JP2007520511A - Plant protection composition and use thereof - Google Patents

Abstract

  pesticides in paddy rice cultivation, comprising a) 2-ethylhexyl lactate, b) one or more active pesticides dissolved therein, and c) optionally one or more formulation aids. The use of plant protection compositions for control and plant protection compositions comprising 2-ethylhexyl lactate and certain pesticide active substances are disclosed.

Description

  The present invention relates to the use of plant protection compositions comprising 2-ethylhexyl lactate (EHL) and certain plant protection compositions comprising EHL.

In paddy rice cultivation, for satisfactory control, the pests present in the rice and / or water are in direct and timely contact with the applied active substance, or the active substance is widely and evenly distributed. Must be distributed throughout the paddy field. For example, it is expensive to use known spray solutions or granules as standard application methods. It is more economical to place the active substance in a water-soluble container on the edge of the rice field, such as the bottle disclosed in Japanese Patent Publication No. 10175804 or the bag disclosed in US Pat. No. 5,439,683. After being released from the container, the uniform distribution of the active substance over the entire water surface depends on several factors and can be improved or even guaranteed by appropriate additives. A slightly water-soluble active substance can be used as a special composition as disclosed in Japanese Patent Publication No. 10017410, and a water-insoluble active substance is disclosed in Japanese Patent Publication No. 05339103. As disclosed, it is dissolved directly in an aprotic solvent such as a (C ₈ -C ₁₃ ) alkyl phthalate. In WO 01/35738, vegetable oil is added to the active substance, and the active substance content in the oil can be further increased by adding more aprotic solvents. The active substance is then uniformly distributed throughout the paddy field by the formation of an oil film. However, oil slicks can interfere with the exchange of oxygen between the atmosphere and water, and certain additional solubility promoters introduced can result in adverse environmental consequences. In addition, there is a further need for new methods that are easier to work with in paddy rice cultivation, more reliable in effect, and safer for users.

  The object of the present invention was to develop an application method that can be used in the control of pests in the cultivation of rice while avoiding the above-mentioned economic and ecological problems to the maximum extent possible.

  It has now been surprisingly found that an EHL solution of an agrochemical active substance provides a plant protection composition that is particularly suitable for controlling pests in paddy rice cultivation.

The plant protection composition used according to the present invention and its application according to the present invention is easy and safe for the user, exhibits favorable properties with respect to toxicity and is reliable in effect when controlling pests in paddy fields. There is sex. In addition, environmental behavior is also improved since EHL as a solvent can be biologically completely decomposed into CO ₂ and water. The solvent film that forms first distributes the active substance evenly across the paddy field, but then collapses into countless small droplets that are exchanged between the atmosphere and water that is hindered by a completely covered water surface. The crisis is no longer there.

  WO 91/14366 discloses EHL as an active substance that regulates the growth of grapes. In this case, EHL is added directly to the water in a defined amount, without any other additives, and is used as a foliar spray solution at the early growth stage of the grape. In this document, the use of EHL as a solvent is neither presented nor suggested.

  In WO 00/18227, EHL is disclosed as a suspending agent for insoluble pesticidal active substances in non-aqueous suspension concentrates.

  In WO 03/075657, EHL is disclosed as a substance that prevents crystallization during application of an insecticide composition, in particular a composition containing an azole fungicide.

  None of these documents suggests a particular advantage in using EHL containing plant protection compositions when applied in paddy rice cultivation.

Thus, in one aspect of the invention,
a) 2-ethylhexyl lactate,
A plant protection composition for controlling pests in paddy rice cultivation, comprising b) one or more pesticide active substances dissolved therein, and c) optionally one or more formulation aids. Use is provided.

In another aspect of the invention,
a) 2-ethyl lactate,
b) one or more agrochemical active substances dissolved therein, and c) optionally one or more formulation aids, wherein the plant protection composition is applied in or on the water of rice paddy fields. A method for controlling pests in rice cultivation is provided.

  “Plant protection composition” within the meaning of the present invention is a formulation of an agrochemical active substance, ie an active substance concentrate comprising EHL and one or more agrochemical active substances, or such active substance concentrates and formulation auxiliaries. One of them. These formulation aids used depending on the situation are additives and auxiliaries conventionally used in most conventional formulation methods of various formulation types, and emulsifiers (eg emulsifiable concentrates (EC ) And microemulsion (ME) formulation types), wetting agents (eg, ready-to-use liquid formulation (AL) formulation types), inert materials (eg, granules (GR) and emulsifiable granules (EG) formulation types) ), Dispersing agents (eg, for oil-in-water emulsion (EW) and suspoemulsion (SE) formulation types) and surfactants (eg, for soluble concentrate (SL) formulation types), and additional solvents, There are also thickeners, fluidity stabilizers, adjuvants, active substance stabilizers, preservatives, antifoaming agents, film-forming agents and antifreeze agents, which are the majority of the various formulation types. Stomach can be used.

  Formulation aids that may be required, such as emulsifiers, wetting agents, inert materials, dispersants, surfactants, solvents and additional additives are known to those skilled in the art and are described, for example, by Watkins, "Insecticides Handbook of Insectide Dust Diluents and Carriers, 2nd Edition, Darling Books Caldwell, NJ; Hv Olphen, “Introductory Clay Colloid Chemistry” , 2nd edition, J.A. Wiley & Sons, N.W. Y. C. Marsden, “Solvents Guide”, 2nd edition, Interscience, N .; Y. 1963; McCutcheon, "Emulsifiers and Detergents-International Edition (Edited by Emulsifiers and Detergents-International)", Annual, MC Publ. Corp. Ridgewood, N .; Y. McCutcheon's "Emulsifiers and Detergents-North America Edition (Edited by Emulsifiers and Detergents-North America)", Annual, MC Publ. Corp. Ridgewood, N .; Y. Sisley and Wood, “Encyclopedia of Surface Active Agents”, Chem. Publ. Co. Inc. , N.A. Y. 1964; Schoenfeldt, "Surface-active ethylene oxide adducts [Grenzflaechenacky acetylenoxydductte]", Wiss. Verlagsgesell. , Stuttgart, 1976; Winnacker-Küchler, “Chemical Technology [Chemical Technology]”, Vol. 7, C.I. Hanser Verlag, Munich, 4th edition, 1986; Mollet and Grubenmann, “Formulation Technology” [Formation Technology], Wiley-VCH-Verlag, Weinheim, 2000.

  Solvent EHL, 2-ethylhexyl lactate is an ester of 2-ethylhexanol and lactic acid, which is preferably, for example, Purac Bioquimica (Gran Vial 19-25, 08160 Montmelo-Barcelone, Spain) or Purac Biochem (Gorinchem). L-(+)-lactic acid available as Purasolv® from the Netherlands. Other names for EHL are 2-ethylhexyl S-lactate, 2-ethylhexyl L-lactic acid, L-lactic acid 2-ethylhexyl ester, CAS-No. 186817-80-1, EC-No. 223-503-2.

EHL exhibits good solvent properties, is biologically completely decomposed into CO ₂ and water in the environment, and has no ozone reducing effect. In addition, EHL is toxicologically harmless with an LD ₅₀ value (rat, oral) exceeding 2000 mg / kg body weight. In the human body, the ester bond of EHL is rapidly broken down, and EHL is broken down into CO ₂ and water by enzymatic hydrolysis. Because of these advantageous properties, EHL is often used accordingly in materials processing for the degreasing of materials and in the printing industry as an additive in colorants and inks.

  These properties are advantageous for the use of EHL in plant protection compositions as well as assisting the action of pesticide active substances on pests, so that undesirable side effects such as the use of pesticides in plants. Damage (phytotoxicity) can occur only to a lesser extent. A further advantage with the use of EHL is the possibility of obtaining a preferred flash point plant protection composition, whereby the required transport and storage regulations can be reduced or completely eliminated. It is. In addition, the storage stability of the plant protection composition can also be improved by the use of EHL. Furthermore, EHL keeps the agrochemical active substance as a solution even at a low temperature, and thus it is possible to ensure stability of the plant protection composition against freezing.

  Thus, the use of EHL may of course also be advantageous in active substance concentrates, for example the stability of an agrochemical active substance before preparing a plant protection composition by wetting the surface of the active substance By increasing Yet further, EHL may contribute to improving the uniformity of active substances in the preparation of plant protection compositions.

  The term “pesticide active substance” refers to all substances used in the fields of agriculture, horticulture, forestry and veterinary medicine as well as in domestic areas and animal husbandry, eg herbicides, insecticides, fungicides, fungicides , Anti-nematode, algicide, molluscicide, viricide, resistance-inducing substance, substance effective as repellent and substance effective as growth regulator, composition containing and not containing biological organism And fertilizers that supply trace elements and nutrients. Substances effective as herbicides, insecticides, fungicides, fungicides and viricides as well as substances effective as growth regulators are preferred. Substances that are effective as herbicides, insecticides and fungicides are particularly preferred.

  Preference is given to agrochemical active substances whose solubility in EHL at 20 ° C. is at least 5 g / L, particularly preferably at least 10 g / L.

  Examples of herbicide active substances include: Aclonifene, amidosulfuron, anilophos, asram, benfresulfate, bispyribac sodium salt, bromoxynil, crotorulone, cyclanilide, desmedifam, diclohopmethyl, diflufenican, diuron, etethon, etofumesate, ethoxysulfuron, phenoxaprop-P-ethyl, Fentrazamide, Flucarbazone sodium, flufenaset, flurtamone, foramsulfuron, glufosinate ammonium, glyphosate, iodosulfuron, ioxonyl, isoproturon, isoxaflutol, linuron, mefenacet, mesosulfuron methyl, metamitron, metoslam, metribudine, oxadiargyl Oxadiazone, fenmedifam, sodium propoxycarbazone, Trion and thidiazuron.

  Examples of the insecticide active substance include the following. Acetamiprid, Acrinatrin, Ardicarb, Amitraz, Azinphosmethyl, Betacyfluthrin, Carbaryl, Clothianidin, Cyfluthrin, Cypermethrin, Deltamethrin, Endosulfan, Ethiprole, Etoprophos, Fenamiphos, Fentione, Fipronil, Imidacloprid, Metamidophos, Metamidophos , Hosalon, prothiophos, silafluophene, spirodiclofen, spiromesifen, thiacloprid, thiodicarb, tralomethrin, triazophos, trichlorfone and triflumuron.

  Examples of fungicides effective substances include the following. Viteltanol, bromconazole, carbendazim, carpropamide, cyproconazole, edifenphos, phenamidon, fenhexamide, fentin, fluoxastrobin, fluquinconazole, fosetylaluminum, iprodione, iprodione, iprovaricurve, pencyclon, prochlorus, propamocurve Hydrochloric acid, propinebu, prothioconazole, pyrimethanil, spiroxamine, tebuconazole, tolylfluanido-diclofluanid, triadimethone, triadimenol, trifloxystrobin and triticonazole.

  Preference is given to substances effective as herbicides and as insecticides. More preferred are substances that are effective as insecticides, especially ethiprol and fipronil.

  The concentration of the active substance in the active substance concentrate in EHL varies within wide limits and depends on the respective end use. Concentrations known to the person skilled in the art as active substance concentrations and as customary for their respective end use are generally used. Preference is given to concentrations of 0.1% to 95% by weight, particularly preferably 0.2% to 85% by weight.

  In a preferred embodiment of the present invention, compounds from the group consisting of polydimethylsiloxanes that are supposed to prevent foam formation (so-called “antifoaming agents”), such as Break Thru® (Goldschmidt, Essen, Germany), Dow Corning® (Dow Chemicals, Wiesbaden, Germany), and Silwet® (Osi Specialties / Akzo Nobel, Frankfurt, Germany) as additional components of plant protection compositions according to the present invention included. Polydimethylsiloxane improves, among other things, the distribution behavior at the water surface.

  The concentration of polydimethylsiloxane varies within wide limits and depends on the desired distribution effect of the plant protection composition. In general, concentrations known to the person skilled in the art to be customary for the desired distribution effect are used in each case. Preference is given to a concentration of 0.5% to 30% by weight, particularly preferably 3% to 10% by weight.

  Polydimethylsiloxane is preferably used in liquid formulations, especially in the AL type (as will be explained later).

  In addition to the compounds already mentioned above, other substances can be used in the formulations according to the invention, depending on the chemical nature of the agrochemical active substance.

  These include substances that stabilize pesticidal active substances, such as butylated hydroxytoluene (BHT) citric acid or acetic acid, the choice and concentration of which vary within a wide range and contribute to the stability of the pesticidal active substance. Dependent. Concentrations known to the person skilled in the art as customary for active pesticides to be dissolved each time are generally used. Preference is given to concentrations of 0.01% to 1% by weight, particularly preferably 0.1% to 0.2% by weight.

Similarly, additional solvents from the group of non-polar or polar and aprotic or protic solvents such as benzyl alcohol, dimethyl sulfoxide (DMSO), C ₁₂ -C ₁₅ alkyl benzoates (Pentonat DB®) , Diisopropyl adipate (Crodamol DA®), N-octylpyrrolidone (NOP) or dimethylacetamide (DMAc) in the preparation according to the invention, preferably a liquid preparation, in particular the AL type (as described later) Can be used in the formulation. The concentration of these additional solvents varies within a wide range and depends on the solubility characteristics of the pesticide active substance to be dissolved in the liquid AL formulation type plant protection composition. Concentrations known to the person skilled in the art as customary for pesticidal active substances to be dissolved each time are generally used. Preference is given to concentrations of 50% to 95% by weight, particularly preferably 75% to 85% by weight.

  The possible formulation types can vary within wide limits. In this case, the methods used are generally well known to those skilled in the art and are described, for example, in Winnacker-Küchler, “Chemical Technology [Chemical Technology]”, Vol. Hanser-Verlag, Munich, 4th edition, 1986; W. van Valkenburg, “Pesticide Formulations”, Marcel Dekker N .; Y. 1973; Martens, "Spray Drying Handbook", 3rd edition, 1979, G.M. Goodwin Ltd. , London, or Mollet and Grubenberg, “Formulation Technology [Formulation Technology]”, Wiley-VCH-Verlag, Weinheim, 2000.

  Give examples of formulation types (for each, the GCPF (Agricultural Manufacturers Association) formulation code is used with abbreviations and descriptions). AE aerosol sprayer, AL all other liquids, CG encapsulated granules, CL contact liquid or gel, CS capsule suspension, DC dispersible concentrate, DP sprayable powder, DT direct application tablet, EC emulsifiable concentrate (Emulsion), ED chargeable liquid, EG emulsifiable granule (granule), EO W / O emulsion, EW O / W emulsion, FG fine granule, FS seed treatment fluid concentrate, GG macro granule, GL emulsifiable Gel, GP floating fine powder, GR granule (granule), GW water-soluble gel, ME microemulsion, MG microgranule, OF oil miscible fluid concentrate / oil miscible suspension, OL oil miscible liquid (oil) , OP Oil dispersible powder, PC gel or paste concentrate, SE Suspo emulsion, SG water-soluble granule, SL soluble concentrate (solution) , SO diffusion oil, SP water-soluble powder, ST water-soluble tablet, SU ultra-low volume (ULV) suspension, TB tablet, TC technical material, TK technical concentrate, UL ultra-low volume (ULV) liquid, WG Water dispersible granules (granular wettable powder), WP wettable powder, XX and others. Preference is given to liquid and solid formulation types obtained via active substance concentrates. These are formulation type EC (GCPF formulation symbol for emulsifiable concentrate), GR (GCPF formulation symbol for granules), EW (GCPF formulation symbol for O / W emulsion), ME (GCPF formulation symbol for microemulsion), EG ( GCPF formulation symbol for emulsifiable granules), SE (GCPF formulation symbol for suspoemulsion), SL (GCPF formulation symbol for soluble concentrate), CS (GCPF formulation symbol for capsule suspension) and AL (liquid formulation ready for use) GCPF formulation symbol for). Special preference is given to liquid formulations, in particular liquid formulations which can be used as they are (formulation type AL).

  The concentration of the active substance concentrate comprising EHL and one or more pesticidal active substances in each formulation type varies within a wide range and depends on the corresponding formulation type. Concentrations commonly known to those skilled in the art for each formulation type are generally used. A concentration of 2% to 95% by weight, particularly preferably 10% to 90% by weight, is preferred.

  The invention also includes the preparation of active substance concentrates comprising EHL and one or more pesticidal active substances, and the preparation of plant protection compositions from the active substance concentrates. The methods used in this case are generally well known to those skilled in the art and are described, for example, in the cited literature, together with various formulation types (see above). In preparation, it is generally advantageous to use a series of additions and mixings, or a series of applications of the individual components shown in the examples.

  The active substance concentrate of the present invention is a true solution, ie the agrochemical active substance of this liquid concentrate is present in dissolved form at ambient temperature (20 ° C.).

  All methods known to the person skilled in the art as customary can be used as application forms. For example, spraying, spraying, many special direct treatments, and indirect application methods in the vicinity of many special plants, for example, mixing of granules into soil or application in flooded rice fields.

  Each amount of plant protection composition of different formulation types according to the invention consumed per unit area and / or per test subject to control pests varies greatly. For this, in general, application media known to the person skilled in the respective field are used in conventional amounts, for example from several hundred liters of water per hectare in the standard spray method. After a few liters of oil per hectare in an ultra-low volume aircraft spray, and even down to a few milliliters in a physiological solution by injection. Therefore, the concentration of the plant protection composition according to the invention in the corresponding application medium varies within a very wide range and depends on the respective field of use. Concentrations commonly known to those skilled in the art for each field of use are generally used. Preference is given to concentrations of 0.01% to 99% by weight, particularly preferably 0.1% to 90% by weight.

  In another preferred embodiment of the invention, the active substance concentrate according to the invention or the plant protection compositions of the various formulation types prepared therefrom are directly applied to further plant protection compositions / formulations (also pesticide active substances and It may be advantageous to mix with additional formulation aids. The methods used in this case, as well as formulation aids and plant protection compositions / formulations that may be required, are generally well known to those skilled in the art and are described in various ways, for example in the cited literature. As well as Watkins, “Handbook of Insectide Dus Diluents and Carriers”, 2nd Edition, Darl Books, Caldwell, New J .; v. Olphen, “Introduction to Clay Colloid Chemistry”, 2nd edition, J. Am. Wiley & Sons, New York; Marsden, “Solvents Guide”, 2nd edition, Interscience, New York, 1963; McCutcheon's “Emulsifiers and Detergents-International Edition” (Edited by Emulsifiers and Detergents-International), Annual MC. Corp. Ridgewood, New York; McCutcheon, “Emulsifiers and Detergents—North America Edition (Edited by Emulsifiers and Detergents-North America)”, Annual, MC Publ. Corp. Ridgewood, New York; Sisley and Wood, “Encyclopedia of Surface Active Agents”, Chem. Publ. Co. Inc. , New York, 1964; Schoenfeldt, “Grenzflaechative acetyladditive [Surface-active ethylene addducts]”, Wiss. Verlagsgesell. Stuttgart, 1976. Preferred methods are tank mixing, complex formulations and coated granules.

  In general, the agrochemical active substances and / or formulation types mentioned above are preferred as additional mixing partners.

  The mixing ratio of the above-mentioned mixing partners varies within a wide range and depends on the respective end use. Mixing ratios commonly known to those skilled in the art for each end use are generally used. These are 1 to 10000 (formulation containing plant protection composition / active substance concentrate): 1 to 10000 (formulation not containing plant protection composition / active substance concentrate), preferably 1 to 1000: 1 to 1000, The mixing ratio is particularly preferably 1 to 100: 1 to 100.

  One preferred embodiment of the present invention is EHL, optionally one or more solvents from the group consisting of nonpolar or polar aprotic or protic solvents, one or more from the group consisting of polydimethylsiloxanes. Use of a plant protection composition that is a liquid formulation, preferably an AL formulation, comprising one or more antifoaming agents, one or more pesticidally active substances and optionally substances for stabilization thereof. Purasolv® EHL, DMSO, Break Thru OE 441® and Ethiprole, particularly preferably 65% by weight for Purasolv® EHL, 30% by weight for DMSO, Break Thru OE 441® ) With a content of 2% by weight and for Ethiprool with a content of 3% by weight.

  For the preparation of preferred embodiments of the present invention, it is generally advantageous to use sequential addition and mixing of the individual components shown in the examples.

  The plant protection compositions used according to the invention are partly known and partly novel.

Thus, in a further aspect of the invention,
a) 2-ethylhexyl lactate b) one or more agrochemical active substances from the group consisting of: 1) acronifene, amidosulfuron, anilophos, aslam, benfresert, bispyribac sodium salt, Bromoxynil, crotorulone, cyclanilide, desmedifam, diclohopmethyl, diflufenican, diuron, etephone, etofumesate, ethoxysulfuron, phenoxaprop-P-ethyl, fentolazamide, flucarbazone sodium, flufenaset, flulutamon, foramsulfuron, glufosinate Ammonium, glyphosate, iodosulfuron, ioxonyl, isoproturon, isoxaflutol, linuron, mefenacet, mesosulfuron methyl, metamitron, methosla , Metribuzin, oxadiargyl, oxadiazon, phenmedipham, propoxy carbazone sodium, sulcotrione and thidiazuron,
2) Acetamiprid, acrinatrin, aldicarb, amitraz, azinphosmethyl, betacifluthrin, carbaryl, clothianidin, cyfluthrin, cypermethrin, deltamethrin, endosulfan, etiprole, etoprophos, phenamiphos, fenthion, fipronil, imidacloprid, methamitonfos, methamethros Permethrin, hosalon, prothiophos, silafluophene, spirodiclofen, spiromesifen, thiacloprid, thiodicarb, tralomethrin, triazophos, trichlorfone and triflumurone,
3) Viteltanol, carbendazim, carpropamide, edifenphos, phenamidon, fenhexamide, fentin, fluoxastrobin, fosetylaluminum, iprodione, iprovaricarb, pencyclon, propamocarb hydrochloride, propineb, prothioconazole, pyrimethanil, spiroxamine, Tolylfuranide-diclofluanide and trifloxystrobin,
c) Plant protection compositions are provided that optionally comprise one or more formulation aids.

  Preferred are compositions comprising one or more pesticidal substances from groups 1) and 2), more preferably from group 2), in particular fipronil and / or etiprole.

  Further preferred are compositions comprising as component c) one or more polydimethylsiloxanes (as described above).

  Further preferred are compositions comprising substances for the stabilization of pesticidal active substances, in particular butylated hydroxytoluene, citric acid or acetic acid.

More preferred include additional non-polar, polar, aprotic or protic solvents, especially benzyl alcohol, DMSO, C ₁₂ -C ₁₅ alkyl benzoates, diisopropyl adipate, N-octyl pyrrolidone, and dimethylacetamide. It is a composition.

  Preferred concentrations of these additional formulation auxiliaries are indicated above.

  Particularly preferred are compositions comprising two or more additional formulation auxiliaries.

  Liquid preparations of these compositions are also preferable, and are preparations that can be used as they are, particularly, AL preparation types.

  In another aspect of the present invention there is provided an active substance concentrate comprising (a) 2-ethylhexyl lactate and (b) one or more pesticidally active compounds from groups 1), 2) and / or 3). Provided.

  In yet another aspect of the invention, a water-soluble container comprising a composition as described above is provided.

  The term “harmful organism” includes any form of organism that causes economic damage and / or damage to health in the associated useful farmland. Preference is given to harmful plants and animals and organisms that cause disease. Terrestrial and aquatic weeds, including grasses, weeds, algae, moss, insects and arachnids (including mites), arthropods, nematodes, worms, rodents, fungi, bacteria and viruses Is particularly preferred.

  Particularly preferred “poisonous organisms” means arthropods including insects and arachnids, and helminths including nematodes.

Examples of harmful organisms in the cultivation of rice (using taxonomic terms and English terms for each) are Acanthosperum hispidum (star burr), Acid Borax Avene subsp . (Acidovorax avenae subsp.) (Bacterial leaf blight), Acridina cineta, Acrida exata (Acida exaltata). pastures), Aeneolamia flavilatera (yellow-sided froghopper), Aeneolamia varia (Aeneolamia varieties) -Northern joint vetch), Ageratum conizoides (goat weed), Agromyza oryzae (rice mince) Agrotis segetum (Turnip moth), Ahasverus advena (Foreign grain beetle), Aleurosibotus indigenous (Aureurocybotus) (Brown Legged Grain Mite brownlegged grain mite), Alphitobius diaperinus (lesser mealworm), Alternanthera phylloxeroid w Squirrel (Althernanthera sessilis) (Sessile joyweed), Arte Maria alternata f. sp. Ryuko Persiki (Alternaria leafspot), Alternaria padwicki (Sternburn disease) (Redroot), Amaranthus spinosus (spiny amaranthus), Anadastas fiformiformis, Anastatus scutellatus, Anadatus scutellatus nagallis arvensis (scarlet pipernel), Anapholipus obsculus (grass thrips), Anapholipus dansulas Anomala antiqua (groundnut chafer), Anomala dimidita, Anomala pallida, Aferencoides besidio yi) (rice leaf nematode), Artrinium pheospermum, Aspavia amigera, Aspergillus spurs, Aspergillus sp. Aspergillus ustus, Ateligona oryzae (Shot fly), Attractomorpha crenalta, Atta podaceps, Attaps ns) (leaf cutting ant), Avena fatua (wild oat), Bacillus cereus, Bacillus subtilis (Bacillus subtilis) Disease disease (udbatta disease), barkulta abdominalis, bandicota indica (grateer bandicoot rat), barredwarf wirdew wilde (bird) )) Bird pests, Blatteria germanica (croton bug), Blissus insularis (southern chinch buls ss) (Chinch bug), Boerhavia diffuser (hogweed), Borbo cinara (rice, leafer) Weed leaf buttonweed), Brachiaria paspaloides (common signal glass), Brevennia rehi (rice mealbug bug, rice mealbug bug) , Burkolderia glumae (bacterial grain rot), Burkolderia plantarii, Cadra cautella urd Tels (Cal otripps striatopterus (black trips of maize), calosoburchchinisus (pounds), pears (Chinese bruchids) Corn-sap beetle, cassia obtusifolia (sicklepod), calopsis cuspidata (longhorn paddy grasshopper) ddy glasshopper), Caulopsis gracilima (longhorn grasshopper (longhorn grasshopper), Longhorn grasshopper (longhorn grasshopper (longhorn grasshopper) ) (Quailgrass), Kenchrus echinatus (bur glass), keratobasidium cereale (sharp eye cereals, sharp eye pods) Ceratophyllum dernersum (contail), Ceresa minor, Chetocnema basalis, Kenopodium album, Chenopodium arum Chiletus malaccensis, Chilo agamemnon (conn, borer, oriental), Chilo auricilius (gold fringed rice boring, gold-fried rice bowl) Gilineus (Chiro diffusilin) us, Chilo partellus (spotted stem borer), Chilo plejadellus (rice stalk borer (USA)), Kiropoli Chris (chirro polis head (Chiro polis) Bowler (dark-headed striped borer), chilo sacchariphagus (spotted borer), chilo suppressaris (kilo supisaris) ), Kironomskile Chironomas kirensis, Chironomas tepperi (bloodworm), Chloris barbata (purpletop chloris), Chloris bartella (e. )), Chondracris rosea (citrus locust), Cleome viscosa (yellow mesambay), Cretus sprung tigers Nuss (Cretus trigon s) (slender rice-bug), Cnaphaloclos medinaris (rice leaf folder), Cochliobolus cereal (Cochlibolus) root rot: cereals), Cochliobolus lunatus (head mould of grasses, rice and sorghum), cochliobols miyabeus (Cochliobolus us)
) (Brown leaf spot of rice), Cochliobolus ravelliii (False smut), Cochliobols sativus spot (Cochliobols satobus disease spot) )), Cofana spectra (white leafhopper), Cofana unimaculata (white leafhopper), Coralia olerasa (Cololarisola) Colposcelis signa), Commerina Bengalensis (Commel) na benghalensis (Benghal dayflower), Commelina diffusa (water grass), Conophaphalides of churrus (Conocephalides oceculus) Horned green pasture grasshopper (Longhorned glass pastry hopper), Conoquephalus propinkus (Longhorned grasshopper (longhorned glasshopper)) us saltator (longhorn glasshopper), Conyza canadensis (Canadian flavans), Coptothermes (es), Coptothermes (es) Corcyra cephalonica (rice meal moth), Corticium rolfsii (scleroti rot), crassiophalum cephraid ceprid Conemelia (ring nematode), Cricotopus biinctus, Cricotopus sylvestris, Crytopus strivestus ferrugineus (rusty grain beetle), Cryptolesses psillus (flat grain beetle), cricoidesur (Curicoidesur) ularia (black kernel), Cymoninus notabilis, Cynodon dactylon (Bermuda grass), Cyprus breviforusus (Sedge)), Cyperus compressus (annual sedges), Cyperus diffisumis (small-flowered nutsedges, small-flowered nutsedges) Cyperus esculetus) low nutsdge), Cyperus iria (grasshopper's cyperus), Cyperus rotundus (nutgrass ytium), dactyl octite (Crowfoot glass)), Deols flavopicta (Demerara, froghopper), Diabrotica speciosa (Debrotica speciosa), Durhamitia cubet sis macrophthalma (stalk-eyed, borer), Diatraea centrella (stalk borer of rice and a lyra), tiger (Neotropical corn stalk borer), Dichelops melacanthus, Dicladispa armigera (Paddy hista diria, Paddy hista diria) s) (tropical finger glass), Dimorphopterus, Dinoderus minutus (bamboo powder-isopis bispies) , Diopsis longicornis (stalk-eyed fly), Ditylenchus angustus (rice stem nematodes) The Doricolis Baccalum Dolicoris baccarum (sloe, bug), Doricoris indicus, Donacia provosti (rice, rootaphra ephra cera peacure peacure peacure pea cure (Sharp-headed leafhopper), Drechslera gigantea (eyespot), ditelx nigrofastisdus (Dysdercus nigrofascustus) us), Dysmicoccus boninsis (pink sugarcane mealbug), Arias insulana (Egyptian chum echinumorum e) (Jungle rice), Echinochloa crus-galli (barnyard grass), Echinocnemus oryzae, Echinocnemus Ecusinus Rice weevil (rice pl) ant wevil), Eichhomia crassipes (water hyacinth), Erasmopulus lignocellus (Erosmopalus lignosellus) ) (Fowlfoot grass), Emilia sonchifolia (consumption weed), Entiloma oryzae (lef Eoreuma loftini , Ephydra macellaria (fly, rice), Epicoccum nigrum (red blotch of grains), Epilacna similis (Epilacna similis) maize lazybird beetle), Eragrostis japonica (delicate lovegrass), Erwinia carotovora subsp. Erwinia carotovora subsp. Carotovora (bacterial root of sweet potato rot), Erwinia chrysanthemi pv. Erwinia chrysanthemi pv. Chrysanthemi (bacterial bacterial blight of dahlia species (bacterial wilt of Dahlia spp.)), Euphorbia heloscopia (sun spurge), Euphorbia hillta (garden surgery (garden surgery), Euprotis viroculi erc ), Eoprotisxant Air (Euproctis Xanthorhoea), Eori de Maventuralis (Eurydema ventralis), Euskirtus concinnus, Eisarcoris rewis (Eysarcoris lewis), Eisarcoris lewis pal Spot-spotted bugs, Eisarcoris ventralis, Fimbrisilis slitaris (Resurfer Bristri fris) lla intonsa) (slip (thrips, flower)), Fusarium octene cis-Pol-time (Fusarium oxysporum), Fusarium professional Li Blow Tum (Fusarium proliferatum), gain cormorant Man Roh Mrs. Gras Minis var. Graminis (crown sheets rot), Galinsoga parviflora (galant soldier (gal) solder), gal asol ), Geoica luc
ifuga), Gibberella avenacea (Fusarium blight), Gibberella baccata (cervical rot: coffee roe, coffee laf) (Gibberella fujikuroi) (Bikanella disease of rice), Gibberella intricans (Gibberella zera) (Grinbera zera light) Leaf hopper, blackfaced (leafhopper, blackfa ed), Grylotalpa africana (african mole criket), Grills assimilis (field crick (field crick), haplotus grass p. thrips), Haplotrips ganglbaueri, Helicotyrenchus dihystera (common spiral nematode) Helicopter Common heliotrope), heliotropium indicum (Indian heliotrope), Helmintosporium sigmoideum var. Helminthosporum sigmoideum var. Irregulare (stem rot: rice), Herodites foveeratus (wevil, peltier) (Grassworm), Heterodera glycines (soybean cyst nematode), Heterodera oryzae (rice heterode tere, H. dera oryzicola (rice cyst nematode), heterodera sacchari (sugar cane cyst nematode (sugarcane cyla necto) ), Heteronychus rioderes, Hieroglyphus banyan (rice grasshopper), Hieroglyphs nigrolet pleats (Hieroglyphus leiples) rschmanniella oryzae (rice root nematode), Hirschmanniella spinica olsra sira il sera sera ) (White grub), Holotrichia seticollis, Hoplolimes indicus (lance nematode), Hoplolimessein Holsty oalaimus seinhorsti (Lance nematode), Hortensia similis (common green sulcane (min) deer (Herdriaede) ) Hydreria griseola (rice leaf miner), Hydreria filippina (i) leaf leaf miner, i ria leaf miner ddy stem maggot)), Hydrelia, Hydrelia tomiokai, Hydrilla verticillata, aquatic weed (aquatic toll) Hylephila phyleus (rice skipper), Hypocrea ruba (actual disease: lemon bioflavonoids (fruit rot: Citrus spp. )), Hypomeces squamosus (green weevil), Hysteroneura setariae (Rusty plum aphid a eu (Water spinach), Ischaemum rugosum (winked duck-beak), Ischemum timorense (centade), centipede Jellyfish (Javesella pelucida), Keiferia licorpelcella (Ke feria lycopersicella (tomato pinworm), Kuskia oryzae (cob rot of maize), anchor (Laelia suffusa) Ladeldelfax STRELLELLUS (small brown planthopper), LASIDERMA SERRICOME (cigarette beetle hex) (Southern cut grass), Remna perpsilla (duckweed), Lepinous reticulatum (lepinotus reticulate) (bookkrouse, reticulw) Rice leaf beetle, Leptochlora chinensis (Asian sprangletop), Leptocorisa acuta (rice seed burdock) Leptocorisa chi Nensis (Covert rice, bug), Leptocorisa oratorius (sender rice bug (Slender rice bug)), Leptogross grassagra (Leptogousgus) )), Lepcophoris irlorata (toy beetle), Leucophoris lepidophora (Areca white gruba (n), lin, delin) Nearanagaris, Linderni Linderia antipoda, Lindernia ciriata, Lindernia crustacea, Lindernia procumbens, common pampel (mm) Lipocelis bostrychophila (book louse), Lipocelis enmophila (grain posocid), Lipocelis esposide lipase Hoptors Brevilostris, Lissol Hoptrus Swissomics, Lissohoptrus oryzophilus (Amer ter, Wer Litacodia distinguenda (rice false looper), Locusta migratoria (migratory locust (parachunturata)) )), Ronchura, Longula malaca, Lophocateres psillus (Nicaraguan grain beetle (Licca)), Root wigia adisen (Ludwig) , Ludwigia hysopifolia (water primrose), Ludwigia octovalvis (primrose willow), primrose willow (Charcoal Disease bean / tobacco (charcoal rot bean / tobacco), macrosteres quadrilinetus (aster leafhopper), macrosteres streifens (Macrosteles riefriges) ) (Rice blast disease), Magnaporthe salvini (stern rot), Marialpha separaterra
(eparatella) (Nica Meiga, white (rice, borer, white)), Marasmia exigua (rice leaf roller), Marasmia pantonales (Marasmia patrelis) Marsmere ruperis (rice leaf roller), Marasmia trapezalis (maize webworm), Marsilea worm wort Tisredais Mene (Me antis leda ismene (rice butterfly), Melanitis suyadana, Melochia corcorifolia (redweed), meloide arena Peanut root-knott nematode), meloidogyne exigua (coffee root-knot nematode), meloid ematode), Meloidogyne incognita (root-knot nephroid (Menniella echinata), Menida meridio (Midano) ) (Composite, shipps), mimosa pigra (giant sensitive plant), mimosa pudica (momosa), moc latipes (grass looper), Monochoria vaginalis (pickelel weed), monographella albescens (fela scaldo, leaf scald) Monographella nivalis (foot root: cereals), Mormidea angustata, Mormidea guertimi v )), Mormidide Aip Ron (Mormidea ypsilon) (Mus musculus domesticus (mouse), Mycalesis horsfield (M) fairy holph (M) ), Mycosphaerella tassiana (lot of pepper fruits), Mycovelosiella oryzae (white leaf streaks (white leaf streaks (white leaf streaks)) yylum aquaticum (parrot-feather), Myriophyllum spicatum (spiked watermilfoil), Mythimnamuthomyomu , Mythymna loreyl (maize caterpillar), Mythimna separata (paddy armyworm (paddy armyworm), Mythimena venalba), Najas graminea (Grassy naiad), Najas marina (Jaly), Nafina )), Naranga diffusa (rice green semilooper), Nectria hematococca var. Brevikona (dry rot of potato), Nectria rigidiuscula (green point falcon), green point goal (green point goal) ) (Longhorned glasshopper), Nephotetics, Nephotetics cinchetics (Rice green leafhoppers, rice green leafhoppers, rice green leafhoppers) ethix malayanus), nephotetics nigropictus (rice green reef (i) tropics (nephotix parvus) , Nezara viridula (green stink bug), Nilaparvata bakeri, Nilaparvatta lugens e plant hopper (BPH)), Nilaparvata maander, Nisaga simplex, Nisia nervosa (Grey plant hopper) septemfascita (red locust), Ebalus insularis (island stinkbug), Ebalus omatus (Oebalus omatus), rice bug (rice bug) Ebalspuna Oebalus pugnax (rice stinkbug), Ebaldu ypsiloinoides (paddy bug), Evalus ipusilisOlygrose, Omalonyx felina (slug), Orphella puntata, Orseolia oryzae (rice stem midiori ori, ori olea lya) African rice Gold rice (African rice gall midge)), (Pennial wild rice), Oryza rufipogon (red rice), Olyzephyllus surimenis (Oryzephyllus surimenis (Oryzephyllus salimensis) Saw-toothed grain beetle), Oryzophagus oryzae, Oulema oryzae (were olesis), oxalis beetles (USA))), Oxalis latif Rear (Oxalis latifolia) (Soler (sorrel)), Ok shear Ji Nene cis (Oxya chinensis) (Hanenagainago), Ok shear japonica (Oxya japonica), Ok shear Nitinol Dura (Oxya nitidula), Okushia species (Oxya spp. ) (Rice field grasshopper), Oxya yezoensis (grasshopper, Japan), Parolsrat eblet (e.) , Panicum repens (torpedo glass), Paralongidorus australis (needle nematode), Parapoinus fructousalporus Tag Naris ( arapoynx stagnalis (rice case bearer), Parasabi bicolor, Parnara guttatus (rice skipper), palna gutta parm (Paspalum conjugatum) (sour grass), Paspalum disticum (knotgrass), Patanga guttulosa (batta, spurhead) Pelopidas Mathias ias (rice skipper), Perkinsiella saccharicida (sugar cane leaf hopper (sugarcane leafpomin) (Pestrotia disatipi leaf) spp.)), Petrobia latens (brown wheat mite), Phalaera combbusta, Phlugis Mantispa (Phlag
is mantispa (long-horned glasshopper), flugisteres (Phlgis teresi) (Shemath blotch), and (Collar rot), Phragmite australis (common reed), Phthia obscura, Phthia picta (black), black pel (black) Taholticola (Phylloperper Horticola) (Bra Blacken clock (blacken clock), Phyllophaga helleri, Piezodorus guildinil (stink bug), ti (a), piliodorides (n) ) (Water lettuce), Ploceus cucullatus (rice weaver bird), Prodia interpuntella (Plodia interpuntella) a annua (annual meadowgrass), Podontia quattu de decuncuta, polygum avicula (b) (Knot grass), Polygonum hydropiper (Marsh pepper), Polymyxa graminis (vector stripes virus vector virus) ), Polypedium Kurte Ratume (Polypedium cultellatum), Pomacare canalicurata (Golden snail), Pomacea glauca (Pulacera braus) (Portula rapes) Pratylenchus brachyurus (root-lesion nematode), Platylenchus penetrens (nematode, northern roots, et al. ) (Root region nematode), Psalis pennatula (hairy rice catapillar), Psamotistolitus pistrosticus trosticus trosticus (Leaf spot: maize (leaf spot: maize)), Pseudomonas aeruginosa (Pseudomonas aeruginosa), Pseudomonas fluorescens (Pseudomonas fluorescens) Aginae (Pseudomonas fuscovaginae) (sheets Brown Tot (sheath brown rot)), Puseudo Minas Petit da (Pseudominas putida) (bio-control, negative bacilli (biocontrol: Erwinia spp. )), Pseudomonas syringe pv. Orise (Pseudomonas syringae pv. Oryzae) (halo blight), Pseudomonas syringe pv. Syringe (Pseudomonas syringae pv. Syringae) (sickness or blast (stoker and pome fruits), Pseudomonas syringoe p. Bacterial leaf streaks), Pseudomonas syringae, Pyralis farinalis (meal moths), Pitium allenum Cereals root rot, Phythium graminicola (Graminee seedling bright), Pythium irregulare (black, beet vasculus spiculas) spinosum) (root rot, ornamentals), Pytium ultimum, Rattus argentiver (rice field rat), Torus Xlance (Rattus exulans) Rat, Norvegicus (brown rat), Rattus rattus (black rat), Rattus rattus ratus diardii (Malaysian house rat), Rattus rattus mindandensis (common Philippine field rat), Lecilia dollar salis (or Recilia gulp) (Zigzag leafhopper)), Rhizoctoni (Rhizoctonia), Rhisoctonia oryzae (Sheath spot), Rhizoglyhus robini (Rhizoglyphus rophini) (Rhopalosimumufum) Rhopalosiphum padi (Oat aphid), Ropalosifum rufiadominal (rice root aphid (rice root adizo)) (American w eat weil), rice black stretched dwarf virus, rice warf virus (dwarf disease of rice), rice hump dwarf rice virus (rice ward rice virus) Growth-inhibiting virus (rice grassy stun virus, rice leaf disease of rice rostice virus, rice-roughed srivirus strain, rice-growing virus) ), Rice tenui virus (rice stripe virus) Blight virus (rice stripe tenuivirus), rice growth-inhibiting rhabdo virus (rice transitory yellowing rhabdovirus), rice yellow stunt virus (rice yellow tuntrovirus), rice straw fungi type virus disease (rice tungro virus), rice tungro spheroidal virus, rice phytoplasma (atrophic) (rice yellow dwarf phytoplasma), rice mottolet virus (rice tuntrovirus) Cardia brasiliensis (white-eye (Australia)), Rivula atmeta (green) cattle in the grass, i. glass, Rupela albinella (South American white borer (of rice)), Saccharum spontaneum, wild suda gitaria guyanensis (lesser arrow-head), Salvinia molesta (cariba weed), sarocladium oryzae (rice rot) ), Scapteriscus kole (Mole crickets), Scapteriscus diductylus (Puerto Rican molesticus), Scaptocolic stacus , Schistocerca pallens (American grasshopper), Schizophis graminum (Spring green aphid), Sophafagain ceru tercter Borer (yellow stern borer), Sipofaga innoctata (white rice stern borer), Sipofaganibira (Scipophagagaibira rice) Psgloss (Scirp s grossus) Greater Club Rush (greater club rush), sill TOPS Yun carp Death (Scirpus juncoides) (Val Rush (bulrush)), Shirupu
Smarpus maritimus saltmarsh bulrush, Sclerophthora macrospora downy mildew, Sclerotium fumigatroumum hydrophilum, Scotinophala cinerea, Scotinophala, Scotinofara coactata (black rice bug in Scotino pula) hara latuscula), Scothophala lurida (black rice bug), Sesamia calamistis (African pink stem cerma smelter cerma stem cerma stem ceram cerma) ) (Greater sugarcane borer), Sesamia inferens (purple stem boner) (Sesamia nonioleidor (Sesamia anoraidone corn) rn stalk borer), sesamenonagrioides botanefaga (Sesamia nonagrioides botanephaga), sesame uniformis (short borer caterpillar (short) Root Foxtail, Setaria pumila (Yellow foxtail), Setaria verticillata (Bristol foxtail foxtail) (Green foxtail), Setaria viridis (green foxtail), cetomorpherutella (Setospharia holmiet), sato pharia (spots) Leaf spot of grasses), fern actor (Sida acuta), bloomweeds, sigmodon (field rat), cetofilus seleze (Sitophylus oryzae in cereal) ) Sitophilus zeamais (Greater grain weevil), Sitotroga cerreala (Grain moth (grain moth), Sola terraf (Siga terafalso) White-backed planthopper (WBPH), Sogatela vibix (white-backed plantaper), Sorghum haresen (Sorghum halesson) S phaerulina oryzina (narrow brown leaf spot), Sphenocrea zeylanica (wedgewort), spopodopteracium lawn)), Spodoptera exempta (black armyworm), Spodoptera exigua (s), beet armywarp or Stolyp (s). Warm, Egyptian cotton rm, Egyptian cotton), (Spodoptera litura), Taro caterpillar, Spodoptera mauritia (Podder territory) Spodoptera mauritia acryloctoides (armywarm), Spodoptera omithogalli (yellow striped stalk) (yellow striped stalk) Gustoe beetle (Drugstore beetle), Stenchaetotrips (rice thrips), Stenopoladorus salis (Stenopola dorsolis), Stenotus brustus plantbug), Strigger angustifolia (Witchweed), Strigger aspera (Witchweed), Strigherwichia (Striggawid) The Striga lutea (witch weed), Synedrelella nodiflora (syndrella), tagosodes banban p (depot) Tagosodes oryzicolus (rice delphacid), Tagosodes pussanus, Tarbinskielsus portetosel (rice field cricket) Tarsonemus Fuzoensis (Tarso) nemus fuzhouensis, Tarsonemus tarpae, Tericota augias, Tenebroids maritanis (Cadnuuret) Rice root aphid), Tetranychus urticae (Two-spotted spider mite), Tia oryzivora (an orange rice leaf) (Thaia subrufa), Thanateforus cucumeris (multiple names depending on host), Thioptera botioides, Thrips palmither dip (Trips palmitre) Deciduous worms (brown stem bug), Tibraca limbativentris (stinkbug), Tilletia Barclayana (rice blast bacterium) (Tipula aino) (Crane f, rice f y, rice)), Toyapropinqua, Trianthema portulacastrum (horse purslane), Tribolium casteumetium (Tribolium casteumetium) Tribolium confusum (confused floor beetle), Trikispa sericea (rice, hispeid (rice), roti ost (ro) or trochodol (us) nema Odes)), Tridactylus minutus, Trigonotylus coelestialium (rice leafbug), Trigonotil sulficornus lugoulturu logo Trogoderma grenarium (Khapra beetle), Trogodera variabile (Grain dermestid), Tyrencorinth naturus (Stunt nematode)), Tylencholhynchus brevillineeats (pod scab nematode), Tiffaester stercore, et al. Typhula ishikariiensis (Speckled cereals snow mould), Tyrophagus putrescentiae (Serialmide U.S.) de mestoides, Uromyces coronatus (rice of rice), Ustylaginoidea virens (false smut), Uturicuraur Bladderwort), Xanthomonas campestris (black rot of crucifers), Xanthomonas oryzae pv. Oryzae (rice leaf blight), Xanthomonas oryzae pv. Oryzae (rice leaf blight). Orijikora
(Xanthomonas oryzae pv. Oryzicola) (bacterial leaf streak of rice), Xifinema (Dager nematode amica) (Dagger nematode)), Xphinema ifacolum (dagger nematode), Zeros orientalis, Zulia entreliana.

  Another aspect is a method of applying a liquid AL formulation type plant protection composition according to the present invention. Appropriate standard methods for this are known to those skilled in the art. In general, plant protection compositions are applied to the edge of paddy fields by using water-soluble bottles, seat bags or other containers, or dripped from special shaking bottles or knapsack type sprayers or similar It is convenient to apply directly to the water surface of a paddy field by spraying using a device.

  The present invention is illustrated by the following examples without however being limited thereto.

1. Preparation example: Plant protection composition of formulation type AL (solution that can be used as it is in all other liquids)-variant 1 (AL1)
In this case, an active substance concentrate was prepared and subsequently mixed with solvent and wetting agent.

2. Preparation example: Plant protection composition of formulation type AL (solution that can be used as it is in all other liquids)-variant 2 (AL2)
In this case, an active substance concentrate was prepared and subsequently mixed with solvent and wetting agent.

3. Preparation example: plant protection composition of formulation type AL (solution that can be used as it is in all other liquids)-variant 3 (AL3)
In this case, an active substance concentrate was prepared and subsequently mixed with solvent and wetting agent.

4). Preparation example: Plant protection composition of formulation type AL (solution that can be used as it is in all other liquids)-variant 4 (AL4)
In this case, an active substance concentrate was prepared and subsequently mixed with solvent and wetting agent.

5). Preparation example: Plant protection composition of formulation type AL (solution that can be used as it is in all other liquids)-variant 5 (AL5)
In this case, an active substance concentrate was prepared and subsequently mixed with solvent and wetting agent.

6). Preparation example: plant protection composition of formulation type AL (solution in all other liquids that can be used as it is)-variant 6 (AL6)
In this case, an active substance concentrate was prepared and subsequently mixed with solvent and wetting agent.

7). Preparation example: Plant protection composition of formulation type GR (granule)-variant 1 (GR1)
In this case, an active substance concentrate was prepared and subsequently absorbed into an inert material.

8). Preparation Example: Plant Protection Composition of Formulation Type GR (Granule)-Variant 2 (GR2)
In this case, an active substance concentrate was prepared and subsequently absorbed into an inert material.

9. Preparation Example: Plant Protection Composition of Formulation Type EC (Emulsifiable Concentrate) In this case, an active substance concentrate was prepared and subsequently mixed with an emulsifier.

10. Preparation Example: Plant Protection Composition of Formulation Type EW (Emulsion, O / W) In this case, an active substance concentrate was prepared and subsequently emulsified in water. The concentrated emulsion was then stabilized.

11. Preparation Example: Plant Protection Composition of Formulation Type ME (Microemulsion) In this case, an active substance concentrate was prepared and subsequently emulsified in water to obtain a microemulsion.

12 Preparation Example: Plant Protection Composition of Formulation Type EG (Emulsifiable Granules) In this case, an active substance concentrate was prepared. Subsequently, the active substance concentrate emulsion was sprayed over the inert material in a granulator.

13. Preparation Example: Plant Protection Composition of Formulation Type SE (Suspoemulsion) In this case, an active substance concentrate was prepared. The emulsion of active substance concentrate was comminuted in an aqueous composition containing a second pesticidal active substance and the solid particles were subsequently dispersed.

14 Preparation Example: Plant Protection Composition of Formulation Type SL (Soluble Concentrate) In this case, an active substance concentrate was prepared and subsequently mixed with a solvent and a surfactant.

  The following were used in the above examples. Purasolv® EHL (2-ethylhexyl lactate) (Purac Biochem, Gorinchem, Netherlands or Barcelona, Spain), Etiprol (generic name), DMSO (Krahn Chemie / Interorgana, Hamburg, Germany), Bree Oh registration 44 Trademark) (polydimethylsiloxane, Goldschmidt, Essen, Germany), BPMC (generic name), thiodicarb (generic name), benzyl alcohol (supplier), Break Thru OE 440 (registered trademark) (polydimethylsiloxane, Goldschmidt, Essen) Germany), Hallcomid M8-10® (CP Hall, Chicago, USA), epilite 30/60 mesh® (Tolsa SA, Madrid, Spain), monopropylene glycol (Sigma-Aldrich, Taufkirchen, Germany), Biodac Carrier 20/40 mesh® (Sasol, Hamburg, Germany) (Generic name), Solvesso 100 (registered trademark) (aromatic hydrocarbon fluid, Exxon, Cologne, Germany), acetic acid (many suppliers), BHT (ptylated hydroxytoluene, Fluka, Germany), Emulsogen EL 360 (registered trademark) ) (Fatty acid polyglycol ester, Clariant, Frankfurt, Germany), dodecylbenzenesulfonic acid Ca salt (chemical group, eg Akz o Nobel, Dueren, Germany), Cyclohexanone (Sigma Aldrich, Taufkirchen, Germany), Benzyl Benzoate (Sigma Aldrich, Tafkirchen, Germany), Methyl paraben (registered trademark) (Chemag, Germany) (Chemag, Frankfurt, Germany), Empiphos O3D® (complex organophosphate, Huntsman, Neu-Isenburg, Germany), Witconol NS 500 K® (polyoxyethylene-polyoxypropylene block copolymer, Osi / Akzo Nobel, Frankfurt, Germany), Genapo X060 (registered trademark) (ethoxylated alcohol, Clariant, Frankfurt, Germany), Polyvinylpyrrolidone K 90 (registered trademark) (also Luviskol K90, BASF, Ludwigshafen, Germany), citric acid (many suppliers il il Rho16) ) (Antifoam, Rhodia, Frankfurt, Germany), Rhodosil 426R® (antifoam, Rhodia, Frankfurt, Germany), anisole (eg, Rhodiasolv MPE®, Rhodia, Frankfurt, Germany) Xylene glycol (Sigma-Aldrich, Taufkirchen, Germany), Soprophor BSU (registered trader) ) (Tristyrylphenol + 16EO, Rhodia, Frankfurt, Germany), Solvesso 200® (aromatic hydrocarbon fluid, Exxon, Cologne, Germany), tributyl phosphate (eg, Merck or Bayer, Germany), Mowiol 3- 83 (registered trademark) (Kuraray, Frankfurt, Germany), Mowiol 4-88 (registered trademark) (Kuraray, Frankfurt, Germany), Dispersing agent 1494 (registered trademark) (Clariant, Frankfurt, Germany), acetophenone (Haarmmann, Haarmann, Haarmann Holzminden, Germany), Soprophor FLK® (polyarylalkoxylate phosphorus) Esters, potassium salts, Rhodia, Frankfurt, Germany), Rhodopol G® (Rhodia, Frankfurt, Germany), Proxel GXL® (Avecia, Frankfurt, Germany), Geropon SDS (registered trademark) Cxinate, Rhodia, Frankfurt, Germany), acetic acid (many suppliers), acetamiprid (generic name), γ-butyrolactone (Sigma-Aldrich, Taufkirchen, Germany), Synperonic A3 (registered trademark) (synthetic primary alcohol ethylene oxide) Condensate, Unichema, Everberg, Belgium), Soprophor D88 15® (ethoxylated distyrylphenol) Le, Rhodia, Frankfurt, Germany).

15. Biological test example 1: Result procedure of greenhouse experiment:
Formulations AL1 and AL2 (see Preparation Examples 1 and 2 for preparation and composition) were tested. The organism harmful to the suppressed rice field is the rice planthopper, Nilaparvata lugens (Tobiro planta, BPH).

Before each test, 40-50 rice seedlings per plant (Oriza sativa, Varia variety) were cultivated in standard soil (ED73) for 10 days. One day before application, the surface of the soil was covered with quartz sand, and the pot was placed in a sufficiently deep container, which was filled with water just below the soil surface (upper edge of the pot). About 50 rice planthoppers (the developmental stage was late larva or early adult) were transferred into each pot. Subsequently, a plastic bag with a hole was put on the entire surface. After the rice planthopper settled on the plant, the water level in the container was gradually raised until it was above the level of the soil surface (the upper edge of the pot). When the water area reached a certain area (cm ² ) in total, it was decided that the water level required for the experiment was reached.

  Application was carried out by pipetting a certain amount with a pipette and pouring it onto the water surface. The dosages tested corresponded to 3, 4 and 5 L / ha (ha). The individual results shown below were obtained by repeating the test consisting of four pots planted with rice twice.

  Evaluation was performed at days after application (DAA) 1, 4, 7, and 13 days. For this, the number of live planthoppers was determined and the effectiveness was calculated in% (using the Henderson-Tilton equation).

  result:

Note:
The effectiveness of the agrochemical active substance etiprol against the pest Nilaparvata lugens was obtained quickly (after 1 DAA), and the effect was sustained (after 13 DDA), regardless of which AL formulation was used.

16. Biological Test Example 2: Procedure procedure for greenhouse experiment on plant damage (see Biological Test Example 1):
Plant damage was determined at 7 and 13 days after application (DAA). For this, the growth and phenotype of rice was rated in% plant damage (in this case high% means severe damage).

Note:
In this greenhouse experiment, the test plants were sufficiently resistant to the two AL formulations tested.

17. Biological test example 3: Results of field test results:
Formulation AL1 (see Preparation Example 1 for preparation and composition) was tested in comparison to a standard EC formulation. AL1 with 3% by weight of etiprole has dosages of 50 (dosage 1), 83 (dosage 2), 117 (dosage 3) 4 and 150 (dosage 4) g / ha, including 10% by weight of standard etiprol. EC was doses 15 (dosage 1), 25 (dosage 2), 35 (dosage 3) and 45 (dosage 4) g / ha, each of which contained the same agrochemical active substance etiprole amount. .

The field test locations were JiangSu-RF, Hun-IPP and Xiushan PPS-CQ in China. Formulations containing the active substance were applied by manually spraying onto paddy fields using a knapsack sprayer. The layout of the test sections was 30 m ² each according to the RCB method. The results for the individual locations below are based on three iterations each.

  The suppressed paddy pests are the rice planthopper Nipaparveta lugens (Blounder, BPH) and Sogatala furcifera (Sesame planta, WBPH), which occur in the area with a natural spread and are two of the useful spiders. The following effects were also confirmed.

  Inhibition results or secondary effects were determined by% inhibition (= decrease in number of organisms compared to untreated controls) or% secondary effects at different post treatment days (= DAT).

Note:
The effect of the pesticide active substance Ethiprol in the AL1 formulation on two harmful organisms was clearly increased on average compared to the standard EC formulation. Secondary effects on useful spiders with the use of AL1 formulations did not increase compared to standard EC formulations.

18. Density, pH value, water surface partition and stability procedures:
Use of each standard method.

  result:

Note:
This data indicates that all formulation types tested have a reasonable density. Regardless of the time and formulation type used in each case, satisfactory or excellent distribution on the water surface was confirmed. Good stability under enhanced storage conditions (50 ° C. for 6 weeks) was confirmed for all formulations tested.

  In addition to this data, for formulation types AL1 to AL6 after storage at −10 ° C., very few signs of crystal formation were observed, demonstrating that these formulation types are stable to freezing. .

  In addition, the preferred flash points of these formulation types, such as 95 ° C for AL1 and 96 ° C for AL3, may eliminate or reduce the expense for special safety measures, so Simple storage of these plant protection compositions becomes possible.

Claims (13)

a) 2-ethylhexyl lactate,
b) Use of a plant protection composition comprising one or more active pesticides dissolved therein, and optionally one or more formulation aids, to control pests in rice cultivation . Pesticide active substances
1) Aclonifene, amidosulfuron, anilophos, aslam, benfresate, bispyribac sodium salt, bromoxynil, clotorulone, cyclanilide, desmedifam, diclohopmethyl, diflufenican, diuron, etephone, etofumesate, ethoxysulfuron, phenoxaprop-P- Ethyl, Fentrazamide, Flucarbazone sodium, Flufenaset, Flurtamone, Foramsulfuron, Glufosinate ammonium, Glyphosate, Iodosulfuron, Ioxonyl, Isoproturon, Isoxaflutol, Linuron, Mefenacet, Mesosulfuron methyl, Metamitron, Methoslam, Metribuzin , Oxadialgyl, oxadiazone, fenmedifam, sodium propoxycarbazone, Rukotorion and thidiazuron,
2) Acetamiprid, acrinatrin, aldicarb, amitraz, azinphosmethyl, betacifluthrin, carbaryl, clothianidin, cyfluthrin, cypermethrin, deltamethrin, endosulfam, etiprole, etoprophos, phenamiphos, fenthion, fipronil, imidacloprio, oxymeclosamide, carbamide Tonmethyl, permethrin, hosalon, prothiophos, silafluophene, spirodiclofen, spiromesifen, thiacloprid, thiodicarb, tralomethrin, triazophos, trichlorfone and triflumurone,
3) Viteltanol, carbendazim, carpropamide, edifenphos, phenamidon, fenhexamide, fentin, fluoxastrobin, fosetylaluminum, iprodione, iprovaricarb, pencyclon, propamocarb hydrochloride, propineb, prothioconazole, pyrimethanil, spiroxamine, 2. Use according to claim 1 selected from the group consisting of tolylfuranide-diclofluanide and trifloxystrobin. Pesticide active substances
2) Acetamiprid, acrinatrin, aldicarb, amitraz, azinphosmethyl, betacifluthrin, carbaryl, clothianidin, cyfluthrin, cypermethrin, deltamethrin, endosulfam, etiprole, etoprophos, phenamiphos, fenthion, fipronil, imidacloprio, oxymeclosamide, carbamide Use according to claim 2, selected from the group consisting of tonmethyl, permethrin, hosalon, prothiophos, silafluophene, spirodiclofen, spiromesifen, thiacloprid, thiodicarb, tralomethrin, triazophos, trichlorfone and triflumuron.   4. Use according to claim 3, wherein the pesticidal active substance is selected from the group consisting of fipronil and etiprol.   Use according to one or more of claims 1 to 4, wherein the plant protection composition comprises polydimethylsiloxane as formulation aid C).   A method for suppressing pests in paddy rice cultivation, wherein the plant protection composition according to any one of claims 1 to 5 is applied to or in the water of a paddy field. a) 2-ethylhexyl lactate,
b) one or more dissolved in this,
1) Aclonifene, amidosulfuron, anilophos, aslam, benfresate, bispyribac sodium salt, bromoxynil, clotorulone, cyclanilide, desmedifam, diclohopmethyl, diflufenican, diuron, etephone, etofumesate, ethoxysulfuron, phenoxaprop-P- Ethyl, Fentrazamide, Flucarbazone sodium, Flufenaset, Flurtamone, Foramsulfuron, Glufosinate ammonium, Glyphosate, Iodosulfuron, Ioxonyl, Isoproturon, Isoxaflutol, Linuron, Mefenacet, Mesosulfuron methyl, Metamitron, Methoslam, Metribuzin , Oxadialgyl, oxadiazone, fenmedifam, sodium propoxycarbazone, Rukotorion and thidiazuron,
2) Acetamiprid, acrinatrin, aldicarb, amitraz, azinphosmethyl, betacifluthrin, carbaryl, clothianidin, cyfluthrin, cypermethrin, deltamethrin, endosulfam, etiprole, etoprophos, phenamiphos, fenthion, fipronil, imidacloprio, oxymeclosamide, carbamide Tonmethyl, permethrin, hosalon, prothiophos, silafluophene, spirodiclofen, spiromesifen, thiacloprid, thiodicarb, tralomethrin, triazophos, trichlorfone and triflumurone,
3) Viteltanol, carbendazim, carpropamide, edifenphos, phenamidon, fenhexamide, fentin, fluoxastrobin, fosetylaluminum, iprodione, iprovaricarb, pencyclon, propamocarb hydrochloride, propineb, prothioconazole, pyrimethanil, spiroxamine, A plant protection composition comprising an agrochemical active substance from the group consisting of tolylfluanide-diclofluanide and trifloxystrobin, and c) optionally one or more formulation aids. Pesticide active substances
2) Acetamiprid, acrinatrin, aldicarb, amitraz, azinphosmethyl, betacifluthrin, carbaryl, clothianidin, cyfluthrin, cypermethrin, deltamethrin, endosulfam, etiprole, etoprophos, phenamiphos, fenthion, fipronil, imidacloprio, oxymeclosamide, carbamide The plant protection composition according to claim 7, which is selected from the group consisting of tonmethyl, permethrin, hosalon, prothiophos, silafluophene, spirodiclofen, spiromesifen, thiacloprid, thiodicarb, tralomethrin, triazophos, trichlorfone and triflumuron.   The plant protection composition according to claim 8, wherein the agrochemical active substance is selected from the group consisting of fipronil and ethiprol.   10. A plant protection composition according to one or more of claims 7 to 9, comprising polydimethylsiloxane as formulation aid C). _11. A plant protection composition according to one or more of claims 7 to 10, comprising a solvent from the group consisting of benzyl alcohol, DMSO, _C12-15 alkyl benzoate, diisopropyl adipate, N-octylpyrrolidone and dimethylacetamide. a) 2-ethylhexyl lactate, and b) one or more dissolved therein
1) Aclonifene, amidosulfuron, anilophos, aslam, benfresate, bispyribac sodium salt, bromoxynil, clotorulone, cyclanilide, desmedifam, diclohopmethyl, diflufenican, diuron, etephone, etofumesate, ethoxysulfuron, phenoxaprop-P- Ethyl, Fentrazamide, Flucarbazone sodium, Flufenaset, Flurtamone, Foramsulfuron, Glufosinate ammonium, Glyphosate, Iodosulfuron, Ioxonyl, Isoproturon, Isoxaflutol, Linuron, Mefenacet, Mesosulfuron methyl, Metamitron, Methoslam, Metribuzin , Oxadialgyl, oxadiazone, fenmedifam, sodium propoxycarbazone, Rukotorion and thidiazuron,
2) Acetamiprid, acrinatrin, aldicarb, amitraz, azinphosmethyl, betacifluthrin, carbaryl, clothianidin, cyfluthrin, cypermethrin, deltamethrin, endosulfam, etiprole, etoprophos, phenamiphos, fenthion, fipronil, imidacloprio, oxymeclosamide, carbamide Tonmethyl, permethrin, hosalon, prothiophos, silafluophene, spirodiclofen, spiromesifen, thiacloprid, thiodicarb, tralomethrin, triazophos, trichlorfone and triflumurone,
3) Viteltanol, carbendazim, carpropamide, edifenphos, phenamidon, fenhexamide, fentin, fluoxastrobin, fosetylaluminum, iprodione, iprovaricarb, pencyclon, propamocarb hydrochloride, propineb, prothioconazole, pyrimethanil, spiroxamine, An active substance concentrate consisting of a pesticide active substance from the group consisting of tolylfuranide-diclofluanide and trifloxystrobin.   A water-soluble container comprising the plant protection composition according to claim 7.