JP2007160233A - Organic matter-containing wastewater treatment apparatus and method - Google Patents
Organic matter-containing wastewater treatment apparatus and method Download PDFInfo
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- JP2007160233A JP2007160233A JP2005360619A JP2005360619A JP2007160233A JP 2007160233 A JP2007160233 A JP 2007160233A JP 2005360619 A JP2005360619 A JP 2005360619A JP 2005360619 A JP2005360619 A JP 2005360619A JP 2007160233 A JP2007160233 A JP 2007160233A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
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- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Abstract
Description
本発明は有機物含有排水の処理装置及び処理方法に係り、特に、有機物を含有する排水を生物処理した後、更に高度処理を行って処理水を回収する場合に、高度処理工程に流入する有機物量を低減することにより高度処理を安定化させると共に効率化し、高水質の処理水を効率良く回収する装置と方法に関する。 The present invention relates to a treatment apparatus and treatment method for organic matter-containing wastewater, and in particular, the amount of organic matter flowing into the advanced treatment step when wastewater containing organic matter is biologically treated and then subjected to advanced treatment to collect treated water. The present invention relates to an apparatus and a method for stabilizing and improving the efficiency of advanced treatment by reducing the amount of water and efficiently recovering high-quality treated water.
近年、水資源のリサイクルが重要視されるようになり、排水を処理して回収することが積極的に行われるようになってきている。特に、限外濾過(UF)膜や逆浸透(RO)膜に代表される微細な孔径を持つ膜分離装置は高分子量の有機物質をも除去することができ、高度な処理水質が得られるために、広く使用されてきている。一方、これらの膜分離装置は、膜の孔径が小さいために、流入する有機物質濃度が上昇すると、膜面に有機物質が蓄積し易く、濾過抵抗の上昇が著しくなって、通水が困難になる。このような場合には、膜分離装置の前段に生物処理装置を設置して、膜分離処理に先立ち、排水中の有機物質濃度を低減することが、安定処理には効果的である。 In recent years, recycling of water resources has been regarded as important, and wastewater has been treated and collected actively. In particular, membrane separators with fine pore sizes, such as ultrafiltration (UF) membranes and reverse osmosis (RO) membranes, can remove high molecular weight organic substances and provide high quality treated water. Have been widely used. On the other hand, since these membrane separators have a small pore size, if the inflowing organic substance concentration increases, the organic substance tends to accumulate on the membrane surface, and the filtration resistance increases remarkably, making it difficult to pass water. Become. In such a case, it is effective for the stable treatment to install a biological treatment device in front of the membrane separation device and reduce the concentration of organic substances in the waste water prior to the membrane separation treatment.
このように膜分離処理の前段で生物処理を行う場合、例えば、図2に示す如く、有機物含有排水を曝気槽11で生物処理し、生物処理水に凝集剤を添加して凝集槽12,13で順次凝集処理し、凝集処理水を沈殿槽14で固液分離し、得られた分離水を濾過装置30で濾過し、濾過水をRO膜分離装置40で膜分離処理する。このような有機物含有排水の処理装置は、例えば、特開2005−238152号公報に開示されている。
When biological treatment is performed before the membrane separation treatment as described above, for example, as shown in FIG. 2, the organic matter-containing wastewater is biologically treated in the
しかしながら、膜分離処理の前段の生物処理工程において、易生物分解性の有機物質を処理しても、排水中の有機物質の分解過程において、難分解性の微生物の代謝物質が数%程度生成し、これが生物処理水中に含まれることとなる。これら代謝物質は、主に原水中の有機物質の分解により生成した微生物体が微生物間の食物連鎖により分解される過程から生じるものとされているが、比較的高分子量のものが多く、濃度が上昇すると膜分離装置の膜面を閉塞させる原因となる。従って、膜分離装置の前段に生物処理装置を設置した場合であっても、排水中の有機物質濃度が高くなるにつれて、生成する生物代謝物質濃度も上昇するので、膜分離装置の安定運転が次第に困難となる傾向があった。 However, even if easily biodegradable organic substances are treated in the biological treatment process preceding the membrane separation treatment, metabolites of persistent microorganisms are produced in the order of several percent in the process of decomposing organic substances in the wastewater. This is included in the biologically treated water. These metabolites are mainly produced from the process in which microbial bodies produced by the decomposition of organic substances in raw water are decomposed by the food chain between microorganisms, but many of them are relatively high in molecular weight and have a high concentration. If it rises, it will cause the membrane surface of the membrane separator to be blocked. Therefore, even when a biological treatment device is installed in the front stage of the membrane separation device, the concentration of the produced biometabolite also increases as the organic substance concentration in the wastewater increases, so that stable operation of the membrane separation device gradually increases. There was a tendency to be difficult.
また、水回収のための高度処理として、イオン交換樹脂や酸化処理による有機物質の除去処理を行う場合においても、高度処理工程に供される水中の有機物濃度の上昇は、イオン交換樹脂の使用樹脂量の増加、イオン交換樹脂の交換頻度の上昇や、酸化剤使用量の増加に繋がり、処理の安定化を妨げる要素であった。
本発明は、膜分離処理等の高度処理の前段で生物処理を行って有機物含有排水を処理するに当たり、生物処理工程で生成する生物代謝物質量を低減することにより、後段の高度処理工程に流入する有機物量を低減して高度処理の安定化、効率化を図り、高水質の処理水を効率良く回収する有機物含有排水の処理装置及び処理方法を提供することを目的とする。 The present invention reduces the amount of biological metabolites generated in the biological treatment process when the biological treatment is performed before the advanced treatment such as membrane separation treatment to treat the wastewater containing organic matter, and flows into the advanced treatment process in the subsequent stage. An object of the present invention is to provide an organic matter-containing wastewater treatment apparatus and treatment method that can reduce the amount of organic matter to stabilize and improve the efficiency of advanced treatment and efficiently recover high-quality treated water.
本発明(請求項1)の有機物含有排水の処理装置は、有機物含有排水を生物処理する第1の生物処理手段と、該第1の生物処理手段から流出する生物処理水を固液分離する第1の固液分離手段と、該第1の固液分離手段で分離された分離水を生物処理する第2の生物処理手段と、該第2の生物処理手段から流出する生物処理水を固液分離する第2の固液分離手段と、該第2の固液分離手段で分離された分離水に含まれる溶存物質を除去する高度処理手段とを有することを特徴とする。 The apparatus for treating organic matter-containing wastewater of the present invention (Claim 1) is a first biological treatment means for biologically treating organic matter-containing wastewater, and a first liquid-separated biologically treated water flowing out from the first biological treatment means. 1 solid-liquid separation means, second biological treatment means for biologically treating the separated water separated by the first solid-liquid separation means, and biologically treated water flowing out from the second biological treatment means It has the 2nd solid-liquid separation means to isolate | separate, and the high processing means which removes the dissolved substance contained in the separated water isolate | separated by this 2nd solid-liquid separation means, It is characterized by the above-mentioned.
請求項2の有機物含有排水の処理装置は、請求項1において、前記高度処理手段は、膜分離装置であることを特徴とする。 The organic substance-containing wastewater treatment apparatus according to claim 2 is characterized in that, in claim 1, the advanced treatment means is a membrane separation apparatus.
請求項3の有機物含有排水の処理装置は、請求項1又は2において、前記第1の生物処理手段と第1の固液分離手段との間、及び/又は、前記第2の生物処理手段と第2の固液分離手段との間に、生物処理水に凝集剤を添加して凝集反応を行わせる凝集槽を有することを特徴とする。 An organic matter-containing wastewater treatment apparatus according to claim 3 is the organic matter-containing wastewater treatment apparatus according to claim 1 or 2, wherein the organic matter-containing wastewater is disposed between the first biological treatment means and the first solid-liquid separation means and / or the second biological treatment means. Between the 2nd solid-liquid separation means, it has a coagulation tank which adds a coagulant | flocculant to biological treatment water and performs a coagulation reaction, It is characterized by the above-mentioned.
本発明(請求項4)の有機物含有排水の処理方法は、有機物含有排水を生物処理する第1の生物処理工程と、該第1の生物処理工程から流出する生物処理水を固液分離する第1の固液分離工程と、該第1の固液分離工程で分離された分離水を生物処理する第2の生物処理工程と、該第2の生物処理工程から流出する生物処理水を固液分離する第2の固液分離工程と、該第2の固液分離工程で分離された分離水に含まれる溶存物質を除去する高度処理工程とを有することを特徴とする。 The method for treating organic matter-containing wastewater according to the present invention (Claim 4) is a first biological treatment step for biologically treating organic matter-containing wastewater, and a first method for solid-liquid separation of biologically treated water flowing out from the first biological treatment step. 1 solid-liquid separation step, a second biological treatment step for biologically treating the separated water separated in the first solid-liquid separation step, and a biologically treated water flowing out from the second biological treatment step It has the 2nd solid-liquid separation process to isolate | separate, and the advanced treatment process which removes the dissolved substance contained in the separated water isolate | separated by this 2nd solid-liquid separation process, It is characterized by the above-mentioned.
請求項5の有機物含有排水の処理方法は、請求項4において、前記高度処理工程は、膜分離工程であることを特徴とする。 The method for treating wastewater containing organic matter according to claim 5 is characterized in that, in claim 4, the advanced treatment step is a membrane separation step.
請求項6の有機物含有排水の処理方法は、請求項4又は5において、前記第1の生物処理工程と第1の固液分離工程との間、及び/又は、前記第2の生物処理工程と第2の固液分離工程との間に、生物処理水に凝集剤を添加して凝集反応を行わせる凝集工程を有することを特徴とする。 The method for treating wastewater containing organic matter according to claim 6 is the method according to claim 4 or 5, wherein the first biological treatment step and the first solid-liquid separation step and / or the second biological treatment step. Between the 2nd solid-liquid separation process, it has the aggregation process which adds a flocculant to biological treatment water and performs aggregation reaction.
本発明によれば、第1の生物処理手段で溶解性有機物質の大部分を分解した後、第1の生物処理手段で生成した微生物体を第1の固液分離手段で分離し、この微生物体が除去された分離水を更に第2の生物処理手段で生物処理した後、第2の生物処理手段で生成した微生物体を第2の固液分離手段で分離する。このように生物処理・固液分離の2段処理を行うことにより、生物代謝物質量を低減して、高度処理手段に流入する有機物質濃度を低減して安定した排水処理を行うことができる。 According to the present invention, the microorganisms produced by the first biological treatment means are separated by the first solid-liquid separation means after most of the soluble organic substance is decomposed by the first biological treatment means. The separated water from which the body has been removed is further biologically treated by the second biological treatment means, and then the microbial bodies produced by the second biological treatment means are separated by the second solid-liquid separation means. Thus, by performing the two-stage treatment of biological treatment and solid-liquid separation, the amount of biological metabolites can be reduced, the concentration of organic substances flowing into the advanced treatment means can be reduced, and stable wastewater treatment can be performed.
そして、有機物質が十分に除去された水を更に高度処理することにより、水質の良好な処理水を得ることができる。この高度処理手段の処理水は極めて水質が良好であるため、そのまま再使用水として、あるいは純水、超純水の原水として回収することができる。 And the water from which the organic substance was fully removed can be further advanced to obtain treated water with good water quality. Since the treated water of this advanced treatment means has extremely good water quality, it can be recovered as it is as reused water or as raw water of pure water or ultrapure water.
また、高度処理手段では、有機物質濃度が十分に低減された水を処理するため、高度処理の負荷が軽減され、高度処理手段が膜分離装置であれば、膜汚染が防止され、経時によるフラックスの低下が少なく、長期にわたり安定した処理を継続することができるようになる。また、イオン交換装置であれば、有機物負荷、有機汚染の低減により、処理水質の向上、樹脂再生頻度の低減、樹脂交換頻度の低減が可能となる。また、酸化装置の場合には、有機物負荷の低減により酸化剤使用量の節減、装置の小型化が可能となる。 In addition, the advanced treatment means treats water with a sufficiently reduced concentration of organic substances, so the load of advanced treatment is reduced. If the advanced treatment means is a membrane separation device, membrane contamination is prevented and flux over time is reduced. Thus, stable treatment can be continued for a long time. In addition, in the case of an ion exchange device, it is possible to improve the quality of treated water, reduce the frequency of resin regeneration, and reduce the frequency of resin exchange by reducing organic load and organic contamination. In the case of an oxidizer, it is possible to reduce the amount of oxidant used and reduce the size of the device by reducing the organic load.
以下に本発明の有機物含有排水の処理装置及び有機物含有排水の処理方法の実施の形態を詳細に説明する。 Embodiments of the organic matter-containing wastewater treatment apparatus and the organic matter-containing wastewater treatment method of the present invention will be described in detail below.
[有機物含有排水]
本発明において、処理対象となる有機物含有排水は、通常生物処理される有機物含有排水であれば良く、特に限定されるものではないが、例えば、電子産業排水、化学工場排水、食品工場排水などが挙げられる。例えば、電子部品製造プロセスでは、現像工程、剥離工程、エッチング工程、洗浄工程などから各種の有機性排水が多量に発生し、しかも排水を回収して純水レベルに浄化して再使用することが望まれているので、これらの排水は本発明の処理対象排水として適している。
[Organic wastewater]
In the present invention, the organic matter-containing wastewater to be treated is not particularly limited as long as it is an organic matter-containing wastewater that is normally biologically treated. Examples thereof include electronic industrial wastewater, chemical factory wastewater, and food factory wastewater. Can be mentioned. For example, in the electronic component manufacturing process, a large amount of various organic wastewater is generated from the development process, peeling process, etching process, cleaning process, etc., and the wastewater can be recovered and purified to a pure water level for reuse. As desired, these wastewaters are suitable as the wastewater to be treated in the present invention.
このような有機性排水としては例えば、イソプロピルアルコール、エチルアルコールなどを含有する有機性排水、モノエタノールアミン(MEA)、テトラメチルアンモニウムハイドロオキサイド(TMAH)などの有機態窒素、アンモニア態窒素を含有する有機性排水、ジメチルスルホキシド(DMSO)などの有機硫黄化合物を含有する有機性排水が挙げられる。 Examples of such organic wastewater include organic wastewater containing isopropyl alcohol and ethyl alcohol, organic nitrogen such as monoethanolamine (MEA) and tetramethylammonium hydroxide (TMAH), and ammonia nitrogen. Organic waste water and organic waste water containing organic sulfur compounds such as dimethyl sulfoxide (DMSO) can be mentioned.
[生物処理]
排水を生物処理するための生物処理手段としては、有機物の分解効率に優れるものであれば良く、既知の好気性又は嫌気性生物処理方式の生物反応槽が使用できる。例えば、活性汚泥を槽内に浮遊状態で保持する浮遊方式、活性汚泥を担体に付着させて保持する生物膜方式などを採用することができる。また、生物膜方式では固定床式、流動床式、展開床式など任意の微生物床方式でよく、更に担体として、活性炭、種々のプラスチック担体、スポンジ担体などがいずれも使用できる。
[Biological treatment]
Any biological treatment means for biologically treating the wastewater may be used as long as it is excellent in the decomposition efficiency of organic matter, and a known aerobic or anaerobic biological treatment type biological reaction tank can be used. For example, a floating method for holding activated sludge in a suspended state in a tank, a biofilm method for holding activated sludge attached to a carrier, and the like can be employed. The biofilm method may be any microbial bed method such as a fixed bed method, a fluidized bed method, and a developed bed method, and as the carrier, any of activated carbon, various plastic carriers, sponge carriers, and the like can be used.
担体としてはスポンジ担体が好ましく、スポンジ担体であれば微生物を高濃度に維持することができる。スポンジ素材としても特に限定されないが、エステル系ポリウレタンが好適である。担体の投入量としても特に制限はないが、通常、生物反応槽の槽容量に対する担体の見掛け容量で10〜50%程度、特に30〜50%程度とすることが好ましい。 A sponge carrier is preferable as the carrier, and microorganisms can be maintained at a high concentration if the sponge carrier is used. The sponge material is not particularly limited, but ester polyurethane is preferable. There is no particular limitation on the amount of the carrier to be charged, but usually it is preferably about 10 to 50%, particularly preferably about 30 to 50% in terms of the apparent capacity of the carrier relative to the volume of the biological reaction tank.
好気性状態で微生物的に有機物を分解する好気性生物反応槽としては、槽内に酸素(空気)を供給するための散気管、曝気機などの酸素ガス供給手段が設けられた曝気槽を用いることができる。 As an aerobic biological reaction tank that microbially decomposes organic matter in an aerobic state, an aeration tank provided with oxygen gas supply means such as an air diffuser for supplying oxygen (air) into the tank and an aerator is used. be able to.
一方、嫌気性状態で微生物的に有機物を分解する嫌気性生物反応槽としては、担体や粒状汚泥を保持した嫌気槽を用いることができる。 On the other hand, as an anaerobic biological reaction tank that microbially decomposes organic matter in an anaerobic state, an anaerobic tank holding a carrier and granular sludge can be used.
生物反応槽は、好気性生物反応槽又は嫌気性生物反応槽の1槽式でも、好気性生物反応槽及び/又は嫌気性生物反応槽の多槽式でもよく、また、1槽式で槽内に仕切り壁を設けてもよい。即ち、本発明において、第1の生物処理手段、第2の生物処理手段として、多槽式のものをそれぞれ用いることもできる。 The biological reaction tank may be an aerobic biological reaction tank or an anaerobic biological reaction tank, or an aerobic biological reaction tank and / or a multi-tank type anaerobic biological reaction tank. A partition wall may be provided. That is, in the present invention, multi-tank type ones can be used as the first biological treatment means and the second biological treatment means, respectively.
[凝集処理]
有機性排水を生物処理して得られる生物処理水は、後段の固液分離手段で微生物体と高分子有機物質を確実に除去するために、好ましくは固液分離に先立ち、凝集処理される。生物処理水の凝集処理には、通常の凝集処理装置が用いられる。この凝集処理装置の凝集槽は1槽のみでも良く、2槽以上を多段に設けてもよい。
[Aggregation treatment]
The biologically treated water obtained by biologically treating the organic wastewater is preferably subjected to an agglomeration treatment prior to the solid-liquid separation in order to surely remove the microorganisms and the macromolecular organic material by the solid-liquid separation means at the subsequent stage. A normal aggregating apparatus is used for the agglomeration treatment of biologically treated water. The aggregation tank of this aggregation processing apparatus may be only one tank or two or more tanks may be provided in multiple stages.
凝集処理装置は一般に凝集剤を被処理水に十分に接触させるための急速撹拌槽と凝集フロックを成長させる緩速撹拌槽で構成される。従って、2槽以上の凝集槽を多段に設ける場合、前段の凝集槽を急速撹拌槽とし、後段の凝集槽を緩速撹拌槽とすることが好ましい。 The agglomeration apparatus is generally composed of a rapid agitation tank for sufficiently bringing the aggregating agent into contact with the water to be treated and a slow agitation tank for growing the agglomeration floc. Accordingly, when two or more flocculation tanks are provided in multiple stages, it is preferable that the preceding flocculation tank be a rapid stirring tank and the latter flocculation tank be a slow stirring tank.
凝集処理に用いる無機凝集剤としては、塩化第二鉄、ポリ硫酸鉄などの鉄系凝集剤、硫酸アルミニウム、塩化アルミニウム、ポリ塩化アルミニウム等のアルミニウム系凝集剤が例示できるが、凝集効果の面からは鉄系凝集剤が好ましい。これらの無機凝集剤は、1種を単独で用いても良く、2種以上を併用しても良い。 Examples of the inorganic flocculant used in the agglomeration treatment include iron-based flocculants such as ferric chloride and polyiron sulfate, and aluminum-based flocculants such as aluminum sulfate, aluminum chloride, and polyaluminum chloride. Is preferably an iron-based flocculant. These inorganic flocculants may be used individually by 1 type, and may use 2 or more types together.
凝集処理時は、必要に応じてpH調整剤を添加して用いた無機凝集剤に好適なpHに調整する。即ち、pH条件としては、例えば、鉄系凝集剤ではpH5.5以下で反応させることが効果的であり、アルミニウム系凝集剤ではpH5.0以下で反応させた後、pH6.0以上に調整すると効果的であるため、必要に応じて、塩酸(HCl)、硫酸(H2SO4)等の酸や、水酸化ナトリウム(NaOH)等のアルカリを添加してpH調整を行うことが好ましい。このようなpH条件における凝集処理により、良好な処理水質が得られる理由の詳細は明らかになっていないが、生物代謝物中のタンパク成分の電荷が中和されることが関係しているものと推定される。 During the flocculation treatment, a pH adjusting agent is added as necessary to adjust the pH to be suitable for the inorganic flocculating agent used. That is, as a pH condition, for example, it is effective to react at a pH of 5.5 or less with an iron-based flocculant, and after reacting at a pH of 5.0 or less with an aluminum-based flocculant, the pH is adjusted to 6.0 or higher. Since it is effective, it is preferable to adjust the pH by adding an acid such as hydrochloric acid (HCl) or sulfuric acid (H 2 SO 4 ) or an alkali such as sodium hydroxide (NaOH) as necessary. Although the details of the reason why a good quality of treated water can be obtained by the aggregation treatment under such pH conditions are not clear, it is related to the neutralization of the charge of the protein component in the biological metabolite. Presumed.
凝集処理により、生物処理水中の溶解性有機物や懸濁物はフロック化する。この凝集フロックを成長させるために、第1凝集槽で無機凝集剤を添加して、第2凝集槽で高分子凝集剤を添加しても良い。 By the coagulation treatment, soluble organic matter and suspension in the biologically treated water are flocked. In order to grow this coagulation floc, an inorganic coagulant may be added in the first coagulation tank and a polymer coagulant may be added in the second coagulation tank.
[固液分離]
生物処理水、好ましくは生物処理水を凝集処理して得られる凝集処理水の固液分離手段としては、沈殿槽、浮上槽、遠心分離機等特に限定されないが、生物処理水の凝集フロックは浮上分離しやすく、また沈殿槽に比べ、小さい面積の装置で良いことから、特に加圧浮上槽が好ましい。また、特に第2の固液分離手段としては浸漬膜等の膜分離手段を用いても良い。
[Solid-liquid separation]
The solid-liquid separation means of the agglomerated treated water obtained by agglomerating the biologically treated water, preferably the agglomerated treated water is not particularly limited, such as a sedimentation tank, a flotation tank, a centrifuge, etc. A pressure levitation tank is particularly preferable because it is easy to separate and an apparatus with a smaller area than the precipitation tank may be used. In particular, membrane separation means such as an immersion membrane may be used as the second solid-liquid separation means.
[高度処理]
高度処理手段は、排水中の有機物を第1、第2の生物処理手段、第1、第2の固液分離手段で除去して得た処理水中に残留する溶存有機物を更に除去するものでも良く、また、処理水中に含まれる溶媒塩類を除去するものでも良く、両者を除去するものでも良い。
[Advanced processing]
The advanced treatment means may further remove dissolved organic matter remaining in the treated water obtained by removing the organic matter in the wastewater by the first and second biological treatment means and the first and second solid-liquid separation means. Moreover, the solvent salt contained in the treated water may be removed, or both may be removed.
高度処理手段としては、次のようなものが挙げられる。
膜分離装置:例えば、有機物除去や脱塩のための、RO、NF(ナノ濾過)、UF膜
分離装置等
イオン交換装置:例えば、脱塩や有機物除去のための、アニオン交換樹脂塔、カチオ
ン交換樹脂塔、カチオン交換樹脂とアニオン交換樹脂とを混合充填
した混床塔、電気脱塩装置等
酸化装置:例えば、有機物除去のための、オゾン酸化装置、過酸化水素酸化装置、塩
素酸化装置、紫外線酸化装置等、或いはこれらを併用した酸化装置。なお
、この酸化装置の後段には、通常、イオン交換、膜分離等の装置が設けら
れることが多い。
Examples of advanced processing means include the following.
Membrane separator: RO, NF (nanofiltration), UF membrane, for example, for organic substance removal and desalting
Separation device, etc. Ion exchange device: for example, anion exchange resin tower, cation for desalting and organic matter removal
Ion exchange resin tower, mixed packing of cation exchange resin and anion exchange resin
Mixed bed tower, electric desalination equipment, etc. Oxidation equipment: For example, ozone oxidation equipment, hydrogen peroxide oxidation equipment, salt for organic matter removal
An oxygen oxidizer, an ultraviolet oxidizer or the like, or an oxidizer using both of them. In addition
In general, an apparatus such as ion exchange or membrane separation is provided downstream of the oxidation apparatus.
It is often done.
これらの高度処理手段は適宜2以上を組み合わせて用いることもできる。また、高度処理手段の一部として、濾過装置や活性炭処理装置等の他の処理装置を更に追加しても良い。 These advanced processing means can be used in combination of two or more as appropriate. Moreover, you may further add other processing apparatuses, such as a filtration apparatus and an activated carbon processing apparatus, as some advanced treatment means.
特に、高度処理手段としてRO膜分離装置を用いる場合、RO膜分離装置の前段に濾過装置を設けて、水中のSSを除去することが好ましい。濾過装置としては、砂、アンスラサイト等の濾材を充填した充填層型濾過装置、精密濾過(MF)膜、限外濾過(UF)膜などの膜を用いた膜濾過装置等を用いることができる。 In particular, when an RO membrane separation device is used as the advanced treatment means, it is preferable to provide a filtration device in front of the RO membrane separation device to remove SS in the water. As the filtration device, a packed bed type filtration device filled with a filter medium such as sand or anthracite, a membrane filtration device using a membrane such as a microfiltration (MF) membrane, an ultrafiltration (UF) membrane, or the like can be used. .
[有機物含有排水の処理装置]
以下に図面を参照して本発明の有機物含有排水の処理装置の一例を説明する。
[Organic wastewater treatment equipment]
An example of the organic matter-containing wastewater treatment apparatus of the present invention will be described below with reference to the drawings.
図1は、本発明の有機物含有排水の処理装置の実施の形態を示す系統図である。なお、図1は本発明の有機物含有排水の処理装置の一例であって、本発明の有機物含有排水の処理装置は何ら図1に示すものに限定されない。例えば、高度処理手段はRO膜分離装置に限らず、イオン交換装置や酸化装置であっても良く、生物処理手段は曝気槽に限らず、嫌気性生物反応槽であっても良い。 FIG. 1 is a system diagram showing an embodiment of the organic matter-containing wastewater treatment apparatus of the present invention. In addition, FIG. 1 is an example of the processing apparatus of the organic substance containing waste_water | drain of this invention, Comprising: The processing apparatus of the organic substance containing waste_water | drain of this invention is not limited to what is shown in FIG. For example, the advanced treatment means is not limited to the RO membrane separation apparatus, but may be an ion exchange apparatus or an oxidation apparatus, and the biological treatment means is not limited to the aeration tank but may be an anaerobic biological reaction tank.
この有機物含有排水の処理装置は、第1の生物処理手段としての曝気槽(以下「No.1曝気槽」と称す。)11、No.1曝気槽11からの生物処理水を凝集処理する2段に配置された凝集槽(以下「No.1−1凝集槽」と称す。)12及び凝集槽(以下「No.1−2凝集槽」と称す。)13、No.1−2凝集槽13からの凝集処理水を固液分離する第1の固液分離手段としての沈殿槽(以下「No.1沈殿槽」と称す。)14とからなる1段目処理装置10と、1段目処理装置10の処理水であるNo.1沈殿槽14の分離水が導入される第2の生物処理手段としての曝気槽(以下「No.2曝気槽」と称す。)21、No.2曝気槽21からの生物処理水を凝集処理する2段に配置された凝集槽(以下「No.2−1凝集槽」と称す。)22及び凝集槽(以下「No.2−2凝集槽」と称す。)23、No.2−2凝集槽23からの凝集処理水を固液分離する第2の固液分離手段としての沈殿槽(以下「No.2沈殿槽」と称す。)24とからなる2段目処理装置20と、2段目処理装置20の処理水であるNo.2沈殿槽24の分離水が導入される濾過装置30と、濾過装置30の濾過水が導入される高度処理手段としてのRO膜分離装置40とで構成される。
This organic matter-containing wastewater treatment apparatus is equipped with an aeration tank (hereinafter referred to as “No. 1 aeration tank”) 11 as a first biological treatment means. A coagulation tank (hereinafter referred to as “No. 1-1 coagulation tank”) 12 and a coagulation tank (hereinafter referred to as “No. 1-2 coagulation tank”) that coagulate the biologically treated water from one
原水(有機物含有排水)は、No.1曝気槽11に導入され、散気管11Aからの曝気下、好気性生物処理される。このNo.1曝気槽11においては、原水中の溶解性有機物質(S−TOC)の大部分を除去することにより、後段の第2曝気槽21に流入する溶解性有機物質濃度を低減する。この第1曝気槽11は、最前段の生物処理槽であるために槽内の微生物量当たりのBOD負荷量が高くなるので、微生物間の食物連鎖による自己分解の進行が抑制される。
Raw water (organic matter-containing wastewater) is no. 1 It introduce | transduces into the
No.1曝気槽11の好ましい運転形態は、原水中に含まれる有機物質の分解性により若干異なるが、原水中の溶解性有機物の60〜95%、より好ましくは70〜90%が除去される負荷量が良い。また、微生物の自己分解抑制の観点からは、微生物の保持量を発生量で除した値であるSRTの値が、5日以下、より好ましくは3日以下、特に1〜3日となるようにすると良い。上記条件が得られるBOD汚泥負荷は、通常0.5〜10Kg−BOD/Kg−VSS/day、より好ましくは1.0〜5.0Kg−BOD/Kg−VSS/dayである。
No. Although the preferable operation mode of the 1
また、No.1曝気槽11でこうした高負荷運転を行うと、沈降性の良い微生物フロックができにくいため、図示の如く、微生物量を安定して保持できるように、担体11bを槽内に投入することが好ましい。担体を添加した場合の保持汚泥量は担体及び充填率によって異なるが、一般的なスポンジ状の担体を見かけ容量で槽容量の30〜50%充填した場合は、曝気槽あたりの汚泥保持量は2500〜6000mg−VSS/L程度となるので、槽負荷として1.5〜60Kg−BOD/m3/day、特に2〜30Kg−BOD/m3/dayが好適である。
No. When such a high-load operation is performed in one
No.1曝気槽11からの生物処理水は、次いでNo.1−1凝集槽12で無機凝集剤が添加されて凝集処理された後、更にNo.1−2凝集槽13でpH調整剤及び/又は高分子凝集剤が添加されてフロックが粗大化され、凝集処理水は次いでNo.1沈殿槽14に送給され凝集フロックが固液分離される。
No. The biologically treated water from the 1
No.1沈殿槽14の固液分離水は、次いでNo.2曝気槽21に導入され、散気管12Aからの曝気下、好気性生物処理される。このNo.2曝気槽21においては、第1段目の生物処理で残留した溶解性有機物質を分解する。このNo.2曝気槽21では、後段の高度処理手段であるRO膜分離装置40に流入する有機物濃度をできるだけ低減できるよう、確実な分解が進行することが望ましい。好ましいBOD汚泥負荷は0.01〜0.30Kg−BOD/Kg−VSS/dayであり、より好ましくは0.05〜0.2Kg−BOD/Kg−VSS/dayである。このNo.2曝気槽21は、特に低負荷でも微生物量を安定して保持できるように、担体22Bを槽内に保持するものが好ましい。このNo.2曝気槽の槽負荷は0.03〜1.8Kg−BOD/m3/day、特に0.15〜1.2Kg−BOD/m3/dayが好適である。また、SRTは5〜50日であることが好ましい。
No. Next, the solid-liquid separated water in the
No.2曝気槽21からの生物処理水は、次いでNo.2−1凝集槽22で無機凝集剤が添加されて凝集処理された後、更にNo.2−2凝集槽23でpH調整剤及び/又は高分子凝集剤が添加されてフロックが粗大化され、凝集処理水は次いでNo.2沈殿槽24に送給され凝集フロックが固液分離される。 No. 2 The biologically treated water from the aeration tank 21 is then No. 2-1, after an inorganic flocculant was added in the agglomeration tank 22 for agglomeration treatment, In the 2-2 coagulation tank 23, a pH adjuster and / or a polymer coagulant is added to coarsen the floc. 2 The flocculated floc is fed to the settling tank 24 and separated into solid and liquid.
No.2沈殿槽24の固液分離水は、次いで濾過装置30で残留SSが除去された後RO膜分離装置40でRO膜分離処理され、透過水が処理水として取り出される。
No. 2 The solid-liquid separation water in the settling tank 24 is then subjected to RO membrane separation treatment by the RO
図1の装置では、RO膜分離装置40の前段で2段の生物処理と固液分離を行うことにより、高水質の処理水を得ることができる上に、FI値の低い水をRO膜分離装置40に給水することができるので、RO膜分離装置の膜フラックスの低下を抑制して、長期間安定して処理水を得ることができる。
In the apparatus of FIG. 1, high-quality treated water can be obtained by performing two stages of biological treatment and solid-liquid separation at the front stage of the RO
なお、FI値とは、水をRO膜分離装置に通水して脱イオン処理する際のRO膜分離装置への給水の水質がRO膜処理に適しているか否かを判断する指標として用いられるものである。水中の溶存有機物やSSの量は概ね同等であっても、これをRO膜処理すると膜フラックスが早期に低下するときとそうでないときがあり、そのような場合、RO給水のFI値では差が生じている。 The FI value is used as an index for determining whether or not the quality of water supplied to the RO membrane separation device when water is passed through the RO membrane separation device for deionization is suitable for the RO membrane treatment. Is. Even if the amount of dissolved organic matter and SS in the water is approximately the same, when the RO membrane treatment is performed, the membrane flux may or may not decrease early. In such a case, there is a difference in the FI value of the RO water supply. Has occurred.
FI値は、所定の孔径を有するメンブレンフィルタに試料水を通水して所定量を濾過するに要する時間を計測する操作を行って、初期の所要時間と、所定時間通水後の所要時間とから求めることができ、膜汚染、膜目詰まりを起こし易い又は起こし難い水質かを判定するのに用いられる。一般に、FI値5以下の水質でもRO給水として許容されることがあるが、通常、FI値3以下の水質であることが望まれている。従って、本発明では、高度処理手段としてRO膜分離装置を用いる場合、2段の生物処理と固液分離でFI値3以下の水を得、これをRO膜分離装置の給水とすることが好ましい。 The FI value is obtained by performing an operation of measuring the time required to pass a sample amount of water through a membrane filter having a predetermined pore size and filtering a predetermined amount. It is used to determine whether the water quality is likely to cause membrane contamination or membrane clogging or is unlikely to occur. In general, water quality with an FI value of 5 or less may be permitted as RO water supply, but it is usually desired that the water quality has an FI value of 3 or less. Therefore, in the present invention, when an RO membrane separation device is used as an advanced treatment means, it is preferable to obtain water having an FI value of 3 or less by two-stage biological treatment and solid-liquid separation, and use this as water supply for the RO membrane separation device. .
以下に実施例及び比較例を挙げて本発明をより具体的に説明する。 Hereinafter, the present invention will be described more specifically with reference to Examples and Comparative Examples.
[実施例1、比較例1]
図1(実施例1)又は図2(比較例1)に示す装置で、IPA(イソプロピルアルコール)を主成分とする下記水質の工場排水を原水として、1000L/dayの処理水量で処理を行った。なお、この原水の生物処理には、窒素及びリンの不足が想定されたので、硫酸アンモニウム及びリン酸をTOC:N:P=100:15:3となるように原水に添加して処理を行った。
<原水水質>
S−TOC:457mg/L
Kj−N:11.5mg/L
PO4−P:1.5mg/L
[Example 1, Comparative Example 1]
Using the apparatus shown in FIG. 1 (Example 1) or FIG. 2 (Comparative Example 1), the following water quality factory effluent mainly composed of IPA (isopropyl alcohol) was used as raw water, and the treatment was performed at a treatment water amount of 1000 L / day. . In addition, since the shortage of nitrogen and phosphorus was assumed in this biological treatment of raw water, ammonium sulfate and phosphoric acid were added to the raw water so that TOC: N: P = 100: 15: 3. .
<Raw water quality>
S-TOC: 457 mg / L
Kj-N: 11.5mg / L
PO 4 -P: 1.5 mg / L
表1に、実施例1及び比較例1で用いた装置の仕様及び処理条件を示す。
また、表2に各部の水質を、表3にRO膜分離装置のフラックス低下率の経日変化を示す。
また、処理水量1000m3/day当たりの反応槽面積(曝気槽、凝集槽、沈殿槽の水深を4mと仮定)を表4に示す。
Table 1 shows the specifications and processing conditions of the apparatuses used in Example 1 and Comparative Example 1.
Table 2 shows the water quality of each part, and Table 3 shows the daily change in the flux reduction rate of the RO membrane separator.
Table 4 shows the reaction tank area (assuming that the water depth of the aeration tank, the coagulation tank, and the precipitation tank is 4 m) per 1000 m 3 / day of treated water.
以上の結果から次のことが明らかである。 From the above results, the following is clear.
実施例1では、前段のNo.1曝気槽において、原水中の有機物の大部分を除去すると共に、自己分解が進行する前に菌体をSSとしてNo.1沈殿槽で固液分離して除去することができる。そして、No.1沈殿槽の分離水を更にNo.2曝気槽で処理することにより残留した有機物を更に高度に分解すると共にNo.2沈殿槽でSSを除去することにより、結果として比較例1の曝気槽容量よりも小さい合計容量のNo.1,2曝気槽でS−TOC、SSが共に低い処理水を得ることができる。また、凝集槽においても少ない凝集剤添加量で十分に凝集処理を行うことができることから、No.1,2凝集槽における合計の凝集剤添加量も比較例1の場合と同等で、膜分離に適した処理水を得ることができる。即ち、S−TOC値が低く、また凝集処理効果の指標であり、膜分離装置の給水水質の指標となるFI値の低い処理水を得、これをRO膜分離装置に供給して、良好な処理水を得ることができる。 In Example 1, No. 1 in the previous stage was used. In the 1 aeration tank, most of the organic matter in the raw water was removed, and before the autolysis proceeded, the fungus body was designated as SS. It can be removed by solid-liquid separation in one precipitation tank. And No. 1 Separate the separated water from the sedimentation tank. 2 The remaining organic matter is decomposed to a higher degree by treating in an aeration tank and 2 By removing SS in the sedimentation tank, as a result, the total capacity of No. 2 smaller than the aeration tank capacity of Comparative Example 1 was obtained. Treated water with low S-TOC and SS can be obtained in 1 and 2 aeration tanks. In addition, since the coagulation treatment can be sufficiently performed in the coagulation tank with a small amount of coagulant added, The total amount of flocculant added in the 1 and 2 flocculants is also the same as in Comparative Example 1, and treated water suitable for membrane separation can be obtained. That is, the S-TOC value is low, and it is an index of the coagulation treatment effect, and treated water having a low FI value that serves as an index of the feed water quality of the membrane separation device is obtained and supplied to the RO membrane separation device. Treated water can be obtained.
10 1段目処理装置
11 No.1曝気槽
12 No.1−1凝集槽
13 No.1−2凝集槽
14 No.1沈殿槽
20 2段目処理装置
21 No.2曝気槽
22 No.2−1凝集槽
23 No.2−2凝集槽
24 No.2沈殿槽
30 濾過装置
40 RO膜分離装置
10 1st
Claims (6)
該第1の生物処理手段から流出する生物処理水を固液分離する第1の固液分離手段と、
該第1の固液分離手段で分離された分離水を生物処理する第2の生物処理手段と、
該第2の生物処理手段から流出する生物処理水を固液分離する第2の固液分離手段と、
該第2の固液分離手段で分離された分離水に含まれる溶存物質を除去する高度処理手段と
を有することを特徴とする有機物含有排水の処理装置。 A first biological treatment means for biologically treating organic matter-containing wastewater;
First solid-liquid separation means for solid-liquid separation of biologically treated water flowing out of the first biological treatment means;
A second biological treatment means for biologically treating the separated water separated by the first solid-liquid separation means;
Second solid-liquid separation means for solid-liquid separation of biologically treated water flowing out from the second biological treatment means;
An organic matter-containing wastewater treatment apparatus comprising: an advanced treatment means for removing dissolved substances contained in the separated water separated by the second solid-liquid separation means.
該第1の生物処理工程から流出する生物処理水を固液分離する第1の固液分離工程と、
該第1の固液分離工程で分離された分離水を生物処理する第2の生物処理工程と、
該第2の生物処理工程から流出する生物処理水を固液分離する第2の固液分離工程と、
該第2の固液分離工程で分離された分離水に含まれる溶存物質を除去する高度処理工程と
を有することを特徴とする有機物含有排水の処理方法。 A first biological treatment process for biologically treating organic matter-containing wastewater;
A first solid-liquid separation step for solid-liquid separation of the biologically treated water flowing out of the first biological treatment step;
A second biological treatment step for biologically treating the separated water separated in the first solid-liquid separation step;
A second solid-liquid separation step for solid-liquid separation of the biologically treated water flowing out of the second biological treatment step;
And an advanced treatment step of removing dissolved substances contained in the separated water separated in the second solid-liquid separation step.
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009208012A (en) * | 2008-03-05 | 2009-09-17 | Japan Organo Co Ltd | Water treating method and water treating apparatus |
JP2012501848A (en) * | 2008-09-10 | 2012-01-26 | ヨーロピアン・スペース・エージェンシー | Equipment, toilet, livestock shed and method for treatment of urea-containing water |
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Citations (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52109761A (en) * | 1976-03-11 | 1977-09-14 | Kobe Steel Ltd | Purification method of waste water |
JPS5413665A (en) * | 1977-07-04 | 1979-02-01 | Ebara Infilco Co Ltd | Process for treating organic waste water |
JPS59142897A (en) * | 1983-02-01 | 1984-08-16 | Ataka Kogyo Kk | Nitrification and denitrification process |
JPS59193196A (en) * | 1983-04-18 | 1984-11-01 | Showa Denko Kk | Treatment of organic waste liquid containing heavy metal |
JPS6012194A (en) * | 1983-07-01 | 1985-01-22 | Mamoru Uchimizu | Treatment of waste water containing organic substance by biological reaction |
JPS6058293A (en) * | 1983-09-07 | 1985-04-04 | Kurita Water Ind Ltd | Waste water treating apparatus |
JPS6377595A (en) * | 1986-09-17 | 1988-04-07 | Kurita Water Ind Ltd | Activated sludge treating device |
JPS63182100A (en) * | 1987-01-23 | 1988-07-27 | Toyota Motor Corp | Treatment of water-soluble cutting/grinding waste liquid |
JPH0330897A (en) * | 1989-06-27 | 1991-02-08 | Hitachi Plant Eng & Constr Co Ltd | Waste water treatment apparatus |
JPH05337479A (en) * | 1992-06-08 | 1993-12-21 | Kurita Water Ind Ltd | Aerobic treatment plant |
JPH0631297A (en) * | 1992-07-10 | 1994-02-08 | Nippon Steel Corp | Method for treating waste water containing high concentration of nitrogen sophistically |
JPH07155784A (en) * | 1993-12-08 | 1995-06-20 | Kubota Corp | Treatment of organic waste water |
JPH0810785A (en) * | 1994-06-27 | 1996-01-16 | Sumitomo Heavy Ind Ltd | Activated sludge device |
JPH08257583A (en) * | 1995-03-23 | 1996-10-08 | Kurita Water Ind Ltd | Waste water treatment apparatus |
JPH0970599A (en) * | 1995-09-06 | 1997-03-18 | Sharp Corp | Waste water treating device and treatment of waste water |
JPH0999294A (en) * | 1995-10-05 | 1997-04-15 | Kurita Water Ind Ltd | Waste water treating equipment |
JPH09276890A (en) * | 1996-04-15 | 1997-10-28 | Ebara Corp | Treatment of organic waste water containing polyvinyl alcohol |
JPH1057984A (en) * | 1996-08-13 | 1998-03-03 | Kurita Water Ind Ltd | Biological treating device |
JPH1080693A (en) * | 1996-09-06 | 1998-03-31 | Sharp Corp | Treatment of waste water and waste water treating device |
JPH1119675A (en) * | 1997-06-30 | 1999-01-26 | Shinko Pantec Co Ltd | Treatment of organic matter-containing water and device therefor |
JP2000042584A (en) * | 1998-07-31 | 2000-02-15 | Kurita Water Ind Ltd | High load biological treatment and device therefor |
JP2001314885A (en) * | 2000-05-10 | 2001-11-13 | Kurita Water Ind Ltd | High load biological treatment method |
JP2003010874A (en) * | 2001-06-29 | 2003-01-14 | Ebara Corp | Method and apparatus for high-speed biological treatment of organic sewage |
JP2005238152A (en) * | 2004-02-27 | 2005-09-08 | Kurita Water Ind Ltd | Organic material-containing water treatment method |
JP2006082024A (en) * | 2004-09-16 | 2006-03-30 | Kurita Water Ind Ltd | Biological treatment apparatus |
JP2006167550A (en) * | 2004-12-14 | 2006-06-29 | Kurita Water Ind Ltd | Biological treatment apparatus |
-
2005
- 2005-12-14 JP JP2005360619A patent/JP5017854B2/en active Active
-
2006
- 2006-12-11 KR KR20060125405A patent/KR101373881B1/en active IP Right Grant
Patent Citations (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52109761A (en) * | 1976-03-11 | 1977-09-14 | Kobe Steel Ltd | Purification method of waste water |
JPS5413665A (en) * | 1977-07-04 | 1979-02-01 | Ebara Infilco Co Ltd | Process for treating organic waste water |
JPS59142897A (en) * | 1983-02-01 | 1984-08-16 | Ataka Kogyo Kk | Nitrification and denitrification process |
JPS59193196A (en) * | 1983-04-18 | 1984-11-01 | Showa Denko Kk | Treatment of organic waste liquid containing heavy metal |
JPS6012194A (en) * | 1983-07-01 | 1985-01-22 | Mamoru Uchimizu | Treatment of waste water containing organic substance by biological reaction |
JPS6058293A (en) * | 1983-09-07 | 1985-04-04 | Kurita Water Ind Ltd | Waste water treating apparatus |
JPS6377595A (en) * | 1986-09-17 | 1988-04-07 | Kurita Water Ind Ltd | Activated sludge treating device |
JPS63182100A (en) * | 1987-01-23 | 1988-07-27 | Toyota Motor Corp | Treatment of water-soluble cutting/grinding waste liquid |
JPH0330897A (en) * | 1989-06-27 | 1991-02-08 | Hitachi Plant Eng & Constr Co Ltd | Waste water treatment apparatus |
JPH05337479A (en) * | 1992-06-08 | 1993-12-21 | Kurita Water Ind Ltd | Aerobic treatment plant |
JPH0631297A (en) * | 1992-07-10 | 1994-02-08 | Nippon Steel Corp | Method for treating waste water containing high concentration of nitrogen sophistically |
JPH07155784A (en) * | 1993-12-08 | 1995-06-20 | Kubota Corp | Treatment of organic waste water |
JPH0810785A (en) * | 1994-06-27 | 1996-01-16 | Sumitomo Heavy Ind Ltd | Activated sludge device |
JPH08257583A (en) * | 1995-03-23 | 1996-10-08 | Kurita Water Ind Ltd | Waste water treatment apparatus |
JPH0970599A (en) * | 1995-09-06 | 1997-03-18 | Sharp Corp | Waste water treating device and treatment of waste water |
JPH0999294A (en) * | 1995-10-05 | 1997-04-15 | Kurita Water Ind Ltd | Waste water treating equipment |
JPH09276890A (en) * | 1996-04-15 | 1997-10-28 | Ebara Corp | Treatment of organic waste water containing polyvinyl alcohol |
JPH1057984A (en) * | 1996-08-13 | 1998-03-03 | Kurita Water Ind Ltd | Biological treating device |
JPH1080693A (en) * | 1996-09-06 | 1998-03-31 | Sharp Corp | Treatment of waste water and waste water treating device |
JPH1119675A (en) * | 1997-06-30 | 1999-01-26 | Shinko Pantec Co Ltd | Treatment of organic matter-containing water and device therefor |
JP2000042584A (en) * | 1998-07-31 | 2000-02-15 | Kurita Water Ind Ltd | High load biological treatment and device therefor |
JP2001314885A (en) * | 2000-05-10 | 2001-11-13 | Kurita Water Ind Ltd | High load biological treatment method |
JP2003010874A (en) * | 2001-06-29 | 2003-01-14 | Ebara Corp | Method and apparatus for high-speed biological treatment of organic sewage |
JP2005238152A (en) * | 2004-02-27 | 2005-09-08 | Kurita Water Ind Ltd | Organic material-containing water treatment method |
JP2006082024A (en) * | 2004-09-16 | 2006-03-30 | Kurita Water Ind Ltd | Biological treatment apparatus |
JP2006167550A (en) * | 2004-12-14 | 2006-06-29 | Kurita Water Ind Ltd | Biological treatment apparatus |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009208012A (en) * | 2008-03-05 | 2009-09-17 | Japan Organo Co Ltd | Water treating method and water treating apparatus |
JP2012501848A (en) * | 2008-09-10 | 2012-01-26 | ヨーロピアン・スペース・エージェンシー | Equipment, toilet, livestock shed and method for treatment of urea-containing water |
WO2012053233A1 (en) * | 2010-10-18 | 2012-04-26 | 栗田工業株式会社 | Ultrapure water production process |
JP2012086124A (en) * | 2010-10-18 | 2012-05-10 | Kurita Water Ind Ltd | Ultrapure water making method |
CN103168006A (en) * | 2010-10-18 | 2013-06-19 | 栗田工业株式会社 | Ultrapure water production process |
US9085475B2 (en) | 2010-10-18 | 2015-07-21 | Kurita Water Industries Ltd. | Ultrapure water producing method and apparatus |
WO2013015128A1 (en) * | 2011-07-22 | 2013-01-31 | 栗田工業株式会社 | Biological treatment method and treatment device for amine-containing waste water |
JP2013022536A (en) * | 2011-07-22 | 2013-02-04 | Kurita Water Ind Ltd | Biological treatment method for amine-containing wastewater and treatment equipment |
CN104230039A (en) * | 2013-06-13 | 2014-12-24 | 中国石油化工股份有限公司 | Advanced processing reuse method for city standard-reaching sewage |
CN103359885A (en) * | 2013-07-30 | 2013-10-23 | 邹振生 | Double-membrane wastewater biological treatment system |
JP2016016363A (en) * | 2014-07-08 | 2016-02-01 | 栗田工業株式会社 | Method and apparatus for treatment of washing wastewater from food and drink production apparatus |
CN106082549A (en) * | 2016-08-03 | 2016-11-09 | 杭州富阳佳畅机械有限公司 | The biophysics of electroplating wastewater processes technique |
CN106082452A (en) * | 2016-08-03 | 2016-11-09 | 杭州富阳佳畅机械有限公司 | A kind of preparation of advanced treatment of electroplating waste |
CN106116042A (en) * | 2016-08-03 | 2016-11-16 | 杭州富阳佳畅机械有限公司 | A kind of method synchronizing to remove the advanced treating electroplating sewerage of cyanogen, chromium |
CN106082549B (en) * | 2016-08-03 | 2019-04-19 | 杭州富阳佳畅机械有限公司 | The biophysics treatment process of electroplating wastewater |
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