JP2007002265A5 - - Google Patents

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Publication number
JP2007002265A5
JP2007002265A5 JP2006275936A JP2006275936A JP2007002265A5 JP 2007002265 A5 JP2007002265 A5 JP 2007002265A5 JP 2006275936 A JP2006275936 A JP 2006275936A JP 2006275936 A JP2006275936 A JP 2006275936A JP 2007002265 A5 JP2007002265 A5 JP 2007002265A5
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JP
Japan
Prior art keywords
average molecular
molecular weight
center
weight
particle
Prior art date
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Pending
Application number
JP2006275936A
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Japanese (ja)
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JP2007002265A (en
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Publication date
Application filed filed Critical
Priority to JP2006275936A priority Critical patent/JP2007002265A/en
Priority claimed from JP2006275936A external-priority patent/JP2007002265A/en
Publication of JP2007002265A publication Critical patent/JP2007002265A/en
Publication of JP2007002265A5 publication Critical patent/JP2007002265A5/ja
Pending legal-status Critical Current

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Claims (5)

粒子の表面から中心に向かって5等分した表面から1/5までを形成する表面部分の重量平均分子量が、前記中心から前記表面に向かって中心から1/5までを形成する中心部分の重量平均分子量より高く、
前記表面部分のゲルパーミエーションクロマトグラフ法のチャートが二山又はショルダーを有することを特徴とするスチレン系発泡性樹脂粒子。
The weight of the central portion forming the surface portion forming 1/5 from the surface divided into 5 equal parts from the surface of the particle to the center is 1/5 from the center toward the surface. Higher than average molecular weight,
A styrenic foamable resin particle, wherein the surface portion has a gel permeation chromatographic chart having two peaks or a shoulder.
前記中心部分の重量平均分子量が200,000〜300,000の範囲であり、
前記表面部分の重量平均分子量が300,000〜450,000の範囲であり、
前記表面部分の重量平均分子量が、前記中心部分の重量平均分子量に対して、1.2倍以上大きいことを特徴とする請求項1記載のスチレン系発泡性樹脂粒子。
The central portion has a weight average molecular weight in the range of 200,000 to 300,000;
The surface portion has a weight average molecular weight in the range of 300,000-450,000,
2. The styrenic expandable resin particle according to claim 1, wherein a weight average molecular weight of the surface portion is 1.2 times or more larger than a weight average molecular weight of the center portion.
粒子の表面から中心に向かって5等分した表面から1/5までを形成する表面部分の重量平均分子量が、前記中心から前記表面に向かって中心から1/5までを形成する中心部分の重量平均分子量より高く、
前記表面部分の、GPC/MALLS法により測定したlog(R.M.S半径)とlog(MW)との相関式の傾きが、0.53以下であることを特徴とするスチレン系発泡性樹脂粒子。
The weight of the center part forming the surface part formed from the surface of the particle equally divided into 5 to 1/5 from the surface to 1/5 from the center to the surface from the center to 1/5. Higher than average molecular weight,
It said surface portion, the slope of the correlation equation between log measured by GPC / MALLS method (R.M.S radius) and log (MW) is a styrene-based resin foam, characterized in that at 0.53 or less particle.
請求項1、請求項2又は請求項3記載のスチレン系発泡性樹脂粒子を発泡させて得られることを特徴とするスチレン系発泡ビーズ。 A styrene foam bead obtained by foaming the styrene foam resin particle according to claim 1, claim 2 or claim 3 . 請求項4記載のスチレン系発泡ビーズを成形させて得られることを特徴とするスチレン系発泡成形品。

A styrene foam-molded article obtained by molding the styrene foam beads according to claim 4 .

JP2006275936A 2002-05-08 2006-10-10 Expandable styrene resin particles, expandable beads, and foamed article Pending JP2007002265A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006275936A JP2007002265A (en) 2002-05-08 2006-10-10 Expandable styrene resin particles, expandable beads, and foamed article

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2002132623 2002-05-08
JP2002242015 2002-08-22
JP2002381173 2002-12-27
JP2006275936A JP2007002265A (en) 2002-05-08 2006-10-10 Expandable styrene resin particles, expandable beads, and foamed article

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP2003129891A Division JP3926289B2 (en) 2002-05-08 2003-05-08 Styrenic expandable resin particles, expanded beads and expanded molded products

Publications (2)

Publication Number Publication Date
JP2007002265A JP2007002265A (en) 2007-01-11
JP2007002265A5 true JP2007002265A5 (en) 2007-03-15

Family

ID=37688138

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006275936A Pending JP2007002265A (en) 2002-05-08 2006-10-10 Expandable styrene resin particles, expandable beads, and foamed article

Country Status (1)

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JP (1) JP2007002265A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5824263B2 (en) * 2010-07-16 2015-11-25 株式会社カネカ Expandable thermoplastic resin particles

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02173130A (en) * 1988-12-27 1990-07-04 Idemitsu Petrochem Co Ltd Styrene-based foam
JP3573473B2 (en) * 1993-10-13 2004-10-06 旭化成ケミカルズ株式会社 Styrene resin for foam
JP3054017B2 (en) * 1993-12-27 2000-06-19 積水化成品工業株式会社 Expandable styrene polymer particles
JP3474995B2 (en) * 1996-02-15 2003-12-08 鐘淵化学工業株式会社 Method for producing expandable styrene polymer particles
JP3729560B2 (en) * 1996-05-27 2005-12-21 旭化成ケミカルズ株式会社 Styrenic resin composition
JPH1135636A (en) * 1997-07-24 1999-02-09 Idemitsu Petrochem Co Ltd Styrene-based polymer having long-chain branched structure and its production
JP4401456B2 (en) * 1998-10-23 2010-01-20 ダイセル化学工業株式会社 Styrenic resin composition and molding sheet using the same
JP2001170945A (en) * 1999-12-20 2001-06-26 Sumitomo Chem Co Ltd Method for manufacturing thermoplastic resin foamed molded object

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