JP5046546B2 - Media stirring type wet disperser and fine particle dispersion method - Google Patents

Description

  The present invention relates to a media agitation type wet disperser that continuously disperses and a method for dispersing fine particles.

  The wet dispersion process is a process in which solid particles contained in a slurry are finely pulverized to form a dispersion composed of finer fine particles. For example, it is often performed in a wide range of fields such as printer ink, paint, polymerized toner, color resist, ceramic fine particles, titanium oxide, metal powder, and pharmaceuticals. That is, these are slurries containing inorganic fine particles, organic fine particles, inorganic organic composite fine particles, or a mixture thereof.

  One of the dispersers used for these processes is a media agitation type disperser. This disperser stirs a slurry-like treatment liquid and a medium together in a container, and pulverizes and disperses particles by the shearing force of the medium. The dispersed treatment liquid is separated from the medium by a separator provided in the container and discharged outside the container. As the separator, a sieve type such as a gap type or a screen type is often used.

  The performance of the dispersion process is greatly influenced by the diameter of the media used. The smaller the media diameter, the smaller the particle size in the dispersion, so the recent trend is to reduce the media diameter. is there. However, as the diameter of the media decreases, the segregation phenomenon that the media is pressed to the discharge side becomes a problem. To solve this problem, a media agitation type wet disperser having an L / D ratio of less than 1 is proposed in Patent Document 1. ing.

  As shown in FIG. 7, a media agitation type wet disperser 101 described in Patent Document 1 has a cylindrical dispersion container 102, and the inside of the dispersion container 102 is radially divided into an inner chamber 121 and an outer chamber 122. A cylindrical separator 103 in which a plurality of slits 131 communicating between both chambers are formed, a rotating shaft 104 that is rotatably inserted through one end of the dispersion vessel 102, and a rotor that is fixed to the rotating shaft 104 and rotates. 105, a processing product supply port 106 provided at the other end of the dispersion vessel 102 and communicating with the inside and outside of the inside of the dispersion vessel 102, and a processing product discharge port 107 provided on the outer periphery of the dispersion vessel 102 and communicating with the outside of the outside chamber. .

  Then, when the processed material is supplied from the supply port 106 into the dispersion container 102 and the rotor 105 is rotated, the processed material is stirred together with the media located in the inner chamber 121 and subjected to pulverization processing and dispersion processing. The medium flows outward from the center of 102, the media is separated by the slit 131 of the separator 103, and is discharged from the outer chamber 122 to the outside of the pulverization container 102 through the discharge port 107.

The disperser 101 can prevent media segregation by reducing the L / D ratio. However, the disperser 101 has a problem that the media located between the rotor 105 and the separator 103 rarely rotate together (group motion). For this reason, there exists a problem that the shear force between the media which should generate | occur | produce around the rotor 105 reduces, and causes the processing efficiency to fall. Further, there is a problem that the speed of the medium contacting the surface of the separator 103 becomes high near the peripheral speed of the rotor 105 and the separator 103 is worn.
Japanese Patent Laid-Open No. 10-15411

  An object of the present invention is to provide a cylindrical container, a cylindrical separator in which the inside of the container is radially divided into an inner chamber and an outer chamber and a plurality of slits communicating between the chambers are formed, and one end of the container A rotating shaft that is inserted and rotated, a rotor that is fixed to the rotating shaft and rotates, a supply port for a processed material that is provided at the other end of the container and communicates with the inside and outside of the container, and an outer surface that is provided on the outer periphery of the container A media agitation type wet disperser equipped with a discharge port for processed materials communicating between the inside and outside of the room, and a disperser capable of improving dispersion processing efficiency and preventing abrasion in separators, etc. by suppressing the media co-rotation phenomenon. Is to provide. Another object of the present invention is to provide a method for dispersing fine particles that can improve the efficiency of the dispersion treatment and prevent abrasion in a separator or the like.

In order to solve the above-mentioned problems, a media agitation type wet disperser according to claim 1 of the present invention divides a cylindrical container, the inside of the container into an inner chamber and an outer chamber in the radial direction, and both A cylindrical separator in which a plurality of slits communicating between the chambers are formed; a rotating shaft that is rotatably inserted through one end of the container; a rotor that is fixed to the rotating shaft and rotates; In the media agitation type wet disperser provided with a processing product supply port provided at the other end and communicating with the inside and outside of the inner chamber and a discharge port for the processing product provided at the outer periphery of the container and communicating with the outside and the outside of the container. There a cylindrical stirring portion and the disc-shaped holding portion, wherein the agitating unit is provided with a plurality of through-holes communicating the internal and external to both sides of which are bisected by said holding unit, the both sides of the Generates a circulating flow that circulates inside and outside the stirring section. Rutotomoni, the holding portion is provided with an opening, it employs a means adapted to the whole without distinction on both sides with homogeneous mixed state.

A media agitation type wet disperser according to claim 2 of the present invention is the media agitation type wet disperser according to claim 1, wherein the inner chamber has a cylindrical shape, and a length L and a diameter D between both ends. A means having the relationship of Formula 1 is adopted between the two.
0.3 <L / D <1 ... Formula 1

Further, the media agitation type wet disperser according to claim 3 of the present invention is the media agitation type wet disperser according to claim 1 or 2, wherein both ends of the inner chamber extend from a predetermined inward position to an end. A means having a relation of the formula 2 is adopted, which is formed so as to be gradually reduced in diameter and has a curved cross section with a radius of curvature R.
L / 30 <R <L / 3 ... Formula 2

The media agitation type wet disperser according to claim 4 of the present invention, the in media-agitation type wet disperser according to any one of claims 1 to 3, the outer diameter d of the stirring portion diameter D The means having the relationship of the expression 3 is adopted.
0.70 <d / D <0.97 ... Formula 3

The media agitation type wet disperser according to claim 5 of the present invention, in the media-agitation type wet disperser according to any one of claims 1 to 4, the width w and the length L of the agitating portion The means which has the relationship of Formula 4 is adopted.
0.7 <w / L <0.9 …… Formula 4

Moreover, the media stirring type wet disperser which concerns on Claim 6 of this invention is a media stirring type wet disperser in any one of Claims 1 thru | or 5. WHEREIN: The said through-hole is an inner periphery of the said stirring part. A means is employed in which the direction from the surface toward the outer peripheral surface is inclined in a direction retreating with respect to the rotation direction.

The media agitation type wet disperser according to claim 7 of the present invention includes the media-agitation type wet disperser according to any one of claims 1 to 6, wherein the agitating unit, the projection on the outer peripheral surface Adopting means.

The media agitation type wet disperser according to claim 8 of the present invention, in the media-agitation type wet disperser according to any one of claims 1 to 7, wherein the holding portion is in the center of the agitating portion The provided means is adopted.

Further, a method of dispersing fine particles according to claim 9 of the present invention, inorganic fine particles, organic fine particles, the method of dispersing slurry treatment liquid containing an inorganic-organic composite particles, or a mixture thereof, any one of claims 1 to 8 1 The means using the media agitation type wet disperser described in the paragraph is adopted.

The fine particle dispersion method according to claim 10 of the present invention is the fine particle dispersion method according to claim 9 , wherein the medium filled in the container is closely packed in a ring shape around the stirring portion. Assuming that this is the case, means having a relationship of Formula 5 between the ring thickness A and the length L is employed.
0.5 <L / A <2 ... Formula 5

  The media agitation type wet disperser of the present invention is configured as described above, so that in the agitation part of the rotor, a circulating flow is generated on both sides divided by the disc-shaped holding part. Become. That is, due to this circulation flow, the processed material and the media positioned around the stirring unit of the rotor flow from the inside to the outside in the through hole, and flow from the center to the end of the container outside the stirring unit. It flows from the outside to the inside at both ends of the, and flows from the end to the holding part inside the stirring unit.

  Due to the generation of this circulating flow, the media around the stirring unit cannot co-rotate, and a powerful shearing force can be generated between the media to perform highly efficient pulverization processing and dispersion processing. Further, the elimination of the co-rotation slows the flow rate of the media in the vicinity of the separator and can prevent the separator from being worn.

Hereinafter, embodiments of the present invention shown in the drawings will be described.
1 to 6 show an embodiment of a media stirring type wet disperser according to the present invention. FIG. 1 is a schematic side sectional view of a media agitation type wet disperser, and FIG. 2 is a schematic sectional view of a rotor.

This media agitation type wet disperser 1 includes a cylindrical separator 3 having a processing product supply port 6 and a discharge port 7, and a cylindrical separator 3 and a rotor 5 fixed to a rotating shaft 4 and rotating. I have.

  The container 2 is partitioned into an inner chamber 21 and an outer chamber 22 in the radial direction by a cylindrical separator 3. And since a grinding | pulverization process and a dispersion | distribution process are performed in the inner side chamber 21, the internal shape of the inner side chamber 21 is an important component of this invention. That is, when the length between the inner both ends of the container 2 is L and the inner diameter of the separator 3 is D, these are the length L and the diameter D between the both ends of the cylindrical inner chamber 21. The ratio between the length L and the diameter D is preferably in the range of 0.3 <L / D <1. By making L / D smaller than 1, even when a medium having a small diameter is used, the occurrence of media segregation and group motion can be suppressed. Moreover, by making it larger than 0.3, the working range of the rotor 5 can be sufficiently ensured.

  In addition, it is preferable that both end portions of the inner chamber 21 are sequentially formed to have a small diameter from a predetermined inward position toward the end so as to have a curved cross section, and between the curvature radius R and the length L, L / It is preferable to have a relationship of 30 <R <L / 3. By making the both ends of the inner chamber 21 have a curved cross section, the fluidity of the circulating flow is improved and the occurrence of segregation and group motion can be suppressed. In addition, as shown in FIG. 4A, the curved portion may be formed so that the inner diameter of the separator 3 is curved, or both ends of the container 2 are curved as shown in FIG. 4B. You may form in a shape.

  The separator 3 is a screen type in which a plurality of slits 31 are formed, and the inner chamber 21 and the outer chamber 22 communicate with each other through the slit 31. The processed product that has been stirred together with the medium in the inner chamber 21 and subjected to the pulverization process and the dispersion process is separated from the medium by the screen 3 and can move to the outer chamber 22. The width of the slit 31 is set according to the diameter of the medium, and the total area is set according to the properties and flow rate of the processed material.

  A rotating shaft 4 is rotatably provided through one end of the container 2, and a rotor 5 is fixed to the end of the rotating shaft 4. The rotating shaft 4 is sealed by a seal member 8, and the processed material and media in the inner chamber 21 can be agitated by rotating the rotating shaft 4 with a driving source (not shown). The other end of the container 2 is provided with a processing product supply port 6 that communicates between the inside and outside of the inner chamber 21, and the outer periphery of the container 2 is provided with a processing product discharge port 7 that communicates between the inside and outside of the outer chamber 22. ing.

  The rotor 5 is devised in a shape that generates a circulating flow, and is an important component of the present invention. That is, the rotor 5 includes a cylindrical stirring unit 51 and a disc-shaped holding unit 52. The stirring unit 51 is divided into two by the holding unit 52, and a plurality of through-holes 53 communicating between the inside and the outside are provided on both sides of the stirring unit 51. In order to balance the generated circulation flow, the holding unit 52 is preferably provided in the center of the stirring unit 51 and has a symmetrical shape on both sides.

  The medium subjected to the centrifugal force flows from the inside to the outside through the through hole 53. In order to improve fluidity, it is preferable that the through hole 53 is inclined in a direction in which the direction from the inner peripheral surface to the outer peripheral surface of the agitating unit 51 is retracted from the rotation direction. And as shown in FIG. 2, it is especially preferable that angle (theta) 1 will be 0-60 degrees with respect to the line which goes to the axial center from the center of the thickness of the stirring part 51. FIG.

  By the rotation of the rotor 5, a shearing force and a centrifugal force are applied to the media around the stirring unit 51. Then, by providing the protrusion 55 on the outer periphery of the stirring unit 51, this shearing force and centrifugal force can be strengthened. Further, by alternately arranging the through holes 53 and the protrusions 55 on the circumference, the formation of the circulation flow is further promoted.

  The relationship between the rotor 5 and the inner chamber 21 is preferably 0.70 <d / D <0.97 between the outer diameter d of the stirring unit 51 and the diameter D of the inner chamber 21. By setting it as this range, while being able to make generation | occurrence | production of a circulating flow favorable, a grinding | pulverization process and a dispersion | distribution process can be made effective. Further, it is preferable that the relationship of 0, 7 <w / L <0, 9 is established between the width w of the stirring unit 51 and the length L of the inner chamber 21. By setting it as this range, while being able to make generation | occurrence | production of a circulating flow favorable, a grinding | pulverization process and a dispersion | distribution process can be made effective.

  By adopting the shape as described above, the processed material and the media around the stirring unit 51 generate a circulating flow as shown by arrows in FIG. 5 on both sides divided by the holding unit 52. Become. That is, this circulating flow flows from the inside to the outside in the through-hole 53, flows from the center of the container to the end at the outside of the stirring unit 51, and flows from the outside to the inside at the end of the stirring unit 51. In the agitation part 51, it flows from the end part toward the holding part.

  The inside of the stirring unit 51 is preferably held in a well-mixed state, and an opening 54 is preferably provided in the holding unit 52 so as not to be separated by the holding unit 52. The opening 54 preferably has an angle θ2 as shown in FIG. 3 when viewed in the section EE in FIG. Depending on the direction of the angle θ2, the flow of the processed material and the medium can be promoted from one side of the inner chamber 21 to the other side, or can be promoted from the other side to the one side. Then, by alternately changing the flow direction of the plurality of openings 54, it is possible to eliminate the distinction on both sides and make the entire mixture uniform.

  By forming the inner chamber 21 and the rotor 5 as described above, good pulverization processing and dispersion processing are performed in the inner chamber 21. That is, a large shearing force is generated by giving a large speed difference between the media between the inner wall of the separator 3 and the outer periphery of the stirring portion 51 of the rotor 5. At the same time, a circulating flow is generated on both sides of the stirring unit 51. The direction of the flow by the circulating flow is a direction orthogonal to the direction of the flow by the rotation of the rotor 5. For this reason, the media cannot move together with the stirring unit 51, and the co-rotation phenomenon is eliminated.

  In the media stirring type wet disperser 1 of the present invention, when the processed material is supplied into the container 2 from the supply port 6 and the rotor 5 is rotated, the processed material is stirred together with the media located in the inner chamber 21, A grinding process and a dispersion process are received. Then, the fluid flows outward from the center of the container 2, the media is separated by the slit 31 of the separator 3, and is discharged from the outer chamber 22 to the outside of the grinding container 2 through the discharge port 7.

  In the vicinity of the peripheral surface of the inner chamber 21, high-efficiency pulverization processing and dispersion processing can be performed by a strong shearing force between the media. At the same time, the elimination of co-rotation slows the flow rate of media in the vicinity of the separator, thereby preventing the separator and the like from being worn. Further, in the vicinity of the center of the inner chamber 21, the processed product and the medium can be kept in a uniform mixed state and processed without causing a short circuit of the processed product. Therefore, it is possible to perform processing utilizing the entire inner chamber 21.

  The media stirring type wet disperser 1 of the present invention can be used in a wide range of fields such as printer ink, paint, polymerized toner, color resist, ceramic fine particles, titanium oxide, metal powder, and pharmaceuticals. That is, these are slurry-like treatment liquids containing inorganic fine particles, organic fine particles, inorganic-organic composite fine particles, or a mixture thereof.

  The amount of media filled in the inner chamber 21 is also related to the occurrence of co-rotation. That is, when it is assumed that the medium to be filled is packed in a ring shape around the stirring unit 51, 0.5 <L / A <2 between the thickness A and the length L of the ring. It is preferable that By setting this range, it is possible to prevent the occurrence of co-rotation and to make the pulverization process and the dispersion process effective.

It is a schematic sectional drawing which shows an example of implementation of the media stirring type wet disperser of this invention. It is a schematic sectional drawing of the rotor shown in FIG. It is the schematic which shows the EE cross section of FIG. It is the schematic which shows the edge part of an inner side chamber. It is explanatory drawing which shows the flow of a circulating flow. It is explanatory drawing which shows the filling state of a medium. It is a schematic sectional drawing which shows the conventional media stirring type wet disperser.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1,101 Media stirring type wet disperser 2,102 Container 3,103 Separator 4,104 Rotating shaft 5,105 Rotor 6,106 Supply port 7,107 Discharge port 8 Seal member 21,121 Inner chamber 22,122 Outer chamber 31 131 Slit 51 Stirring section 52 Holding section 53 Through hole 54 Opening 55 Projection

Claims (10)

A cylindrical container, a cylindrical separator in which the inside of the container is radially divided into an inner chamber and an outer chamber and a plurality of slits communicating between the chambers are formed, and one end of the container is inserted and rotated. A rotating shaft that is freely provided, a rotor that is fixed to the rotating shaft and rotates, a supply port for a processed material that is provided at the other end of the vessel and communicates with the inside and outside of the vessel, and that is provided on the outer periphery of the vessel. In a media agitation type wet disperser equipped with a discharge port for the processed material communicating between the outside and the outside of the room,
The rotor includes a cylindrical stirring unit and a disc-shaped holding unit,
The stirring portion, a plurality of through-holes communicating the internal and external to both sides of which are bisected by said holding unit, together with both sides of generating a circulation flow to circulate in and out of the stirring portion,
The media agitation type wet disperser characterized in that the holding part is provided with an opening so as to eliminate the distinction between both sides and to make the whole in a uniform mixed state . 2. The media stirring type wet disperser according to claim 1, wherein the inner chamber has a cylindrical shape, and a relationship of Formula 1 exists between a length L and a diameter D between both ends.
0.3 <L / D <1 ... Formula 1 The both end portions of the inner chamber are formed so as to gradually decrease in diameter from a predetermined inward position toward the end, have a cross-sectional curved shape with a radius of curvature R, and have a relationship of Formula 2. The media agitation type wet disperser described in 1.
L / 30 <R <L / 3 ... Formula 2 Media-agitation type wet disperser according to any one of claims 1 to 3, characterized in that there is a relationship of Formula 3 between the diameter D and the outer diameter d of the stirring portion.
0.70 <d / D <0.97 ... Formula 3 Media-agitation type wet disperser according to any one of claims 1 to 4, characterized in that there is a relationship of formula 4 between the width w and the length L of the agitating portion.
0.7 <w / L <0.9 …… Formula 4 The through hole is, according to any one of claims 1 to 5 direction toward the outer peripheral surface from the inner peripheral surface of the stirring portion and being inclined in a direction to retreat with respect to the rotational direction Media agitation type wet disperser. The stirring unit, media-agitation type wet disperser according to any one of claims 1 to 6, characterized in that it comprises a projection on the outer peripheral surface. The holding portion, media-agitation type wet disperser according to any one of claims 1 to 7, characterized in that provided at the center of the stirring portion. Inorganic fine particles, organic fine particles, in a distributed method of slurry treatment liquid containing an inorganic-organic composite particles or mixtures thereof, and characterized by using a media-agitation type wet disperser according to any one of claims 1 to 8 To disperse fine particles. When it is assumed that the medium to be filled in the container is closely packed in a ring shape around the stirring portion, there is a relationship of Equation 5 between the thickness A of the ring and the length L. The method for dispersing fine particles according to claim 9 .
0.5 <L / A <2 ... Formula 5

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