JP2007277115A - Oily cosmetic - Google Patents
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- JP2007277115A JP2007277115A JP2006102554A JP2006102554A JP2007277115A JP 2007277115 A JP2007277115 A JP 2007277115A JP 2006102554 A JP2006102554 A JP 2006102554A JP 2006102554 A JP2006102554 A JP 2006102554A JP 2007277115 A JP2007277115 A JP 2007277115A
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Abstract
Description
本発明は油性化粧料に関するものであり、更に詳しくは、触り心地の良い柔らかな使用感触を有し、安定性に優れ、皮膚への塗布時にはなめらかな伸びと光沢を示し、かつ、化粧効果の持続性に優れた油性化粧料に関する。
The present invention relates to an oily cosmetic, and more specifically, has a soft feel that is comfortable to touch, has excellent stability, exhibits smooth elongation and gloss when applied to the skin, and has a cosmetic effect. The present invention relates to a long-lasting oily cosmetic.
従来、アイシャドウやファンデーションのようなメイクアップ製品では固形粉末化粧料が主流であり、これはパウダリィな感触でさらっとしているものの肌への付着性が悪く化粧効果の持続性に劣るなどの欠点を有していた。また、固形粉末化粧料の付着性、化粧効果の持続性を改善するために、油性固形化粧料が開発されている（例えば、特許文献１、２参照）。しかしながら、油性固形化粧料に関しては、しっとりした感触を有し肌への塗布時の伸びは良いもののいつまでもずるずるとして止まりが悪い、油っぽく経時でパールや顔料がよれるなどの欠点を有していた。
In the past, makeup powders such as eye shadows and foundations have been mainly used for solid powder cosmetics, which have a drawback that they have a powdery feel, but have poor adhesion to the skin and inferior makeup effect. Had. In addition, oil-based solid cosmetics have been developed in order to improve the adhesion of the solid powder cosmetic and the durability of the cosmetic effect (see, for example, Patent Documents 1 and 2). However, oil-based solid cosmetics have a moist feel and good elongation when applied to the skin, but they do not stop as long as they slick, and they are oily and have the disadvantages of pearls and pigments aging over time. It was.
一方、近年のメイクアップ製品市場においてその製品数は著しく増加しており、他社商品との差別化を図るために、また、多様化する消費者のニーズに応えるために特徴のある製剤が必要とされていた。
On the other hand, the number of products in the makeup products market in recent years has increased remarkably, and in order to differentiate from other companies' products and to meet diversifying consumer needs, a characteristic formulation is required. It had been.
そこで、特徴的な感触である触り心地の良い柔らかな使用感触を有し、安定性に優れ、皮膚への塗布時にはなめらかな伸びと光沢を示し、かつ、化粧効果の持続性に優れた化粧料に関してさらに高いレベルで実現した油性化粧料の開発が望まれていた。
Therefore, it is a cosmetic material that has a soft touch that is a distinctive touch and that is comfortable to touch, has excellent stability, exhibits smooth elongation and gloss when applied to the skin, and has a long-lasting makeup effect. Therefore, development of oily cosmetics realized at a higher level has been desired.
斯かる状況下、本発明の目的は、特徴的な感触である触り心地の良い柔らかな使用感触を有し、安定性に優れ、皮膚への塗布時にはなめらかな伸びと光沢を示し、かつ、化粧効果の持続性に優れた油性化粧料を提供することにある。
Under such circumstances, the object of the present invention is to provide a soft feeling that is characteristic to the touch that is comfortable to touch, has excellent stability, exhibits smooth elongation and gloss when applied to the skin, and has a cosmetic effect. An object of the present invention is to provide an oily cosmetic material with excellent durability.
この目的を達成する本発明は、次の成分（Ａ）から（Ｅ）を含有する油性化粧料にある。
（Ａ）エチレン、プロピレン、ブチレン、イソプレン、ブタジエン及びスチレンからなる群より選ばれる２種以上のブロックを有するブロックコポリマー
（Ｂ）シリコーンエラストマー
（Ｃ）ポリテトラフルオロエチレン
（Ｄ）３０℃で粘度が１０，０００ｍＰａ・ｓ以上の高粘性油から選ばれる少なくとも一種の油
を含有する油性化粧料にある。
また、更に（Ｅ）成分として油性増粘剤または油性ゲル化剤を少なくとも一種含有する上記油性化粧料にある。
The present invention which achieves this object is an oily cosmetic containing the following components (A) to (E).
(A) a block copolymer having two or more blocks selected from the group consisting of ethylene, propylene, butylene, isoprene, butadiene and styrene
(B) Silicone elastomer
(C) Polytetrafluoroethylene
(D) At least one oil selected from high-viscosity oil having a viscosity of 10,000 mPa · s or higher at 30 ° C.
Oil-based cosmetics containing
Further, the oily cosmetic composition further contains at least one oily thickener or oily gelling agent as component (E).
本発明により、特徴的な感触である触り心地の良い柔らかな使用感触を有し、安定性に
優れ、皮膚への塗布時にはなめらかな伸びと光沢を示し、かつ、化粧効果の持続性に優れた油性化粧料を提供することができる。
According to the present invention, it has a soft feel that is comfortable to touch, which is a characteristic feel, and is stable.
It is possible to provide an oily cosmetic that is excellent, exhibits a smooth elongation and gloss when applied to the skin, and has a long-lasting cosmetic effect.
以下、本発明を詳細に説明する。
Hereinafter, the present invention will be described in detail.
本発明に用いられる成分（Ａ）は、エチレン、プロピレン、ブチレン、イソプレン、ブタジエン及びスチレンからなる群より選ばれる２種以上のブロックを有するブロックコポリマーである。これらのブロックポリマーは化粧料に一般に用いられる物であれば特に限定されるものではなく、例えば、（スチレン／ブタジエン）コポリマー、（スチレン／イソプレン）コポリマー、（エチレン/プロピレン/スチレン）コポリマー、（ブチレン/エチレン/スチレン）コポリマーなどが挙げられる。好ましくは、水素化されたコポリマーである。
Component (A) used in the present invention is a block copolymer having two or more blocks selected from the group consisting of ethylene, propylene, butylene, isoprene, butadiene and styrene. These block polymers are not particularly limited as long as they are generally used in cosmetics. For example, (styrene / butadiene) copolymer, (styrene / isoprene) copolymer, (ethylene / propylene / styrene) copolymer, (butylene) / Ethylene / styrene) copolymer and the like. Preferably, it is a hydrogenated copolymer.
このコポリマーは任意のオイルとプレミックスされた原料として市販されており、その例として、ＴＲＡＮＳＧＥＬ １１０、５１０などのＴＲＡＮＳＧＥＬシリーズ（ＡＩＧＬＯＮ社）、及び、Ｖｅｒｓａｇｅｌ ＭＥ７５０、ＭＤ１６００などのＶｅｒｓａｇｅｌシリーズ（Ｐｅｎｒｅｃｏ社）などがある。
This copolymer is commercially available as a raw material premixed with any oil, for example, TRANSGEL series (AIGLON) such as TRANSGEL 110, 510, and Versagel series (Penreco) such as Versagel ME750, MD1600, etc. There is.
この成分（Ａ）の配合量は、発現する効果の程度とのびなどの使用感の観点から化粧料総量を基準として０．０１〜１５質量％、より好ましくは０．０３〜１０質量％、さらに好ましくは０．０５〜５質量％が好適である。０．０１質量％未満では十分な安定性が保てず、１５質量％を超えると塗布時の伸びが重くなる等感触的に好ましくない場合がある。
The blending amount of this component (A) is 0.01 to 15% by mass, more preferably 0.03 to 10% by mass, more preferably 0.03 to 10% by mass, based on the total amount of cosmetics from the viewpoint of the degree of effect to be exhibited and the feeling of use such as stretch. Preferably 0.05-5 mass% is suitable. If it is less than 0.01% by mass, sufficient stability cannot be maintained, and if it exceeds 15% by mass, the elongation at the time of application may become heavy, which may be undesirable.
本発明に用いられる成分（Ｂ）は化粧料に用いられるシリコーンエラストマーなら問題なく、（ジメチコン／ビニルジメチコン）クロスポリマー、（ビニルジメチコン／ラウリルジメチコン）クロスポリマー、ジメチコンクロスポリマー、ジメチコンクロスポリマー３、ポリシリコーン−１１などが挙げられる。具体的な市販品として、ＫＳＧ−１５、１６、１８、４１、４２などのＫＳＧシリーズ（信越化学工業社）、ＤＣ９０４０、９０４１、９０４５、９５４６（東レ・ダウコーニング社）、ＪＥＥＳＩＬＣ ＩＤＤ、ＪＥＥＣＨＥＭ ＨＰＩＢなど（Ｊｅｅｎ Ｉｎｔｅｒｎａｔｉｏｎａｌ社）、Ｇｒａｎｓｉｌ
ＧＣＭ−５、ＤＭＧ−６、ＰＣ−１２などのＧｒａｎｓｉｌシリーズ（Ｇｒａｎｔ Ｉｎｄｕｓｔｒｉｅｓ社）などが挙げられる。
The component (B) used in the present invention may be any silicone elastomer used in cosmetics without any problem. (Dimethicone / vinyl dimethicone) crosspolymer, (vinyl dimethicone / lauryl dimethicone) crosspolymer, dimethicone crosspolymer, dimethicone crosspolymer 3, poly Silicone-11 etc. are mentioned. Specific commercial products include KSG series such as KSG-15, 16, 18, 41, 42 (Shin-Etsu Chemical Co., Ltd.), DC9040, 9041, 9045, 9546 (Toray Dow Corning), JEESILC IDD, JEECHEM HPIB, etc. (Jen International), Gransil
Gransil series (Grant Industries, Inc.) such as GCM-5, DMG-6, and PC-12.
この成分（Ｂ）の配合量は、発現する効果の程度とのびなどの使用感の観点から化粧料総量を基準として０．１〜２０質量％、より好ましくは０．２〜１５質量％、さらに好ましくは０．４〜１０質量％が好適である。０．１質量％未満では特徴的な感触が発揮できず、２０質量％を超えると指または塗布具への適用が悪くなる等好ましくない場合がある。
The blending amount of this component (B) is 0.1 to 20% by mass, more preferably 0.2 to 15% by mass, more preferably 0.2 to 15% by mass, based on the total amount of cosmetics from the viewpoint of the degree of effect to be exhibited and the feeling of use such as stretch. Preferably 0.4-10 mass% is suitable. If it is less than 0.1% by mass, a characteristic feel cannot be exhibited, and if it exceeds 20% by mass, application to a finger or an applicator may be unfavorable.
本発明に用いられる成分（Ｃ）は化粧料に用いられるポリテトラフルオロエチレンなら問題なく、具体的な市販品としては、ＭＩＣＲＯＳＬＩＰ ５１９、５１９Ｌ（ＭＩＣＲＯ ＰＯＷＤＥＲＳ社）などが挙げられる。
If the component (C) used in the present invention is polytetrafluoroethylene used in cosmetics, there is no problem. Specific examples of commercially available products include MICROSLIP 519, 519L (MICRO POWDERS).
この成分（Ｃ）の配合量は、発現する効果の程度とのびなどの使用感の観点から化粧料総量を基準として１〜５０質量％、より好ましくは３〜４５質量％、さらに好ましくは５〜４０質量％が好適である。１質量％未満では特徴的な柔らかな感触が発揮できず、５０質量％を超えると皮膚に塗布しづらく、仕上がりが美しくない等好ましくない場合がある。
The blending amount of this component (C) is from 1 to 50% by mass, more preferably from 3 to 45% by mass, and even more preferably from 5 to 45% by mass, based on the total amount of cosmetics, from the viewpoint of the degree of effect to be manifested and feeling of use such as stretch. 40% by mass is preferred. If it is less than 1% by mass, a characteristic soft feel cannot be exhibited, and if it exceeds 50% by mass, it may be difficult to apply to the skin and the finish may not be beautiful.
本発明に用いられる成分（Ｄ）は化粧料に用いられる高粘性油なら問題なく、水添ポリイソブテンやペンタイソステアリン酸ジペンタエリスリトール、テトライソステアリン酸ジペンタエリスリトール、ワセリン、ラウロイルグルタミン酸ジ（フィトステリル・ベヘニル・オクチルドデシル）、ダイマージリノール酸（フィトステアリル／イソステアリル／セチル／ステアリル／ベヘニル）、ダイマージリノール酸水添ヒマシ油などが挙げられる。
また、本発明において粘度は、Ｂ型粘度計、例えば、単一円筒型回転粘度計ビストロンＶＳ−Ａ１（芝浦システム社製）で測定した値である。
Component (D) used in the present invention is not a problem if it is a highly viscous oil used in cosmetics. Octyldodecyl), dimer linoleic acid (phytostearyl / isostearyl / cetyl / stearyl / behenyl), dimer linoleic acid hydrogenated castor oil, and the like.
In the present invention, the viscosity is a value measured with a B-type viscometer, for example, a single cylindrical rotational viscometer vistron VS-A1 (manufactured by Shibaura System Co., Ltd.).
この成分（Ｄ）の配合量は、発現する効果の程度とのびなどの使用感の観点から化粧料総量を基準として１〜５０質量％、より好ましくは３〜４０質量％、さらに好ましくは５〜３０質量％が好適である。１質量％未満では化粧持ちの効果が発揮できず、５０質量％を超えると感触が重くなり塗布しづらい等好ましくない場合がある。
The blending amount of this component (D) is 1 to 50% by mass, more preferably 3 to 40% by mass, and still more preferably 5 to 5% by mass based on the total amount of cosmetics from the viewpoint of the degree of effect to be exhibited and the feeling of use such as stretch. 30% by mass is preferred. If it is less than 1% by mass, the effect of holding the makeup cannot be exhibited, and if it exceeds 50% by mass, the feel becomes heavy and it may be difficult to apply.
本発明に用いられる成分（Ｅ）は通常の化粧料に用いられる油性増粘剤、または、油性ゲル化剤なら問題なく、ワックス、ロウ、有機変性粘土鉱物、脂肪酸デキストリンなどが挙げられ、更に具体的には、パラフィン、セレシン、合成炭化水素ワックス、フィッシャートロプシュワックス、マイクロクリスタリンワックス、ポリエチレンワックス、エチレンプロピレンコポリマー、キャンデリラロウ、ミツロウ、カルナバロウ、パルミチン酸デキストリン、ミリスチン酸デキストリン、ステアリン酸イヌリン、１２−ヒドロキシステアリン酸、ジステアルジモニウムヘクトライト、ステアラルコニウムヘクトライト、及び、シリル化シリカなどが挙げられる。
The component (E) used in the present invention may be any oily thickener or oily gelling agent used in ordinary cosmetics, and examples thereof include waxes, waxes, organically modified clay minerals, fatty acid dextrins, and the like. In particular, paraffin, ceresin, synthetic hydrocarbon wax, Fischer-Tropsch wax, microcrystalline wax, polyethylene wax, ethylene propylene copolymer, candelilla wax, beeswax, carnauba wax, dextrin palmitate, dextrin myristate, inulin stearate, 12- Examples thereof include hydroxystearic acid, disteardimonium hectorite, stearalkonium hectorite, and silylated silica.
本発明の化粧料には、本発明の目的を損なわない範囲で、前記の必須成分以外にオレイン酸フィトステリル、スクワラン、トリ（カプリル・カプリン）酸グリセリル、オクチルドデカノール、ラウロイルグルタミン酸ジ（フィトステリル／オクチルドデシル）、イソノナン酸イソノニル、ヒドロキシステアリン酸オクチル、ジメチルポリシロキサン、メチルフェニルポリシロキサン、メチルシクロポリシロキサン、イソドデカン等の油性成分、酸化チタン、酸化鉄などの無機着色顔料、赤色２０２号、赤色２２３号、黄色４号等の有機色素及びそのレーキ化物、雲母チタン、ベンガラ被覆雲母チタン、カルミン被覆雲母チタン、酸化チタン被覆ガラスフレーク、ポリエチレンテレフタレート・ポリメチルメタクリレート積層フィルム末等の光輝性着色顔料、マイカ、タルク、カオリン、ナイロンパウダー、シリカビーズ、架橋型シリコーン末等の粉体成分、１，３−ブチレングリコール、ジプロピレングリコール、エタノール等のアルコール、植物抽出物、紫外線吸収剤、防腐剤、香料、及び、抗酸化剤等を配合することができる。
The cosmetics of the present invention include phytosteryl oleate, squalane, glyceryl tri (capryl / caprylate), octyldodecanol, dilauroylglutamate di (phytosteryl / octyl) in addition to the above essential components, as long as the object of the present invention is not impaired. Dodecyl), isononyl isononanoate, octyl hydroxystearate, dimethylpolysiloxane, methylphenylpolysiloxane, methylcyclopolysiloxane, inorganic color pigments such as isododecane, titanium oxide, iron oxide, red 202, red 223 , Organic dyes such as Yellow No. 4 and their lakes, mica titanium, Bengala coated mica titanium, carmine coated mica titanium, titanium oxide coated glass flakes, polyethylene terephthalate / polymethyl methacrylate laminated film powder, etc. Active pigment, mica, talc, kaolin, nylon powder, silica beads, cross-linked silicone powder and other powder components, 1,3-butylene glycol, dipropylene glycol, ethanol and other alcohols, plant extracts, UV absorbers, An antiseptic, a fragrance | flavor, an antioxidant, etc. can be mix | blended.
本発明の油性化粧料とは、油剤を連続相とし、油中に粉体が分散している状態の化粧料を指し、１％以下で植物抽出物や水などを含むことが出来る。具体的に好適なものとしては、ファンデーション、アイシャドウ、チーク、油性ジェル、及び、口紅などが挙げられる。
The oily cosmetic of the present invention refers to a cosmetic in a state where an oil agent is a continuous phase and powder is dispersed in oil, and it can contain a plant extract, water, etc. at 1% or less. Specific examples include foundation, eye shadow, teak, oily gel, and lipstick.
以下、実施例及び比較例を挙げ本発明を詳説するが、本発明はこれらにより限定されるものではない。尚、実施例及び比較例に示す％とは質量％である。
EXAMPLES Hereinafter, although an Example and a comparative example are given and this invention is explained in full detail, this invention is not limited by these. In addition,% shown in an Example and a comparative example is the mass%.
（１）使用特性評価試験方法
女性パネラー２０名に、実施例、比較例を塗布してもらい、以下の項目について５点から１点までの５段階評価をしてもらい、点数が高いほうがより良い評価とした。そして２０名のつけた点数の平均をその実施例もしくは比較例の点数とした。（小数点第二位を四
捨五入）
・塗布時の感触（柔らかさなど）
・塗布時の仕上がり（光沢など）
・３時間経過時の化粧効果持続
（２）経時安定性試験方法
実施例及び比較例をそれぞれ４５℃の恒温槽に静置し、３ヶ月後に観察を行い、問題のなかったものを○、若干の油の分離がみられたものを△、著しく油の分離がみられたものを×とした。
(1) Usage characteristic evaluation test method
Twenty female panelists applied the examples and comparative examples, and the following items were evaluated on a five-point scale from 5 to 1, and the higher the score, the better. And the average of the scores given by 20 people was taken as the score of the example or comparative example. (4 decimal places
Rounded off)
・ Feeling during application (softness, etc.)
・ Finish when finished (such as gloss)
・ Continuation of makeup effect after 3 hours
(2) Stability test method over time
Examples and Comparative Examples were each left in a 45 ° C. constant temperature bath and observed after 3 months. If there was no problem, ○, if some oil separation was found, Δ, oil separation was marked. What was seen was made into x.
＜実施例１、２、比較例１〜４（口紅）＞
＜調製方法＞
成分１〜６を均一に溶解混合し、プレミックスした７〜９、１０及び１１を加え均一に分散した後、成分１２〜１９を加え混練し、半製品を得る。その半製品を脱気した後容器に充填して目的の口紅を得る。成分組成及び評価試験結果を表１に示す。
<Examples 1 and 2 and Comparative Examples 1 to 4 (lipstick)>
<Preparation method>
Components 1 to 6 are uniformly dissolved and mixed, premixed 7 to 9, 10 and 11 are added and dispersed uniformly, then components 12 to 19 are added and kneaded to obtain a semi-finished product. The semi-finished product is deaerated and then filled into a container to obtain the desired lipstick. The component composition and evaluation test results are shown in Table 1.
表１に示すように、本発明の実施例１及び２は、安定性、塗布時の感触や光沢、及び、化粧効果の持続性において比較例１〜４のものより明らかに優れたものであった。
As shown in Table 1, Examples 1 and 2 of the present invention were clearly superior to those of Comparative Examples 1 to 4 in stability, feel and gloss at the time of application, and durability of the makeup effect. It was.
＜実施例３〜５、比較例５〜８（アイシャドウ）＞
＜調製方法＞
成分１〜９を均一に溶解混合し、プレミックスした１０〜１２及び１３〜１５を加え均一に分散した後、成分１６〜２４を加え混練し、半製品を得る。その半製品を脱気した後容器に充填して目的のアイシャドウを得る。成分組成及び評価試験結果を表２に示す。
<Examples 3-5, Comparative Examples 5-8 (Eyeshadow)>
<Preparation method>
Components 1 to 9 are uniformly dissolved and mixed, premixed 10 to 12 and 13 to 15 are added and dispersed uniformly, and then components 16 to 24 are added and kneaded to obtain a semi-finished product. The semi-finished product is deaerated and then filled into a container to obtain the desired eye shadow. The component composition and evaluation test results are shown in Table 2.
表２に示すように、本発明の実施例３〜５のものは、安定性、塗布時の感触や光沢、及び、化粧効果の持続性において比較例５〜８のものより明らかに優れたものであった。
As shown in Table 2, those of Examples 3 to 5 of the present invention are clearly superior to those of Comparative Examples 5 to 8 in stability, feel and gloss at the time of application, and durability of the makeup effect. Met.
＜実施例６、比較例９，１０（チーク）＞
＜調製方法＞
成分１〜５を均一に溶解混合し、プレミックスした６〜８、９及び１０を加え均一に分散した後、成分１１〜２１を加え混練し、半製品を得る。その半製品を脱気した後容器に充填して目的のチークを得る。成分組成及び評価試験結果を表３に示す。
<Example 6, Comparative Examples 9 and 10 (Teak)>
<Preparation method>
Components 1 to 5 are uniformly dissolved and mixed, premixed 6 to 8, 9 and 10 are added and dispersed uniformly, then components 11 to 21 are added and kneaded to obtain a semi-finished product. The semi-finished product is deaerated and then filled into a container to obtain the desired cheek. Table 3 shows the component composition and the evaluation test results.
表３に示すように、本発明の実施例６は、安定性、塗布時の感触や光沢、及び、化粧効果の持続性において比較例９及び１０のものより明らかに優れたものであった。
As shown in Table 3, Example 6 of the present invention was clearly superior to those of Comparative Examples 9 and 10 in stability, feel and gloss when applied, and durability of the cosmetic effect.
＜実施例７、比較例１１、１２（ファンデーション）＞
＜調製方法＞
成分１〜７を均一に溶解混合し、プレミックスした８〜１０、１１及び１２を加え均一に分散した後、成分１３〜２０を加え混練し、半製品を得る。その半製品を脱気した後容器に充填して目的のファンデーションを得る。成分組成及び評価試験結果を表４に示す。
<Example 7, Comparative Examples 11 and 12 (Foundation)>
<Preparation method>
Components 1 to 7 are uniformly dissolved and mixed, and premixed 8 to 10, 11 and 12 are added and dispersed uniformly, and then components 13 to 20 are added and kneaded to obtain a semi-finished product. The semi-finished product is deaerated and then filled into a container to obtain the desired foundation. The component composition and evaluation test results are shown in Table 4.
表４に示すように、本発明の実施例７は、安定性、塗布時の感触や光沢、及び、化粧効果の持続性において比較例１１及び１２のものより明らかに優れたものであった。
As shown in Table 4, Example 7 of the present invention was clearly superior to those of Comparative Examples 11 and 12 in stability, feel and gloss when applied, and durability of the cosmetic effect.
＜実施例８、比較例１３（油性ジェル）＞
＜調製方法＞
成分１〜７を均一に溶解混合し、プレミックスした８〜１０、１１及び１２を加え均一に分散した後、成分１３及び１４を加え混練し、半製品を得る。その半製品を脱気した後容器に充填して目的の油性ジェルを得る。成分組成及び評価試験結果を表５に示す。
<Example 8, Comparative Example 13 (oil-based gel)>
<Preparation method>
Components 1 to 7 are uniformly dissolved and mixed, premixed 8 to 10, 11 and 12 are added and dispersed uniformly, then components 13 and 14 are added and kneaded to obtain a semi-finished product. The semi-finished product is deaerated and then filled into a container to obtain the desired oily gel. The component composition and evaluation test results are shown in Table 5.
表５に示すように、本発明の実施例８は、安定性、塗布時の感触や光沢、及び、化粧効果の持続性において比較例１３のものより明らかに優れたものであった。
As shown in Table 5, Example 8 of the present invention was clearly superior to that of Comparative Example 13 in stability, feel and gloss when applied, and durability of the cosmetic effect.
以上のように本発明品は、触り心地の良い柔らかな使用感触を有し、安定性に優れ、皮膚への塗布時にはなめらかな伸びと光沢を示し、かつ、化粧効果の持続性に優れた油性化粧料を提供できる。
As described above, the product of the present invention has an easy-to-touch, soft feel, excellent stability, smooth elongation and gloss when applied to the skin, and excellent persistence of cosmetic effect. Can provide cosmetics.
Claims (3)
（Ａ）エチレン、プロピレン、ブチレン、イソプレン、ブタジエン及びスチレンからなる群より選ばれる２種以上のブロックを有するブロックコポリマー
（Ｂ）シリコーンエラストマー
（Ｃ）ポリテトラフルオロエチレン
（Ｄ）３０℃での粘度が１０，０００ｍＰａ・ｓ以上の高粘性油から選ばれる少なくとも一種の油
を含有する油性化粧料。
The following components (A) to (D):
(A) a block copolymer having two or more blocks selected from the group consisting of ethylene, propylene, butylene, isoprene, butadiene and styrene
(B) Silicone elastomer
(C) Polytetrafluoroethylene
(D) At least one oil selected from high viscosity oils having a viscosity at 30 ° C. of 10,000 mPa · s or more
Containing oily cosmetics.
（Ｂ）シリコーンエラストマーの配合量が、得られる化粧料全量に対し０．１〜２０質量％
（Ｃ）ポリテトラフルオロエチレンの配合量が、得られる化粧料全量に対し１〜５０質量％
（Ｄ）３０℃での粘度が１０，０００ｍＰａ・ｓ以上の高粘性油から選ばれる少なくとも一種の油の配合量が、得られる化粧料全量に対し１〜５０質量％
であることを特徴とする請求項１に記載の油性化粧料。
(A) The blending amount of the block copolymer having two or more blocks selected from the group consisting of ethylene, propylene, butylene, isoprene, butadiene and styrene is 0.01 to 15% by mass with respect to the total amount of the obtained cosmetic.
(B) The blending amount of the silicone elastomer is 0.1 to 20% by mass with respect to the total amount of the cosmetic to be obtained.
(C) 1 to 50% by mass of polytetrafluoroethylene based on the total amount of the cosmetic obtained
(D) The blending amount of at least one oil selected from high-viscosity oil having a viscosity at 30 ° C. of 10,000 mPa · s or more is 1 to 50% by mass with respect to the total amount of the obtained cosmetic.
The oily cosmetic according to claim 1, wherein
The oily cosmetic according to claim 1 or 2, further comprising at least one oily thickener or oily gelling agent as component (E).
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| JP2006102554A JP4897337B2 (en) | 2006-04-03 | 2006-04-03 | Oily cosmetics |
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| US20100272663A1 (en) * | 2007-12-10 | 2010-10-28 | Chanel Parfums Beaute | Cosmetic composition including an anhydrous gel and a glyceryl ester |
| WO2012124938A2 (en) * | 2011-03-11 | 2012-09-20 | 코스맥스 주식회사 | Cosmetic composition for make-up containing silicone elastomer |
| WO2014030863A1 (en) * | 2012-08-23 | 2014-02-27 | 코스맥스 주식회사 | Wet-forming solid cosmetic composition containing silicone elastomer, silicone gel and non-volatile dispersing medium |
| KR20190020485A (en) * | 2017-08-21 | 2019-03-04 | 코스맥스 주식회사 | Make-up cosmetic composition comprising synthetic mica and coated inorganic sunscreen |
| KR20200143996A (en) * | 2019-06-17 | 2020-12-28 | 코스맥스 주식회사 | Anhydrous Eyebrow Make-up Cosmetic Composition |
| WO2022177011A1 (en) * | 2021-02-22 | 2022-08-25 | 株式会社 資生堂 | Oily cosmetic |
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| US20100272663A1 (en) * | 2007-12-10 | 2010-10-28 | Chanel Parfums Beaute | Cosmetic composition including an anhydrous gel and a glyceryl ester |
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| WO2012124938A3 (en) * | 2011-03-11 | 2012-12-27 | 코스맥스 주식회사 | Cosmetic composition for make-up containing silicone elastomer |
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| WO2014030863A1 (en) * | 2012-08-23 | 2014-02-27 | 코스맥스 주식회사 | Wet-forming solid cosmetic composition containing silicone elastomer, silicone gel and non-volatile dispersing medium |
| KR20190020485A (en) * | 2017-08-21 | 2019-03-04 | 코스맥스 주식회사 | Make-up cosmetic composition comprising synthetic mica and coated inorganic sunscreen |
| KR102012169B1 (en) | 2017-08-21 | 2019-08-20 | 코스맥스 주식회사 | Make-up cosmetic composition comprising synthetic mica and coated inorganic sunscreen |
| KR20200143996A (en) * | 2019-06-17 | 2020-12-28 | 코스맥스 주식회사 | Anhydrous Eyebrow Make-up Cosmetic Composition |
| KR102321529B1 (en) | 2019-06-17 | 2021-11-04 | 코스맥스 주식회사 | Anhydrous Eyebrow Make-up Cosmetic Composition |
| WO2022177011A1 (en) * | 2021-02-22 | 2022-08-25 | 株式会社 資生堂 | Oily cosmetic |
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