JP2007332335A - Coke creating apparatus including fully automated, waste tire, and whole waste rubber liquefaction through extraction of oil component - Google Patents

Coke creating apparatus including fully automated, waste tire, and whole waste rubber liquefaction through extraction of oil component Download PDF

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JP2007332335A
JP2007332335A JP2006187210A JP2006187210A JP2007332335A JP 2007332335 A JP2007332335 A JP 2007332335A JP 2006187210 A JP2006187210 A JP 2006187210A JP 2006187210 A JP2006187210 A JP 2006187210A JP 2007332335 A JP2007332335 A JP 2007332335A
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cooling
heat
chamber
reaction chamber
oil
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Shinichiro Kojima
信一郎 小嶋
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Abstract

<P>PROBLEM TO BE SOLVED: To provide such an apparatus for disposing of wastes such as waste rubbers and waste tires which can resolve the problems of the safety aspect, cost aspect and loading. <P>SOLUTION: The apparatus has a heat pyrolytic reaction chamber 1 in which the reaction and modification of the weak radiation generated by heating a mica rock, mica-containing rock or mica with the reaction auxiliary gas give the thermal decomposition of wastes such as waste rubbers and waste tires at a low temperature and succeedingly has a slow cooling chamber 2 in which an oil component is condensed, and furthermore has an earthquake-resistant automatic device built-in which is provided with various kinds of sensors to inspect automatically the changes of the whole machines, the temperature range, the flow range and the operation circumstances of the machines and which shows them on a display panel. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

0001−10001-1

本装置は先ず熱源に石油類、ガス類等を活用したバーナーを使用するか、直接加熱するために高周波、又はマイクロ波(単数、複数)IHヒーター(単数、複数)抵抗ヒーター(単数、複数)等を処理物(廃タイヤ、廃ゴム、廃棄物)等を熱分解処理するために構築した装置であり、その装置の原理はガス、LPG、LNG、又は油バーナーを使用した場合、バーナー燃焼室を箱形燃焼室とし、箱形燃焼室の内側には上部に熱を集中して使用するため、内壁側面、底面に不定形耐火物、又は耐火煉瓦、断熱耐熱ボード等を使用し、箱の材質にはステンレス系、耐熱、耐蝕合金、又はニッケル基、耐熱、耐蝕合金、等を使用するか、酸化還元雰囲気に強いハステロイ、ニッケル板等を使用し、燃焼ボックスを形成する。燃焼ボックスのバーナー焚き込み口にバーナーをセットし、箱形燃焼室に静圧を掛ける場合もあるが、常圧の場合もある。箱の内部で燃焼を行い、箱上部は処理用輻射対流遠赤熱が処理物に効率よく、付加加熱されるようフラット面及び波打ち面、凹凸面等を付けることもあるが、加工上の問題で平板の上に雲母含有石、又は雲母石、雲母の何れかを使用する場合と、それらの物を同一条件で使用するか、何れかの方法をとり、出来るだけ下部の箱形燃焼室上面の熱交換効率を考慮して配置し、そこから熱によって生じるアルファ線、熱線、遠赤外線、対流熱、輻射熱、等が上部に搬送セットされた処理用トレイ下部、及び処理物の雰囲気よりトレイ内の処理物(処理を行う物)をムラ無く加熱し、処理物の複数点に触媒(熱分解促進剤)を処理する物に合わせてその量をケミカルダイヤフラムポンプ及び定量ポンプ等で定量でない場合、ポンプの吐出量を運転注入タイム等で調整し、処理物に合わせて反応室に挿入及び注入等の行為を行い、この行為の為に注入用、挿入用ノズルは注入時、挿入時目的物に接触、又は挿入、接近させる構造を有し、それ以外は待機位置まで引き上げノズルの消耗及び詰まり等を防止することとし、そのノズルの中間部分及びメンテナンス可能部分に封止のため、つまり内部反応室で反応した油分の逆止をする役目を備え持つ構造とし、必要に応じてノズルを稼働させる構造とする。熱分解を促進するために処理物が反応温度近辺の温度に上昇した時、反応促進剤を速やかに挿入し、反応室内にガス化、霧化し充満することにより油分の抽出、熱分解分離反応を促進する雰囲気を作る。この場合二通りの方法を活用することがある。一つは注入、挿入した触媒が反応室の熱によりガス化、又はナノミスト化することで均一に処理物の分子粒解に働き、それに熱が加わることと、熱を処理物の隅々まで均一に運ぶことで油分の抽出ができる。もう一つはガス化、又はナノミスト化した触媒、雰囲気内に位置する雲母石、又は雲母含有石、雲母加熱することで発する微少な放射線エリアを触媒が接触することで触媒自体を置換し、ゴム類やプラスチック類が有するステッチ構造の干渉方向に働きかけ更に分解速度、分解温度を改善できるような方法と構造を有した方式を使用する場合もある。  This device uses a burner that uses petroleum, gas, etc. as a heat source, or a high frequency or microwave (single, plural) IH heater (single, plural) resistance heater (single, plural) for direct heating Is a device built to thermally decompose treated materials (waste tires, waste rubber, waste), etc. The principle of the device is a burner combustion chamber when using a gas, LPG, LNG, or oil burner Is used as a box-type combustion chamber, and heat is concentrated on the inside of the box-type combustion chamber.Therefore, an indeterminate refractory, or a refractory brick, a heat-resistant heat-resistant board, etc. are used on the side and bottom of the inner wall. The combustion box is formed by using stainless steel, heat-resistant, corrosion-resistant alloy, nickel base, heat-resistant, corrosion-resistant alloy, or the like as the material, or using hastelloy, nickel plate, etc. that are strong in an oxidation-reduction atmosphere. In some cases, a burner is set in the burner inlet of the combustion box, and a static pressure is applied to the box-shaped combustion chamber. Combustion is performed inside the box, and the upper part of the box is subject to processing radiant convection far red heat efficiently and may add a flat surface, a wavy surface, an uneven surface, etc. to be additionally heated. When using either mica-containing stones, mica stones, or mica on a flat plate, either use them under the same conditions, or take one of the methods as much as possible on the upper surface of the lower box combustion chamber. Arranged in consideration of heat exchange efficiency, alpha ray, heat ray, far infrared ray, convection heat, radiant heat, etc. generated by the heat from there are transferred to the upper part of the processing tray lower part and the atmosphere of the processed product in the tray If the processed material (the material to be processed) is heated evenly, and the amount of the processed material is not fixed by a chemical diaphragm pump or metering pump, etc., depending on the material to be treated with the catalyst (thermal decomposition accelerator) at multiple points, the pump Operating discharge volume Adjust according to the time, etc., and perform actions such as insertion and injection into the reaction chamber according to the treatment object. For this action, the injection and insertion nozzles contact, insert, or approach the target object at the time of injection. Other than that, it is raised to the standby position to prevent the nozzle from being worn out and clogged, and the intermediate part and maintainable part of the nozzle are sealed, that is, the non-return of the oil that has reacted in the internal reaction chamber A structure having a function to perform the above and a structure in which the nozzle is operated as necessary. When the treated product rises to a temperature close to the reaction temperature in order to promote thermal decomposition, a reaction accelerator is quickly inserted, and gasification, atomization and filling of the reaction chamber allows oil extraction and pyrolysis separation reaction. Create an atmosphere to promote. In this case, two methods may be used. One is that the injected and inserted catalyst is gasified or nano-misted by the heat of the reaction chamber to work uniformly on the molecular particles of the processed material, and heat is added to it, and the heat is uniformly distributed to every corner of the processed material. Oil content can be extracted by carrying it to The other is gasified or nano-misted catalyst, mica stone located in the atmosphere, or mica-containing stone, the catalyst itself is replaced by contacting the minute radiation area emitted by heating mica, and rubber In some cases, a method having a method and a structure that works in the direction of interference of the stitch structure of plastics and plastics and further improves the decomposition speed and decomposition temperature may be used.

0001−20001-2

熱分解反応室の温度コントロールは熱分解反応室内、及び箱形加熱炉内に設置された温度センサーにより、バーナーの場合は停止、着火、燃焼を断続的に行い、一定の温度を維持するよう制御する。又、熱分解反応室(開放区域)の内部に加熱と反応促進剤、等によって抽出された油煙を凝縮層に効率良く、迅速に導くため、熱分解反応炉内の熱源、箱形燃焼室は断熱構造とし、その断熱構造とは出来るだけ気孔率が高く、熱伝導が低く施工しやすいセラミックウール、等を単数、複数枚一定の厚みまで重ね合わせ、それらを固定するため耐熱、耐蝕性に優れた耐熱、耐蝕ステンレス合金板、等を使用して、断熱仕切りを兼ね備えた取り付け板を四側面と底部にセットし、更に空気層を設けることもあり、その外側に水冷ジャケットで覆い上部発熱部にはジャケットは付けないが、四側面と底部にジャケットをセットし、側面温度と下部温度は異なり、特に底部温度はジャケットをセットした下側が凝縮層の機能を果たすよう低い温度で温度設定をし、四側面ジャケットは熱を外に漏らさないよう空気層の外側より底部ジャケットとは異なる温度設定とし、ジャケット内を通過する水、ブライン溶液等の自動流量調整を各ジャケットの入り口に設置するか、内部ジャケットの場合、適正な温度コントロールを行うため、ジャケットの任意の位置に温度センサーを設置する場合もある。殆どの場合、ジャケットの出口側に温度センサーをセットし、その温度センサーの信号で温度調節器に働きかけ自動流量調整即ち流量の調整を測り常時一定の条件が保てるような構造とし、この全自動流量調整方式は燃焼室部分の外部壁面及び底面、凝縮室の外部壁面及び底面もジャケット構造とし、上記と同じ方法でジャケットの入り口側の全自動流量調整弁、出口側と任意の位置に設置した温度センサーによってジャケットはそれぞれ異なった温度設定が出来るような構造を有し、本発明の本装置の各仕切りゲート部分のゲート温度においても同じような全自動流量制御で異なった温度制御をできるよう構造をとる。それと同様、加熱反応側挿入ゲート、加熱反応側出口ゲート、冷却室側挿入ゲート、冷却室側出口ゲートはしゅう動面になるため固体潤滑性のあるダクタイル鋳鉄等と滑りをよくするためにその相対する反対側のフランジジャケット、しゅう動面についてはハステロイ、インコネル等を使用することが最適であるが、同じダクタイル鋳鉄でも硬度の高いFC200、又はFCD450以上のものを使用する場合もあるが、この場合、引き抜き品、又は連続鋳造品、鋳物、等の材料を使用するが、摺動、機密性を重視するため、加工前に球状化率60%以上の球状化焼鈍を施す。この場合でも全部のゲートは冷却を要するため水冷ジャケット構造とし、その構造は水路をプラス、マイナス放物線上にゲート板の片面に半割状に彫り込み、もう一方に二枚合わせして同じ位置するよう水路を彫り込み、耐熱防水パッキンにも同じ放物線形状で一端を仕上げ、二枚のゲート用水冷通路を備えた物を適度なピッチでパッキンを中心に置き、耐熱防水接着剤をパッキンに均一に塗布し、一枚の板に挫繰りを入れ、耐熱耐食仕様キャップスクリュー等で均一に二枚が接合できるよう締め付ける構造。この構造は熱分解反応層入り口、熱分解反応層出口、除冷層出口に設置し、それらに流す冷却媒体の温度は異なり、又、一定の場合もあり得る。制御については入り口側自動流量調整弁、出口側温度センサーにより常時適温に制御できる構造。The temperature control of the pyrolysis reaction chamber is controlled by a temperature sensor installed in the pyrolysis reaction chamber and in the box heating furnace so that the burner is stopped, ignited and burned intermittently to maintain a constant temperature. To do. In addition, in order to efficiently and quickly guide oil smoke extracted by heating, reaction accelerators, etc. to the condensation layer inside the pyrolysis reaction chamber (open area), the heat source in the pyrolysis reactor, the box combustion chamber is It has a heat insulation structure. The heat insulation structure has as high a porosity as possible, low thermal conductivity and easy to apply ceramic wool, etc. A heat-resistant, corrosion-resistant stainless steel alloy plate, etc. is used to set a mounting plate that also has a heat insulating partition on the four sides and bottom, and an air layer may be provided. Although the jacket is not attached, the jacket is set on the four sides and the bottom, and the side and bottom temperatures are different.In particular, the bottom temperature is low so that the lower side where the jacket is set functions as a condensing layer. In order to prevent heat from leaking outside, the temperature of the four-sided jacket is set differently from that of the bottom jacket from the outside of the air layer, and automatic flow adjustment of water, brine solution, etc. passing through the jacket is installed at the entrance of each jacket In the case of an internal jacket, a temperature sensor may be installed at an arbitrary position of the jacket in order to perform appropriate temperature control. In most cases, a temperature sensor is set on the outlet side of the jacket, and the temperature sensor signal is used to operate the temperature controller to measure the automatic flow rate, that is, to adjust the flow rate so that a constant condition can be maintained at all times. The adjustment method is that the outer wall surface and bottom surface of the combustion chamber part and the outer wall surface and bottom surface of the condensing chamber also have a jacket structure. Depending on the sensor, the jacket has a structure that allows different temperature settings, and the gate temperature of each partition gate part of the present device of the present invention can also be controlled by different fully automatic flow control. Take. Similarly, the heating reaction side insertion gate, the heating reaction side exit gate, the cooling chamber side insertion gate, and the cooling chamber side exit gate are sliding surfaces, so that they can be compared with ductile iron with solid lubricity to improve sliding. It is best to use Hastelloy, Inconel, etc. for the flange jacket and sliding surface on the opposite side, but the same ductile cast iron with high hardness FC200 or FCD450 or more may be used, but in this case However, in order to emphasize sliding and confidentiality, spheroidizing annealing with a spheroidizing rate of 60% or more is performed before processing. Even in this case, since all the gates need to be cooled, a water-cooled jacket structure is used, and the structure is such that the water channel is plus and minus, and the gate plate is engraved in half on one side of the gate plate, and the other two are placed in the same position. Engrave the water channel, finish one end of the heat-resistant and waterproof packing with the same parabolic shape, place an object with two water cooling passages for the gate around the packing at an appropriate pitch, and evenly apply heat-resistant and waterproof adhesive to the packing A structure in which a single plate is wound and tightened so that two pieces can be joined uniformly with a heat-resistant and corrosion-resistant cap screw. This structure is installed at the pyrolysis reaction layer entrance, pyrolysis reaction layer exit, and decooling layer exit, and the temperature of the cooling medium flowing through them is different and may be constant. Concerning the control, it has a structure that can always be controlled at an appropriate temperature by an automatic flow control valve on the inlet side and a temperature sensor on the outlet side.

0001−30001-3

本発明のゲートの開閉は先ず第一に挿入口、熱分解反応室終了移動時、除冷排出口というような順序で動く、これらを稼働させる1分前から緩やかな不活性雰囲気を各区画の中で行い、反応時も緩やかな不活性雰囲気を継続する場合がある。尚、廃棄ゴムの種類によっては不活性雰囲気は一切使用せず、廃棄物が持つ油化分解したガスにより、還元雰囲気を形成し、使用する場合もある。挿入時、熱分解反応室の温度が反応温度まで上昇し、反応が終了と同時に不活性ガスの濃度を上げ、完全な不活性雰囲気を作る。熱分解反応室から除冷冷却室に移動するとき排出口から排出するところまで移動するときと言うような順序で作動する場合が多い。即ち常時待機トレー位置、熱分解反応トレー位置、除冷冷却室位置、除冷冷却終了位置というような順序で一時的に各位置にトレーがあること。運転時間については制御盤に設けたタイマー等で処理する量と形状により異なるが、処理時間を任意に設定できる方式と構造、原理。In the opening and closing of the gate of the present invention, first of all, it moves in the order of the insertion port, the end of the pyrolysis reaction chamber, the cooling outlet, etc. In some cases, a mild inert atmosphere may be maintained during the reaction. Depending on the type of waste rubber, an inert atmosphere may not be used at all, and a reducing atmosphere may be formed and used by the oily decomposed gas of waste. At the time of insertion, the temperature of the thermal decomposition reaction chamber rises to the reaction temperature, and at the same time as the reaction is completed, the concentration of the inert gas is increased to create a completely inert atmosphere. When moving from the pyrolysis reaction chamber to the cooling and cooling chamber, the operation is often performed in the order of moving from the discharge port to the discharge position. That is, there must be a tray at each position temporarily in the order of the standby tray position, pyrolysis reaction tray position, cooling / cooling chamber position, and cooling / cooling end position. The operating time varies depending on the amount and shape processed by the timer etc. provided on the control panel, but the system, structure and principle can arbitrarily set the processing time.

0001−40001-4

除冷冷却室には熱分解反応室同様、水冷ジャケットで除冷冷却室を囲い、上層天井面、中層中間面、下層下の残留油を集め熱分解反応室下部に設けられた凝縮部分に傾斜方向にダクト、又は耐油ホース等でジョイントし、凝縮層内で完全凝縮し、半ガス化状態の油分を凝縮し、完全な油分として凝縮層より外部に凝縮し油として排出出来る構造。又、除冷冷却室上部には防爆モーターを外部に設置し、内部には熱交換促進用ファン、又は循環冷却用防爆対策を施した、シロッコファン等を使用し、循環冷却を行うこともある。熱分解反応室で大方の油は抽出できる物の残留した油分を完全に凝縮させるため、冷却ファンの下部にフィン巻きチューブ、フィンチューブ、メッキ銅管等を熱交換効率を考慮し、ファン直下にハニカム状、千鳥状に複数本設置し、又、メンテナンス性を容易にするためロータリー熱交換器、可変回転型の物を直接除冷冷却室に取り付け、そのロータリー熱交換器の構造はメッキ銅管、ステンレス管等の円筒状の物を媒体の流れるよう両端を残し、管本体を変形させた形状でシロッコファンの羽状、又はロータリー熱交換器外周に送風撹拌用の羽を取り付けることにより施工性もより容易になる。それにより冷風を直接除冷冷却室内のガスを撹拌し、直接冷却を行う場合もある。この場合、メンテナンスが容易で熱交換用ロータリーシロッコファンを可変回転出来るような構造を持つことで低速流域で予め除冷冷却室内に貫通された洗浄用ノズル管からロータリーシロッコ熱交換器に付着した付着物を洗浄する事が出来る。この場合、固定ファンのように分解洗浄する必要が無いので、メンテナンス性がよいと共に高速回転で洗浄液、又は洗浄油を吹き付けることでその遠心力により、除冷冷却室内部の内壁に付着した付着物も同時に洗浄できる。除冷冷却室を強制除冷できる構造としたもの。そのときの温度調整、冷却媒体については他の部分と同じように入り口側に自動流量調整弁を設置し、出口側に温度センサーを設置し、その信号により流量調整温度センサーより自動流量調整弁に信号が入り、処理物処理の状態等を任意に変えることが出来る構造と除冷冷却室内の温度が検知できるよう、温度センサーを設置し、複数個、単数個、複数信号、単数信号により除冷冷却室内の温度状態を確認し、除冷冷却室内に設けたロータリーシロッコファンないしロータリー熱交換器フィン付きローターの回転の上げ下げと全自動流量調節弁に送る熱センサーを冷却媒体の出口側に設置し、ロータリー熱交換器の冷却媒体の流量を全自動調整する構造もあり、このロータリー熱交換シロッコ方式とフィン付き方式の個数については複数個、単数個設置し、複数個の場合、交互方向回転、同一回転、逆回転、正逆回転、単数個の場合、左回転、右回転に可動させる様な構造を有する原理。この原理について除冷冷却室内に反応処理の反応油抽出処理の終了したトレイ及び残留したコークスが室内に入り、ゲートが閉じた状態で回転熱交換する構造を有した物とする。ファン、フィンチューブの組み合わせの場合も同様とする。Like the thermal decomposition reaction chamber, the cooling chamber is surrounded by a water cooling jacket, and the residual oil below the upper ceiling, middle layer, and lower layers is collected and inclined to the condensing part at the bottom of the thermal decomposition chamber. A structure that can be jointed in the direction with a duct or oil-resistant hose, etc., completely condensed in the condensing layer, condensing semi-gasified oil, and condensed out of the condensing layer to be discharged as oil. In addition, an explosion-proof motor is installed outside the upper cooling cooling chamber, and the inside may be cooled by using a heat exchange promoting fan or a sirocco fan with circulation cooling explosion-proof measures. . Most of the oil in the pyrolysis reaction chamber condenses the remaining oil that can be extracted, so a finned tube, finned tube, plated copper tube, etc. are placed directly under the fan in consideration of heat exchange efficiency. A plurality of honeycombs and zigzags are installed, and a rotary heat exchanger and a variable rotation type are directly attached to the cooling room for easy maintenance, and the structure of the rotary heat exchanger is a plated copper tube. Workability can be achieved by attaching cylindrical blades such as stainless steel pipes to the flow of the medium, leaving both ends of the pipe and sirocco fan wings in a deformed shape of the pipe body, or wings for air stirring on the outer periphery of the rotary heat exchanger. Will also be easier. Thereby, the cooling air may be directly cooled by directly stirring the gas in the cooling chamber. In this case, it is easy to maintain and has a structure that can rotate the rotary sirocco fan for heat exchange in a variable manner. Kimono can be washed. In this case, there is no need to disassemble and wash like a fixed fan, so maintenance is good and the deposits adhered to the inner wall of the cooling / cooling chamber due to its centrifugal force by spraying cleaning liquid or cleaning oil at high speed rotation Can be cleaned at the same time. A structure in which the cooling room can be forcibly removed. As for the temperature adjustment and cooling medium at that time, an automatic flow control valve is installed on the inlet side, and a temperature sensor is installed on the outlet side as in the other parts. A temperature sensor is installed to detect the temperature inside the decooling / cooling chamber so that a signal can be entered and the state of processing of the workpiece can be changed arbitrarily, and cooling is performed by multiple, single, multiple signals, single signal. A temperature sensor is installed on the outlet side of the cooling medium to check the temperature condition in the cooling chamber, and to increase or decrease the rotation of the rotary sirocco fan or rotor with fins installed in the cooling cooling chamber and send it to the fully automatic flow control valve. , There is also a structure that automatically adjusts the flow rate of the cooling medium of the rotary heat exchanger, about the number of this rotary heat exchange sirocco method and finned method, Several established, when a plurality of alternating rotating, the same rotation, reverse rotation, forward and reverse rotation, for single several principles having a structure such as is movable left rotation, right rotation. Regarding this principle, a tray having a reaction oil extraction process and a remaining coke in the cooling cooling chamber enter the room and have a structure in which the heat is exchanged with the gate closed. The same applies to the combination of a fan and a fin tube.

0001−50001-5

本発明の特徴は機械を小型化、効率化するため凝縮能力が問題になるが、その問題を本原理で解消する。本原理はフィン巻きチューブ、フィンチューブ、メッキ銅管、ステンレス管等を中心部をパイプ状のシャフトを通し、そのシャフト中央部を遮蔽し、両端にロータリージョイントを設け、フィン巻きチューブ、フィンチューブ、メッキ銅管、ステンレス管等を筒状エリア内に設置し、両端に水路を持つフランジを設置し、そこから各熱交換チューブ類を反対側の同一物に繋ぎ、その部分を回転させることで熱交換効率を大幅に改善できると共に凝縮室内に単数、複数設置することでより効率を高める。この場合ロータリー熱交換機を回す駆動軸は外部に貫通し、貫通した部分にはロータリージョイントを入り口側、出口側に設置し、メンテナンス性の良いような構造とし、さらに本発明のロータリー熱交換機はその機能上油スラッジなどの付着物が回転するので付きにくい物の機能上付着は避けられないため、ロータリー熱交換機、回転エリア外に高圧パイプ、この場合耐食性を要するのでステンレス系のパイプにロータリー熱交換機に均一に噴霧出来るよう噴射ノズル、又は直線上にハニカム状の小さい穴を開け、外部より高圧洗浄液、又は油分と同等の洗い油等を高圧ポンプで噴射しながらロータリーを回転させ、分解することなく洗浄ができる構造と原理。尚駆動については処理物により凝縮速度が異なるため、ギヤーモーターにスプロケット等を取り付け、複数の場合、回転方向を効率のよい方向に変える場合がある。インバーター等により可変、逆転減増速が自由自在にでき、更に副次的に起きる現象であるが熱交換機が回転することにより周囲の負荷熱雰囲気を同様攪拌することにより、より効率を高め小型化することを可能にした原理と構造。The feature of the present invention is that the condensing capacity becomes a problem in order to reduce the size and efficiency of the machine, and this problem is solved by this principle. In this principle, a fin-wound tube, fin tube, plated copper tube, stainless steel tube, etc. are passed through a pipe-shaped shaft, the center of the shaft is shielded, rotary joints are provided at both ends, fin-wound tube, fin tube, Install plated copper tubes, stainless steel tubes, etc. in the cylindrical area, install flanges with water channels at both ends, connect each heat exchange tube to the same thing on the opposite side, and rotate that part to rotate The exchange efficiency can be greatly improved, and the efficiency can be improved by installing one or more in the condensing chamber. In this case, the drive shaft that rotates the rotary heat exchanger penetrates to the outside, and rotary joints are installed on the entrance side and the exit side in the penetrated part to make the structure easy to maintain, and the rotary heat exchanger of the present invention has its structure. Because deposits such as oil sludge are rotated due to their function, they are unavoidably attached to the function of the rotary heat exchanger, high-pressure pipe outside the rotating area, and in this case, corrosion resistance is required. Without disassembling by rotating the rotary while spraying a high-pressure cleaning liquid or washing oil equivalent to the oil from the outside with a high-pressure pump. Structure and principle that can be cleaned. In addition, since the condensing speed differs depending on the processed product, a sprocket or the like is attached to the gear motor, and in the case of a plurality of cases, the rotation direction may be changed to an efficient direction. Variable and reverse speed increase / decrease speed can be freely controlled by an inverter, etc. This phenomenon occurs as a secondary phenomenon, but the heat exchanger is rotated and the ambient load heat atmosphere is agitated in the same manner, thereby improving efficiency and downsizing. The principle and structure that made it possible.

0001−60001-6

本発明は乾留炉に一部は相当する部分があるが、移送用ゲートの開閉時、両端方向より空気の混入を防ぐため、ゲート開閉部分に不活性ガス及び不燃ガス、噴射ノズルを単数、複数設置する事がある。不活性ガス及び不燃ガスの噴射タイミングはゲートを上げる前にあらかじめ不活性エリアを形成するものとするか、各ゲート下部に不燃不活性ガスの噴出口を設け、噴射することで開閉時、空気や可燃ガスの進入を阻止する構造も同様兼ねることとする。又、停電や自然災害で装置全体の停止信号が働いた時など、圧縮液体窒素ボンベ等より緊急冷却用バルブの設置で各炉内全てに冷却と防爆を兼ねて、気体窒素を急速挿入する機構。この場合、挿入量が多いため出口側にも排出弁を設置した構造を有する場合があること。Although the present invention has a part corresponding to the dry distillation furnace, when opening and closing the transfer gate, in order to prevent air from entering from both ends, the gate opening and closing part has a single or plural inert gas, non-combustible gas, and injection nozzle. May be installed. Inert gas and non-flammable gas injection timing shall be formed in advance before raising the gate, or a non-flammable inert gas jet outlet is provided at the bottom of each gate to inject air, The structure that prevents the inflow of combustible gas also serves as the same. In addition, when a stop signal of the entire device is activated due to a power failure or natural disaster, a mechanism that rapidly inserts gaseous nitrogen into each furnace for both cooling and explosion prevention by installing an emergency cooling valve from a compressed liquid nitrogen cylinder etc. . In this case, since there is a large amount of insertion, it may have a structure with a discharge valve installed on the outlet side.

0001−70001-7

本発明は熱源に石油類、又はガス類を燃焼させて熱を得るバーナー等を設置したり、高周波誘導コイル、マイクロ波、IHヒーター、抵抗式ヒーター等を使用するが、その中でバーナーを使用した場合できるだけ安価なエネルギー源を活用するため、A重油からA重質油、又はB重油相当の油が使用できるよう燃料供給燃焼経路に予熱ヒーターをセットして、燃焼条件が整うよう予熱をかけようとするものであり、その予熱ヒーターは耐油性のものを活用し、尚かつそれを温度制御し、一定温度にしてバーナーノズルに導く道中は熱伝導のよい銅管などを使い火傷などをしないよう保護対策を十分施したもの。In the present invention, a burner or the like that obtains heat by burning petroleum or gas as a heat source is used, or a high frequency induction coil, microwave, IH heater, resistance heater or the like is used, among which a burner is used. In order to use the cheapest possible energy source, set a preheater heater in the fuel supply combustion path so that the fuel equivalent to A heavy oil or A heavy oil can be used, and preheat it so that the combustion conditions are adjusted The pre-heater is oil-resistant, and the temperature is controlled, and the temperature is set to a constant temperature and led to the burner nozzle. The protection measures were taken.

0001−80001-8

本発明の冷却部分の根源はブラインチラーを主として使用し、その他にも直接膨張冷媒冷却方式、冷水冷却方式などの組み合わせを使用する場合もあるが、本発明にとりあえず標記する事柄はブラインチラーとブライン溶液を使用し、ブラインチラー内をブライン溶液を通過させ、冷やされた溶液を冷却ブライン溶液タンク下層部に入れ、冷却プールを形成する。ブラインチラーから冷やされた冷却媒体(ブライン水)は本発明の冷却部分に集合管より送り出す(ラインポンプを使用する)を送り出すことによりタンク内部に吸引口が必要となるが、吸引口はブラインチラーより所定の温度まで冷却された液を溶液タンク内の集合管吸引口まで誘導管を設け、インテークポートに吸引されるよう誘導管を設ける。この誘導管にはブライン溶液等の減量に伴うラインへの供給を検知するため、流量センサーと圧力スイッチを二次側ラインポンプ出口近くの集合管に取り付け、ラインポンプ等の空運転の防止、チラーの運転状態を検知するため、ブライン溶液の温度検知を行う。この信号を制御盤に送り、この装置で重要な冷却温度勾配が出来るよう感知する機構を設置することで安全性が増す。ブライン溶液の補充は純水器とブライン溶液の自動混合をした後、タンク内に設けたレベルセンサーで減量を検知し、減量した物だけ自動補充するような構造を設置することもある。尚溶液タンクの形状は長方形、正方形、円筒形、どのような形でもほぼ似たような方法を講じ、集合管、アウトテーク(戻り)については集合管に集合し、ブライン溶液タンク上部に静かに戻し、循環使用する場合と戻りを高温の場合、熱交換機を通し、熱を回収し、多目的に使用をすることもあること。The root of the cooling part of the present invention mainly uses a branchler, and in addition, there are cases where a combination of a direct expansion refrigerant cooling method, a cold water cooling method, or the like is used. Use the solution to pass the brine solution through the branchler and place the cooled solution in the lower part of the cooling brine solution tank to form a cooling pool. The cooling medium (brine water) cooled from the blownler requires a suction port inside the tank by sending it out from the collecting pipe (using a line pump) to the cooling part of the present invention. A guide pipe is provided so that the liquid cooled to a predetermined temperature is provided to the collecting pipe suction port in the solution tank and sucked into the intake port. A flow sensor and pressure switch are attached to the collecting pipe near the outlet of the secondary side line pump to detect the supply of the brine solution to the line when the brine solution is reduced. The temperature of the brine solution is detected in order to detect the operating state. Safety is increased by installing a mechanism that sends this signal to the control panel and senses the critical cooling temperature gradient in the device. In order to replenish the brine solution, after automatically mixing the pure water device and the brine solution, the level sensor provided in the tank may detect the decrease, and a structure may be installed to automatically replenish only the reduced amount. The shape of the solution tank is rectangular, square, cylindrical, and almost the same method is used. Collecting pipes and outtakes (returns) are gathered in the collecting pipe and gently placed above the brine solution tank. When returning and circulating, and when the return is at high temperature, heat may be collected through a heat exchanger and used for multiple purposes.

0001−90001-9

本発明のバーナーを使用した場合、熱源燃焼室(箱形燃焼室)より燃焼、排熱は内部の静圧を正しく調整できるよう単数、複数の排気口に排気調整ダンパーを設置し、その後においては排熱を集合し、本装置で回収できた油の分留装置に導き、冷却液(ブライン水)の一部を全自動流量制御弁を取り付け、出口で温度センサーによる検知を行い、温度調節器で一定の温度を設定し、さらに分留装置に設けられた凝縮室にも同じような低めな温度設定をし、油分の分留を行うこと。When the burner of the present invention is used, an exhaust adjustment damper is installed at one or more exhaust ports so that combustion and exhaust heat from the heat source combustion chamber (box combustion chamber) can be adjusted correctly, and thereafter The exhaust heat is gathered and led to the oil fractionation device that can be recovered by this device. A part of the coolant (brine water) is attached with a fully automatic flow control valve, detected by the temperature sensor at the outlet, and the temperature controller Set a constant temperature at, and set a similar lower temperature in the condensing chamber provided in the fractionator to perform fractional distillation of oil.

0001−100001-10

本発明の装置は今まで小型の場合、殆どの装置が考慮されていなかった耐震自動停止装置及び設置場所によっては傾きが生じる場合があり、又、設置時についても傾いたまま設置することがあることを想定して、傾斜計等を内蔵させ、常に正常な状態で運転できるよう操作パネルには大型タッチパネルを使用し、表示においては機械構造等を表示し、温度、機器の状態等は誰にでもわかりやすくアニメ表示等を表示し、それに併せて音声素子を内蔵させ、常にオペレーターに対して装置の状態を把握できるよう考慮した物でこの考慮も本発明の主たる原理を活用し、機械本体のコストが大幅に下げられたために新しい廃棄物処理思想として定着させることができること。When the device of the present invention is small in size up to now, there may be a tilt depending on the earthquake-proof automatic stop device and installation location, which most devices have not been considered, and may be installed while tilting. As a precaution, the operation panel uses a large touch panel so that it can always be operated in a normal state, and the display shows the mechanical structure, etc. However, an easy-to-understand animation display etc. is displayed, and in addition to this, a sound element is built in, and this is also considered so that the operator can always grasp the state of the device, and this consideration also utilizes the main principle of the present invention, Since the cost has been greatly reduced, it can be established as a new waste disposal concept.

0001−110001-11

本発明は環境のクリーン化、即ち臭気、排煙、余剰な二酸化炭素等の排出を抑え更に省エネルギーを装置全体に駆使した発明であるが、本装置を制御する制御回路、計装回路に従来では希に見る補助回路つまり主回路が故障等を起こした場合自動、又は手動により、予備制御回路に切り替えられる仕組みと構造を有した物で安全対策としても十分な制御方式を取ることを考慮し、廃棄物処理の常識を覆す如く、その構造全てを変化させた物であり、主回路には入手の簡単なシーケンサ等を活用し、予備回路にはマイクロコンピューターを主としたIC基板回路による制御方式を取り、これに自己診断機能を入れて相互に運転状態を確認出来るような構造ないし回路を構成し、尚かつ本装置の状態を電話回線網を通し、常時運転情報を管理場所ないし監視、メンテナンス、販売会社、メーカー等に情報を通知するシステムを用い、その逆で各装置に対し、パラメーターや温度設定、処理条件等を変更できる仕組みを持ち得た物とする場合もあること。The present invention is an invention that cleans the environment, i.e. suppresses the emission of odor, smoke, excess carbon dioxide, etc., and makes full use of energy savings. Considering taking a sufficient control method as a safety measure with a mechanism and structure that can be switched to a spare control circuit automatically or manually when an auxiliary circuit that is rarely seen, that is, the main circuit has failed, etc. The entire structure has been changed so as to overturn the common sense of waste disposal. The main circuit uses a simple sequencer, etc., and the spare circuit is controlled by an IC board circuit mainly composed of a microcomputer. A structure or circuit that can check the operating status of each other by adding a self-diagnostic function to this, and also the status of this device through the telephone line network, to manage the constantly operating information There may be cases where a system that notifies information to the monitoring, maintenance, sales company, manufacturer, etc. is used, and vice versa, and that each device can have a mechanism for changing parameters, temperature settings, processing conditions, etc. .

0001−120001-12

本発明の装置については冷却が伴うため、その部分に十分な結露対策と断熱対策を施し、省エネルギーを図るため通常はグラスウール、アルミホイル付き断熱材の上にラッキングを施した場合もあるが、本発明は主体的に結露は断熱材と本体冷却部の隙間で発生するため、防性塗料塗布、又は吹きつけ完了後、発泡ウレタンの吹きつけ処理、又はウレタンの塗布を数回重ね合わせ施工を行い結露を完全に防止する構造を有し、この発泡ウレタンは耐熱性が無いため、その吹きつけ後直ちに表面を小手等で成型し、商品価値を上げる形を整える行為を吹きつけとほぼ同時に行い、メンテナンス部分については予めスリーブ等を入れ、発泡ウレタンが付着しないようにする。これらの作業が終了した後、その上に耐熱塗料等を直接数回に分けて吹き付けるか、予め予定していたカバー取り付けビス止め用ステーを設けておき、その上から(吹きつけウレタン)の火災などの保護を目的にカバーを取り付け、メンテナンス部分についてはメンテナンスハッチないしビス止めカバーをし、環境改善循環処理装置としてふさわしいデザインを形成し、デザイン用塗料などを吹き付ける。又は塗布する。但しステンレス系、アルミ系のように耐食性の優れた物を使う場合、全体に塗料を塗布しない場合がある。これは発泡ウレタン吹きつけ時の下地、錆止めも同様でステンレス系を本体に使用したり、パイプ等をステンレス系にした場合も同様下地を作らず、直接吹きつけ処理を行う場合もある。但し取り付け、取り外しのどうしても必要な場所については耐熱グラスウール、結露防止塗料等を使用し、比較的簡単に開放できるようする場合がある。もう一つの方法として結露防止断熱対策部分については箱形カバーを予め設置し、その中に既に硬化した発泡ウレタン片等を挿入し、密閉して封しする場合もある。Since the device of the present invention involves cooling, sufficient condensation measures and heat insulation measures are applied to the part, and in order to save energy, racking is usually performed on glass wool and heat insulating material with aluminum foil. Since the invention mainly causes condensation to occur in the gap between the heat insulating material and the cooling part of the main body, after the completion of spray coating or spraying, the urethane foam spraying process or the urethane coating is performed several times. Since this foamed urethane has a structure that completely prevents condensation, and the foamed urethane has no heat resistance, the surface is molded with a hand or the like immediately after spraying, and the act of adjusting the shape to increase the product value is performed almost simultaneously with the spraying, For the maintenance part, insert a sleeve or the like in advance to prevent urethane foam from adhering. After these operations are completed, heat-resistant paint or the like is sprayed directly on it several times, or a pre-scheduled cover mounting screw stay is provided, and a fire of sprayed urethane is fired from above. A cover is attached for the purpose of protection, etc., and a maintenance hatch or screw stop cover is provided for the maintenance part, a design suitable for an environmental improvement circulation processing device is formed, and paint for design is sprayed. Or apply. However, when using a material with excellent corrosion resistance such as stainless steel and aluminum, the paint may not be applied to the whole. This also applies to the base and rust prevention when foamed urethane is blown, and even if stainless steel is used for the main body, or the pipe or the like is made of stainless steel, the base is not made and spraying may be performed directly. However, in places where installation and removal are absolutely necessary, heat-resistant glass wool, anti-condensation paint, etc. may be used so that they can be opened relatively easily. As another method, there is a case in which a box-shaped cover is installed in advance for the dew condensation prevention heat insulation measure portion, and an already cured urethane foam piece or the like is inserted into the box cover and hermetically sealed.

0001−130001-13

本発明で待機場所から排出完了待機場所に搬送する機構は外部に設けた駆動用ギヤードモーターにインバーター、ステッピングドライバーの場合、ステッピングモーター、サーボモーターの場合、サーボドライバー、インダクションモーターの場合、インバーター等によって待機位置から熱分解反応室内部終了端までの間を一区画とし、その区間に外部でダブルスプロケット、又はタイミングギヤーその他等を使用し、区間駆動を行う。その行動は待機位置より反応室終端部までホイルの側面に耳を付け、蛇行防止するよう形を整え、そのホイルを適度な間隔で搬送方向に配置し、熱分解反応室では放射熱や対流熱、分解促進用助剤通過視角をなくすためにホイルの駆動シャフトを外部と内部で両持ちし、ホイルを駆動する駆動シャフト内に空洞部のあるシャフトを用い、外部に伏流用ロータリージョイントを設置し、熱分解反応室の熱からシャフトを守る行為と同様、熱分解反応室内に既に分解した油煙等を一時的に補助冷却するような構造を有し、更に内部反応室両側面にはトレイ、走行方向に対して平行に二本の水冷ジャケット軸受けを設置し、この軸受けに対しても一時冷却を兼ね、内部対流を促進するため、冷却水を流すと共に搬送用複数個のホイルがトレイと処理物の重量に耐え、加熱されても耐えるよう下部熱源箱形燃焼室の視角まで控え、ホイルを複数個搬送方向に向けて水平に設置し、その一個一個のホイルが搬送用トレイの接触部分に油化、凝縮した油等が付着することでスリップする可能性があるので、トレイのホイルとの接触面の仕上げは摩擦係数を上げるよう、成型を行う。又、尚かつホイル接触面も摩擦係数を上げるようローレット仕上げ等で摩擦係数を上げ、油が付着してもスリップを抑える状況を構築し、熱分解反応室から除冷冷却室に搬送用トレイが移動する際、除冷冷却室側の独立したトレイ搬送用ホイルの回転数は熱分解反応室と反応室用ホイルの周速は受け取り側の除冷冷却室用搬送ホイルと同期運転し、速やかに除冷冷却室に搬送し、受け渡し終了後、熱分解反応室と除冷冷却室の仕切水冷ゲートは閉まるような仕組みを構成した物とし、完全な双方の縁切りを行うような構造を有した物であること。又、除冷冷却室より排出される際、除冷冷却室用に配置されたトレイ搬送用ホイルは、熱分解反応室関係なく冷却が完了できれば排出単独で出来るような構造をいうものである。除冷冷却室のホイルはそのホイルに外部より駆動される駆動軸を左右に伝達するため、一端に水冷貫通シャフトを設け、このシャフトは内部が中空で貫通しており、反対側のホイルに回転を伝達する役目を有し、本シャフトの本体外部両端にダブルスプロケットをセットし、その外側にロータリージョイントをセットし冷却水を本装置にそぐう適正な温度のブライン水を通過させ、必要以上の膨張とダレ、たるみ、材質の劣化等を抑える構造を有している。更にこれは熱分解反応室入り口の低温部分の左右伝達シャフトにも同様機構を備え持つこととし、本装置の搬送伝達機構を形成する物である。外部伝達機構にはダブルスプロケットに交互にチェーンを掛け、熱分解反応室側と除冷冷却室側との駆動系統は別々に別れる仕組みを構成している物で、この仕組みによりそれぞれの条件に合った運転状態を取ることが出来る構造を有する物とする。尚かつ熱分解反応室と除冷冷却室との搬送ホイルの高さなどにバラツキが製作状態で出来る可能性があるので、外部軸受けアジャストによりホイルを一定のレベルに調整できる構造を有していることも同様である。いずれも水冷ジャケットを貫通し、外部に動力伝達部を構築するため、ジャケット貫通部には片面スリーブ機構とし、それを耐熱、耐蝕、耐薬グランドパッキン等で貫通したシャフトをジャケットスリーブの隙間の漏れを阻止するため、調整締め込みにより、耐熱、耐蝕、耐薬グランドパッキン、リーク防止機構を兼ね備えた物である。In the present invention, the mechanism for transporting from the standby location to the discharge completion standby location is an external drive geared motor with an inverter, a stepping driver, a stepping motor, a servo motor, a servo driver, an induction motor, an inverter, etc. The section from the standby position to the end of the pyrolysis reaction chamber is defined as one section, and the section is driven by using a double sprocket, timing gear, or the like outside the section. The action is to listen to the side of the foil from the standby position to the end of the reaction chamber, arrange the shape to prevent meandering, arrange the foil in the transport direction at appropriate intervals, and in the pyrolysis reaction chamber, radiant heat and convection heat In order to eliminate the viewing angle through the auxiliary agent for promoting decomposition, both the outside and inside of the drive shaft of the foil are supported, a shaft with a hollow portion is used inside the drive shaft that drives the foil, and a rotary joint for downflow is installed outside. Like the act of protecting the shaft from the heat of the pyrolysis reaction chamber, it has a structure that temporarily cools the already decomposed oil smoke etc. in the pyrolysis reaction chamber, and further, trays and running on both sides of the internal reaction chamber Two water-cooled jacket bearings are installed in parallel to the direction, and this bearing also serves as temporary cooling and promotes internal convection. In order to withstand the weight of the heat source, keep it at the viewing angle of the lower heat source box combustion chamber so that it can withstand even when heated, and place a number of foils horizontally in the transport direction. Since there is a possibility of slipping due to adhesion of condensed or condensed oil or the like, the finish of the contact surface of the tray with the foil is molded so as to increase the coefficient of friction. In addition, the friction coefficient of the foil contact surface is also increased by knurling so as to increase the friction coefficient, and a situation where slippage is suppressed even if oil adheres is constructed, and the transfer tray is moved from the thermal decomposition reaction chamber to the cooling cooling chamber. When moving, the rotation speed of the independent tray transfer foil on the side of the cooling chamber is the same as the peripheral speed of the pyrolysis reaction chamber and the reaction chamber foil is synchronized with the transfer foil of the receiving side cooling chamber. Conveyed to the cooling chamber, and after the delivery is finished, the partition water cooling gate of the pyrolysis reaction chamber and the cooling cooling chamber is configured to be closed, and has a structure that completely cuts both edges. Be. In addition, when discharged from the cooling cooling chamber, the tray transfer foil disposed for the cooling cooling chamber has a structure that can be discharged alone if cooling can be completed regardless of the thermal decomposition reaction chamber. The foil in the cooling / cooling chamber is provided with a water-cooling penetrating shaft at one end to transmit the drive shaft driven from the outside to the left and right, and this shaft is hollow inside and rotates to the opposite foil. A double sprocket is set at both ends of the main body of the shaft, and a rotary joint is set on the outside of the shaft to allow cooling water to flow through the device. It has a structure that suppresses expansion, sagging, sagging, material deterioration, and the like. Furthermore, this also has a similar mechanism on the left and right transmission shafts in the low temperature portion at the entrance of the pyrolysis reaction chamber, and forms the transfer transmission mechanism of this apparatus. In the external transmission mechanism, double sprockets are alternately chained, and the drive systems for the pyrolysis reaction chamber side and the cooling / cooling chamber side are configured to be separated separately. It shall be the thing which has the structure which can take the operating state. In addition, there is a possibility that variations in the height of the transfer foil between the pyrolysis reaction chamber and the cooling / cooling chamber can be made in the production state, so the foil can be adjusted to a certain level by adjusting the external bearing. The same is true. In both cases, a water-cooled jacket is penetrated and a power transmission part is constructed outside, so the jacket penetration part has a single-sided sleeve mechanism, and a shaft penetrated by heat-resistant, corrosion-resistant, chemical-resistant gland packing, etc. to leak through the gap in the jacket sleeve. In order to prevent it, it is a thing which has heat resistance, corrosion resistance, chemical-resistant gland packing, and a leak prevention mechanism by adjusting tightening.

従来タイヤは破砕され燃焼して熱源として使用したり、或いは800度から900度という高温で熱分解し、油分の抽出をしていた。非常に高温なので抽出油が炭化物を多く含み殆どが抽出油の確保しかできないというのが現状で確保した重質油も高い精度を誇る内燃機関の燃料等にはむかず、舶用エンジンそれも大型のB重油、C重油を燃料とする内燃機にその一部が使用可能となっているだけでまだこれといった技術の確立がされていない。又、装置についても全自動装置自体の開発が行われているものの今のところこれといったものが誕生していないのが現状である。即ち確たる技術の裏付けと原理の構築が出来ていないのが現状である。本発明では、上記の諸問題を解決した上、極めて低い温度で油分の抽出ができ、良質のコークスを生むことも可能になった。Conventional tires are crushed and burned and used as a heat source, or pyrolyzed at a high temperature of 800 to 900 degrees to extract oil. Because the oil is so hot that the extracted oil contains a lot of carbides and most of the oil can only be secured, the heavy oil that is currently secured is not suitable for the fuel of internal combustion engines with high accuracy. Only a part of the internal combustion engine using heavy oil or C heavy oil can be used, and such a technology has not been established yet. In addition, as for the apparatus, a fully automatic apparatus itself has been developed, but at present, no such apparatus has been born. In other words, the current situation is that we have not been able to prove the technology and build the principle. In the present invention, in addition to solving the above-mentioned problems, oil can be extracted at an extremely low temperature, and high-quality coke can be produced.

発明が解決しょうとする課題Problems to be solved by the invention

本発明が解決しようとするのは廃ゴム、廃タイヤ、全般の二次公害のないそしてエネルギーロスのない処理リサイクル燃料全自動生成装置等の開発が社会通念上急務となっている現在、如何に原理を集約して廃棄物の再エネルギー化を実施しようとしているもので、本課題が解消されれば社会的に大きな貢献が可能となり、尚かつ環境面でも不法投棄、焼却時の臭い公害或いは二次使用のアスファルト等に使用され、その次の使用が不可能なのが現状で一時的にはこのような使い方で今まで使用されてきたが、今後このような使用は舗装などのやり換え工事時にでる廃棄物をそのまま埋立などに使用して放置しているに将来はこれらが二次公害として大きな課題となるのは必然的な事だと考え、又、自動化を図ったりする場合、これといった原理もなく、ただ単に乾留釜にて高温に上げて処理しても大変多くのエネルギーロスを作るばかりで、これらを解決しないと資源の再利用はおろか化石資源の枯渇を早めると共に大気中の二酸化炭素の濃度を益々上げ、自然現象即ち地球環境を揺るがす事になりかねないのが現状であり、これらを一つ一つ解決していくのが課題である。The present invention intends to solve the problem of the development of waste rubber, waste tires, fully automatic generation equipment for recyclable fuel that is free of general secondary pollution and energy loss. The principle is being consolidated to re-energize waste, and if this issue is resolved, it will be possible to make a significant social contribution, and also from the environmental perspective, illegal dumping, odor pollution during incineration, or two It is used for asphalt of the next use, and the next use is impossible at present, but it has been temporarily used in this way until now, but such use will be used at the time of replacement work such as pavement in the future In the future, it is inevitable that these wastes will be a major issue as secondary pollution, and if you plan to automate them. Unreasonably, simply raising the temperature to a high temperature in a carbonization kettle will cause a great deal of energy loss. If these problems are not solved, resource reuse will accelerate depletion of fossil resources and atmospheric CO2 emissions. The current situation is that the concentration of carbon will increase and the natural phenomenon, that is, the global environment, may be shaken, and the problem is to solve them one by one.

課題を解決するための手段Means for solving the problem

本発明は今まで高温で処理、油化分離していたものを低温で効率よく油化し、尚かつ残りの部分でコークス等の固形エネルギーとして分離、処理出来る構造と原理を実現可能としたもので、まず第一に熱反応処理室の温度を処理物によっては異なるが、圧倒的に低温で処理可能にしたもので、これを可能にしたのは例一、雲母石、又は雲母含有石、雲母等を加熱したことにより、これより微弱な放射線を放させ、その放射線に反応助剤ガスが反応し、変成して処理物の粒解に入り込み処理物を短時間で分解し、熱をあまり必要としないため、臭気も抑えることが出来、抽出された油分の温度も低く、炭化状態になりにくく凝縮冷却も余り熱損が無く、間接エネルギー使用量を抑えることが出来、これらの原理を凝縮して主々の原理を付随させながら自動化を図ることが出来たのが本原理であり、又、本原理を活用して装置を作ることにより、[0003]の課題を解消したのが本発明である。(但し、熱分解だけでも時間はかかり抽出量は少なくなる。又、分解温度は高くなり、回収できる油分、コークスの品質も低下する。)The present invention makes it possible to realize a structure and principle capable of efficiently converting oil that has been processed and oiled and separated at high temperatures up to now, and separating and processing the remaining portion as solid energy such as coke. First of all, although the temperature of the thermal reaction processing chamber differs depending on the processing object, it can be processed at an overwhelmingly low temperature, and this is made possible by, for example, mica stone, mica-containing stone, mica By heating the etc., weaker radiation is emitted, the reaction aid gas reacts with the radiation, transforms and enters into the granulation of the processed material, decomposes the processed material in a short time, and requires much heat. Therefore, the odor can be suppressed, the temperature of the extracted oil is low, it is difficult to become carbonized, the condensation cooling is not so much heat loss, the indirect energy consumption can be suppressed, and these principles are condensed. With the main principle Was able to achieve a reluctant automation is present principles, also by making the device by utilizing this principle, was to solve the problem of [0003] is an invention. (However, thermal decomposition alone takes time and the amount of extraction decreases. In addition, the decomposition temperature increases, and the quality of recovered oil and coke also decreases.)

発明の効果The invention's effect

本発明の目的は現在社会問題としてクローズアップされている廃棄物の有効的且つ自動的要素を可能にし、今まで普及し得なかった廃タイヤ、廃ゴム、全般等を極めて低温で元々廃棄物自身の持っていた性状を大筋で極端に落とさず炭化水素として分解し、灰分を含まない良質な軽重質油として抽出を可能とし、その用途としては陸上用内燃機関は元より民生用、産業用、工業用、農業用エネルギー源として今後重要な位置づけになるのは元より、この発明によりこれまで行われてきた超大型プラント等で行うような不合理な面と設備投資費を最小限度に納め、又、尚かつメンテナンス性に優れ、ランニングコストも低減し、今まで活用困難であった零細までが使用出来るようにコスト面の方からも大幅な低減が図れる故、普及率が高くなり環境産業が成り立つようなコストとも将来的には可能になる。そうなるとゴミとして捨てることを考える必要もなく有効なエネルギーとして使える資源廃棄物として全て処理されることを前提に発明した物である。The object of the present invention is to enable an effective and automatic element of waste that is currently highlighted as a social problem, and waste tires, rubber, etc. that could not be widely used so far at a very low temperature originally waste itself It is possible to extract it as a high-quality light heavy oil that does not contain ash, and its use as a land-use internal combustion engine is not limited to civilian, industrial, In the future, it will be positioned as an important source of energy for industrial and agricultural use. In addition, the maintenance rate is excellent, the running cost is reduced, and since the cost can be drastically reduced so that it can be used up to the minute that has been difficult to use, the penetration rate is increased. Both cost, such as border industry holds become possible in the future. In that case, it was invented on the premise that it would be treated as resource waste that can be used as effective energy without having to consider throwing it away as garbage.

本発明は廃タイヤ、廃ゴム、全般等の油化つまり廃ゴム、廃タイヤ等においては反応促進剤、又は処理温度が異なるが、何れにしても反応促進剤熱置換、変性ガス雰囲気下で低温加熱、無酸化に近い状態に置かれ、反応熱分解させるが故、良質な油分と良質なコークスが生成出来る物であり、装置自体が小さく処理エリアも単純な構造になっており、それに加え過酷な廃棄物などの油化を行うため、それに伴うメンテナンス性も十分考慮し、それぞれの箇所に新しい原理を発明取り入れ、より一層使い勝手の良い装置として今後環境問題に取り組む方式自体を根底から変えた物で操作の方法もタッチパネルで絵やアニメ等を表示し、専門のオペレーターを必要とせず、又、安全面では地震時に備え耐震自動停止装置等を内蔵し、長期間同じ場所に設置した場合に起こりやすい自然傾斜等によって誤動作等を防ぐ意味で傾斜計も内蔵し、必要以上装置自体に傾きが生じた場合、自動的に運転を停止し、表示パネルに表示するようにしたこと。又、機械全体の動きや温度領域、流域、機械の運転状況等を自動的に検出し、表示パネルに表示して誰にでも使えるよう考慮したもので、表示パネルは無論、音声による操作手順の説明、異常箇所の検知状況の説明等が音声でオペレーターに伝えることができるよう安全で尚かつ正確さを追求した物である。In the present invention, waste tires, waste rubbers, generalized oils, that is, waste rubbers, waste tires, etc., have different reaction accelerators or treatment temperatures, but in any case, the reaction accelerators are replaced with heat in a modified gas atmosphere at low temperature Because it is placed in a state close to heating and non-oxidation and undergoes reaction pyrolysis, it can produce high quality oil and high quality coke, and the equipment itself is small and the processing area has a simple structure. In order to make oily waste, etc., carefully consider the maintainability associated with it, invent new principles at each location, and fundamentally change the system to tackle environmental issues as a more convenient device in the future The operation method also displays pictures, animations, etc. on the touch panel, and does not require a specialized operator. Inclinometer is also built in to prevent malfunction due to natural tilt that is likely to occur when installed in the system, and when the device itself tilts more than necessary, the operation is automatically stopped and displayed on the display panel. thing. In addition, the movement of the entire machine, temperature range, flow range, machine operating status, etc. are automatically detected and displayed on the display panel so that anyone can use it. It is a product that is safe and accurate so that explanations, explanations of the detection status of abnormal parts, etc. can be conveyed to the operator by voice.

本発明の廃ゴム、廃タイヤ、廃ゴム類の装置の横から見た、各区画の水冷ゲートの位置、及び搬送用ホイルに対する駆動動力、伝達経路の簡単な図面、及び配置を表記したものである。Viewed from the side of the waste rubber, waste tire and waste rubber device of the present invention, the position of the water cooling gate in each section, the driving power for the conveying foil, a simple drawing of the transmission path, and the arrangement. is there. 本発明の装置、断面を表記し、その中でも凝縮液化室のロータリー熱交換機、等を明確にした例図であり、それに加え、上部反応促進剤挿入ノズルの動きなどを表記し、又尚かつ、除冷冷却室の標準的ファンだけのもので、表記した例で、これより他には技術の説明の部分で明確に文字で説明したものが、同じ位置に横方向に取り付く場合もあります。The apparatus of the present invention, showing a cross section, and in particular, a rotary heat exchanger in the condensate liquefaction chamber, etc., is an example diagram, in addition to the movement of the upper reaction accelerator insertion nozzle, etc. There are cases where only the standard fan of the cooling / cooling room is used, and in the example shown, what is clearly described in the text in the explanation of the technology may be installed horizontally in the same position. 本発明で図面の中に記載されている例は、搬送処理用トレイの乗っているホイルとその周辺の機構例を記載したもので、部分断面図、つまり搬送部分を上面より見た図面であります。The example described in the drawing of the present invention describes the foil on which the transfer processing tray is placed and an example of the mechanism around it, and is a partial cross-sectional view, that is, a drawing in which the transfer portion is viewed from above. . 本発明中、もし万が一、爆発の危険を考慮して、内部ガスが急激に膨張し、逃げ道として熱分解反応室の上に付く、水冷ジャケットの水路も併せ持って記載したものであり、この部分には実際には千鳥状の位置に垂直に補強バーが設置するが、本図には記載されていませんので技術の説明を熟読して頂ければ、面に対してどれぐらいの圧力が加わるか、十分にご理解頂けるものとしてあえて記載を避けたものである。In the present invention, in the unlikely event that an explosion has occurred, the internal gas expands rapidly and attaches to the thermal decomposition reaction chamber as an escape route, and also includes a water cooling jacket channel. In fact, a reinforcing bar is installed vertically in a staggered position, but it is not shown in this figure, so if you read the technical explanation carefully, how much pressure will be applied to the surface, The description is intentionally avoided as it can be fully understood. 本発明の一番重要な熱分解反応室を真上から見たもので、本発明の技術の分野に十分に記載されているように、ジャケット四面と除冷冷却通路、冷却パイプの配置、温度センサーなどの位置関係が記載された例図であり、これをもって全てとはしないものである。The most important pyrolysis reaction chamber of the present invention is seen from directly above, and as fully described in the technical field of the present invention, the four sides of the jacket, the cooling cooling passage, the arrangement of the cooling pipe, the temperature It is the example figure by which positional relationships, such as a sensor, were described, and this is not all. 本発明の中で除冷冷却室や熱分解反応室の出入りゲート、水冷位置や噴射ノズル、等を記載した例図で、本発明の中で凝縮液化室内に設けたロータリー熱交換機、回転駆動方法、等の例を簡単に記載したものであり、不明点は技術の分野を見て頂ければ良いと思います。In the present invention, it is an example diagram describing the entrance / exit gate of the cooling room and the thermal decomposition reaction chamber, the water cooling position, the injection nozzle, etc. in the present invention. This is just a simple example, and if you have any questions, you should look at the technical field. 本発明の中で燃焼室とその周辺に付随する水冷ジャケット、或いは凝縮用メッキ銅管の設置、熱波の反射板の位置関係の例などを分かりやすく、下部凝縮室を除く、断面で表したものである。In the present invention, the water cooling jacket attached to the combustion chamber and its surroundings, or the installation of a plated copper pipe for condensation, examples of the positional relationship of the heat wave reflectors, etc. are easy to understand, and are represented by a cross section excluding the lower condensation chamber. Is. 除冷冷却室の構造を例として、簡単に表したものである。The structure of the cooling / cooling chamber is simply shown as an example. 本図は駆動伝達機構を待機場所の構造断面として、その例を表したものである。This figure shows an example of the drive transmission mechanism as a structural section of the standby place. 駆動を左から右に伝達し、その水冷経路、封止状態などを例として表したものである。The drive is transmitted from left to right, and its water cooling path, sealing state, and the like are shown as examples. 搬送用ホイルの取り付け状態と負荷の状態、及び熱分解反応室内に貫通する部分の駆動、冷却系統を例として表したものである。The mounting state and load state of the transfer foil, and the driving and cooling system of the portion penetrating the pyrolysis reaction chamber are shown as examples. 本発明で最も重要なのは、熱分解反応室、及び熱源周辺の冷却要素を外部でどのようにコントロールしているかを例として系統図に表したもので、本系統図が全てではありません。The most important aspect of the present invention is a system diagram that shows how the pyrolysis reaction chamber and the cooling elements around the heat source are controlled externally. This system diagram is not all.

符号の説明Explanation of symbols

▲1▼.熱分解反応室側面を出来るだけ分かりやすく表記したもので、熱分解反応室は▲1▼の部分の内部に位置するものである。
▲2▼.除冷冷却室、技術の分野で十分に説明出来ているとは思いますが、このように標準スタイルとして、フィンチューブの上に防爆ファンを設けるよう図は書いてありますが、これはあくまで例であり、冷やし方には技術の分野で説明しているロータリー熱交換ファン付きがメンテナンス時、分解することなく、洗浄でき、熱交換効率が高いため、本発明の目玉原理として、各部分に取り入れる説明を記していますので、技術の分野を十分に熟読下さい。
(1). The side surface of the pyrolysis reaction chamber is described as clearly as possible, and the pyrolysis reaction chamber is located inside the portion (1).
(2). I think that it can be explained enough in the field of cooling and cooling chambers and technology, but as shown in the standard style, there is a figure to install an explosion-proof fan on the fin tube, but this is only an example There is a rotary heat exchange fan explained in the technical field for cooling, but it can be cleaned without disassembling during maintenance and heat exchange efficiency is high, so the main principle of the present invention is explanation to incorporate in each part Please read carefully the technical field.

Claims (13)

全自動流量調節弁を各指定されたジャケット入り口付近に設置し、出口、又は任意の位置に温度センサーを単数個、複数個設置し、本原理で指定された部分の冷却ジャケットの温度調節を温度調節器により温度をセットし、その信号を全自動流量調節弁に送り、個々のジャケットの温度を設定通りに維持しながら必要とする温度に各区間、及び部分の内部ジャケット、及び本体ジャケット、反射板、等の温度設定をすること。A fully automatic flow control valve is installed near each designated jacket inlet, and one or more temperature sensors are installed at the outlet or at an arbitrary position. The temperature is set by the controller, and the signal is sent to the fully automatic flow control valve to maintain the temperature of each jacket as it is set to each section, and the inner jacket of the section, and the body jacket, reflection Set the temperature of the board, etc. 各必要箇所の冷却に必要とするブラインチラーは省エネルギーを目的とするため、インバーター制御型、及びブライン溶液、冷却効率の良いものを使う事とし、固定回転型の物についても省エネルギーを図るため個々の力率を向上させるため、適正な進相器等を付加し、省エネルギーを考慮すると共にブライン貯蔵冷水循環タンクはタンク外面に発泡ウレタンの数回塗布、又は二重タンクとし、真空断熱構造等を有する物を使用する事もあること。In order to save energy, the brachinlers required for cooling each required part use inverter-controlled types, brine solutions, and those with good cooling efficiency. In order to improve the power factor, an appropriate phase advancer, etc. is added, energy saving is taken into consideration, and the brine storage cold water circulation tank is coated with foamed urethane several times on the outer surface of the tank, or a double tank, and has a vacuum insulation structure, etc. Sometimes things are used. 凝縮室内にロータリー熱交換機を単数、複数使用し、それを固定回転、又は可変回転、正逆回転、同方向回転、逆方向回転、ギヤーモーター、スプロケット、チェーン、インバーター、等を用いて変幻自在に回転できるようにすると共に、スラッジ等が交換部に或いは交換フィンに付着することを考慮して、ロータリー熱交換機と平行線上に高圧洗浄用ノズル付き、又は穴付きパイプを設置し、上記の通り、外部に一時的(メンテナンス時)の場合と常設した外部、高圧ポンプにより、内蔵した洗浄用ノズル管、及び穴あきパイプなどを熱交換ロータリーに対して、洗浄剤、洗浄油、等が確実に洗浄用に改めて回転を任意に設定し、ロータリー熱交換機を高速、低速、正逆、回転させながら視角無しに洗浄できる構造を有すること。Use a single or multiple rotary heat exchangers in the condensing chamber, which can be fixed or variable, forward / reverse, same direction, reverse direction, gear motor, sprocket, chain, inverter, etc. Considering that sludge and the like adhere to the exchange part or exchange fin, and to install a high pressure washing nozzle or a pipe with a hole on the parallel line with the rotary heat exchanger, as described above, The cleaning nozzle, cleaning oil, etc. are reliably cleaned against the heat exchanging rotary nozzle pipe for cleaning and perforated pipe, etc. by temporary (maintenance) outside and permanent external, high-pressure pump. It has a structure that can be rotated without any viewing angle while rotating the rotary heat exchanger at high speed, low speed, forward / reverse, and rotation at any time. 雲母石、又は雲母含有石、雲母等、何れか使用する場合と、組み合わせて使用する場合もあり、加熱し、それらから発するアルファ線に反応促進剤(触媒)のガス状、又は蒸気状の物が反応促進剤の分子構造を置換させ、反応力を増し、油化を促進し、更に発熱部上部より直接放される熱線、及び雲母石、又は雲母含有石、雲母等から放される熱線、遠赤外線、アルファ線等の相乗効果により、熱分解反応室内の処理物を効率よく、油化分離、低温で効率の良い油の抽出能力を上げる事と、後に残った良質なコークスとが分離する原理、機構である事と、常圧と共に短時間で油化分離でき、この反応においては、不活性雰囲気、又は還元雰囲気内で行い、(還元雰囲気とは、上記の通り、反応促進剤の置換、変成触媒により、分解した油分、炭化水素の還元雰囲気を言う)良質な油の抽出が半連続的に出来る原理と構造であること。Mica stones, mica-containing stones, mica, etc., may be used in combination with them, may be used in combination, heated, and the alpha rays emitted from them are gaseous or vaporous as a reaction accelerator (catalyst) Replaces the molecular structure of the reaction accelerator, increases the reaction force, promotes oil formation, and heat rays emitted directly from the upper part of the heat generating part, and heat rays emitted from mica, or mica-containing stones, mica, etc. By synergistic effects such as far-infrared rays and alpha rays, the processed material in the pyrolysis reaction chamber is efficiently separated into oil and separated, and the ability to extract oil efficiently at low temperatures is separated from the remaining high-quality coke. The principle, mechanism, and oil-separation can be performed in a short time together with normal pressure. In this reaction, the reaction is carried out in an inert atmosphere or a reducing atmosphere. (Reducing atmosphere is the replacement of a reaction accelerator as described above. , Oil decomposed by the conversion catalyst, Of say a reducing atmosphere of hydrogen) high quality that oil extraction is the principle and structure that can semi-continuously. 本原理の装置の熱源には熱の使用の仕方が同じ目的であり、電気エネルギーを基に加熱板直下にIH式発信器を取り付け、上部加熱板を多重加熱板とし、一番上部には耐蝕性の強い、又、耐熱性も共有するニッケル系、等の板を使用し、発熱させる場合もある。高周波誘導加熱の場合、加熱コイルを単数個、又は複数個巻き、そのコイルの中心部に超耐熱鋼、等を上部加熱板と接合し、誘導高周波電流を流して、効率の良い局部加熱するか、加熱板直下に絶縁物を挟み、抵抗式ヒーターを設置し、それらを発熱源として局部加熱する事で、他に熱の転移を抑える事ができ、使用上の効率は良いものの電力の消費をできる限り抑えるため、本原理内で使用する熱源の一部として発明したバーナー方式による熱源には本原理で抽出できた油の一部を使用し、それをバーナーの燃料とし、それより熱を得て、熱分解反応室に必要な熱の供給をはかると共に本バーナーで使用する燃料はA重油、又はB重油相当のものを使用するため、燃料を予め予熱機で予熱し、予熱については、温度調節器を備え持った予熱機を使用し、予熱機からバーナー本体の噴射ポンプ、又は予熱機に直接接続した予熱燃焼用循環ポンプを三方向弁でバーナーのオン、オフを行ったとき、循環状態と噴射状態が自動的に切り替わり、使用する燃料に合わせて、一定の予熱ができ、大気汚染を防止し、完全燃焼を行うよう構築し、加温、加熱部分からポンプ圧双、又は循環される部分には銅パイプ等の熱伝導の高い物を使用し、安全のため、その配管部分には断熱、耐火材などを安全に施工した構造を有し、火傷などの人災の起こらないような構造であること。予熱については、本発明の装置、運転、着火、直前に予熱をかけると十分に予熱されない油がバーナーノズルより噴出され、排ガスや不着火の原因になるため、予め適正温度に予熱して運転できる構造であること。The heat source of this principle has the same purpose of using heat. Based on electrical energy, an IH transmitter is attached directly below the heating plate, the upper heating plate is a multiple heating plate, and the top is corrosion resistant. There is also a case where heat is generated by using a nickel-based plate or the like that has strong properties and also shares heat resistance. In the case of high-frequency induction heating, is it possible to wind one or more heating coils, join super-heat-resistant steel, etc. to the upper heating plate at the center of the coil, and flow an induction high-frequency current for efficient local heating? In addition, by placing an insulator directly under the heating plate and installing a resistance heater and locally heating them using them as a heat source, heat transfer can be suppressed, and although power efficiency is good, power consumption is reduced. In order to suppress as much as possible, a part of the oil extracted by this principle is used for the heat source by the burner method invented as a part of the heat source used within this principle, and it is used as fuel for the burner to obtain heat from it. In addition, the fuel required for the pyrolysis reaction chamber is supplied and the fuel used in this burner is equivalent to A heavy oil or B heavy oil, so the fuel is preheated in advance with a preheater. Preheating with regulator When the burner is turned on and off with a three-way valve from the preheater to the burner main body injection pump or the preheating combustion circulation pump directly connected to the preheater, the circulation state and the injection state are automatically switched. It can be preheated according to the fuel to be used, and it is constructed to prevent air pollution and complete combustion. For safety reasons, use a highly conductive material, and have a structure where heat insulation, fireproof materials, etc. are safely installed in the piping part, so as not to cause human injury such as burns. As for preheating, the device of the present invention, operation, ignition, preheated immediately before, oil that is not sufficiently preheated is ejected from the burner nozzle, causing exhaust gas and non-ignition, so it can be preheated to an appropriate temperature in advance. It must be a structure. 本発明に使用する装置の処理工程は待機場所を始めとし、それぞれの仕切り水冷遮へいゲート下よりオープンしたとき不活性ガスをゲート下部ノズルより(複数個)噴射し、不活性ガスカーテンを有する場合もあるが、不活性ガスを排泄せしめる排泄口を設置することもある。待機場所から加熱反応室に挿入し、仕切り水冷ゲートを閉め、油化反応を開始終息するまで反応室に処理物用バスケット、又はボックス型キャリア(搬送トレイ)等を留め置き、任意に設定したタイマーの設定時間アップで熱分解反応室出口の水冷仕切りドアを開き、上記同様、除冷冷却室に移動させる事と、除冷冷却室からバスケット待機位置に水冷仕切りゲートを開き、上記同様、移動し、移動後ゲートを閉じる構造を有しているが、連続運転の場合、挿入水冷ゲート下部、並びに熱分解反応室内の酸素濃度を著しく落として爆発などの危険がないよう雰囲気調整を行う必要があるので、雰囲気ガスのコストを削減するため、窒素、酸素、分離窒素、選製装置を設置し、コストの安い窒素ガスを使用する場合もある。尚、圧力が必要な場合、予め窒素、選製装置を通過した窒素を専用コンプレッサーなどで加圧して、レシーバーに貯圧して、それを使用する事もあるが、この場合、窒素選製機を通過する時、窒素の温度が上がり、密度が上昇するので同じ機構、原理状に設けたブラインチラー、ラインより冷却水を用いコンプレッサーとの接続管を強制的に冷却し、窒素密度を上げ、コンプレッサーで効率よく、圧縮されるような原理を有する事とすること。The processing steps of the apparatus used in the present invention include a standby place, and when each partition water cooling shield is opened from under the gate, an inert gas is injected from the nozzle below the gate, and there may be an inert gas curtain. There is also a case where an excretion opening for excreting inert gas is provided. Insert into the heating reaction chamber from the waiting area, close the partition water cooling gate, and keep the basket for treatment or box type carrier (conveyance tray) etc. in the reaction chamber until the end of the oil conversion reaction, and set a timer of your choice Open the water cooling partition door at the pyrolysis reaction chamber outlet at the set time up and move it to the cooling cooling chamber as above, open the water cooling partition gate from the cooling cooling chamber to the basket standby position, move as above, Although it has a structure that closes the gate after moving, it is necessary to adjust the atmosphere so that there is no danger of explosion by drastically reducing the oxygen concentration in the lower part of the inserted water cooling gate and the pyrolysis reaction chamber in the case of continuous operation. In order to reduce the cost of atmospheric gas, nitrogen, oxygen, separated nitrogen, and a production apparatus are installed, and low-cost nitrogen gas may be used. If pressure is required, nitrogen or nitrogen that has passed through a pre-selection device may be pressurized with a dedicated compressor and stored in the receiver and used in some cases. When passing through, the temperature of the nitrogen rises and the density rises, so the cooling mechanism is used to forcibly cool the connecting pipe with the compressor by using the same mechanism, the principle of the Blainchler, and the line to raise the nitrogen density. And have the principle of being compressed efficiently. 本発明で熱分解反応室と除冷冷却室とのトレー(本発明の装置の中で比較的重要な位置を占めるのは構造上、熱分解反応室下部の加熱部分より、発せられた熱の通過と熱分解反応室に適時、適量、挿入された反応促進剤が急激にガス化して、ワーク即ち廃ゴム、廃タイヤ類、等に満遍なく接触し、反応を起こすよう搬送用トレイには底面に補強用メッシュとダスト落下防止用ミクロンメッシュ、このメッシュは耐熱性のあるステンレスメッシュを使用し、ダストを熱分解反応ボックス上部に落下したり、除冷冷却室にて冷却される際、落下や飛散を防止するため、ボックス上部にも蓋状のマイクロメッシュ蓋を設ける場合があるので極めて重要な意味を持つ)移動用水冷駆動装置が複数の場合、(単数の場合もあることがある)この装置には搬送スピード、同期運転等を行うためインバータードライブ、ステッピングドライブ、サーボドライブ等を使用して同期運転を可能にしたものであること。In the present invention, the trays of the pyrolysis reaction chamber and the cooling / cooling chamber (which occupies a relatively important position in the apparatus of the present invention are structurally the heat generated from the heating portion at the bottom of the pyrolysis reaction chamber. The reaction accelerator inserted in the passage and pyrolysis reaction chamber in a timely and appropriate amount is suddenly gasified, and evenly contacts the work, that is, waste rubber, waste tires, etc. Reinforcing mesh and dust drop-preventing micron mesh, this mesh uses a heat-resistant stainless steel mesh, and when dust falls to the top of the pyrolysis reaction box or cools in the cooling room, it falls or scatters. This is extremely important because there is a case where a lid-like micromesh lid is also provided on the upper part of the box). When there are a plurality of water-cooling drive devices for movement (this may be singular) In Feed speed, inverter drive for performing synchronous operation, etc., it stepper drives, is obtained by allowing the synchronous operation using the servo drive and the like. 本発明装置に使用される水冷ジャケット部分の空洞部、材料面に直角に穴を貫通し、そこに耐蝕鋼、ステンレス鋼、シャフト、等を直線、又は千鳥状に一定の間隔を持たせ、平面に対する圧力の補強を施し、本装置に装置して使用する物の本原理では冷却、温水ジャケット内部に熱交換などで生じる熱によるブライン水層部分の温度上昇、及びジャケットの形状によっては流体の性質として片側から加圧し、もう一方から排出する場合、流体の中心部の流速は早いが、本発明で使用しているジャケットは上部に熱波などを反射するため、反射板を取り付け、凝縮通路入り口部分の雰囲気温度が下がるよう、反射板の両袖部分に水冷ジャケットを位置している。両袖から頂点にかけて温度勾配を取る為、頂点から両袖にかけて反射板の温度が徐々に低下し、最終負荷接点部分の温度は、油煙を半凝縮出来るくらいに温度を設定しているもので、これらのジャケットの部分の水圧等による膨らみ等が生じないように上記のように最初から補強を施し、熱波、及び気体対流を速やかに完全液化凝縮室に降下させるよう目的を有するが為、変形、等が生じることで本発明の効果を十分に出せるよう、その構造を重要視すると共に、燃焼室周囲底部を熱遮蔽する意味で設置される、水冷ジャケットでも同じような事が生じる恐れもあり、又、破損等が生じやすい温度流域と圧力流域にあり、もし最悪、ブライン水が強制循環されなくなった場合、ウォーターハンマー、等の発生も十分考慮に入れて上記の通り、補強構造としたものであり、それらの原理と構造を使用すること。The hollow part of the water-cooled jacket used in the apparatus of the present invention, a hole that passes through the hole at right angles to the material surface, and a corrosion-resistant steel, stainless steel, shaft, etc. are provided in a straight line or a staggered pattern at a constant interval. In the present principle of the object used as an apparatus in this apparatus, the temperature of the brine water layer portion is increased by heat generated by heat exchange inside the hot water jacket, and depending on the shape of the jacket, the fluid property is on one side. When the pressure is discharged from the other and discharged from the other, the flow velocity at the center of the fluid is fast, but the jacket used in the present invention reflects a heat wave etc. on the upper part, so a reflector is attached, A water-cooled jacket is located on both sleeves of the reflector so that the ambient temperature is lowered. In order to take a temperature gradient from both sleeves to the apex, the temperature of the reflector gradually decreases from the apex to both sleeves, and the temperature of the final load contact part is set so that the oil smoke can be semi-condensed, These jackets are reinforced from the beginning to prevent swelling due to water pressure, etc., and the purpose is to quickly drop the heat wave and gas convection into the complete liquefaction condensation chamber. In order to obtain the effects of the present invention sufficiently, the water cooling jacket installed in the sense of heat shielding the bottom around the combustion chamber may cause the same effect. In addition, it is in the temperature flow area and pressure flow area where breakage is likely to occur, and in the worst case, when brine water is no longer forcedly circulated, the occurrence of water hammer, etc. is fully taken into consideration as described above. Is obtained by a strong structure, the use of those principles and structure. 本装置はメンテナンス性、制御安全性、情報通信性、制御予備回路検知システム等を有すると共に自然災害、等による二次災害を防止するため振動検知器、傾斜計、保護回路については停電時、冷却できるまで本装置が作動を緊急中止し、速やかに冷却をはかり、熱分解反応室については、ノーマルオープンタイプのガス用電磁弁を取り付け、窒素ガスの急速な冷却効果と不活性雰囲気作りを自動的に行い、作業中でも安全に問題なく、緊急時、停止することが出来るような構造とシステムを有する事とし、本装置の可動状態、可動変更、等が遠隔地で出来うる機能を有する事とすること。This device has maintainability, control safety, information communication property, control spare circuit detection system, etc., and in order to prevent secondary disasters due to natural disasters, etc., vibration detectors, inclinometers, and protection circuits are cooled during power outages. The operation of this equipment is urgently stopped until it is possible to cool it down quickly, and in the pyrolysis reaction chamber, a normally open gas solenoid valve is installed to automatically produce a rapid cooling effect of nitrogen gas and creation of an inert atmosphere. The system shall have a structure and system that can be stopped in an emergency without any safety problems even during work, and it shall have a function that enables the movable state, movable change, etc. of this device to be performed remotely. thing. 本発明は熱分解反応室(開放区域)の内部に加熱と反応促進剤、等によって抽出された油煙を凝縮層に効率良く、迅速に導くため、熱分解反応炉内の熱源、箱形燃焼室は断熱構造とし、その断熱構造とは出来るだけ気孔率が高く、熱伝導が低く施工しやすいセラミックウール、等を単数、複数枚、一定の厚みまで重ね合わせ、それらを固定するため耐熱、耐蝕性に優れた耐熱、耐蝕ステンレス合金板、又は耐熱、耐蝕性に優れたニッケル基合金板、等を使用して、断熱仕切りを兼ね備えた取り付け板を四側面と底部にセットし、更に空気層を設けると共にその外側に上部熱分解反応部分で分解された分解ガスが速やかに凝縮冷却通路を通り、液化冷却室に効率よく、流れるよう微熱遮断用水冷ジャケットを四面と底部に設け、底部ジャケットは液化凝縮部に直接、熱の転移がはかれないよう低温でコントロールするようブライン冷却水の流量調整をする全自動流量調整弁に送る信号を作るために設置した温度調節器、その温度調節器に送る温度センサーを出口、若しくはメンテナンスしやすくて精度の高い検知が出来る任意の位置にセットして、正確にブライン水流制御を行う。それと共に側面に位置した四枚のうち、凝縮通路に当たる長手方向、二面の冷却用ブラインチラー水流制御も底部と同様、低めにセットし、上部加熱板が本ジャケットに重なり、熱を無駄に伝導による消費をしないよう、上部加熱板には断熱材を入れて、ジャケットへの熱の転移を阻止した構造を有した事とする。The present invention provides a heat source in a pyrolysis reactor, a box-shaped combustion chamber, in order to efficiently and quickly guide oil smoke extracted by heating, a reaction accelerator, and the like into a condensation layer inside a pyrolysis reaction chamber (open area). Is a heat insulating structure, and the heat insulating structure has as high a porosity as possible, low thermal conductivity and easy to apply ceramic wool, etc., one or more pieces, stacked to a certain thickness and fixed to fix them, heat and corrosion resistance Use a heat-resistant and corrosion-resistant stainless steel alloy plate, or a nickel-based alloy plate with excellent heat and corrosion resistance, etc., and set the mounting plates that also have heat insulation partitions on the four sides and bottom, and provide an air layer At the same time, a water-cooling jacket for heat insulation is provided on the four sides and bottom so that the cracked gas decomposed in the upper pyrolysis reaction part quickly passes through the condensation cooling passage and flows efficiently into the liquefaction cooling chamber. A temperature controller installed to create a signal to be sent to a fully automatic flow control valve that adjusts the flow rate of brine cooling water to control at a low temperature so as not to transfer heat directly to the liquefaction condensing unit, to the temperature controller Set the temperature sensor to be sent to the outlet or any position where maintenance is easy and highly accurate detection is possible, and brine water flow control is performed accurately. At the same time, among the four sheets located on the side, the longitudinal direction of the condensing passage and the cooling water flow control for cooling the two faces are set lower as well as the bottom, and the upper heating plate overlaps the main jacket, conducting heat wastefully. It is assumed that the upper heating plate has a structure in which a heat insulating material is inserted to prevent heat transfer to the jacket. 本発明のゲートの開閉は先ず第一に挿入口、熱分解反応室終了移動時、除冷排出口というような順序で動く、これらを稼働させる1分前から緩やかな不活性雰囲気を各区画の中で行い、反応時も緩やかな不活性雰囲気を継続する場合がある。尚、廃棄ゴムの種類によっては不活性雰囲気は一切使用せず、廃棄物が持つ油化分解したガスにより、還元雰囲気を形成し、使用する場合もある。挿入時、熱分解反応室の温度が反応温度まで上昇し、反応が終了と同時に不活性ガスの濃度を上げ、完全な不活性雰囲気を作る。熱分解反応室から除冷冷却室に移動するとき排出口から排出するところまで移動するときと言うような順序で作動する場合が多い。即ち常時待機トレー位置、熱分解反応トレー位置、除冷冷却室位置、除冷冷却終了位置というような順序で一時的に各位置にトレーがあること。運転時間については制御盤に設けたタイマー等で処理する量と形状により異なるが、処理時間を任意に設定できる方式と構造、原理であること。In the opening and closing of the gate of the present invention, first of all, it moves in the order of the insertion port, the end of the pyrolysis reaction chamber, the cooling outlet, etc. In some cases, a mild inert atmosphere may be maintained during the reaction. Depending on the type of waste rubber, an inert atmosphere may not be used at all, and a reducing atmosphere may be formed and used by the oily decomposed gas of waste. At the time of insertion, the temperature of the thermal decomposition reaction chamber rises to the reaction temperature, and at the same time as the reaction is completed, the concentration of the inert gas is increased to create a completely inert atmosphere. When moving from the pyrolysis reaction chamber to the cooling and cooling chamber, the operation is often performed in the order of moving from the discharge port to the discharge position. That is, there must be a tray at each position temporarily in the order of the standby tray position, pyrolysis reaction tray position, cooling / cooling chamber position, and cooling / cooling end position. Although the operating time varies depending on the amount and shape processed by a timer or the like provided on the control panel, it must be a method, structure and principle that can arbitrarily set the processing time. 本発明の除冷冷却室上部には防爆モーターを外部に設置し、内部には熱交換促進用ファン、又は循環冷却用防爆対策を施した、シロッコファン等を使用し、循環冷却を行うこともある。熱分解反応室で大方の油は抽出できる物の残留した油分を完全に凝縮させるため、冷却ファンの下部にフィン巻きチューブ、フィンチューブ、メッキ銅管等を熱交換効率を考慮し、ファン直下にハニカム状、千鳥状に複数本設置し、又、メンテナンス性を容易にするためロータリー熱交換器、可変回転型の物を直接除冷冷却室に取り付け、そのロータリー熱交換器の構造はメッキ銅管、ステンレス管等の円筒状の物を媒体の流れるよう両端を残し、管本体を変形させた形状でシロッコファンの羽状、又はロータリー熱交換器外周に送風撹拌用の羽を取り付けることにより施工性もより容易になる。それにより冷風を直接除冷冷却室内のガスを撹拌し、直接冷却を行う場合もある。この場合、メンテナンスが容易で熱交換用ロータリーシロッコファンを可変回転出来るような構造を持つことで低速流域で予め除冷冷却室内に貫通された洗浄用ノズル管からロータリーシロッコ熱交換器に付着した付着物を洗浄する事が出来る。この場合、固定ファンのように分解洗浄する必要が無いので、メンテナンス性がよいと共に高速回転で洗浄液、又は洗浄油を吹き付けることでその遠心力により、除冷冷却室内部の内壁に付着した付着物も同時に洗浄できること。An explosion-proof motor is installed outside in the upper part of the cooling cooling chamber of the present invention, and the inside is cooled by using a fan for promoting heat exchange, or a sirocco fan with explosion-proof measures for circulation cooling. is there. Most of the oil in the pyrolysis reaction chamber condenses the remaining oil that can be extracted, so a finned tube, finned tube, plated copper tube, etc. are placed directly under the fan in consideration of heat exchange efficiency. A plurality of honeycombs and zigzags are installed, and a rotary heat exchanger and a variable rotation type are directly attached to the cooling room for easy maintenance, and the structure of the rotary heat exchanger is a plated copper tube. Workability can be achieved by attaching cylindrical blades such as stainless steel pipes to the flow of the medium, leaving both ends of the pipe and sirocco fan wings in a deformed shape of the pipe body, or wings for air stirring on the outer periphery of the rotary heat exchanger. Will also be easier. Thereby, the cooling air may be directly cooled by directly stirring the gas in the cooling chamber. In this case, it is easy to maintain and has a structure that can rotate the rotary sirocco fan for heat exchange in a variable manner. Kimono can be washed. In this case, there is no need to disassemble and wash like a fixed fan, so maintenance is good and the deposits adhered to the inner wall of the cooling / cooling chamber due to its centrifugal force by spraying cleaning liquid or cleaning oil at high speed rotation Can be cleaned at the same time. 本発明で待機場所から排出完了待機場所に搬送する機構は外部に設けた駆動用ギヤードモーターにインバーター、ステッピングドライバーの場合、ステッピングモーター、サーボモーターの場合、サーボドライバー、インダクションモーターの場合、インバーター等によって待機位置から熱分解反応室内部終了端までの間を一区画とし、その区間に外部でダブルスプロケット、又はタイミングギヤーその他等を使用し、区間駆動を行う。その行動は待機位置より反応室終端部までホイルの側面に耳を付け、蛇行防止するよう形を整え、そのホイルを適度な間隔で搬送方向に配置し、熱分解反応室では放射熱や対流熱、分解促進用助剤通過視角をなくすためにホイルの駆動シャフトを外部と内部で両持ちし、ホイルを駆動する駆動シャフト内に空洞部のあるシャフトを用い、外部に伏流用ロータリージョイントを設置し、熱分解反応室の熱からシャフトを守る行為と同様、熱分解反応室内に既に分解した油煙等を一時的に補助冷却するような構造を有し、更に内部反応室両側面にはトレイ、走行方向に対して平行に二本の水冷ジャケット軸受けを設置し、この軸受けに対しても一時冷却を兼ね、内部対流を促進するため、冷却水を流すと共に搬送用複数個のホイルがトレイと処理物の重量に耐え、加熱されても耐えるよう下部熱源箱形燃焼室の視角まで控え、ホイルを複数個搬送方向に向けて水平に設置し、その一個一個のホイルが搬送用トレイの接触部分に油化、凝縮した油等が付着することでスリップする可能性があるので、トレイのホイルとの接触面の仕上げは摩擦係数を上げるよう、成型を行う。又、尚かつホイル接触面も摩擦係数を上げるようローレット仕上げ等で摩擦係数を上げ、油が付着してもスリップを抑える状況を構築し、熱分解反応室から除冷冷却室に搬送用トレイが移動する際、除冷冷却室側の独立したトレイ搬送用ホイルの回転数は熱分解反応室と反応室用ホイルの周速は受け取り側の除冷冷却室用搬送ホイルと同期運転し、速やかに除冷冷却室に搬送し、受け渡し終了後、熱分解反応室と除冷冷却室の仕切水冷ゲートは閉まるような仕組みを構成した物とし、完全な双方の縁切りを行うような構造を有した物であること。又、除冷冷却室より排出される際、除冷冷却室用に配置されたトレイ搬送用ホイルは、熱分解反応室関係なく冷却が完了できれば排出単独で出来るような構造をいうものである。除冷冷却室のホイルはそのホイルに外部より駆動される駆動軸を左右に伝達するため、一端に水冷貫通シャフトを設け、このシャフトは内部が中空で貫通しており、反対側のホイルに回転を伝達する役目を有し、本シャフトの本体外部両端にダブルスプロケットをセットし、その外側にロータリージョイントをセットし冷却水を本装置にそぐう適正な温度のブライン水を通過させ、必要以上の膨張とダレ、たるみ、材質の劣化等を抑える構造を有している。更にこれは熱分解反応室入り口の低温部分の左右伝達シャフトにも同様機構を備え持つこととし、本装置の搬送伝達機構を形成する物である。外部伝達機構にはダブルスプロケットに交互にチェーンを掛け、熱分解反応室側と除冷冷却室側との駆動系統は別々に別れる仕組みを構成している物で、この仕組みによりそれぞれの条件に合った運転状態を取ることが出来る構造を有する物とする。尚かつ熱分解反応室と除冷冷却室との搬送ホイルの高さなどにバラツキが製作状態で出来る可能性があるので、外部軸受けアジャストによりホイルを一定のレベルに調整できる構造を有していることも同様である。いずれも水冷ジャケットを貫通し、外部に動力伝達部を構築するため、ジャケット貫通部には片面スリーブ機構とし、それを耐熱、耐蝕、耐薬グランドパッキン等で貫通したシャフトをジャケットスリーブの隙間の漏れを阻止するため、調整締め込みにより、耐熱、耐蝕、耐薬グランドパッキン、リーク防止機構を兼ね備えた物であること。In the present invention, the mechanism for transporting from the standby location to the discharge completion standby location is an external drive geared motor with an inverter, a stepping driver, a stepping motor, a servo motor, a servo driver, an induction motor, an inverter, etc. The section from the standby position to the end of the pyrolysis reaction chamber is defined as one section, and the section is driven by using a double sprocket, timing gear, or the like outside the section. The action is to listen to the side of the foil from the standby position to the end of the reaction chamber, arrange the shape to prevent meandering, arrange the foil in the transport direction at appropriate intervals, and in the pyrolysis reaction chamber, radiant heat and convection heat In order to eliminate the viewing angle through the auxiliary agent for promoting decomposition, both the outside and inside of the drive shaft of the foil are supported, a shaft with a hollow portion is used inside the drive shaft that drives the foil, and a rotary joint for downflow is installed outside. Like the act of protecting the shaft from the heat of the pyrolysis reaction chamber, it has a structure that temporarily cools the already decomposed oil smoke etc. in the pyrolysis reaction chamber, and further, trays and running on both sides of the internal reaction chamber Two water-cooled jacket bearings are installed in parallel to the direction, and this bearing also serves as temporary cooling and promotes internal convection. In order to withstand the weight of the heat source, keep it at the viewing angle of the lower heat source box combustion chamber so that it can withstand even when heated, and place a number of foils horizontally in the transport direction. Since there is a possibility of slipping due to adhesion of condensed or condensed oil or the like, the finish of the contact surface of the tray with the foil is molded so as to increase the coefficient of friction. In addition, the friction coefficient of the foil contact surface is also increased by knurling so as to increase the friction coefficient, and a situation where slippage is suppressed even if oil adheres is constructed, and the transfer tray is moved from the thermal decomposition reaction chamber to the cooling cooling chamber. When moving, the rotation speed of the independent tray transfer foil on the side of the cooling chamber is the same as the peripheral speed of the pyrolysis reaction chamber and the reaction chamber foil is synchronized with the transfer foil of the receiving side cooling chamber. Conveyed to the cooling chamber, and after the delivery is finished, the partition water cooling gate of the pyrolysis reaction chamber and the cooling cooling chamber is configured to be closed, and has a structure that completely cuts both edges. Be. In addition, when discharged from the cooling cooling chamber, the tray transfer foil disposed for the cooling cooling chamber has a structure that can be discharged alone if cooling can be completed regardless of the thermal decomposition reaction chamber. The foil in the cooling / cooling chamber is provided with a water-cooling penetrating shaft at one end to transmit the drive shaft driven from the outside to the left and right, and this shaft is hollow inside and rotates to the opposite foil. A double sprocket is set at both ends of the main body of the shaft, and a rotary joint is set on the outside of the shaft to allow cooling water to flow through the device. It has a structure that suppresses expansion, sagging, sagging, material deterioration, and the like. Furthermore, this also has a similar mechanism on the left and right transmission shafts in the low temperature portion at the entrance of the pyrolysis reaction chamber, and forms the transfer transmission mechanism of this apparatus. In the external transmission mechanism, double sprockets are alternately chained, and the drive systems for the pyrolysis reaction chamber side and the cooling / cooling chamber side are configured to be separated separately. It shall be the thing which has the structure which can take the operating state. In addition, there is a possibility that variations in the height of the transfer foil between the pyrolysis reaction chamber and the cooling / cooling chamber can be made in the production state, so the foil can be adjusted to a certain level by adjusting the external bearing. The same is true. In both cases, a water-cooled jacket is penetrated and a power transmission part is constructed outside, so the jacket penetration part has a single-sided sleeve mechanism, and a shaft penetrated by heat-resistant, corrosion-resistant, chemical-resistant gland packing, etc. to leak through the gap in the jacket sleeve. In order to prevent it, it must be equipped with heat resistance, corrosion resistance, chemical resistant gland packing, and leak prevention mechanism by adjusting tightening.
JP2006187210A 2006-06-10 2006-06-10 Coke creating apparatus including fully automated, waste tire, and whole waste rubber liquefaction through extraction of oil component Pending JP2007332335A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101828312B1 (en) 2017-02-13 2018-02-13 곽재경 Waste plastics oil system using a microwave
CN109382054A (en) * 2018-12-07 2019-02-26 洛阳天疆精细化工有限公司 The after-treatment device of Boron chelate complexes in a kind of production of Norfloxacin
US10605203B2 (en) 2014-09-25 2020-03-31 Patched Conics, LLC. Device, system, and method for pressurizing and supplying fluid
CN112843758A (en) * 2021-01-11 2021-05-28 中海油天津化工研究设计院有限公司 Heat separation device for recycling marine oil field oil-based drilling waste

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10605203B2 (en) 2014-09-25 2020-03-31 Patched Conics, LLC. Device, system, and method for pressurizing and supplying fluid
KR101828312B1 (en) 2017-02-13 2018-02-13 곽재경 Waste plastics oil system using a microwave
CN109382054A (en) * 2018-12-07 2019-02-26 洛阳天疆精细化工有限公司 The after-treatment device of Boron chelate complexes in a kind of production of Norfloxacin
CN112843758A (en) * 2021-01-11 2021-05-28 中海油天津化工研究设计院有限公司 Heat separation device for recycling marine oil field oil-based drilling waste

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