JP2011238714A5 - - Google Patents

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JP2011238714A5
JP2011238714A5 JP2010107764A JP2010107764A JP2011238714A5 JP 2011238714 A5 JP2011238714 A5 JP 2011238714A5 JP 2010107764 A JP2010107764 A JP 2010107764A JP 2010107764 A JP2010107764 A JP 2010107764A JP 2011238714 A5 JP2011238714 A5 JP 2011238714A5
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precursor composition
functional
manufacturing
functional device
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JP2011238714A (en
JP5198506B2 (en
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Priority claimed from JP2010107764A external-priority patent/JP5198506B2/en
Priority to JP2010107764A priority Critical patent/JP5198506B2/en
Priority to US13/696,551 priority patent/US9202895B2/en
Priority to CN201180021920.6A priority patent/CN102870245B/en
Priority to PCT/JP2011/060581 priority patent/WO2011138958A1/en
Priority to KR1020127031785A priority patent/KR101442943B1/en
Priority to TW100116093A priority patent/TWI514585B/en
Publication of JP2011238714A publication Critical patent/JP2011238714A/en
Publication of JP2011238714A5 publication Critical patent/JP2011238714A5/ja
Publication of JP5198506B2 publication Critical patent/JP5198506B2/en
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Priority to US14/531,723 priority patent/US9123752B2/en
Expired - Fee Related legal-status Critical Current
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Claims (17)

熱処理することにより金属酸化物セラミックス又は金属からなる機能性固体材料となる機能性液体材料を準備する第1工程と、
基材上に前記機能性液体材料を塗布することにより、前記機能性固体材料の前駆体組成物層を形成する第2工程と、
前記前駆体組成物層を80℃〜200℃の範囲内にある第1温度に加熱することにより、前記前駆体組成物層の流動性を予め低くしておく第3工程と、
前記前駆体組成物層を80℃〜300℃の範囲内にある第2温度に加熱した状態で前記前駆体組成物層に対して、80℃〜300℃の範囲内にある第4温度に加熱した型を用いて型押し加工を施すことにより、前記前駆体組成物層に型押し構造を形成する第4工程と、
前記前駆体組成物層を前記第2温度よりも高い第3温度で熱処理することにより、前記前駆体組成物層から前記機能性固体材料層を形成する第5工程とをこの順序で含む
機能性デバイスの製造方法。
A first step of preparing a functional liquid material to be a functional solid material made of metal oxide ceramics or metal by heat treatment;
A second step of forming a precursor composition layer of the functional solid material by applying the functional liquid material on a substrate;
A third step of preliminarily lowering the fluidity of the precursor composition layer by heating the precursor composition layer to a first temperature in the range of 80 ° C. to 200 ° C .;
Heating the precursor composition layer to a fourth temperature in the range of 80 ° C. to 300 ° C. with the precursor composition layer heated to a second temperature in the range of 80 ° C. to 300 ° C. A fourth step of forming a stamping structure in the precursor composition layer by performing a stamping process using the mold that has been performed;
A fifth step of forming the functional solid material layer from the precursor composition layer by heat-treating the precursor composition layer at a third temperature higher than the second temperature in this order .
A method for manufacturing a functional device.
記第4工程においては、1MPa〜20MPaの範囲内にある圧力で型押し加工を施す
請求項1に記載の機能性デバイスの製造方法
Before SL in the fourth step is subjected to embossing at a pressure in the range of 1MPa~20MPa,
The manufacturing method of the functional device of Claim 1 .
記第4工程においては、少なくとも前記前駆体組成物層の表面に対する離型処理又は前記型の型押し面に対する離型処理を施した後、前記前駆体組成物層に対して型押し加工を施す
請求項1又は請求項2に記載の機能性デバイスの製造方法。
In the prior SL fourth step, after applying a release treatment to at least the backside treatment to the surface of the precursor composition layer or embossing surface of the mold, the embossing relative to the precursor composition layer Apply ,
The manufacturing method of the functional device of Claim 1 or Claim 2.
記機能性液体材料は、
金属アルコキシドを含有する溶液、
金属有機酸塩を含有する溶液、
金属無機酸塩を含有する溶液、
金属ハロゲン化物を含有する溶液、
金属、窒素及び水素を含有する無機化合物を含有する溶液、
金属水素化物を含有する溶液、
金属ナノ粒子を含有する溶液又は
セラミックス微粒子を含有する溶液である
請求項1〜請求項3のいずれか1項に記載の機能性デバイスの製造方法。
Before Symbol functional liquid material,
A solution containing a metal alkoxide,
A solution containing a metal organic acid salt,
A solution containing a metal inorganic acid salt,
A solution containing a metal halide,
A solution containing an inorganic compound containing metal, nitrogen and hydrogen,
A solution containing a metal hydride,
A solution containing metal nanoparticles or a solution containing ceramic fine particles ,
The manufacturing method of the functional device of any one of Claims 1-3.
記機能性液体材料は、金属アルコキシドを含有する溶液、金属有機酸塩を含有する溶液又は金属無機酸塩を含有する溶液であり、
前記第4工程における前記前駆体組成物層から前記機能性固体材料層への体積収縮率は、30%〜90%の範囲内にある
請求項4に記載の機能性デバイスの製造方法。
Before Symbol functional liquid material, a solution containing a metal alkoxide, a solution containing a solution or metal inorganic salt containing a metal organic acid salt,
The volume shrinkage rate from the precursor composition layer to the functional solid material layer in the fourth step is in the range of 30% to 90% .
The manufacturing method of the functional device of Claim 4.
記機能性液体材料は、金属ハロゲン化物を含有する溶液、金属、窒素及び水素を含有する無機化合物を含有する溶液、金属水素化物を含有する溶液、金属ナノ粒子を含有する溶液又はセラミックス微粒子を含有する溶液であり、
前記第5工程における前記前駆体組成物層から前記機能性固体材料層への体積収縮率は、1%〜30%の範囲内にある
請求項4に記載の機能性デバイスの製造方法。
Before Symbol functional liquid material, a solution containing a metal halide, a metal, nitrogen and a solution containing an inorganic compound containing hydrogen, the solution containing the metal hydride, the solution or ceramic fine particles containing metal nanoparticles A solution containing
The volume shrinkage ratio from the precursor composition layer to the functional solid material layer in the fifth step is in the range of 1% to 30% .
The manufacturing method of the functional device of Claim 4.
記第5工程においては、酸素含有雰囲気で熱処理することにより、金属酸化物セラミックスからなる機能性固体材料層を形成する
請求項4〜請求項6のいずれか1項に記載の機能性デバイスの製造方法
In the prior SL fifth step, by heat treatment in an oxygen-containing atmosphere to form a functional solid material layer comprising a metal oxide ceramics,
The manufacturing method of the functional device of any one of Claims 4-6 .
前記第5工程においては、還元雰囲気で熱処理することにより、金属からなる機能性固体材料層を形成する、
請求項4〜請求項6のいずれか1項に記載の機能性デバイスの製造方法。
In the fifth step, a functional solid material layer made of metal is formed by heat treatment in a reducing atmosphere.
The manufacturing method of the functional device of any one of Claims 4-6.
記第4工程においては、前記第5工程における熱処理により、最も層厚が薄い領域でクラックが発生するような型押し構造を形成する
請求項1〜請求項8のいずれか1項に記載の機能性デバイスの製造方法
In the prior SL fourth step, by heat treatment in the fifth step, to form embossed structure as cracks most layer is thin region,
The manufacturing method of the functional device of any one of Claims 1-8 .
記第4工程と前記第5工程との間に、型押し加工が施された前記前駆体組成物層のうち最も層厚が薄い領域において前記前駆体組成物層が完全に除去されるような条件で、前記前駆体組成物層を全体的にエッチングする工程をさらに含む
請求項1〜請求項8のいずれか1項に記載の機能性デバイスの製造方法
Between the front Symbol fourth step and the fifth step, so that the in the region most layer thickness is small of the precursor composition layer embossing is applied precursor composition layer is completely removed Further comprising a step of etching the precursor composition layer entirely under various conditions .
The manufacturing method of the functional device of any one of Claims 1-8 .
記第2工程においては、前記基材として、表面に前記前駆体組成物層に対する親和性の異なる2つの領域を有する基材を用い、
前記第4工程においては、前記2つの領域のうち前記前駆体組成物層に対する親和性が相対的に高い第1領域においては、前記2つの領域のうち前記前駆体組成物層に対する親和性が相対的に低い第2領域においてよりも層厚が厚くなるように、前記前駆体組成物層に型押し構造を形成する
請求項9又は請求項10に記載の機能性デバイスの製造方法。
In the prior SL second step, as the substrate, using a substrate having two regions with different affinities for the precursor composition layer on the surface,
In the fourth step, in the first region having a relatively high affinity for the precursor composition layer in the two regions, the affinity for the precursor composition layer in the two regions is relatively high. Forming an embossed structure in the precursor composition layer such that the layer thickness is greater than in the lower second region ,
The manufacturing method of the functional device of Claim 9 or Claim 10.
前記機能性デバイスは、薄膜トランジスタであり、
前記機能性固体材料層は、前記薄膜トランジスタにおけるゲート電極層、ゲート絶縁層、ソース層、ドレイン層、チャネル層及び配線層のうち少なくとも1つの層である
請求項1〜請求項11のいずれか1項に記載の機能性デバイスの製造方法。
The functional device is a thin film transistor;
The functional solid material layer is at least one of a gate electrode layer, a gate insulating layer, a source layer, a drain layer, a channel layer, and a wiring layer in the thin film transistor .
The manufacturing method of the functional device of any one of Claims 1-11.
記機能性デバイスは、圧電体層を備えるアクチュエーターであり、
前記機能性固体材料層は、前記圧電体層である
請求項1〜請求項11のいずれか1項に記載の機能性デバイスの製造方法。
Before Symbol functional device is an actuator comprising a piezoelectric layer,
The functional solid material layer is the piezoelectric layer .
The manufacturing method of the functional device of any one of Claims 1-11.
記機能性デバイスは、基材上に複数の格子層を備える光学デバイスであり、
前記機能性固体材料層は、前記格子層である
請求項1〜請求項11のいずれか1項に記載の機能性デバイスの製造方法。
Before Symbol functional device is an optical device comprising a plurality of grating layer on a substrate,
The functional solid material layer is the lattice layer .
The manufacturing method of the functional device of any one of Claims 1-11.
ソース領域及びドレイン領域並びにチャネル領域を含む酸化物導電体層と、
前記チャネル領域の導通状態を制御するゲート電極と、
前記ゲート電極と前記チャネル領域との間に形成され強誘電体材料又は常誘電体材料からなるゲート絶縁層とを備え、
前記チャネル領域の層厚は、前記ソース領域の層厚及び前記ドレイン領域の層厚よりも薄いことを特徴とする薄膜トランジスタであって、
前記チャネル領域の層厚が前記ソース領域の層厚及び前記ドレイン領域の層厚よりも薄い前記酸化物導電体層は、請求項1〜請求項12のいずれか1項に記載の機能性デバイスの製造方法を用いて形成されたものである
膜トランジスタ。
An oxide conductor layer including source and drain regions and a channel region;
A gate electrode for controlling the conduction state of the channel region;
A gate insulating layer formed between the gate electrode and the channel region and made of a ferroelectric material or a paraelectric material;
The thin film transistor is characterized in that the channel region has a layer thickness smaller than that of the source region and the drain region.
13. The functional device according to claim 1 , wherein the oxide conductor layer has a layer thickness of the channel region that is thinner than a layer thickness of the source region and a layer thickness of the drain region. It is formed using a manufacturing method .
Thin-film transistor.
記チャネル領域のキャリア濃度及び層厚は、前記薄膜トランジスタがオフ状態のときに、前記チャネル領域全体が空乏化するような値に設定され、かつ
前記チャネル領域のキャリア濃度は、1×10 15 cm −3 〜1×10 21 cm −3 の範囲内にあり、
前記チャネル領域の層厚は、5nm〜100nmの範囲内にある、
請求項15に記載の薄膜トランジスタ。
Carrier concentration and thickness of the front SL channel region, said thin film transistor is in the off state, the whole the channel region is set to a value such depleted, and
The carrier concentration of the channel region is in the range of 1 × 10 15 cm −3 to 1 × 10 21 cm −3 ,
The channel region has a layer thickness in the range of 5 nm to 100 nm;
The thin film transistor according to claim 15.
キャビティ部材と、
前記キャビティ部材の一方側に取り付けられ、圧電体層が形成された振動板と、
前記キャビティ部材の他方側に取り付けられ、ノズル孔が形成されたノズルプレートと、
前記キャビティ部材、前記振動板及び前記ノズルプレートによって画成されるインク室と
を備える圧電式インクジェットヘッドであって、
前記圧電体層及び/又は前記キャビティ部材は、請求項1〜請求項11のいずれか1項に記載の機能性デバイスの製造方法を用いて形成されたものである
圧電式インクジェットヘッド。
A cavity member;
A diaphragm attached to one side of the cavity member and having a piezoelectric layer formed thereon;
A nozzle plate attached to the other side of the cavity member and formed with nozzle holes;
A piezoelectric inkjet head comprising: an ink chamber defined by the cavity member, the vibration plate, and the nozzle plate;
The piezoelectric layer and / or the cavity member is formed using the method for producing a functional device according to any one of claims 1 to 11 .
Piezoelectric inkjet head.
JP2010107764A 2010-05-07 2010-05-07 Method for manufacturing functional device, thin film transistor, and piezoelectric ink jet head Expired - Fee Related JP5198506B2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2010107764A JP5198506B2 (en) 2010-05-07 2010-05-07 Method for manufacturing functional device, thin film transistor, and piezoelectric ink jet head
KR1020127031785A KR101442943B1 (en) 2010-05-07 2011-05-06 Process for production of functional device, process for production of ferroelectric material layer, process for production of field effect transistor, thin film transistor, field effect transistor, and piezoelectric inkjet head
CN201180021920.6A CN102870245B (en) 2010-05-07 2011-05-06 The manufacture method of function device, field-effect transistor and thin-film transistor
PCT/JP2011/060581 WO2011138958A1 (en) 2010-05-07 2011-05-06 Process for production of functional device, process for production of ferroelectric material layer, process for production of field effect transistor, thin film transistor, field effect transistor, and piezoelectric inkjet head
US13/696,551 US9202895B2 (en) 2010-05-07 2011-05-06 Process for production of functional device, process for production of ferroelectric material layer, process for production of field effect transistor, thin film transistor, field effect transistor, and piezoelectric inkjet head
TW100116093A TWI514585B (en) 2010-05-07 2011-05-06 A manufacturing method of a functional element, a thin film transistor, and a piezoelectric ink jet head
US14/531,723 US9123752B2 (en) 2010-05-07 2014-11-03 Process for production of functional device, process for production of ferroelectric material layer, process for production of field effect transistor, thin film transistor, field effect transistor, and piezoelectric ink jet head

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JP2010107764A JP5198506B2 (en) 2010-05-07 2010-05-07 Method for manufacturing functional device, thin film transistor, and piezoelectric ink jet head

Related Child Applications (1)

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JP2012280468A Division JP5615894B2 (en) 2012-12-25 2012-12-25 Thin film transistor manufacturing method, actuator manufacturing method, optical device manufacturing method, thin film transistor, and piezoelectric inkjet head

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JP2011238714A5 true JP2011238714A5 (en) 2012-10-11
JP5198506B2 JP5198506B2 (en) 2013-05-15

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JP5901942B2 (en) 2011-11-09 2016-04-13 国立研究開発法人科学技術振興機構 Functional device manufacturing method and functional device manufacturing apparatus
JP6286636B2 (en) * 2012-07-19 2018-03-07 俊 保坂 Sensor device and manufacturing method thereof
JP2014175453A (en) * 2013-03-08 2014-09-22 Japan Science & Technology Agency Oxide layer, oxide layer manufacturing method, capacitor with oxide layer, semiconductor device and micro electromechanical system
CN105103277B (en) * 2013-03-22 2018-03-20 国立研究开发法人科学技术振兴机构 The manufacture method and solid-state electronic devices of dielectric layer and dielectric layer and the manufacture method of solid-state electronic devices
KR101511932B1 (en) 2013-11-12 2015-04-13 한국과학기술원 Liquid-phase composition for preparing semiconductor and preparing methods of semiconductor thin film and thin film transistor using the same
JP6347084B2 (en) * 2014-02-18 2018-06-27 アドバンストマテリアルテクノロジーズ株式会社 Ferroelectric ceramics and method for producing the same
JP6584881B2 (en) 2015-09-11 2019-10-02 株式会社東芝 Semiconductor device
JP6708597B2 (en) * 2017-11-03 2020-06-10 俊 保坂 Sensor device and manufacturing method thereof

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JPH07156414A (en) * 1993-12-03 1995-06-20 Canon Inc Ink jet recording head, production thereof and recording apparatus
JP3442069B2 (en) * 2001-05-28 2003-09-02 松下電器産業株式会社 Plasma display panel, method of manufacturing the same, and transfer film
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