannot be rotated by fitting in the recessed part in a housing, The Claim 1 or Claim 2 characterized by the above-mentioned. A pressing member for an accelerator operating resistance generator. 前記フッ素樹脂が四フッ化エチレン樹脂および変性四フッ化エチレン樹脂から選ばれた少なくとも一つの樹脂であることを特徴とする請求項1、請求項2または請求項3記載のアクセル操作抵抗発生装置用押し当て部材。   4. The accelerator operating resistance generator according to claim 1, wherein the fluororesin is at least one resin selected from a tetrafluoroethylene resin and a modified tetrafluoroethylene resin. Pushing member. 前記ウィスカは、アスペクト比が 10 以上の単結晶であることを特徴とする請求項1ないし請求項4のいずれか一項記載のアクセル操作抵抗発生装置用押し当て部材。   The pressing member for an accelerator operating resistance generator according to any one of claims 1 to 4, wherein the whisker is a single crystal having an aspect ratio of 10 or more. 前記硬質樹脂粉末が、ポリイミド樹脂粉末またはポリアミドイミド樹脂粉末であり、前記フッ素樹脂 100 体積部に対して 5〜25 体積部配合してなることを特徴とする請求項1ないし請求項5のいずれか一項記載のアクセル操作抵抗発生装置用押し当て部材。   6. The hard resin powder is a polyimide resin powder or a polyamide-imide resin powder, and is blended in an amount of 5 to 25 parts by volume with respect to 100 parts by volume of the fluororesin. A pressing member for an accelerator operating resistance generator according to one item.
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JP2015199783A (en) * 2014-04-04 2015-11-12 三菱化学株式会社 Polycarbonate resin composition and molded part made thereof

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