JP2007052992A - Water cut-off treatment method of vehicle-mounted electric wire - Google Patents

Water cut-off treatment method of vehicle-mounted electric wire Download PDF

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JP2007052992A
JP2007052992A JP2005236791A JP2005236791A JP2007052992A JP 2007052992 A JP2007052992 A JP 2007052992A JP 2005236791 A JP2005236791 A JP 2005236791A JP 2005236791 A JP2005236791 A JP 2005236791A JP 2007052992 A JP2007052992 A JP 2007052992A
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water
agent
vehicle
electric wire
curing
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JP4884719B2 (en
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Kenji Miyamoto
賢次 宮本
Tetsuji Tanaka
徹児 田中
Hiroki Hirai
宏樹 平井
Hirotaka Yamada
浩孝 山田
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Sumitomo Wiring Systems Ltd
AutoNetworks Technologies Ltd
Sumitomo Electric Industries Ltd
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Sumitomo Wiring Systems Ltd
AutoNetworks Technologies Ltd
Sumitomo Electric Industries Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To carry out water cut-off treatment of a vehicle-mounted electric wire more rapidly and steadily. <P>SOLUTION: Water cut-off treatment of the vehicle-mounted electric wire (for example, grounding wire 10) is carried out by a water cut-off treatment method including a water cut-off agent supply process in which a cut-off agent 1, with a property of promoting hardening by a specific hardening treatment (for example, irradiation of light) and fluidity at an initial state, is supplied to one of the terminals of the vehicle-mounted wire, a decompression process in which the air inside a covering material 14 is sucked and decompressed from the other terminal of the vehicle-mounted wire during and after supply of the cut-off agent 1 so that the other portion of the cut-off agent 1 supplied may penetrate inside the covering material 14 while a part of the cut-off agent is exposed at one of the terminals of the vehicle-mounted wire, and a cut-off agent hardening process in which, after the decompression process, the cut-off agent 1 exposed at one of the terminals is applied a hardening treatment (for example, irradiation of light by an optical irradiation device 50) and the surface of at least the exposed cut-off agent 1 is hardened. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、車両に搭載される車載用電線に止水処理を施す技術に関するものである。   The present invention relates to a technique for performing a water stop treatment on an in-vehicle electric wire mounted on a vehicle.

前記車載用電線としては、高い防水性が求められるものがある。例えば、車両等に設けられる電気回路をアース端子に接続するためのアース用電線は、その端末に固定されたアース接続端子が外部に露出した状態で適当なアース部位(例えば車両のボディ)に接続されるため、当該端末から水分が侵入しやすく、当該水分が被覆材の内側を伝って回路に侵入すると当該回路の正常な動作を妨げるおそれがある。   Some of the on-vehicle electric wires are required to have high waterproof properties. For example, a grounding wire for connecting an electric circuit provided in a vehicle or the like to a grounding terminal is connected to a suitable grounding part (for example, a vehicle body) with the grounding terminal fixed to the terminal exposed to the outside. Therefore, moisture easily enters from the terminal, and if the moisture enters the circuit through the inside of the covering material, there is a possibility that normal operation of the circuit is hindered.

そこで、このようなアース用電線をはじめとする車載用電線の止水処理を行う方法として、下記特許文献1には、車載用電線の一方の端末に流動性を有する止水剤を供給するとともに他方の端末を吸引することにより、当該止水剤を前記車載用電線の導体と被覆材との隙間に引き込んで充填する方法が開示されている。
特開2004−355851号公報
Therefore, as a method for performing a water-stop treatment of an in-vehicle electric wire including such a grounding electric wire, the following Patent Document 1 supplies a water-stopping agent having fluidity to one end of the in-vehicle electric wire. A method is disclosed in which the other end is sucked and the water-stopping agent is drawn into the gap between the conductor of the in-vehicle electric wire and the covering material.
JP 2004-355851 A

ここで、前記特許文献1では、前記車載用電線の一方の端末に供給される止水剤として、供給時に流動性を有し、かつ供給後に硬化して粘度が高まるものが好適であるとされ、その材質の具体例として、自然硬化性のシリコーン樹脂が挙げられている。   Here, in the said patent document 1, it is said that what has fluidity | liquidity at the time of supply, and hardens | cures after supply and a viscosity increases is suitable as a water stop agent supplied to one terminal of the said vehicle-mounted electric wire. As a specific example of the material, a naturally curable silicone resin is cited.

しかしながら、供給された止水剤を自然硬化させる前記特許文献1の方法による場合、止水剤を被覆材の内側に充填した直後の段階では流動性の高い止水剤が前記一方の端末側に逆流し、止水構造が崩れるおそれがある。このため、止水剤を充填した後は、止水剤がある程度自然硬化するまでしばらく時間を置く必要があった。もちろん、止水剤として素早く自然硬化する材質を選択すれば当該硬化のための待ち時間を短縮することができるが、あまりに硬化速度の速い材質を選択すると、止水剤が電線内部に充分に浸透することができなくなり、かえって止水性能を低下させることとなる。このため、素早く自然硬化する止水剤を用いることにより止水処理に要する時間を短縮するのにも限界があった。   However, in the case of the method of Patent Document 1 in which the supplied water-stopping agent is naturally cured, a highly fluid water-stopping agent is placed on the one terminal side immediately after the water-stopping agent is filled inside the coating material. It may flow backward and the water stop structure may collapse. For this reason, after filling with the water-stopping agent, it was necessary to wait for a while until the water-stopping agent was naturally cured to some extent. Of course, if you select a material that spontaneously cures quickly as the water-stopping agent, you can reduce the waiting time for the curing, but if you select a material that has a too fast curing rate, the water-stopper will penetrate sufficiently into the wire. It will not be possible to do so, rather it will reduce the water stop performance. For this reason, there was a limit to shortening the time required for the water stop treatment by using a water stop agent that spontaneously hardens quickly.

本発明は、このような事情に鑑みてなされたものであり、より迅速かつ確実に車載用電線の止水処理を行うことを目的とする。   This invention is made | formed in view of such a situation, and it aims at performing the water stop process of the vehicle-mounted electric wire more rapidly and reliably.

前記課題を解決するための手段として、本発明は、導体の外側に被覆材を有して車両に搭載される車載用電線を止水処理するための方法であって、前記車載用電線の一方の端末に、特定の硬化処理が施されることにより硬化が促進される特性を有するとともに初期状態では流動性を有する止水剤を供給する止水剤供給工程と、この供給された止水剤の一部が前記車載用電線の一方の端末に露出する状態で他の部分が前記被覆材の内側に浸透するように、前記止水剤の供給中又は供給後に前記車載用電線の他方の端末から前記被覆材の内側のエアを吸引して減圧する減圧工程と、この減圧工程後、前記一方の端末に露出した止水剤に前記硬化処理を施すことにより、少なくとも当該露出した止水剤の表面を硬化させる止水剤硬化工程とを含むことを特徴とするものである(請求項1)。   As means for solving the above-mentioned problems, the present invention provides a method for water-stopping an in-vehicle electric wire mounted on a vehicle having a coating material on the outside of the conductor, and one of the in-vehicle electric wires. A water-stopping agent supplying step of supplying a water-stopping agent having a property that the hardening is promoted by being subjected to a specific hardening process and having fluidity in an initial state, and the supplied water-stopping agent The other end of the in-vehicle electric wire during or after the supply of the water-stopping agent so that the other portion penetrates into the inside of the covering material while a part of the in-vehicle electric wire is exposed to the one end of the in-vehicle electric wire From the decompression step of sucking and decompressing the air inside the covering material from, and after the decompression step, by applying the curing treatment to the waterproofing agent exposed to the one terminal, at least the exposed waterproofing agent Including a water-stopper curing process for curing the surface. And it is characterized in (Claim 1).

この車載用電線の止水処理方法によれば、特定の硬化処理が施されることにより硬化が促進される特性を有するとともに初期状態では流動性を有する止水剤の一部を被覆材の内側に引き込んで残りの一部を車載用電線の一方の端末に露出させておき、この一方の端末に露出した止水剤に前記硬化処理を施すことによって少なくとも当該露出した止水剤の表面を強制的に素早く硬化させるという構成であるため、この硬化処理が完了した時点で、前記被覆材の内側に引き込まれた止水剤が前記一方の端末側に逆流して止水構造が崩れるのを確実に食い止めることができ、その結果、止水剤が自然硬化するのを待つ必要のあった従来の止水処理方法に比べて、より迅速かつ確実に安定した止水構造を構築することができる。しかも、硬化処理を行うことによって強制的に止水剤を硬化させる構成であることから、従来の止水処理方法において止水処理に要する時間を短縮するために比較的素早く自然硬化する止水剤を用いた場合と異なり、止水剤が被覆材の内側に浸透するために必要な止水剤の流動性が前記減圧工程中において確実に維持されるため、充分な量の止水剤を被覆材の内側に浸透させることができ、その結果、高い止水性能をより確実に得ることができる。   According to the water stop treatment method for an in-vehicle electric wire, a part of the water stop agent having a property that the hardening is accelerated by being subjected to a specific hardening treatment and having fluidity in the initial state is provided inside the coating material. The remaining part is exposed to one end of the in-vehicle electric wire, and at least the surface of the exposed water stopping agent is forced by applying the curing treatment to the water stopping agent exposed to the one end. Therefore, when the curing process is completed, it is ensured that the water-stopping agent drawn inside the coating material flows backward to the one terminal side and the water-stopping structure is destroyed. As a result, it is possible to construct a stable water stop structure more quickly and reliably than the conventional water stop treatment method in which it is necessary to wait for the water stop agent to naturally cure. Moreover, since the water-stopping agent is forcibly hardened by performing a hardening treatment, the water-stopping agent that spontaneously hardens relatively quickly in order to shorten the time required for the water-stopping treatment in the conventional water-stopping treatment method. Unlike the case of using the water-stop agent, the fluidity of the water-stop agent necessary for the water-stop agent to permeate the inside of the coating material is reliably maintained during the decompression step. As a result, high water-stopping performance can be obtained more reliably.

なお、前記車載用電線の種類や配設個所は特に限定されるものではないが、好ましいものとして、車両に搭載される回路をアースに接続するためのアース用電線が挙げられる(請求項2)。   In addition, although the kind and arrangement | positioning location of the said vehicle-mounted electric wire are not specifically limited, The electric wire for earthing for connecting the circuit mounted in a vehicle to earth | ground is mentioned as a preferable thing (Claim 2). .

この構成によれば、アース用電線に前記止水処理を施すことができるので、一般に車両の外部環境の影響を受けやすいアース部位(例えば、車両のボディ)に接続されるアース用電線の端末から反対の端末へ水分が浸入するのを防止することができる。   According to this configuration, since the water stop treatment can be performed on the grounding wire, the terminal of the grounding wire that is generally connected to a ground part (for example, the body of the vehicle) that is easily affected by the external environment of the vehicle. It is possible to prevent moisture from entering the opposite terminal.

ただし、本発明に係る止水処理方法は、前記アース用電線に限られず、例えば、電線途中部の被覆材が剥離されたスプライス線のように被覆材内部への水分の浸入が発生し易い種類のもの、又はコネクタに防水機能が備えられていてもその回路自体に特に高い防水性が要求される回路に接続されるものにも好適に採用することができる。   However, the water stop treatment method according to the present invention is not limited to the grounding wire, and is, for example, a type in which moisture is likely to enter the inside of the covering material, such as a splice wire from which the covering material is peeled off in the middle of the wire. Even if the connector is provided with a waterproof function, it can be suitably used for a circuit connected to a circuit that requires a particularly high waterproof property.

ここで、前記特定の硬化処理が施されることにより硬化が促進される特性を有する止水剤としては、例えば、光硬化特性を有する止水剤を好適に用いることができる。この場合、前記止水剤硬化工程における硬化処理は、前記一方の端末に露出した止水剤に光を照射することによって行えばよい(請求項3)。   Here, as the water-stopping agent having the property that curing is accelerated by the specific curing treatment, for example, a water-stopping agent having photocuring properties can be suitably used. In this case, the curing process in the water stopping agent curing step may be performed by irradiating the water stopping agent exposed to the one terminal with light (Claim 3).

また、前記特定の硬化処理が施されることにより硬化が促進される特性を有する止水剤としては、熱硬化特性を有する止水剤を用いることも可能である。この場合、前記止水剤硬化工程における硬化処理は、前記一方の端末に露出した止水剤を加熱することによって行えばよい(請求項4)。   In addition, as the water-stopping agent having a property that curing is accelerated by the specific curing treatment, a water-stopping agent having a thermosetting property can be used. In this case, the curing process in the water stopping agent curing step may be performed by heating the water stopping agent exposed to the one terminal (claim 4).

ここで、前記止水剤としては、前記硬化処理が施された際の硬化速度よりも遅い速度で自然硬化する特性を併せ持った止水剤を用いることが好ましい(請求項5)。   Here, as the water-stopping agent, it is preferable to use a water-stopping agent having a property of spontaneously curing at a rate slower than the curing rate when the curing treatment is performed (Claim 5).

このように止水剤に自然硬化特性をも持たせることにより、前記被覆材の内側に引き込まれた止水剤であって前記硬化処理が施されることが困難な部分の止水剤についても確実に硬化させることができるため、被覆材内側における止水剤の充填位置が電線使用時にずれるのを防止することができ、止水構造をより安定して維持することができる。しかも、自然硬化時の硬化速度が遅めに設定されていることにより、前記減圧工程中に止水剤の自然硬化が進行することにより止水剤が充分に被覆材の内部に浸透できなくなる事態が有効に回避される。   In this way, by providing the water-stopping agent with natural curing characteristics, the water-stopping agent drawn into the inside of the coating material and difficult to be subjected to the curing treatment is also used. Since it can harden | cure reliably, it can prevent that the filling position of the water stop agent inside a coating | covering material shifts at the time of electric wire use, and can maintain a water stop structure more stably. In addition, since the curing rate at the time of natural curing is set to be slow, the water-stopping agent cannot sufficiently penetrate into the coating material due to the natural curing of the water-stopping agent during the decompression step. Is effectively avoided.

また、前記止水剤硬化工程は、前記一方の端末に露出した止水剤のうち、少なくとも当該端末における導体と被覆材との隙間を覆うのに必要な止水剤を残して、残りの余分な止水剤を除去してから行うものであることが好ましい(請求項6)。   In addition, the water-stopper curing step leaves at least a water-stopper that is necessary to cover at least a gap between the conductor and the covering material at the terminal among the water-stopper exposed at the one terminal, and the remaining excess. It is preferable to carry out after removing the water-stopping agent (Claim 6).

この構成によれば、光照射又は加熱によって硬化させるべき部分の止水剤の表面積が小さくなるため、前記止水剤硬化工程に要する時間を短くすることができ、さらに迅速に車載用電線の止水処理を行うことができる。   According to this configuration, since the surface area of the water-stopping agent in the portion to be cured by light irradiation or heating is reduced, the time required for the water-stopping agent hardening process can be shortened, and the vehicle-mounted electric wire can be stopped more quickly. Water treatment can be performed.

以上のように、本発明の車載用電線の止水処理方法によれば、より迅速かつ確実に車載用電線の止水処理を行うことができる。   As described above, according to the water stop treatment method for in-vehicle electric wires of the present invention, the water stop treatment for in-vehicle electric wires can be performed more quickly and reliably.

本発明の好ましい実施の形態を図面を参照しながら説明する。   A preferred embodiment of the present invention will be described with reference to the drawings.

なお、本実施形態では、車両に搭載された回路をアースに接続するためのアース用電線に止水処理する方法を説明するが、本発明はこれに限らず、高い防水性が求められる各種の車載用電線にも適用可能である。   In addition, although this embodiment demonstrates the method of carrying out a water stop process to the electric wire for earth | ground for connecting the circuit mounted in the vehicle to earth | ground, this invention is not limited to this, The various waterproofness in which high waterproofness is calculated | required It can also be applied to in-vehicle electric wires.

この実施の形態にかかるアース用電線の止水処理方法は、次の各工程を含む。   The water stopping method for grounding wires according to this embodiment includes the following steps.

1)端子圧着工程
この工程は、図1(a)(b)に示すようなアース用電線10の一方の端末にアース接続端子20を圧着固定する工程である。
1) Terminal crimping process This process is a process of crimping and fixing the ground connection terminal 20 to one end of the grounding electric wire 10 as shown in FIGS.

前記アース用電線10には、導体12の周囲に被覆材14を有する絶縁電線を用いる。そして、その一方の端末の被覆材14を所定長さだけ除去して前記導体12を露出させておく。   As the grounding wire 10, an insulated wire having a covering 14 around the conductor 12 is used. Then, the covering material 14 at one end is removed by a predetermined length to expose the conductor 12.

このアース用電線10の端末に対し、図1(a)(b)に示すようなアース接続端子20を圧着固定する。図示のアース接続端子20は、単一の金属板で構成され、車両のボディアースに接続されるアース接続部21と、導体バレル22及びインシュレーションバレル24とを一体に有している。アース接続部21には図略のボルトが挿通可能なボルト挿通孔21aが設けられ、当該ボルトによって前記アース接続部21が車両のボディに締結されることにより、当該ボディに電気的に接続される(すなわちボディアースに接続される)ようになっている。   A ground connection terminal 20 as shown in FIGS. 1A and 1B is fixed to the end of the ground wire 10 by pressure. The illustrated ground connection terminal 20 is formed of a single metal plate, and integrally includes a ground connection portion 21 connected to a vehicle body ground, a conductor barrel 22 and an insulation barrel 24. The ground connection portion 21 is provided with a bolt insertion hole 21a through which a not-illustrated bolt can be inserted, and the ground connection portion 21 is fastened to the vehicle body by the bolt to be electrically connected to the body. (Ie connected to the body ground).

このアース接続端子20の前記両バレル22,24が開いた状態で、前記のように被覆材14が除去されたアース用電線10の端末をセットし、その後、前記導体バレル22及びインシュレーションバレル24をそれぞれ閉じて前記導体12及び被覆材14に圧着(かしめ)固定する。   In a state where both the barrels 22 and 24 of the ground connection terminal 20 are opened, the end of the grounding wire 10 from which the covering material 14 has been removed as described above is set, and then the conductor barrel 22 and the insulation barrel 24. Are closed and fixed to the conductor 12 and the covering material 14 by crimping.

2)止水剤供給工程
この工程は、図4に示すように、前記アース用電線10の一方の端末(アース接続端子20が固定された側の端末)に対して、止水剤1を供給する工程である。具体的には、アース接続端子20の導体バレル22とインシュレーションバレル24との間に止水剤1を溜めるように、図略のディスペンサによって止水剤1を滴下する。なお、この滴下位置は端子構造に応じて適宜設定が可能である。
2) Water-stopping agent supplying step This step supplies the water-stopping agent 1 to one terminal of the grounding wire 10 (the terminal on the side where the ground connection terminal 20 is fixed), as shown in FIG. It is a process to do. Specifically, the water-stopping agent 1 is dropped by a dispenser (not shown) so that the water-stopping agent 1 is stored between the conductor barrel 22 and the insulation barrel 24 of the ground connection terminal 20. In addition, this dripping position can be appropriately set according to the terminal structure.

この止水剤1の滴下は1回で行ってもよいが、後述する減圧工程を開始すると、止水剤1が被覆材14の内側に浸透していき、前記アース接続端子20上に溜まっている止水剤1の量が徐々に減少するため、これを補給するように追って止水剤1を滴下することにより、当該滴下を複数回にわけて行うのが好ましい。これにより、前記アース接続端子20上に溜まっている止水剤1の量をほぼ均一に保ちながら、充分な量の止水剤1を導体12と被覆材14との隙間にむらなく確実に充填することができる。   The dripping of the water-stopping agent 1 may be performed once, but when the pressure reducing process described later is started, the water-stopping agent 1 penetrates into the inside of the covering material 14 and accumulates on the ground connection terminal 20. Since the amount of the water-stopping agent 1 gradually decreases, it is preferable to drop the water-stopping agent 1 in a plurality of times by dropping the water-stopping agent 1 so as to replenish it. Thereby, a sufficient amount of the water-stopping agent 1 is uniformly filled in the gap between the conductor 12 and the covering material 14 while keeping the amount of the water-stopping agent 1 collected on the ground connection terminal 20 substantially uniform. can do.

前記止水剤1は、初期状態では流動性を有するが、光の照射を受けると硬化する(光硬化特性を有する)材質によって構成されている。   The water-stopping agent 1 has fluidity in the initial state, but is made of a material that cures when irradiated with light (has photocuring characteristics).

この止水剤1が初期状態において有する流動性は、後述する減圧工程時において止水剤1が被覆材14内に浸透し得る程度のものであればよい。具体的には、0.006〜6Pa・s程度の初期粘度であれば、10kPa〜100kPa程度の圧力で5〜120秒ほど減圧することにより、止水剤1を被覆材14内に浸透させることが可能であることが確認されている。   The fluidity of the water-stopping agent 1 in the initial state may be such that the water-stopping agent 1 can permeate into the coating material 14 during the decompression step described later. Specifically, if the initial viscosity is about 0.006 to 6 Pa · s, the waterstop agent 1 can be infiltrated into the coating material 14 by reducing the pressure for about 5 to 120 seconds at a pressure of about 10 kPa to 100 kPa. It has been confirmed that.

そして、光の照射を受けて硬化した後の止水剤1においては、少なくとも止水剤1の形態が安定して維持される程度にその粘度が高まっていればよい。ただし、当該光硬化後の止水剤1は、配線時に端末部に外力が加わった場合等における止水剤1の割れや破損の回避のため、ある程度の弾性(柔軟性)を有することが好ましい。また、この止水剤1が光硬化する際の硬化速度は、止水処理に要する時間の短縮のため、比較的速い方が好ましい。   And in the water-stopping agent 1 after receiving the light irradiation and hardening, it is sufficient that the viscosity is increased to such an extent that at least the form of the water-stopping agent 1 is stably maintained. However, the water-stopping agent 1 after the photocuring preferably has a certain degree of elasticity (flexibility) in order to avoid cracking or breakage of the water-stopping agent 1 when an external force is applied to the terminal portion during wiring. . In addition, the curing rate when the water-stopping agent 1 is photocured is preferably relatively fast in order to shorten the time required for the water-stopping treatment.

ここで、止水剤1が前記のように光硬化特性を有していても、止水剤1のうち被覆材14の内側深くに充填される部分については、光の照射を受けて硬化することが困難である。従って、止水剤1は、自然に硬化する特性を併せ持っていることが好ましい。これにより、被覆材14の内側における止水剤1の充填位置が電線使用時にずれることが防止される。この場合、被覆材14内に充填された止水剤1が電線の曲げ等に良好に追従して変形できるように、止水剤1は自然硬化後においても弾性(柔軟性)に富むものが好適である。また、この自然硬化の際の硬化速度が速すぎると、止水剤1が充分に被覆材14の内側に浸透しなくなるため、止水剤1としては、少なくとも前記光硬化の際の硬化速度よりも遅い速度で自然硬化するものが好適である。なお、止水剤1は、初期状態から比較的粘度の高いものであれば、その性状が供給時からほとんど時間変化しないものであってもよい。   Here, even if the water-stopping agent 1 has photocuring properties as described above, the portion of the water-stopping agent 1 that is filled deep inside the coating material 14 is cured by receiving light irradiation. Is difficult. Therefore, it is preferable that the water-stopping agent 1 has a property of naturally curing. Thereby, it is prevented that the filling position of the water-stopping agent 1 inside the covering material 14 is shifted when the electric wire is used. In this case, the water-stopping agent 1 filled in the covering material 14 is excellent in elasticity (flexibility) even after natural curing so that the water-stopping agent 1 can be deformed by following the bending of the electric wire. Is preferred. In addition, if the curing rate at the time of natural curing is too high, the water-stopping agent 1 will not sufficiently penetrate into the inside of the coating material 14, so that the water-stopping agent 1 is at least faster than the curing rate at the time of photocuring. Those that spontaneously cure at a slow speed are preferred. In addition, as long as the water-stopper 1 is a thing with comparatively high viscosity from an initial state, the property may hardly change over time from the time of supply.

このような止水剤1としては、例えば、紫外線硬化型シリコーン樹脂が好適である。この紫外線硬化型シリコーン樹脂は、一般に、主成分である多官能性シリコーンオリゴマーに、光重合開始剤(例えば、ベンゾフェノン系、ベンゾイン系、アセトフェノン系等の化合物)を含有させたものであり、紫外線の照射を受けると、この光重合開始剤が励起状態となって前記シリコーンオリゴマーを重合させるためのラジカルを生成する構成となっている。このような紫外線硬化型シリコーン樹脂には、さらに前記のような自然硬化特性を持たせることが好ましく、そのためには、例えば、空気中の湿気の存在下で硬化反応を促進させる硬化触媒等をさらに前記シリコーンオリゴマーに含有させればよい。   As such a water-stopping agent 1, for example, an ultraviolet curable silicone resin is suitable. This ultraviolet curable silicone resin generally contains a polyfunctional silicone oligomer as a main component containing a photopolymerization initiator (for example, a benzophenone-based, benzoin-based, acetophenone-based compound, etc.) When irradiated, the photopolymerization initiator is excited to generate radicals for polymerizing the silicone oligomer. Such an ultraviolet curable silicone resin preferably further has the above-mentioned natural curing characteristics. For this purpose, for example, a curing catalyst that accelerates the curing reaction in the presence of moisture in the air is further added. What is necessary is just to make it contain in the said silicone oligomer.

ただし、前記止水剤1の材質はこのような紫外線硬化型シリコーン樹脂に限られるものではなく、光硬化特性を有するとともに初期状態では流動性を有するものであれば、各種材質を使用することが可能である。このような材質としては、例えば、エポキシ樹脂、ポリウレタン、ポリエステル、ポリブタジエンのアクリレートのような多官能性モノマーやオリゴマーに前記のような光重合開始剤を含有させたものが挙げられる。また、止水剤1は、紫外線によって硬化するものでなくてもよく、可視光やレーザ光によって硬化するものであってもよい。   However, the material of the water-stopping agent 1 is not limited to such an ultraviolet curable silicone resin, and various materials can be used as long as they have photocuring characteristics and fluidity in the initial state. Is possible. Examples of such a material include a polyfunctional monomer or oligomer such as an epoxy resin, polyurethane, polyester, or polybutadiene acrylate containing a photopolymerization initiator as described above. Moreover, the water stop agent 1 may not be hardened | cured by an ultraviolet-ray, and may be hardened | cured by visible light or a laser beam.

3)減圧工程
この工程は、アース用電線10の他方の端末(アース接続端子20が固定された端末と反対側の端末)から被覆材14の内側のエアを吸引する工程である。これにより、前記止水剤供給工程において供給された止水剤1を、強制的に被覆材14の内側に浸透させる。
3) Depressurization step This step is a step of sucking air inside the covering material 14 from the other end of the ground wire 10 (the end opposite to the end to which the ground connection terminal 20 is fixed). Thereby, the water-stopping agent 1 supplied in the water-stopping agent supply step is forcibly permeated inside the covering material 14.

この減圧工程は、前記止水剤供給工程による1回目の滴下によって止水剤1をアース接続端子20上の導体バレル22とインシュレーションバレル24との間に溜め、この止水剤1が当該端末における導体12と被覆材14との隙間を全周にわたって覆う状態にしてから開始することが好ましい。このようにすれば、止水剤1にエアが巻き込まれるのを有効に抑止しながら安定した状態で止水剤1を導体12と被覆材14との隙間に引き込むことができる。   In this decompression step, the water-stopping agent 1 is accumulated between the conductor barrel 22 and the insulation barrel 24 on the ground connection terminal 20 by the first dripping in the water-stopping agent supply step, and the water-stopping agent 1 is connected to the terminal. It is preferable to start after the gap between the conductor 12 and the covering material 14 is covered over the entire circumference. In this way, the water-stopping agent 1 can be drawn into the gap between the conductor 12 and the covering material 14 in a stable state while effectively preventing air from being caught in the water-stopping agent 1.

また、この減圧工程は、1本のアース用電線10ごとに個別に行ってもよいが、この実施の形態では複数本のアース用電線10について同時に行うようにする。具体的には、複数本のアース用電線10の他方の端末を、図2に示すように、共通の電線接続装置30に接続し、この電線接続装置30を圧力制御盤42を介して吸引ポンプ44の吸込み口に接続することにより、前記各アース用電線10に対し減圧工程を同時に行うようにする。このようにすれば、止水処理のための一連の工程(止水剤供給工程、減圧工程、及び後述する止水剤硬化工程)を、複数本のアース用電線10に対して同時に行うことができ、止水処理の効率化を図ることができる。   In addition, this decompression step may be performed individually for each grounding wire 10, but in this embodiment, it is performed simultaneously for a plurality of grounding wires 10. Specifically, as shown in FIG. 2, the other end of the plurality of grounding wires 10 is connected to a common wire connecting device 30, and the wire connecting device 30 is connected to the suction pump via the pressure control panel 42. By connecting to the suction port 44, a pressure reducing step is simultaneously performed on each of the grounding wires 10. If it does in this way, a series of processes (water stop agent supply process, pressure reduction process, and water stop agent hardening process mentioned below) for water stop processing can be simultaneously performed to a plurality of grounding electric wires 10. It is possible to improve the efficiency of the water stop treatment.

図2に示す電線接続装置30は、内部が密閉されたハウジング32を備え、このハウジング32内の密閉空間が適当な配管40及び前記圧力制御盤42を介して前記吸引ポンプ44の吸い込み口に接続されている。   An electric wire connection device 30 shown in FIG. 2 includes a housing 32 whose inside is sealed, and a sealed space in the housing 32 is connected to a suction port of the suction pump 44 via an appropriate pipe 40 and the pressure control panel 42. Has been.

前記ハウジング32の前壁にはゴム栓保持板34が設けられている。このゴム栓保持板34には、図3に示すような複数個のゴム栓36が縦横に並んだ状態で保持されている。そして、各ゴム栓36に各アース用電線10の端末が接続されるようになっている。   A rubber stopper holding plate 34 is provided on the front wall of the housing 32. The rubber stopper holding plate 34 holds a plurality of rubber stoppers 36 as shown in FIG. Each rubber plug 36 is connected to the terminal of each grounding wire 10.

具体的に、前記ゴム栓保持板34には、これを板厚方向に貫通する複数のゴム栓取付孔34aが設けられ、各ゴム栓取付孔34a内に前記ゴム栓36がそれぞれ嵌着されている。   Specifically, the rubber plug holding plate 34 is provided with a plurality of rubber plug mounting holes 34a penetrating in the thickness direction, and the rubber plugs 36 are respectively fitted in the rubber plug mounting holes 34a. Yes.

各ゴム栓36は、その中心軸上に貫通孔36aをもつ筒状に形成され、当該貫通孔36aの内周面にはシール用突条36bが形成されている。このシール用突条36bは、前記貫通孔36a内に挿入される前記アース用電線10の被覆材14の表面と圧接することにより、ハウジング32内の密閉状態を保つ役割を果たす。同様に、ゴム栓36の外周面にもシール用突条36cが形成され、このシール用突条36cが前記ゴム栓取付孔34aの内周面と圧接することによりシールがなされている。   Each rubber plug 36 is formed in a cylindrical shape having a through hole 36a on its central axis, and a sealing protrusion 36b is formed on the inner peripheral surface of the through hole 36a. The sealing protrusion 36b plays a role of maintaining a sealed state in the housing 32 by being pressed against the surface of the covering material 14 of the grounding wire 10 inserted into the through hole 36a. Similarly, a sealing protrusion 36c is formed on the outer peripheral surface of the rubber plug 36, and the sealing protrusion 36c is pressed against the inner peripheral surface of the rubber plug mounting hole 34a to provide a seal.

各ゴム栓取付孔34aの外側端部には、前記ゴム栓36の外周部を外側から覆うゴム栓カバー38が設けられ、このゴム栓カバー38は、前記ゴム栓36の貫通孔36a内にアース用電線10の端末を誘い込むためのテーパー状貫通孔38aを中心に有している。   A rubber plug cover 38 that covers the outer peripheral portion of the rubber plug 36 from the outside is provided at the outer end of each rubber plug mounting hole 34 a. The rubber plug cover 38 is grounded in the through hole 36 a of the rubber plug 36. A taper-shaped through hole 38a for guiding the end of the electric wire 10 is provided at the center.

この電線接続装置30において、各ゴム栓カバー38の貫通孔38aを通じてその奥のゴム栓36の貫通穴36aに各アース用電線10の他方の端末(アース接続端子20が固定された端末と反対側の端末)を圧入することにより、これらのアース用電線10をハウジング32内の共通の密閉空間に接続することができる。そして、この密閉空間内を前記圧力制御盤42の制御下で前記吸引ポンプ44の作動により一定の負圧になるまで減圧することにより、各アース用電線10における被覆材14の内側空間もそれぞれ同時に減圧することができる。   In this electric wire connecting device 30, the other end of each earthing wire 10 (opposite side to the end to which the earth connecting terminal 20 is fixed) is inserted into the through hole 36 a of the rubber plug 36 at the back through the through hole 38 a of each rubber plug cover 38. These terminals can be connected to a common sealed space in the housing 32 by press-fitting the terminal. Then, the inside space of the covering material 14 in each grounding wire 10 is also simultaneously reduced by reducing the pressure in the sealed space under the control of the pressure control panel 42 until the suction pump 44 operates to a certain negative pressure. The pressure can be reduced.

以上のような減圧工程は、最後に滴下された止水剤1が被覆材14の内側に完全に浸透する前に終了する。これにより、減圧工程後の止水剤1は、その一部が電線端末に露出している状態で、他の部分が被覆材14の内側に浸透した状態となる。   The decompression step as described above ends before the water-stopping agent 1 dripped at the end completely penetrates the inside of the covering material 14. Thereby, the water-stopping agent 1 after the pressure-reducing step is in a state where a part of the water-stopper 1 is exposed to the wire terminal and the other part penetrates into the inside of the covering material 14.

4)止水剤硬化工程
この工程は、前記減圧工程後、アース用電線10の一方の端末(アース接続端子20が固定された側の端末)に露出した止水剤1に光を照射することにより、少なくとも当該露出した止水剤1の表面を強制的に硬化させる工程である。
4) Water-stopping agent curing step This step is to irradiate the water-stopping agent 1 exposed to one terminal of the grounding wire 10 (the terminal on the side to which the ground connection terminal 20 is fixed) after the decompression step. Is a step of forcibly curing at least the surface of the exposed water-stopping agent 1.

具体的には、図5に示すように、前記一方の端末に露出した止水剤1に対し、光照射装置50によって光を照射する。この光照射装置50としては、止水剤1の光硬化特性に合わせて、紫外線、可視光、レーザ光等の、適切な種類の光を発生するものを使用する。例えば、止水剤1として紫外線硬化型シリコーン樹脂を用いた場合は、光照射装置50として紫外線を発生するものを使用すればよい。このような紫外線照射装置としては、例えば高圧水銀灯が挙げられる。   Specifically, as shown in FIG. 5, the light irradiating device 50 irradiates light to the water-stopping agent 1 exposed at the one terminal. As this light irradiation apparatus 50, the thing which generate | occur | produces appropriate types of light, such as an ultraviolet-ray, visible light, a laser beam, according to the photocuring characteristic of the water-stopping agent 1 is used. For example, when an ultraviolet curable silicone resin is used as the water-stopping agent 1, a material that generates ultraviolet rays may be used as the light irradiation device 50. An example of such an ultraviolet irradiation device is a high-pressure mercury lamp.

この光照射装置50による光照射は、前記一方の端末に露出した止水剤1のうち、図5に示すように少なくとも当該端末における導体12と被覆材14との隙間を覆うのに必要な止水剤1を残して、拭き取りや吸引(電線外部からの吸引)等により残りの余分な止水剤1を除去してから行うことが好ましい。これにより、光照射によって硬化させるべき部分の止水剤1の表面積が小さくなるため、この止水剤硬化工程に要する時間を短くすることができる。ただし、このように余分な止水剤1を強制的に除去しなくても、止水剤1の最後の滴下後に減圧工程をある程度長い時間続行すれば、端末部に露出する止水剤1の量を少なくすることが可能である。ただしその場合は、減圧時間を微調整する必要が生じる。   The light irradiation by the light irradiation device 50 is a stop necessary for covering at least the gap between the conductor 12 and the covering material 14 in the water-stopping agent 1 exposed at the one terminal, as shown in FIG. It is preferable to carry out after removing the remaining water-stopping agent 1 by wiping or suctioning (suctioning from the outside of the electric wire) or the like leaving the liquid agent 1. Thereby, since the surface area of the waterproofing agent 1 of the part which should be hardened by light irradiation becomes small, the time which this waterproofing agent hardening process requires can be shortened. However, even if the extra water-stopping agent 1 is not forcibly removed in this way, if the decompression process is continued for a certain period of time after the last dripping of the water-stopping agent 1, It is possible to reduce the amount. However, in that case, it is necessary to finely adjust the decompression time.

以上のような止水剤硬化工程が完了すると、アース用電線10のアース接続端子20側の端末部の拡大断面図である図6に示すように、止水剤1の露出部分及びその近傍が光硬化して光硬化部1aが形成される。この光硬化部1aの厚みは、前記光照射装置50の照射時間を増減することによって調整することが可能であり、照射時間が長いほど光硬化部1aの厚みが大きくなる。この光硬化部1aが形成されると、当該端末における導体12と被覆材14との隙間が光硬化部1aにより閉塞され(図例では導体12が複数の導体素線12aによって構成されているために、これら導体素線12aどうしの隙間についても光硬化部1aにより閉塞され)、これにより、止水剤1のうち被覆材14の内側に充填された部分である内側充填部1bが電線端末側に逆流して外部に漏れ出すことが防止される。なお、止水剤1として、初期状態では比較的粘度が低くかつ比較的緩やかに自然硬化するものを用いた場合、この止水剤硬化工程が完了した時点では内側充填部1bの自然硬化が充分に進行していない(つまり、内側充填部1bがある程度の流動性を有する)こととなるが、そのような場合でも、前記のように光硬化部1aが形成されていれば、内側充填部1bが外部に漏れ出すことはないため、止水構造が大きく崩れることはない。従って、この止水剤硬化工程が完了すれば、内側充填部1bの自然硬化を待つことなく、アース用電線10を次工程(例えば検査工程や、出荷・梱包工程など)に送ることが可能である。   When the water-stopping agent curing process as described above is completed, as shown in FIG. 6 which is an enlarged cross-sectional view of the terminal portion on the ground connection terminal 20 side of the ground wire 10, the exposed portion of the water-stopping agent 1 and the vicinity thereof are The photocuring part 1a is formed by photocuring. The thickness of the photocuring portion 1a can be adjusted by increasing or decreasing the irradiation time of the light irradiation device 50. The longer the irradiation time, the larger the thickness of the photocuring portion 1a. When this photocured portion 1a is formed, the gap between the conductor 12 and the covering material 14 at the terminal is closed by the photocured portion 1a (in the illustrated example, the conductor 12 is composed of a plurality of conductor strands 12a). In addition, the gap between the conductor strands 12a is also closed by the photocuring portion 1a), so that the inner filling portion 1b, which is a portion of the water blocking agent 1 filled inside the covering material 14, is It is prevented from flowing back and leaking outside. In the case where a water-stopper 1 is used which has a relatively low viscosity in the initial state and is naturally cured relatively slowly, when the water-stopper curing step is completed, the inner filling portion 1b is sufficiently cured naturally. (In other words, the inner filling portion 1b has a certain degree of fluidity), but even in such a case, if the photocured portion 1a is formed as described above, the inner filling portion 1b is not formed. Will not leak to the outside, so the water-stop structure will not collapse significantly. Therefore, when this water-stopper curing process is completed, the grounding wire 10 can be sent to the next process (for example, inspection process, shipping / packaging process, etc.) without waiting for the natural curing of the inner filling portion 1b. is there.

以上説明したように、本実施形態のアース用電線10の止水処理方法によれば、光硬化特性を有するとともに初期状態では流動性を有する止水剤1の一部を被覆材14の内側に引き込んで残りの一部をアース用電線10の一方の端末(アース接続端子20が固定された側の端末)に露出させておき、当該端末に露出した止水剤1に光を照射することによって少なくとも当該露出した止水剤1の表面を強制的に素早く硬化させて光硬化部1aを形成する構成であるため、この光照射が完了した時点で、止水剤1のうち前記被覆材14の内側に引き込まれた部分である内側充填部1bが前記一方の端末側に逆流して止水構造が崩れるのを前記光硬化部1aによって確実に食い止めることができ、その結果、止水剤1が自然硬化するのを待つ必要のあった従来の止水処理方法に比べて、より迅速かつ確実に安定した止水構造を構築することができる。しかも、止水剤硬化工程において光を照射することにより強制的に止水剤1を硬化させる構成であることから、従来の止水処理方法において止水処理に要する時間を短縮するために比較的素早く自然硬化する止水剤1を用いた場合と異なり、止水剤1が被覆材14の内側に浸透するために必要な止水剤1の流動性が前記減圧工程中において確実に維持されるため(止水剤1として自然硬化特性を併せ持ったものを用いた場合でも、その自然硬化時の硬化速度を遅めに設定することにより止水剤1の流動性が維持される)、充分な量の止水剤1を被覆材14の内側に浸透させることができ、その結果、高い止水性能をより確実に得ることができる。   As described above, according to the water stop treatment method for the grounding electric wire 10 of the present embodiment, a part of the water stop agent 1 having photocuring characteristics and fluidity in the initial state is placed inside the covering material 14. By pulling in and exposing the remaining part to one terminal (terminal on the side where the ground connection terminal 20 is fixed) of the grounding wire 10 and irradiating the water-stopping agent 1 exposed to the terminal with light Since at least the surface of the exposed water-stopping agent 1 is forcibly and quickly cured to form the photocuring portion 1a, the light covering portion 14 of the water-stopping agent 1 of the water-stopping agent 1 is formed when this light irradiation is completed. The photocuring portion 1a can reliably prevent the inner filling portion 1b, which is a portion drawn inward, from flowing backward to the one terminal side and the water-stopping structure from collapsing, and as a result, the water-stopping agent 1 I need to wait for natural hardening Compared to conventional waterproofing processing method Tsu can be constructed more quickly and reliably stable water stopping structure. And since it is the structure which hardens the water stop agent 1 by irradiating light in a water stop agent hardening process, in order to shorten the time which a water stop process requires in the conventional water stop treatment method, it is comparatively Unlike the case where the water-stopping agent 1 that spontaneously cures quickly is used, the fluidity of the water-stopping agent 1 that is necessary for the water-stopping agent 1 to permeate the inside of the covering material 14 is reliably maintained during the decompression step. Therefore, even when a water-stopper 1 having both natural curing characteristics is used, the fluidity of the water-stopper 1 is maintained by setting the cure rate at the time of natural cure slower. An amount of the water-stopping agent 1 can be infiltrated into the inside of the covering material 14, and as a result, high water-stopping performance can be obtained more reliably.

なお、本実施形態では、止水剤1として光硬化特性を有するものを使用したが、特定の硬化処理を施すことによって硬化が促進される特性を有するものであればこれに限るものではなく、例えば、加熱により硬化する熱硬化特性を有するものを使用してもよい。このような熱硬化性の材質は広く知られているが、その一例としては、加熱状況下で重合反応を促進する熱硬化触媒(例えば白金触媒)等を含有した熱硬化型シリコーン樹脂が挙げられる。もちろん、熱硬化性の止水剤1としてはこのような熱硬化型シリコーン樹脂に限られず、熱硬化特性を有する各種材質の中から適宜選択したものを使用可能である。なお、止水剤1としてこのような熱硬化性の材質を使用した場合、前記止水剤硬化工程は、例えば、前記一方の端末に露出した止水剤1に温風をブローすることによって行うことが可能である。   In the present embodiment, the water-stopping agent 1 having a photo-curing property is used. However, the water-stopping agent 1 is not limited to this as long as it has the property of being cured by applying a specific curing treatment. For example, you may use what has the thermosetting characteristic hardened | cured by heating. Such thermosetting materials are widely known, and an example thereof is a thermosetting silicone resin containing a thermosetting catalyst (for example, a platinum catalyst) that accelerates a polymerization reaction under heating conditions. . Of course, the thermosetting water-stopping agent 1 is not limited to such a thermosetting silicone resin, and a material appropriately selected from various materials having thermosetting characteristics can be used. In addition, when such a thermosetting material is used as the water-stopping agent 1, the water-stopping agent curing step is performed, for example, by blowing warm air to the water-stopping agent 1 exposed at the one terminal. It is possible.

また、本実施形態では、止水剤供給工程を端子圧着工程によってアース接続端子20を接続した後に行っているが、これをアース接続端子20の接続前に行うことも可能である。ただしその場合には、前記のようにアース接続端子20を止水剤受けとして利用することができないため、止水剤1の供給が不安定になるおそれがある。それでも、止水剤1を受けるための何らかの治具を別途電線端末に取り付けながら止水剤1の供給を行うようにすれば、安定して止水剤1を供給することができる。   Moreover, in this embodiment, although the water-stopping agent supply process is performed after connecting the ground connection terminal 20 by the terminal crimping process, this can be performed before the connection of the ground connection terminal 20. However, in that case, since the ground connection terminal 20 cannot be used as a water-stopping agent receiver as described above, the supply of the water-stopping agent 1 may become unstable. Still, the water-stopping agent 1 can be stably supplied by supplying the water-stopping agent 1 while separately attaching some jig for receiving the water-stopping agent 1 to the wire terminal.

さらに、前記端子圧着工程で固定する端子は、必ずしもアース接続端子20でなくてもよく、これと反対側の端末に固定される端子(例えば車載負荷側に接続される端子)であってもよい。この場合も、当該端子よりも電線内側の位置に良好な止水構造を構築することが可能である。ただし、この場合には、アース接続部からこれと反対側の端末の前記止水構造に至るまでの領域で被覆材14内に水分が侵入するおそれがあるのに対し、前記のようにアース接続端子20が固定される側(すなわちアース接続部から侵入する水分の入口側)の端末に止水剤を供給すれば、被覆材14の内側への水分の侵入をほぼ確実に阻止できるという利点が得られる。   Furthermore, the terminal to be fixed in the terminal crimping step is not necessarily the ground connection terminal 20, but may be a terminal (for example, a terminal connected to the vehicle load side) fixed to the terminal on the opposite side. . Also in this case, it is possible to construct a good water stop structure at a position inside the electric wire from the terminal. However, in this case, there is a possibility that moisture may enter the coating material 14 in the region from the ground connection portion to the water stop structure of the terminal on the opposite side, whereas the ground connection is performed as described above. If a water stop agent is supplied to the terminal on the side where the terminal 20 is fixed (that is, the inlet side of moisture entering from the ground connection portion), there is an advantage that moisture can be almost surely prevented from entering the inside of the covering material 14. can get.

ここで、前記止水剤1の色については特に言及しなかったが、例えば着色剤を混入させた有色の止水剤1を使用してもよい。このようにすれば、止水処理が施された電線であるかどうかを目視で容易に判別することが可能となる。ただし、本実施形態のように止水剤1を光照射により硬化させる場合には、光が比較的透過し易い色に止水剤1を着色することが好ましい(例えば、群青色は紫外線を透過させ易い)。   Here, although the color of the water-stopping agent 1 is not particularly mentioned, for example, a colored water-stopping agent 1 mixed with a colorant may be used. If it does in this way, it will become possible to discriminate | determine easily visually whether it is the electric wire which performed the water stop process. However, when the water-stopping agent 1 is cured by light irradiation as in this embodiment, it is preferable to color the water-stopping agent 1 in a color that allows light to pass through relatively easily (for example, ultramarine blue transmits ultraviolet light). Easy to do).

前記図1〜図6に示した方法により、次の条件下で止水処理を行った。
・止水剤…吸湿硬化特性(自然硬化特性)を併せ持った紫外線硬化型シリコーン樹脂「TB−3161;スリーボンド社製」
紫外線硬化前の粘度:0.3 Pa・s
紫外線硬化特性:照度150mW/cm2で20秒→硬化膜厚6mm
吸湿硬化特性:25℃湿度55%で120時間→硬化膜厚7mm
・紫外線照射機…200W高圧水銀灯 φ3.0mmライトガイド「OMNICURE 2000;EXFO社製」
照射距離:5cm
照度:1W/cm2
・電線断面積…1.25mm2
・止水剤滴下量…15mg
・減圧時の圧力…-50kPa(ゲージ圧)
・減圧時間…止水剤の滴下開始から30秒間
・紫外線照射時間…5秒間(端末部に露出した止水剤のうち余分な部分を拭き取ってから照射を開始)
The water stop treatment was performed under the following conditions by the method shown in FIGS.
・ Waterproofing agent: UV-curing silicone resin that has both moisture absorption and curing properties (natural curing properties) “TB-3161; manufactured by ThreeBond Co., Ltd.”
Viscosity before UV curing: 0.3 Pa · s
UV curing characteristics: 20 seconds at illuminance of 150 mW / cm 2 → cured film thickness 6 mm
Moisture absorption and curing characteristics: 120 hours at 25 ° C and 55% humidity → cured film thickness 7 mm
・ Ultraviolet irradiation machine… 200W high-pressure mercury lamp φ3.0mm light guide “OMNICURE 2000; manufactured by EXFO”
Irradiation distance: 5cm
Illuminance: 1W / cm 2
・ Cross section area ... 1.25mm 2
・ Waterproofing agent dripping amount… 15mg
・ Pressure during decompression: -50kPa (gauge pressure)
・ Decompression time: 30 seconds from the start of dripping of the water-stopping agent ・ UV irradiation time: 5 seconds (irradiation starts after wiping off the excess portion of the water-stopping agent exposed to the terminal)

以上のような条件下で止水処理を行った後、端末部に露出した止水剤が硬化していることを指触により確認することができた。さらに、当該端末部を水槽に浸漬した状態で、反対側の端末からエアを吹き込んで50kPa(ゲージ圧)の圧力を加えたところ、水槽内に気泡の発生がないことを確認することができた。   After the water stop treatment was performed under the above conditions, it was confirmed by finger touch that the water stop agent exposed to the terminal portion was cured. Furthermore, when the terminal part was immersed in the water tank and air was blown from the terminal on the opposite side and a pressure of 50 kPa (gauge pressure) was applied, it was confirmed that no bubbles were generated in the water tank. .

(a)は本発明の実施の形態にかかるアース用電線の一方の端末にアース接続端子を圧着固定した構造を示す平面図、(b)はその正面図である。(A) is a top view which shows the structure which crimped-fixed the ground connection terminal to one terminal of the electric wire for earth | ground concerning embodiment of this invention, (b) is the front view. 前記アース用電線における被覆材の内側を減圧するための装置の例を示す図である。It is a figure which shows the example of the apparatus for decompressing the inside of the coating | covering material in the said electric wire for earth | grounds. 図2に示される電線接続装置の電線接続部を示す断面図である。It is sectional drawing which shows the electric wire connection part of the electric wire connection apparatus shown by FIG. 前記アース用電線の一方の端末に止水剤を滴下した状態を表す図である。It is a figure showing the state which dripped the water stop agent on one terminal of the said electric wire for earthing | grounding. 光照射装置を用いて前記アース用電線の一方の端末に光を照射している状況を表す図である。It is a figure showing the condition which is irradiating light to one terminal of the said electric wire for earth | ground using a light irradiation apparatus. 前記アース用電線の一方の端末部の拡大断面図である。It is an expanded sectional view of one end part of the electric wire for earthing.

符号の説明Explanation of symbols

1 止水剤
10 アース用電線
12 導体
14 被覆材
DESCRIPTION OF SYMBOLS 1 Water stop agent 10 Electric wire for ground 12 Conductor 14 Coating | covering material

Claims (7)

導体の外側に被覆材を有して車両に搭載される車載用電線を止水処理するための方法であって、
前記車載用電線の一方の端末に、特定の硬化処理が施されることにより硬化が促進される特性を有するとともに初期状態では流動性を有する止水剤を供給する止水剤供給工程と、
この供給された止水剤の一部が前記車載用電線の一方の端末に露出する状態で他の部分が前記被覆材の内側に浸透するように、前記止水剤の供給中又は供給後に前記車載用電線の他方の端末から前記被覆材の内側のエアを吸引して減圧する減圧工程と、
この減圧工程後、前記一方の端末に露出した止水剤に前記硬化処理を施すことにより、少なくとも当該露出した止水剤の表面を硬化させる止水剤硬化工程とを含むことを特徴とする車載用電線の止水処理方法。
A method for water-stopping an in-vehicle electric wire mounted on a vehicle having a coating material outside the conductor,
One end of the on-vehicle electric wire has a characteristic that curing is promoted by being subjected to a specific curing treatment, and in the initial state, a water-stopping agent supplying step of supplying a water-stopping agent having fluidity,
During or after the supply of the water-stopping agent, the other portion penetrates into the inside of the covering material in a state where a part of the supplied water-stopping agent is exposed at one end of the in-vehicle electric wire. A decompression step of sucking and decompressing the air inside the covering material from the other end of the in-vehicle electric wire;
After the pressure reduction step, the vehicle-mounted vehicle includes a water-stopping agent curing step of hardening at least the surface of the exposed water-stopping agent by performing the curing treatment on the water-stopping agent exposed to the one terminal. Water stop treatment method for industrial wires.
請求項1記載の車載用電線の止水処理方法において、
前記車載用電線は、車両に搭載される回路をアースに接続するためのアース用電線であることを特徴とする車載用電線の止水処理方法。
In the water stop processing method of the electric cable for vehicles according to claim 1,
The on-vehicle electric wire is a grounding electric wire for connecting a circuit mounted on a vehicle to an earth, and a water stop treatment method for an on-vehicle electric wire.
請求項1又は2記載の車載用電線の止水処理方法において、
前記止水剤供給工程は、前記特定の硬化処理が施されることにより硬化が促進される特性として光硬化特性を有する止水剤を供給する工程であり、
前記止水剤硬化工程は、前記一方の端末に露出した止水剤に光を照射することにより前記硬化処理を行う工程であることを特徴とする車載用電線の止水処理方法。
In the water stop processing method of the vehicle-mounted electric wire according to claim 1 or 2,
The water-stop agent supplying step is a step of supplying a water-stop agent having a photo-curing property as a property that curing is accelerated by the specific curing treatment being performed,
The water stopping agent curing step is a step of performing the curing treatment by irradiating the water stopping agent exposed to the one terminal with light.
請求項1又は2記載の車載用電線の止水処理方法において、
前記止水剤供給工程は、前記特定の硬化処理が施されることにより硬化が促進される特性として熱硬化特性を有する止水剤を供給する工程であり、
前記止水剤硬化工程は、前記一方の端末に露出した止水剤を加熱することにより前記硬化処理を行う工程であることを特徴とする車載用電線の止水処理方法。
In the water stop processing method of the vehicle-mounted electric wire according to claim 1 or 2,
The water-stop agent supplying step is a step of supplying a water-stop agent having a thermosetting property as a property that the curing is accelerated by the specific curing treatment being performed,
The water stopping agent curing step is a step of performing the curing treatment by heating the water stopping agent exposed to the one terminal, and a water stopping treatment method for an in-vehicle electric wire.
請求項1〜4のいずれか1項に記載の車載用電線の止水処理方法において、
前記止水剤として、前記硬化処理が施された際の硬化速度よりも遅い速度で自然硬化する特性を併せ持った止水剤を用いることを特徴とする車載用電線の止水処理方法。
In the water stop processing method of the electric cable for vehicles according to any one of claims 1 to 4,
A water-stop treatment method for an in-vehicle electric wire, characterized in that a water-stop agent having a property of spontaneously curing at a rate slower than a cure rate when the curing treatment is performed is used as the water-stop agent.
請求項1〜5のいずれか1項に記載の車載用電線の止水処理方法において、
前記止水剤硬化工程は、前記一方の端末に露出した止水剤のうち、少なくとも当該端末における導体と被覆材との隙間を覆うのに必要な止水剤を残して、残りの余分な止水剤を除去してから行うものであることを特徴とする車載用電線の止水処理方法。
In the water stop processing method of the electric cable for vehicles according to any one of claims 1 to 5,
In the water-stopper curing step, of the water-stopper exposed at the one terminal, at least the water-stopper necessary for covering the gap between the conductor and the covering material at the terminal is left, and the remaining extra water-stopper is left. A water stop treatment method for an in-vehicle electric wire, which is performed after removing the liquid agent.
導体の外側に被覆材を有して車両に搭載される車載用電線であって、
請求項1〜6のいずれか1項に記載の止水処理方法により被覆材の内側に止水剤が充填されていることを特徴とする車載用電線。
An in-vehicle electric wire that is mounted on a vehicle with a covering material outside the conductor,
A vehicle-mounted electric wire, wherein a water-stopping agent is filled inside the coating material by the water-stopping treatment method according to any one of claims 1 to 6.
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JP2010192129A (en) * 2009-02-16 2010-09-02 Asti Corp Water cut-off treatment method of electric wire, and water cut-off structure of electric wire
JP2011216192A (en) * 2010-03-31 2011-10-27 Furukawa Electric Co Ltd:The Connecting part and its connecting method of conductor and terminal
WO2013011846A1 (en) * 2011-07-19 2013-01-24 株式会社オートネットワーク技術研究所 Anti-corrosion agent, sheathed electrical wire with terminal, and wire harness
WO2013011847A1 (en) * 2011-07-19 2013-01-24 株式会社オートネットワーク技術研究所 Anti-corrosion agent, sheathed electrical wire with terminal, and wire harness
JP2015153715A (en) * 2014-02-19 2015-08-24 住友電装株式会社 Method of manufacturing electrical wire with terminal
JP2016181387A (en) * 2015-03-24 2016-10-13 古河電気工業株式会社 Electric wire with terminal, and manufacturing method thereof
JP2017091865A (en) * 2015-11-12 2017-05-25 山里産業株式会社 Cable for temperature sensor and manufacturing method therefor
WO2018074153A1 (en) * 2016-10-17 2018-04-26 住友電装株式会社 Corrosion inhibitor supply device, and method for producing terminal-equipped wire
JP2020035635A (en) * 2018-08-30 2020-03-05 古河電気工業株式会社 Terminal-equipped wire and manufacturing method thereof

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Publication number Priority date Publication date Assignee Title
JP2010192129A (en) * 2009-02-16 2010-09-02 Asti Corp Water cut-off treatment method of electric wire, and water cut-off structure of electric wire
JP2011216192A (en) * 2010-03-31 2011-10-27 Furukawa Electric Co Ltd:The Connecting part and its connecting method of conductor and terminal
WO2013011846A1 (en) * 2011-07-19 2013-01-24 株式会社オートネットワーク技術研究所 Anti-corrosion agent, sheathed electrical wire with terminal, and wire harness
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JP2015153715A (en) * 2014-02-19 2015-08-24 住友電装株式会社 Method of manufacturing electrical wire with terminal
JP2016181387A (en) * 2015-03-24 2016-10-13 古河電気工業株式会社 Electric wire with terminal, and manufacturing method thereof
JP2017091865A (en) * 2015-11-12 2017-05-25 山里産業株式会社 Cable for temperature sensor and manufacturing method therefor
WO2018074153A1 (en) * 2016-10-17 2018-04-26 住友電装株式会社 Corrosion inhibitor supply device, and method for producing terminal-equipped wire
JP2020035635A (en) * 2018-08-30 2020-03-05 古河電気工業株式会社 Terminal-equipped wire and manufacturing method thereof
JP7097265B2 (en) 2018-08-30 2022-07-07 古河電気工業株式会社 Wire with terminal and its manufacturing method

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