JP2007007427A - ゴルフボール用配合物 - Google Patents

Info

Publication number

JP2007007427A

JP2007007427A JP2006182914A JP2006182914A JP2007007427A JP 2007007427 A JP2007007427 A JP 2007007427A JP 2006182914 A JP2006182914 A JP 2006182914A JP 2006182914 A JP2006182914 A JP 2006182914A JP 2007007427 A JP2007007427 A JP 2007007427A

Authority

JP

Japan

Prior art keywords

acid

core

golf ball

boron

salts

Prior art date

2005-07-01

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Pending

Links

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• 239000000203 mixture Substances 0.000 title claims abstract description 70
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• 239000004814 polyurethane Substances 0.000 claims abstract description 11
• 229920003226 polyurethane urea Polymers 0.000 claims abstract description 3
• -1 sulfur-substituted borate Chemical class 0.000 claims description 246
• 150000003839 salts Chemical class 0.000 claims description 91
• 239000010410 layer Substances 0.000 claims description 82
• 239000002253 acid Substances 0.000 claims description 78
• 239000000654 additive Substances 0.000 claims description 76
• 150000001875 compounds Chemical class 0.000 claims description 69
• 229910052751 metal Inorganic materials 0.000 claims description 41
• 239000002184 metal Substances 0.000 claims description 41
• 238000007906 compression Methods 0.000 claims description 35
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• 239000003999 initiator Substances 0.000 claims description 30
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• 229920005601 base polymer Polymers 0.000 claims description 28
• 125000004432 carbon atom Chemical group C* 0.000 claims description 25
• ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 22
• 229910052796 boron Inorganic materials 0.000 claims description 22
• 150000001768 cations Chemical class 0.000 claims description 22
• 238000009472 formulation Methods 0.000 claims description 22
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 20
• 229920002554 vinyl polymer Polymers 0.000 claims description 20
• 239000000945 filler Substances 0.000 claims description 19
• 150000007513 acids Chemical class 0.000 claims description 17
• 229910052717 sulfur Inorganic materials 0.000 claims description 17
• 229910052799 carbon Inorganic materials 0.000 claims description 15
• 235000014113 dietary fatty acids Nutrition 0.000 claims description 15
• 125000006575 electron-withdrawing group Chemical group 0.000 claims description 15
• 239000000194 fatty acid Substances 0.000 claims description 15
• 229930195729 fatty acid Natural products 0.000 claims description 15
• UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims description 15
• 150000004665 fatty acids Chemical class 0.000 claims description 14
• 229910052760 oxygen Inorganic materials 0.000 claims description 14
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
• 239000012792 core layer Substances 0.000 claims description 12
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
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• 125000005842 heteroatom Chemical group 0.000 claims description 10
• 239000011593 sulfur Substances 0.000 claims description 10
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• 229910052755 nonmetal Chemical class 0.000 claims description 7
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• 229920001021 polysulfide Polymers 0.000 claims description 6
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• 239000004327 boric acid Substances 0.000 claims description 5
• 150000002391 heterocyclic compounds Chemical class 0.000 claims description 5
• 125000002524 organometallic group Chemical group 0.000 claims description 5
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
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• AGLSQWBSHDEAHB-UHFFFAOYSA-N azane;boric acid Chemical class N.OB(O)O AGLSQWBSHDEAHB-UHFFFAOYSA-N 0.000 claims description 4
• ZADPBFCGQRWHPN-UHFFFAOYSA-N boronic acid Chemical compound OBO ZADPBFCGQRWHPN-UHFFFAOYSA-N 0.000 claims description 4
• 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 4
• 125000005031 thiocyano group Chemical group S(C#N)* 0.000 claims description 4
• UYANAUSDHIFLFQ-UHFFFAOYSA-N borinic acid Chemical compound OB UYANAUSDHIFLFQ-UHFFFAOYSA-N 0.000 claims description 3
• 125000004434 sulfur atom Chemical group 0.000 claims description 3
• 239000007787 solid Substances 0.000 abstract description 15
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• 230000036314 physical performance Effects 0.000 abstract 1
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• 125000000217 alkyl group Chemical group 0.000 description 26
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• 239000005062 Polybutadiene Substances 0.000 description 21
• 125000005843 halogen group Chemical group 0.000 description 21
• 239000000543 intermediate Substances 0.000 description 20
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• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 18
• 150000002978 peroxides Chemical class 0.000 description 18
• 239000005060 rubber Substances 0.000 description 18
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• 229910052736 halogen Inorganic materials 0.000 description 17
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• NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 12
• 229910052708 sodium Inorganic materials 0.000 description 12
• 239000011734 sodium Substances 0.000 description 12
• 229910052725 zinc Inorganic materials 0.000 description 12
• 239000011701 zinc Substances 0.000 description 12
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 11
• 239000005977 Ethylene Substances 0.000 description 11
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 11
• 235000018417 cysteine Nutrition 0.000 description 11
• XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 11
• 125000000962 organic group Chemical group 0.000 description 11
• 229920001187 thermosetting polymer Polymers 0.000 description 11
• NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
• XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 10
• 150000001336 alkenes Chemical class 0.000 description 10
• 239000003795 chemical substances by application Substances 0.000 description 10
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• 229920001519 homopolymer Polymers 0.000 description 9
• 229910052749 magnesium Inorganic materials 0.000 description 9
• 239000011777 magnesium Substances 0.000 description 9
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
• PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
• 229910052757 nitrogen Inorganic materials 0.000 description 9
• 150000007524 organic acids Chemical class 0.000 description 9
• 239000011669 selenium Substances 0.000 description 9
• 125000001424 substituent group Chemical group 0.000 description 9
• 239000004416 thermosoftening plastic Substances 0.000 description 9
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
• XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
• 229910052791 calcium Inorganic materials 0.000 description 8
• 239000011575 calcium Substances 0.000 description 8
• 229910052744 lithium Inorganic materials 0.000 description 8
• 238000002156 mixing Methods 0.000 description 8
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• ZKZBPNGNEQAJSX-UHFFFAOYSA-N selenocysteine Natural products [SeH]CC(N)C(O)=O ZKZBPNGNEQAJSX-UHFFFAOYSA-N 0.000 description 8
• LLMLGZUZTFMXSA-UHFFFAOYSA-N 2,3,4,5,6-pentachlorobenzenethiol Chemical compound SC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl LLMLGZUZTFMXSA-UHFFFAOYSA-N 0.000 description 7
• FDKWRPBBCBCIGA-UWTATZPHSA-N D-Selenocysteine Natural products [Se]C[C@@H](N)C(O)=O FDKWRPBBCBCIGA-UWTATZPHSA-N 0.000 description 7
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
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• 230000005540 biological transmission Effects 0.000 description 7
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
• 229910052739 hydrogen Inorganic materials 0.000 description 7
• 239000007788 liquid Substances 0.000 description 7
• 229910052700 potassium Inorganic materials 0.000 description 7
• 235000016491 selenocysteine Nutrition 0.000 description 7
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• 125000001931 aliphatic group Chemical group 0.000 description 6
• 150000001993 dienes Chemical class 0.000 description 6
• 238000000034 method Methods 0.000 description 6
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• 150000002898 organic sulfur compounds Chemical class 0.000 description 6
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
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• XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
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• ZMCWFMOZBTXGKI-UHFFFAOYSA-N tritert-butyl borate Chemical compound CC(C)(C)OB(OC(C)(C)C)OC(C)(C)C ZMCWFMOZBTXGKI-UHFFFAOYSA-N 0.000 description 1
• 125000002221 trityl group Chemical class [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
• 150000003658 tungsten compounds Chemical class 0.000 description 1
• ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten(VI) oxide Inorganic materials O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 1
• 229920001567 vinyl ester resin Polymers 0.000 description 1
• 239000005050 vinyl trichlorosilane Substances 0.000 description 1
• ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
• UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
• NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
• 239000000080 wetting agent Substances 0.000 description 1
• 239000002023 wood Substances 0.000 description 1
• 239000011667 zinc carbonate Substances 0.000 description 1
• 229910000010 zinc carbonate Inorganic materials 0.000 description 1
• 235000004416 zinc carbonate Nutrition 0.000 description 1
• 239000011592 zinc chloride Substances 0.000 description 1
• 235000005074 zinc chloride Nutrition 0.000 description 1
• NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
• 229910000368 zinc sulfate Inorganic materials 0.000 description 1
• 229960001763 zinc sulfate Drugs 0.000 description 1
• CITILBVTAYEWKR-UHFFFAOYSA-L zinc trifluoromethanesulfonate Chemical compound [Zn+2].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F CITILBVTAYEWKR-UHFFFAOYSA-L 0.000 description 1
• PIMBTRGLTHJJRV-UHFFFAOYSA-L zinc;2-methylprop-2-enoate Chemical compound [Zn+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O PIMBTRGLTHJJRV-UHFFFAOYSA-L 0.000 description 1
• AJVBIUVVPVHGGJ-UHFFFAOYSA-L zinc;3-sulfanylpropanoate Chemical compound [Zn+2].[O-]C(=O)CCS.[O-]C(=O)CCS AJVBIUVVPVHGGJ-UHFFFAOYSA-L 0.000 description 1
• RIUORJCWAHCMSA-UHFFFAOYSA-L zinc;4-aminobenzenesulfonate Chemical compound [Zn+2].NC1=CC=C(S([O-])(=O)=O)C=C1.NC1=CC=C(S([O-])(=O)=O)C=C1 RIUORJCWAHCMSA-UHFFFAOYSA-L 0.000 description 1
• NTUATFLSTOSLCJ-UHFFFAOYSA-L zinc;benzenesulfinate;dihydrate Chemical compound O.O.[Zn+2].[O-]S(=O)C1=CC=CC=C1.[O-]S(=O)C1=CC=CC=C1 NTUATFLSTOSLCJ-UHFFFAOYSA-L 0.000 description 1
• JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
• MFMKGXZULQONRI-UHFFFAOYSA-L zinc;diiodate Chemical compound [Zn+2].[O-]I(=O)=O.[O-]I(=O)=O MFMKGXZULQONRI-UHFFFAOYSA-L 0.000 description 1
• ZTUVUXVSZXNSCL-UHFFFAOYSA-L zinc;hydrogen sulfite Chemical compound [Zn+2].OS([O-])=O.OS([O-])=O ZTUVUXVSZXNSCL-UHFFFAOYSA-L 0.000 description 1
• CHNQZRKUZPNOOH-UHFFFAOYSA-J zinc;manganese(2+);n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[Zn+2].[S-]C(=S)NCCNC([S-])=S.[S-]C(=S)NCCNC([S-])=S CHNQZRKUZPNOOH-UHFFFAOYSA-J 0.000 description 1
• KMNUDJAXRXUZQS-UHFFFAOYSA-L zinc;n-ethyl-n-phenylcarbamodithioate Chemical compound [Zn+2].CCN(C([S-])=S)C1=CC=CC=C1.CCN(C([S-])=S)C1=CC=CC=C1 KMNUDJAXRXUZQS-UHFFFAOYSA-L 0.000 description 1
• DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
• 150000007934 α,β-unsaturated carboxylic acids Chemical group 0.000 description 1