JP2007231371A - Cold-rolled steel sheet, galvanized steel sheet, and manufacturing method therefor - Google Patents
Cold-rolled steel sheet, galvanized steel sheet, and manufacturing method therefor Download PDFInfo
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本発明は、340MPa以上の引張強度を有する冷延鋼板および溶融亜鉛めっき鋼板ならびにそれらの製造方法に関する。特に、本発明は、サイドパネル等の自動車外板パネルに適した強度340MPa級以上の高強度亜鉛系めっき鋼板、冷延鋼板およびその製造方法に関する。 The present invention relates to a cold-rolled steel sheet and a hot-dip galvanized steel sheet having a tensile strength of 340 MPa or more and a method for producing them. In particular, the present invention relates to a high-strength galvanized steel sheet having a strength of 340 MPa or higher, a cold-rolled steel sheet, and a method for producing the same, which are suitable for an automobile outer panel such as a side panel.
自動車の高強度軽量化のニーズを受けて、自動車の外板等に適用される鋼板には、強度と合わせて成形性、耐二次加工脆性、表面性状などの特性が求められている。成形性に対してはr値が高いことや降伏強度(YS)が低いことが効果的である。近年は高強度鋼板に対しても成形性向上の要求が高い。高いr値を得るためには、C濃度30ppm程度以下の極炭素鋼をベースとしてTi、Nbなどの炭窒化物生成元素を添加することが有効であり、一般的にIF鋼として広く用いられている。 In response to the need for high strength and light weight of automobiles, steel sheets applied to automobile outer plates and the like are required to have properties such as formability, secondary work brittleness resistance, and surface properties in combination with strength. For formability, it is effective that the r value is high and the yield strength (YS) is low. In recent years, there is a high demand for improving formability even for high-strength steel sheets. In order to obtain a high r value, it is effective to add carbonitride-forming elements such as Ti and Nb based on an extremely carbon steel having a C concentration of about 30 ppm or less, and it is generally widely used as IF steel. Yes.
しかし、IF鋼は結晶粒が粗大になりやすいため、r値を向上させるために焼鈍温度を高温とした場合に、プレス後に肌荒れが生じて表面性状が劣化する場合がある。また、熱延鋼板の微細化に適した鋼材組成の検討が不十分なこともあって、冷間圧延、焼鈍後のr値の改善は難しかった。 However, IF steel tends to be coarse in crystal grains. Therefore, when the annealing temperature is set to a high temperature in order to improve the r value, roughening may occur after pressing and the surface properties may deteriorate. In addition, it was difficult to improve the r-value after cold rolling and annealing because the study of the steel composition suitable for refinement of the hot-rolled steel sheet was insufficient.
一方、高いr値を備えるとともに高い強度を備える鋼板として、IF鋼をベースとしてMn、Pなどの固溶強化元素を添加した鋼板が開発されている。しかし、固溶強化元素は一般に高価であり、鋼板のコストアップを招くため、特許文献1には、固溶強化元素を削減する目的でNbCやTiCで析出強化する技術が開示されている。 On the other hand, as a steel plate having a high r value and a high strength, a steel plate to which solid solution strengthening elements such as Mn and P are added based on IF steel has been developed. However, since the solid solution strengthening element is generally expensive and causes an increase in the cost of the steel sheet, Patent Document 1 discloses a technique for precipitation strengthening with NbC or TiC for the purpose of reducing the solid solution strengthening element.
しかしながら、TiCはAr3点以上の高温で生成するため、析出物のサイズが大きく、熱延鋼板組織の微細化によるr値向上の効果や、冷延鋼板組織の微細化による析出強化や表面性状改善の効果は小さい。 However, since TiC is generated at a high temperature of Ar 3 or higher, the size of the precipitate is large, the effect of improving the r value by refining the hot-rolled steel sheet structure, precipitation strengthening and surface properties by refining the cold-rolled steel sheet structure The effect of improvement is small.
また、TiとNbとを複合添加すると、冷却中にCがTiCとして高温で先に析出してしまうことにより、NbC微細析出物の生成が不十分となる場合がある。従って、Nbを単独添加した場合における特有のNbCの微細析出の効果による表面性状とプレス成形性に優れた鋼板を製造する技術は十分には確立されていなかった。 In addition, when Ti and Nb are added in combination, C may be precipitated as TiC at a high temperature during cooling, resulting in insufficient generation of NbC fine precipitates. Therefore, a technique for producing a steel sheet excellent in surface properties and press formability due to the effect of the unique fine precipitation of NbC when Nb is added alone has not been sufficiently established.
さらに、鋼中にTiを含有したものを母材として溶融亜鉛めっきを施した場合には、鋼板表面にすじ状のめっきムラが発生するため、自動車外板用として用いる場合に支障を来たす場合があった。 Furthermore, when hot dip galvanizing is performed using steel containing Ti as a base material, streaky plating unevenness occurs on the surface of the steel sheet, which may cause problems when used for automobile outer plates. there were.
特許文献2では、上記問題の解決を目的に、C:0.0040〜0.01%を含有する鋼板にNbを適正に添加することにより、NbCの微細析出物を生成させて組織の細粒化を図り、表面性状、機械特性を向上させる鋼板が開示されている。 In Patent Document 2, for the purpose of solving the above-mentioned problem, Nb is appropriately added to a steel sheet containing C: 0.0040 to 0.01%, thereby generating fine precipitates of NbC and fine grains of the structure. Steel sheets that improve the surface properties and mechanical properties are disclosed.
しかし、サイドパネル、ドア、フード、ルーフ等自動車外板パネルへの適用を考慮すると、しわや面歪みが顕在化しやすいものであり、また伸びが低く、耐二次加工脆性も十分ではなかった。
上述したように、従来は、強度、成形性、耐二次加工脆性及び表面性状(耐肌荒れ性、めっきムラ性)の全てを満足する高品質の冷延鋼板、亜鉛めっき鋼板はなかった。したがって、本発明は、フード、ドア、フェンダー、サイドパネル等の自動車外板パネルに要求される高プレス成形性を備え、優れた耐肌荒れ性を有し、めっき鋼板でのすじ模様欠陥や冷延鋼板での外観不良が生じない優れた表面性状を呈するTS340MPa級以上の高強度冷延鋼板、その亜鉛めっき鋼板およびそれらの製造方法を提供することを目的とする。 As described above, conventionally, there has been no high-quality cold-rolled steel sheet and galvanized steel sheet that satisfy all of the strength, formability, secondary work brittleness resistance and surface properties (skin roughness resistance, plating unevenness). Therefore, the present invention has a high press formability required for automobile outer panel such as hood, door, fender, side panel, etc., has excellent skin roughness resistance, and has a streak pattern defect or cold rolling in a plated steel sheet. An object of the present invention is to provide a TS340 MPa grade or higher high-strength cold-rolled steel sheet that exhibits excellent surface properties that do not cause appearance defects on the steel sheet, its galvanized steel sheet, and methods for producing them.
本発明者らは、まず、サイドパネル、フード、ドア、フェンダー等の自動車外板パネルに要求される高プレス成形性に関して検討を行った。
これら用途に供するブランク材は、鋼板からプレス加工で製造される自動車部品のなかでも最大クラスのサイズであるため、小物部品のようなスリットコイルからではなく、コイル幅のまま、それも最大クラスの広幅コイルから、ほぼ長方形にブランクカットしたものを若干トリムしてプレスに供されるものである。
The present inventors first examined high press formability required for automobile outer panel such as side panels, hoods, doors, and fenders.
The blank material used for these applications is the largest class size of automotive parts manufactured by pressing from steel plates, so it is not the slit coil like small parts, but the coil width is the largest class. A wide coil, which is blank-cut into a substantially rectangular shape, is trimmed slightly and used for pressing.
本発明者らは、例えば、サイドパネルならば、しわや割れが発生し易い部分となるフロントドア、リアドア開口部の4隅のコーナーが鋼板の圧延方向に対し45°方向に位置することや、フード、ドア、フェンダーも、4隅のコーナー部近辺が、しわや割れが発生し易い部分であり、その位置がコイル圧延方向に対し45°方向に位置することに着目した。 For example, if the side panel is a side panel, the corners of the four corners of the front door and the rear door opening that are likely to be wrinkled and cracked are 45 ° with respect to the rolling direction of the steel sheet, The hood, the door, and the fender also focused on the fact that wrinkles and cracks are likely to occur in the vicinity of the four corners, and their positions are located in the 45 ° direction with respect to the coil rolling direction.
図1は、鋼板ブランク材からプレス成形するサイドパネルの方向を示す平面図であり、図示のサイドパネルばかりでなく、ドア、フード、ルーフ等自動車外板パネルは、大型かつ概ね長方形の鋼板ブランク材を用いるため、通常、鋼板コイルに対して0°又は90°方向に板取りされる。 FIG. 1 is a plan view showing the direction of a side panel that is press-formed from a steel plate blank. Not only the illustrated side panel but also an automobile outer panel such as a door, a hood, and a roof are large and generally rectangular steel plate blanks. Therefore, the sheet is usually taken in the direction of 0 ° or 90 ° with respect to the steel plate coil.
その結果、鋼板の45°方向がプレス時の、割れやしわ危険位置に合致する。
そして、鋼板における機械特性の面内異方性に起因して、圧延方向に対して45°方向の機械特性が0°方向や90°方向より著しく劣ると、プレス成形に際して割れやしわなどのプレス不具合が生じ易くなることから、45°方向の機械特性を向上させて、成形難易度が高く、しわや割れが発生し易いサイドパネル、フード、ドア、フェンダー等のコーナー部における成形性を向上させることにより、鋼板全体についての過剰な高成形性を要求することなしに、斯かる大型プレス加工用に適した鋼板を得ることを着想した。
As a result, the 45 ° direction of the steel sheet coincides with a crack or wrinkle danger position during pressing.
Then, due to the in-plane anisotropy of the mechanical properties of the steel sheet, if the mechanical properties in the 45 ° direction are significantly inferior to the 0 ° direction or 90 ° direction with respect to the rolling direction, presses such as cracks and wrinkles during press forming Improves the mechanical properties in the 45 ° direction and improves the formability at the corners of side panels, hoods, doors, fenders, etc., which are highly difficult to form and easily wrinkle and crack. Thus, the present inventors have conceived of obtaining a steel plate suitable for such a large press work without requiring excessively high formability of the entire steel plate.
そこで、本発明者らは、圧延方向に対して45°方向の機械特性が優れ、かつ0°、45°、90°方向のうち、最も低いr値の値を1.0以上とすることにより、プレス成形性が良好な、自動車のサイドパネル、フード、ドア、フェンダー等の大型プレス部品の成形に最適な鋼板が得られることを着想した。 Therefore, the inventors have excellent mechanical properties in the 45 ° direction with respect to the rolling direction, and the lowest r value in the 0 °, 45 °, and 90 ° directions is 1.0 or more. It was conceived that a steel plate optimal for molding large press parts such as automobile side panels, hoods, doors, fenders, etc., having good press formability was obtained.
上記課題を解決するため、本発明者らは鋼組成、製造条件について鋭意検討を行い、C含有量を0.0005〜0.0040%に制御し、かつ、NbとTiのバランスを最適化することにより、NbCの微細析出効果により、熱延鋼板の結晶粒径を微細化させ、r値を向上させるとともに、プレス成形時の耐肌荒れ性を改善し、さらに、NbCの析出強化や固溶Nbにより、Mn、P、Siを多量に添加することなく、高強度化を可能にすることを見出した。Mn、P、Siの多量配合は外観品質、耐二次加工脆性、めっき品質を低下させる。 In order to solve the above-mentioned problems, the present inventors have intensively studied the steel composition and production conditions, control the C content to 0.0005 to 0.0040%, and optimize the balance of Nb and Ti. As a result, the crystal grain size of the hot-rolled steel sheet is refined due to the fine precipitation effect of NbC, the r value is improved, and the rough surface resistance during press forming is improved. Further, precipitation strengthening of NbC and solid solution Nb Thus, it was found that high strength can be achieved without adding a large amount of Mn, P, and Si. A large amount of Mn, P, and Si deteriorates appearance quality, secondary work brittleness resistance, and plating quality.
さらに、NbとTiのバランスを適正に制御することにより、本発明の課題である、45°方向の機械特性が優れた異方性バランスを実現することができることを見出した。
また、Cを0.0005%以上、0.0040%未満に制御し、強度不足分をMn、Nbなどで強化することで、加工性を低下させずに高加工性を確保できることも確認した。
Furthermore, it has been found that by properly controlling the balance between Nb and Ti, an anisotropic balance having excellent mechanical properties in the 45 ° direction, which is an object of the present invention, can be realized.
It was also confirmed that high workability can be secured without lowering workability by controlling C to 0.0005% or more and less than 0.0040% and strengthening the insufficient strength with Mn, Nb or the like.
本発明にかかる、プレス成形性、耐二次加工脆性、鋼板表面品質に優れる鋼板をサイドパネル、ドア、フェンダーなどの自動車外板に適用すると、それら部品のプレス加工で面歪み、しわ、割れが発生し易い主応力方向の圧延方向に対して45°方向の材料特性が特に優れることで、適材適所の異方性をもった最適な高強度冷延鋼板製品を製造することができ、産業上、極めて有益である。 Applying steel sheets with excellent press formability, secondary work brittleness resistance, and steel sheet surface quality according to the present invention to automobile outer panels such as side panels, doors, fenders, etc., surface distortion, wrinkles, and cracks occur during press processing of these parts. The material characteristics in the direction of 45 ° with respect to the rolling direction of the main stress direction, which is likely to occur, are particularly excellent, making it possible to manufacture optimal high-strength cold-rolled steel sheet products with anisotropy in the right place for the industry. , Extremely beneficial.
本発明にかかる鋼板は、加工用冷延鋼板としてのみならず、加工用表面処理鋼板の原板としても適用できる。その表面処理としては、亜鉛めっき(合金系を含む)、すずめっき等がある。また、本発明鋼板には、焼鈍または亜鉛めっき後、特殊な処理を施して、化成処理性、溶接性、プレス成形性および耐食性等の改善を行ってもよい。 The steel sheet according to the present invention can be applied not only as a cold-rolled steel sheet for processing but also as an original sheet of a surface-treated steel sheet for processing. Examples of the surface treatment include galvanization (including alloy system) and tin plating. The steel sheet of the present invention may be subjected to special treatment after annealing or galvanization to improve chemical conversion properties, weldability, press formability, corrosion resistance, and the like.
本発明において、成分組成範囲を上述のように規定した理由は次の通りである。なお、本明細書において鋼組成を示す「%」は特にことわりがない限り「質量%」である。
C:0.0005%以上0.0040%未満
CはNbと結合し、NbCの微細炭化物を形成する。C含有量を適正化することは微細なNbCを適当な体積率で析出させるため、かつ成形性を高めるために好ましい。微細に析出したNbCは熱延鋼板結晶粒径を微細化し、冷間圧延鋼板の焼鈍後のr値を向上させる効果がある。また、NbCは極めて微細に析出させることが出来るため、大きな析出強化の効果が得られ、Mn、P、Siなどの固溶元素の多量の添加を必要とせずに高強度化できる。
In the present invention, the reason why the component composition range is defined as described above is as follows. In this specification, “%” indicating the steel composition is “% by mass” unless otherwise specified.
C: 0.0005% or more and less than 0.0040% C combines with Nb to form fine carbides of NbC. It is preferable to optimize the C content in order to precipitate fine NbC at an appropriate volume ratio and to improve the moldability. Finely precipitated NbC has the effect of reducing the crystal grain size of the hot rolled steel sheet and improving the r value after annealing of the cold rolled steel sheet. In addition, since NbC can be precipitated very finely, a great effect of precipitation strengthening can be obtained, and the strength can be increased without requiring the addition of a large amount of solid solution elements such as Mn, P, and Si.
C含有量が0.0005%未満では耐二次加工脆性が劣化する場合がある。一方、C含有量が0.0040%以上になるとNbCが過剰に生成して焼鈍板の粒成長の抑制効果が過大となり、YSが上昇し伸びが低下して加工時に面歪みや割れを生じやすくなる。したがって、C含有量を0.0005%以上0.0040%未満とする。好ましい下限は0.0007%以上であり、好ましい上限は0.0035%以下である。 If the C content is less than 0.0005%, the secondary work brittleness resistance may deteriorate. On the other hand, when the C content is 0.0040% or more, NbC is excessively generated and the effect of suppressing the grain growth of the annealed sheet becomes excessive, YS rises and the elongation decreases, and surface distortion and cracking are likely to occur during processing. Become. Therefore, the C content is 0.0005% or more and less than 0.0040%. A preferable lower limit is 0.0007% or more, and a preferable upper limit is 0.0035% or less.
Si:0.5%以下
Siは、不純物として含有される元素であるが、低コストで固溶強化により鋼板を高強度化する有用な元素であるので、強度向上を目的として含有させることができる。但し、Si含有量が0.5%を超えるとスケール疵が生じやすくなる。また、YSが高くなり伸びが劣化して加工時に面歪みや割れが生じやすくなる。したがって、Si含有量を0.5%以下とする。より優れた外観性状を求める場合等には、Si含有量を0.25%以下とすることが好ましい。一方、Siはめっき密着性を向上させる作用を有するので、0.002%以上含有させることが好ましい。
Si: 0.5% or less Si is an element contained as an impurity, but it is a useful element for increasing the strength of a steel sheet by solid solution strengthening at a low cost, so it can be contained for the purpose of improving the strength. . However, when the Si content exceeds 0.5%, scale wrinkles are likely to occur. Moreover, YS becomes high and elongation deteriorates, and surface distortion and cracking are likely to occur during processing. Therefore, the Si content is 0.5% or less. When more excellent appearance properties are required, the Si content is preferably set to 0.25% or less. On the other hand, since Si has the effect | action which improves plating adhesiveness, it is preferable to make it contain 0.002% or more.
Mn:0.1〜2.5%
Mnは、固溶強化により鋼板を高強度化する作用を有する。Mn含有量が0.1%未満では、目的とする高強度化が図れない場合がある。一方、Mn含有量が2.5%超ではYSが上昇し伸びが劣化し加工時にしわや割れが生じやすくなる。このためMn含有量を0.1〜2.5%とする。加工性をさらに良好にするためには、Mn含有量を2.0%以下とすることが好ましい。引張強度390MPa以上を安定的に確保するために、Mn含有量を0.5%以上とすることが好ましい。
Mn: 0.1 to 2.5%
Mn has the effect of increasing the strength of the steel sheet by solid solution strengthening. If the Mn content is less than 0.1%, the intended increase in strength may not be achieved. On the other hand, if the Mn content exceeds 2.5%, YS increases and elongation deteriorates, and wrinkles and cracks are likely to occur during processing. Therefore, the Mn content is set to 0.1 to 2.5%. In order to further improve the workability, the Mn content is preferably set to 2.0% or less. In order to stably secure a tensile strength of 390 MPa or more, the Mn content is preferably 0.5% or more.
P:0.06%以下
Pは、r値の低下を抑えながら固溶強化により鋼板を高強度化する有用な元素であるので、強度向上を目的として含有させることができる。P含有量が0.06%を超えると、合金化溶融亜鉛めっき鋼板の場合には合金化処理性を低下させてめっき密着性を低下させたり、めっき表面にすじ模様を呈したりする場合がある。このため、P含有量を0.06%以下とする。390MPa以上の引張強度を安定的に確保するために、P含有量を0.03%以上とすることが好ましい。
P: 0.06% or less P is a useful element for increasing the strength of a steel sheet by solid solution strengthening while suppressing a decrease in r value, and can be contained for the purpose of improving the strength. When the P content exceeds 0.06%, in the case of an alloyed hot-dip galvanized steel sheet, the alloying processability may be lowered to lower the plating adhesion, or the surface of the plating may be striped. . For this reason, the P content is set to 0.06% or less. In order to stably secure a tensile strength of 390 MPa or more, the P content is preferably 0.03% or more.
S:0.05%以下
Sは不純物として鋼板中に存在するが、その含有量が多いとスケール疵が生じやすくなり表面外観を著しく劣化させる場合があるため、その含有量を0.05%以下とする。好ましくは0.03%以下である。
S: 0.05% or less S is present in the steel sheet as an impurity, but if the content is large, scale wrinkles are likely to occur and the surface appearance may be significantly deteriorated, so the content is 0.05% or less. And Preferably it is 0.03% or less.
sol.Al:0.005〜0.1%
Alは、脱酸のためsol.Al 0.1%以下となる量を含有させる。sol.Al含有量が0.005%未満では脱酸が不十分となり、0.1%を超えるとAlの固溶強化で鋼板が強化し延性が低下することがあるため、好ましくはAl含有量を0.005〜0.1%とする。
sol. Al: 0.005 to 0.1%
Al is sol. An amount of 0.1% or less of Al is contained. sol. If the Al content is less than 0.005%, deoxidation becomes insufficient, and if it exceeds 0.1%, the steel sheet may be strengthened by solid solution strengthening of Al and ductility may be lowered. 0.005 to 0.1%.
N:0.006%以下
Nは、過剰に含有するとYSが上昇して面歪みが生じやすくなったりFe中に固溶してストレッチャーストレインマークなどの表面欠陥を発生させる原因となったりする。このため、N含有量を0.006%以下とする。好ましくは0.0035%以下である。
N: 0.006% or less When N is excessively contained, YS rises and surface distortion is likely to occur, or it may cause solid defects in Fe and cause surface defects such as stretcher strain marks. For this reason, N content shall be 0.006% or less. Preferably it is 0.0035% or less.
Nb:0.04〜0.20%
Nbは、Cと結合してNbCの微細析出物を生成し、これにより組織を微細化し、機械的特性や表面性状を向上させる。NbはAr3点直下で炭化物を析出するため極めて微細な析出物が得られるという点で、本発明が目的とする効果を得る手段として炭化物生成元素の中で最も好適な元素である。一方、同じ炭化物生成元素であるTiは、Ar3点以上の高温で炭化物を析出するので、析出物が粗大となり、本発明が目的とする効果を得る手段としては不適切である。
Nb: 0.04 to 0.20%
Nb combines with C to produce NbC fine precipitates, thereby refining the structure and improving mechanical properties and surface properties. Nb is the most preferable element among the carbide-forming elements as a means for obtaining the intended effect of the present invention in that carbides are precipitated just below the Ar 3 point, so that very fine precipitates are obtained. On the other hand, Ti, which is the same carbide-forming element, precipitates carbide at a high temperature of Ar 3 or higher, so that the precipitate becomes coarse and is inappropriate as a means for obtaining the intended effect of the present invention.
したがってNbを適正に含有させることは本発明において重要である。Nb含有量が0.04%未満では、NbCの析出量が不足して340MPa以上の引張強度を安定的に確保することが困難になる場合がある。また、固溶Cが残留してストレッチャーストレインなどの表面欠陥が発生しやすくなる場合がある。一方、Nb含有量が0.20%を超えると、Cに比してNbが過剰となるために、YSが上昇し伸びが低下して加工時にしわが生じやすくなる。よって、Nb含有量を0.04〜0.20%とする。好ましくは、0.06〜0.10%である。 Therefore, it is important in the present invention to appropriately contain Nb. If the Nb content is less than 0.04%, the amount of NbC deposited may be insufficient, and it may be difficult to stably secure a tensile strength of 340 MPa or more. In addition, solid solution C may remain and surface defects such as stretcher strain are likely to occur. On the other hand, if the Nb content exceeds 0.20%, Nb becomes excessive as compared with C, so that YS increases and elongation decreases, and wrinkles are likely to occur during processing. Therefore, the Nb content is set to 0.04 to 0.20%. Preferably, it is 0.06 to 0.10%.
Ti:(N/14×48×0.5)%以上、(0.02+N/14×48)%以下
Tiは、NをTiNとして析出させることにより、NによるストレッチャーストレインやYSの上昇を抑制して加工時の面歪みを生じ難くする。また、圧延方向に対する角度が0°、45°、90°の3方向におけるr値の特性差(異方性)を小さくすることができるため、プレス加工時の割れやしわの発生を抑制することができる。これらの効果を得るためにTi含有量を[N(48/14)×0.5]、つまり(N/14×48×0.5)%以上とする。
Ti: (N / 14 × 48 × 0.5)% or more, (0.02 + N / 14 × 48)% or less Ti suppresses the rise of stretcher strain and YS due to N by precipitating N as TiN. This makes it difficult for surface distortion to occur during processing. Moreover, since the characteristic difference (anisotropy) of the r value in the three directions of 0 °, 45 °, and 90 ° with respect to the rolling direction can be reduced, the generation of cracks and wrinkles during pressing is suppressed. Can do. In order to obtain these effects, the Ti content is set to [N (48/14) × 0.5], that is, (N / 14 × 48 × 0.5)% or more.
しかしながら、(0.02+N/14×48)%を超えてTiを含有させると、TiCの析出量が増加して伸びを劣化させて加工時に面歪みや割れが生じやすくなる。また、溶融亜鉛めっき鋼板の場合にはめっき表面にすじ模様を呈する場合がある。このためTi含有量を[0.02+N(48/14)]、つまり(0.02+N/14×48)%以下とする。好ましくは(0.01+N/14×48)%以下である。 However, if Ti is contained in excess of (0.02 + N / 14 × 48)%, the amount of TiC deposited increases and the elongation deteriorates, and surface distortion and cracking are likely to occur during processing. Moreover, in the case of a hot dip galvanized steel sheet, a stripe pattern may be exhibited on the plating surface. Therefore, the Ti content is set to [0.02 + N (48/14)], that is, (0.02 + N / 14 × 48)% or less. Preferably, it is (0.01 + N / 14 × 48)% or less.
Nb/Ti:2以上、20以下
本発明が対象とする、自動車のサイドパネル、フード、ドア、フェンダー等の大型プレス部品の成形に最適な、圧延方向に対する角度が45°方向におけるr値を1.5以上とするためにNbとTiとの含有量の比(Nb/Ti)を2以上とする。45°方向におけるr値が1.5未満では、サイドパネル、フード、ドア、フェンダー等で最も成形が厳しいコーナー部の材料特性が不足する。また、このことを補償するために、より高グレードの鋼板を使用する必要が生じる。Nb/Tiが2未満では、45°方向におけるr値が1.5未満となる場合がある。
Nb / Ti: 2 or more and 20 or less The optimum value for molding large press parts such as automobile side panels, hoods, doors, and fenders, which is the object of the present invention, is an r value of 1 at an angle with respect to the rolling direction of 45 °. In order to make it 0.5 or more, the ratio of the content of Nb and Ti (Nb / Ti) is made 2 or more. If the r value in the 45 ° direction is less than 1.5, the material properties of the corner part, which is the most severely molded, in the side panels, hoods, doors, fenders and the like are insufficient. Moreover, in order to compensate for this, it is necessary to use a higher grade steel plate. If Nb / Ti is less than 2, the r value in the 45 ° direction may be less than 1.5.
一方、Nb/Tiが過剰に高いと、r値の最小値が1.0以下となる場合があるので、Nb/Tiの上限は20以下とする。
B:0.0020%以下
Bは二次加工脆化を防止する作用を有するので含有させることが好ましい。但し、B含有量が0.0020%を超えるとYSが上昇し伸びが低下して加工時にしわや割れが生じやすくなる。このためB含有量は0.0020%以下とする。好ましくは0.0010%以下である。上記作用を確実に得るには、B含有量を0.0001%以上とすることが好ましく、より好ましくは0.0003%以上である。
On the other hand, if Nb / Ti is excessively high, the minimum r value may be 1.0 or less, so the upper limit of Nb / Ti is 20 or less.
B: 0.0020% or less B is preferably contained because it has an effect of preventing secondary work embrittlement. However, if the B content exceeds 0.0020%, YS increases and elongation decreases, and wrinkles and cracks are likely to occur during processing. For this reason, B content shall be 0.0020% or less. Preferably it is 0.0010% or less. In order to reliably obtain the above action, the B content is preferably 0.0001% or more, and more preferably 0.0003% or more.
Cr:1%以下、Mo:1%以下、V:1%以下およびNi:1%以下から選ばれる1種または2種以上
これらの元素は強度確保のため含有させても良い。各元素の含有量が1%を超えると強度向上の効果が飽和してコストが嵩むため各元素の含有量を1%以下とする。好ましくは0.5%以下である。
One or more selected from Cr: 1% or less, Mo: 1% or less, V: 1% or less, and Ni: 1% or less. These elements may be contained for securing strength. If the content of each element exceeds 1%, the effect of improving the strength is saturated and the cost increases, so the content of each element is set to 1% or less. Preferably it is 0.5% or less.
本発明にかかる冷延鋼板の鋼組成は残部Feおよび不純物であるが、不純物としては、Cu,Ca,REMなどは合計0.1%以下は許容される。
このような鋼組成を有する冷延鋼板の機械特性は次の通りである。
The steel composition of the cold-rolled steel sheet according to the present invention is the balance Fe and impurities, but as impurities, Cu, Ca, REM, etc. are allowed to be 0.1% or less in total.
The mechanical properties of the cold rolled steel sheet having such a steel composition are as follows.
r値の最小値:1.0以上
ここに云うr値は圧延方向に対する角度が0°、45°および90°の3方向におけるr値であり、r値の最小値とはそれらの各方向におけるr値のうちの最小値を云う。
Minimum value of r value: 1.0 or more The r value mentioned here is an r value in three directions at angles of 0 °, 45 °, and 90 ° with respect to the rolling direction, and the minimum value of the r value is in each direction. This is the minimum value among the r values.
自動車のサイドパネル、フード、ドア、フェンダー等の成形において、圧延方向に対する角度が0°、45°および90°の3方向におけるr値の最小値が1.0より小さいと、r値が最小となる方向に主たる加工が加わる部位に於いて割れが生じる場合がある。したがって、圧延方向に対する角度が0°、45°および90°の3方向におけるr値の最小値を1.0以上とする。好ましくは1.2以上である。 In the molding of automobile side panels, hoods, doors, fenders, etc., the minimum r value in the three directions of 0 °, 45 ° and 90 ° with respect to the rolling direction is less than 1.0. In some cases, cracks may occur at the site where the main processing is applied in a certain direction. Accordingly, the minimum value of the r value in the three directions of 0 °, 45 ° and 90 ° with respect to the rolling direction is set to 1.0 or more. Preferably it is 1.2 or more.
圧延方向に対する角度が45°方向におけるr値:1.5以上
圧延方向に対する角度が45°方向におけるr値が1.5未満では、自動車のサイドパネル、フード、ドア、フェンダー等の成形において、コーナー部にしわや割れが発生し易くなる。したがって、圧延方向に対する角度が45°方向におけるr値を1.5以上とする。
R value when the angle to the rolling direction is 45 °: 1.5 or more If the r value is less than 1.5 when the angle to the rolling direction is less than 1.5, it is a corner when molding automobile side panels, hoods, doors, fenders, etc. Wrinkles and cracks are likely to occur in the part. Therefore, the r value when the angle with respect to the rolling direction is 45 ° is 1.5 or more.
次に、上記にて説明した高強度冷延鋼板・高強度溶融亜鉛めっき鋼板を製造するための好適な製造方法を以下に説明する。
(1)熱間圧延工程
熱間圧延開始温度:1100〜1280℃
上記の鋼組成を備える鋼塊または鋼片を1100〜1280℃とした後に熱間圧延を施す。ここで、前記鋼塊または鋼片は、1100℃未満の温度にあるものを再加熱して1100〜1280℃として熱間圧延に供してもよいし、連続鋳造スラブを用いる場合には連続鋳造後1100℃未満に低下させることなく1100〜1280℃とした後に熱間圧延に供してもよいし、鋼片を用いる場合には分塊圧延後の鋼片を1100℃未満に低下させることなく1100〜1280℃とした後に熱間圧延に供してもよい。
Next, the suitable manufacturing method for manufacturing the high intensity | strength cold-rolled steel plate and high-strength hot-dip galvanized steel plate demonstrated above is demonstrated below.
(1) Hot rolling process Hot rolling start temperature: 1100 to 1280 ° C
Hot rolling is performed after the steel ingot or steel slab having the above steel composition is set to 1100 to 1280 ° C. Here, the steel ingot or steel slab may be reheated to a temperature of less than 1100 ° C. and subjected to hot rolling at 1100 to 1280 ° C., or after continuous casting when a continuous casting slab is used. You may use for hot rolling, after making it 1100-1280 degreeC, without reducing it to less than 1100 degreeC, and when using a steel piece, 1100 without reducing the steel piece after partial rolling to less than 1100 degreeC. You may use for hot rolling after setting it as 1280 degreeC.
熱間圧延に供する鋼塊または鋼片が1100℃未満の場合には変形抵抗が高く熱間圧延が困難となる場合があり、1280℃を超える場合には過剰なスケールが生成し冷延後まで残留して表面性状を劣化させる場合がある。 When the steel ingot or steel slab to be subjected to hot rolling is less than 1100 ° C, deformation resistance may be high and hot rolling may be difficult, and when it exceeds 1280 ° C, an excessive scale is generated until after cold rolling. It may remain and deteriorate the surface properties.
このため、熱間圧延に供する鋼塊または鋼片の温度を1100〜1280℃とすることが好ましい。
熱間圧延完了温度:Ar3点〜1000℃
熱間圧延完了温度(以下、「仕上温度」または「FT」ともいう。)がAr3点未満の場合には、表層がフェライト化して熱延組織が粗大化するため製品段階におけるr値が低下して加工時に割れが生じたり、溶融亜鉛めっき鋼板についてはめっき表面にすじ模様を呈したりする場合がある。
For this reason, it is preferable that the temperature of the steel ingot or steel slab used for hot rolling shall be 1100-1280 degreeC.
Hot rolling completion temperature: Ar 3 points to 1000 ° C
When the hot rolling completion temperature (hereinafter also referred to as “finishing temperature” or “FT”) is less than Ar 3 points, the surface layer becomes ferritic and the hot rolled structure becomes coarse, so the r value in the product stage decreases. As a result, cracking may occur during processing, or the hot dip galvanized steel sheet may exhibit a streak pattern on the plated surface.
一方、熱間圧延完了温度が1000℃を超える場合には、熱延組織の微細化が困難となるため製品段階におけるr値が低下して加工時に割れが生じたり、スケールにより表面性状が劣化したりする場合がある。 On the other hand, when the hot rolling completion temperature exceeds 1000 ° C., it is difficult to refine the hot-rolled structure, so the r value in the product stage is lowered and cracking occurs during processing, or the surface properties are deteriorated by the scale. Sometimes.
したがって、熱間圧延完了温度をAr3点〜1000℃とすることが好ましい。
巻取温度:400〜650℃
巻取温度が400℃未満では、巻取り後におけるNbCが生成が不十分となり、本発明が目的とするNbCの効果を十分に享受することができずにr値が低下する場合があり加工時に割れが生じやすくなる。
Therefore, it is preferable that the hot rolling completion temperature is Ar 3 points to 1000 ° C.
Winding temperature: 400-650 ° C
When the coiling temperature is less than 400 ° C., NbC is not sufficiently formed after winding, and the r value may be lowered during processing because the NbC intended by the present invention cannot be fully enjoyed. Cracks are likely to occur.
一方、巻取温度が650℃超の場合には、r値が低下する。
したがって、巻取温度は400〜650℃とすることが好ましい。
(2)酸洗工程、冷間圧延工程、焼鈍工程
熱間圧延により得られる熱間圧延鋼板は、酸洗により脱スケールされ、冷間圧延が施された後に焼鈍が施される。高強度溶融亜鉛めっき鋼板については、さらに溶融亜鉛めっきが施され、必要に応じて合金化処理が施される。
On the other hand, when the coiling temperature exceeds 650 ° C., the r value decreases.
Therefore, the winding temperature is preferably 400 to 650 ° C.
(2) Pickling step, cold rolling step, annealing step A hot rolled steel sheet obtained by hot rolling is descaled by pickling and is annealed after cold rolling. The high-strength hot-dip galvanized steel sheet is further subjected to hot-dip galvanization, and an alloying treatment is performed as necessary.
酸洗は常法で構わない。
冷間圧延は焼鈍後のr値を向上させるため圧下率を50%以上とする。
焼鈍は、高いr値を得るために、焼鈍温度:780〜900℃として行う。焼鈍温度が780℃未満ではYSが上昇しr値が不十分となって加工時に面歪みや割れが生じやすくなり、900℃を超えるとYSが上昇して加工時に面歪みや割れが生じる場合がある。このため、焼鈍温度を780〜900℃とする。
Pickling may be performed by a conventional method.
In cold rolling, the rolling reduction is set to 50% or more in order to improve the r value after annealing.
Annealing is performed at an annealing temperature of 780 to 900 ° C. in order to obtain a high r value. When the annealing temperature is less than 780 ° C., YS increases and the r value becomes insufficient, and surface distortion and cracking are likely to occur during processing. When it exceeds 900 ° C., YS increases and surface distortion and cracking may occur during processing. is there. For this reason, an annealing temperature shall be 780-900 degreeC.
(3)溶融亜鉛めっき工程
溶融亜鉛めっき鋼板を製造する場合には、その後溶融亜鉛めっきを施す。溶融亜鉛めっきの方法は常法で構わないが、連続溶融亜鉛めっきラインを用いて、前記焼鈍工程と前記溶融亜鉛めっき工程を連続して行うことが生産性の観点から好ましい。また、溶融亜鉛めっきを施した後に合金化処理を行ってもよい。合金化処理も常法で構わない。なお、本発明における溶融亜鉛めっき鋼板には、合金化溶融亜鉛めっき鋼板も含む。
(3) Hot dip galvanizing process When manufacturing a hot dip galvanized steel sheet, hot dip galvanization is performed after that. Although the method of hot dip galvanization may be a conventional method, it is preferable from the viewpoint of productivity to perform the annealing step and the hot dip galvanizing step continuously using a continuous hot dip galvanizing line. Further, the alloying treatment may be performed after hot dip galvanization. Alloying treatment may be performed by a conventional method. In addition, the galvanized steel sheet in the present invention includes an alloyed galvanized steel sheet.
かくして本発明によれば、成形性に優れるとともにすじ模様などの外観不良のみられない表面性状にすぐれた引張強度340MPa以上の高強度溶融亜鉛めっき鋼板および合金化溶融亜鉛めっき鋼板が得られる。 Thus, according to the present invention, it is possible to obtain a high-strength hot-dip galvanized steel sheet and an alloyed hot-dip galvanized steel sheet having a tensile strength of 340 MPa or more, which have excellent formability and excellent surface properties such as streak patterns.
また、本発明における冷延鋼板には、その後に表面処理を施すことにより得られる、電気亜鉛めっき鋼板、すずめっき鋼板、塗装鋼板その他の表面処理用鋼板が含まれる。これらの表面処理方法は常法で構わない。 Moreover, the cold-rolled steel sheet in the present invention includes an electrogalvanized steel sheet, a tin-plated steel sheet, a coated steel sheet, and other surface-treated steel sheets obtained by performing a surface treatment thereafter. These surface treatment methods may be conventional methods.
表1に示す化学成分を含有する供試材である鋼No.1〜39の鋼板を試作し、表2に示す条件で、スラブ加熱後、熱間圧延により粗圧延後板厚40mm、仕上圧延後板厚3.2mmとし、その後、冷却して巻き取った。さらに0.65mmまで冷間圧延を行い、連続焼鈍ラインにて連続焼鈍を施し、冷却後、0.6%の伸率の調質圧延を施した。 Steel No. which is a test material containing chemical components shown in Table 1. Trial steel plates 1 to 39 were manufactured, and under the conditions shown in Table 2, after slab heating, hot rolled to a thickness of 40 mm after rough rolling and a thickness of 3.2 mm after finish rolling, and then cooled and wound up. Further, cold rolling was performed to 0.65 mm, continuous annealing was performed in a continuous annealing line, and after cooling, temper rolling with an elongation of 0.6% was performed.
得られた供試材について耐二次加工脆性(縦割れ発生温度)、表面性状、および成形性を調査した。 The obtained specimens were investigated for secondary work brittleness resistance (longitudinal crack initiation temperature), surface properties, and moldability.
結果は、同じく表2にまとめて示す。
耐二次加工脆性は、得られた冷延鋼板から90mmφの試験片を採取し,直径50mmの円筒ポンチを用いてしぼり比1.8で絞り加工を行い、各種温度に5分以上保持した後、円錐台にセットして52.6kgの錘を1.901mの高さから落錘させ、破面観察から脆性破断が発生する上限温度を縦割れ発生温度として求め評価した。
The results are also summarized in Table 2.
Secondary work brittleness resistance is obtained by collecting a 90 mmφ test piece from the obtained cold-rolled steel sheet, performing drawing with a squeezing ratio of 1.8 using a cylindrical punch with a diameter of 50 mm, and holding at various temperatures for 5 minutes or more. Then, a 52.6 kg weight was dropped from a height of 1.901 m by setting on a truncated cone, and the upper limit temperature at which brittle fracture occurred was determined from the fracture surface observation and evaluated as the vertical crack initiation temperature.
表面性状は、冷延鋼板表面の外観を自動車外装用途の基準を満たすか否か、すなわち、すじ模様やスケール欠陥の有無を目視で判定した。欠陥のない場合を「OK」とした。
成形性は、図2に示すように、サイドパネルのセンターピラー部を模したT字型試験片を用いて、絞り深さ25mmでプレス加工を施し、割れ、しわ、面歪みの有無を評価した。それらの表面欠陥のない場合も「OK」とした。なお、図2中の数字は寸法(mm)を示す。
The surface properties were determined by visual observation of whether or not the appearance of the cold-rolled steel sheet surface satisfies the standards for automotive exterior applications, that is, the presence or absence of streaks or scale defects. The case where there was no defect was defined as “OK”.
As shown in FIG. 2, the formability was evaluated by using a T-shaped test piece simulating the center pillar portion of the side panel at a drawing depth of 25 mm and evaluating the presence of cracks, wrinkles, and surface distortion. . The case where there was no surface defect was also “OK”. In addition, the number in FIG. 2 shows a dimension (mm).
また、表1に示す化学成分を含有する供試材である鋼No.1〜39の鋼板を試作し、表3に示す条件で、スラブ加熱後、熱間圧延により粗圧延後板厚40mm、仕上圧延後板厚3.2mmとし、その後、冷却して巻き取った。さらに0.65mmまで冷間圧延を行い、連続溶融めっきラインにて連続焼鈍を施した後、片面当り45g/m2の溶融亜鉛めっきを施し、470〜550℃で合金化処理を行い、冷却後、0.6%の伸率の調質圧延を施した。 Moreover, steel No. which is a test material containing the chemical components shown in Table 1. 1 to 39 steel plates were manufactured, and under the conditions shown in Table 3, after slab heating, hot rolled to a thickness of 40 mm after rough rolling and a thickness of 3.2 mm after finish rolling, and then cooled and wound up. Furthermore, after cold rolling to 0.65 mm and continuous annealing in a continuous hot dipping line, 45 g / m 2 hot dip galvanizing is applied per side, alloying is performed at 470 to 550 ° C., and after cooling Then, temper rolling with an elongation of 0.6% was performed.
得られた供試材について、合金化度、めっき密着性、耐二次加工脆性、表面性状および成形性を調査した。 The obtained specimens were investigated for alloying degree, plating adhesion, secondary work brittleness resistance, surface properties and formability.
結果は、同じく表3にまとめて示す。
合金化度はめっき層のFe含有量(質量%)で示す。
めっき密着性は、めっき鋼板について90mmφの試験片を採取し、50mmφのポンチでカップ成形を行い、縦壁部にセロテープ(登録商標)を接着、剥離し、テープに付着した剥離めっき量を自動車外装用途として基準を満たすか否かにより判定した。「OK」は剥離量25mg/個以下の場合を云う。
The results are also summarized in Table 3.
The degree of alloying is indicated by the Fe content (% by mass) of the plating layer.
For plating adhesion, a 90 mmφ test piece was taken from the plated steel sheet, cup-formed with a 50 mmφ punch, and cello tape (registered trademark) was adhered to and peeled from the vertical wall. Judgment was made based on whether or not the standard was satisfied as an application. “OK” refers to the case where the peel amount is 25 mg / piece or less.
表面性状は、めっき表面の外観を自動車外装用途の基準を満たすか否か、すなわち、すじ模様やスケール欠陥の有無を目視で判定した。欠陥のない場合を「OK」とした。
耐二次加工脆性(縦割り発生温度)および成形性は、実施例1と同一の方法により評価を行った。
The surface properties were determined by visual observation of whether the appearance of the plating surface satisfies the standards for automotive exterior applications, that is, the presence or absence of streaks or scale defects. The case where there was no defect was defined as “OK”.
Secondary processing brittleness resistance (vertical split generation temperature) and formability were evaluated by the same method as in Example 1.
本発明の成分範囲の鋼板は強度、r値、表面外観のすべてに優れ、自動車外板用に最適である。
No.24は、C含有量が高いため、YSが高く伸びが低く、成形において面歪みが発生した。
The steel sheet of the component range of the present invention is excellent in all of strength, r value, and surface appearance, and is optimal for an automobile outer plate.
No. No. 24 had a high C content, so YS was high and elongation was low, and surface distortion occurred during molding.
No.25は、Si含有量が高いため、スケールにより表面性状が不芳であった。また、めっき密着性が不芳であった。
No.26は、Mn含有量が高いため、YSが高く伸び、r値が低いため、成形において割れが発生した。
No. No. 25 had a poor surface property due to the scale because of its high Si content. Further, the plating adhesion was unsatisfactory.
No. In No. 26, since the Mn content was high, YS was highly elongated and the r value was low, so that cracking occurred during molding.
No.27はPが高いため、鋼板の表面にすじ模様が生じた。また、めっき密着性が不芳であった。
No.28は、S含有量が高いため、スケールにより表面性状が不芳であった。
No. Since No. 27 had a high P, a streak pattern occurred on the surface of the steel sheet. Further, the plating adhesion was unsatisfactory.
No. No. 28 had a poor surface property due to the scale because of its high S content.
No.29は、Ti含有量が低いため、0°方向のr値が低く、成形において割れが生じた。
No.30は、Ti含有量が高いため、鋼板の表面にすじ模様が生じた。
No. No. 29 has a low Ti value, so the r value in the 0 ° direction was low, and cracking occurred during molding.
No. Since No. 30 had a high Ti content, a streak pattern was generated on the surface of the steel sheet.
No.31は、Nb含有量が低いため、45°方向のr値が1.5未満と低く、成形において割れが発生した。
No.32は、Nb含有量が高いため、YSが高く伸びも低いため、成形において割れが発生した。
No. No. 31 had a low Nb content, so the r value in the 45 ° direction was as low as less than 1.5, and cracking occurred during molding.
No. Since No. 32 had a high Nb content, YS was high and elongation was low, so that cracking occurred in molding.
No.33は、N含有量が高いため、YSが高く、成形において面歪みが発生した。
No.34は、B含有量が高いため、0°方向のr値が他の方向のr値に比して著しく低く、また伸びも低いため、成形において割れが発生した。
No. Since No. 33 had a high N content, YS was high, and surface distortion occurred during molding.
No. Since No. 34 has a high B content, the r value in the 0 ° direction is remarkably lower than the r value in the other directions, and the elongation is also low.
No.35〜37は、Nb/Tiが低いため、45°方向のr値が1.5未満であり、成形において割れが発生した。
No.38、39は、Nb/Tiが高いため、0°方向のr値が低く、成形において割れが発生した。
No. Nos. 35 to 37 have a low Nb / Ti, so that the r value in the 45 ° direction was less than 1.5, and cracking occurred during molding.
No. Nos. 38 and 39 had high Nb / Ti, so the r value in the 0 ° direction was low, and cracking occurred in molding.
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