JP2007312551A - Electrostatic induction type converting device - Google Patents

Electrostatic induction type converting device Download PDF

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JP2007312551A
JP2007312551A JP2006140889A JP2006140889A JP2007312551A JP 2007312551 A JP2007312551 A JP 2007312551A JP 2006140889 A JP2006140889 A JP 2006140889A JP 2006140889 A JP2006140889 A JP 2006140889A JP 2007312551 A JP2007312551 A JP 2007312551A
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electrostatic induction
electret
conversion element
fluorine
electrets
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JP4871642B2 (en
Inventor
Yuji Suzuki
雄二 鈴木
Nobuhide Kasagi
伸英 笠木
Takumi Tsutsumino
匠 堤野
Yukiisa Tsurumi
行功 鶴見
Yoshihiko Sakane
好彦 坂根
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University of Tokyo NUC
AGC Inc
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Asahi Glass Co Ltd
University of Tokyo NUC
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an electrostatic induction type converting device which properly maintain a mutual distance when substrates move relatively to each other. <P>SOLUTION: Two substrates 10, 12 are arranged oppositely each other, and electrets 14 and conductors 16 are formed on opposite faces of each substrate 10, 12. Moreover, the substrates 10, 12 move relatively in a direction parallel to the opposite faces (directions of arrow marks A, B in a Figure), and the electrets 14 move relatively to the conductors 16 involved in relative movement of the substrates 10, 12 to generate electromotive force to the conductors 16 by electrostatic induction. The electrets 14 and the conductors 16 are arranged so that attraction force generated by opposite arrangement of the electrets 14 and the conductors 16 may balance with repulsive force generated by opposite arrangement of the electrets 14, in order to properly maintain the distance between the substrates 10, 12. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、電気エネルギと運動エネルギとを変換する静電誘導型変換素子の改良に関する。   The present invention relates to an improvement of an electrostatic induction conversion element that converts electrical energy and kinetic energy.

従来より、絶縁材料に電荷を注入したエレクトレットを使用した発電装置、マイクロフォン等が提案されている。このような、エレクトレットを使用した装置においては、電気エネルギと運動エネルギとの変換効率が高いことが知られている。例えば、下記特許文献1にも、エレクトレットを使用した静電アクチュエータの例が開示されている。図6(A)、(B)には、この静電アクチュエータの構成例が示される。
特開2005−229707号公報
Conventionally, a power generation device, a microphone, and the like using an electret in which an electric charge is injected into an insulating material have been proposed. In such an apparatus using an electret, it is known that the conversion efficiency between electric energy and kinetic energy is high. For example, Patent Document 1 below also discloses an example of an electrostatic actuator using an electret. 6A and 6B show a configuration example of this electrostatic actuator.
JP 2005-229707 A

しかし、上記従来の技術である図6(A)に示される形状では、片側のエレクトレットが駆動電極に対して一様に形成されているので、発電器やセンサに適用することができない。ただし、図6(B)に示される形状において、駆動電極を電荷が誘導される発電電極と考えれば発電器となりえる。しかし、この図から半ピッチずれた位置で可動子のエレクトレットと駆動電極が引き合うため、可動子と固定基板が密着するという問題がある。   However, in the shape shown in FIG. 6A, which is the conventional technique, the electret on one side is uniformly formed with respect to the drive electrode, and thus cannot be applied to a power generator or a sensor. However, in the shape shown in FIG. 6B, if the drive electrode is considered as a power generation electrode for inducing charge, it can be a power generator. However, since the electret of the mover and the drive electrode attract each other at a position shifted by a half pitch from this figure, there is a problem that the mover and the fixed substrate are in close contact.

本発明は、上記従来の課題に鑑みなされたものであり、その目的は、基板が互いに相対運動する際に、互いの距離を適正に維持することができる静電誘導型変換素子を提供することにある。   The present invention has been made in view of the above-described conventional problems, and an object of the present invention is to provide an electrostatic induction conversion element capable of maintaining a mutual distance appropriately when substrates move relative to each other. It is in.

上記目的を達成するために、本発明は、電気エネルギと運動エネルギとを変換する静電誘導型変換素子であって、互いに対向し、対向面に平行な方向に相対運動する基板と、前記基板の各対向面に混在して形成されたエレクトレット及び導体と、を備え、前記エレクトレットと導体とは、前記エレクトレットと導体とが対向して発生する吸引力と、前記エレクトレット同士が対向して発生する反発力とが略釣り合うように配置されていることを特徴とする。   In order to achieve the above object, the present invention provides an electrostatic induction conversion element that converts electrical energy and kinetic energy, the substrates facing each other and relatively moving in a direction parallel to the facing surface, and the substrate Electrets and conductors formed in a mixed manner on each of the opposing surfaces, wherein the electrets and the conductors are generated by the attracting force generated by the electrets and the conductors facing each other and the electrets facing each other. It arrange | positions so that a repulsive force may be substantially balanced.

また、上記静電誘導型変換素子において、前記基板の少なくとも一方で、前記エレクトレットと導体の各総面積が異なった値であることを特徴とする。   In the electrostatic induction conversion element, the total area of the electret and the conductor is a different value on at least one of the substrates.

また、上記静電誘導型変換素子において、前記エレクトレットと導体とは、細片状に形成されていることを特徴とする。   In the electrostatic induction conversion element, the electret and the conductor are formed in a strip shape.

また、上記静電誘導型変換素子において、前記エレクトレットと導体とは、碁盤格子状に配置されていることを特徴とする。   In the electrostatic induction conversion element, the electret and the conductor are arranged in a grid pattern.

また、上記静電誘導型変換素子において、前記エレクトレットは、PTFE(ポロテトラフルオロエチレン)、FEP(テトラフルオロエチレン/ヘキサフルオロプロピレン共重合体)、PFA(テトラフルオロエチレン/パーフルオロ(アルキルビニルエーテル))共重合体、酸化珪素、含フッ素脂肪族環構造を有する重合体または溶剤可溶性の含フッ素樹脂により構成されていることを特徴とする。   In the electrostatic induction conversion element, the electret may be PTFE (polytetrafluoroethylene), FEP (tetrafluoroethylene / hexafluoropropylene copolymer), PFA (tetrafluoroethylene / perfluoro (alkyl vinyl ether)). It is composed of a copolymer, silicon oxide, a polymer having a fluorine-containing aliphatic ring structure, or a solvent-soluble fluorine-containing resin.

また、上記静電誘導型変換素子において、前記含フッ素脂肪族環構造を有する重合体は、2つ以上の重合性二重結合を有する含フッ素モノマーを環化重合して得られる、主鎖に含フッ素脂肪族環構造を有する重合体により構成されていることを特徴とする。   In the electrostatic induction conversion element, the polymer having the fluorine-containing aliphatic ring structure is obtained by subjecting the main chain to cyclopolymerization of a fluorine-containing monomer having two or more polymerizable double bonds. It is characterized by comprising a polymer having a fluorine-containing aliphatic ring structure.

また、上記静電誘導型変換素子において、前記含フッ素脂肪族環構造には、エーテル性酸素原子が1個以下含まれることを特徴とする。   In the electrostatic induction conversion device, the fluorine-containing aliphatic ring structure contains one or less etheric oxygen atoms.

上記各構成によれば、基板が互いに相対運動する際に、摩擦が無く、且つ互いの距離を適正に維持することができる静電誘導型変換素子を実現できる。   According to each of the above configurations, it is possible to realize an electrostatic induction conversion element that is free from friction and can maintain the distance between each other properly when the substrates move relative to each other.

以下、本発明を実施するための最良の形態(以下、実施形態という)を、図面に従って説明する。   Hereinafter, the best mode for carrying out the present invention (hereinafter referred to as an embodiment) will be described with reference to the drawings.

図1(a)、(b)には、本発明にかかる静電誘導型変換素子の構成例の断面図が示される。図1(a)、(b)において、静電誘導型変換素子は、2つの基板10、12が互いに対向して配置されており、各基板10、12の対向面上には、エレクトレット14と導体16とが混在して形成されている。また、上記基板10、12は、対向面に平行な方向(図の矢印A、B方向)に相対運動するように構成されている。なお、基板10、12を相対運動させる機構は従来公知の方法により適宜構成できるので、図示及び説明は省略する。   1A and 1B are cross-sectional views showing a configuration example of an electrostatic induction conversion element according to the present invention. 1A and 1B, the electrostatic induction conversion element has two substrates 10 and 12 arranged to face each other, and electrets 14 and The conductor 16 is mixed and formed. Moreover, the said board | substrates 10 and 12 are comprised so that a relative motion may be carried out in the direction (arrow A, B direction of a figure) parallel to an opposing surface. Note that the mechanism for relatively moving the substrates 10 and 12 can be appropriately configured by a conventionally known method, and thus illustration and description thereof are omitted.

上記エレクトレット14は、絶縁材料の表面付近に電荷を注入して形成されている。この電荷の注入には、液体接触、コロナ放電、電子ビーム、バック・ライテッド・サイラトロン等公知の方法を用いることができる。また、エレクトレット14は、基板10、12の相対運動に伴い導体16に対して相対的に運動し、導体16に静電誘導による起電力を発生させる。   The electret 14 is formed by injecting charges near the surface of an insulating material. For this charge injection, a known method such as liquid contact, corona discharge, electron beam, back-lit thyratron, or the like can be used. In addition, the electret 14 moves relative to the conductor 16 with the relative movement of the substrates 10 and 12, and causes the conductor 16 to generate an electromotive force due to electrostatic induction.

基板10、12に形成された導体16は、上記エレクトレット14との相対運動により静電誘導される起電力の位相が同じもの同士で接続され、それぞれ端子18、20から誘導起電力を取り出せるように構成されている。これにより、運動エネルギを電気エネルギに変換して取り出すことができる。このような構成により、本発明の静電誘導型変換素子を発電機またはセンサとして機能させることができる。センサとしての応用例としては、マイクロフォン、圧力センサ、加速度センサ、地震計等がある。また、導体16に電源を接続すると、電気エネルギにより基板10、12を図1(a)、(b)の矢印A及びBの方向に運動させることができる。この場合には、本発明の静電誘導型変換素子がアクチュエータとして機能する。   The conductors 16 formed on the substrates 10 and 12 are connected to each other with the same phase of the electromotive force electrostatically induced by the relative motion with the electret 14 so that the induced electromotive force can be taken out from the terminals 18 and 20, respectively. It is configured. Thereby, kinetic energy can be converted into electric energy and taken out. With such a configuration, the electrostatic induction conversion element of the present invention can function as a generator or a sensor. Examples of application as a sensor include a microphone, a pressure sensor, an acceleration sensor, and a seismometer. When a power source is connected to the conductor 16, the substrates 10 and 12 can be moved in the directions of arrows A and B in FIGS. 1A and 1B by electric energy. In this case, the electrostatic induction conversion element of the present invention functions as an actuator.

本実施形態において特徴的な点は、上記エレクトレット14と導体16とが、エレクトレット14と導体16とが対向して発生する吸引力と、エレクトレット14同士が対向して発生する反発力とが略釣り合うように配置されている点にある。   A characteristic point in the present embodiment is that the electret 14 and the conductor 16 are substantially balanced by the attractive force generated when the electret 14 and the conductor 16 face each other and the repulsive force generated when the electrets 14 face each other. It is in the point where it is arranged.

すなわち、エレクトレット14の表面には同じ極性の電荷が注入されているので、エレクトレット14同士が対向した場合には反発力が生じ、エレクトレット14と導体16とが対向した場合には吸引力が生じる。そこで、エレクトレット14と導体16とが対向する総面積とエレクトレット14同士が対向する総面積とを調整することにより、上記吸引力と反発力とを釣り合わせることができる。なお、導体16同士では、反発力及び吸引力は生じないので、上記釣り合いには関与しない。   That is, since charges of the same polarity are injected into the surface of the electret 14, a repulsive force is generated when the electrets 14 face each other, and an attractive force is generated when the electret 14 and the conductor 16 face each other. Therefore, the suction force and the repulsive force can be balanced by adjusting the total area where the electret 14 and the conductor 16 face each other and the total area where the electrets 14 face each other. In addition, since repulsive force and attraction | suction force do not arise in the conductors 16, it does not participate in the said balance.

図1(a)に示された例において、基板10、12で全面積のうちエレクトレット14が占める面積割合をそれぞれx(基板10)、z(基板12)とし、導体16が占める面積割合をそれぞれy(基板10)、w(基板12)とすると、エレクトレット14と導体16との間の吸引力と、エレクトレット14同士の間の反発力が等しくなるときに上記釣り合いの状態になるが、このとき基板10、12の相対する面において、
xz=xw+yz ただし、x+y=1、z+w=1
が成り立つ。この式からyとwを消去すると、
x=z/(3z−1)
となる。
In the example shown in FIG. 1A, the area ratios occupied by the electrets 14 in the total area of the substrates 10 and 12 are x (substrate 10) and z (substrate 12), respectively, and the area ratios occupied by the conductors 16 are respectively Assuming y (substrate 10) and w (substrate 12), when the attractive force between the electret 14 and the conductor 16 and the repulsive force between the electrets 14 are equal, the above-mentioned balance is achieved. On the opposing surfaces of the substrates 10, 12,
xz = xw + yz where x + y = 1, z + w = 1
Holds. If y and w are deleted from this equation,
x = z / (3z-1)
It becomes.

ここで、0<x<1、0<z<1の両方を満たさなければならないことを考慮すると、0.5<x<1、0.5<z<1となる。例えばx=zとすると、x=z=2/3となる。従って、基板10、12の少なくとも一方でエレクトレット14と導体16の面積が等分でない、すなわち異なった値となることが分かる。   Here, considering that both 0 <x <1 and 0 <z <1 must be satisfied, 0.5 <x <1 and 0.5 <z <1. For example, when x = z, x = z = 2/3. Therefore, it can be seen that the area of the electret 14 and the conductor 16 is not evenly divided, that is, has different values on at least one of the substrates 10 and 12.

図1(a)では、基板10側でエレクトレット14が8個、導体16が4個となっており、エレクトレット14と導体16の面積が異なった値となっている。   In FIG. 1A, there are eight electrets 14 and four conductors 16 on the substrate 10 side, and the areas of the electrets 14 and the conductors 16 are different values.

次に、図1(a)の状態から基板10を矢印Aの方向に移動させ、図1(b)の状態にした場合には、基板10、12が重なり合った部分において、基板10側でエレクトレット14が7個、導体16が4個となっており、基板12側でエレクトレット14が5個、導体16が6個となっている。従って、2つの基板10、12においてエレクトレット14と導体16の面積が異なった値となっている。   Next, when the substrate 10 is moved in the direction of the arrow A from the state of FIG. 1A to the state of FIG. 1B, the electret is formed on the substrate 10 side in the portion where the substrates 10 and 12 overlap. There are seven 14 and four conductors 16, and five electrets 14 and six conductors 16 on the substrate 12 side. Accordingly, the areas of the electret 14 and the conductor 16 in the two substrates 10 and 12 have different values.

以上のような構成によれば、基板10と基板12との間の反発力と吸引力とを略釣り合わせることができ、基板10、12間の距離を適正に維持することができる。なお、基板10と基板12との間は、空気等のガス、液体または真空状態とすることができ、基板10、12間の摩擦を無くして相対運動を容易に行わせることができる。   According to the above configuration, the repulsive force and the suction force between the substrate 10 and the substrate 12 can be substantially balanced, and the distance between the substrates 10 and 12 can be properly maintained. In addition, between the board | substrate 10 and the board | substrate 12, it can be set as gas, liquid, or a vacuum state, such as air, A friction between the board | substrates 10 and 12 can be eliminated, and a relative motion can be performed easily.

図2(a)、(b)には、エレクトレット14と導体16との配置例が示される。図2(a)は、基板10上における配置例であり、図2(b)は、基板12上における配置例であって、それぞれエレクトレット14と導体16とが形成された面の側の平面図である。   2A and 2B show an arrangement example of the electret 14 and the conductor 16. 2A is an arrangement example on the substrate 10, and FIG. 2B is an arrangement example on the substrate 12, and is a plan view on the side where the electret 14 and the conductor 16 are formed. It is.

図2(a)、(b)において、エレクトレット14と導体16とは細片状(長方形の薄板状)に形成されており、導体16には斜線を付してエレクトレット14と区別している。図2(a)に示された基板10では、エレクトレット14が8個、導体16が4個形成されている。また、図2(b)に示された基板12では、エレクトレット14と導体16とが交互に6個ずつ形成されている。本実施形態にかかる静電誘導型変換素子は、図2(a)に示された基板10を、図の上下方向に裏返して図2(b)に示された基板12に対向させる。これにより、図1(a)に示された静電誘導型変換素子が構成される。   2A and 2B, the electret 14 and the conductor 16 are formed in a strip shape (a rectangular thin plate), and the conductor 16 is distinguished from the electret 14 by hatching. In the substrate 10 shown in FIG. 2A, eight electrets 14 and four conductors 16 are formed. Further, in the substrate 12 shown in FIG. 2B, six electrets 14 and six conductors 16 are alternately formed. In the electrostatic induction conversion element according to the present embodiment, the substrate 10 shown in FIG. 2A is turned upside down so as to face the substrate 12 shown in FIG. 2B. Thereby, the electrostatic induction type conversion element shown in FIG.

図3(a)、(b)には、エレクトレット14と導体16との他の配置例が示される。図3(a)は、基板10上における配置例であり、図3(b)は、基板12上における配置例であって、それぞれエレクトレット14と導体16とが形成された面の側の平面図である。   FIGS. 3A and 3B show other arrangement examples of the electret 14 and the conductor 16. 3A is an arrangement example on the substrate 10, and FIG. 3B is an arrangement example on the substrate 12, and is a plan view on the side where the electret 14 and the conductor 16 are formed. It is.

図3(a)、(b)において、エレクトレット14と導体16とは正方形状に形成され、ており、碁盤格子状に配置されている。また、本実施形態においても、導体16に斜線を付してエレクトレット14と区別している。図3(a)に示された基板10では、エレクトレット14が24個、導体16が12個形成されている。また、図3(b)に示された基板12では、エレクトレット14と導体16とが市松模様状に18個ずつ形成されている。   3A and 3B, the electrets 14 and the conductors 16 are formed in a square shape and are arranged in a grid pattern. Also in this embodiment, the conductor 16 is hatched to distinguish it from the electret 14. In the substrate 10 shown in FIG. 3A, 24 electrets 14 and 12 conductors 16 are formed. Moreover, in the board | substrate 12 shown by FIG.3 (b), the electret 14 and the conductor 16 are formed in 18 pieces each in the checkered pattern shape.

本実施形態にかかる静電誘導型変換素子は、図3(a)に示された基板10を、図の上下方向または左右方向に裏返して図3(b)に示された基板12に対向させる。これにより、エレクトレット14と導体16とが対向する組合せが18組、エレクトレット14同士が対向する組合せが12組となる。なお、導体16同士が対向し、吸引力も反発力も生じない組合せは6組となる。   In the electrostatic induction conversion element according to the present embodiment, the substrate 10 shown in FIG. 3A is turned over in the vertical direction or the horizontal direction in the drawing so as to face the substrate 12 shown in FIG. . As a result, there are 18 combinations in which the electrets 14 and the conductors 16 face each other, and 12 combinations in which the electrets 14 face each other. Note that there are six combinations in which the conductors 16 face each other and no attractive force or repulsive force occurs.

以上の図2(a)、(b)及び図3(a)、(b)に示された配置例によれば、エレクトレット14と導体16との吸引力と、エレクトレット14同士の反発力とを略釣り合わせることができる。   According to the arrangement examples shown in FIGS. 2A and 2B and FIGS. 3A and 3B, the attractive force between the electret 14 and the conductor 16 and the repulsive force between the electrets 14 are obtained. Can be roughly balanced.

図4には、エレクトレット14と導体16とのさらに他の配置例が示される。図4において、基板10、12を複数の領域(I、II、III…)に分けた場合に、エレクトレット14と導体16との組み合わせとエレクトレット14同士の組み合わせと導体16同士の組み合わせとがそれぞれ異なる比率となる領域を分布させて、吸引力と反発力とを釣り合わせている。図4の例では、領域Iでエレクトレット14同士の反発の状態を形成し、領域IIでエレクトレット14と導体16との吸引の状態を形成し、以後反発力を生じる領域と吸引力を生じる領域を交互に形成している。   FIG. 4 shows still another arrangement example of the electret 14 and the conductor 16. In FIG. 4, when the substrates 10 and 12 are divided into a plurality of regions (I, II, III...), The combination of the electret 14 and the conductor 16, the combination of the electrets 14 and the combination of the conductors 16 are different. The ratio region is distributed to balance the attractive force and the repulsive force. In the example of FIG. 4, the repulsion state between the electrets 14 is formed in the region I, the suction state between the electret 14 and the conductor 16 is formed in the region II, and the region where the repulsion force is generated and the region where the suction force is generated thereafter. They are formed alternately.

図5には、本発明にかかる静電誘導型変換素子の応用例が示される。図5において、基板10は、ばね24を介して筐体22に接続され、基板12に対して相対的に振動できるように構成されている。   FIG. 5 shows an application example of the electrostatic induction conversion element according to the present invention. In FIG. 5, the substrate 10 is connected to the housing 22 via a spring 24 and is configured to vibrate relative to the substrate 12.

以上のような構成によれば、筐体22が振動した場合に、基板10が基板12に対して相対的に運動することになる。このときに発生する誘導起電力を図1(a)、(b)に示された端子18、20から取り出すように構成すれば、図5の装置を発電器あるいは振動計として使用することができる。   According to the above configuration, the substrate 10 moves relative to the substrate 12 when the housing 22 vibrates. If the induced electromotive force generated at this time is taken out from the terminals 18 and 20 shown in FIGS. 1A and 1B, the apparatus shown in FIG. 5 can be used as a generator or a vibrometer. .

以上に述べたエレクトレット14を形成する絶縁材料としては、例えばPTFE(ポロテトラフルオロエチレン)、FEP(テトラフルオロエチレン/ヘキサフルオロプロピレン共重合体)、PFA(テトラフルオロエチレン/パーフルオロ(アルキルビニルエーテル))共重合体、酸化珪素、含フッ素脂肪族環構造を有する重合体または溶剤可溶性の含フッ素樹脂を使用することができる。   Examples of the insulating material forming the electret 14 described above include PTFE (polytetrafluoroethylene), FEP (tetrafluoroethylene / hexafluoropropylene copolymer), and PFA (tetrafluoroethylene / perfluoro (alkyl vinyl ether)). A copolymer, silicon oxide, a polymer having a fluorine-containing aliphatic ring structure, or a solvent-soluble fluorine-containing resin can be used.

ここで、上記含フッ素脂肪族環構造を有する重合体としては、2つ以上の重合性二重結合を有する含フッ素モノマーを環化重合して得られる、主鎖に含フッ素脂肪族環構造を有する重合体、が好適である。   Here, the polymer having the above-mentioned fluorinated aliphatic ring structure has a fluorinated aliphatic ring structure in the main chain obtained by cyclopolymerizing a fluorinated monomer having two or more polymerizable double bonds. The polymer having is preferred.

主鎖に含フッ素脂肪族環構造を有するとは、脂肪族環を構成する炭素原子の1以上が主鎖を構成する炭素連鎖中の炭素原子であり、かつ脂肪族環を構成する炭素原子の少なくとも一部にフッ素原子またはフッ素含有基が結合している構造を有することを意味する。なお、含フッ素脂肪族環構造には、エーテル性酸素原子が1個含まれていてもよい。   Having a fluorine-containing aliphatic ring structure in the main chain means that at least one carbon atom constituting the aliphatic ring is a carbon atom in the carbon chain constituting the main chain, and the carbon atom constituting the aliphatic ring is It means having a structure in which a fluorine atom or a fluorine-containing group is bonded to at least a part. The fluorine-containing aliphatic ring structure may contain one etheric oxygen atom.

2つ以上の重合性二重結合を有する含フッ素モノマーを環化重合して得られる、主鎖に含フッ素脂肪族環構造を有する重合体は、特開昭63−238111号公報や特開昭63−238115号公報、USP 6,936,668 B2等により知られている。すなわち、パーフルオロ(アリルビニルエーテル)やパーフルオロ(ブテニルビニルエーテル)等の2つ以上の重合性二重結合を有する含フッ素モノマーの環化重合体、または2つ以上の重合性二重結合を有する含フッ素モノマーとテトラフルオロエチレン等のラジカル重合性モノマーとの共重合体が挙げられる。または、パーフルオロ(2,2−ジメチル−1,3−ジオキソール)等の含フッ素脂肪族環構造を有するモノマーとパーフルオロ(アリルビニルエーテル)やパーフルオロ(ブテニルビニルエーテル)等の2つ以上の重合性二重結合を有する含フッ素モノマーを共重合して得られる重合体でもよい。   Polymers having a fluorinated aliphatic ring structure in the main chain obtained by cyclopolymerization of a fluorine-containing monomer having two or more polymerizable double bonds are disclosed in JP-A-63-238111 and JP-A-2003-238111. No. 63-238115, USP 6,936,668 B2, and the like. That is, a cyclized polymer of a fluorine-containing monomer having two or more polymerizable double bonds such as perfluoro (allyl vinyl ether) or perfluoro (butenyl vinyl ether), or having two or more polymerizable double bonds Examples thereof include a copolymer of a fluorine-containing monomer and a radical polymerizable monomer such as tetrafluoroethylene. Alternatively, a monomer having a fluorine-containing aliphatic ring structure such as perfluoro (2,2-dimethyl-1,3-dioxole) and two or more polymerizations such as perfluoro (allyl vinyl ether) or perfluoro (butenyl vinyl ether) It may be a polymer obtained by copolymerizing a fluorine-containing monomer having an ionic double bond.

また、上記溶剤可溶性の含フッ素樹脂としては、例えばフッ素化ペリレン、フッ素化ポリイミド、フッ素化ベンゾオキサザールを使用することができる。   Examples of the solvent-soluble fluorine-containing resin include fluorinated perylene, fluorinated polyimide, and fluorinated benzoxazal.

なお、上述したような含フッ素脂肪族環構造を有する重合体を使用して、スピンコート等の方法によりエレクトレット14を形成すると、エレクトレット14の厚さを10μm以上とすることができる。エレクトレット14を使用した静電誘導型変換素子の最大発電出力は、以下の式で表される。   In addition, when the electret 14 is formed by a method such as spin coating using the polymer having the fluorine-containing aliphatic ring structure as described above, the thickness of the electret 14 can be set to 10 μm or more. The maximum power generation output of the electrostatic induction conversion element using the electret 14 is expressed by the following equation.

Figure 2007312551
Figure 2007312551

ここで、σはエレクトレット14の表面電荷密度、nは極数すなわちエレクトレット14の数、Aは導体16の面積、fは導体16の往復運動の周波数、dはエレクトレット14の厚さ、gはエレクトレット14と導体16との距離、εは比誘電率である。   Here, σ is the surface charge density of the electret 14, n is the number of poles, that is, the number of electrets 14, A is the area of the conductor 16, f is the frequency of reciprocation of the conductor 16, d is the thickness of the electret 14, and g is the electret. 14 is the distance between the conductor 16 and ε is the relative permittivity.

上記式からわかるように、エレクトレット14の厚さdが大きいほど発電出力も大きくなる。従来使用されていた材料では、エレクトレット14の厚さdは数〜10μm程度にしかできなかったが、上記含フッ素脂肪族環構造を有する重合体を使用する場合には、上述したように、エレクトレット14の厚さdを10μm以上とすることができ、静電誘導型変換素子の最大発電出力を増大することができる。   As can be seen from the above equation, the greater the thickness d of the electret 14, the greater the power generation output. In the material conventionally used, the thickness d of the electret 14 could only be about several tens to 10 μm. However, when the polymer having the fluorinated aliphatic ring structure is used, as described above, the electret The thickness d of 14 can be 10 μm or more, and the maximum power generation output of the electrostatic induction conversion element can be increased.

上記の主鎖に含フッ素脂肪族環構造を有する重合体は、旭硝子株式会社より「CYTOP(登録商標)」の商品名で市販されており、本発明ではこのような公知の含フッ素重合体を使用することができる。なお、このCYTOP(登録商標)の絶縁破壊強度は、11kV/0.1mmであり、例えば従来使用されていた材料であるテフロン(登録商標)AFの絶縁破壊強度5kV/0.1mmより高くなっている。絶縁破壊強度を高くできると、エレクトレット14への電荷注入量を増加でき、静電誘導型変換素子の最大発電出力をさらに増大することができる。この結果、発電機の発電量やセンサの感度を向上させることができる。   The polymer having a fluorine-containing aliphatic ring structure in the main chain is commercially available from Asahi Glass Co., Ltd. under the trade name “CYTOP (registered trademark)”. In the present invention, such a known fluorine-containing polymer is used. Can be used. In addition, the dielectric breakdown strength of this CYTOP (registered trademark) is 11 kV / 0.1 mm, for example, higher than the dielectric breakdown strength of 5 kV / 0.1 mm of Teflon (registered trademark) AF which is a conventionally used material. Yes. If the dielectric breakdown strength can be increased, the amount of charge injected into the electret 14 can be increased, and the maximum power generation output of the electrostatic induction conversion element can be further increased. As a result, the power generation amount of the generator and the sensitivity of the sensor can be improved.

本発明にかかる静電誘導型変換素子の構成例の断面図である。It is sectional drawing of the structural example of the electrostatic induction type conversion element concerning this invention. エレクトレットと導体との配置例を示す図である。It is a figure which shows the example of arrangement | positioning of an electret and a conductor. エレクトレットと導体との他の配置例を示す図である。It is a figure which shows the other example of arrangement | positioning of an electret and a conductor. エレクトレットと導体とのさらに他の配置例を示す図である。It is a figure which shows the further example of arrangement | positioning of an electret and a conductor. 本発明にかかる静電誘導型変換素子の応用例を示す図である。It is a figure which shows the application example of the electrostatic induction type conversion element concerning this invention. 従来における静電アクチュエータの構成例を示す図である。It is a figure which shows the structural example of the conventional electrostatic actuator.

符号の説明Explanation of symbols

10、12 基板、14 エレクトレット、16 導体、18、20 端子、22 筐体、24 ばね。   10, 12 substrates, 14 electrets, 16 conductors, 18, 20 terminals, 22 housings, 24 springs.

Claims (7)

電気エネルギと運動エネルギとを変換する静電誘導型変換素子であって、
互いに対向し、対向面に平行な方向に相対運動する基板と、
前記基板の各対向面に混在して形成されたエレクトレット及び導体と、
を備え、前記エレクトレットと導体とは、前記エレクトレットと導体とが対向して発生する吸引力と、前記エレクトレット同士が対向して発生する反発力とが略釣り合うように配置されていることを特徴とする静電誘導型変換素子。
An electrostatic induction conversion element that converts electrical energy and kinetic energy,
Substrates that face each other and move relatively in a direction parallel to the facing surface;
Electrets and conductors formed mixed on each facing surface of the substrate;
The electret and the conductor are arranged so that a suction force generated by the electret and the conductor facing each other and a repulsive force generated by the electret facing each other are substantially balanced. An electrostatic induction type conversion element.
請求項1記載の静電誘導型変換素子において、前記基板の少なくとも一方で、前記エレクトレットと導体の各総面積が異なった値であることを特徴とする静電誘導型変換素子。   2. The electrostatic induction conversion element according to claim 1, wherein the total areas of the electret and the conductor are different values on at least one of the substrates. 請求項1または請求項2記載の静電誘導型変換素子において、前記エレクトレットと導体とは、細片状に形成されていることを特徴とする静電誘導型変換素子。   3. The electrostatic induction conversion element according to claim 1 or 2, wherein the electret and the conductor are formed in a strip shape. 請求項1または請求項2記載の静電誘導型変換素子において、前記エレクトレットと導体とは、碁盤格子状に配置されていることを特徴とする静電誘導型変換素子。   3. The electrostatic induction conversion element according to claim 1, wherein the electrets and the conductors are arranged in a grid pattern. 請求項1から請求項4のいずれか一項記載の静電誘導型変換素子において、前記エレクトレットは、PTFE(ポロテトラフルオロエチレン)、FEP(テトラフルオロエチレン/ヘキサフルオロプロピレン共重合体)、PFA(テトラフルオロエチレン/パーフルオロ(アルキルビニルエーテル))共重合体、酸化珪素、含フッ素脂肪族環構造を有する重合体または溶剤可溶性の含フッ素樹脂により構成されていることを特徴とする静電誘導型変換素子。   5. The electrostatic induction conversion element according to claim 1, wherein the electret includes PTFE (polytetrafluoroethylene), FEP (tetrafluoroethylene / hexafluoropropylene copolymer), PFA ( Electrostatic induction conversion comprising a tetrafluoroethylene / perfluoro (alkyl vinyl ether)) copolymer, silicon oxide, a polymer having a fluorine-containing aliphatic ring structure, or a solvent-soluble fluorine-containing resin element. 請求項5記載の静電誘導型変換素子において、前記含フッ素脂肪族環構造を有する重合体は、2つ以上の重合性二重結合を有する含フッ素モノマーを環化重合して得られる、主鎖に含フッ素脂肪族環構造を有する重合体により構成されていることを特徴とする静電誘導型変換素子。   6. The electrostatic induction conversion element according to claim 5, wherein the polymer having a fluorine-containing aliphatic ring structure is obtained by cyclopolymerizing a fluorine-containing monomer having two or more polymerizable double bonds. An electrostatic induction conversion element comprising a polymer having a fluorine-containing aliphatic ring structure in a chain. 請求項6記載の静電誘導型変換素子において、前記含フッ素脂肪族環構造には、エーテル性酸素原子が1個以下含まれることを特徴とする静電誘導型変換素子。
7. The electrostatic induction conversion element according to claim 6, wherein the fluorine-containing aliphatic ring structure contains one or less etheric oxygen atoms.
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WO2020027510A1 (en) * 2018-07-30 2020-02-06 경희대학교산학협력단 Electrostatic power generator using ionic elastomer
JP7282365B2 (en) 2019-06-12 2023-05-29 国立大学法人 東京大学 Electrode substrates used in electrostatic induction power generating elements
WO2021141065A1 (en) 2020-01-08 2021-07-15 ダイキン工業株式会社 Electret material and induction conversion element
KR20220123681A (en) 2020-01-08 2022-09-08 다이킨 고교 가부시키가이샤 Electret Materials and Electrostatic Dielectric Conversion Elements

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