JP2007030226A - Treatment method of wood - Google Patents

Treatment method of wood Download PDF

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JP2007030226A
JP2007030226A JP2005213289A JP2005213289A JP2007030226A JP 2007030226 A JP2007030226 A JP 2007030226A JP 2005213289 A JP2005213289 A JP 2005213289A JP 2005213289 A JP2005213289 A JP 2005213289A JP 2007030226 A JP2007030226 A JP 2007030226A
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wood
paint
coating
unevenness
polished
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JP4517967B2 (en
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Naohiko Maeda
直彦 前田
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Panasonic Electric Works Co Ltd
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Matsushita Electric Works Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a treatment method of wood for imparting water resistance and antistaining properties to wood while putting its feel to practical use. <P>SOLUTION: In the treatment method of wood, the wood 1 is heat-treated under an inert gas atmosphere and, after the surface of the wood 1 is polished, the polished surface of the wood 1 is coated with coating to form a coating film layer 2 along the surface unevenness of the wood 1. The coating comprises a urethane resin containing fine ceramics, the non-volatile component of the applied coating is 2-20 g/m<SP>2</SP>, and thereby the coating film layer 2 is formed along the surface unevenness of the wood 1 to obtain the wood excellent in antistaining properties, abrasion resistance or weatherability while putting the feel of the wood. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本願発明は、水廻り用木材に耐水性を付与するための木材の処理方法に関する。   The present invention relates to a method for treating wood for imparting water resistance to watering wood.

従来、浴室、トイレなどの水廻りに木材を用いる場合、カビの発生や、腐敗、汚れなどの問題があるため、木材に何らかの処理を行い、耐水性を付与することが行われてきた。木材に耐水性を付与する処理方法としては、木材に樹脂を含浸させるWPC(Wood Plastic Combination)や、木材に不活性ガス雰囲気下で加熱処理を行う(例えば、特開平6−158830号公報)方法などが挙げられる。   Conventionally, when wood is used around water in bathrooms, toilets, etc., there are problems such as generation of mold, spoilage, dirt, etc., so that some treatment has been applied to the wood to impart water resistance. As a treatment method for imparting water resistance to wood, WPC (Wood Plastic Combination) in which wood is impregnated with resin, or heat treatment of wood in an inert gas atmosphere (for example, JP-A-6-158830) Etc.

しかしながら、WPCでは木材の細胞壁や細胞内腔に樹脂が含浸されるために耐水性が向上するものの、木材の表層に樹脂が多く含まれることで木材の風合いが損なわれてしまうという問題があった。一方、不活性ガス雰囲気下で加熱処理を行うと、木材細胞中の水酸基が減少し、耐水性が向上するものの、木材の表面は多孔質のままであり、汚れが付着しやすく、又、一度汚れが付着してしまうと除去しにくかった。
特開平6−158830号公報
However, in WPC, although water resistance is improved because the resin is impregnated into the cell walls and cell lumens of wood, there is a problem that the texture of the wood is impaired due to a large amount of resin in the surface layer of wood. . On the other hand, when heat treatment is performed in an inert gas atmosphere, the hydroxyl groups in the wood cells are reduced and the water resistance is improved, but the surface of the wood remains porous, and dirt is easily attached. It was difficult to remove the dirt.
JP-A-6-158830

本願発明は、上記背景技術に鑑みて発明されたものであり、その課題は、木材に、その風合いを生かしながら、耐水性及び防汚性を付与する木材の加工方法を提供することである。   This invention is invented in view of the said background art, The subject is providing the processing method of the wood which provides water resistance and antifouling property, making use of the texture to wood.

上記課題を解決するために、本願発明の請求項1に係る木材の処理方法においては、木材の処理方法であって、不活性ガス雰囲気下で木材を加熱処理した後、その表面を研磨し、研磨された表面に塗料を塗布することで、木材の表面の凹凸に沿って塗膜層を形成することを特徴とするものである。
又、請求項2記載の木材の処理方法においては、塗料が、ウレタン樹脂を主成分とし、ファインセラミックスを含有したものであることを特徴とするものである。
In order to solve the above problems, in the wood treatment method according to claim 1 of the present invention, the wood treatment method, after heat-treating the wood in an inert gas atmosphere, the surface is polished, The coating layer is formed along the unevenness of the surface of the wood by applying a paint to the polished surface.
In the wood processing method according to claim 2, the paint is mainly composed of a urethane resin and contains fine ceramics.

又、請求項3記載の木材の処理方法においては、塗布される塗料の不揮発成分が、2〜20g/m2となるように塗布することを特徴とするものである。 According to a third aspect of the present invention, there is provided a method for treating wood, wherein the non-volatile component of the paint to be applied is 2 to 20 g / m 2 .

本願発明の請求項1に係る木材の処理方法によると、不活性ガス雰囲気下で木材を加熱処理することで耐水性を付与できる。更に、木材の表面を研磨し、研磨された表面に塗料を塗布することで、木材の表面の凹凸に沿って塗膜層を形成することで、塗料を塗布しても木材表面の凹凸が残り、木材の風合いを生かしながらその表面に防汚性を付与することができる。
又、請求項2に係る木材の処理方法によると、塗料が、ウレタン樹脂を主成分とし、ファインセラミックスを含有したものであるため、磨耗性、耐候性に優れた木材となる。
又、請求項3に係る木材の処理方法によると、塗布される塗料の不揮発成分が、2〜20g/m2であるため、木材表面の凹凸に沿って塗料が塗布され、塗布量が多すぎて木材表面の凹凸がなくなることで木材の風合いが損なわれたり、塗布量が少なすぎて塗りむらが生じたりすることがない。
According to the wood processing method of the present invention, water resistance can be imparted by heat-treating wood in an inert gas atmosphere. Furthermore, by polishing the surface of the wood and applying a paint to the polished surface, a coating layer is formed along the unevenness of the surface of the wood, so that the unevenness of the wood surface remains even when the paint is applied. It is possible to impart antifouling properties to the surface while making use of the texture of wood.
According to the wood processing method of claim 2, since the paint is mainly composed of a urethane resin and contains fine ceramics, the wood is excellent in wear and weather resistance.
Further, according to the wood processing method according to claim 3, since the non-volatile component of the applied paint is 2 to 20 g / m 2 , the paint is applied along the unevenness of the wood surface, and the application amount is too large. As a result, the texture of the wood is not impaired by eliminating the irregularities on the surface of the wood, and the coating amount is too small to cause uneven coating.

この実施形態の木材の処理方法は、不活性ガス雰囲気下で木材1を加熱処理した後、その表面を研磨し、研磨された表面に塗料を塗布することで、木材1の表面の凹凸に沿って塗膜層2を形成している。
又、塗料が、ウレタン樹脂を主成分とし、ファインセラミックスを含有したものである。
又、塗布される塗料の不揮発成分が、2〜20g/m2となるように塗布している。
In the wood processing method of this embodiment, after heat-treating the wood 1 in an inert gas atmosphere, the surface is polished, and a paint is applied to the polished surface so that the surface of the wood 1 is uneven. Thus, the coating layer 2 is formed.
Further, the coating material is mainly composed of urethane resin and contains fine ceramics.
Moreover, it has apply | coated so that the non-volatile component of the coating material to apply | coat may be 2-20 g / m < 2 >.

以下、この実施形態の木材の処理工程を、より具体的詳細に説明する。この実施形態の木材の処理方法は、木材1を不活性ガス雰囲気下で加熱処理する工程と、加熱処理された木材1の表面を研磨する工程、研磨された表面に塗料を塗布する工程とからなっている。   Hereinafter, the wood treatment process of this embodiment will be described in more detail. The wood processing method of this embodiment includes a step of heat-treating the wood 1 in an inert gas atmosphere, a step of polishing the surface of the heat-treated wood 1 and a step of applying a paint to the polished surface. It has become.

まず、木材1を熱処理釜に入れて減圧することで脱気した後、不活性ガスを導入して加圧し、加熱処理を行う。このとき用いる不活性ガスとしては、ヘリウムやアルゴンなどの希ガス、窒素や二酸化炭素などから1種類のみを用いるか、もしくは2種類以上を混合して用いても良い。
又、加熱する温度は、100〜250℃が好ましく、更に好ましくは160〜180℃である。100℃以下であると木質の乾燥、すなわち水分の蒸発が起こるのみであり、木材1の性質の改善、すなわち木材1細胞中の水酸基の減少が起こりにくい。又、250℃以上であると木材1の炭化が起こりやすく、機械的強度の低下や変色のおそれがある。又、加熱時間は木材1の種類や形状によっても異なるが、5〜30時間が望ましい。
続いて、木材1の表面を研磨する。このときの研磨の目的は、木材表面のささくれを削り略平面とすることで、この後の工程で塗料を塗布するとき、塗料を均一に塗布しやすくすると共に、その接着性を高めることであるため、木目出しを行う必要はない。研磨をする方法としては、サンドペーパーを用いて手作業で行っても、ベルトサンダーやワイドサンダーなどの研磨機を用いて行ってもよい。
最後に、研磨した木材1に塗料を塗布する。このとき用いる塗料としては、ウレタン樹脂、アクリル樹脂、メラミン樹脂、フェノール樹脂及びジアリールフタレート樹脂などを主成分として含むものなどが挙げられる。この場合、ウレタン樹脂を用いている。更に、この塗料は、ファインセラミックを含有していてもよい。ファインセラミックとしては、シリカ、アルミナ、タルク、マイカなどが挙げられる。これらのファインセラミックはこれらのいずれかを単独で用いても良いし、2種類以上を併用して用いても良い。
塗料を塗布するときには、上記の樹脂やファインセラミックスなどの塗料成分をシンナーなどの有機溶媒で希釈し、塗布する。塗布の方法は、はけなどを用いて行っても良いが、この場合、塗料用のスプレー装置を用いてスプレー塗装している。塗料を塗布する量は、塗料の不揮発成分が2〜20g/m2となるように塗布する。例えば、不揮発成分が20質量%になるようにシンナーで希釈した塗料を、30g/m2となるように塗布することにより、木材1表面には塗料の不揮発成分が6g/m2である塗膜層2が形成される。このように、塗料の希釈度及び塗布量は、塗料の不揮発成分が2〜20g/m2となるように調節する。上記の塗装方法をとることで、図1に示す如く、木材1表面の動管や師管などによって形成されている凹凸に沿って塗膜層2が形成される。塗料の不揮発成分が、これ以上であると木材1表面の凹凸に関係なく平坦な塗膜層2が形成されて木材1の風合いが失われ(図2)、これ以下である場合には塗料の塗りむらが発生する(図3)おそれがある。
従って、この実施形態の木材1の加工方法においては、不活性ガス雰囲気下で木材1を加熱処理した後、その表面を研磨し、研磨された表面に塗料を塗布することで、木材1の表面の凹凸に沿って塗膜層2を形成するため、木材1が加熱処理されることで改質が起こることで耐水性が付与されると共に、その表面の凹凸に沿って塗膜層2が形成されるために木材1の風合いを生かしながら防汚性が付与される。又、加熱処理することにより木材1の平衡含水率が低下するため、塗料が浸透しやすい状態となっており、塗料の塗りむらを防ぐことができると共に、木材1の表面に厚い塗膜層2が形成されにくく、木材1表面の凹凸に沿って薄い塗膜層2が形成され、木材1の風合いがより生かされた木材1を製造できる。又、加熱処理後の木材1の表面を研磨することで、更に塗料の塗りむらを防ぎ、塗料の密着性を向上させることで耐摩耗性を向上させることができる。このことは、この実施形態の木材1の処理方法では、木材1表面の凹凸に沿って塗膜層2が形成される、すなわち木材1表面の形状がそのまま保持されるため、予め木材1の表面を平滑化しておくことで、木材1の仕上がりを良くすることができる。
又、塗料が、ファインセラミックスを含有したウレタン樹脂であるため、耐摩耗性や防汚性が付与される。この木材1の処理方法においては、木材1表面の凹凸を生かし、その風合いを生かすためには薄い塗膜層2を形成することが必要であるが、塗料にファインセラミックを含有させることで、薄い塗膜層2であっても高い耐摩耗性を有するために非常に効果的である。
First, after degassing by putting the wood 1 in a heat treatment kettle and depressurizing, an inert gas is introduced and pressurized to perform heat treatment. As the inert gas used at this time, only one kind from rare gases such as helium and argon, nitrogen and carbon dioxide, or a mixture of two or more kinds may be used.
The heating temperature is preferably 100 to 250 ° C, more preferably 160 to 180 ° C. When the temperature is 100 ° C. or less, only the drying of the wood, that is, the evaporation of water occurs, and the property of the wood 1 is improved, that is, the reduction of the hydroxyl groups in the wood 1 cells hardly occurs. On the other hand, when the temperature is 250 ° C. or higher, the wood 1 is easily carbonized, and there is a risk that the mechanical strength is lowered or discolored. The heating time varies depending on the type and shape of the wood 1, but is preferably 5 to 30 hours.
Subsequently, the surface of the wood 1 is polished. The purpose of polishing at this time is to make the rough surface of the wood surface sharpened, so that when applying the paint in the subsequent process, it is easy to apply the paint uniformly and to increase its adhesion. Therefore, it is not necessary to perform wood graining. As a method of polishing, it may be performed manually using sandpaper or using a polishing machine such as a belt sander or a wide sander.
Finally, a paint is applied to the polished wood 1. Examples of the paint used at this time include those containing, as a main component, a urethane resin, an acrylic resin, a melamine resin, a phenol resin, a diaryl phthalate resin, and the like. In this case, urethane resin is used. Furthermore, this paint may contain a fine ceramic. Examples of the fine ceramic include silica, alumina, talc, and mica. These fine ceramics may be used either alone or in combination of two or more.
When applying the paint, the paint components such as the above resin and fine ceramics are diluted with an organic solvent such as thinner and applied. The application method may be performed using a brush or the like, but in this case, spray coating is performed using a paint spray device. The amount of coating is applied so that the nonvolatile component of the coating is 2 to 20 g / m 2 . For example, a coating nonvolatile component was diluted with a thinner so that 20 mass%, by applying such that the 30 g / m 2, coating the wood 1 surface nonvolatile components of the coating material is 6 g / m 2 Layer 2 is formed. Thus, the dilution degree and the coating amount of the paint are adjusted so that the non-volatile component of the paint is 2 to 20 g / m 2 . By taking the above-mentioned coating method, as shown in FIG. 1, the coating layer 2 is formed along the unevenness formed by the moving tube, the teacher tube, etc. on the surface of the wood 1. When the non-volatile component of the paint is more than this, a flat coating layer 2 is formed regardless of the unevenness of the surface of the wood 1 and the texture of the wood 1 is lost (FIG. 2). There is a risk of uneven coating (FIG. 3).
Therefore, in the processing method of the wood 1 of this embodiment, the surface of the wood 1 is obtained by heat-treating the wood 1 in an inert gas atmosphere, polishing the surface, and applying a paint to the polished surface. In order to form the coating film layer 2 along the unevenness of the film, the heat treatment is applied to the wood 1 to impart water resistance, and the coating film layer 2 is formed along the unevenness of the surface. Therefore, antifouling properties are imparted while taking advantage of the texture of the wood 1. Moreover, since the equilibrium moisture content of the wood 1 is reduced by the heat treatment, the paint is in a state of being easily infiltrated, so that coating unevenness can be prevented and a thick coating layer 2 is formed on the surface of the wood 1. Can be formed, and the thin coating layer 2 is formed along the unevenness of the surface of the wood 1, so that the wood 1 in which the texture of the wood 1 is further utilized can be manufactured. Further, by polishing the surface of the wood 1 after the heat treatment, it is possible to further prevent uneven coating of the paint and to improve the wear resistance by improving the adhesion of the paint. This is because, in the method for treating wood 1 according to this embodiment, the coating layer 2 is formed along the irregularities on the surface of the wood 1, that is, the shape of the surface of the wood 1 is maintained as it is. By smoothing, the finish of the wood 1 can be improved.
Moreover, since the paint is a urethane resin containing fine ceramics, wear resistance and antifouling properties are imparted. In this method for treating wood 1, it is necessary to make use of the unevenness of the surface of wood 1 and to form a thin coating layer 2 in order to make use of the texture. Even the coating layer 2 is very effective because it has high wear resistance.

塗布される塗料の不揮発成分が、2〜20g/m2となるように塗布するため、塗料の塗りむらを防ぐ一方、塗料が木材1表面の凹凸を埋めてしまうような厚塗りを防ぐことで木材1の風合いを保持することができる。つまり、これにより木材1表面の凹凸に沿ってむらなく塗膜層2が形成される。 Since the non-volatile component of the paint to be applied is 2 to 20 g / m 2 , it prevents the paint from being unevenly coated, while preventing the paint from being thickly coated to fill the uneven surface of the wood 1. The texture of the wood 1 can be maintained. That is, the coating layer 2 is thereby formed uniformly along the unevenness of the surface of the wood 1.

以下に実施例、比較例を挙げて本発明を説明するが、本発明はこれらに限定されるものではない。
[木材1の処理方法]
[実施例1]
木材1の含水率を5〜10%に調整した後、木材1を加熱処理釜に入れ、50Torrまで減圧した後、窒素を入れ、0.5MPaまで加圧し、温度160〜180℃で8時間加熱した。この木材1の表面をサンドペーパーで研磨し、研磨された表面に、ウレタン樹脂及びファインセラミックスを含む塗料成分を、シンナーでその不揮発成分が20質量%になるように希釈し、塗布量が30g/m2になるようにスプレー塗装した。
[実施例2]
塗料を、その不揮発成分が15質量%になるように希釈した以外は、実施例1と同様に処理した。
[実施例3]
塗料の塗布量を40g/m2にしてスプレー塗装した以外は、実施例1と同様に処理した。
[実施例4]
塗料にファインセラミックスを含有させなかったこと以外は、実施例1と同様に処理した。
[比較例1]
塗料を、その不揮発成分が30重量%になるように希釈し、塗布量を80g/m2にした以外は、実施例1と同様に処理した。
[比較例2]
塗料を、その不揮発成分が9質量%になるように希釈し、塗布量を20g/m2にすること以外は、実施例1と同様に処理した。
上記のように処理した木材1について、下記の外観の評価、耐汚染性試験、耐摩耗性試験及び耐候性試験を行った。この結果を表1に示す。
Hereinafter, the present invention will be described with reference to examples and comparative examples, but the present invention is not limited thereto.
[Wood 1 treatment method]
[Example 1]
After adjusting the moisture content of the wood 1 to 5 to 10%, the wood 1 is put into a heat treatment kettle, depressurized to 50 Torr, nitrogen is added, the pressure is raised to 0.5 MPa, and the temperature is heated at 160 to 180 ° C. for 8 hours. did. The surface of the wood 1 is polished with sandpaper, and the paint component containing urethane resin and fine ceramics is diluted with the thinner so that the nonvolatile component becomes 20% by mass, and the coating amount is 30 g / Spray paint was applied to m 2 .
[Example 2]
The paint was treated in the same manner as in Example 1 except that the paint was diluted so that its non-volatile component was 15% by mass.
[Example 3]
The same treatment as in Example 1 was conducted except that the coating amount was 40 g / m 2 and spray coating was performed.
[Example 4]
The treatment was performed in the same manner as in Example 1 except that the fine ceramic was not contained in the paint.
[Comparative Example 1]
The paint was treated in the same manner as in Example 1 except that the non-volatile component was diluted to 30% by weight and the coating amount was 80 g / m 2 .
[Comparative Example 2]
The paint was treated in the same manner as in Example 1 except that the non-volatile component was diluted to 9% by mass and the coating amount was 20 g / m 2 .
The wood 1 treated as described above was subjected to the following appearance evaluation, stain resistance test, abrasion resistance test, and weather resistance test. The results are shown in Table 1.

Figure 2007030226
(1)外観
処理した木材1を観察し、木材1表面の凹凸に沿って塗膜層2が形成されているか評価した。表1には、木材1表面の凹凸に沿って塗膜層2が形成されているものを○、塗料の塗りむらがあるもの及び木材1表面の凹凸が失われて厚塗りになっているものを×と表記した。
(2)耐汚染性試験
処理した木材1に、浴室用洗剤(中性、アルカリ性)や入浴剤、メイク落とし等の薬品を1時間放置した後に拭き取り、その表面を観察した。表1には、変色や着色がなかったものを○、変色や着色があったものを×、変色や着色があるが、微少であるものを△と表記した。
(3)耐摩耗性試験
処理した木材1に、磨耗試験機を用いて、浴槽用スポンジたわしに1kgの荷重をかけ、13000回往復させ、その表面を観察した。表1には、艶変化や変色がなかったものを○、艶変化や変色があったものを×、艶変化や変色があるが、微少であるものを△と標記している。
(4)耐候性試験
処理した木材1を、サンシャインウェザオメ−タ−試験機にて所定の光量で照射しながら100時間放置し、その表面を観察した。表1には、割れの発生、白化や変色がなかったものを○、割れの発生、白化や変色がなかったものを×、割れの発生、白化や変色があったが、微少であるものを△と表記した。
表1から分かるように、実施例1〜4のように塗布される塗料の不揮発成分量を2〜20g/m2とすることで、比較例1のように木材1表面の凹凸が失われたり(図2)、又、比較例2のように塗りむらを生じたりする(図3)こともない。又、実施例1〜3と実施例4を比較して分かるように、塗料にファインセラミックスを含有させることで、防汚性、耐摩耗性及び耐候性がより優れたものになっていることが分かる。
Figure 2007030226
(1) The appearance-treated wood 1 was observed, and it was evaluated whether the coating layer 2 was formed along the unevenness of the wood 1 surface. Table 1 shows that the coating layer 2 is formed along the unevenness on the surface of the wood 1, the unevenness of the paint is applied, and the unevenness on the surface of the wood 1 is lost and the coating is thick Was written as x.
(2) Contamination resistance test On the treated wood 1, chemicals such as bathroom detergents (neutral and alkaline), bathing agents, makeup removers, etc. were left for 1 hour and then wiped off and the surface was observed. In Table 1, the case where there was no discoloration or coloring was indicated as ◯, the case where there was discoloration or coloring, and the case where there was discoloration or coloring, but the slight amount was indicated as Δ.
(3) Wear resistance test Using a wear tester, a 1 kg load was applied to the sponge sponge for bathtub, and the surface of the wood 1 was observed by reciprocating 13,000 times. In Table 1, those having no gloss change or discoloration are marked with ◯, those with gloss change or discoloration are marked with “X”, and those with gloss change or discoloration, but slight, are marked with “△”.
(4) The weather resistance test-treated wood 1 was left for 100 hours while irradiating it with a predetermined amount of light with a sunshine weatherometer tester, and its surface was observed. Table 1 shows that there was no cracking, whitening or discoloration, ○, cracking, whitening or discoloration x, cracking, whitening or discoloration, but slight Indicated as △.
As can be seen from Table 1, the unevenness of the surface of the wood 1 is lost as in Comparative Example 1 by setting the amount of non-volatile components of the paint applied as in Examples 1 to 4 to 2 to 20 g / m 2. (FIG. 2) Also, there is no occurrence of uneven coating as in Comparative Example 2 (FIG. 3). In addition, as can be seen by comparing Examples 1 to 3 and Example 4, the antifouling property, wear resistance, and weather resistance can be improved by adding fine ceramics to the paint. I understand.

本願発明の一実施形態である木材の処理方法により処理した木材の断面を示す模式図。The schematic diagram which shows the cross section of the timber processed by the processing method of the timber which is one Embodiment of this invention. 比較例1の断面を示す模式図。FIG. 5 is a schematic diagram showing a cross section of Comparative Example 1. 比較例2の断面を示す模式図。The schematic diagram which shows the cross section of the comparative example 2. FIG.

符号の説明Explanation of symbols

1 木材
2 塗膜層
1 Wood 2 Coating layer

Claims (3)

木材の処理方法であって、不活性ガス雰囲気下で木材を加熱処理した後、その表面を研磨し、研磨された表面に塗料を塗布することで、木材の表面の凹凸に沿って塗膜層を形成することを特徴とする木材の処理方法。   A method for treating wood, in which a wood is heated in an inert gas atmosphere, and then the surface is polished, and a paint is applied to the polished surface, whereby a coating layer is formed along the unevenness of the surface of the wood. A method for treating wood, characterized by 塗料が、ウレタン樹脂を主成分とし、ファインセラミックスを含有したものであることを特徴とする請求項1記載の木材の処理方法。   2. The method for treating wood according to claim 1, wherein the paint is mainly composed of a urethane resin and contains fine ceramics. 塗布される塗料の不揮発成分が、2〜20g/m2となるように塗布することを特徴とする請求項1又は2記載の木材の処理方法。 The method for treating wood according to claim 1 or 2, wherein the non-volatile component of the paint to be applied is applied so as to be 2 to 20 g / m2.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018532907A (en) * 2015-08-20 2018-11-08 インダストリアル コーペレーション ファウンデーション チョンブク ナショナル ユニバーシティーIndustrial Cooperation Foundation Chonbuk National University Flameproof, flame retardant, semi-incombustible plywood ceiling material, and manufacturing method thereof

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JPS5939371A (en) * 1982-08-27 1984-03-03 Asahi Tokushu Gohan Kk Manufacture of grain-patterned veneer
JPH01314102A (en) * 1988-06-13 1989-12-19 Noda Corp Decorative sheet and its manufacture
JPH06158830A (en) * 1992-11-25 1994-06-07 Matsushita Electric Works Ltd Floor material
JP2001353835A (en) * 2000-06-13 2001-12-25 Hamada Mokuzai Kogyo Kk Decorative sheet used in furniture, fixtures or the like, and method for manufacture the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5939371A (en) * 1982-08-27 1984-03-03 Asahi Tokushu Gohan Kk Manufacture of grain-patterned veneer
JPH01314102A (en) * 1988-06-13 1989-12-19 Noda Corp Decorative sheet and its manufacture
JPH06158830A (en) * 1992-11-25 1994-06-07 Matsushita Electric Works Ltd Floor material
JP2001353835A (en) * 2000-06-13 2001-12-25 Hamada Mokuzai Kogyo Kk Decorative sheet used in furniture, fixtures or the like, and method for manufacture the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018532907A (en) * 2015-08-20 2018-11-08 インダストリアル コーペレーション ファウンデーション チョンブク ナショナル ユニバーシティーIndustrial Cooperation Foundation Chonbuk National University Flameproof, flame retardant, semi-incombustible plywood ceiling material, and manufacturing method thereof

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