JP2007283631A - Liquid discharge head - Google Patents

Liquid discharge head Download PDF

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Publication number
JP2007283631A
JP2007283631A JP2006113318A JP2006113318A JP2007283631A JP 2007283631 A JP2007283631 A JP 2007283631A JP 2006113318 A JP2006113318 A JP 2006113318A JP 2006113318 A JP2006113318 A JP 2006113318A JP 2007283631 A JP2007283631 A JP 2007283631A
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adhesive
light
irradiated
liquid discharge
transferred
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Hiroyuki Yamamoto
裕之 山本
Masami Kasamoto
雅己 笠本
Teruo Ozaki
照夫 尾崎
Toshio Kashino
俊雄 樫野
Shuji Koyama
修司 小山
Junichiro Iri
潤一郎 井利
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Canon Inc
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Canon Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a liquid discharge head for bonding an orifice plate to a head body with an adhesive, wherein an adhesive is prevented from flowing into a head flow path and ink resistant reliability is achieved as well. <P>SOLUTION: The liquid discharge head is provided in which a UV-curable adhesive is transferred on a head body and an orifice plate is bonded thereto, wherein the adhesive is previously irradiated with trace amounts of UV rays before transferring and irradiated so as to have a partially different exposure dose of the UV rays, and the adhesive is prevented from flowing and adherence reliability is also achieved by firstly irradiating an entire region of the adhesive to be transferred with UV rays, and secondly partially irradiating the resulting adhesive with UV rays. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は複写機、ファクシミリ、ワープロ、ホストコンピューター等の出力用端末としてのプリンタ、ビデオプリンタ等に用いられるインクジェット記録ヘッドに関する。特に、インク吐出エネルギーとして熱エネルギーを発生する発熱体(電気熱変換素子) を形成した基板を有し、記録用のインクを飛翔液滴として吐出口(オリフィス)から吐出させて、記録媒体に付着させることによって記録を行う液体吐出ヘッドに関する。   The present invention relates to an ink jet recording head used in printers, video printers, and the like as output terminals of copying machines, facsimiles, word processors, host computers and the like. In particular, it has a substrate on which a heating element (electrothermal conversion element) that generates thermal energy as ink ejection energy is formed, and ink for recording is ejected as a flying droplet from an ejection port (orifice) and adheres to the recording medium. It is related with the liquid discharge head which records by making it.

尚、本発明における「記録」とは、文字や図形等の意味を持つ画像を被記録媒体に形成することだけでなく、意味を持たないパターン等の画像を形成することも含む。   Note that “recording” in the present invention includes not only forming an image having a meaning such as a character or a figure on a recording medium but also forming an image such as a pattern having no meaning.

従来、液体吐出ヘッドを用いて記録を行う方法は、ノンインパクト記録であり、騒音が小さく、高密度化、高速印字が可能であること、保守が比較的簡単でメンテナンスフリーになり得るなどの理由から、近年、多用されている。   Conventionally, the method of recording using a liquid discharge head is non-impact recording, with low noise, high density, high-speed printing possible, maintenance is relatively easy and can be maintenance-free, etc. In recent years, it has been widely used.

従来のこの種の液体吐出ヘッドの一例について図7を参照して説明する。   An example of this type of conventional liquid discharge head will be described with reference to FIG.

図7に示す液体吐出ヘッドは、インクを吐出するためのエネルギーを発生するエネルギー発生素子である発熱素子1005とインク流路1006を構成する溝が複数個並列に設けられた基板1001と、 インク供給口が形成された天板1002と、これら基板1001及び天板1002の端面と接合され、インクを吐出するためのオリフィス1012が上記液流路1006と連通する位置に形成されたオリフィスプレート1004とを有する。   The liquid discharge head shown in FIG. 7 includes a heating element 1005 that is an energy generation element that generates energy for discharging ink, a substrate 1001 in which a plurality of grooves constituting the ink flow path 1006 are provided in parallel, and ink supply A top plate 1002 having a mouth, and an orifice plate 1004 formed at a position where the orifice 1012 for ejecting ink is connected to the liquid channel 1006 are bonded to the end surfaces of the substrate 1001 and the top plate 1002. Have.

オリフィスプレートは1004に形成されるオリフィス1012は非常に微細なものであり、このオリフィス1012が液体吐出ヘッドの吐出特性を左右する重要な要素の一つとなっている。すなわち、液体吐出ヘッドのオリフィスプレート1004は、微細なオリフィス1012が形成されることから加工性に優れ、また、インクに直接接触するものであるから耐インク性がよいことが必要とされる。   The orifice 1012 formed in the orifice plate 1004 is very fine, and the orifice 1012 is one of the important factors that influence the ejection characteristics of the liquid ejection head. That is, the orifice plate 1004 of the liquid ejection head is excellent in workability because the fine orifice 1012 is formed, and needs to have good ink resistance because it is in direct contact with ink.

このオリフィスプレートとヘッド本体の接合は接着剤を用いて行われる。接着剤としては熱硬化型又はUV硬化型又は熱、UV併用硬化型の接着剤が用いられ、オリフィスプレートあるいはヘッド本体に接着剤を転写し、お互いを貼り合せた後、熱を加えて又はUV光を照射して接着剤を硬化させ、接合を完了させるものである。   The orifice plate and the head body are joined using an adhesive. As the adhesive, a thermosetting type, UV curable type, heat, or UV combined type curable adhesive is used. After the adhesive is transferred to the orifice plate or the head body and bonded together, heat is applied or UV is applied. The adhesive is cured by irradiating light to complete the bonding.

又、別の従来例としては、特許文献1をあげることが出来る。
特開2003-237073号公報
As another conventional example, Patent Document 1 can be cited.
JP 2003-237073 A

しかしながら、従来の液体吐出ヘッドには以下に示す問題点があった。   However, the conventional liquid discharge head has the following problems.

オリフィスプレートあるいはヘッド本体に接着剤を転写し、貼り合せた際、転写されていた接着剤がヘッド本体の流路壁のエッジを伝わり流路内へ流れ込んでしまう。流れ込んだ接着剤は流路壁後端に溜まってマッチ棒の様な形状になり、さらには流路を塞いでしまい吐出に影響を与える。また、ヒーター表面に接着剤が流れ込むとヒーターの熱が逃げにくくなり、ヒーターの耐久寿命に影響を与える。また、ヒーター上に可動部材がある場合にはヒーターと可動部材の隙間を接着剤で埋めてしまい、ヒーター及び可動部材が機能しなくなり、良好な吐出が行えなくなってしまう。   When the adhesive is transferred to the orifice plate or the head main body and bonded, the transferred adhesive flows along the edge of the flow path wall of the head main body and flows into the flow path. The adhesive that has flowed in accumulates at the rear end of the flow path wall and has a shape like a match rod, and further blocks the flow path and affects the discharge. In addition, when the adhesive flows into the heater surface, it is difficult for the heat of the heater to escape, which affects the durable life of the heater. In addition, when there is a movable member on the heater, the gap between the heater and the movable member is filled with an adhesive, and the heater and the movable member do not function, and good discharge cannot be performed.

接着剤の粘度を変えることにより流動性を悪化させ、接着剤の流れ込みを防ぐ方法もあるが、粘度を高めると、接着剤自体の薄膜化が困難であり、厚膜の接着剤を転写することになってしまい、多量に接着剤が流路先端に入り込んでしまい、これも良好な吐出が行えなくなってしまう。   There is a method to prevent the adhesive from flowing by changing the viscosity of the adhesive, but if the viscosity is increased, it is difficult to reduce the thickness of the adhesive itself. As a result, a large amount of the adhesive enters the front end of the flow path, and this also makes it impossible to perform good discharge.

UV硬化型又はUV、熱併用硬化型の接着剤を用い、あらかじめUV光を接着剤全面に照射させ硬化反応を開始させることで流動性を悪化させてから転写し、貼り合せる方法においては、接着信頼性(耐インク性)が低下してしまい、インクがオリフィスプレートとヘッド本体の接着剤界面に染み出して混色したり、吐出に影響をおよぼしたりする。UV光の照射量を制御しても、接着剤の流路内への入り込みを無くすことと接着信頼性を確保することの両立は困難であった。また、UV光を照射する部分としない部分を作り、転写する方法においてはUV光を照射しない部分が存在すると、流路内への接着剤の入り込みが発生し、吐出に影響を与えてしまう。   In the method of using UV curing type or UV, heat combined curing type adhesive, transferring the light after deteriorating the fluidity by irradiating the entire surface with UV light and starting the curing reaction, bonding The reliability (ink resistance) is lowered, and the ink oozes out to the adhesive interface between the orifice plate and the head main body and mixes colors or affects ejection. Even if the irradiation amount of UV light was controlled, it was difficult to achieve both the elimination of the adhesive entering the flow path and the securing of the adhesive reliability. In addition, if there is a portion that does not irradiate with UV light in the method of transferring and creating a portion that does not irradiate with UV light, the adhesive will enter the flow path and affect the ejection.

そこで本発明はオリフィスプレートとヘッド本体を接着剤にて貼り合せ、硬化させる際に流路内へ多量に流れ込む接着剤に起因する吐出不良及び、接着信頼性を確保した液体吐出ヘッドを提供することを目的とする。   Accordingly, the present invention provides a liquid ejection head that ensures ejection failure and adhesion reliability due to an adhesive that flows in a large amount into a flow path when an orifice plate and a head body are bonded together and cured. With the goal.

インクを吐出させるために利用されるエネルギーを発生するエネルギー素子を備え、互いに平行に配列された複数のインク流路が端面に開口するヘッド本体と各インク流路に対応する部位にそれぞれ各インク流路と連通するオリフィスを有するオリフィスプレートをヘッド本体にUV硬化型又は熱、UV併用硬化型接着剤を転写した後、貼り合せる液体吐出ヘッドにおいて、UV光を照射した照射量が異なる部分が存在する接着剤を転写し、貼り合せることを特徴とする。   Each of the ink flow paths includes an energy element that generates energy used for ejecting ink, and a plurality of ink flow paths arranged in parallel to each other at a head body that opens at an end surface and a portion corresponding to each ink flow path. In the liquid discharge head to be bonded after transferring the UV curable adhesive or heat and UV combined curable adhesive to the head body with an orifice plate that has an orifice communicating with the path, there are parts with different irradiation amounts irradiated with UV light The adhesive is transferred and bonded.

(作用)
接着剤に対し微量なUV光を照射した部分と極微量なUV光を照射した部分を作り出し、その後転写し、貼り合せる。転写される接着剤の全領域にUV光が照射されているため接着剤の流動性が悪くなり、流路内への多量な接着剤の入り込みを防ぐことができる。接着剤全域に超微量なUV光を照射し、転写したものと比べ、微量なUV光を照射した部分も存在するため、この部分が超微量なUV光を照射した部分の接着剤の流動をある程度、ブロックしてくれる。また、超微量なUV光を照射した部分が存在するため、接着剤の接着性を保持したまま、貼り合わせることができる。これにより、接着剤の流路内への多量な入り込みを防ぐとともに、接着信頼性も確保できる。
(Function)
Create a part irradiated with a minute amount of UV light and a part irradiated with a minute amount of UV light on the adhesive, and then transfer and paste them together. Since UV light is irradiated to the entire area of the adhesive to be transferred, the fluidity of the adhesive is deteriorated, and a large amount of adhesive can be prevented from entering the flow path. Compared to the part that was irradiated with a very small amount of UV light and transferred to the entire area of the adhesive, there is also a part that was irradiated with a very small amount of UV light. Will block to some extent. In addition, since there is a portion irradiated with an extremely small amount of UV light, it can be bonded while maintaining the adhesiveness of the adhesive. As a result, a large amount of adhesive can be prevented from entering the flow path, and adhesion reliability can be ensured.

本発明はオリフィスプレートとヘッド本体を接合する際の接着剤にあらかじめUV光を照射し、その後、転写するものである。UV光照射を2段階に分けることで、照射量が異なる部分が存在する接着剤を作り出すことができる。UV光を全領域に照射しているため接着剤の流動性が改善される。そのため、接着剤の多量な流路内への流れ込みを防ぐことができ、良好な吐出が行え、液体吐出ヘッドの歩留りを大幅に改善することができた。また、接着剤にはUV光を極微量照射している部分が存在するため、接着信頼性(耐インク性)も確保でき、接着剤界面へのインクの染み出しによる混色、インク漏れ等も防ぐことができた。   In the present invention, UV light is preliminarily applied to an adhesive for joining an orifice plate and a head body, and then transferred. By dividing the UV light irradiation into two stages, it is possible to create an adhesive with parts with different irradiation amounts. Since the entire area is irradiated with UV light, the fluidity of the adhesive is improved. Therefore, it was possible to prevent a large amount of adhesive from flowing into the flow path, perform good discharge, and greatly improve the yield of the liquid discharge head. In addition, since there is a part where the UV light is irradiated in the adhesive agent, adhesion reliability (ink resistance) can be secured, and color mixing and ink leakage due to ink seepage from the adhesive interface are prevented. I was able to.

次に、本発明の詳細を実施例の記述に従って説明する。   Next, details of the present invention will be described in accordance with the description of the embodiments.

本実施の形態は図1に示すように、液体を吐出させるためのエネルギー素子を備えた基板(11)上に感光性樹脂をパターニングして流路壁、液室枠を形成した。流路壁上方にインク供給口及び流路の一部を形成する天板(12)を接着剤により接合しヘッド本体(13)を形成させた。   In the present embodiment, as shown in FIG. 1, a photosensitive resin is patterned on a substrate (11) provided with an energy element for discharging a liquid to form a flow path wall and a liquid chamber frame. A head body (13) was formed by bonding an ink supply port and a top plate (12) forming a part of the flow path above the flow path wall with an adhesive.

オリフィスプレート(15)には加工性、耐インク性の観点から、ポリサルフォンを用いレーザー加工にてオリフィス(14)を形成した。また、ヘッド本体との接合時に接着剤がオリフィス内へ流れ込むことを防止するためにオリフィスプレート接合面に突起(16)を設けた。この突起もレーザー加工にて形成させた。   From the viewpoint of processability and ink resistance, the orifice plate (15) was formed with an orifice (14) by laser processing using polysulfone. Further, in order to prevent the adhesive from flowing into the orifice at the time of joining to the head body, a projection (16) is provided on the orifice plate joining surface. These protrusions were also formed by laser processing.

接着剤はUV、熱併用硬化型のカチオン重合型エポキシ接着剤を用いた。UV硬化型の接着剤を完全硬化するためにはオリフィスプレートとヘッド本体を貼り合せた後、オリフィスを通して多量のUV光を照射しなくてはならない。これは、オリフィス周囲に塗布してある撥水剤に悪影響を及ぼすため今回はUV、熱併用硬化型の接着剤を用いた。   As the adhesive, a UV / heat combination curing type cationic polymerization type epoxy adhesive was used. In order to completely cure the UV curable adhesive, it is necessary to irradiate a large amount of UV light through the orifice after the orifice plate and the head body are bonded together. Since this has an adverse effect on the water repellent applied around the orifice, this time, UV and heat curing type adhesive was used.

図2は接着剤の薄膜形成方法を示す。Siウェハー(21)上にPETフィルム(22)をラミネートし、接着剤(23)をPETフィルム上に約10g塗布し、スピンコーターにて5000rpm、300〜400Sec回転させPETフィルム上に厚さは約3μmの接着剤を形成させた。   FIG. 2 shows a method for forming an adhesive thin film. The PET film (22) is laminated on the Si wafer (21), and about 10 g of the adhesive (23) is applied on the PET film. The spin coater is rotated at 5000 rpm for 300 to 400 sec, and the thickness is about A 3 μm adhesive was formed.

図4は今回用いたフォトマスクを示す。フォトマスクの下側半分は全領域にUV光が照射されるようにし、上側半分は部分的にUV光が照射されるようにした。UV光が照射されない部分をUV光が照射される部分で囲む様にし、さらに、UV光が照射されない一つ一つの大きさを5×5μmと極力小さくした。また、規則的かつヘッド本体の転写領域よりも大きい領域のマスクパターンにすることでUV照射後の接着剤とヘッド本体の精度良い転写位置決めを不要にしてある。   FIG. 4 shows the photomask used this time. The lower half of the photomask was irradiated with UV light over the entire area, and the upper half was partially irradiated with UV light. The portion not irradiated with UV light was surrounded by the portion irradiated with UV light, and each size not irradiated with UV light was made as small as 5 × 5 μm. Further, by using a mask pattern in a regular and larger area than the transfer area of the head main body, accurate transfer positioning of the adhesive after UV irradiation and the head main body is unnecessary.

次に図3に示すようにPET上接着剤にUV光を照射させた。まず、スピンコートした接着剤付PETフィルムをエキスパンドし、固定する。次に、接着剤面とは逆面のPETフィルム側にUV光を部分的にカットするフォトマスク(33)を押し付け、密着させ、フォトマスク越しにUV光を照射させた。UV光は照射領域の照射強度が均一になるようにUVファイバー(31)先端に集光レンズ(32)を取り付け、照射強度15mW/cm2、時間5〜10Secの条件で照射させた。   Next, UV light was irradiated to the adhesive on PET as shown in FIG. First, the PET coated adhesive film is expanded and fixed. Next, a photomask (33) that partially cuts UV light was pressed against and adhered to the PET film side opposite to the adhesive surface, and UV light was irradiated through the photomask. A condenser lens (32) was attached to the tip of the UV fiber (31) so that the irradiation intensity in the irradiation area was uniform, and the UV light was irradiated under the conditions of an irradiation intensity of 15 mW / cm 2 and a time of 5 to 10 Sec.

照射が完了したら、一度フォトマスクを上昇させPETフィルムとの密着を解除する。図5のようにPETフィルムをフォトマスクの半分の距離だけスライドさせ、再び、フォトマスクを下降させ、PETフィルムと密着させる。その後、2度目のUV光を照射させ、UV照射を完了させた。1度目に転写全領域に対しUV光を照射させ、2度目に部分的にUV光を照射させることで、転写全領域にUV光を照射させ、かつ照射量の異なる部分が存在する接着剤を作り出すことができた。   When the irradiation is completed, the photomask is once lifted to release contact with the PET film. As shown in FIG. 5, the PET film is slid by half the distance of the photomask, the photomask is lowered again, and is brought into close contact with the PET film. Thereafter, the second UV light was irradiated to complete the UV irradiation. By irradiating UV light to the entire transfer area at the first time and partially irradiating UV light at the second time, the entire area of the transfer is irradiated with UV light, and an adhesive having a portion with a different irradiation amount is present. I was able to produce it.

その後、フォトマスクを上昇させ、接着剤付PETフィルム(34)をヘッド本体の接着剤転写部に移動させ下降させる。下降ポイントはヘッド本体と接着剤の距離約1mmになるようにした。   Thereafter, the photomask is raised, and the PET film with adhesive (34) is moved to the adhesive transfer portion of the head body and lowered. The descending point was set so that the distance between the head body and the adhesive was about 1 mm.

図6に示すようにゴムローラー(51)をPETフィルム上に荷重約300gf、スピード約10mm/Secの条件にて回転させた。そして、PETフィルムを上昇させヘッド本体から剥し、接着剤の転写を完成させた。ヘッド本体に転写された接着剤の厚さはPET上にスピンコートされた厚みの約半分である1.5μmである。   As shown in FIG. 6, the rubber roller (51) was rotated on the PET film under the conditions of a load of about 300 gf and a speed of about 10 mm / Sec. Then, the PET film was raised and peeled off from the head body to complete the transfer of the adhesive. The thickness of the adhesive transferred to the head body is 1.5 μm, which is about half of the thickness spin-coated on PET.

接着剤が転写されたヘッド本体とオリフィスプレート所定の位置関係で接触させ、その後、約3Kgfの荷重で圧着する。最後にエポキシ接着剤の硬化を加速させるため、圧着状態を保ったまま120℃で1時間以上加熱しキュアを行い接合を完了させた。   The head main body to which the adhesive is transferred is brought into contact with the orifice plate in a predetermined positional relationship, and thereafter, the pressure bonding is performed with a load of about 3 kgf. Finally, in order to accelerate the curing of the epoxy adhesive, it was cured by heating at 120 ° C. for 1 hour or more while maintaining the pressure-bonded state to complete the joining.

本発明の実施例のインクジェットヘッドの構成概略図。1 is a schematic configuration diagram of an inkjet head according to an embodiment of the present invention. 本発明の実施例の接着剤の薄膜形成概略図。The thin film formation schematic of the adhesive agent of the Example of this invention. 本発明の実施例の接着剤にUV光を照射する概略図。Schematic which irradiates UV light to the adhesive agent of the Example of this invention. 本発明の実施例の接着剤に部分的にUV光を照射するフォトマスク概略図。The photomask schematic diagram which irradiates UV light partially to the adhesive agent of the Example of this invention. 本発明の実施例の2段階UV光照射方法概略図。1 is a schematic diagram of a two-stage UV light irradiation method according to an embodiment of the present invention. 本発明の実施例のヘッド本体に接着剤を転写する概略図。Schematic which transfers an adhesive agent to the head main body of the Example of this invention. 従来のインクジェットヘッドの構成概略図。1 is a schematic diagram of a configuration of a conventional inkjet head.

符号の説明Explanation of symbols

11 Si基板
12 天板
13 ヘッド本体
14 オリフィス
15 オリフィスプレート
16 オリフィスプレート凸部
21 Siウェハー
22 PETフィルム
23 接着剤
31 UV光ファイバー
32 集光レンズ
33 フォトマスク
34 接着剤付PETフィルム
51 転写ローラー
11 Si substrate
12 Top plate
13 Head body
14 Orifice
15 Orifice plate
16 Orifice plate convex
21 Si wafer
22 PET film
23 Adhesive
31 UV optical fiber
32 condenser lens
33 Photomask
34 PET film with adhesive
51 Transfer roller

Claims (6)

インクを吐出させるために利用されるエネルギーを発生するエネルギー素子を備え、互いに平行に配列された複数のインク流路が端面に開口するヘッド本体と各インク流路に対応する部位にそれぞれ各インク流路と連通するオリフィスを有するオリフィスプレートをヘッド本体にUV硬化型あるいは、熱、UV併用硬化型接着剤を用い、接着剤にあらかじめ微量なUV光を照射してから転写し、貼り合せる液体吐出ヘッドにおいてUV光を照射した照射量が異なる部分が存在する接着剤を転写し、貼り合せることを特徴とする液体吐出ヘッド。   Each of the ink flow paths includes an energy element that generates energy used for ejecting ink, and a plurality of ink flow paths arranged in parallel to each other at a head body that opens at an end surface and a portion corresponding to each ink flow path. A liquid discharge head that uses a UV curable adhesive or a combination of heat and UV curable adhesive for the head body with an orifice plate that has an orifice that communicates with the path. The liquid discharge head is characterized by transferring and bonding the adhesive in which the portions irradiated with UV light are different from each other. 第一に、転写される接着剤の全領域にUV光を照射し、第二に、転写される接着剤の一部にUV光を照射した接着剤を転写することを特徴とする請求口1に記載の液体吐出ヘッド。   First, the entire area of the transferred adhesive is irradiated with UV light, and secondly, the adhesive irradiated with UV light is transferred to a part of the transferred adhesive. The liquid discharge head described in 1. 第一に、転写される接着剤の一部にUV光を照射し、第二に、転写される接着剤の全領域にUV光を照射した接着剤を転写することを特徴とする請求口1に記載の液体吐出ヘッド。 First, UV light is irradiated to a part of the transferred adhesive, and secondly, the adhesive irradiated with UV light is transferred to the entire area of the transferred adhesive. The liquid discharge head described in 1. 転写される接着剤の面積のうち、より多くUV光を照射した部分の接着剤面積がより少なくUV光を照射した部分の接着剤面積より多い、又は少ない、又は等しい接着剤を転写することを特徴とする請求項1に記載の液体吐出ヘッド。   Of the adhesive area to be transferred, the adhesive area of the part irradiated with more UV light is less, and the adhesive area of the part irradiated with UV light is larger, smaller or equal to the adhesive area. The liquid discharge head according to claim 1, wherein the liquid discharge head is a liquid discharge head. 転写される接着剤においてUV光を照射した照射量の異なる部分が規則的に配置されている接着剤を転写することを特徴とする請求項1〜請求項4のいずれかに記載の液体吐出ヘッド。   5. The liquid discharge head according to claim 1, wherein an adhesive in which portions having different irradiation amounts irradiated with UV light are regularly arranged in the transferred adhesive is transferred. . より少ないUV光を照射した部分の周りを全てより多くUV光を照射した部分で囲んでいる接着剤を転写することを特徴とする請求項1〜請求項5のいずれかに記載の液体吐出ヘッド。   6. The liquid discharge head according to claim 1, wherein the adhesive surrounding the portion irradiated with less UV light is surrounded by the portion irradiated with more UV light. .
JP2006113318A 2006-04-17 2006-04-17 Liquid discharge head Withdrawn JP2007283631A (en)

Priority Applications (1)

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Family

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Country Link
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