JP2007184353A5 - - Google Patents

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JP2007184353A5
JP2007184353A5 JP2006000533A JP2006000533A JP2007184353A5 JP 2007184353 A5 JP2007184353 A5 JP 2007184353A5 JP 2006000533 A JP2006000533 A JP 2006000533A JP 2006000533 A JP2006000533 A JP 2006000533A JP 2007184353 A5 JP2007184353 A5 JP 2007184353A5
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Prior art keywords
nitride
compound semiconductor
gas
based compound
stacking
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JP2006000533A
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Japanese (ja)
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JP4767020B2 (en
JP2007184353A (en
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Priority claimed from JP2006000533A external-priority patent/JP4767020B2/en
Publication of JP2007184353A publication Critical patent/JP2007184353A/en
Publication of JP2007184353A5 publication Critical patent/JP2007184353A5/ja
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Publication of JP4767020B2 publication Critical patent/JP4767020B2/en
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Claims (5)

基板の上に、窒化物系化合物半導体からなるn型クラッド層を積層する第1積層工程と、
前記n型クラッド層の上に、窒化物系化合物半導体からなる活性層を積層する第2積層工程と、
900℃以上1100℃以下の温度において、窒素ガスと水素ガスとアンモニアガスとを供給しながら、前記活性層の上に、Mgを含有する窒化物系化合物半導体からなるp型クラッド層及びMgを含有する窒化物系化合物半導体からなるp型キャップ層をこの順番に積層して、積層体を形成する第3積層工程と、
前記第3積層工程の後、前記水素ガス及び前記アンモニアガスの供給を停止する一方、前記窒素ガスまたは該窒素ガス及び希ガスを供給し、前記積層体を900℃以上1100℃以下の温度から450℃以上550℃以下の温度にまで冷却させる冷却工程と、
450℃以上550℃以下の温度にまで冷却された積層体を室温にまで放冷させる放冷工程と
を備え、
前記冷却工程では、
800℃以上で、供給するガスの量を、前記第3積層工程で供給する前記窒素ガスの量と前記水素ガスの量との合計量以上にまで増加させ、
70℃/分以上100℃/分以下の冷却速度で前記積層体を450℃以上550℃以下の温度にまで冷却させることを特徴とする窒化物系化合物半導体素子の製造方法。
A first stacking step of stacking an n-type cladding layer made of a nitride-based compound semiconductor on a substrate;
A second stacking step of stacking an active layer made of a nitride-based compound semiconductor on the n-type cladding layer;
While supplying nitrogen gas, hydrogen gas and ammonia gas at a temperature of 900 ° C. or higher and 1100 ° C. or lower, a p-type cladding layer made of a nitride compound semiconductor containing Mg and Mg is contained on the active layer A p-type cap layer made of a nitride compound semiconductor to be laminated in this order to form a laminated body;
After the third stacking step, the supply of the hydrogen gas and the ammonia gas is stopped, while the nitrogen gas or the nitrogen gas and the rare gas are supplied, and the stack is heated from 900 ° C. to 1100 ° C. to 450 ° C. A cooling step of cooling to a temperature of 550C to 550C;
A cooling step of cooling the laminated body cooled to a temperature of 450 ° C. or higher and 550 ° C. or lower to room temperature,
In the cooling step ,
Increasing the amount of gas supplied at 800 ° C. or higher to a total amount of the amount of nitrogen gas and the amount of hydrogen gas supplied in the third stacking step ,
A method for producing a nitride-based compound semiconductor device , wherein the laminate is cooled to a temperature of 450 ° C. to 550 ° C. at a cooling rate of 70 ° C./min to 100 ° C./min .
前記第3積層工程では、5%(体積百分率)以下の前記希ガスを含むガスを供給することを特徴とする請求項1に記載の窒化物系化合物半導体素子の製造方法。   2. The method for producing a nitride-based compound semiconductor device according to claim 1, wherein in the third stacking step, a gas containing the rare gas of 5% (volume percentage) or less is supplied. 前記基板として、窒化物系化合物半導体からなるとともにその貫通転位密度が面内で略均一であり3×10cm−2以下である基板を用いることを特徴とする請求項1に記載の窒化物系化合物半導体素子の製造方法。 2. The nitride according to claim 1, wherein the substrate is made of a nitride-based compound semiconductor and has a threading dislocation density that is substantially uniform in a plane and is 3 × 10 6 cm −2 or less. For manufacturing a semiconductor compound semiconductor device. 前記第3積層工程では、前記p型キャップ層の含有Mg濃度を前記p型クラッド層の含有Mg濃度の3倍以上20倍以下とするとともに、該p型キャップ層の層厚を60nm以上とすることを特徴とする請求項1に記載の窒化物系化合物半導体素子の製造方法。   In the third stacking step, the Mg concentration of the p-type cap layer is set to 3 to 20 times the Mg concentration of the p-type cladding layer, and the thickness of the p-type cap layer is set to 60 nm or more. The method for producing a nitride-based compound semiconductor device according to claim 1. さらに、前記冷却工程の後に、冷却された積層体を450℃以上550℃以下の温度で加熱するアニール工程を備えていることを特徴とする請求項1に記載の窒化物系化合物半導体素子の製造方法。 2. The method for producing a nitride-based compound semiconductor device according to claim 1, further comprising an annealing step for heating the cooled laminated body at a temperature of 450 ° C. or higher and 550 ° C. or lower after the cooling step. Method.
JP2006000533A 2006-01-05 2006-01-05 Method of manufacturing nitride compound semiconductor device Expired - Fee Related JP4767020B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006000533A JP4767020B2 (en) 2006-01-05 2006-01-05 Method of manufacturing nitride compound semiconductor device

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Application Number Priority Date Filing Date Title
JP2006000533A JP4767020B2 (en) 2006-01-05 2006-01-05 Method of manufacturing nitride compound semiconductor device

Publications (3)

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JP2007184353A JP2007184353A (en) 2007-07-19
JP2007184353A5 true JP2007184353A5 (en) 2008-11-27
JP4767020B2 JP4767020B2 (en) 2011-09-07

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Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4845055B2 (en) * 2008-03-07 2011-12-28 古河電気工業株式会社 Surface emitting laser device manufacturing method and surface emitting laser device
JP5206699B2 (en) 2010-01-18 2013-06-12 住友電気工業株式会社 Group III nitride semiconductor laser device and method of manufacturing group III nitride semiconductor laser device
JP4475357B1 (en) * 2009-06-17 2010-06-09 住友電気工業株式会社 Group III nitride semiconductor laser device and method of manufacturing group III nitride semiconductor laser device
US7933303B2 (en) 2009-06-17 2011-04-26 Sumitomo Electric Industries, Ltd. Group-III nitride semiconductor laser device, and method for fabricating group-III nitride semiconductor laser device
JP2011023398A (en) * 2009-07-13 2011-02-03 Sharp Corp Semiconductor light-emitting element
JP5131266B2 (en) 2009-12-25 2013-01-30 住友電気工業株式会社 Group III nitride semiconductor laser device and method of manufacturing group III nitride semiconductor laser device
JP5327154B2 (en) 2009-12-25 2013-10-30 住友電気工業株式会社 Group III nitride semiconductor laser device and method of manufacturing group III nitride semiconductor laser device
JP5201129B2 (en) 2009-12-25 2013-06-05 住友電気工業株式会社 Group III nitride semiconductor laser device and method of manufacturing group III nitride semiconductor laser device
JP5625355B2 (en) 2010-01-07 2014-11-19 住友電気工業株式会社 Group III nitride semiconductor laser device and method for manufacturing group III nitride semiconductor laser device
JP5152393B2 (en) * 2011-10-26 2013-02-27 住友電気工業株式会社 Group III nitride semiconductor laser device and method of manufacturing group III nitride semiconductor laser device
JP5152391B2 (en) * 2011-10-26 2013-02-27 住友電気工業株式会社 Group III nitride semiconductor laser device
JP5152392B2 (en) * 2011-10-26 2013-02-27 住友電気工業株式会社 Group III nitride semiconductor laser device
JPWO2016143653A1 (en) * 2015-03-06 2018-01-18 スタンレー電気株式会社 Group III nitride laminate and light emitting device having the laminate
US10529561B2 (en) * 2015-12-28 2020-01-07 Texas Instruments Incorporated Method of fabricating non-etch gas cooled epitaxial stack for group IIIA-N devices

Family Cites Families (4)

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JP2919788B2 (en) * 1995-08-31 1999-07-19 株式会社東芝 Semiconductor device, method of manufacturing semiconductor device, and method of growing gallium nitride based semiconductor
JP4103309B2 (en) * 2000-07-13 2008-06-18 松下電器産業株式会社 Method for manufacturing p-type nitride semiconductor
US20020157596A1 (en) * 2001-04-30 2002-10-31 Stockman Stephen A. Forming low resistivity p-type gallium nitride
JP4397695B2 (en) * 2003-01-20 2010-01-13 パナソニック株式会社 Method for manufacturing group III nitride substrate

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