JP2007048654A - Power generator - Google Patents

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JP2007048654A
JP2007048654A JP2005233134A JP2005233134A JP2007048654A JP 2007048654 A JP2007048654 A JP 2007048654A JP 2005233134 A JP2005233134 A JP 2005233134A JP 2005233134 A JP2005233134 A JP 2005233134A JP 2007048654 A JP2007048654 A JP 2007048654A
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water
water treatment
pipe
storage tank
heat exchanger
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JP4986424B2 (en
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Hidenori Nakabayashi
秀則 中林
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Kyocera Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a power generator capable of simplifying piping construction work and reducing construction cost. <P>SOLUTION: This device has a reformer 38 to steam reform hydrocarbon fuel gas, a fuel cell 1 to generate power by using the fuel gas and oxidizer gas supplied from the reformer 38, a water treatment device 10 to purify pure water to be used for steam reforming in the reformer 38, a heat exchanger 5 in order to recover exhaust heat of the fuel cell 1, and a hot-water tank 6 to store the hot water, and in the water treatment device 10, a water supply piping 15 to supply water to the water treatment device 10 and an exhaust water piping 35 to exhaust water after water treatment from the water treatment device 10 are connected, the heat exchanger 5 and the hot-water tank 6 are coupled by a circulation piping 7, and the water supply piping 15 and/or the exhaust water piping 35 connected to the water treatment device 10 are coupled to the circulation piping 7. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、炭化水素系原燃料ガスを水蒸気改質する改質器と、電力を発生させる燃料電池と、改質器内の水蒸気改質に用いる純水を精製する水処理装置と、燃料電池の排熱を回収するための熱交換器と、湯水を貯える貯湯タンクとを有する発電装置に関するものである。   The present invention relates to a reformer for steam reforming a hydrocarbon-based raw fuel gas, a fuel cell for generating electric power, a water treatment device for purifying pure water used for steam reforming in the reformer, and a fuel cell. The present invention relates to a power generator having a heat exchanger for recovering the exhaust heat of the water and a hot water storage tank for storing hot water.

従来の固体酸化物形燃料電池を用いた発電装置は、図3に示すように、固体酸化物形燃料電池1、天然ガスなどを燃料電池1に供給するための燃料供給装置2、および酸化剤ガスとしての空気を燃料電池1に供給するための空気供給装置3、燃料電池1に供給する天然ガスなどを加湿する燃料加湿器4、燃料加湿器4に純水を供給する水処理装置10を具備している。水処理装置10には、純水化用の水を供給する純水化用水供給配管15、精製された純水を燃料加湿器4に供給する純水供給配管30が接続され、また水処理装置10には、水処理後の濃縮水を排出する排水配管35が接続されている。   As shown in FIG. 3, a conventional power generator using a solid oxide fuel cell includes a solid oxide fuel cell 1, a fuel supply device 2 for supplying natural gas or the like to the fuel cell 1, and an oxidant. An air supply device 3 for supplying air as gas to the fuel cell 1, a fuel humidifier 4 for humidifying natural gas supplied to the fuel cell 1, and a water treatment device 10 for supplying pure water to the fuel humidifier 4 It has. Connected to the water treatment apparatus 10 are a pure water supply pipe 15 for supplying pure water, a pure water supply pipe 30 for supplying purified pure water to the fuel humidifier 4, and a water treatment apparatus. 10 is connected to a drain pipe 35 for discharging concentrated water after water treatment.

また、燃料加湿器4には、加湿された天然ガスなどの原燃料ガスを改質するための改質器37が接続されている。   The fuel humidifier 4 is connected to a reformer 37 for reforming raw fuel gas such as humidified natural gas.

水処理装置10は、発電時は殆ど燃料加湿器4に処理水を供給すると共に、水処理後の濃縮水を常時排水している(例えば、特許文献1参照)。   The water treatment device 10 supplies treated water to the fuel humidifier 4 almost at the time of power generation, and always drains concentrated water after water treatment (see, for example, Patent Document 1).

燃料電池1には、発電により生じる排熱を湯水に熱交換する熱交換器5が接続され、さらに熱交換器5には、貯湯タンク6内の水を循環するための循環配管7が接続され、循環配管7には循環配管7内の水を熱交換器5に強制的に循環するための循環ポンプ8が設けられている。循環配管7の一端は貯湯タンク6の底部に、他端は貯湯タンク6の上部に接続され、循環ポンプ8により、貯湯タンク底部の水を熱交換器5を通して貯湯タンク6の上部に戻す。   The fuel cell 1 is connected to a heat exchanger 5 for exchanging heat generated by power generation to hot water, and the heat exchanger 5 is connected to a circulation pipe 7 for circulating water in the hot water storage tank 6. The circulation pipe 7 is provided with a circulation pump 8 for forcibly circulating the water in the circulation pipe 7 to the heat exchanger 5. One end of the circulation pipe 7 is connected to the bottom of the hot water storage tank 6, and the other end is connected to the upper part of the hot water storage tank 6, and the water at the bottom of the hot water storage tank is returned to the upper part of the hot water storage tank 6 through the heat exchanger 5.

燃料電池1は、発電と共に熱を発生するが、その発生した熱の大半は燃料電池1自体の温度を維持するために用いられ、残った熱は、熱交換器5内の循環配管7を通過する水と熱交換し、加熱された水は貯湯タンク6へ回収される(例えば、特許文献2参照)。
特開2002−280031号公報 特開2002−134143号公報
The fuel cell 1 generates heat with power generation, but most of the generated heat is used to maintain the temperature of the fuel cell 1 itself, and the remaining heat passes through a circulation pipe 7 in the heat exchanger 5. The heated water is exchanged with the water to be recovered, and the heated water is collected in the hot water storage tank 6 (see, for example, Patent Document 2).
JP 2002-280031 A JP 2002-134143 A

しかしながら、水処理装置10に純水化用水を供給する純水化用水供給配管15は、水源から、貯湯タンク6への水供給配管とは別個に設けていたため、配管が複雑になり、施工に費用が増加するという問題があった。   However, since the pure water supply pipe 15 for supplying the pure water to the water treatment apparatus 10 is provided separately from the water supply pipe from the water source to the hot water storage tank 6, the pipe becomes complicated and construction is difficult. There was a problem of increased costs.

また、水処理装置10による水処理後の濃縮水(純水化されなかった水)を排水するための排水配管35を、燃料電池外にまで延設する必要があり、配管が複雑になり、施工に費用が増加するという問題があった。   Moreover, it is necessary to extend the drainage pipe 35 for draining the concentrated water (water that has not been purified) after the water treatment by the water treatment apparatus 10 to the outside of the fuel cell, and the pipe becomes complicated. There was a problem that the construction cost increased.

本発明は、配管施工を簡素化し施工費用を削減できる発電装置を提供することを目的とする。   An object of this invention is to provide the electric power generating apparatus which can simplify piping construction and reduce construction cost.

本発明の発電装置は、炭化水素系原燃料ガスを水蒸気改質する改質器と、該改質器から供給された燃料ガスと酸化剤ガスを用いて発電する燃料電池と、前記改質器内の水蒸気改質に用いる純水を精製する水処理装置と、前記燃料電池からの排熱を回収するための熱交換器と、湯水を貯える貯湯タンクとを有するとともに、前記水処理装置には、該水処理装置に水を供給するための水供給配管、精製された純水を供給するための純水供給配管、及び純水に精製されなかった水処理後の排水を前記水処理装置から排出するための排水配管が接続されており、前記熱交換器と前記貯湯タンクとを循環配管により連結し、前記水処理装置に接続された水供給配管及び/又は排水配管を、前記循環配管に連結してなることを特徴とする。   The power generation device of the present invention includes a reformer that performs steam reforming of a hydrocarbon-based raw fuel gas, a fuel cell that generates power using the fuel gas and oxidant gas supplied from the reformer, and the reformer A water treatment device for purifying pure water used for steam reforming, a heat exchanger for recovering exhaust heat from the fuel cell, and a hot water storage tank for storing hot water, and the water treatment device , A water supply pipe for supplying water to the water treatment apparatus, a pure water supply pipe for supplying purified pure water, and waste water after water treatment that has not been purified to pure water from the water treatment apparatus A drainage pipe for discharging is connected, the heat exchanger and the hot water storage tank are connected by a circulation pipe, and a water supply pipe and / or a drainage pipe connected to the water treatment device is connected to the circulation pipe. It is characterized by being connected.

このような発電装置では、水処理装置の水供給配管及び排水配管のうち少なくとも一つを循環配管に連結したため、外部から、もしくは外部へ配管されていた従来の配管構造と比較し、配管が簡素化され、小型化を達成できるとともに、施工費用を大幅に削減できる。   In such a power generation device, since at least one of the water supply piping and drainage piping of the water treatment device is connected to the circulation piping, the piping is simpler than the conventional piping structure that is piped from the outside or outside. It is possible to achieve downsizing and construction costs can be greatly reduced.

即ち、水処理装置の水供給配管を循環配管に接続する場合、貯湯タンクに供給され、循環配管を流れる水を水供給配管を介して水処理装置に供給することができ、水源から貯湯タンクへの水供給路が一つで良いため、配管が簡素化され、施工費用を大幅に削減できる。また、水処理装置の排水配管を循環配管に接続する場合、従来のように排水配管を燃料電池外にまで延設する必要がないため、配管が簡素化され、施工費用を大幅に削減できるとともに、水資源の無駄を無くすこともできる。   That is, when the water supply pipe of the water treatment apparatus is connected to the circulation pipe, the water that is supplied to the hot water storage tank and flows through the circulation pipe can be supplied to the water treatment apparatus through the water supply pipe, from the water source to the hot water storage tank. Since only one water supply path is required, piping is simplified and construction costs can be greatly reduced. In addition, when connecting the drainage pipe of the water treatment device to the circulation pipe, it is not necessary to extend the drainage pipe to the outside of the fuel cell as in the past, so the piping is simplified and construction costs can be greatly reduced. In addition, waste of water resources can be eliminated.

即ち、従来、水処理装置による水処理後の濃縮水(純水に精製できなかった水)は、排水として排水配管により外部に捨てられており、例えば、1kw級の燃料電池の場合、燃料を加湿するのに1L/hの処理水が必要で、この処理水量を得るのに約2L/hの水を捨てており、一日15時間の発電運転とすると、捨てられる水の量は約30リットルとなり非常に無駄であった。本発明では、水処理装置の排水配管を循環配管に接続したため、純水に精製されなかった水が外部に捨てられることなく、貯湯タンクに供給され、再利用され、これにより、水資源を有効に用いることができる。   That is, conventionally, concentrated water after water treatment by a water treatment device (water that could not be purified to pure water) has been discarded to the outside as drainage by a drainage pipe. For example, in the case of a 1 kW class fuel cell, the fuel is To humidify, 1 L / h of treated water is required, and about 2 L / h of water is thrown away to obtain this amount of treated water. When generating power for 15 hours a day, the amount of water discarded is about 30 It became a liter and was very useless. In the present invention, since the drainage pipe of the water treatment apparatus is connected to the circulation pipe, the water that has not been purified into pure water is supplied to the hot water storage tank without being discarded to the outside and reused. Can be used.

また、本発明の発電装置は、前記循環配管は、前記貯湯タンクの底部と前記熱交換器を連結する往路循環配管と、前記熱交換器と前記貯湯タンク上部とを連結する復路循環配管とからなり、前記往路循環配管途中に循環ポンプを有するとともに、前記水処理装置の水供給配管を、前記循環ポンプと前記熱交換器との間における往路循環配管に接続してなることを特徴とする。このような発電装置では、循環ポンプにより、ある一定の圧力で強制的に水を水処理装置に供給することができ、水処理装置による純水精製効率を向上できる。   Further, in the power generator according to the present invention, the circulation pipe includes an outward circulation pipe that connects the bottom of the hot water storage tank and the heat exchanger, and a return circulation pipe that connects the heat exchanger and the upper part of the hot water storage tank. And having a circulation pump in the middle of the forward circulation pipe, and connecting the water supply pipe of the water treatment device to the forward circulation pipe between the circulation pump and the heat exchanger. In such a power generation device, water can be forcibly supplied to the water treatment device at a certain pressure by the circulation pump, and the pure water purification efficiency by the water treatment device can be improved.

さらに、本発明の発電装置は、前記循環配管は、前記貯湯タンクの底部と前記熱交換器を連結する往路循環配管と、前記熱交換器と前記貯湯タンク上部とを連結する復路循環配管とからなり、前記水処理装置の排水配管を、前記復路循環配管に接続してなることを特徴とする。一般に熱交換器においては、水供給配管が細く、長くなり、圧力損失が大きくなるため、熱交換器よりも下流側(復路循環配管)が上流側(往路循環配管)よりも圧力が低くなる。このような圧力の低い復路循環配管に排水配管を接続することにより、排水をスムーズに行うことができる。   Furthermore, in the power generator according to the present invention, the circulation pipe includes an outward circulation pipe that connects the bottom of the hot water storage tank and the heat exchanger, and a return circulation pipe that connects the heat exchanger and the hot water storage tank upper part. The drainage pipe of the water treatment apparatus is connected to the return circulation pipe. In general, in a heat exchanger, the water supply pipe is thin and long, and the pressure loss increases, so that the pressure on the downstream side (return circulation pipe) is lower than that on the upstream side (outward circulation pipe). By connecting the drain pipe to the return circulation pipe having such a low pressure, drainage can be performed smoothly.

また、本発明の発電装置は、前記水処理装置に供給される水の温度が所定温度以上となると、前記貯湯タンク内の湯を放出し、前記水供給配管により供給される水の温度が所定温度以下となるよう運転制御する制御装置を有することを特徴とする。例えば、熱交換器の入口水温を検出する温度検出器が検出した水の温度が所定温度以上になると、水処理装置に供給される水の温度が所定温度以上となるため、この場合には、貯湯タンク内の湯を放出し、水処理装置に導入される水の温度が所定の温度以下となるよう運転制御する。   In the power generation device of the present invention, when the temperature of the water supplied to the water treatment device becomes equal to or higher than a predetermined temperature, the hot water in the hot water storage tank is discharged, and the temperature of the water supplied by the water supply pipe is predetermined. It has the control apparatus which carries out operation control so that it may become below temperature. For example, when the temperature of the water detected by the temperature detector that detects the inlet water temperature of the heat exchanger is equal to or higher than a predetermined temperature, the temperature of the water supplied to the water treatment device is equal to or higher than the predetermined temperature. The hot water in the hot water storage tank is discharged, and operation control is performed so that the temperature of the water introduced into the water treatment device is equal to or lower than a predetermined temperature.

水処理装置は、高分子膜である逆浸透膜を利用しているため、処理水の水温が、高温になると破壊されるという弱点がある。このため、装置内の前記熱交換器の入口水温が、例えば40℃以上となると、貯湯タンクのお湯を放出することにより、貯湯タンク下部に冷たい上水が補給され、この低い温度の水が、循環配管より分岐した水供給配管を通って水処理装置に供給されることになり、逆浸透膜を保護でき、水処理装置の信頼性を向上できる。   Since the water treatment apparatus uses a reverse osmosis membrane which is a polymer membrane, there is a weak point that the water temperature of the treated water is destroyed when the temperature of the treated water becomes high. For this reason, when the inlet water temperature of the heat exchanger in the apparatus is, for example, 40 ° C. or more, the hot water in the hot water storage tank is discharged, so that cold hot water is supplied to the lower part of the hot water storage tank. It will be supplied to the water treatment apparatus through the water supply pipe branched from the circulation pipe, so that the reverse osmosis membrane can be protected and the reliability of the water treatment apparatus can be improved.

さらに、本発明の発電装置は、前記水処理装置の水供給配管内の水の温度が所定温度以下となると、前記循環ポンプを運転し、前記貯湯タンク内の水を前記水供給配管により前記水処理装置に供給して凍結を防ぎ、前記水処理装置の水供給配管内の水の温度が所定温度以上となると、前記循環ポンプの運転を停止するよう運転制御する制御装置を有することを特徴とする。例えば、熱交換器の入口水温を検出する温度検出器が検出した水の温度が所定温度以下になると、水処理装置の水供給配管内の水の温度が所定温度以下となるため、循環ポンプを運転し貯湯タンク内の水を水処理装置に循環させて凍結を防ぎ、熱交換器の入口水温を検出する温度検出器が検出した水の温度が所定温度以上になると、循環ポンプの運転を停止するよう運転制御する。   Furthermore, the power generation device of the present invention operates the circulation pump when the temperature of the water in the water supply pipe of the water treatment device is equal to or lower than a predetermined temperature, and causes the water in the hot water storage tank to flow through the water supply pipe. A control device that controls the operation to stop the operation of the circulation pump when the temperature of the water in the water supply pipe of the water treatment device is equal to or higher than a predetermined temperature is supplied to the treatment device to prevent freezing. To do. For example, when the temperature of the water detected by the temperature detector that detects the inlet water temperature of the heat exchanger becomes a predetermined temperature or lower, the temperature of the water in the water supply pipe of the water treatment device becomes lower than the predetermined temperature. Operate and circulate the water in the hot water storage tank to the water treatment device to prevent freezing, and stop the circulation pump when the temperature detected by the temperature detector that detects the inlet water temperature of the heat exchanger exceeds the specified temperature Control the operation.

発電装置は、設置して試運転後、実使用まで停止する場合や、夜間運転を休止する場合、メンテナンス等により停止する場合がある。冬季このような発電停止状態になると、水処理装置内の水が凍結し、水処理装置が破損するばかりでなく、発電装置自体が破損する恐れがある。これを防ぐため、装置内の最も温度が低くなる箇所、例えば熱交換器の入口水温を検出する温度検出器が4℃以下を検出した場合、発電装置全体を運転させるのではなく循環ポンプだけを運転して、水処理装置内の水を循環させることにより、凍結を未然に防ぐことができる。   The power generation device may be stopped due to maintenance or the like when installed and stopped after trial operation until actual use, or when the night operation is suspended. When the power generation is stopped in winter, the water in the water treatment apparatus is frozen, and the water treatment apparatus may be damaged and the power generation apparatus itself may be damaged. In order to prevent this, when the temperature detector that detects the lowest temperature in the device, for example, the temperature detector that detects the inlet water temperature of the heat exchanger detects 4 ° C. or less, it does not operate the entire power generator but only the circulation pump. Freezing can be prevented by operating and circulating the water in the water treatment device.

本発明の発電装置によれば、燃料電池を駆動させるために必要な、水処理装置の水供給配管、排水配管を、発電装置内の循環配管に連結させることにより、施工を簡素化でき、小型化を達成できるとともに、施工費用も大幅に低減できる。   According to the power generator of the present invention, the construction can be simplified by connecting the water supply pipe and drain pipe of the water treatment apparatus necessary for driving the fuel cell to the circulation pipe in the power generator. The construction cost can be greatly reduced.

本発明に係る実施形態を図面に基づき詳細に説明する。   Embodiments according to the present invention will be described in detail with reference to the drawings.

図1は本発明の発電装置を示すもので、図1において、図3で示した従来の発電装置と同じ機能を有するものについては、同一の符号を付与しており、それらの機能の詳細は、図3に準ずるものとして説明を省略する。   FIG. 1 shows a power generator according to the present invention. In FIG. 1, components having the same functions as those of the conventional power generator shown in FIG. 3 are given the same reference numerals. The description will be omitted because it conforms to FIG.

即ち、発電装置は、炭化水素系原燃料ガスを水蒸気改質する改質器38と、この改質器38から供給された燃料ガスと酸化剤ガスを用いて電力を発生させる燃料電池1と、改質器38内の水蒸気改質に用いる純水を精製する水処理装置10と、燃料電池1からの排熱を回収するための熱交換器5と、湯水を貯える貯湯タンク6とを具備して構成され、熱交換器5と貯湯タンク6とは循環配管7により連結されている。   That is, the power generator includes a reformer 38 for steam reforming the hydrocarbon-based raw fuel gas, a fuel cell 1 for generating electric power using the fuel gas and the oxidant gas supplied from the reformer 38, A water treatment device 10 for purifying pure water used for steam reforming in the reformer 38, a heat exchanger 5 for recovering exhaust heat from the fuel cell 1, and a hot water storage tank 6 for storing hot water are provided. The heat exchanger 5 and the hot water storage tank 6 are connected by a circulation pipe 7.

改質器38は燃料電池1を収容するケース内に収納され、燃料電池1の熱により加熱されて原燃料ガスの改質が行われる。   The reformer 38 is housed in a case housing the fuel cell 1 and is heated by the heat of the fuel cell 1 to reform the raw fuel gas.

また、図1において、符号11は、熱交換器5の入り口水温を検出する入口温度検出器、符号12は、熱交換器5の出口水温を検出する出口温度検出器、符号13は、燃料電池1の発電量に応じ発生する排熱を回収するために必要なポンプ出力を制御する制御装置である。符号14は、貯湯タンク6の水温を検出するタンク温度検出器である。   In FIG. 1, reference numeral 11 denotes an inlet temperature detector that detects the inlet water temperature of the heat exchanger 5, reference numeral 12 denotes an outlet temperature detector that detects the outlet water temperature of the heat exchanger 5, and reference numeral 13 denotes a fuel cell. It is a control apparatus which controls the pump output required in order to collect | recover the exhaust heat generated according to the electric power generation amount of 1. Reference numeral 14 denotes a tank temperature detector that detects the water temperature of the hot water storage tank 6.

そして、本発明の発電装置では、水処理装置10には、この水処理装置10に水を供給するための水供給配管15、精製された純水を燃料加湿器4に供給する純水供給配管30及び純水に精製されなかった水処理後の排水を水処理装置10から排出するための排水配管35が接続されており、水処理装置10の水供給配管15は、循環配管7に連結され、排水配管35は、外部に延設されている。   In the power generation apparatus of the present invention, the water treatment apparatus 10 includes a water supply pipe 15 for supplying water to the water treatment apparatus 10 and a pure water supply pipe for supplying purified pure water to the fuel humidifier 4. 30 and a drainage pipe 35 for discharging wastewater after water treatment that has not been purified to pure water from the water treatment apparatus 10 is connected. A water supply pipe 15 of the water treatment apparatus 10 is connected to the circulation pipe 7. The drain pipe 35 is extended outside.

即ち、循環配管7は、貯湯タンク6の底部と熱交換器5を連結する往路循環配管7aと、熱交換器5と貯湯タンク6上部とを連結する復路循環配管7bとからなり、往路循環配管7a途中に循環ポンプ8を有し、水処理装置10の水供給配管15は、循環ポンプ8と熱交換器5との間における往路循環配管7aに接続されている。熱交換器5には、燃料電池1からの排ガスが導入され、また、貯湯タンク6内の水が往路循環配管7aにより導入され、熱交換が行われる。   That is, the circulation pipe 7 includes an outward circulation pipe 7 a that connects the bottom of the hot water storage tank 6 and the heat exchanger 5, and a return circulation pipe 7 b that connects the heat exchanger 5 and the upper part of the hot water storage tank 6. 7 a has a circulation pump 8, and the water supply pipe 15 of the water treatment device 10 is connected to the forward circulation pipe 7 a between the circulation pump 8 and the heat exchanger 5. Exhaust gas from the fuel cell 1 is introduced into the heat exchanger 5, and water in the hot water storage tank 6 is introduced through the outward circulation pipe 7a to perform heat exchange.

また、制御装置13は、水処理装置10に供給される水の温度が所定温度以上となると、貯湯タンク6内の湯を放出し、水供給配管15により供給される水の温度が所定温度以下となるよう運転制御する。   Further, when the temperature of the water supplied to the water treatment device 10 is equal to or higher than the predetermined temperature, the control device 13 releases hot water in the hot water storage tank 6 and the temperature of the water supplied through the water supply pipe 15 is lower than the predetermined temperature. Control the operation so that

即ち、水処理装置10は高分子膜で構成されているため高温になると劣化し、ついには破損してしまう。その為常に低温、例えば40℃以下の水を供給していなければならない。そこで、熱交換器5の入口水温を検出する温度検出器11が検出した水の温度が所定温度、例えば40℃以上になると、水処理装置10に供給される水の温度が例えば40℃以上となると仮定して、貯湯タンク6内の湯を放出する。すると、貯湯タンク6の下部に水源からの冷たい水が供給され、循環配管7を通して水処理装置10に冷たい水が供給される。   That is, since the water treatment apparatus 10 is composed of a polymer film, the water treatment apparatus 10 deteriorates and eventually breaks at high temperatures. Therefore, it is necessary to always supply water at a low temperature, for example, 40 ° C. or lower. Therefore, when the temperature of the water detected by the temperature detector 11 that detects the inlet water temperature of the heat exchanger 5 becomes a predetermined temperature, for example, 40 ° C. or higher, the temperature of the water supplied to the water treatment device 10 is, for example, 40 ° C. or higher. Assuming that, the hot water in the hot water storage tank 6 is discharged. Then, cold water from the water source is supplied to the lower part of the hot water storage tank 6, and cold water is supplied to the water treatment device 10 through the circulation pipe 7.

一方、熱交換器5の入口水温を検出する温度検出器11が検出した水の温度が所定温度、例えば40℃以下になると貯湯タンク6内の湯の放出を停止する。このように水処理装置10に導入される水の温度が所定の温度以下となるよう運転制御するものである。   On the other hand, when the temperature of the water detected by the temperature detector 11 that detects the inlet water temperature of the heat exchanger 5 becomes a predetermined temperature, for example, 40 ° C. or less, the discharge of hot water in the hot water storage tank 6 is stopped. In this way, operation control is performed so that the temperature of the water introduced into the water treatment apparatus 10 is equal to or lower than a predetermined temperature.

尚、この制御は貯湯タンク6の水温が全量高温になった時だけ働くので、通常は湯水を放出することは殆どない。一方、湯水を放出することが多い場合には、貯湯タンク6の他に、放出した湯水をためるための補助タンクを設けても良い。この場合には、資源をさらに有効に活用できる。   This control works only when the water temperature in the hot water storage tank 6 reaches a high temperature. Therefore, normally, the hot water is hardly discharged. On the other hand, when hot water is often discharged, an auxiliary tank for accumulating the discharged hot water may be provided in addition to the hot water storage tank 6. In this case, resources can be used more effectively.

このような制御をすることにより、水処理装置10の性能を維持し、信頼性を向上させることができる。   By performing such control, the performance of the water treatment apparatus 10 can be maintained and the reliability can be improved.

さらに、制御装置13は、発電停止状態の場合に、水処理装置10の水供給配管15内の水の温度が所定温度以下となると、発電装置全体ではなく循環ポンプ8だけを運転し、貯湯タンク6内の暖かい水を水供給配管15により水処理装置10に供給して凍結を防ぎ、水処理装置10の水供給配管15内の水の温度が所定温度以上となると、循環ポンプ8の運転を停止するよう運転制御する。   Furthermore, when the temperature of the water in the water supply pipe 15 of the water treatment device 10 is equal to or lower than a predetermined temperature in the power generation stop state, the control device 13 operates only the circulation pump 8 instead of the entire power generation device, and the hot water storage tank The warm water in 6 is supplied to the water treatment device 10 through the water supply pipe 15 to prevent freezing. When the temperature of the water in the water supply pipe 15 of the water treatment device 10 exceeds a predetermined temperature, the circulation pump 8 is operated. Control the operation to stop.

即ち、発電装置は、設置して試運転後、実使用まで停止する場合や、夜間運転を休止する場合、長期間利用しないため停止する場合、メンテナンスのため停止する場合がある。冬季にこのような状況になると、寒冷地では水処理装置10内の滞留水が凍結し、高価な水処理装置10が破損するばかりでなく、発電装置自体が破損する恐れがある。これを防ぐため、装置内の最も温度が低くなる箇所、例えば熱交換器5の入口水温を検出する温度検出器11が4℃以下を検出した場合、水処理装置10の水供給配管15内の水の温度が凍結しうる温度以下となったと仮定して、発電装置が停止中であるにもかかわらず、循環ポンプ8を運転して、貯湯タンク6内の湯水を水処理装置10内に循環させ、熱交換器5の入口水温を検出する温度検出器11が例えば10℃以上を検出した時、循環ポンプ8を停止する制御を行なうものである。この制御により、電気ヒーター等を用いることなく凍結を未然に防ぐことができる。   That is, the power generation device may be stopped for maintenance when it is installed and stopped until actual use, when it is stopped at night, when it is not used for a long time, or when it is stopped. If such a situation occurs in winter, the accumulated water in the water treatment apparatus 10 freezes in a cold region, and not only the expensive water treatment apparatus 10 is damaged but also the power generation apparatus itself may be damaged. In order to prevent this, when the temperature detector 11 for detecting the inlet water temperature of the heat exchanger 5 detects a temperature of 4 ° C. or less in a place where the temperature is lowest in the apparatus, for example, in the water supply pipe 15 of the water treatment apparatus 10 Assuming that the temperature of the water is below the freezing temperature, the circulating pump 8 is operated to circulate hot water in the hot water storage tank 6 into the water treatment device 10 even though the power generation device is stopped. Then, when the temperature detector 11 that detects the inlet water temperature of the heat exchanger 5 detects, for example, 10 ° C. or more, control is performed to stop the circulation pump 8. By this control, freezing can be prevented without using an electric heater or the like.

燃料電池1と貯湯タンク6は、一つのケースに収容されることが、コンパクト化という点で望ましいが、燃料電池1と、貯湯タンク6とを別々のケースに収容しても良い。   Although it is desirable that the fuel cell 1 and the hot water storage tank 6 be accommodated in one case in terms of compactness, the fuel cell 1 and the hot water storage tank 6 may be accommodated in separate cases.

次に本発明の発電装置の動作および作用について説明する。発電装置の運転は、燃料供給装置2により燃料となる天然ガスなどの炭化水素系原燃料ガスを、加湿器4、改質器38に供給し、この改質器38にて原燃料ガスを水蒸気改質し、この改質された燃料ガスを燃料電池1の発電素子に供給する。また、空気供給装置3により酸化剤ガスが燃料電池1に供給される。   Next, the operation and action of the power generator of the present invention will be described. In the operation of the power generation apparatus, a hydrocarbon-based raw fuel gas such as natural gas, which becomes fuel, is supplied to the humidifier 4 and the reformer 38 by the fuel supply device 2, and the raw fuel gas is steamed by the reformer 38. The reformed fuel gas is supplied to the power generation element of the fuel cell 1. Further, an oxidant gas is supplied to the fuel cell 1 by the air supply device 3.

最初に燃料電池1内部で燃料ガスを燃焼させ、その燃焼熱で燃料電池1自体を発電可能な温度まで加熱する。所定の温度になると、水処理装置10で精製した純水を、燃料加湿器4に供給し、改質器38にて水蒸気改質で天然ガスなどから水素をとりだし、燃料電池1の発電素子に供給されて発電が開始され、発電により発生する熱により燃料電池1の温度を維持する。さらに、発電により発生する熱が余り、外部に排熱として放出されるようになる。この排熱(排ガス)を排気管9により熱交換器5へ導き、熱交換器5を介して循環配管7内を循環する水に熱を移動せしめる。   First, fuel gas is combusted inside the fuel cell 1, and the fuel cell 1 itself is heated to a temperature at which power can be generated by the combustion heat. When a predetermined temperature is reached, pure water purified by the water treatment device 10 is supplied to the fuel humidifier 4, and hydrogen is extracted from natural gas or the like by steam reforming in the reformer 38, and is used as a power generation element of the fuel cell 1. The power is supplied and power generation is started, and the temperature of the fuel cell 1 is maintained by the heat generated by the power generation. Furthermore, the heat generated by the power generation is excessive and is released to the outside as exhaust heat. The exhaust heat (exhaust gas) is guided to the heat exchanger 5 through the exhaust pipe 9, and heat is transferred to the water circulating in the circulation pipe 7 through the heat exchanger 5.

制御装置13は、タンク温度検出器14が検出するタンク水温が貯湯運転可能温度の上限値未満であるときは、燃料電池1の発電量に応じて排熱を回収するために循環ポンプ8の出力を制御する。即ち、燃料電池による発電量が多い場合には、循環ポンプ8による水供給量を増加させ、熱交換器5による熱交換を活発に行わせるとともに、原燃料ガスを増加させて、水処理装置10への水供給量を増加させ、純水精製量を増加させて原燃料ガスへの加湿量を増加させ、水素への改質を活発化させる。   When the tank water temperature detected by the tank temperature detector 14 is less than the upper limit value of the hot water storage operation temperature, the control device 13 outputs the output of the circulation pump 8 to recover the exhaust heat according to the amount of power generated by the fuel cell 1. To control. That is, when the amount of power generated by the fuel cell is large, the water supply amount by the circulation pump 8 is increased, the heat exchange by the heat exchanger 5 is actively performed, the raw fuel gas is increased, and the water treatment device 10 is increased. The amount of purified water is increased, the amount of purified water is increased, the amount of humidification of the raw fuel gas is increased, and reforming to hydrogen is activated.

この時水処理装置10には、貯湯タンク6の貯湯圧力と循環ポンプ8の吐出圧力の2つが加わり純水化用水供給配管15を通して貯湯タンク底部の水が供給される。水処理装置10は、高価なフィルターや活性炭、逆浸透膜を用いて構成されており、精製された純水が燃料加湿器4に移送され、改質器38にて水蒸気改質に供される。一方、逆浸透膜から水処理後の凝縮水が排水配管35から排水される。   At this time, the water treatment apparatus 10 is supplied with water at the bottom of the hot water storage tank 15 through the pure water supply pipe 15 through the addition of the hot water storage pressure of the hot water storage tank 6 and the discharge pressure of the circulation pump 8. The water treatment apparatus 10 is configured by using an expensive filter, activated carbon, and reverse osmosis membrane. Purified pure water is transferred to the fuel humidifier 4 and subjected to steam reforming by the reformer 38. . On the other hand, condensed water after water treatment is drained from the drain pipe 35 from the reverse osmosis membrane.

このような構成にすることにより、純水化用水供給配管15は発電装置内にあらかじめ付設されているため、装置を設置する時に新たに水供給配管15を施工する必要が無く、施工の簡略化、施工費用を削減できる。   By adopting such a configuration, the water supply pipe 15 for pure water is attached in advance in the power generator, so that it is not necessary to newly construct the water supply pipe 15 when installing the apparatus, and the construction is simplified. , Construction costs can be reduced.

図2は本発明の他の発電装置を示すもので、この発電装置では、この水処理装置10に水を供給するための水供給配管15及び水処理後の水を水処理装置10から排出するための排水配管36を有しており、水処理装置10の水供給配管15及び排水配管36は、循環配管7に連結されている。   FIG. 2 shows another power generation apparatus of the present invention. In this power generation apparatus, water supply pipe 15 for supplying water to the water treatment apparatus 10 and water after water treatment are discharged from the water treatment apparatus 10. The water supply pipe 15 and the drain pipe 36 of the water treatment apparatus 10 are connected to the circulation pipe 7.

即ち、循環配管7は、貯湯タンク6の底部と熱交換器5を連結する往路循環配管7aと、熱交換器5と貯湯タンク6上部とを連結する復路循環配管7bとからなり、往路循環配管7a途中に循環ポンプ8を有し、水処理装置10の水供給配管15は、循環ポンプ8と熱交換器5との間における往路循環配管7aに接続され、排水配管36は、熱交換器5と貯湯タンク6との間の復路循環配管7bに接続されている。   That is, the circulation pipe 7 includes an outward circulation pipe 7 a that connects the bottom of the hot water storage tank 6 and the heat exchanger 5, and a return circulation pipe 7 b that connects the heat exchanger 5 and the upper part of the hot water storage tank 6. 7 a has a circulation pump 8, the water supply pipe 15 of the water treatment device 10 is connected to the forward circulation pipe 7 a between the circulation pump 8 and the heat exchanger 5, and the drain pipe 36 is connected to the heat exchanger 5. And a return circulation pipe 7b between the hot water storage tank 6 and the hot water storage tank 6.

この場合、水供給配管15と排水配管36を循環配管7に接続するため、循環ポンプ8の吐出圧が不足する場合は、排水配管36に排水ポンプ39を設けることが望ましい。   In this case, since the water supply pipe 15 and the drain pipe 36 are connected to the circulation pipe 7, it is desirable to provide a drain pump 39 in the drain pipe 36 when the discharge pressure of the circulation pump 8 is insufficient.

このような発電装置では、図1の発電装置と同様の作用効果を有するが、さらに、水供給配管15のみならず、排水配管36も循環配管7に接続するため、従来のように排水配管を外部まで延設することがなく、循環配管7に接続すれば良いため、配管自体も短くなり、配管が簡素化され、小型化を達成できるとともに、施工費用を大幅に削減できる。   Such a power generator has the same effect as that of the power generator of FIG. 1, but further, since not only the water supply pipe 15 but also the drain pipe 36 is connected to the circulation pipe 7, the drain pipe is not provided in the conventional manner. Since it suffices to connect to the circulation pipe 7 without extending to the outside, the pipe itself is shortened, the pipe is simplified, miniaturization can be achieved, and construction costs can be greatly reduced.

さらに、水処理装置10は、水を純水化するため、大量の水から一部の純水を精製していたため、純水とできなかった水は外部に放出していたが、本発明では、純水化できなかった水処理後の凝縮水を外部に捨てることなく、貯湯タンクに供給され、再利用されるため、水資源を有効に活用でき、経済性も向上する。   Further, since the water treatment apparatus 10 purifies a part of pure water from a large amount of water in order to purify the water, the water that could not be made pure water was discharged to the outside. Since the condensed water after the water treatment that could not be purified is supplied to the hot water storage tank and reused without being thrown outside, water resources can be used effectively and the economic efficiency is improved.

この場合には、制御装置13により、水処理装置10の水供給配管15内の水の温度が凍結しうる温度以下となった場合に、発電装置が停止中であるにもかかわらず、循環ポンプ8を運転して、貯湯タンク6内の湯水を水処理装置10内に循環させるため、水処理装置10の凍結による破損を防止できるとともに、発電装置自体の破損を防止でき、さらに、凍結防止用の湯水も水処理装置10に供給された後、水処理装置10からの排水を排水配管36により貯湯タンク6に戻すことができ、水資源の有効活用を図ることができる。   In this case, when the temperature of the water in the water supply pipe 15 of the water treatment device 10 is below a temperature that can be frozen by the control device 13, the circulation pump is in spite of the fact that the power generation device is stopped. 8 is operated to circulate the hot water in the hot water storage tank 6 into the water treatment device 10, so that the water treatment device 10 can be prevented from being damaged by freezing, the power generation device itself can be prevented from being damaged, After the hot water is also supplied to the water treatment apparatus 10, the drainage from the water treatment apparatus 10 can be returned to the hot water storage tank 6 by the drainage pipe 36, and water resources can be effectively utilized.

尚、上記図1、図2の形態において、循環ポンプ8の吐出圧により水処理装置10に水を供給したが、発電量によって循環ポンプ8の吐出圧を制御し、熱交換器5への水供給量、水処理装置10への水供給量を制御しても良い。   1 and 2, the water is supplied to the water treatment device 10 by the discharge pressure of the circulation pump 8, but the discharge pressure of the circulation pump 8 is controlled by the amount of power generation, and the water to the heat exchanger 5 is controlled. The supply amount and the water supply amount to the water treatment apparatus 10 may be controlled.

即ち、固体電解質形の燃料電池1では、例えば中空平板型の燃料電池セルの上方で、余剰の燃料ガスが燃焼されるが、負荷が多くなり発電量を多くするためには燃料ガスを多く供給する必要があるため、燃焼ガスが多くなり、排熱も多くなる。従って、燃料電池1の発電量を負荷により変動させる場合には、例えば、最大出力させる場合には、制御装置13により、循環配管7の循環ポンプ8による吐出圧を大きく制御し、水処理装置10への水の供給量を増加させ、純水精製を活発化させ、燃料ガスへの改質量を活発化させ、発電量を増加させることができるとともに、熱交換器5への水供給量を増加させ、増加した高温の排ガスとの熱交換を活発化させることができる。   That is, in the solid electrolyte fuel cell 1, for example, surplus fuel gas is burned above the hollow flat plate fuel cell, but a large amount of fuel gas is supplied to increase the load and increase the amount of power generation. Therefore, combustion gas increases and exhaust heat also increases. Accordingly, when the power generation amount of the fuel cell 1 is varied depending on the load, for example, when the maximum output is to be obtained, the discharge pressure by the circulation pump 8 of the circulation pipe 7 is largely controlled by the control device 13, and the water treatment device 10. The amount of water supplied to the heat exchanger can be increased, the purification of pure water can be activated, the amount of reforming into fuel gas can be activated, the amount of power generated can be increased, and the amount of water supplied to the heat exchanger 5 can be increased. The heat exchange with the increased high temperature exhaust gas can be activated.

この場合、循環ポンプ8の吐出圧を一定とし、熱交換器5への水供給量を一定とし、水処理装置10への水供給配管7に水供給ポンプを新たに設けても良い。また、水供給ポンプを新たに設ける代わりに、水処理装置10に、逆浸透膜への水供給量を制御する弁を設けても良い。この場合には、水処理装置10への水供給量を水供給ポンプ、弁により制御することができる。   In this case, the discharge pressure of the circulation pump 8 may be constant, the water supply amount to the heat exchanger 5 may be constant, and a water supply pump may be newly provided in the water supply pipe 7 to the water treatment device 10. Moreover, you may provide the valve which controls the water supply amount to a reverse osmosis membrane in the water treatment apparatus 10 instead of providing a water supply pump newly. In this case, the water supply amount to the water treatment apparatus 10 can be controlled by the water supply pump and the valve.

また、図1、図2の発電装置では、燃料加湿器4を設け、この燃料加湿器4に純水を供給した例について説明したが、燃料加湿器を設けることなく改質器自体に直接純水を供給し、この改質器にて原燃料ガスと混合し、水蒸気改質してもよい。また、原燃料ガスを供給する配管に純水供給管を接続しても良い。   1 and 2, the fuel humidifier 4 is provided and pure water is supplied to the fuel humidifier 4. However, the pure water is directly supplied to the reformer itself without providing the fuel humidifier. Water may be supplied, mixed with the raw fuel gas in this reformer, and steam reformed. Further, a pure water supply pipe may be connected to a pipe for supplying raw fuel gas.

さらに、図1、図2の発電装置では、燃料電池1を収納するケース内に改質器38を収納した例について説明したが、燃料電池1の収納ケース外に別個に改質器を設けても良い。   Further, in the power generation device of FIGS. 1 and 2, the example in which the reformer 38 is housed in the case for housing the fuel cell 1 has been described, but a reformer is separately provided outside the housing case for the fuel cell 1. Also good.

本発明の発電装置を示す構成図である。It is a block diagram which shows the electric power generating apparatus of this invention. 本発明の他の発電装置を示す構成図である。It is a block diagram which shows the other electric power generating apparatus of this invention. 従来の発電装置を示す構成図である。It is a block diagram which shows the conventional electric power generating apparatus.

符号の説明Explanation of symbols

1・・・燃料電池
5・・・熱交換器
6・・・貯湯タンク
7・・・循環配管
7a・・・往路循環配管
7b・・・復路循環配管
8・・・循環ポンプ
10・・・水処理装置
13・・・制御装置
15・・・水供給配管
35、36・・・排水配管
37、38・・・改質器
DESCRIPTION OF SYMBOLS 1 ... Fuel cell 5 ... Heat exchanger 6 ... Hot water storage tank 7 ... Circulation piping 7a ... Outward circulation piping 7b ... Return circulation piping 8 ... Circulation pump 10 ... Water Treatment device 13 ... Control device 15 ... Water supply piping 35, 36 ... Drainage piping 37, 38 ... Reformer

Claims (5)

炭化水素系原燃料ガスを水蒸気改質する改質器と、該改質器から供給された燃料ガスと酸化剤ガスを用いて発電する燃料電池と、前記改質器内の水蒸気改質に用いる純水を精製する水処理装置と、前記燃料電池からの排熱を回収するための熱交換器と、湯水を貯える貯湯タンクとを有するとともに、前記水処理装置には、該水処理装置に水を供給するための水供給配管、精製された純水を供給するための純水供給配管、及び純水に精製されなかった水処理後の排水を前記水処理装置から排出するための排水配管が接続されており、前記熱交換器と前記貯湯タンクとを循環配管により連結し、前記水処理装置に接続された水供給配管及び/又は排水配管を、前記循環配管に連結してなることを特徴とする発電装置。 A reformer that performs steam reforming of a hydrocarbon-based raw fuel gas, a fuel cell that generates power using the fuel gas and oxidant gas supplied from the reformer, and steam reforming in the reformer A water treatment device for purifying pure water; a heat exchanger for recovering exhaust heat from the fuel cell; and a hot water storage tank for storing hot water. A water supply pipe for supplying water, a pure water supply pipe for supplying purified pure water, and a drain pipe for discharging waste water after water treatment that has not been purified to pure water from the water treatment device. The heat exchanger and the hot water storage tank are connected by a circulation pipe, and a water supply pipe and / or a drain pipe connected to the water treatment device are connected to the circulation pipe. A power generator. 前記循環配管は、前記貯湯タンクの底部と前記熱交換器を連結する往路循環配管と、前記熱交換器と前記貯湯タンク上部とを連結する復路循環配管とからなり、前記往路循環配管途中に循環ポンプを有するとともに、前記水処理装置の水供給配管を、前記循環ポンプと前記熱交換器との間における往路循環配管に接続してなることを特徴とする請求項1記載の発電装置。 The circulation pipe includes an outward circulation pipe that connects the bottom of the hot water storage tank and the heat exchanger, and a return circulation pipe that connects the heat exchanger and the upper part of the hot water storage tank, and circulates in the middle of the outward circulation pipe. The power generator according to claim 1, further comprising a pump, wherein a water supply pipe of the water treatment apparatus is connected to an outward circulation pipe between the circulation pump and the heat exchanger. 前記循環配管は、前記貯湯タンクの底部と前記熱交換器を連結する往路循環配管と、前記熱交換器と前記貯湯タンク上部とを連結する復路循環配管とからなり、前記水処理装置の排水配管を、前記復路循環配管に接続してなることを特徴とする請求項1又は2記載の発電装置。 The circulation pipe is composed of an outward circulation pipe that connects the bottom of the hot water storage tank and the heat exchanger, and a return circulation pipe that connects the heat exchanger and the upper part of the hot water storage tank, and is a drain pipe of the water treatment device. The power generator according to claim 1, wherein the power generator is connected to the return circulation pipe. 前記水処理装置に供給される水の温度が所定温度以上となると、前記貯湯タンク内の湯を放出し、前記水供給配管により供給される水の温度が所定温度以下となるよう運転制御する制御装置を有することを特徴とする請求項1乃至3のうちいずれかに記載の発電装置。 When the temperature of the water supplied to the water treatment device becomes equal to or higher than a predetermined temperature, the hot water in the hot water storage tank is discharged, and the operation is controlled so that the temperature of the water supplied by the water supply pipe becomes equal to or lower than the predetermined temperature. The power generator according to claim 1, further comprising a device. 前記水処理装置の水供給配管内の水の温度が所定温度以下となると、前記循環ポンプを運転し、前記貯湯タンク内の水を前記水供給配管により前記水処理装置に供給して凍結を防ぎ、前記水処理装置の水供給配管内の水の温度が所定温度以上となると、前記循環ポンプの運転を停止するよう運転制御する制御装置を有することを特徴とする請求項2乃至4のうちいずれかに記載の発電装置。 When the temperature of the water in the water supply pipe of the water treatment apparatus becomes equal to or lower than a predetermined temperature, the circulating pump is operated and the water in the hot water storage tank is supplied to the water treatment apparatus through the water supply pipe to prevent freezing. 5. The control device according to claim 2, further comprising a control device that controls the operation of the circulating pump so as to stop when the temperature of the water in the water supply pipe of the water treatment device exceeds a predetermined temperature. A power generation device according to claim 1.
JP2005233134A 2005-08-11 2005-08-11 Power generator Expired - Fee Related JP4986424B2 (en)

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