JP2007283192A - Method and apparatus for deodorizing biomass - Google Patents
Method and apparatus for deodorizing biomass Download PDFInfo
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- JP2007283192A JP2007283192A JP2006112222A JP2006112222A JP2007283192A JP 2007283192 A JP2007283192 A JP 2007283192A JP 2006112222 A JP2006112222 A JP 2006112222A JP 2006112222 A JP2006112222 A JP 2006112222A JP 2007283192 A JP2007283192 A JP 2007283192A
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- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000002028 Biomass Substances 0.000 title abstract 3
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- 239000010865 sewage Substances 0.000 claims abstract description 50
- 239000007789 gas Substances 0.000 claims abstract description 45
- 239000008235 industrial water Substances 0.000 claims abstract description 45
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims abstract description 38
- 239000000945 filler Substances 0.000 claims abstract description 14
- 238000005507 spraying Methods 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- 238000004332 deodorization Methods 0.000 claims description 64
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- 235000020679 tap water Nutrition 0.000 claims description 39
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 35
- 229910052698 phosphorus Inorganic materials 0.000 claims description 35
- 239000011574 phosphorus Substances 0.000 claims description 35
- 239000000126 substance Substances 0.000 claims description 14
- 235000015097 nutrients Nutrition 0.000 claims description 10
- 238000012545 processing Methods 0.000 claims description 3
- 238000005259 measurement Methods 0.000 claims 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract description 4
- 239000007921 spray Substances 0.000 abstract 3
- 230000035764 nutrition Effects 0.000 abstract 1
- 235000016709 nutrition Nutrition 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 42
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 28
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 28
- 229910052757 nitrogen Inorganic materials 0.000 description 21
- 235000019645 odor Nutrition 0.000 description 18
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 14
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- 229920002451 polyvinyl alcohol Polymers 0.000 description 9
- 239000010801 sewage sludge Substances 0.000 description 7
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- 238000010586 diagram Methods 0.000 description 6
- 244000005700 microbiome Species 0.000 description 5
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 3
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000009287 sand filtration Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 230000006978 adaptation Effects 0.000 description 2
- 238000005273 aeration Methods 0.000 description 2
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 229930182556 Polyacetal Natural products 0.000 description 1
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003621 irrigation water Substances 0.000 description 1
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- 238000012544 monitoring process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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Abstract
Description
本発明は、臭気ガスの生物学的脱臭方法及び装置に係り、特に下水処理場から発生する臭気ガスを生物学的に脱臭する方法及び装置に関する。 The present invention relates to a method and apparatus for biological deodorization of odor gas, and more particularly to a method and apparatus for biological deodorization of odor gas generated from a sewage treatment plant.
微生物を付着させた担体を充填した充填層に、臭気ガスを通気して生物学的に脱臭する充填塔式生物脱臭法は、低ランニングコストで維持管理性が良いことが評価され、硫黄系悪臭物質を含む臭気が発生する下水処理場等で、脱臭対策における中心的役割を担っている。
充填塔式生物脱臭法においては、充填材に生物を馴養するために、散水用水が必要となる。従来、散水用水には、下水二次処理水や下水二次処理水の砂ろ過水を用いて、有効利用を図ったり（特許文献１）、下水処理施設内の工業用水（工水）や水道水を用いていた（特許文献２）。
ここで、下水二次処理水とは、下水を生物処理（二次処理）した水で、最終沈殿池を流出した水をいう。また、工業用水とは、工業用水道又は水道から調達する用水のことであり、一般的な使用の形態としては、原料用水、洗浄用水、ボイラー用水、冷却用水、調温用水、製品用水などがある（非特許文献１）。
The packed tower type biological deodorization method, in which odor gas is passed through a packed bed packed with a carrier to which microorganisms are attached, for biological deodorization, is evaluated for its low running cost and good maintainability. It plays a central role in deodorizing measures at sewage treatment plants where odors containing substances are generated.
In the packed tower type biological deodorization method, water for sprinkling is required in order to acclimate the organism to the filler. Conventionally, as water for watering, the sewage secondary treated water and the sand filtered water of the sewage secondary treated water are used effectively (Patent Document 1), industrial water (industrial water) or water supply in sewage treatment facilities. Water was used (Patent Document 2).
Here, the sewage secondary treated water refers to water that has been biologically treated (secondary treated) with sewage and has flowed out of the final sedimentation basin. In addition, industrial water refers to industrial water or water procured from tap water, and common usage forms include raw material water, cleaning water, boiler water, cooling water, temperature control water, product water, etc. Yes (Non-Patent Document 1).
しかし、下水二次処理水を散水用水に使用した場合には、浮遊物質（ＳＳ）由来の固形分が多いため、充填層内に蓄積し、担体の有効表面積の減少によって悪臭物質除去性能が低下するばかりでなく、充填層の空隙部分が閉塞してしまう問題があった。一方、砂ろ過水は、ＳＳ由来の固形分は少なく散水用水には適するが、砂ろ過設備を有しない下水処理施設もある。また、使用量に制限があり「脱臭用」に使用できない場合もある。
一方、工業用水や水道水は、ＳＳ分が少ないが、工業用水や水道水中に微生物の増殖に必要なリンや窒素等の栄養塩含量が少ないため、馴致に長期間を要したり、脱臭性能が低下するといった問題がある。また、工業用水や水道水に溶解促進剤を添加する方法もあるが（特許文献３）、ランニングコストや設備費用がかかるという問題がある。
Industrial water and tap water, on the other hand, have a small amount of SS, but because of the low content of nutrient salts such as phosphorus and nitrogen necessary for the growth of microorganisms in industrial water and tap water, it takes a long time to acclimatize or deodorizing performance. There is a problem that decreases. In addition, there is a method of adding a dissolution accelerator to industrial water or tap water (Patent Document 3), but there is a problem that running cost and equipment cost are required.
本発明は、上記従来技術の問題点を解消し、充填層が閉塞せず、かつ、馴致に長期間を要することのない生物脱臭方法及びその装置を提供することを課題とする。 An object of the present invention is to solve the above-mentioned problems of the prior art, and to provide a biological deodorization method and an apparatus therefor in which the packed bed does not block and does not require a long period of acclimatization.
上記課題を解決するために、鋭意研究を重ねた結果、馴致段階で散水用水に下水二次処理水を用い、馴致後は散水用水に工業用水又は水道水からなる水を用いることにより、充填層が閉塞せず、短期間で馴致でき、悪臭物質除去性能も充分に満足できることを見出し、本発明を完成させた。
本発明では、充填材を充填した充填層に、臭気ガスを通気して脱臭を行う生物脱臭方法において、前記充填層に、まず全リン濃度が０．２ｍｇ／Ｌ以上の水を散水させた後、該充填層の圧力損失に基づいて、浮遊物質濃度が１０ｍｇ／Ｌ未満の水に切替えて散水することを特徴とする生物脱臭方法としたものである。
前記脱臭方法において、充填層に散水する水の切替えは、充填層の圧力損失が０．３ｋＰａ以上となった場合に、全リン濃度０．２ｍｇ／Ｌ以上の水から浮遊物質濃度１０ｍｇ／Ｌ未満の水に切替えることができる。
In order to solve the above-mentioned problems, as a result of intensive research, the secondary treatment water was used as the water for sprinkling at the acclimatization stage, and after acclimatization, water consisting of industrial water or tap water was used as the water for sprinkling. The present invention was completed by finding that it was not clogged, could be acclimatized in a short period of time, and sufficiently satisfied the malodorous substance removal performance.
In the present invention, in a biological deodorization method in which odor gas is passed through a packed bed filled with a filler to perform deodorization, water having a total phosphorus concentration of 0.2 mg / L or more is first sprinkled into the packed bed. The biological deodorization method is characterized in that, based on the pressure loss of the packed bed, the water is switched to water having a suspended solid concentration of less than 10 mg / L and sprayed.
In the deodorization method, switching of water sprayed to the packed bed is performed when the pressure loss of the packed bed is 0.3 kPa or more, and the suspended matter concentration is less than 10 mg / L from water having a total phosphorus concentration of 0.2 mg / L or more. Can be switched to water.
また、本発明では、充填材を充填した充填層に、臭気ガスを通気して脱臭を行う生物脱臭方法において、前記充填層に、まず全リン濃度が０．２ｍｇ／Ｌ以上の水を散水させた後、硫化水素濃度除去率に基づいて、浮遊物質濃度が１０ｍｇ／Ｌ未満の水に切替えて散水することを特徴とする生物脱臭方法としたものである。
前記脱臭方法において、全リン濃度が０．２ｍｇ／Ｌ以上の水は、下水二次処理水、又は、工業用水又は水道水に栄養塩を添加して調整した水であり、浮遊物質濃度が１０ｍｇ／Ｌ未満の水は、工業用水又は水道水とすることができる。
Further, in the present invention, in the biological deodorization method in which odor gas is passed through a packed bed filled with a filler to perform deodorization, water having a total phosphorus concentration of 0.2 mg / L or more is first sprinkled into the packed bed. Then, based on the hydrogen sulfide concentration removal rate, the biological deodorization method is characterized in that water is switched to water with a suspended solid concentration of less than 10 mg / L.
In the deodorization method, the water having a total phosphorus concentration of 0.2 mg / L or more is sewage secondary treated water, or water prepared by adding nutrient salt to industrial water or tap water, and the suspended solid concentration is 10 mg. Water less than / L can be industrial water or tap water.
さらに、本発明では、充填材を充填した充填層に、臭気ガスを通気して脱臭を行う生物脱臭装置において、該生物脱臭装置は、該臭気ガスを導入する導入口と、該充填層に散水をするための散水部と、該充填層の圧力損失を測定する圧力センサと、該圧力センサの測定値により、前記散水部に送水する全リン濃度０．２ｍｇ／Ｌ以上の水と浮遊物質濃度１０ｍｇ／Ｌ未満の水を切替える切替手段とを具備することを特徴とする生物脱臭装置としたものである。
前記脱臭装置において、切替手段は、充填層の圧力損失が０．３ｋＰａ以上となった場合に、全リン濃度０．２ｍｇ／Ｌ以上の水から浮遊物質濃度１０ｍｇ／Ｌ未満の水に切替える制御部を具備することができる。
Furthermore, in the present invention, in a biological deodorization apparatus that performs deodorization by aeration of odor gas through a packed bed filled with a filler, the biological deodorization apparatus includes an inlet for introducing the odor gas, and water sprayed into the packed bed. A watering part for measuring the pressure loss of the packed bed, and a measured value of the pressure sensor, the total phosphorous concentration of 0.2 mg / L or more and the suspended solids concentration sent to the watering part The biological deodorizing apparatus is characterized by comprising switching means for switching water of less than 10 mg / L.
In the deodorization apparatus, the switching unit is configured to switch from water having a total phosphorus concentration of 0.2 mg / L or more to water having a suspended substance concentration of less than 10 mg / L when the pressure loss of the packed bed becomes 0.3 kPa or more. Can be provided.
また、本発明では、充填材を充填した充填層に、臭気ガスを通気して脱臭を行う生物脱臭装置において、該生物脱臭装置は、該臭気ガスを導入する導入口と、該充填層に散水をするための散水部と、該臭気がスと処理ガスの硫化水素濃度を測定する硫化水素濃度計と、該硫化水素濃度計の測定値により硫化水素濃度除去率を算出する演算部と、該演算部の算出値により、前記散水部に送水する全リン濃度０．２ｍｇ／Ｌ以上の水と浮遊物質濃度１０ｍｇ／Ｌ未満の水を切替える切替手段とを具備することを特徴とする生物脱臭装置としたものである。
本発明においては、充填層を充填した充填層の圧力損失を測定して、圧力損失の変化傾向を算出し、圧力損失が上昇傾向にある場合に、下水二次処理水から工業用水又は水道水に切替えて散水することができ、その際、工業用水又は水道水に、栄養塩又は下水二次処理水を添加することができ、栄養塩又は下水二次処理水を添加した後のリン酸濃度は０．１ｍｇ／Ｌ以上とすることができる。
Further, in the present invention, in a biological deodorization apparatus that performs deodorization by aeration of odor gas through a packed bed filled with a filler, the biological deodorization apparatus includes an inlet for introducing the odor gas, and water sprayed into the packed bed. A watering unit for measuring the hydrogen sulfide concentration of the treatment gas and the odor, a calculation unit for calculating a hydrogen sulfide concentration removal rate based on the measured value of the hydrogen sulfide concentration meter, A biological deodorizing apparatus comprising switching means for switching between water having a total phosphorus concentration of 0.2 mg / L or higher and water having a suspended solids concentration of less than 10 mg / L to be sent to the watering unit according to a calculated value of the arithmetic unit It is what.
In the present invention, the pressure loss of the packed bed filled with the packed bed is measured, the change tendency of the pressure loss is calculated, and when the pressure loss is increasing, the industrial water or tap water is treated from the secondary sewage treatment water. In this case, nutrient salt or sewage secondary treated water can be added to industrial water or tap water, and phosphoric acid concentration after adding nutrient salt or sewage secondary treated water Can be 0.1 mg / L or more.
本発明により、散水用水を馴致終了後に下水二次処理水から工業用水や水道水に切替えるという極めて簡便な方法により、充填層へのＳＳの閉塞を解消でき、悪臭物質除去性能を充分に満足できる。また、砂ろ過設備がなく下水二次処理水しか得られない下水処理施設においては、調達が容易な工業用水や水道水を利用することができる。 According to the present invention, the clogging of the SS in the packed bed can be eliminated by an extremely simple method of switching from sewage secondary treated water to industrial water or tap water after the irrigation water has been adapted, and the malodorous substance removal performance can be sufficiently satisfied. . In a sewage treatment facility where there is no sand filtration facility and only sewage secondary treated water can be obtained, industrial water and tap water that can be easily procured can be used.
以下に、本発明を図面を参照して詳細に説明する。
図１は、本発明の生物脱臭装置の概略構成図である。
図１において、脱臭塔３は、微生物を担持させるための充填材を充填した充填層４と、充填層４に散水用水を散水するための散水部５と、散水した後の水を排水するための排水管６を備える。充填層に用いる充填材としては、ポリビニルアルコール（ＰＶＡ）、ポリウレタン、ポリスチレン、ポリプロピレン、ポリエチレン又はポリアセタールの発泡成形物、多孔質セラミック、ゼオライト又はピートのような天然材料、破砕炭、成形炭等あるが、特にこれらに限定されない。また、散水用水として、下水二次処理水１０と工業用水又は水道水１１を給水槽７に貯水し、散水部５に送水する。また、下水二次処理水切替バルブ８と工業用水又は水道水切替バルブ９により、給水槽７に送る水を、下水二次処理水１０と工業用水又は水道水１１とを切替えることができる。
Hereinafter, the present invention will be described in detail with reference to the drawings.
FIG. 1 is a schematic configuration diagram of the biological deodorization apparatus of the present invention.
In FIG. 1, a
切替えた後の水は、浮遊物質濃度が１０ｍｇ／Ｌ未満であることが好ましい。１０ｍｇ／Ｌ以上であると、充填層へ浮遊物質の付着し、圧力損失が上昇する。さらに、工業用水又は水道水１０に下水二次処理水９を一部混合することもできる。この場合、下水二次処理水を添加した後の全窒素濃度は０．１ｍｇ/Ｌ以上、全リン濃度は０．２ｍｇ/Ｌ以上であることが好ましい。全リン濃度が０．２ｍｇ/Ｌ以下の場合は、馴致が不十分になったり、馴致期間が極めて長くなる。圧力センサ１２により、充填層の圧力損失を測定する。制御部１３から、圧力損失が０．３ｋＰａ以上となった場合に、下水二次処理水１０から工業用水又は水道水１１に切替えるよう下水二次処理水切替バルブ８を閉じ、工業用水又は水道水切替バルブ９を開くように信号をだす。充填層の圧力損失は、一般には０．０１〜０．２ｋＰａ程度であるが、充填層へのＳＳ分や汚泥の蓄積等により徐々に増え、ある時点より急激に上昇することが知られている。そのため、０．３ｋＰａとなったときが圧力損失が上昇傾向にあるかを知る上での一つの目安となる。
The water after switching preferably has a suspended solid concentration of less than 10 mg / L. When it is 10 mg / L or more, floating substances adhere to the packed bed and pressure loss increases. Furthermore, the sewage secondary treated
図２は、本発明の別の生物脱臭装置の概略構成図である。
図２において、脱臭塔３は、微生物を担持させるための充填材を充填した充填層４と、充填層４に散水用水を散水するための散水部５と、散水した後の水を排水するための排水管６を備える。散水用水として、工業用水又は水道水と下水二次処理水を給水槽７に貯水する。また、栄養塩添加装置１４を備えており、栄養塩添加装置１１から給水槽７に栄養塩を添加する。栄養塩としては、尿素、リン酸カリウム（KH2PO4、K2HPO4）等がある。給水槽７の水を散水部５に送水する。散水用水の水質監視や制御にＳＳ計、全窒素測定計、全リン測定計を用いても良い。また、下水二次処理水切替バルブ８と工業用水又は水道水切替バルブ９により、給水槽７に送る水を、下水二次処理水１０と工業用水又は水道水１１とを切替えることができる。さらに、工業用水又は水道水１０に下水二次処理水９を一部混合することもできる。この場合、下水二次処理水を添加した後の全窒素濃度は０．１ｍｇ/Ｌ以上、全リン濃度は０．２ｍｇ/Ｌ以上であることが好ましい。圧力センサ１２により、充填層の圧力損失を測定する。制御部１３から、圧力損失が０．３ｋＰａ以上となった場合に、下水二次処理水１０から工業用水又は水道水１１に切替えるよう下水二次処理水切替バルブ８を閉じ、工業用水又は水道水切替バルブ９を開くように信号をだす。
FIG. 2 is a schematic configuration diagram of another biological deodorization apparatus of the present invention.
In FIG. 2, the
図３は、本発明の別の生物脱臭装置の概略構成図である。
図３において、脱臭塔３は、微生物を担持させるための充填材を充填した充填層４と、充填層４に散水用水を散水するための散水部５と、散水した後の水を排水するための排水管６を備える。散水用水として、工業用水又は水道水と下水二次処理水を給水槽７に貯水する。給水槽７の水を散水部５に送水する。また、下水二次処理水切替バルブ８と工業用水又は水道水切替バルブ９により、給水槽７に送る水を、下水二次処理水１０と工業用水又は水道水１１とを切替えることができる。この場合、下水二次処理水を添加した後の全窒素濃度は０．１ｍｇ/Ｌ以上、全リン濃度は０．２ｍｇ/Ｌ以上であることが好ましい。原ガス硫化水素濃度計１５及び処理ガス硫化水素濃度計１６により、原ガスと処理ガスの硫化水素濃度を測定する。測定した硫化水素濃度より演算部１７にて硫化水素除去率を算出する。硫化水素除去率に基づいて、下水二次処理水１０から工業用水又は水道水１１に切替えるよう下水二次処理水切替バルブ８を閉じ、工業用水又は水道水切替バルブ９を開くように信号をだす。充填層にＳＳ分が付着し圧力損失が上昇すると、硫化水素除去率が悪くなることが知られており、散水用水を切替えるのは、硫化水素除去率が7０〜９０％以下となったときがよい。
FIG. 3 is a schematic configuration diagram of another biological deodorization apparatus of the present invention.
In FIG. 3, the
以下、本発明を実施例により具体的に説明する。
実施例１
図１に示す脱臭塔３の充填層５にポリビニルアセタール（ＰＶＡ）を充填し、下水汚泥集約処理施設から発生する臭気を、原ガス１として脱臭処理した。運転条件は次のとおりである。
原ガス性状 硫化水素濃度 ：２４ｐｐｍ
メチルメルカプタン濃度 ： ２．０ｐｐｍ
硫化メチル濃度 ： ０．０７９ｐｐｍ
二硫化メチル濃度 ： ０．０３６ｐｐｍ
温度 ：２０℃
空塔速度 ：１８０ｈｒ−１
空塔線速度 ： ０．１１ｍ／ｓｅｃ
Hereinafter, the present invention will be specifically described by way of examples.
Example 1
The packed bed 5 of the
Raw gas properties Hydrogen sulfide concentration: 24ppm
Methyl mercaptan concentration: 2.0ppm
Methyl sulfide concentration: 0.079ppm
Methyl disulfide concentration: 0.036ppm
Temperature: 20 ° C
Superficial velocity: 180 hr -1
Empty line speed: 0.11 m / sec
脱臭処理開始から６０日経過後の脱臭成績を表１に示す。下水二次処理水を３０日間散水したところ、圧力損失が０．３ｋＰａ以上となった。また、このときの硫化水素の除去率は８９％であった。その後、散水用水を工業用水に切替えた。工業用水に切替えてから３０日後の処理ガスの悪臭物質濃度は、硫化水素０．００１ｐｐｍ以下、メチルメルカプタン０．００１ｐｐｍ以下、硫化メチル０．００１ｐｐｍ以下、二硫化メチル０．００１ｐｐｍ以下となった。また、脱臭処理開始より６０日後の圧力損失は０．１６ｋＰａであった。
なお、散水用水のＳＳ濃度、全窒素濃度、全リン濃度を表２に示す。下水二次処理水のＳＳ濃度は１０ｍｇ／Ｌ、全窒素濃度は１３ｍｇ／Ｌ、全リン濃度は２．１ｍｇ／Ｌであった。工業用水のＳＳ濃度は１ｍｇ／Ｌ、全窒素濃度は０．５ｍｇ／Ｌ、全リン濃度は１．０ｍｇ／Ｌであった。
Table 1 shows the deodorization results after 60 days from the start of the deodorization treatment. When the sewage secondary treated water was sprinkled for 30 days, the pressure loss became 0.3 kPa or more. At this time, the removal rate of hydrogen sulfide was 89%. Thereafter, the water for watering was switched to industrial water. The malodorous substance concentration of the treatment gas 30 days after switching to industrial water was 0.001 ppm or less of hydrogen sulfide, 0.001 ppm or less of methyl mercaptan, 0.001 ppm or less of methyl sulfide, and 0.001 ppm or less of methyl disulfide. Moreover, the pressure loss 60 days after the start of the deodorization treatment was 0.16 kPa.
In addition, Table 2 shows SS concentration, total nitrogen concentration, and total phosphorus concentration of water for watering. The SS concentration of sewage secondary treated water was 10 mg / L, the total nitrogen concentration was 13 mg / L, and the total phosphorus concentration was 2.1 mg / L. The SS concentration of industrial water was 1 mg / L, the total nitrogen concentration was 0.5 mg / L, and the total phosphorus concentration was 1.0 mg / L.
実施例２
図１に示す脱臭塔３の充填層５にＰＶＡを充填し、下水汚泥集約処理施設から発生する臭気を原ガス１として、脱臭処理した。運転条件は次のとおりである。
原ガス性状 硫化水素濃度 ：２９ｐｐｍ
メチルメルカプタン濃度 ： １．７ｐｐｍ
硫化メチル濃度 ： ０．０６９ｐｐｍ
二硫化メチル濃度 ： ０．０３９ｐｐｍ
温度 ：２１℃
空塔速度 ：１８０ｈｒ−１
空塔線速度 ： ０．１１ｍ／ｓｅｃ
Example 2
The packed bed 5 of the
Raw gas properties Hydrogen sulfide concentration: 29ppm
Methyl mercaptan concentration: 1.7 ppm
Methyl sulfide concentration: 0.069ppm
Methyl disulfide concentration: 0.039 ppm
Temperature: 21 ° C
Superficial velocity: 180 hr -1
Empty line speed: 0.11 m / sec
脱臭処理開始から６０日経過後の脱臭成績を表１に示す。下水二次処理水を３０日間散水したところ圧力損失が０．３ｋＰａ以上となった。また、このときの硫化水素の除去率は８９％であった。その後、散水用水を水道水に切替えた。上水に切替えてから３０日後の処理ガスの悪臭物質濃度は、硫化水素０．００１ｐｐｍ以下、メチルメルカプタン０．００１ｐｐｍ以下、硫化メチル０．００１ｐｐｍ以下、二硫化メチル０．００１ｐｐｍ以下となった。また、脱臭処理開始より６０日後の圧力損失は０．１５ｋＰａであった。
なお、散水用水のＳＳ濃度、全窒素濃度、全リン濃度を表２に示す。下水二次処理水のＳＳ濃度は１１ｍｇ／Ｌ、全窒素濃度は１２ｍｇ／Ｌ、全リン濃度は２．７ｍｇ／Ｌであった。水道水のＳＳ濃度は１ｍｇ／Ｌ、全窒素濃度は２．０ｍｇ／Ｌ、全リン濃度は０．１ｍｇ／Ｌ以下であった。
Table 1 shows the deodorization results after 60 days from the start of the deodorization treatment. When the sewage secondary treated water was sprinkled for 30 days, the pressure loss became 0.3 kPa or more. At this time, the removal rate of hydrogen sulfide was 89%. Thereafter, the water for watering was switched to tap water. The malodorous substance concentration of the treatment gas 30 days after switching to clean water was 0.001 ppm or less of hydrogen sulfide, 0.001 ppm or less of methyl mercaptan, 0.001 ppm or less of methyl sulfide, and 0.001 ppm or less of methyl disulfide. Moreover, the pressure loss 60 days after the start of the deodorizing treatment was 0.15 kPa.
In addition, Table 2 shows SS concentration, total nitrogen concentration, and total phosphorus concentration of water for watering. The SS concentration of sewage secondary treated water was 11 mg / L, the total nitrogen concentration was 12 mg / L, and the total phosphorus concentration was 2.7 mg / L. The SS concentration of tap water was 1 mg / L, the total nitrogen concentration was 2.0 mg / L, and the total phosphorus concentration was 0.1 mg / L or less.
実施例３
図１に示す脱臭塔３の充填層５にポリビニルアセタール（ＰＶＡ）を充填し、下水汚泥集約処理施設から発生する臭気を、原ガス１として脱臭処理した。運転条件は次のとおりである。
原ガス性状 硫化水素濃度 ：２８ｐｐｍ
メチルメルカプタン濃度 ： ２．５ｐｐｍ
硫化メチル濃度 ： ０．０９０ｐｐｍ
二硫化メチル濃度 ： ０．０３５ｐｐｍ
温度 ：２０℃
空塔速度 ：１８０ｈｒ−１
空塔線速度 ： ０．１１ｍ／ｓｅｃ
Example 3
The packed bed 5 of the
Raw gas properties Hydrogen sulfide concentration: 28ppm
Methyl mercaptan concentration: 2.5ppm
Methyl sulfide concentration: 0.090ppm
Methyl disulfide concentration: 0.035ppm
Temperature: 20 ° C
Superficial velocity: 180 hr -1
Empty line speed: 0.11 m / sec
脱臭処理開始から６０日経過後の脱臭成績を表１に示す。下水二次処理水を３５日間散水したところ、硫化水素の除去率がそれまでは９０％以上であったものが、８９％となった。このときの圧力損失が０．３５ｋＰａであった。その後、散水用水を工業用水に切替えた。工業用水に切替えてから２５日後の処理ガスの悪臭物質濃度は、硫化水素０．００１ｐｐｍ以下、メチルメルカプタン０．００１ｐｐｍ以下、硫化メチル０．００１ｐｐｍ以下、二硫化メチル０．００１ｐｐｍ以下となった。また、脱臭処理開始より６０日後の圧力損失は０．１９ｋＰａであった。
なお、散水用水のＳＳ濃度、全窒素濃度、全リン濃度を表２に示す。下水二次処理水のＳＳ濃度は１０ｍｇ／Ｌ、全窒素濃度は１３ｍｇ／Ｌ、全リン濃度は２．１ｍｇ／Ｌであった。工業用水のＳＳ濃度は１ｍｇ／Ｌ、全窒素濃度は０．５ｍｇ／Ｌ、全リン濃度は１．０ｍｇ／Ｌであった。
Table 1 shows the deodorization results after 60 days from the start of the deodorization treatment. When the sewage secondary treated water was sprinkled for 35 days, the removal rate of hydrogen sulfide was 89%, which was 90% or more. The pressure loss at this time was 0.35 kPa. Thereafter, the water for watering was switched to industrial water. The malodorous substance concentration of the treatment gas 25 days after switching to industrial water was 0.001 ppm or less of hydrogen sulfide, 0.001 ppm or less of methyl mercaptan, 0.001 ppm or less of methyl sulfide, and 0.001 ppm or less of methyl disulfide. Moreover, the pressure loss 60 days after the start of the deodorizing treatment was 0.19 kPa.
In addition, Table 2 shows SS concentration, total nitrogen concentration, and total phosphorus concentration of water for watering. The SS concentration of sewage secondary treated water was 10 mg / L, the total nitrogen concentration was 13 mg / L, and the total phosphorus concentration was 2.1 mg / L. The SS concentration of industrial water was 1 mg / L, the total nitrogen concentration was 0.5 mg / L, and the total phosphorus concentration was 1.0 mg / L.
実施例４
図１に示す脱臭塔３の充填層５にポリビニルアセタール（ＰＶＡ）を充填し、下水汚泥集約処理施設から発生する臭気を、原ガス１として脱臭処理した。運転条件は次のとおりである。
原ガス性状 硫化水素濃度 ：２５ｐｐｍ
メチルメルカプタン濃度 ： １．９ｐｐｍ
硫化メチル濃度 ： ０．０６５ｐｐｍ
二硫化メチル濃度 ： ０．０４０ｐｐｍ
温度 ：２０℃
空塔速度 ：１８０ｈｒ−１
空塔線速度 ： ０．１１ｍ／ｓｅｃ
Example 4
The packed bed 5 of the
Raw gas properties Hydrogen sulfide concentration: 25ppm
Methyl mercaptan concentration: 1.9ppm
Methyl sulfide concentration: 0.065ppm
Methyl disulfide concentration: 0.040 ppm
Temperature: 20 ° C
Superficial velocity: 180 hr -1
Empty line speed: 0.11 m / sec
脱臭処理開始から６０日経過後の脱臭成績を表１に示す。下水二次処理水を３５日間散水したところ、硫化水素の除去率がそれまでは９０％以上であったものが、８９％となった。このときの圧力損失が０．３５ｋＰａであった。その後、散水用水を水道水に切替えた。水道水に切替えてから２５日後の処理ガスの悪臭物質濃度は、硫化水素０．００１ｐｐｍ以下、メチルメルカプタン０．００１ｐｐｍ以下、硫化メチル０．００１ｐｐｍ以下、二硫化メチル０．００１ｐｐｍ以下となった。また、脱臭処理開始より６０日後の圧力損失は０．１８ｋＰａであった。
なお、散水用水のＳＳ濃度、全窒素濃度、全リン濃度を表２に示す。下水二次処理水のＳＳ濃度は１１ｍｇ／Ｌ、全窒素濃度は１２ｍｇ／Ｌ、全リン濃度は２．７ｍｇ／Ｌであった。水道水のＳＳ濃度は１ｍｇ／Ｌ、全窒素濃度は２．０ｍｇ／Ｌ、全リン濃度は０．１ｍｇ／Ｌ以下であった。
Table 1 shows the deodorization results after 60 days from the start of the deodorization treatment. When the sewage secondary treated water was sprinkled for 35 days, the removal rate of hydrogen sulfide was 89%, which was 90% or more. The pressure loss at this time was 0.35 kPa. Thereafter, the water for watering was switched to tap water. The malodorous substance concentration of the treatment gas 25 days after switching to tap water was 0.001 ppm or less of hydrogen sulfide, 0.001 ppm or less of methyl mercaptan, 0.001 ppm or less of methyl sulfide, and 0.001 ppm or less of methyl disulfide. Moreover, the pressure loss 60 days after the start of the deodorization treatment was 0.18 kPa.
In addition, Table 2 shows SS concentration, total nitrogen concentration, and total phosphorus concentration of water for watering. The SS concentration of sewage secondary treated water was 11 mg / L, the total nitrogen concentration was 12 mg / L, and the total phosphorus concentration was 2.7 mg / L. The SS concentration of tap water was 1 mg / L, the total nitrogen concentration was 2.0 mg / L, and the total phosphorus concentration was 0.1 mg / L or less.
比較例１
図１に示す脱臭塔３の充填層５にＰＶＡを充填し、下水汚泥集約処理施設から発生する臭気を原ガス１として、脱臭処理した。運転条件は次のとおりである。
原ガス性状 硫化水素濃度 ：２８ｐｐｍ
メチルメルカプタン濃度 ： １．６ｐｐｍ
硫化メチル濃度 ： ０．０７９ｐｐｍ
二硫化メチル濃度 ： ０．０３９ｐｐｍ
温度 ：２０℃
空塔速度 ：１８０ｈｒ−１
空塔線速度 ： ０．１１ｍ／ｓｅｃ
Comparative Example 1
The packed bed 5 of the
Raw gas properties Hydrogen sulfide concentration: 28ppm
Methyl mercaptan concentration: 1.6ppm
Methyl sulfide concentration: 0.079ppm
Methyl disulfide concentration: 0.039ppm
Temperature: 20 ° C
Superficial velocity: 180 hr -1
Empty line speed: 0.11 m / sec
脱臭処理開始から６０日経過後の脱臭成績を表１に示す。試験開始時より散水用水には下水二次処理水を使用した。脱臭処理開始より６０日後の処理ガスの悪臭物質濃度は、硫化水素５．１ｐｐｍ、メチルメルカプタン０．０１０ｐｐｍ、硫化メチル０．００４ｐｐｍ、二硫化メチル０．００１ｐｐｍ以下であり、実施例１及び実施例２に比して脱臭性能が悪くなった。このときの硫化水素除去率は、８２％であった。また、脱臭処理開始より６０日後の圧力損失も０．５ｋＰａと実施例１及び実施例２に比して高かった。
なお、散水用水のＳＳ濃度、アンモニア態窒素濃度、リン酸濃度を表２に示す。下水二次処理水のＳＳ濃度は１１ｍｇ／Ｌ、アンモニア態窒素濃度は１３ｍｇ／Ｌ、リン酸濃度は２．５ｍｇ／Ｌであった。
Table 1 shows the deodorization results after 60 days from the start of the deodorization treatment. Sewage secondary treated water was used for watering from the start of the test. The malodorous substance concentration of the treatment gas 60 days after the start of the deodorization treatment is 5.1 ppm or less of hydrogen sulfide, 0.010 ppm of methyl mercaptan, 0.004 ppm of methyl sulfide, and 0.001 ppm of methyl disulfide. Deodorization performance was worse than that. At this time, the removal rate of hydrogen sulfide was 82%. Moreover, the pressure loss 60 days after the start of the deodorizing treatment was 0.5 kPa, which was higher than those in Examples 1 and 2.
In addition, Table 2 shows the SS concentration, ammonia nitrogen concentration, and phosphoric acid concentration of water for watering. The SS concentration of the sewage secondary treated water was 11 mg / L, the ammonia nitrogen concentration was 13 mg / L, and the phosphoric acid concentration was 2.5 mg / L.
比較例２
図１に示す脱臭塔３の充填層５にＰＶＡを充填し、下水汚泥集約処理施設から発生する臭気を原ガス１として、脱臭処理した。運転条件は次のとおりである。
原ガス性状 硫化水素濃度 ：２２ｐｐｍ
メチルメルカプタン濃度 ： １．９ｐｐｍ
硫化メチル濃度 ： ０．０８６ｐｐｍ
二硫化メチル濃度 ： ０．０４３ｐｐｍ
温度 ：２２℃
空塔速度 ：１８０ｈｒ−１
空塔線速度 ： ０．１１ｍ／ｓｅｃ
Comparative Example 2
The packed bed 5 of the
Raw gas properties Hydrogen sulfide concentration: 22ppm
Methyl mercaptan concentration: 1.9ppm
Methyl sulfide concentration: 0.086ppm
Methyl disulfide concentration: 0.043ppm
Temperature: 22 ° C
Superficial velocity: 180 hr -1
Empty line speed: 0.11 m / sec
脱臭処理開始から６０日経過後の脱臭成績を表１に示す。試験開始時より散水用水には工業用水を使用した。脱臭処理開始より６０日後の処理ガスの悪臭物質濃度は、硫化水素０．００２ｐｐｍ以下、メチルメルカプタン０．０６４ｐｐｍ、硫化メチル０．０１６ｐｐｍ、二硫化メチル０．０１５ｐｐｍ以下であり、実施例１及び実施例２に比して脱臭性能が悪くなった。また、脱臭処理開始より６０日後の圧力損失は０．０２ｋＰａであった。
なお、散水用水のＳＳ濃度、全窒素濃度、全リン濃度を表２に示す。工業用水のＳＳ濃度は１ｍｇ／Ｌ、全窒素濃度は０．５ｍｇ／Ｌ、全リン濃度は１．０ｍｇ／Ｌ以下であった。
Table 1 shows the deodorization results after 60 days from the start of the deodorization treatment. Industrial water was used for watering from the start of the test. The malodorous substance concentration of the treatment gas 60 days after the start of the deodorization treatment is 0.002 ppm or less of hydrogen sulfide, 0.064 ppm of methyl mercaptan, 0.016 ppm of methyl sulfide, and 0.015 ppm or less of methyl disulfide. Deodorizing performance was worse than 2. Moreover, the pressure loss 60 days after the start of the deodorizing treatment was 0.02 kPa.
In addition, Table 2 shows SS concentration, total nitrogen concentration, and total phosphorus concentration of water for watering. The SS concentration of industrial water was 1 mg / L, the total nitrogen concentration was 0.5 mg / L, and the total phosphorus concentration was 1.0 mg / L or less.
比較例３
図１に示す脱臭塔３の充填層５にＰＶＡを充填し、下水汚泥集約処理施設から発生する臭気を原ガス１として、脱臭処理した。運転条件は次のとおりである。
原ガス性状 硫化水素濃度 ：２８ｐｐｍ
メチルメルカプタン濃度 ： ２．１ｐｐｍ
硫化メチル濃度 ： ０．０７２ｐｐｍ
二硫化メチル濃度 ： ０．０３５ｐｐｍ
温度 ：２１℃
空塔速度 ：１８０ｈｒ−１
空塔線速度 ： ０．１１ｍ／ｓｅｃ
Comparative Example 3
The packed bed 5 of the
Raw gas properties Hydrogen sulfide concentration: 28ppm
Methyl mercaptan concentration: 2.1ppm
Methyl sulfide concentration: 0.072ppm
Methyl disulfide concentration: 0.035ppm
Temperature: 21 ° C
Superficial velocity: 180 hr -1
Empty line speed: 0.11 m / sec
脱臭処理開始から６０日経過後の脱臭成績を表１に示す。試験開始時より散水用水には水道水を使用した。脱臭処理開始より６０日後の処理ガスの悪臭物質濃度は、硫化水素０．００３ｐｐｍ以下、メチルメルカプタン０．０５６ｐｐｍ、硫化メチル０．０１２ｐｐｍ、二硫化メチル０．０２０ｐｐｍ以下であり、実施例１及び実施例２に比して脱臭性能が悪くなった。また、脱臭処理開始より６０日後の圧力損失は０．０２ｋＰａであった。
なお、散水用水のＳＳ濃度、全窒素濃度、全リン濃度を表２に示す。水道水のＳＳ濃度は１ｍｇ／Ｌ、全窒素濃度は２．０ｍｇ／Ｌ以下、全リン濃度は０．１ｍｇ／Ｌ以下であった。
Table 1 shows the deodorization results after 60 days from the start of the deodorization treatment. Tap water was used for watering from the start of the test. The malodorous substance concentration of the treatment gas 60 days after the start of the deodorization treatment is 0.003 ppm or less of hydrogen sulfide, 0.056 ppm of methyl mercaptan, 0.012 ppm of methyl sulfide, and 0.020 ppm or less of methyl disulfide. Deodorizing performance was worse than 2. Moreover, the pressure loss 60 days after the start of the deodorizing treatment was 0.02 kPa.
In addition, Table 2 shows SS concentration, total nitrogen concentration, and total phosphorus concentration of water for watering. The SS concentration of tap water was 1 mg / L, the total nitrogen concentration was 2.0 mg / L or less, and the total phosphorus concentration was 0.1 mg / L or less.
１：原ガス、２：処理ガス、３：脱臭塔、４充填層、５：散水部、６：排水、７：給水槽、８：下水二次処理水切替バルブ、９：工業用水又は水道水切替バルブ、１０：下水二次処理水、１１：工業用水又は水道水、１２：圧力センサ、１３：制御部、１４：栄養塩添加装置、１５，１６：硫化水素濃度計、１７：演算部 1: raw gas, 2: treatment gas, 3: deodorization tower, 4 packed bed, 5: sprinkling section, 6: drainage, 7: water tank, 8: sewage secondary treatment water switching valve, 9: industrial water or tap water Switching valve, 10: Sewage secondary treated water, 11: Industrial water or tap water, 12: Pressure sensor, 13: Control unit, 14: Nutrient addition device, 15, 16: Hydrogen sulfide concentration meter, 17: Calculation unit
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| CN108421368A (en) * | 2018-03-27 | 2018-08-21 | 苏州巨联环保有限公司 | The recovery method of air separator of oxygenerator and organic exhaust gas |
| FR3112967A1 (en) * | 2020-08-03 | 2022-02-04 | Veolia Water Solutions & Technologies Support | Process for the purification and deodorization of a gaseous effluent and installation for the implementation of such a process. |
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