JP2007009368A - Spinneret and method for producing ultrafine fiber - Google Patents

Spinneret and method for producing ultrafine fiber Download PDF

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JP2007009368A
JP2007009368A JP2005192213A JP2005192213A JP2007009368A JP 2007009368 A JP2007009368 A JP 2007009368A JP 2005192213 A JP2005192213 A JP 2005192213A JP 2005192213 A JP2005192213 A JP 2005192213A JP 2007009368 A JP2007009368 A JP 2007009368A
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spinneret
polymer
introduction hole
holes
discharge
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JP4725213B2 (en
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Minoru Fujimori
稔 藤森
Yasuki Kobayashi
靖希 小林
Naoyuki Kinoshita
直之 木下
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Toray Industries Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a spinneret capable of stably producing an ultrafine fiber. <P>SOLUTION: The spinneret has the following characteristics. (1) The outside diameter of the spinneret is 75-125 mm. (2) Polymer-introducing holes are arranged in 2-6 lines in a circumferential state. (3) The relationship between D2 (mm) defined as two time of maximum value of a line (radius) binding the center of the spinneret and the center of the polymer-introducing hole and the outside diameter D1 (mm) satisfies the formula: 0.6×D1≤D2≤0.85×D1. (4) The relationship between line interval L (mm) of the polymer-introducing holes and an introducing hole diameter D3 (mm) satisfies the formula: 1.3×D3≤L≤6×D3. (5) The numbers of discharge holes per polymer-introducing hole are 2-8. (6) The ratio D4/D3 of D4 (mm) defined as two times of maximum value of a line (radius) binding the center of the polymer-introducing hole and the center of the discharge hole to the diameter D3(mm) of the polymer-introducing hole is 0.5-0.9. (7) Total numbers of discharge holes are 120-600. (8) Discharge holes in one group are not arranged in a radial direction of the spinneret. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、従来より優れた品質を有する極細繊維を製造するのに好適な口金およびこれを用いた合成繊維の製造方法に関するものである。   The present invention relates to a die suitable for producing ultrafine fibers having superior quality than conventional ones and a method for producing synthetic fibers using the same.

極細繊維は、その細さ、柔らかさから衣料用途において広く使用されており、また近年ではカーシートなどの車輌内装材等の産業資材用途にも用いられつつある。   Extra fine fibers are widely used in clothing applications due to their thinness and softness, and in recent years, they are also being used in industrial material applications such as vehicle interior materials such as car seats.

中でもポリエチレンテレフタレ―トに代表されるポリエステル極細繊維は高強度、高ヤング率、熱寸法安定性に優れた繊維であり、上記用途の中でもとりわけて需要が高い。   Among them, polyester microfibers typified by polyethylene terephthalate are fibers having high strength, high Young's modulus, and excellent thermal dimensional stability, and demand is particularly high among the above applications.

しかしながら、極細繊維はその製造工程の難しさから、生産性、品質上の課題が残されているのも事実である。   However, it is also a fact that the problems of productivity and quality remain for the ultrafine fibers because of the difficulty of the production process.

一般的に溶融紡糸により製造されるポリエステル、ポリアミド等において、極細繊維を得るためには一定の面積の紡糸口金から多数の糸条を吐出する必要があるため、そのフィラメントの数には限りがあった。また、多数のフィラメントを吐出後に冷却風にて冷却する工程においても、フィラメント数が多いため冷却風が通りにくく、均一な冷却が困難であるため、ウースター斑が悪化し、このような極細繊維を用いた布帛の品位が低下するという問題を有する。   In general, in polyester, polyamide, etc. produced by melt spinning, in order to obtain ultrafine fibers, it is necessary to discharge a large number of yarns from a spinneret of a certain area, so the number of filaments is limited. It was. Also, in the process of cooling with a cooling air after discharging a large number of filaments, the cooling air is difficult to pass due to the large number of filaments, and uniform cooling is difficult. There is a problem that the quality of the used fabric is lowered.

かかる問題を解決するために、紡糸口金から吐出した糸条を糸条に対して直角方向から冷却風を吹き付け冷却固化した後、環状の保護筒に通すことにより外乱を防止することでウースター斑を低減する方法が提案されている(例えば、特許文献1参照)。しかしながら、この方法では糸条が冷却される部分については考慮されておらず、このためウースター斑の改善は不十分である。   In order to solve such a problem, the yarn discharged from the spinneret is cooled and solidified by blowing cooling air from a direction perpendicular to the yarn, and then passed through an annular protective cylinder to prevent disturbance, thereby preventing Wooster spots. A reduction method has been proposed (see, for example, Patent Document 1). However, this method does not consider the portion where the yarn is cooled, and therefore the improvement of Wooster spots is insufficient.

また、紡糸口金と冷却風による冷却域との間に仕切板を設け、口金の冷えを抑制しつつ口金下の冷却風の流れを安定化することでウースター斑を低減する方法が提案されている(例えば、特許文献2参照)。しかしながら、この方法によっても、仕切板と糸条の近接する部分での冷却風の乱流化により糸揺れが誘発されるため、ウースター斑の改善は不十分なものにとどまっている。   In addition, a method has been proposed in which a partition plate is provided between the spinneret and the cooling area by the cooling air to reduce Wooster spots by stabilizing the flow of the cooling air under the base while suppressing the cooling of the base. (For example, refer to Patent Document 2). However, even with this method, the yarn sway is induced by the turbulent flow of the cooling air in the portion where the partition plate and the yarn are close to each other, so that the improvement of the Wooster spot remains insufficient.

一方、ポリマーのパック内、および口金部分での異常滞留を防止することによりウースター斑、糸切れを改善する方法も提案されている(例えば、特許文献3参照)。しかしながら、この方法は異常滞留の減少によるポリマーのクリーン化については言及されているものの、吐出後の糸条の冷却を考慮したものではなく、均一冷却によるウースター斑の改善は図れていないのが実状である。
特開昭62−243824号公報(第1頁) 特開平09−137317号公報(第2頁) 特開平07−300716号公報(第2頁)
On the other hand, there has also been proposed a method for improving Wooster spots and thread breakage by preventing abnormal stagnation in the polymer pack and in the mouthpiece (see, for example, Patent Document 3). However, although this method mentions cleaning of the polymer by reducing abnormal stagnation, it does not consider the cooling of the yarn after discharge, and the fact that the Wooster spots are not improved by uniform cooling is the actual situation. It is.
Japanese Patent Laid-Open No. 62-243824 (first page) JP 09-137317 A (second page) Japanese Patent Application Laid-Open No. 07-300716 (second page)

本発明の目的は、従来より優れたウースター斑を有する極細繊維を高生産性の下に安定して製造することができる紡糸口金およびこれを用いた極細繊維の製造方法を提供することにある。   An object of the present invention is to provide a spinneret capable of stably producing ultrafine fibers having Wooster spots superior to conventional ones with high productivity and a method for producing ultrafine fibers using the same.

上記目的を達成するため、本発明は以下の構成を採用する。すなわち、
[1]下記(1)〜(8)
(1)外径D1が75〜125mmである円形の口金を有し、
(2)前記口金には、ポリマー導入孔が円周状に2〜6列配列され、
(3)前記口金中心とポリマー導入孔の中心とを結ぶ線を半径として、その最大値の2倍で定義されるD2(mm)と口金の外径D1(mm)との関係が、
0.6×D1≦D2≦0.85×D1
を満足し、
(4)前記ポリマー導入孔の列間隔L(mm)と導入孔径D3(mm)との関係が、
1.3×D3≦L≦6×D3
を満足し、
(5)前記1つのポリマー導入孔に対して吐出孔が2〜8孔穿孔され、
(6)前記1つのポリマー導入孔に穿孔された吐出孔を1つの群として、ポリマー導入孔の中心と吐出孔の中心とを結ぶ線を半径として、その最大値の2倍で定義されるD4(mm)とポリマー導入孔径D3(mm)との比、
D4/D3=0.5〜0.9
を満足し、
(7)さらに、吐出孔の総数が120〜600孔であるとともに、
(8)1つの群内の吐出孔が口金中心に対して半径方向に並ばないように配列されている、
の要件を具備することを特徴とする紡糸口金。
In order to achieve the above object, the present invention adopts the following configuration. That is,
[1] The following (1) to (8)
(1) having a circular base having an outer diameter D1 of 75 to 125 mm,
(2) In the base, 2 to 6 rows of polymer introduction holes are arranged circumferentially,
(3) The relationship between D2 (mm) defined by twice the maximum value and the outer diameter D1 (mm) of the die, with the line connecting the center of the die and the center of the polymer introduction hole as the radius,
0.6 × D1 ≦ D2 ≦ 0.85 × D1
Satisfied,
(4) The relationship between the row interval L (mm) of the polymer introduction holes and the introduction hole diameter D3 (mm)
1.3 × D3 ≦ L ≦ 6 × D3
Satisfied,
(5) 2 to 8 discharge holes are drilled with respect to the one polymer introduction hole,
(6) D4 defined by twice the maximum value with the discharge hole perforated in the one polymer introduction hole as one group, and a line connecting the center of the polymer introduction hole and the center of the discharge hole as a radius (Mm) and the ratio of the polymer introduction hole diameter D3 (mm),
D4 / D3 = 0.5-0.9
Satisfied,
(7) Furthermore, the total number of ejection holes is 120 to 600 holes,
(8) The discharge holes in one group are arranged so as not to be aligned in the radial direction with respect to the center of the die.
A spinneret characterized by having the following requirements.

[2]1つの群内の吐出孔が同心円状に穿孔されていることを特徴とする前記[1]に記載の紡糸口金
[3]2山用の分離帯が設けられていることを特徴とする前記[1]または[2]に記載の紡糸口金。
[2] The spinneret according to [1] above, wherein the discharge holes in one group are concentrically drilled. [3] A separation band for two ridges is provided. The spinneret according to [1] or [2].

[4]分離帯幅W(mm)=12〜24であることを特徴とする前記[3]に記載の紡糸口金。   [4] The spinneret according to [3], wherein the separation band width W (mm) is 12 to 24.

[5]請求項1〜4のいずれか1項に記載の口金を用い、かつ環状冷却装置を用いて紡糸することを特徴とする極細繊維の製造方法。   [5] A method for producing an ultrafine fiber, characterized in that the base according to any one of claims 1 to 4 is used for spinning using an annular cooling device.

[6]合成繊維が、フィラメント数が60〜600、単糸繊度が0.2〜1.0dtexの極細繊維であることを特徴とする前記[5]に記載の極細繊維の製造方法である。   [6] The method for producing ultrafine fibers according to [5], wherein the synthetic fiber is an ultrafine fiber having a filament number of 60 to 600 and a single yarn fineness of 0.2 to 1.0 dtex.

本発明の紡糸口金によれば、ウースター斑が改善されるとともに、製造する際の糸切れも減少し、高生産性の下に安定に極細繊維を製造することが可能となる。   According to the spinneret of the present invention, Worcester spots are improved, yarn breakage during production is reduced, and it becomes possible to produce ultrafine fibers stably with high productivity.

本発明の紡糸口金は、図1に示すように、円形の口金であり、かつその外径D1が75〜125mmのものである。円形でない場合は口金を装着するパックの取り扱いが煩雑になり、かつ環状冷却に適さなくなる。また、外径D1が75mm未満の場合はその口金に穿孔可能な吐出孔の数が制限されるため、極細繊維を製造する際に同時に要求される多フィラメント化が不十分となる。また、外径D1が125mmを越える場合は、以下に記す要件を満たさなくても多数の吐出孔を穿孔できるため、本発明の効果が小さくなる。   As shown in FIG. 1, the spinneret of the present invention is a circular die and has an outer diameter D1 of 75 to 125 mm. If it is not circular, handling of the pack on which the base is mounted becomes complicated and is not suitable for annular cooling. Further, when the outer diameter D1 is less than 75 mm, the number of discharge holes that can be perforated in the die is limited, so that the number of multifilaments required at the same time when producing ultrafine fibers is insufficient. In addition, when the outer diameter D1 exceeds 125 mm, a large number of discharge holes can be drilled without satisfying the requirements described below, so the effect of the present invention is reduced.

本発明の紡糸口金は、その導入孔を円周状に2〜6列とするものである。円周状としない場合には、吐出後の環状冷却によって均一冷却することによる、得られる極細繊維の均一性が損なわれる。また、列数を7列以上とすると、環状に配列しているにも関わらず、ポリマーを吐出孔より吐出した後冷却風によって冷却する工程において、冷却風が糸条の間を通りにくくなるため、目的とする均一冷却の効果が損なわれる。   In the spinneret of the present invention, the introduction holes are circumferentially arranged in 2 to 6 rows. In the case of not having a circumferential shape, the uniformity of the ultrafine fibers obtained by uniform cooling by annular cooling after discharge is impaired. Further, when the number of rows is 7 or more, the cooling air is less likely to pass between the yarns in the process of cooling with the cooling air after the polymer is discharged from the discharge holes even though the rows are arranged in an annular shape. The target uniform cooling effect is impaired.

本発明の紡糸口金は、その口金中心とポリマー導入孔の中心とを結ぶ線を半径として、その最大値の2倍で定義されるD2(mm)を0.6×口金外径D1(mm)以上0.85×口金外径D1(mm)とするものである。D2が0.6×D1より小さいと、ポリマーを吐出孔より吐出した後冷却風によって冷却する工程において、冷却風が糸条の間を通りにくくなるため、目的とする均一冷却の効果が損なわれる。またD2が0.85×D1より大きい場合には、糸条が揺れた際に環状冷却装置との接触等を起こし、糸切れを発生する場合がある。   The spinneret of the present invention has a line connecting the center of the base and the center of the polymer introduction hole as a radius, and D2 (mm) defined by twice the maximum value is 0.6 × the outer diameter of the base D1 (mm) The above is 0.85 × the outer diameter of the base D1 (mm). When D2 is smaller than 0.6 × D1, the cooling air is less likely to pass between the yarns in the step of cooling with cooling air after the polymer is discharged from the discharge holes, so that the intended uniform cooling effect is impaired. . Further, when D2 is larger than 0.85 × D1, when the yarn sways, contact with the annular cooling device or the like may occur, and yarn breakage may occur.

また、本発明の紡糸口金は、ポリマー導入孔の列間隔をL(mm)、導入孔径をD3(mm)としたとき、1.3×D3≦L≦6×D3とするものである。Lが1.3×D3より小さい場合には、2つの導入孔から吐出される2つのそれぞれの糸条群の間隔が小さすぎるため、ポリマーを吐出孔より吐出した後冷却風によって冷却する工程において、冷却風が通りにくくなり、目的とする均一冷却の効果が損なわれる。またLが6×D3より大きい場合には、列間隔が大きすぎるため吐出孔を多数穿孔することができず、目的とする多フィラメント糸を得ることができない。   Further, the spinneret of the present invention is such that 1.3 × D3 ≦ L ≦ 6 × D3, where L (mm) is the interval between the polymer introduction holes and D3 (mm) is the introduction hole diameter. In the case where L is smaller than 1.3 × D3, the interval between the two yarn groups discharged from the two introduction holes is too small, and therefore the polymer is discharged from the discharge holes and then cooled by cooling air. This makes it difficult for the cooling air to pass through and impairs the intended uniform cooling effect. On the other hand, when L is larger than 6 × D3, the row interval is too large, so that a large number of discharge holes cannot be punched, and the desired multifilament yarn cannot be obtained.

また、本発明の紡糸口金は、1つの導入孔に対して吐出孔が2〜8孔穿孔されているものである。1つの導入孔に対する吐出孔が1孔では、極細繊維を製造する際に同時に要求される多フィラメント化が不十分となる。また9孔以上では、1つの導入孔から吐出される各フィラメントの間隔が小さすぎるため、ポリマーを吐出孔より吐出した後冷却風によって冷却する工程において、冷却風が通りにくくなり、目的とする均一冷却の効果が損なわれる。   Further, the spinneret of the present invention has 2 to 8 discharge holes per one introduction hole. When the number of discharge holes for one introduction hole is one, the number of filaments required at the same time when producing ultrafine fibers is insufficient. In the case of 9 holes or more, since the interval between the filaments discharged from one introduction hole is too small, the cooling air becomes difficult to pass in the process of cooling with the cooling air after discharging the polymer from the discharging hole, and the desired uniform The effect of cooling is impaired.

また、本発明の紡糸口金は、1つの導入孔に対して穿孔された吐出孔を1つの群とし、その吐出孔群のPCDをD4(mm)としたとき、ポリマー導入孔径D3(mm)に対して、D4/D3を0.5〜0.9とするものである(図3参照)。   Further, in the spinneret of the present invention, when the discharge holes perforated with respect to one introduction hole are made into one group and the PCD of the discharge hole group is set to D4 (mm), the diameter of the polymer introduction hole is D3 (mm). On the other hand, D4 / D3 is set to 0.5 to 0.9 (see FIG. 3).

なお、吐出孔群のPCDとは、図3に示すように、ポリマー導入孔の中心と吐出孔の中心とを結ぶ線を半径としてその最大値の2倍で定義される。すなわちポリマー導入孔の中心から最も遠い吐出孔の中心を通る、ポリマー導入孔の中心を中心とする円の直径を指す。   As shown in FIG. 3, the PCD of the discharge hole group is defined as a radius that is a line connecting the center of the polymer introduction hole and the center of the discharge hole, which is twice the maximum value. That is, it refers to the diameter of a circle centered on the center of the polymer introduction hole that passes through the center of the discharge hole farthest from the center of the polymer introduction hole.

D4/D3を0.5未満とした場合は各フィラメントの間隔が小さすぎるため、ポリマーを吐出孔より吐出した後冷却風によって冷却する工程において、糸条の間を冷却風が通りにくくなり、目的とする均一冷却の効果が損なわれる。また、導入孔底部でのポリマーの異常滞留が懸念される場合がある。また0.9を越えると、吐出孔を穿孔する際の加工が難しくなる。   When D4 / D3 is less than 0.5, the interval between the filaments is too small, so in the process of cooling with cooling air after discharging the polymer from the discharge holes, it becomes difficult for the cooling air to pass between the yarns. The effect of uniform cooling is impaired. In addition, there may be a concern about abnormal retention of the polymer at the bottom of the introduction hole. On the other hand, if it exceeds 0.9, it is difficult to process the discharge holes.

また、導入孔底部の形状については特に制限されないが、穿孔加工の容易性およびコストの点から底部は水平であることが好ましい。   Further, the shape of the bottom portion of the introduction hole is not particularly limited, but the bottom portion is preferably horizontal from the viewpoint of ease of drilling and cost.

また、本発明の紡糸口金は、吐出孔の総数が120〜600孔であるものである。120孔未満であると、極細繊維を製造する際に同時に要求される多フィラメント化が不十分となる。600より多い場合には、冷却風によって冷却する工程において、冷却風が通りにくくなり、目的とする均一冷却の効果が損なわれる。   The spinneret of the present invention has a total number of ejection holes of 120 to 600 holes. When the number is less than 120 holes, the multifilament formation required at the same time when producing ultrafine fibers becomes insufficient. In the case of more than 600, in the process of cooling with cooling air, it becomes difficult for the cooling air to pass through and the intended effect of uniform cooling is impaired.

また、本発明の紡糸口金は、1つの群内の吐出孔が半径方向に並ばないように配列されているものである。1つの群内の吐出孔が半径方向に並んだ場合、半径方向から吹き付ける環状冷却において、外側の糸条によって内側の糸条の冷却が妨げられるため、目的とする均一冷却の効果が損なわれる。1つの群内の吐出孔は、各吐出孔と口金中心を結んだ線同士のなす角度θが0.3°以上5°以下であることが好ましく、0.6°以上であることがさらに好ましい。0.3°未満である場合には冷却風によって冷却する工程において、冷却風が通りにくくなり、目的とする均一冷却の効果が損なわれる。また5°より大きい場合には極細繊維を製造する際に同時に要求される多フィラメント化が不十分となる。   The spinneret of the present invention is arranged so that the discharge holes in one group are not aligned in the radial direction. When the discharge holes in one group are arranged in the radial direction, in the annular cooling that is blown from the radial direction, the cooling of the inner yarn is hindered by the outer yarn, so that the intended uniform cooling effect is impaired. In the discharge holes in one group, the angle θ formed by the lines connecting the discharge holes and the center of the die is preferably 0.3 ° or more and 5 ° or less, and more preferably 0.6 ° or more. . When the angle is less than 0.3 °, the cooling air becomes difficult to pass in the step of cooling with the cooling air, and the intended uniform cooling effect is impaired. On the other hand, when the angle is larger than 5 °, the number of multifilaments required at the same time when producing ultrafine fibers is insufficient.

本発明の紡糸口金は1つの導入孔に穿孔される吐出孔が同心円状に穿孔されていることが好ましい。このことにより1つの導入孔から吐出孔を経て吐出される各フィラメントの熱履歴がほぼ同等となるため、得られる極細繊維の均一性が向上する。   In the spinneret of the present invention, it is preferable that the discharge holes formed in one introduction hole are formed concentrically. As a result, the thermal histories of the filaments discharged from one introduction hole through the discharge hole become substantially equal, so that the uniformity of the obtained ultrafine fibers is improved.

本発明の紡糸口金は、その目的である極細繊維をより多フィラメントで効率良く得るために、2山としてもよい。この際、2山とするための山間の分離帯を設けてもよい。また、この分離帯の幅Wは12〜24mmとすることが好ましい。この分離帯の幅Wを12mm未満とすると、山間の距離が小さいため、得られる2つの糸条群を分離することが難しくなる、あるいは片方の糸条群のフィラメントが他方の糸条群に混入するといった課題が発生する場合があるため好ましくない。また24mmより大きくすると上記課題は解決されるものの、穿孔可能な孔の数が制限されるため、極細繊維を製造する際に同時に要求される多フィラメント化が不十分となる。   The spinneret of the present invention may have two piles in order to efficiently obtain the objective ultrafine fiber with more multifilaments. At this time, a separation zone between the mountains for the purpose of forming two mountains may be provided. The width W of the separation band is preferably 12 to 24 mm. If the width W of the separation band is less than 12 mm, it is difficult to separate the two obtained yarn groups because the distance between the mountains is small, or the filaments of one yarn group are mixed into the other yarn group. This is not preferable because there may be a problem such as. On the other hand, when the size is larger than 24 mm, the above-mentioned problem is solved, but the number of holes that can be perforated is limited, so that the number of multifilaments required at the same time when producing ultrafine fibers becomes insufficient.

本発明の紡糸口金を用いて極細繊維を製造する場合は、熱可塑性ポリマーを紡糸口金から溶融吐出、引き取った後一旦巻き取り、ついで延伸または延伸仮撚してもよく、また延伸せずに巻き取ってもよい。   When producing the ultrafine fiber using the spinneret of the present invention, the thermoplastic polymer may be melted and discharged from the spinneret, taken up and then wound up, and then drawn or drawn false twisted, or wound without being drawn. You may take it.

本発明の紡糸口金を用いた極細繊維の製造に使用する熱可塑性ポリマーとして具体的には、ポリエステル、ポリアミド、ポリエチレン等が挙げられる。   Specific examples of the thermoplastic polymer used for the production of the ultrafine fiber using the spinneret of the present invention include polyester, polyamide, and polyethylene.

なかでもポリエステルについては、ジカルボン酸またはそのエステル形成性誘導体およびジオールまたはそのエステル形成性誘導体から合成されるポリマーであり、繊維、フィルム、ボトル等の成形品として用いることができるものが好ましい。   Of these, polyesters are polymers synthesized from dicarboxylic acids or their ester-forming derivatives and diols or their ester-forming derivatives, and those that can be used as molded articles such as fibers, films and bottles are preferred.

このようなポリエステルとして具体的には、例えばポリエチレンテレフタレート、ポリプロピレンテレフタレート、ポリテトラメチレンテレフタレート、ポリエチレン−2,6−ナフタレンジカルボキシレ−ト、ポリエチレン−1,2−ビス(2−クロロフェノキシ)エタン−4,4’−ジカルボキシレート等が挙げられる。本発明は、なかでも最も汎用的に用いられているポリエチレンテレフタレートまたは主としてエチレンテレフタレート単位を含むポリエステル共重合体において好適である。   Specific examples of such polyester include polyethylene terephthalate, polypropylene terephthalate, polytetramethylene terephthalate, polyethylene-2,6-naphthalene dicarboxylate, polyethylene-1,2-bis (2-chlorophenoxy) ethane. 4,4′-dicarboxylate and the like. The present invention is suitable for polyethylene terephthalate or polyester copolymers mainly containing ethylene terephthalate units, which are most commonly used.

また、これらのポリエステルには、本発明の目的、効果を損なわない範囲で各種のエステル形成性誘導体が共重合されていてもよい。   These polyesters may be copolymerized with various ester-forming derivatives as long as the objects and effects of the present invention are not impaired.

また、これらのポリエステルには、本発明の目的、効果を損なわない範囲で、二酸化チタン等の艶消し剤、酸化ケイ素、カオリン等の各種機能性粒子のほか、着色防止剤、安定剤、抗酸化剤等の添加剤を含有してもよい。   In addition, these polyesters include a matting agent such as titanium dioxide, various functional particles such as silicon oxide and kaolin, as well as an anti-coloring agent, a stabilizer, and an antioxidant as long as the objects and effects of the present invention are not impaired. You may contain additives, such as an agent.

次に本発明の極細繊維の製造方法を説明する。具体例としてポリエチレンテレフタレートを用いた極細繊維の例を記載するがこれに限定されるものではない。   Next, the manufacturing method of the ultrafine fiber of this invention is demonstrated. Although the example of the ultrafine fiber using a polyethylene terephthalate is described as a specific example, it is not limited to this.

ポリエステル繊維は通常、(1)ポリエステルを溶融し、計量し、濾過した後に吐出するプロセス、(2)吐出されたポリエステルフィラメントを冷却風により冷却した後引き取るプロセス、(3)引き取られたポリエステルフィラメントを巻き取るプロセス、(4)場合によって得られたポリエステル繊維を延伸または延伸仮撚するプロセスにより得られる。   Polyester fibers are usually (1) a process in which the polyester is melted, weighed, filtered, and discharged, (2) a process in which the discharged polyester filament is cooled by cooling air, and then (3) It is obtained by a winding process and (4) a process of stretching or stretching false twisting of the polyester fiber obtained in some cases.

本発明の紡糸口金を用いて極細繊維を得る際は、上記プロセスのうち(1)については常法によって行う。(2)については、本発明の紡糸口金は冷却風の通り抜けが良いため、一方向から冷却風を吹き付ける方法でもよいが、環状冷却装置を用い、冷却風を糸条を囲む全円周方向から中心に向かって吹き付ける方法が好ましい。以下(3)および(4)のプロセスは常法に従って行えばよい。   When ultrafine fibers are obtained using the spinneret of the present invention, (1) of the above processes is performed by a conventional method. As for (2), since the spinneret of the present invention allows the cooling air to pass through, the cooling air may be blown from one direction, but an annular cooling device is used and the cooling air is drawn from the entire circumferential direction surrounding the yarn. A method of spraying toward the center is preferable. The following processes (3) and (4) may be performed according to a conventional method.

本発明の紡糸口金を用いて極細繊維を得る場合、その極細繊維はフィラメント数が60以上、単糸繊度が1.0dtex以下であることが好ましい。フィラメント数が60未満あるいは単糸繊度が1.0dtexより大きい場合は、極細繊維のウースター斑は常法においても悪くないため、本発明の紡糸口金によるウースター斑改善の効果が小さいものとなる。   When ultrafine fibers are obtained using the spinneret of the present invention, the ultrafine fibers preferably have 60 or more filaments and a single yarn fineness of 1.0 dtex or less. When the number of filaments is less than 60 or the single yarn fineness is greater than 1.0 dtex, the Worcester spots of the ultrafine fibers are not bad even in the usual method, and therefore the effect of improving the Wooster spots by the spinneret of the present invention is small.

以下、実施例により本発明をさらに具体的に説明する。なお、実施例中の物性値は以下に述べる方法で測定した。
(1)ポリマーの固有粘度IV
オルソクロロフェノールを溶媒として25℃で測定した。
(2)ウースター斑
zellweger社製USTER TESTER UT−4を用い、糸速度100m/分、撚り数8000T/mで5分間測定する間の平均値を算出しウースター斑(H%)とした。
(3)糸切れ判定
32錘で同時に紡糸を行い、120時間紡糸する間の糸切れ回数を測定し、1回以下なら◎、2〜3回なら○、4〜5回なら△、6回以上なら×とした。
Hereinafter, the present invention will be described more specifically with reference to examples. In addition, the physical-property value in an Example was measured by the method described below.
(1) Intrinsic viscosity of polymer IV
Measurement was performed at 25 ° C. using orthochlorophenol as a solvent.
(2) Wooster spots Using the USTER TESTER UT-4 manufactured by Zellweger, the average value during measurement for 5 minutes at a yarn speed of 100 m / min and a twist number of 8000 T / m was calculated to obtain Wooster spots (H%).
(3) Determination of yarn breakage Spinning simultaneously with 32 spindles and measuring the number of yarn breakage during spinning for 120 hours, ◎ if 1 or less, ○ if 2 or 3 times, Δ if 4 to 5 times, 6 times or more If it was x.

実施例1
ポリマーの固有粘度IVが0.66のポリエチレンテレフタレートのホモポリマーペレットを乾燥し、水分率を70ppm以下とする。この乾燥ペレットを溶融し、口金外径D1=110mm、紡糸口金最外周径D2=88mm、ポリマー導入孔径D3=4.0mm、吐出孔群のPCDD4=3.0mm、ポリマー導入孔の列間隔L=7mm、3列環状配列、1導入孔あたり4吐出孔、総吐出孔数288、1導入孔に穿孔された吐出孔が半径方向に並んでいない、2山で分離帯幅W=16mmである口金からポリマー温度292℃で吐出した後、環状冷却装置にて冷却し、油剤付与後4020m/分の速度で引き取り、続いて4000m/分で巻き取ることにより80dtex、144フィラメントのポリエステル極細繊維を得た。紡糸の際の糸切れおよび得られた極細繊維のウースター斑は表1に示すとおり良好な結果が得られた。
Example 1
The polyethylene terephthalate homopolymer pellets having a polymer intrinsic viscosity IV of 0.66 are dried to a moisture content of 70 ppm or less. The dried pellets were melted, and the outer diameter D1 of the nozzle D1 = 110 mm, the outermost diameter D2 of the spinneret D88 = 88 mm, the diameter D3 of the polymer introduction hole D3 = 4.0 mm, the PCDD4 = 3.0 mm of the discharge hole group, and the interval L = 7 mm, 3 rows annular array, 4 discharge holes per introduction hole, total number of discharge holes 288, 1 discharge holes perforated in the introduction hole are not aligned in the radial direction, and the separation band width W = 16 mm After being discharged at a polymer temperature of 292 ° C., it was cooled by an annular cooling device, taken up at a speed of 4020 m / min after applying the oil, and subsequently wound up at 4000 m / min to obtain a polyester ultrafine fiber having 80 dtex and 144 filaments. . As shown in Table 1, good results were obtained with respect to yarn breakage during spinning and Worcester spots of the obtained ultrafine fibers.

実施例2
実施例1と同様のポリエステルペレットを実施例1と同様に乾燥、溶融し、口金外径D1=75mm、紡糸口金最外周径D2=60mm、ポリマー導入孔径D3=4.0mm、吐出孔群のPCDD4=3.5mm、L=6mm、2列環状配列、1導入孔あたり8吐出孔、総吐出孔数192、1導入孔に穿孔された吐出孔が半径方向に並んでいない、2山で分離帯幅W=12mmである口金からポリマー温度292℃で吐出した後、環状冷却装置にて冷却し、油剤付与後4020m/分の速度で引き取り、続いて4000m/分で巻き取ることにより80dtex、96フィラメントのポリエステル極細繊維を得た。紡糸の際の糸切れおよび得られた極細繊維のウースター斑は表1に示すとおり良好な結果が得られた。
Example 2
The same polyester pellets as in Example 1 were dried and melted in the same manner as in Example 1. The outer diameter D1 of the die D = 75 mm, the outermost diameter D2 of the spinneret D2 = 60 mm, the diameter D3 of the polymer introduction hole D3 = 4.0 mm, and the PCDD4 of the discharge hole group = 3.5mm, L = 6mm, 2 rows annular arrangement, 8 discharge holes per introduction hole, total number of discharge holes 192, 1 discharge holes perforated in the radial direction are not aligned in the radial direction. After discharging at a polymer temperature of 292 ° C. from a die having a width W = 12 mm, the polymer is cooled by an annular cooling device, taken up at a speed of 4020 m / min after applying the oil, and subsequently wound up at 4000 m / min to obtain 80 dtex, 96 filaments Polyester microfiber was obtained. As shown in Table 1, good results were obtained with respect to yarn breakage during spinning and Worcester spots of the obtained ultrafine fibers.

実施例3
実施例1と同様のポリエステルペレットを実施例1と同様に乾燥、溶融し、口金外径D1=125mm、紡糸口金最外周径D2=100mm、ポリマー導入孔径D3=4.0mm、吐出孔群のPCDD4=3.0mm、ポリマー導入孔の列間隔L=6mm、6列環状配列、1導入孔あたり4吐出孔、総吐出孔数384、1導入孔に穿孔された吐出孔が半径方向に並んでいない、2山で分離帯幅W=24mmである口金からポリマー温度292℃で吐出した後、環状冷却装置にて冷却し、油剤付与後4020m/分の速度で引き取り、続いて4000m/分で巻き取ることにより80dtex、192フィラメントのポリエステル極細繊維を得た。紡糸の際の糸切れおよび得られた極細繊維のウースター斑は表1に示すとおり良好な結果が得られた。
Example 3
The same polyester pellets as in Example 1 were dried and melted in the same manner as in Example 1, and the outer diameter D1 of the die D = 125 mm, the outermost diameter D2 of the spinneret D100 = 100 mm, the diameter D3 of the polymer introduction hole D3 = 4.0 mm, and the PCDD4 of the discharge hole group = 3.0 mm, polymer introduction hole row interval L = 6 mm, 6 rows annular array, 4 discharge holes per introduction hole, total number of discharge holes 384, 1 discharge holes drilled in the introduction holes are not aligned in the radial direction After discharging at a polymer temperature of 292 ° C. from a die having a separation band width W = 24 mm in two ridges, it is cooled by an annular cooling device, taken up at a speed of 4020 m / min after applying an oil agent, and then wound up at 4000 m / min. As a result, a polyester ultrafine fiber of 80 dtex and 192 filaments was obtained. As shown in Table 1, good results were obtained with respect to yarn breakage during spinning and Worcester spots of the obtained ultrafine fibers.

実施例4
実施例1と同様のポリエステルペレットを実施例1と同様に乾燥、溶融し、図4に示す紡糸口金を用い、口金外径D1=125mm、紡糸口金最外周径D2=100mm、ポリマー導入孔径D3=6.0mm、吐出孔群のPCDD4=5.0mm、ポリマー導入孔の列間隔L=8mm、2列環状配列、1導入孔あたり5吐出孔、総吐出孔数300で、1導入孔に穿孔された吐出孔が半径方向に並んでいない、1山である口金からポリマー温度292℃で吐出した後、環状冷却装置にて冷却し、油剤付与後4020m/分の速度で引き取り、続いて4000m/分で巻き取ることにより167dtex、300フィラメントのポリエステル極細繊維を得た。紡糸の際の糸切れおよび得られた極細繊維のウースター斑は表1に示すとおり良好な結果が得られた。
Example 4
Polyester pellets similar to those in Example 1 were dried and melted in the same manner as in Example 1, and using the spinneret shown in FIG. 4, the outer diameter D1 = 125 mm of the spinneret, the outermost peripheral diameter D2 = 100 mm of the spinneret, and the diameter D3 of the polymer introduction hole = 3 6.0mm, discharge hole group PCDD4 = 5.0mm, polymer introduction hole row interval L = 8mm, two rows annular array, 5 discharge holes per introduction hole, total number of discharge holes 300, 1 introduction hole drilled The discharge holes are not arranged in the radial direction, and are discharged from a single base at a polymer temperature of 292 ° C., then cooled by an annular cooling device, taken up at a speed of 4020 m / min after applying the oil, and subsequently 4000 m / min. Was wound to obtain a polyester ultrafine fiber of 167 dtex, 300 filaments. As shown in Table 1, good results were obtained with respect to yarn breakage during spinning and Worcester spots of the obtained ultrafine fibers.

比較例1
実施例1と同様のポリエステルペレットを実施例1と同様に乾燥、溶融し、口金外径D1=65mm、紡糸口金最外周径D2=45mm、ポリマー導入孔径D3=4.0mm、吐出孔群のPCDD4=3.0mm、ポリマー導入孔の列間隔L=5mm、3列環状配列、1導入孔あたり4吐出孔、総吐出孔数192で、1導入孔に穿孔された吐出孔が半径方向に並んでいない、1山である口金からポリマー温度292℃で吐出した後、環状冷却装置にて冷却し、油剤付与後4020m/分の速度で引き取り、続いて4000m/分で巻き取ることにより80dtex、192フィラメントのポリエステル極細繊維を得た。表2に示すとおり、紡糸の際の糸切れが多く、また得られた極細繊維のウースター斑も悪化した。
Comparative Example 1
The same polyester pellets as in Example 1 were dried and melted in the same manner as in Example 1, and the nozzle outer diameter D1 = 65 mm, the spinneret outermost diameter D2 = 45 mm, the polymer introduction hole diameter D3 = 4.0 mm, and the PCDD4 of the discharge hole group = 3.0 mm, polymer introduction hole row interval L = 5 mm, 3 rows annular arrangement, 4 discharge holes per introduction hole, total discharge hole number 192, discharge holes perforated in one introduction hole are aligned in the radial direction After being discharged from a single base at a polymer temperature of 292 ° C., cooled by an annular cooling device, taken up at a speed of 4020 m / min after applying the oil, and then wound up at 4000 m / min to obtain 80 dtex, 192 filament Polyester microfiber was obtained. As shown in Table 2, there were many yarn breaks during spinning, and Worcester spots of the obtained ultrafine fibers were also deteriorated.

比較例2
実施例1と同様のポリエステルペレットを実施例1と同様に乾燥、溶融し、口金外径D1=75mm、紡糸口金最外周径D2=60mm、ポリマー導入孔径D3=4.0mm、吐出孔群のPCDD4=3.0mm、1列環状配列、1導入孔あたり4吐出孔、総吐出孔数192、1導入孔に穿孔された吐出孔が半径方向に並んでいない、2山で分離帯幅W=10mmであるで口金からポリマー温度292℃で吐出した後、環状冷却装置にて冷却し、油剤付与後4020m/分の速度で引き取り、続いて4000m/分で巻き取ることにより80dtex、96フィラメントのポリエステル極細繊維を得ようと試みたが、2山の糸条群を分割することが非常に困難であり巻き取り不可能であった。
Comparative Example 2
The same polyester pellets as in Example 1 were dried and melted in the same manner as in Example 1. The outer diameter D1 of the die D = 75 mm, the outermost diameter D2 of the spinneret D2 = 60 mm, the diameter D3 of the polymer introduction hole D3 = 4.0 mm, and the PCDD4 of the discharge hole group = 3.0 mm, 1 row annular arrangement, 4 discharge holes per introduction hole, total number of discharge holes 192, 1 discharge holes perforated in the radial direction are not aligned in the radial direction, separation band width W = 10 mm After being discharged from the die at a polymer temperature of 292 ° C., it is cooled by an annular cooling device, taken up at a speed of 4020 m / min after application of the oil, and subsequently wound up at 4000 m / min to obtain 80 dtex, 96 filament polyester extra fine An attempt was made to obtain a fiber, but it was very difficult to divide the two yarn groups, and winding was impossible.

比較例3
実施例1と同様のポリエステルペレットを実施例1と同様に乾燥、溶融し、口金外径D1=110mm、紡糸口金最外周径D2=88mm、ポリマー導入孔径D3=3.0mm、吐出孔群のPCDD4=2.4mm、ポリマー導入孔の列間隔L=5mm、8列環状配列、1導入孔あたり3吐出孔、総吐出孔数384、1導入孔に穿孔された吐出孔が半径方向に並んでいない、2山で分離帯幅W=14mmであるで口金からポリマー温度292℃で吐出した後、環状冷却装置にて冷却し、油剤付与後4020m/分の速度で引き取り、続いて4000m/分で巻き取ることにより80dtex、192フィラメントのポリエステル極細繊維を得た。表2に示すとおり、紡糸の際の糸切れが多く、得られた極細繊維のウースター斑も悪化した。
Comparative Example 3
Polyester pellets similar to those in Example 1 were dried and melted in the same manner as in Example 1. The nozzle outer diameter D1 = 110 mm, the spinneret outermost diameter D2 = 88 mm, the polymer introduction hole diameter D3 = 3.0 mm, and the PCDD4 of the discharge hole group = 2.4 mm, polymer introduction hole row interval L = 5 mm, 8-row annular arrangement, 3 discharge holes per introduction hole, total number of discharge holes 384, 1 discharge holes drilled in the introduction holes are not aligned in the radial direction The separation width W is 14 mm in two ridges. After discharging from the die at a polymer temperature of 292 ° C., it is cooled by an annular cooling device, taken up at a speed of 4020 m / min after applying the oil, and then wound at 4000 m / min. As a result, a polyester fine fiber of 80 dtex and 192 filaments was obtained. As shown in Table 2, there were many yarn breaks during spinning, and Worcester spots of the obtained ultrafine fibers were also deteriorated.

比較例4
実施例1と同様のポリエステルペレットを実施例1と同様に乾燥、溶融し、口金外径D1=110mm、紡糸口金最外周径D2=88mm、ポリマー導入孔径D3=4.0mm、吐出孔群のPCDD4=3.8mm、ポリマー導入孔の列間隔L=6mm、5列環状配列、1導入孔あたり6吐出孔、総吐出孔数384、1導入孔に穿孔された吐出孔が半径方向に並んでいない、2山で分離帯幅W=14mmであるで口金からポリマー温度292℃で吐出した後、環状冷却装置にて冷却し、油剤付与後4020m/分の速度で引き取り、続いて4000m/分で巻き取ることにより80dtex、192フィラメントのポリエステル極細繊維を得た。表2に示すとおり、紡糸の際の糸切れが多く、得られた極細繊維のウースター斑も悪化した。
Comparative Example 4
The same polyester pellets as in Example 1 were dried and melted in the same manner as in Example 1, and the outer diameter D1 of the nozzle D1 = 110 mm, the outermost diameter D2 of the spinneret D88 = 88 mm, the diameter D3 of the polymer introduction hole D3 = 4.0 mm, and the PCDD4 of the discharge hole group = 3.8 mm, polymer introduction hole row interval L = 6 mm, 5 rows annular array, 6 discharge holes per introduction hole, total number of discharge holes 384, 1 discharge holes drilled in the introduction holes are not aligned in the radial direction The separation width W is 14 mm in two ridges. After discharging from the die at a polymer temperature of 292 ° C., it is cooled by an annular cooling device, taken up at a speed of 4020 m / min after applying the oil, and then wound at 4000 m / min. As a result, a polyester fine fiber of 80 dtex and 192 filaments was obtained. As shown in Table 2, there were many yarn breaks during spinning, and Worcester spots of the obtained ultrafine fibers were also deteriorated.

比較例5
実施例1と同様のポリエステルペレットを実施例1と同様に乾燥、溶融し、口金外径D1=110mm、紡糸口金最外周径D2=88mm、ポリマー導入孔径D3=5.0mm、吐出孔群のPCDD4=2.2mm、ポリマー導入孔の列間隔L=6mm、5列環状配列、1導入孔あたり4吐出孔、総吐出孔数384、1導入孔に穿孔された吐出孔が半径方向に並んでいない、2山で分離帯幅W=14mmであるで口金からポリマー温度292℃で吐出した後、環状冷却装置にて冷却し、油剤付与後4020m/分の速度で引き取り、続いて4000m/分で巻き取ることにより80dtex、192フィラメントのポリエステル極細繊維を得た。表2に示すとおり、紡糸の際の糸切れが多く、得られた極細繊維のウースター斑も悪化した。
Comparative Example 5
The same polyester pellets as in Example 1 were dried and melted in the same manner as in Example 1, and the nozzle outer diameter D1 = 110 mm, the spinneret outermost diameter D2 = 88 mm, the polymer introduction hole diameter D3 = 5.0 mm, and the PCDD4 of the discharge hole group = 2.2 mm, polymer introduction hole row spacing L = 6 mm, 5 rows annular arrangement, 4 discharge holes per introduction hole, total number of discharge holes 384, 1 discharge holes drilled in the introduction holes are not aligned in the radial direction The separation width W is 14 mm in two ridges. After discharging from the die at a polymer temperature of 292 ° C., it is cooled by an annular cooling device, taken up at a speed of 4020 m / min after applying the oil, and then wound at 4000 m / min. As a result, a polyester fine fiber of 80 dtex and 192 filaments was obtained. As shown in Table 2, there were many yarn breaks during spinning, and Worcester spots of the obtained ultrafine fibers were also deteriorated.

比較例6
実施例1と同様のポリエステルペレットを実施例1と同様に乾燥、溶融し、口金外径D1=110mm、紡糸口金最外周径D2=60mm、ポリマー導入孔径D3=4.0mm、吐出孔群のPCDD4=3.0mm、ポリマー導入孔の列間隔L=7mm、2列環状配列、1導入孔あたり4吐出孔、総吐出孔数144、1導入孔に穿孔された吐出孔が半径方向に並んでいない、2山で分離帯幅W=12(mm)であるで口金からポリマー温度292℃で吐出した後、環状冷却装置にて冷却し、油剤付与後4020m/分の速度で引き取り、続いて4000m/分で巻き取ることにより60dtex、72フィラメントのポリエステル極細繊維を得た。表2に示すとおり、紡糸の際の糸切れが多く、得られた極細繊維のウースター斑も悪化した。
Comparative Example 6
The same polyester pellets as in Example 1 were dried and melted in the same manner as in Example 1. The nozzle outer diameter D1 = 110 mm, the spinneret outermost diameter D2 = 60 mm, the polymer introduction hole diameter D3 = 4.0 mm, and the PCDD4 of the discharge hole group = 3.0 mm, polymer introduction hole row interval L = 7 mm, two rows annular arrangement, 4 discharge holes per introduction hole, total number of discharge holes 144, 1 discharge holes perforated in the introduction hole are not aligned in the radial direction The separation band width W is 12 (mm) at two ridges, and after discharging from the die at a polymer temperature of 292 ° C., it is cooled by an annular cooling device, taken up at a speed of 4020 m / min. The polyester extra fine fiber of 60 dtex and 72 filaments was obtained by winding in minutes. As shown in Table 2, there were many yarn breaks during spinning, and Worcester spots of the obtained ultrafine fibers were also deteriorated.

比較例7
実施例1と同様のポリエステルペレットを実施例1と同様に乾燥、溶融し、口金外径D1=110mm、紡糸口金最外周径D2=88mm、ポリマー導入孔径D3=4.0mm、吐出孔群のPCDD4=3.0mm、ポリマー導入孔の列間隔L=7mm、3列環状配列、1導入孔あたり4吐出孔、総吐出孔数288、1導入孔に穿孔された吐出孔が半径方向に並んでいる、2山で分離帯幅W=16mmであるで口金からポリマー温度292℃で吐出した後、環状冷却装置にて冷却し、油剤付与後4020m/分の速度で引き取り、続いて4000m/分で巻き取ることにより80dtex、144フィラメントのポリエステル極細繊維を得た。表2に示すとおり、紡糸の際の糸切れが多く、得られた極細繊維のウースター斑も悪化した。
Comparative Example 7
The same polyester pellets as in Example 1 were dried and melted in the same manner as in Example 1, and the outer diameter D1 of the nozzle D1 = 110 mm, the outermost diameter D2 of the spinneret D88 = 88 mm, the diameter D3 of the polymer introduction hole D3 = 4.0 mm, and the PCDD4 of the discharge hole group = 3.0 mm, polymer introduction hole row spacing L = 7 mm, three rows annular arrangement, four discharge holes per introduction hole, total number of discharge holes 288, and discharge holes perforated in the introduction hole are arranged in the radial direction The separation band width W is 16 mm in two ridges, and after discharging from the die at a polymer temperature of 292 ° C., it is cooled by an annular cooling device, taken up at a speed of 4020 m / min after applying the oil, and then wound at 4000 m / min. By taking, a polyester ultrafine fiber of 80 dtex, 144 filaments was obtained. As shown in Table 2, there were many yarn breaks during spinning, and Worcester spots of the obtained ultrafine fibers were also deteriorated.

Figure 2007009368
Figure 2007009368

Figure 2007009368
Figure 2007009368

本発明の紡糸口金の一例を示す図である。It is a figure which shows an example of the spinneret of this invention. 本発明の紡糸口金の他の一例を示す図である。It is a figure which shows another example of the spinneret of this invention. 本発明の実施例4の紡糸口金の導入孔部分の拡大の一例を示す図である。It is a figure which shows an example of the expansion of the introduction hole part of the spinneret of Example 4 of this invention. 従来の紡糸口金の一例を示す図である。It is a figure which shows an example of the conventional spinneret.

符号の説明Explanation of symbols

1:導入孔
2:吐出孔
3:分離帯
D1:口金外径
D2:紡糸口金最外周径
D3:ポリマー導入孔径
D4:吐出孔群のPCD
L:ポリマー導入孔の列間隔
θ:1つの群内の吐出孔同士において、各吐出孔と口金中心を結んだ線同士のなす角度
W:分離帯の幅
1: Introduction hole 2: Discharge hole 3: Separation zone D1: Outer diameter D2: Spinneret outermost diameter D3: Polymer introduction diameter D4: PCD of discharge hole group
L: Row spacing of polymer introduction holes θ: Angle formed by lines connecting each discharge hole and the center of the nozzle in each group of discharge holes W: Width of separation band

Claims (6)

下記(1)〜(8)
(1)外径D1が75〜125mmである円形の口金であって、
(2)前記口金には、ポリマー導入孔が円周状に2〜6列配列され、
(3)前記口金中心とポリマー導入孔の中心とを結ぶ線を半径として、その最大値の2倍で定義されるD2(mm)と口金の外径D1(mm)との関係が、
0.6×D1≦D2≦0.85×D1
を満足し、
(4)前記ポリマー導入孔の列間隔L(mm)と導入孔径D3(mm)との関係が、
1.3×D3≦L≦6×D3
を満足し、
(5)前記1つのポリマー導入孔に対して吐出孔が2〜8孔穿孔され、
(6)前記1つのポリマー導入孔に穿孔された吐出孔を1つの群として、ポリマー導入孔の中心と吐出孔の中心とを結ぶ線を半径として、その最大値の2倍で定義されるD4(mm)とポリマー導入孔径D3(mm)との比、
D4/D3=0.5〜0.9
を満足し、
(7)さらに、吐出孔の総数が120〜600孔であるとともに、
(8)1つの群内の吐出孔が口金中心に対して半径方向に並ばないように配列されている、
の要件を具備することを特徴とする紡糸口金。
Following (1)-(8)
(1) A circular base having an outer diameter D1 of 75 to 125 mm,
(2) In the base, 2 to 6 rows of polymer introduction holes are arranged circumferentially,
(3) The relationship between D2 (mm) defined by twice the maximum value and the outer diameter D1 (mm) of the die, with the line connecting the center of the die and the center of the polymer introduction hole as the radius,
0.6 × D1 ≦ D2 ≦ 0.85 × D1
Satisfied,
(4) The relationship between the row interval L (mm) of the polymer introduction holes and the introduction hole diameter D3 (mm)
1.3 × D3 ≦ L ≦ 6 × D3
Satisfied,
(5) 2 to 8 discharge holes are drilled with respect to the one polymer introduction hole,
(6) D4 defined by twice the maximum value with the discharge hole perforated in the one polymer introduction hole as one group, and a line connecting the center of the polymer introduction hole and the center of the discharge hole as a radius (Mm) and the ratio of the polymer introduction hole diameter D3 (mm),
D4 / D3 = 0.5-0.9
Satisfied,
(7) Furthermore, the total number of ejection holes is 120 to 600 holes,
(8) The discharge holes in one group are arranged so as not to be aligned in the radial direction with respect to the center of the die.
A spinneret characterized by having the following requirements.
1つの群内の吐出孔が同心円状に穿孔されていることを特徴とする請求項1に記載の紡糸口金   The spinneret according to claim 1, wherein the discharge holes in one group are formed concentrically. 2山用の分離帯が設けられていることを特徴とする請求項1または2に記載の紡糸口金。   The spinneret according to claim 1 or 2, wherein a separation band for two mountains is provided. 分離帯幅W(mm)=12〜24であることを特徴とする請求項3に記載の紡糸口金。   The spinneret according to claim 3, wherein the separation band width W (mm) = 12 to 24. 請求項1〜4のいずれか1項に記載の口金を用い、かつ環状冷却装置を用いて紡糸することを特徴とする極細繊維の製造方法。   A method for producing ultrafine fibers, wherein the base according to any one of claims 1 to 4 is used, and spinning is performed using an annular cooling device. 合成繊維が、フィラメント数が60〜600、単糸繊度が0.2〜1.0dtexの極細繊維であることを特徴とする請求項5に記載の極細繊維の製造方法。   The method for producing an ultrafine fiber according to claim 5, wherein the synthetic fiber is an ultrafine fiber having 60 to 600 filaments and a single yarn fineness of 0.2 to 1.0 dtex.
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JP2009074192A (en) * 2007-09-19 2009-04-09 Toray Ind Inc Method and apparatus for producing thermoplastic fiber
JP2010196219A (en) * 2009-02-27 2010-09-09 Toray Ind Inc Method for producing extremely fine synthetic fiber comprising multiple fiber yarn, and device for producing the same
CN103526311A (en) * 2013-10-18 2014-01-22 王振海 Multi-row synthetic tow cooling device
EP3800283A3 (en) * 2019-10-02 2021-04-14 TMT Machinery, Inc. Yarn production system

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JP2009074192A (en) * 2007-09-19 2009-04-09 Toray Ind Inc Method and apparatus for producing thermoplastic fiber
JP2010196219A (en) * 2009-02-27 2010-09-09 Toray Ind Inc Method for producing extremely fine synthetic fiber comprising multiple fiber yarn, and device for producing the same
CN103526311A (en) * 2013-10-18 2014-01-22 王振海 Multi-row synthetic tow cooling device
EP3800283A3 (en) * 2019-10-02 2021-04-14 TMT Machinery, Inc. Yarn production system

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