JP2007030268A - Sound absorbing/cutting-off material - Google Patents
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- JP2007030268A JP2007030268A JP2005214814A JP2005214814A JP2007030268A JP 2007030268 A JP2007030268 A JP 2007030268A JP 2005214814 A JP2005214814 A JP 2005214814A JP 2005214814 A JP2005214814 A JP 2005214814A JP 2007030268 A JP2007030268 A JP 2007030268A
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- 239000011347 resin Substances 0.000 claims abstract description 114
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- 230000035699 permeability Effects 0.000 claims abstract description 44
- 239000011358 absorbing material Substances 0.000 claims description 53
- 239000011810 insulating material Substances 0.000 claims description 46
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- Soundproofing, Sound Blocking, And Sound Damping (AREA)
Abstract
Description
本発明は吸遮音材に関し、さらに詳しくは建設用機械や自動車のエンジンルーム等に使用される、遮音性、吸音性に優れた吸遮音材に関する。 The present invention relates to a sound absorbing and insulating material, and more particularly to a sound absorbing and insulating material having excellent sound insulating properties and sound absorbing properties, which is used in construction machines, automobile engine rooms, and the like.
建設用機械や自動車のエンジンルーム等に使用される吸音材には、低〜中周波数域の吸音性の向上が強く要請されている。さらにこのような吸音材は吸音性を向上させるため、通気性を持たせることになるが雨や水洗等により、吸音材に水が侵入すると吸音性が悪化すると共に、吸音材の劣化が早まり、耐久性も低下するという問題がある。しかしながら、表面を非通気性の材料で被覆してしまうと、進入音波の反射による吸音材の低下が懸念される。 There is a strong demand for sound-absorbing materials used in construction machinery, automobile engine rooms, and the like to improve sound absorption in the low to medium frequency range. Furthermore, in order to improve the sound absorption, such a sound absorbing material will have air permeability, but when the water enters the sound absorbing material due to rain or water washing, the sound absorbing property is deteriorated, and the sound absorbing material is rapidly deteriorated, There is a problem that durability is lowered. However, if the surface is covered with a non-breathable material, there is a concern that the sound absorbing material may be deteriorated due to reflection of an incoming sound wave.
低〜中周波数域の吸音性を向上する方法として、通常の軟質ウレタンフォームに通気性を付与したプラスチックフィルムを積層することにより吸音性を改良する技術が提案されている(例えば、特許文献1参照。)。しかしながら、公知の軟質ウレタンフォームを用いた場合には、十分な通気性が得られず、音波進入による振動減衰の観点からはなお改良の余地があった。
これをうけて、本願出願人は、特定の厚さの難燃性軟質ウレタンフォームの片面にポリエステルフィルム又はポリエチレンフィルムを積層溶融接着させ、全体の通気性を制御した難燃性吸音材を提案した(例えば、特許文献2参照。)。この吸音材は、防水性、難燃性及び吸音性に優れたものであるが、製造時において原料シート間の溶融接着を必要とするため、低温施工性の観点からはさらなる改良が望まれているのが現状である。
In response, the applicant of the present application has proposed a flame-retardant sound-absorbing material in which a polyester film or a polyethylene film is laminated and melt-bonded to one side of a flame-retardant flexible urethane foam having a specific thickness to control the overall breathability. (For example, refer to Patent Document 2). This sound-absorbing material is excellent in waterproofness, flame retardancy, and sound-absorbing property, but requires further fusion bonding between raw material sheets at the time of manufacture, and therefore further improvement is desired from the viewpoint of low-temperature workability. The current situation is.
上記課題を考慮してなされた本発明の目的は、低温施工性及び低〜中周波数域での高吸音性、遮音性に優れた吸遮音材を提供することにある。 An object of the present invention made in consideration of the above problems is to provide a sound absorbing and insulating material excellent in low-temperature workability, high sound absorbing property and sound insulating property in a low to medium frequency range.
本発明者らは、ウレタンフォームと樹脂層との積層型の吸遮音材の通気性に着目し、鋭意検討した結果、両者の通気性を所定の条件で制御することにより、上記目的が達成しうることを見出し、本発明を完成するに至った。
即ち、本発明の構成は以下に示す通りである。
<1> 連続通気性を有する発泡性樹脂基材表面に、該発泡樹脂基材の1/2〜1/50の通気性を有する樹脂層を有する吸遮音材。
<2> 連続通気性を有する発泡性樹脂基材表面に、開孔部を形成してなる樹脂フィルムからなる樹脂層を有する吸遮音材。
<3> 前記開孔部を形成してなる樹脂フィルムの開孔径が10〜500μmであることを特徴とする<2>の吸遮音材。
The inventors of the present invention have focused on the air permeability of a laminated sound absorbing and insulating material composed of a urethane foam and a resin layer, and as a result of intensive studies, the above object has been achieved by controlling the air permeability of both under predetermined conditions. As a result, the present invention has been completed.
That is, the configuration of the present invention is as follows.
<1> A sound absorbing and insulating material having a resin layer having a breathability of 1/2 to 1/50 of the foamed resin substrate on the surface of the foamable resin substrate having continuous breathability.
<2> A sound-absorbing and insulating material having a resin layer made of a resin film in which an aperture is formed on the surface of a foamable resin base material having continuous air permeability.
<3> The sound absorbing and insulating material according to <2>, wherein an opening diameter of the resin film formed with the opening is 10 to 500 μm.
<4> 前記樹脂層が、局所的に薄肉化された樹脂フィルムからなることを特徴とする<1>又は<2>に記載の吸遮音材。
<5> 前記樹脂層が、ポリウレタンフィルムからなることを特徴とする<1>又は<2>に記載の吸遮音材。
<6> 前記発泡性樹脂基材の通気性が3〜100ml/cm2 ・秒の範囲であり、前記樹脂層の通気性が0.06〜50ml/cm2 ・秒の範囲であることを特徴とする<1>〜<5>のいずれか1項に記載の吸遮音材。
<7> 前記樹脂層の表面に、さらに、樹脂不織布層を有することを特徴とする<1>〜<6>のいずれか1項に記載の吸遮音材。
<4> The sound absorbing and insulating material according to <1> or <2>, wherein the resin layer is made of a locally thinned resin film.
<5> The sound absorbing and insulating material according to <1> or <2>, wherein the resin layer is made of a polyurethane film.
<6> The air permeability of the foamable resin substrate is in the range of 3 to 100 ml / cm 2 · sec, and the air permeability of the resin layer is in the range of 0.06 to 50 ml / cm 2 · sec. The sound absorbing and insulating material according to any one of <1> to <5>.
<7> The sound absorbing and insulating material according to any one of <1> to <6>, further including a resin nonwoven fabric layer on the surface of the resin layer.
本発明によれば、低温施工性及び低〜中周波数域での高吸音性、遮音性に優れた吸遮音材を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the sound-absorbing / insulating material excellent in low temperature construction property, the high sound-absorbing property in the low-medium frequency range, and the sound-insulating property can be provided.
以下に本発明を詳細に説明する。
本発明の吸遮音材は、連続通気性を有する発泡性樹脂基材の表面に、該発泡樹脂基材の1/2〜1/50の通気性を有する樹脂層、或いは、開孔部を形成してなる樹脂フィルムからなる樹脂層を積層してなるとの積層構造を有し、所望により、樹脂層表面にさらに、樹脂不織布層を有していてもよい。
以下、各層について説明する。
The present invention is described in detail below.
The sound-absorbing and insulating material of the present invention forms a resin layer or an opening having a breathability of 1/2 to 1/50 of the foamed resin base material on the surface of the foamable resin base material having continuous breathability. It has a laminated structure that is formed by laminating a resin layer made of a resin film, and if desired, a resin nonwoven fabric layer may be further provided on the surface of the resin layer.
Hereinafter, each layer will be described.
(連続通気性を有する発泡性樹脂基材)
本発明に用いられる発泡性樹脂基材は、気泡を内在する樹脂基材であって、連続通気性を有することを特徴とする。このような発泡性樹脂基材としては、例えば連続気泡を有する発泡性樹脂からなるシートなどが挙げられ、エネルギーの内部減衰特性に優れているため、音波の効果的な減衰、遮断に有用である。
(Foamed resin base material with continuous air permeability)
The foamable resin substrate used in the present invention is a resin substrate containing bubbles, and has continuous air permeability. Examples of such a foamable resin base material include a sheet made of a foamable resin having open cells, and is excellent in the internal attenuation characteristics of energy, so that it is useful for effective attenuation and blocking of sound waves. .
発泡性樹脂基材としては、ポリエーテル系ウレタンフォーム、ポリエステル系ウレタンフォームなどの樹脂からなるシート状の基材が好ましく、なかでも、減衰特性の観点からは、ポリエーテル系ウレタンフォームが好ましい。
具体的には、UL−94、HF−1、MVSS302、空検、A−A基準等に適合する軟質ウレタンフォームであれは特に制限されないが例えばエバーライトVHZ、VP、VD(商品名、プリヂストン製)等を挙げることができる。
このような発泡性樹脂基材の厚みは、目的とする吸遮音効果、配置される場所などにより適宜選択できるが、一般的には、10〜100mmの範囲であり、好ましくは10〜50mmである。
As the foamable resin base material, a sheet-like base material made of a resin such as a polyether-based urethane foam and a polyester-based urethane foam is preferable, and among them, a polyether-based urethane foam is preferable from the viewpoint of damping characteristics.
Specifically, it is not particularly limited as long as it is a flexible urethane foam that meets UL-94, HF-1, MVSS302, blank inspection, AA standards, etc., but, for example, Everlite VHZ, VP, VD (trade name, manufactured by Pridestone) And the like.
The thickness of such a foamable resin base material can be appropriately selected depending on the intended sound absorbing and insulating effect, the place where the foamed resin base material is disposed, etc., but is generally in the range of 10 to 100 mm, preferably 10 to 50 mm. .
本発明において、吸遮音材に使用される発泡性樹脂基材の通気性は3〜100ml/cm2 ・秒であることが好ましく、効果の点からさらに好ましくは5〜50ml/cm2 ・秒である。この範囲の通気性において優れた吸音性能が得られる。なお、本発明における通気性は、JIS L 1096A法に従って測定した値を用いている。 In the present invention, breathability of the foamable resin substrate to be used in吸遮sound material is preferably from 3~100ml / cm 2 · sec, more preferably from the viewpoint of the effect 5~50ml / cm 2 · sec is there. Excellent sound absorbing performance is obtained in this range of air permeability. In addition, the value measured according to JISL1096A method is used for the air permeability in this invention.
(前記発泡樹脂基材の1/2〜1/50の通気性を有する樹脂層)
本発明の吸遮音材の第1の態様においては、前記発泡樹脂基材表面に、特定の通気性を有する樹脂層を有する。
この樹脂層は、発泡樹脂基材表面に剥離しない状態で密着して形成されるが、一般的には、発泡樹脂基材表面に樹脂層を溶融接着させて積層されることが好ましい。
樹脂層としては、ポリエステル、ポリエチレン、ポリアミド、ポリエーテルなどの樹脂製フィルムが用いられ、具体的な素材としては、EVA、変性EVA、ポリエチレン、ポリプロピレン、ポリエステル、ポリアミド、ポリウレタン等のホットメルトフィルムが挙げられる。
(Resin layer having breathability of 1/2 to 1/50 of the foamed resin base material)
In the first aspect of the sound absorbing and insulating material of the present invention, a resin layer having specific air permeability is provided on the surface of the foamed resin base material.
This resin layer is formed in close contact with the surface of the foamed resin base material without being peeled off. In general, it is preferable that the resin layer be laminated on the surface of the foamed resin base material by melting and bonding.
As the resin layer, resin films such as polyester, polyethylene, polyamide, and polyether are used, and specific materials include hot melt films such as EVA, modified EVA, polyethylene, polypropylene, polyester, polyamide, and polyurethane. It is done.
なかでも、低温施工性の観点からは、高融点で低Tgのポリウレタンフィルムが好ましい。
樹脂層を構成するフィルムの融点は低いほど、低温で溶融でき作業性はよいが、一方、製品性能からみれば、使用温度が高くなると、フィルムが溶けたり、はがれたりして不具合が発生し易く、その観点からは融点は高いほうがよい。また、低温施工性の観点からはガラス転移温度(Tg)が低いもの、具体的には0℃以下の如きものが低温で接着可能であるため好ましい。
このようにホットメルト接着剤を用いることなく、発泡樹脂基材と熱融着が可能でな樹脂層を用いることで、工程が軽減でき、経済的にも好ましく、また、このような材料を使用することによる防水性や吸音性の低下などはみられない。
Among these, a polyurethane film having a high melting point and a low Tg is preferable from the viewpoint of low-temperature workability.
The lower the melting point of the film constituting the resin layer, the better the workability is because it can be melted at a low temperature. On the other hand, from the viewpoint of product performance, when the operating temperature is high, the film is likely to melt or peel off, causing problems. From that point of view, it is better that the melting point is higher. Further, from the viewpoint of low temperature workability, those having a low glass transition temperature (Tg), specifically those having a temperature of 0 ° C. or lower, are preferable because they can be bonded at a low temperature.
By using a resin layer that can be heat-sealed with a foamed resin base material without using a hot melt adhesive in this way, the process can be reduced and economically preferable, and such a material is used. There is no decrease in waterproofness or sound absorption due to the operation.
本発明に用いられる樹脂層の厚さは20〜50μmであり、効果の点から好ましくは30〜40μmである。この厚みが薄すぎた場合、発泡樹脂基材との十分な密着が得られず、表面層としての機能が十分発揮できない懸念があり、厚すぎると、進入音波の反射により吸音特性が低下する傾向がある。 The thickness of the resin layer used in the present invention is 20 to 50 μm, and preferably 30 to 40 μm from the viewpoint of effects. If this thickness is too thin, there is a concern that sufficient adhesion with the foamed resin base material cannot be obtained and the function as a surface layer cannot be sufficiently exhibited, and if it is too thick, the sound absorption characteristics tend to be reduced due to reflection of incoming sound waves. There is.
樹脂層の通気性は、前記発泡樹脂基材の1/2〜1/5であることを要する。樹脂層の好ましい通気性は、好ましくは絶対量で5〜50ml/cm2 ・秒の範囲であり、且つ、積層される発泡樹脂基材の通気性の1/2〜1/50の範囲、言い換えれば、発泡性樹脂基材の通気量の2〜50%の通気量を有するものが用いられ、好ましくは1/3〜1/20の範囲である。
この樹脂層は発泡性樹脂基材表面に密着した被膜となり、その作用は明確ではないが、連通気性を有する発泡性樹脂からなるシート表面において膜振動によるエネルギー減衰特性を高めることで、進入音波に対する吸遮音効果を向上させるものと考えられる。
The air permeability of the resin layer needs to be 1/2 to 1/5 of the foamed resin base material. The preferable air permeability of the resin layer is preferably in the range of 5 to 50 ml / cm 2 · sec in absolute amount, and in the range of 1/2 to 1/50 of the air permeability of the foamed resin base material to be laminated, in other words. For example, those having an air flow rate of 2 to 50% of the air flow rate of the foamable resin base material are used, preferably in the range of 1/3 to 1/20.
This resin layer is a film that adheres to the surface of the foamable resin base material, and its action is not clear, but by increasing the energy attenuation characteristics due to membrane vibration on the sheet surface made of foamable resin with continuous air permeability, It is thought to improve the sound absorption and insulation effect on the water.
樹脂層に通気性を与える方法としては、樹脂層を構成するフィルムに開孔部を設ける方法の他、樹脂製フィルムをエンボス加工することで局所的に肉薄の領域を形成する方法が挙げられる。このような肉薄の領域を有する樹脂フィルムを発泡性樹脂基材に積層、熱圧着する際に、肉薄部が溶融し適切な開孔部が形成される。薄肉化された領域の厚みの最も薄いところは、直径10〜500μmの範囲であることが好ましく、その厚みは、0〜10μm程度が好ましい。局所的肉薄部の形成の方法としては、エンボスロールによる圧縮方法が挙げられる。 Examples of a method for imparting air permeability to the resin layer include a method of forming a thin region locally by embossing a resin film in addition to a method of providing an opening in a film constituting the resin layer. When a resin film having such a thin region is laminated on a foamable resin substrate and thermocompression bonded, the thin portion is melted to form an appropriate aperture. The thinnest area of the thinned region is preferably in the range of 10 to 500 μm in diameter, and the thickness is preferably about 0 to 10 μm. Examples of the method for forming the local thin portion include a compression method using an emboss roll.
また、本発明の第2の態様は、前記発泡樹脂基材表面に、樹脂層として通気性に優れた樹脂製のフィルムに微細な開孔部を設けるものを用いることを特徴としている。このように樹脂製フィルムに開孔部を設ける方法によれば、樹脂層の通気性の制御が容易となるという利点を有する。開孔部の直径(真円ではない場合にはその長径)が10〜500μmの範囲であることが好ましく、100〜200μmの範囲であることがより好ましい。開孔密度は、5〜50個/cm2 であることが好ましく、目的に応じて開孔径と開孔密度を制御することで所望の通気性が達成できる。開孔径が小さすぎると進入音波の反射が生じることがあり、大きすぎた場合、発泡性樹脂基材との通気性の差異を上記範囲に収めることが困難となる。
樹脂フィルムに開孔部を形成する方法には特に制限はなく、例えば、レーザー溶融による開孔方法、ニードルパンチ法など公知の樹脂フィルム穿孔方法を適用することができる。
この方法によれば、開孔径及び開孔密度を容易に所望の条件とすることができ、先に述べたように通気性の制御を容易に行うことができる。
Further, the second aspect of the present invention is characterized in that a resin film having a fine opening is provided on the surface of the foamed resin base material as a resin layer having excellent air permeability. Thus, according to the method of providing the opening in the resin film, there is an advantage that the air permeability of the resin layer can be easily controlled. It is preferable that the diameter of the aperture (the long diameter when not a perfect circle) is in the range of 10 to 500 μm, and more preferably in the range of 100 to 200 μm. The hole density is preferably 5 to 50 holes / cm 2 , and desired air permeability can be achieved by controlling the hole diameter and the hole density according to the purpose. If the aperture diameter is too small, the incident sound wave may be reflected. If it is too large, it becomes difficult to keep the difference in air permeability from the foamable resin base material within the above range.
There is no particular limitation on the method for forming the aperture in the resin film, and for example, a known resin film perforation method such as a laser melting aperture method or a needle punch method can be applied.
According to this method, the hole diameter and the hole density can be easily set to desired conditions, and the air permeability can be easily controlled as described above.
なお、本発明における発泡性樹脂基材表面に樹脂層を熱圧着により形成する場合、温度条件によっては、樹脂層の溶融により開孔部が形成されることがある。しかしながら、このような製造上の不均一などに起因する開孔部の形成によっては、本発明に規定される所望の通気性を達成することは極めて困難であることは言うまでもない。 When the resin layer is formed on the surface of the foamable resin base material in the present invention by thermocompression bonding, an opening portion may be formed by melting of the resin layer depending on temperature conditions. However, it goes without saying that it is extremely difficult to achieve the desired air permeability defined in the present invention by forming the opening due to such non-uniform manufacturing.
(樹脂不織布層)
本発明の吸遮音材において、使用目的によって、溶融接着させた樹脂層に高度の耐引裂性が要求される場合には、樹脂層表面にさらに通気性が5ml/cm2 ・秒以上で、可撓性のある樹脂不織布層を設けることができる。この不織布層の存在により、吸遮音材の特性を損うことなく耐引裂性を大幅に向上することができる。
(Resin nonwoven layer)
In the sound-absorbing and insulating material of the present invention, when a high tear resistance is required for the melt-bonded resin layer depending on the purpose of use, the air permeability on the resin layer surface should be 5 ml / cm 2 · sec or more. A flexible resin nonwoven fabric layer can be provided. Due to the presence of the nonwoven fabric layer, tear resistance can be greatly improved without impairing the properties of the sound absorbing and insulating material.
本発明に用いることができる樹脂不織布は通気性が5ml/cm2 ・秒以上であって、可撓性を有するものであればよく、特に制限されない。この場合、例えば通気性が80ml/cm2 ・秒以上のものも使うことが好ましい。
樹脂不織布としては、ポリエステル、ポリアミド、ポリプロピレンなどの樹脂からなる繊維を用いた不織布が好ましく、具体的には、例えば、ナイロン不織布(目付量;20g/m2 、通気性;400ml/cm2 ・秒以上)、ナイロン不織布(目付量;30g/m2 、通気性;400ml/cm2 ・秒以上)等を挙げることができる。
The resin nonwoven fabric that can be used in the present invention is not particularly limited as long as it has air permeability of 5 ml / cm 2 · sec or more and has flexibility. In this case, for example, it is preferable to use one having air permeability of 80 ml / cm 2 · sec or more.
The resin nonwoven fabric is preferably a nonwoven fabric using fibers made of a resin such as polyester, polyamide, and polypropylene. Specifically, for example, a nylon nonwoven fabric (weight per unit area: 20 g / m 2 , air permeability: 400 ml / cm 2 · second) And the like), nylon nonwoven fabric (weight per unit area: 30 g / m 2 , air permeability: 400 ml / cm 2 · sec or more), and the like.
上記、樹脂不織布の中で、目の細かい(構成繊維の太さの大きい、目付量の大きい、通気性の小さい)ものはフィルムの耐引裂性(補強性)が大きくなるが、現状ではそれ程の耐引裂性は必要とされず、高価であり、さらに吸遮音材の通気性が小さくなるという観点から不利であるのに対し、目の粗い(構成セイン委の太さの小さい、目付量の小さい、通気性の大きい)ものは、耐引裂性は本発明における要求特性を満たすことが可能であり、安価であり、さらに吸遮音材の通気性が大きくなるといった観点から有利である。この観点から前記例示の中でも、ナイロン不織布(目付量:20g/cm2 程度のもの)が好ましく用いられる。 Among the above-mentioned resin nonwoven fabrics, fine ones (thickness of constituent fibers, large basis weight, small air permeability) increase the tear resistance (reinforcing property) of the film. Tear resistance is not required, it is expensive, and it is disadvantageous from the viewpoint that the air permeability of the sound absorbing and insulating material is reduced. On the other hand, it is rough (the thickness of the component sane committee is small, the basis weight is small) The material having a high air permeability is advantageous from the viewpoint that the tear resistance can satisfy the required characteristics in the present invention, is inexpensive, and further the air permeability of the sound absorbing and insulating material is increased. From this viewpoint, among the above examples, nylon nonwoven fabric (weight per unit area: about 20 g / cm 2 ) is preferably used.
(吸遮音材の製造)
本発明の吸遮音材の製造方法は、該吸遮音材が前記したような特定の発泡性樹脂基材及び樹脂層が積層され、前記特定の通気性条件を満足する限り、如何なる方法をとってもよいが、例えば、連通気性のウレタンフォームシート(発泡性樹脂基材)と特定の開孔部を有するポリエステルフィルム(樹脂層)とをホットメルト接着剤なしで熱圧着する際に、積層体の表面に離型紙を積層し、その上側から熱盤にて、例えば125℃以上で加圧加熱し、該発泡性樹脂基材と該樹脂層とを熱融着し、熱盤を加熱したまま、熱盤から、離型紙を積層した吸遮音材を離脱させ、室温で冷却固化したのち、離型紙を剥ぎとる方法をとることができ、この方法によれば、吸遮音材をエネルギーロスが少なく、且つ、短時間で容易に製造することができる。
(Manufacture of sound absorbing and insulating materials)
The sound absorbing and insulating material manufacturing method of the present invention may take any method as long as the sound absorbing and insulating material is laminated with the specific foamable resin base material and the resin layer as described above and satisfies the specific air permeability condition. However, the surface of the laminate when, for example, thermocompression bonding of a breathable urethane foam sheet (foamable resin base material) and a polyester film (resin layer) having a specific opening without a hot melt adhesive is used. A release paper is laminated on the top, and heated with a heating plate from above, for example, at 125 ° C. or higher, and the foamable resin base material and the resin layer are heat-sealed. After removing the sound absorbing and insulating material laminated with release paper from the board and cooling and solidifying at room temperature, it is possible to take the method of peeling the release paper. According to this method, the sound absorbing and insulating material has little energy loss, and Can be easily manufactured in a short time.
また、必要に応じて、上記樹脂層の上に、フィルム補強材として樹脂不織布を積層し、その上に離型紙を積層して、上記と同様にして、フィルム補強材を有する難燃性吸遮音材を製造することができる。また、ここで目の細かい樹脂不織布を用いる場合、フィルムが熱盤にべたつかないことが多いので、必ずしも離型紙を用いなくてもよい。 Further, if necessary, a non-woven resin as a film reinforcing material is laminated on the resin layer, a release paper is laminated thereon, and a flame retardant sound absorbing and insulating sound having the film reinforcing material is obtained in the same manner as described above. The material can be manufactured. Further, when a fine resin nonwoven fabric is used here, the film does not often stick to the hot platen, and thus it is not always necessary to use a release paper.
以下に実施例を挙げて、本発明をより具体的に説明するが、本発明の主旨を越えない限り、本実施例に限定されるものではない。 EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to the examples as long as the gist of the present invention is not exceeded.
各種の測定は下記の方法によった。
1.通気性の測定方法
吸遮音材を構成する発泡性樹脂基材及び樹脂層のそれぞれの厚さのものを試料とし、通気性をJIS L 1096A法に従って測定した。
Various measurements were performed by the following methods.
1. Measuring method of air permeability The thickness of each of the foamable resin base material and the resin layer constituting the sound absorbing and insulating material was used as a sample, and the air permeability was measured according to JIS L 1096A method.
2.吸音率の測定方法
周波数200〜5000Hzにて、残響室法吸音率で測定した。残響室法吸音率αは次式によって計算される。
α=(4loge 106 /c)×V/S×(1/T1 −1/T0 )
(式中、c:音速、V:残響室容積=9m3 、S:試料面積=1.2m2 、T0 :空室残響時間、T1 :残響時間)
吸音性の測定方法には音響管を使う垂直入射法吸音率測定による方法と残響室で行う残響室法吸音率測定による方法がある。被膜付き吸遮音材は、共振現象によって吸音性能を発現するので、垂直入射法吸音率測定では正確性を欠くので、残響室法吸音率測定法を用いた。
2. Measuring method of sound absorption rate It measured by the reverberation room method sound absorption rate in frequency 200-5000Hz. The reverberation room method sound absorption coefficient α is calculated by the following equation.
α = (4
(Where c: sound velocity, V: reverberation chamber volume = 9 m 3 , S: sample area = 1.2 m 2 , T 0 : vacant reverberation time, T 1 : reverberation time)
There are two methods for measuring sound absorption: a method based on normal incidence method sound absorption measurement using an acoustic tube and a method based on reverberation chamber method sound absorption rate measurement performed in a reverberation room. Since the sound-absorbing and insulating material with a coating exhibits sound absorbing performance due to a resonance phenomenon, the sound absorption coefficient measurement using the reverberation chamber method is used because the sound absorption coefficient measurement is not accurate.
3.遮音性
無音響室に、図1に示す如き「垂直入射遮音率測定装置」10を準備し、実施例及び比較例の吸遮音材を500×600mmに裁断したサンプル12をセットし、サンプル12表面より高さ200mmに位置するマイクロホン14にて遮音ボックス16中に配置された4個のスピーカー18から発生した音の音圧を測定する。その後、サンプル12を取り除いた状態で同様の測定を行い、両者の音圧の差から遮音性を評価する。
なお、遮音カバーは2重構造とし、音響インテンシティ測定箇所は6点で行い、遮音カバーとサンプルとの間は粘土を用いてシールした。
3. 1. Sound insulation property In a soundless room, a “normal incidence sound insulation rate measuring device” 10 as shown in FIG. 1 is prepared, and a
In addition, the sound insulation cover was made into the double structure, the sound intensity measurement location was performed at six points, and the sound insulation cover and the sample were sealed with clay.
4.低温施工性
実施例及び比較例の吸遮音材をサンプルとし、硬質表面に配置して、−10℃の雰囲気下に24時間放置する。その後、該雰囲気下で高さ500mmの位置から50mm角で重さが500gのおもりをサンプル表面に落下させる。サンプルを目視で観察してクラックの有無を調べる。クラックが1個以下で○、クラックが2個以上発生した場合を×として評価する。
4). Low-temperature workability The sound-absorbing and insulating materials of Examples and Comparative Examples are used as samples, placed on a hard surface, and allowed to stand in an atmosphere of −10 ° C. for 24 hours. Thereafter, a weight of 500 mm and a weight of 500 g is dropped on the surface of the sample from a position of 500 mm in the atmosphere. The sample is visually observed for cracks. Evaluation is given as ◯ when 1 or less cracks occur and x when 2 or more cracks occur.
〔実施例1〕
125℃に加熱された上、下の熱盤を備えたプレス成型装置の下の熱盤上に、密度23kg/m3 、硬さ10kgf、厚さ25mm、通気性130ml/cm2 ・秒の連通気性ウレタンフォーム(VHZ、商品名、ブリヂストン社製)を置き、その上に厚さ30μmのポリウレタンフィルム(U1490、商品名、倉敷紡績社製)に直径300μmの開孔部を100個/cm2形成してなる通気性30ml/cm2 ・秒の樹脂層を積層し、さらに離型紙(SBK70J、商品名、リンテック社製)を配置し、これを上の熱盤により125℃、90秒、圧縮歪20%で加圧、加熱し、この離型紙付き吸遮音材を加熱熱盤から離脱させ、室温にて放冷後、離型紙を剥ぎとり、実施例1の吸遮音材を得た。この吸遮音材の諸特性(低温施工性、遮音性、吸音率)を測定し、その結果を表1に示した。
[Example 1]
On a heating plate below a press molding apparatus heated to 125 ° C. and provided with a lower heating plate, a density of 23 kg / m 3 , a hardness of 10 kgf, a thickness of 25 mm, and a breathability of 130 ml / cm 2 · sec. A breathable urethane foam (VHZ, trade name, manufactured by Bridgestone Corporation) is placed thereon, and a polyurethane film (U1490, trade name, manufactured by Kurashiki Textile Co., Ltd.) having a thickness of 30 μm is formed thereon with 100 apertures of 300 μm in diameter / cm 2. A resin layer with a permeability of 30 ml / cm 2 · second is formed, and a release paper (SBK70J, trade name, manufactured by Lintec Corporation) is placed, and this is compressed by the upper heating plate at 125 ° C for 90 seconds. The sound absorbing and insulating material with release paper was removed from the heating platen by applying pressure and heating at a strain of 20%. After leaving to cool at room temperature, the release paper was peeled off to obtain the sound absorbing and insulating material of Example 1. Various properties (low temperature workability, sound insulation, sound absorption rate) of this sound absorbing and insulating material were measured, and the results are shown in Table 1.
〔比較例1〕
実施例1で用いた開孔部を有するポリウレタンフィルム樹脂層に代えて、厚さ30μmのポリエスエルフィルム(D2810、商品名、ダイセル社製)であって開孔処理をしていない樹脂層を用いた以外、実施例1と同様にして、比較例1の吸遮音材吸遮音材を得た。ポリエステルフィルムは熱接着時に一部溶融して空隙が形成される。この吸遮音材の諸特性を実施例1と同様に測定し、その結果を表1に示した。
[Comparative Example 1]
Instead of the polyurethane film resin layer having an aperture used in Example 1, a 30 μm thick polyester film (D2810, trade name, manufactured by Daicel Corp.) that is not subjected to aperture treatment is used. In the same manner as in Example 1 except that the sound absorbing and insulating material of Comparative Example 1 was obtained. The polyester film is partially melted during heat bonding to form voids. Various characteristics of the sound absorbing and insulating material were measured in the same manner as in Example 1, and the results are shown in Table 1.
〔実施例2〕
実施例1の吸遮音材において、樹脂層を積層後、この上に補強材として、樹脂不織布(ナイロン不織布、目付量;20g/m2 、通気性;400ml/cm2 ・秒以上)を積層した以外は、実施例1と同様にして、補強材付き吸遮音材を得た。実施例2の吸遮音材及び実施例1の吸遮音材について、耐引裂性を測定した結果、それぞれ1.36kgf/cm及び0.33kgf/cmであった。また実施例2の吸遮音材の通気性、低温施工性、吸音率、遮音性を測定した結果、実施例1の吸遮音材と同様の特性を有することが確認された。
[Example 2]
In the sound absorbing and insulating material of Example 1, after laminating the resin layer, a resin nonwoven fabric (nylon nonwoven fabric, basis weight: 20 g / m 2 , air permeability: 400 ml / cm 2 · sec or more) was laminated thereon as a reinforcing material. Except for the above, a sound absorbing and insulating material with a reinforcing material was obtained in the same manner as in Example 1. As a result of measuring the tear resistance of the sound absorbing and insulating material of Example 2 and the sound absorbing and insulating material of Example 1, they were 1.36 kgf / cm and 0.33 kgf / cm, respectively. Moreover, as a result of measuring the air permeability, low-temperature workability, sound absorption rate, and sound insulation of the sound absorbing and insulating material of Example 2, it was confirmed that it had the same characteristics as the sound absorbing and insulating material of Example 1.
表1に示されるように、本発明の吸遮音材は、低温施工性、遮音性、吸音性に優れており、さらに実施例2に明らかなように必要に応じて樹脂不織布層を設けた場合、さらにこれらの良好な諸特性に加え、優れた耐引裂性を達成しうることがわかる。 As shown in Table 1, the sound absorbing and insulating material of the present invention is excellent in low-temperature workability, sound insulating properties, and sound absorbing properties, and when a resin nonwoven fabric layer is provided as necessary, as is clear in Example 2 Furthermore, it can be seen that in addition to these good properties, excellent tear resistance can be achieved.
10 垂直入射遮音率測定装置
12 サンプル
14 マイクロホン
16 遮音ボックス
18 スピーカー
10 Normal incident sound insulation
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2010184655A (en) * | 2009-02-13 | 2010-08-26 | Kurabo Ind Ltd | Laminated sound absorbing material |
JP2010196421A (en) * | 2009-02-27 | 2010-09-09 | Three M Innovative Properties Co | Sound absorbing decorative sheet |
JP2016028893A (en) * | 2008-04-14 | 2016-03-03 | スリーエム イノベイティブ プロパティズ カンパニー | Multilayer sound absorbing sheet |
JP2020134765A (en) * | 2019-02-21 | 2020-08-31 | 株式会社イノアック技術研究所 | Laminated sound absorbing material |
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JPH10119219A (en) * | 1996-08-27 | 1998-05-12 | Bridgestone Corp | Fire retardant sound absorbing material |
JPH10121597A (en) * | 1996-10-22 | 1998-05-12 | Nissan Motor Co Ltd | Sound absorption body and vehicle using the same |
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JPH10119219A (en) * | 1996-08-27 | 1998-05-12 | Bridgestone Corp | Fire retardant sound absorbing material |
JPH10121597A (en) * | 1996-10-22 | 1998-05-12 | Nissan Motor Co Ltd | Sound absorption body and vehicle using the same |
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Publication number | Priority date | Publication date | Assignee | Title |
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JP2016028893A (en) * | 2008-04-14 | 2016-03-03 | スリーエム イノベイティブ プロパティズ カンパニー | Multilayer sound absorbing sheet |
JP2010184655A (en) * | 2009-02-13 | 2010-08-26 | Kurabo Ind Ltd | Laminated sound absorbing material |
JP2010196421A (en) * | 2009-02-27 | 2010-09-09 | Three M Innovative Properties Co | Sound absorbing decorative sheet |
JP2020134765A (en) * | 2019-02-21 | 2020-08-31 | 株式会社イノアック技術研究所 | Laminated sound absorbing material |
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