JP2007307522A - Medium agitation type wet dispersion machine and dispersion method of fine particle - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a medium agitation type wet dispersion machine having high dispersion efficiency and causing no abrasion problem, by eliminating a co-rotation phenomenon of mediums. <P>SOLUTION: This dispersion machine is provided with a cylindrical separator 3 and a rotor 5 rotating being fixed to a rotary shaft 4 inside a cylindrical vessel 2 having a supply port 6 and a discharge port 7 of a treating object. The rotor 5 comprises multiple small rotors 50 having cylindrical agitation parts 51 and disc-type holding parts 52, and is provided with multiple through-holes 53 communicating the inner side with outside of the agitation parts 51. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a media agitation type wet disperser that continuously disperses.

  The wet dispersion process is a process in which solid particles contained in a slurry are finely pulverized to form a dispersion composed of finer fine particles. For example, it is often performed in a wide range of fields such as printer ink, paint, polymerized toner, color resist, ceramic fine particles, titanium oxide, metal powder, and pharmaceuticals. That is, these are slurries containing inorganic fine particles, organic fine particles, inorganic organic composite fine particles, or a mixture thereof.

  One of the dispersers used for these processes is a media agitation type disperser. This disperser stirs a slurry-like treatment liquid and a medium together in a container, and pulverizes and disperses particles by the shearing force of the medium. The dispersed treatment liquid is separated from the medium by a separator provided in the container and discharged outside the container. As the separator, a sieve type such as a gap type or a screen type is often used.

  The performance of the dispersion process is greatly influenced by the diameter of the media used. The smaller the media diameter, the smaller the particle size in the dispersion, so the recent trend is to reduce the media diameter. is there. However, as the diameter of the media decreases, the segregation phenomenon that the media is pressed to the discharge side becomes a problem. To solve this problem, a media agitation type wet disperser having an L / D ratio of less than 1 is proposed in Patent Document 1. ing.

  As shown in FIG. 9, a media agitation type wet disperser 101 described in Patent Document 1 is divided into a cylindrical container 102 and an inner chamber 121 and an outer chamber 122 in the radial direction inside the container 102 and both chambers. A cylindrical separator 103 having a plurality of slits 131 communicating therewith, a rotating shaft 104 that is rotatably inserted through one end of the container 102, a rotor 105 that is fixed to the rotating shaft 104 and rotates, A processing product supply port 106 provided at the other end of the container 102 and communicating with the inside and outside of the container 102 and a processing product discharge port 107 provided on the outer periphery of the container 102 and communicating with the outside of the outside chamber are provided.

  Then, when the processed material is supplied into the container 102 from the supply port 106 and the rotor 105 is rotated, the processed material is stirred together with the media located in the inner chamber 121 and subjected to pulverization processing and dispersion processing. The medium flows outward from the center, is separated by the slit 131 of the separator 103, and is discharged from the outer chamber 122 to the outside of the container 102 through the discharge port 107.

The disperser 101 can prevent media segregation by reducing the L / D ratio and increasing the surface area of the separator 103. However, the disperser 101 has a problem in that the media positioned between the rotor 105 and the separator 103 cause a common rotation (group motion). For this reason, there exists a problem that the shear force between the media which should generate | occur | produce around the rotor 105 reduces, and causes the processing efficiency to fall. Further, there is a problem that the speed of the medium contacting the surface of the separator 103 becomes high near the peripheral speed of the rotor 105 and the separator 103 is worn.
Japanese Patent Laid-Open No. 10-15411

  An object of the present invention is to provide a cylindrical container, a cylindrical separator in which the inside of the container is radially divided into an inner chamber and an outer chamber and a plurality of slits communicating between the chambers are formed, and one end of the container A rotating shaft that is inserted and rotated, a rotor that is fixed to the rotating shaft and rotates, a supply port for a processed material that is provided at the other end of the container and communicates with the inside and outside of the container, and an outer surface that is provided on the outer periphery of the container A media agitation type wet disperser equipped with a discharge port for processed materials communicating between the inside and outside of the room, and a disperser capable of improving dispersion processing efficiency and preventing abrasion in separators, etc. by suppressing the media co-rotation phenomenon. Is to provide. Another object of the present invention is to provide a method for dispersing fine particles, which can improve the efficiency of dispersion treatment and prevent abrasion in a separator or the like.

  In order to solve the above-mentioned problems, a media agitation type wet disperser according to claim 1 of the present invention divides a cylindrical container, the inside of the container into an inner chamber and an outer chamber in the radial direction, and both A cylindrical separator in which a plurality of slits communicating between the chambers are formed; a rotating shaft that is rotatably inserted through one end of the container; a rotor that is fixed to the rotating shaft and rotates; In the media agitation type wet disperser provided with a processing product supply port provided at the other end and communicating with the inside and outside of the inner chamber and a discharge port for the processing product provided at the outer periphery of the container and communicating with the outside and the outside of the container. However, a means comprising a plurality of small rotors provided with a cylindrical stirring portion and a disc-shaped holding portion, and the stirring portion including a plurality of through holes communicating between the inside and the outside is employed.

A media agitation type wet disperser according to a second aspect of the present invention is the media agitation type wet disperser according to the first aspect, wherein the inner chamber has a cylindrical shape with a diameter D and a length L between both ends. When the number of the small rotors is N, means having the relationship of Formula 1 is adopted.
0.3L <L / D <0.75L ... Formula 1

Further, the media agitation type wet disperser according to claim 3 of the present invention is the media agitation type wet disperser according to claim 1 or 2, wherein both ends of the inner chamber extend from a predetermined inward position to an end. A means having a relationship of the formula 2 between the diameter D and the diameter D is formed.
D / 30 <R <D / 3 ...... Equation 2

Further, the media agitation type wet disperser according to claim 4 of the present invention is the media agitation type wet disperser according to any one of claims 1 to 3, wherein the outer diameter d of the agitation part is the diameter D. A means having the relationship of the expression 3 is adopted.
0.70 <d / D <0.97 ... Formula 3

Further, the media agitation type wet disperser according to claim 5 of the present invention is the media agitation type wet disperser according to any one of claims 1 to 4, wherein the width w of the agitation part is the length L and A means having a relationship of Formula 4 with the number N is adopted.
0.7L <wN <0.9L ... Formula 4

  A media agitation type wet disperser according to claim 6 of the present invention is the media agitation type wet disperser according to any one of claims 1 to 5, wherein the agitation unit is directed from the inner peripheral surface toward the outer peripheral surface. A means is employed in which the direction of the through hole is inclined in a direction retreating with respect to the rotation direction.

  In addition, the media agitation type wet disperser according to claim 7 of the present invention is the media agitation type wet disperser according to any one of claims 1 to 6, wherein the agitation unit has a protrusion on the outer peripheral surface. Means.

  The media agitation type wet disperser according to claim 8 of the present invention is the media agitation type wet disperser according to any one of claims 1 to 7, wherein the agitation unit is divided into two by the holding unit, Means having the through-holes on both sides of the agitator is divided.

  In addition, the media agitation type wet disperser according to claim 9 of the present invention employs the media agitation type wet disperser according to any one of claims 1 to 8, wherein the holding portion includes an opening. is doing.

  The fine particle dispersion method according to claim 10 of the present invention is a dispersion method of a slurry-like treatment liquid containing inorganic fine particles, organic fine particles, inorganic-organic composite fine particles, or a mixture thereof. The means using the described media agitation type wet disperser is employed.

The fine particle dispersion method according to an eleventh aspect of the present invention is the fine particle dispersion method according to the tenth aspect, in which the medium filled in the container is closely packed in a ring shape around the stirring portion. Assuming that, the thickness A of the ring employs means having the relationship of Equation 5 between the length L and the number N.
0.67N <L / A <1.5N ... Formula 5

  Since the media stirring type wet disperser of the present invention is configured as described above, a circulating flow passing through the through hole is generated in the stirring portion of the small rotor. That is, the processed material and media located around the stirring portion of the small rotor flow from the inside to the outside in the through hole, and flow from the center to the end of the stirring portion outside the stirring portion. Flows from the outside toward the inside, and flows from the end toward the through hole inside the stirring portion.

  Due to the generation of this circulating flow, the media around the stirring unit cannot co-rotate, and a powerful shearing force can be generated between the media to perform highly efficient pulverization processing and dispersion processing. Further, the elimination of the co-rotation slows the flow rate of the media in the vicinity of the separator and can prevent the separator from being worn.

Hereinafter, embodiments of the present invention shown in the drawings will be described.
1 to 8 show an embodiment of a media agitation type wet disperser according to the present invention. FIG. 1 is a schematic side sectional view of a media agitation type wet disperser, and FIG. 2 is a schematic sectional view of a rotor.
This media agitation type wet disperser 1 includes a cylindrical separator 3 having a processing product supply port 6 and a discharge port 7, and a cylindrical separator 3 and a rotor 5 fixed to a rotating shaft 4 and rotating. The rotor 5 includes a plurality of small rotors 50.

  The container 2 is partitioned into an inner chamber 21 and an outer chamber 22 in the radial direction by a cylindrical separator 3. And since a grinding | pulverization process and a dispersion | distribution process are performed in the inner side chamber 21, the internal shape of the inner side chamber 21 is an important component of this invention. That is, when the length between the inner both ends of the container 2 is L and the inner diameter of the separator 3 is D, these are the length L and the diameter D between the both ends of the cylindrical inner chamber 21. When the number of the small rotors 50 is N, the ratio of the length L to the diameter D is preferably in the range of 0.3N <L / D <0.75N. By making L / D smaller than 0.75N, it is possible to suppress the occurrence of media segregation and group motion even when media having a small diameter are used. In addition, by making the value larger than 0.3 N, the working range of the rotor 5 can be sufficiently ensured.

  In addition, it is preferable that both end portions of the inner chamber 21 are formed so as to be gradually reduced in diameter from a predetermined inward position toward the end so as to have a curved cross section, and between the curvature radius R and the diameter D, D / 30 It is preferable to have a relationship of <R <D / 3. By making the both ends of the inner chamber 21 have a curved cross section, the fluidity of the circulating flow is improved and the occurrence of segregation and group motion can be suppressed. As shown in FIG. 4a, the inner diameter of the separator 3 may be formed in a curved shape, or both ends of the container 2 may be formed in a curved shape as shown in FIG. 4b. good.

  The separator 3 is a screen type in which a plurality of slits 31 are formed, and the inner chamber 21 and the outer chamber 22 communicate with each other through the slit 31. The processed product that has been stirred together with the medium in the inner chamber 21 and subjected to the pulverization process and the dispersion process is separated from the medium by the separator 3 and can be moved to the outer chamber 22. The width of the slit 31 is set according to the diameter of the medium, and the total area is set according to the properties and flow rate of the processed material.

  A rotating shaft 4 is rotatably provided through one end of the container 2, and a rotor 5 including a plurality of small rotors 50 is fixed to the rotating shaft 4. The rotating shaft 4 is sealed by a seal member 8, and the processed material and media in the inner chamber 21 can be agitated by rotating the rotating shaft 4 with a driving source (not shown). The other end of the container 2 is provided with a processing product supply port 6 that communicates between the inside and outside of the inner chamber 21, and the outer periphery of the container 2 is provided with a processing product discharge port 7 that communicates between the inside and outside of the outer chamber 22. ing.

  The rotor 5 is devised in a shape that generates a circulating flow, and is an important component of the present invention. That is, the rotor 5 includes a plurality of small rotors 50, and each of the small rotors 50 includes a cylindrical stirring unit 51 and a disk-shaped holding unit 52. The small rotor 50 can be an end holding type in which the holding unit 52 is provided at the end of the stirring unit 51, or can be a central holding type provided in the center of the stirring unit 51 so as to bisect the stirring unit 51. it can. In the case of the center holding type, the through holes 53 are provided on both sides divided into two.

  The media agitation type wet disperser 1 shown in FIG. 1 includes two end holding small rotors 50. The media agitation type wet disperser 1 shown in FIG. 6 includes three central holding type small rotors 50. Further, the media agitation type wet disperser 1 shown in FIG. 7 includes one end holding small rotor 50 and two central holding small rotors 50. In addition, the number and combination of the small rotors 50 can be selected as appropriate.

  The medium subjected to the centrifugal force flows from the inside to the outside through the through hole 53. In order to improve fluidity, it is preferable that the through hole 53 is inclined in a direction in which the direction from the inner peripheral surface to the outer peripheral surface of the agitating unit 51 is retracted from the rotation direction. And as shown in FIG. 2, it is especially preferable that angle (theta) 1 will be 0-60 degrees with respect to the line which goes to the axial center from the center of the thickness of the stirring part 51. FIG.

  Due to the rotation of the rotor 5, the media around the stirring unit 51 are given a shearing force and a centrifugal force. Then, by providing the protrusion 55 on the outer periphery of the stirring unit 51, this shearing force and centrifugal force can be strengthened. Furthermore, by alternately arranging the through holes 53 and the protrusions 55 on the circumference, the formation of the circulation flow is further promoted.

  The relationship between the rotor 5 and the inner chamber 21 is preferably such that 0.70 <d / D <0.97 between the outer diameter d of the stirring unit 51 and the diameter D of the inner chamber 21. By setting it as this range, while being able to make generation | occurrence | production of a circulating flow favorable, a grinding | pulverization process and a dispersion | distribution process can be made effective. In addition, it is preferable that the width w of the stirring unit 51 be in a relationship of 0, 7L <wN <0, 9L between the length L of the inner chamber 21 and the number N of the small rotors 50. By setting it as this range, while being able to make generation | occurrence | production of a circulating flow favorable, a grinding | pulverization process and a dispersion | distribution process can be made effective.

  By setting it as the above shapes, about each small rotor 50, the processed material and medium which exist around the stirring part 51 generate | occur | produce the circulation flow as shown by the arrow of FIG. That is, this circulating flow flows from the inside to the outside in the through hole 53, flows from the center to the end of the stirring unit 51 outside the stirring unit 51, and from the outside to the inside at the end of the stirring unit 51. And flows from the end portion toward the through hole 53 inside the stirring portion 51.

  The inside of the stirring unit 51 is preferably held in a well-mixed state, and an opening 54 is preferably provided in the holding unit 52 so as not to be separated by the holding unit 52. The opening 54 preferably has an angle θ2 as shown in FIG. 3 when viewed in the section EE in FIG. Depending on the direction of the angle θ2, the flow of the processed material and the medium can be promoted from one side of the inner chamber 21 to the other side, or can be promoted from the other side to the one side. Then, by alternately changing the flow direction of the plurality of openings 54, it is possible to eliminate the distinction on both sides and make the entire mixture uniform.

  By forming the inner chamber 21 and the rotor 5 as described above, good pulverization processing and dispersion processing are performed in the inner chamber 21. That is, a large shearing force is generated by giving a large speed difference between the media between the inner wall of the separator 3 and the outer periphery of the stirring portion 51 of the rotor 5. At the same time, a circulating flow is generated in the agitation unit 51 of each small rotor 50. The direction of the flow by the circulating flow is a direction orthogonal to the direction of the flow by the rotation of the rotor 5. For this reason, the media cannot move together with the stirring unit 51, and the segregation phenomenon and the co-rotation phenomenon are eliminated.

  In the media stirring type wet disperser 1 of the present invention, when the processed material is supplied into the container 2 from the supply port 6 and the rotor 5 is rotated, the processed material is stirred together with the media located in the inner chamber 21, A grinding process and a dispersion process are received. Then, the fluid flows outward from the center of the container 2, the media is separated by the slit 31 of the separator 3, and is discharged from the outer chamber 22 to the outside of the grinding container 2 through the discharge port 7.

  In the vicinity of the peripheral surface of the inner chamber 21, high-efficiency pulverization processing and dispersion processing can be performed by a strong shearing force between the media. At the same time, the elimination of co-rotation slows the flow rate of the media in the vicinity of the separator 3 and prevents wear of the separator 3 and the like. Further, in the vicinity of the center of the inner chamber 21, the processing object and the medium can be kept in a uniform mixed state and processed without causing a short circuit of the processing object. Therefore, it is possible to perform processing utilizing the entire inner chamber 21.

  The media stirring type wet disperser 1 of the present invention can be used in a wide range of fields such as printer ink, paint, polymerized toner, color resist, ceramic fine particles, titanium oxide, metal powder, and pharmaceuticals. That is, these are slurry-like treatment liquids containing inorganic fine particles, organic fine particles, inorganic-organic composite fine particles, or a mixture thereof.

  The amount of media filled in the inner chamber 21 is also related to the occurrence of co-rotation. That is, when it is assumed that the medium to be filled is packed in a ring shape around the stirring portion 51, the ring thickness A is 0 between the length L and the number N of the small rotors 50. It is preferable that the relationship is .67N <L / A <1.5N. By setting this range, it is possible to prevent the occurrence of co-rotation and to make the pulverization process and the dispersion process effective.

It is a schematic sectional drawing which shows an example of implementation of the media stirring type wet disperser of this invention. It is a schematic sectional drawing of the rotor shown in FIG. It is the schematic which shows the EE cross section of FIG. It is the schematic which shows the edge part of an inner side chamber. It is explanatory drawing which shows the flow of a circulating flow. It is a schematic sectional drawing which shows the other example of implementation of the media stirring type wet disperser of this invention. It is the schematic which shows the further another example of implementation of the media stirring type wet disperser of this invention. It is explanatory drawing which shows the filling state of a medium. It is a schematic sectional drawing which shows the conventional media stirring type wet disperser.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1,101 Media stirring type wet disperser 2,102 Container 3,103 Separator 4,104 Rotating shaft 5,105 Rotor 6,106 Supply port 7,107 Outlet 8 Seal member 21,121 Inner chamber 22,122 Outer chamber 31 131 Slit 50 Small rotor 51 Stirring section 52 Holding section 53 Through hole 54 Opening 55 Projection

Claims (11)

A cylindrical container, a cylindrical separator in which the inside of the container is radially divided into an inner chamber and an outer chamber and a plurality of slits communicating between the chambers are formed, and one end of the container is inserted and rotated. A rotating shaft that is freely provided, a rotor that is fixed to the rotating shaft and rotates, a supply port for a processed material that is provided at the other end of the vessel and communicates with the inside and outside of the vessel, and that is provided on the outer periphery of the vessel. In the media agitation type wet disperser provided with a discharge port for the processed material communicating between the outside and the outside of the room,
The rotor is composed of a plurality of small rotors each having a cylindrical stirring portion and a disc-shaped holding portion, and the stirring portion includes a plurality of through-holes communicating inside and outside. Type wet disperser. 2. The media agitation type according to claim 1, wherein the inner chamber has a cylindrical shape with a diameter D and a length L between both ends, and when the number of the small rotors is N, the relationship of Formula 1 is satisfied. Wet disperser.
0.3N <L / D <0.75N ... Formula 1 Both end portions of the inner chamber are sequentially formed with a small diameter from a predetermined inward position toward the end to form a cross-sectional curved shape with a radius of curvature R, and there is a relationship of Formula 2 with the diameter D. The media stirring type wet disperser according to claim 1 or 2.
D / 30 <R <D / 3 ... Formula 2 4. The media stirring type wet disperser according to claim 1, wherein an outer diameter d of the stirring unit has a relationship of Formula 3 with the diameter D. 5.
0.70 <d / D <0.97 ... Formula 3 The media agitation type wet disperser according to any one of claims 1 to 4, wherein the width w of the agitation unit has a relationship of Formula 4 between the length L and the number N.
0.7L <wN <0.9L ... Formula 4   The media agitation according to any one of claims 1 to 5, wherein a direction of the through hole from the inner peripheral surface of the agitating portion toward the outer peripheral surface is inclined in a direction retreating with respect to the rotation direction. Type wet disperser.   The media agitation type wet disperser according to any one of claims 1 to 6, wherein the agitation unit includes a protrusion on an outer peripheral surface.   The media agitation type according to any one of claims 1 to 7, wherein the agitation unit is bisected by the holding unit, and the through hole is provided on both sides where the agitation unit is bisected. Wet disperser.   The media stirring type wet disperser according to any one of claims 1 to 8, wherein the holding portion includes an opening.   10. A method for dispersing a slurry-like treatment liquid containing inorganic fine particles, organic fine particles, inorganic organic composite fine particles or a mixture thereof, wherein the fine particles are characterized by using the media stirring type wet disperser according to any one of claims 1 to 9. How to distribute. When it is assumed that the medium filled in the container is packed in a ring shape around the stirring unit, the thickness A of the ring is between the length L and the number N as shown in Equation 5 below. The method for dispersing fine particles according to claim 10, wherein there is a relationship.
0.67N <L / A <1.5N ... Formula 5

Images