JP2007000696A - Porosity molded body - Google Patents
Porosity molded body Download PDFInfo
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- JP2007000696A JP2007000696A JP2005180581A JP2005180581A JP2007000696A JP 2007000696 A JP2007000696 A JP 2007000696A JP 2005180581 A JP2005180581 A JP 2005180581A JP 2005180581 A JP2005180581 A JP 2005180581A JP 2007000696 A JP2007000696 A JP 2007000696A
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- 239000011148 porous material Substances 0.000 claims abstract description 52
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 37
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 33
- 238000005192 partition Methods 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 11
- 239000000919 ceramic Substances 0.000 claims description 10
- 230000000149 penetrating effect Effects 0.000 claims description 6
- 229920003002 synthetic resin Polymers 0.000 claims description 4
- 239000000057 synthetic resin Substances 0.000 claims description 4
- 230000002093 peripheral effect Effects 0.000 claims description 3
- 229910052573 porcelain Inorganic materials 0.000 claims description 2
- 239000002781 deodorant agent Substances 0.000 abstract description 2
- 230000003115 biocidal effect Effects 0.000 abstract 1
- 239000012815 thermoplastic material Substances 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 230000001877 deodorizing effect Effects 0.000 description 8
- 239000000843 powder Substances 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 3
- 235000019645 odor Nutrition 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 241000237858 Gastropoda Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000013032 photocatalytic reaction Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
Images
Abstract
Description
本発明は多孔成形体に係り、セラミック等成形体に多数の細孔が、同一方向を向いて貫通形成され、細孔の薄隔壁に酸化チタン層が形成された多孔成形体に関する。 The present invention relates to a porous molded body, and more particularly to a porous molded body in which a large number of pores are formed penetratingly in the same direction and a titanium oxide layer is formed on a thin partition wall of the pores.
従来、多孔セラミックとして、例えば椰子殻活性炭、木炭等が知られ、消臭材として使用されている。 Conventionally, coconut shell activated carbon, charcoal, and the like are known as porous ceramics, and are used as deodorants.
前記椰子殻活性炭、木炭は形状が不特定で、前後に気流が通過しない。また細片や粉末となり、取扱いに困難という難点がある。また汚れが付着すると除去しにくいという難点がある。この発明は、任意の形状にすることができ、消臭・殺菌作用があり、美的に掛置することができ、また水洗をしても消臭・殺菌効果が変らない、多孔成形体を提供することを目的としている。 The shape of the coconut shell activated carbon and charcoal is unspecified, and the airflow does not pass back and forth. In addition, it becomes a small piece or powder, which is difficult to handle. In addition, there is a drawback that it is difficult to remove if dirt adheres. The present invention provides a porous molded body which can be formed into any shape, has a deodorizing / sterilizing action, can be aesthetically placed, and does not change the deodorizing / sterilizing effect even when washed with water. The purpose is to do.
この発明の多孔成形体は、薄い隔壁を介して多数の貫通孔が形成された成形体細孔の薄隔壁に、酸化チタン層が形成された多孔成形体に係る。発明の具体的な内容は次の通りである。 The porous molded body of the present invention relates to a porous molded body in which a titanium oxide layer is formed on a thin partition wall of a molded body pore in which a large number of through holes are formed through a thin partition wall. The specific contents of the invention are as follows.
(1) 可塑性物に薄隔壁を介して、一方向へ向いて貫通する多数の細孔が形成されて、硬化された成形体細孔の薄隔壁に、酸化チタン層が形成されている多孔成形体。 (1) Porous molding in which a large number of pores penetrating in one direction are formed in a plastic material through thin partition walls, and a titanium oxide layer is formed on the thin partition walls of the cured molded product pores. body.
(2) 前記細孔は、孔形の大きさが貫通方向へ段階的に大小違差されて貫通されていること、を特徴とする請求項１に記載された多孔成形体。 (2) The porous molded body according to claim 1, wherein the pores are penetrated in such a manner that the size of the pore shape is gradually changed in the penetration direction.
(3) 酸化チタンを含有する可塑性物を押出成形し、薄隔壁を介して、一方向へ向いて貫通する多数の細孔が形成され、硬化された成形体からなる、多孔成形体。 (3) A porous molded body comprising a cured molded body formed by extruding a plastic material containing titanium oxide and forming a plurality of pores penetrating in one direction through thin partition walls.
(4) 前記可塑性物は陶土で、成形体はセラミックである、前記(1)〜(3)のいずれかに記載された多孔成形体。 (4) The porous molded body according to any one of (1) to (3), wherein the plastic is ceramic clay and the molded body is ceramic.
(5) 前記可塑性物は、合成樹脂である、前記(1)〜(3)のいずれかに記載された多孔成形体。 (5) The porous molded body according to any one of (1) to (3), wherein the plastic is a synthetic resin.
(6) 前記成形体には、薄隔壁の前面に色模様が形成されている、前記(1)〜(5)のいずれかに記載された多孔成形体。 (6) The porous molded body according to any one of (1) to (5), wherein the molded body has a color pattern formed on a front surface of a thin partition wall.
(7) 前記成形体には、主細孔の配列の中に、大きさの異なった異細孔による孔模様が形成されている、前記(1)〜(6)のいずれかに記載された多孔成形体。 (7) The molded body described in any one of (1) to (6) above, wherein a hole pattern with different pores having different sizes is formed in the array of main pores. Porous molded body.
(8) 前記成形体は、靴底中敷形に形成されている、前記(1)〜(6)のいずれかに記載された多孔成形体。 (8) The porous molded body according to any one of (1) to (6), wherein the molded body is formed in a shoe insole shape.
(9) 前記成形体は、具象物形に形成されている、前記(1)〜(8)のいずれかに記載された多孔成形体。 (9) The porous molded body according to any one of (1) to (8), wherein the molded body is formed into a concrete shape.
(10) 前記成形体の外周部に、額枠が装着されている、前記(1)〜(9)のいずれかに記載された多孔成形体。 (10) The porous molded body according to any one of (1) to (9), wherein a frame is attached to an outer peripheral portion of the molded body.
(11) 前記成形体は、多角立方状に形成され、袋に多数収容されている、前記(1)〜(6)のいずれかに記載された多孔成形体。 (11) The porous molded body according to any one of (1) to (6), wherein the molded body is formed in a polygonal cubic shape and is contained in a large number of bags.
本発明によると、次のような効果がある。 The present invention has the following effects.
(1) 請求項１に記載された発明の多孔成形体は、成形体に多数形成された細孔の薄隔壁に、酸化チタン層が形成されており、細孔は同一方向を向いているので、空気の流通性に優れ、空気との接触面積が広く、例えばトイレや犬小屋などに置くとき、空気に含まれている臭気は、細孔薄隔壁の酸化チタンの触媒作用によって分解され、短時間で消臭される。また風呂場などに置くとき、カビ菌の除菌をすることができる。 (1) The porous molded body of the invention described in claim 1 has a titanium oxide layer formed on a thin partition wall of pores formed in a large number in the molded body, and the pores are directed in the same direction. For example, when placed in a toilet or kennel, the odor contained in the air is decomposed by the catalytic action of titanium oxide in the fine pores, and is short. Deodorized over time. Also, when placed in a bathroom, etc., it is possible to sterilize mold fungi.
(2) 請求項２に記載された発明の多孔成形体は、細孔の大きさが、前から後にかけて途中で大きさが大小に変化しているので、隣同士の細孔が連通しているところもあり、薄隔壁の面積が大きいので、酸化チタン層の付着面積も大きく、消臭効果も大きい。
(2) In the porous molded body of the invention described in
(3) 請求項３に記載された発明の多孔成形体は、酸化チタンを含有する可塑性物を押出成形して形成するので、全域に平均的に酸化チタンが分布しており、行程が簡略される。
(3) Since the porous molded body of the invention described in
(4) 請求項４に記載された発明の多孔成形体は、陶土で製造されるので、セラミックとなり、長年の使用にも美しく耐用される。
(4) Since the porous molded body of the invention described in
(5) 請求項５に記載された発明の多孔成形体は、合成樹脂製であるので、落下させても破損しにくく、耐久性に優れている。
(5) Since the porous molded body of the invention described in
(6) 請求項６に記載された発明の多孔成形体は、成形体に色模様が形成されているので、消臭作用があり、装飾品として使用することができる。
(6) The porous molded body of the invention described in
(7) 請求項７に記載された発明の多孔成形体は、主たる細孔の配列の中に、大きさの異った異細孔による孔模様が形成されているので、模様がはっきりしていて、１行程で孔模様を表現することができる。
(7) Since the porous molded body of the invention described in
(8) 請求項８に記載された発明の多孔成形体は、成形体が靴底中敷形に形成されているので、使用後の靴の中に入れておくと、靴中の消臭をさせることができる。 (8) In the porous molded body of the invention described in claim 8, since the molded body is formed in a shoe insole shape, deodorizing in the shoe is prevented if it is placed in the shoe after use. Can be made.
(9) 請求項９に記載された発明の多孔成形体は、成形体が具象物形に形成されているので、装飾置物として使用して、室内の消臭をすることができる。 (9) In the porous molded body of the invention described in claim 9, since the molded body is formed in a concrete shape, it can be used as a decorative figurine to deodorize the room.
(10) 請求項１０に記載された発明の多孔成形体は、成形体の外周部に、額枠が装着されているので、壁面などに掛吊ることができる。 (10) The porous molded body of the invention described in claim 10 can be hung on a wall surface or the like because a frame is attached to the outer peripheral portion of the molded body.
(11) 請求項１１に記載された発明の多孔成形体は、成形体が、略サイコロ状の多角立方形に形成されているので、植木鉢の側などに置くと、酸化チタンの酸によって、ナメクジ、ダンゴ虫などの排除をすることができる。また袋に多数収容されるとき、多孔成形体を壁などに掛吊したり、犬猫の寝床などにおくことができる。また立沸しの浴槽の中に入れて、湯垢や水の汚れを除去することができる。 (11) In the porous molded body of the invention described in claim 11, since the molded body is formed in a substantially dice-shaped polygonal cubic shape, when placed on the side of a flower pot or the like, the slug is formed by the acid of titanium oxide. , Dango insects can be eliminated. Moreover, when many are accommodated in a bag, a porous molded body can be hung on a wall or placed on a bed of a dog or cat. It can also be placed in a standing bath to remove scales and water stains.
多孔成形体の、同方向を向く多数の細孔内の薄隔壁に酸化チタン層を形成させる。 A titanium oxide layer is formed on thin partition walls in a large number of pores facing in the same direction of the porous molded body.
本願発明の実施の形態例を、図面を参照して説明する。図１は本発明に係る多孔成形体の斜視図、図２は要部拡大平面図である。 Embodiments of the present invention will be described with reference to the drawings. FIG. 1 is a perspective view of a porous molded body according to the present invention, and FIG. 2 is an enlarged plan view of a main part.
図１において、多孔成形体(1)は、可塑性物の一っとして陶土が選択され、陶土を押出成形により、薄隔壁(2)を介して、１方向を向く多数の細孔(3)を並列形成した棒体とし、これを任意の厚さに裁断して、板体の成形体(5)に形成されている。板体の面積は、例えば１辺５ｃｍ〜２０ｃｍなど、成形機の大きさによって選択される。細孔(3)は細かく多数なので、細孔(3)の薄隔壁(2)の総面積は広い。 In FIG. 1, for the porous molded body (1), porcelain clay is selected as one of the plastic materials, and the porcelain clay is extruded to form a large number of pores (3) facing one direction through the thin partition wall (2). The rods formed in parallel are cut into an arbitrary thickness and formed into a plate body (5). The area of the plate is selected according to the size of the molding machine, for example, 5 cm to 20 cm on a side. Since the pores (3) are fine and numerous, the total area of the thin partition walls (2) of the pores (3) is large.
板体の裁断板厚は、用途によって２ｍｍ〜３ｃｍ等任意に設定することができる。板体の正面形状は、図１では方形であるが、三角、丸、動物形、その他の具象形等、任意に設定される。薄隔壁(2)の厚みは薄い方が好ましいが、素材が陶土であるため、崩れないように、例えば０．５ｍｍ〜１mmの範囲で設定される。 The cutting plate thickness of the plate can be arbitrarily set such as 2 mm to 3 cm depending on the application. The front shape of the plate is rectangular in FIG. 1, but may be arbitrarily set such as a triangle, a circle, an animal shape, and other concrete shapes. The thickness of the thin partition wall (2) is preferably thin. However, since the material is porcelain, it is set within a range of, for example, 0.5 mm to 1 mm so as not to collapse.
細孔(3)は、表面積を広くするために細かい方が好ましいが、１ｍｍ〜２ｍｍ等任意に設定される。細孔(3)の正面形状は、図１では方形であるが、例えば丸孔、三角形、六角形、ハート形、千鳥形など任意に設定される。 The fine pores (3) are preferably fine in order to increase the surface area, but are arbitrarily set such as 1 mm to 2 mm. The front shape of the pore (3) is a square in FIG. 1, but may be arbitrarily set, for example, a round hole, a triangle, a hexagon, a heart shape, or a staggered shape.
板体に形成された後、素焼をして後、酸化チタン分散溶液の中に浸して、細孔(3)内の薄隔壁(2)表面に、酸化チタン微粉末層(4)が、図２に示すように形成されてセラミックの多孔成形体(1)に形成される。このままでも使用することができるが、剥離しないようにするためには、２通りの手段が使用される。 After being formed into a plate body, baked and then immersed in a titanium oxide dispersion solution, a fine titanium oxide powder layer (4) is formed on the surface of the thin partition walls (2) in the pores (3). 2 is formed into a ceramic porous molded body (1). Although it can be used as it is, two means are used in order not to peel off.
１っは、前記酸化チタン微粉末分散溶液を付着させて後、窯炉で１８０℃〜８００℃の加熱をする。あるいは、酸化チタン微粉末分散溶液中にアクリル樹脂を添加しておき、付着させてからアクリル樹脂を架橋反応させて、硬化させる。酸化チタン層(4)の厚みは１５μ〜２０μで十分である。
あるいは、酸化チタン微粉末を陶土に混合して練り、押出し成形をする。
First, after the titanium oxide fine powder dispersion solution is attached, heating is performed at 180 ° C. to 800 ° C. in a kiln. Alternatively, an acrylic resin is added to the titanium oxide fine powder dispersion solution and allowed to adhere, and then the acrylic resin is subjected to a crosslinking reaction and cured. A thickness of 15 to 20 μ is sufficient for the titanium oxide layer (4).
Alternatively, titanium oxide fine powder is mixed with porcelain clay and kneaded and extruded.
酸化チタンは、正方結晶系のアナターゼ型（低温系）とルチル型（高温系）が、３００ｎｍ〜４００ｎｍの紫外線により、光触媒反応を持ち、強い親水性と強い酸化力とをもっている。その結果、触媒作用により、空気中の臭気を分解し、また殺菌、防汚作用を有している。使用についてはアナターゼ型が好ましい。 Titanium oxide is a tetragonal crystalline anatase type (low temperature type) and rutile type (high temperature type) having a photocatalytic reaction with ultraviolet rays of 300 nm to 400 nm, and has strong hydrophilicity and strong oxidizing power. As a result, the catalytic action decomposes odors in the air, and also has a sterilizing and antifouling action. The anatase type is preferred for use.
酸化チタン分散液は、例えばアナターゼ型微粉末を、アルコールと水の溶液中に分散させたものが使用される。酸化チタン分散液は、噴霧器による噴射、刷毛塗布、侵漬等により多孔成形体に付着させ、乾燥させる。 As the titanium oxide dispersion, for example, an anatase type fine powder dispersed in a solution of alcohol and water is used. The titanium oxide dispersion is adhered to the porous molded body by spraying with a sprayer, applying a brush, dipping, or the like, and dried.
図３は、セラミックの成形体(5)の周囲に、額枠(6)を固定した壁掛けとしての多孔成形体(1)の正面図、図４はその左側面を示す。額枠(6)は、前後枠(6a)(6b)の間に、成形体(5)が、細孔(3)を前後に向けて挟装されている。額枠(6)の上部には、掛吊部(6c)が形成されて、釘などに掛吊ることができる。 FIG. 3 is a front view of a porous molded body (1) as a wall hanging with a frame (6) fixed around a ceramic molded body (5), and FIG. 4 shows the left side surface thereof. In the frame (6), the molded body (5) is sandwiched between the front and rear frames (6a) and (6b) with the pores (3) facing front and rear. A hanging part (6c) is formed on the upper part of the frame (6) and can be hung on a nail or the like.
図４に示す状態で、多孔成形体(1)を、例えばトイレの壁に掛けると、突体(6d)が壁面に当り、壁面と額枠(6)の間に間隙が生じる。すると、成形体(5)の前面と背面とでは、気圧が異なる（気温の高い方が気圧が低い）ので、気圧の高い方から低い方へと、細孔(3)を通って空気が流通して、気流の中に含まれている臭気物質が、細孔(3)内の薄隔壁(2)における、酸化チタンの触媒作用によって分解されて、消臭される。 When the porous molded body (1) is hung on, for example, a toilet wall in the state shown in FIG. 4, the protrusion (6d) hits the wall surface, and a gap is generated between the wall surface and the frame (6). Then, since the atmospheric pressure is different between the front and back of the molded body (5) (the higher the temperature, the lower the atmospheric pressure), air flows through the pores (3) from the higher pressure to the lower pressure. The odorous substance contained in the airflow is decomposed and deodorized by the catalytic action of titanium oxide in the thin partition walls (2) in the pores (3).
酸化チタンは、光エネルギーによって、空気中の水分や酸素から、強力の酸化分解力を持つ働きを作り出し、酸化力で殺菌作用もあるので、空気中に浮遊しているカビ菌、その他の菌も殺菌される。また空気中のガスなどの汚れ物質も、酸化チタンの触媒作用によって分解される。また、酸化チタンの親水性により、空気中の微細な埃も吸着される。 Titanium oxide creates a function with strong oxidative degradation power from moisture and oxygen in the air by light energy, and also has bactericidal action with oxidizing power, so mold fungi and other bacteria floating in the air Sterilized. Also, dirt substances such as gas in the air are decomposed by the catalytic action of titanium oxide. Further, fine dust in the air is also adsorbed due to the hydrophilic property of titanium oxide.
定期的に多孔成形体(１)を水洗すると、酸化チタンの親水性により、成形体(5)に付着している汚れは、水だけで除去されて、元通りに使用することができる。再使用するときは、直射日光に当てて、細孔(3)に紫外線をよく当てる。 When the porous molded body (1) is periodically washed with water, the dirt adhering to the molded body (5) is removed only with water due to the hydrophilic property of titanium oxide, and can be used as it is. When reusing it, expose it directly to direct sunlight and UV light to the pores (3).
図５は、実施例２を示す多孔成形体(１)の正面図である。前例と同じ部位には同じ符号を付して説明を省略する。この実施例２は、成形体(5)の前面に、色模様(7)が形成されている。該色模様(7)は、例えば陶器用の顔料で、手描き、型使用吹きつけ、捺染（含シルクスクリーン）等で染付けて焼付ける。これによって、トイレなどの壁に掛けて、飾額となり和みを与えることができる。ここでいう色模様(7)とは、文字も含むものとする。 5 is a front view of a porous molded body (1) showing Example 2. FIG. The same parts as those in the previous example are denoted by the same reference numerals and description thereof is omitted. In Example 2, a color pattern (7) is formed on the front surface of the molded body (5). The color pattern (7) is, for example, a pigment for ceramics, and is baked by hand drawing, spraying with a mold, dyeing by printing (including silk screen) or the like. As a result, it can be hung on the wall of a toilet or the like to become a decorative amount and to be softened. The color pattern (7) here includes characters.
図６は、実施例３を示す多孔成形体(１)の正面図である。前例と同じ部位には、同じ符号を付して説明を省略する。この実施例３は、成形体(5)の主たる細孔(3)の配列の中に、大きさの異なった異細孔(3a)が部分的に配列されて、孔模様(8)が形成されている。 6 is a front view of a porous molded body (1) showing Example 3. FIG. The same parts as those in the previous example are denoted by the same reference numerals and description thereof is omitted. In Example 3, different pores (3a) having different sizes are partially arranged in the arrangement of main pores (3) of the molded body (5) to form a hole pattern (8). Has been.
この異細孔(3a)の薄隔壁(2)にも酸化チタン層(4)が形成される。この孔模様(8)は、細孔(3)と同様に押出成形なので同時に形成することができ、コスト負担にならない。孔模様(8)は前記色模様(7)と組合わせることができる。 A titanium oxide layer (4) is also formed on the thin partition walls (2) having the different pores (3a). This hole pattern (8) can be formed at the same time because it is extrusion-molded like the hole (3), and does not impose a cost burden. The hole pattern (8) can be combined with the color pattern (7).
図７は実施例４を示す多孔成形体(１)の正面図である。前例と同じ部位には、同じ符号を付して説明を省略する。この実施例３は、額枠(6)の前後面に格子(6e)をつけたものである。
これによって、セラミックの成形体(5)に衝撃が加えられても、割れにくくなる。従って、犬小屋の中に掛吊ったり、猫の寝床の下に敷いても破損されにくい。
7 is a front view of a porous molded body (1) showing Example 4. FIG. The same parts as those in the previous example are denoted by the same reference numerals and description thereof is omitted. In Example 3, a lattice (6e) is attached to the front and rear surfaces of the frame (6).
Thus, even when an impact is applied to the ceramic molded body (5), it becomes difficult to break. Therefore, it is difficult to break even if hung in a kennel or laid under a cat's bed.
図８は、実施例５を示す消臭具の平面図である。前例と同じ部位には同じ符号を付して説明を省略する。この実施例４は、多孔成形体(1)を靴底中敷の形状に形成したものである。厚みは５ｍｍ前後である。これは、外から帰って来て脱いだ靴の中に、納れておくものである。図７で判るように、底面は凹凸が形成されている。 FIG. 8 is a plan view of the deodorizing tool showing the fifth embodiment. The same parts as those in the previous example are denoted by the same reference numerals and description thereof is omitted. In Example 4, the porous molded body (1) is formed in the shape of a shoe insole. The thickness is around 5 mm. This is to be stored in the shoes that came back from the outside and removed. As can be seen in FIG. 7, the bottom surface is uneven.
これによって、靴の中の臭気が、細孔(3)内における薄隔壁(2)の酸化チタンの触媒作用によって分解されて、消臭される。押出成形なので、この形で長く押し出されたものを、適宜の厚みに裁断されて焼成される。 As a result, the odor in the shoe is decomposed and deodorized by the catalytic action of titanium oxide in the thin partition walls (2) in the pores (3). Since it is extrusion molding, what was extruded long in this shape is cut into an appropriate thickness and fired.
図９は、実施例６を示す多孔成形体の正面図である。前例と同じ部位には同じ符号を付して説明を省略する。この実施例５は、成形体(5)を魚形の置物に形成された多孔成形体(1)である。表面には、単色あるいは多彩色模様を形成することができる。あるいは細孔(3)をウロコ形に形成することができる。置物としては、動物形、乗物形、その他具象物形が選択される。 FIG. 9 is a front view of a porous molded body showing Example 6. The same parts as those in the previous example are denoted by the same reference numerals and description thereof is omitted. Example 5 is a porous molded body (1) in which the molded body (5) is formed into a fish-shaped figurine. A monochromatic or multicolored pattern can be formed on the surface. Alternatively, the pores (3) can be formed in a scale shape. As the figurine, an animal shape, a vehicle shape, and other concrete shapes are selected.
図１０は、実施例７を示す多孔成形体の正面図である。前例と同じ部位には同じ符号を付して説明を省略する。この実施例７は、多孔成形体(1)が小さな略サイコロ状の、多角立方体に形成されているものである。大きさは、例えば１辺１ｃｍ〜３ｃｍなど任意である。着色をしておき、多色の組合わせにすることができる。 10 is a front view of a porous molded body showing Example 7. FIG. The same parts as those in the previous example are denoted by the same reference numerals and description thereof is omitted. In Example 7, the porous molded body (1) is formed into a small, substantially dice-shaped polygonal cube. The size is arbitrary, for example, 1 cm to 3 cm per side. It can be colored and combined into multiple colors.
この多角立方体状成形体(5)からなる多孔成形体(1)は、例えば植木鉢の側に置くと、酸化チタン層(4)の酸化力によってナメクジ、ダンゴ虫などを排除することができる。
また籠や袋に入れて、犬小屋に吊ったり、下駄箱の中、押入の中、トイレなどに吊る。また浴槽の中にいれて、立沸しの湯の湯垢よごれを除去することができる。
When the porous molded body (1) composed of the polygonal cubic shaped body (5) is placed on the side of a flower pot, for example, slugs, snails and the like can be eliminated by the oxidizing power of the titanium oxide layer (4).
Also, put it in a bag or bag and hang it in a kennel, in a clog box, in a closet, or in a toilet. You can also put it in the bathtub to remove dirt from the boiling water.
図１１は実施例８を示す多孔成形体の正面図、図１２は額枠をつけた正面図である。前例と同じ部位には同じ符号を付して説明を省略する。
この実施例８における成形体(5)は、大きさの異なる細孔(3)が、網目状に広がり、かつ前から後方向にかけて、大きさの異なる細孔(3)が重なって前後に貫通しているので、隣同士の細孔(3)が部分的に連通しており、あたかも網を数枚重ねたように、左右上下方向にも細孔(3)が貫通形成されている。
FIG. 11 is a front view of a porous molded body showing Example 8, and FIG. 12 is a front view with a frame. The same parts as those in the previous example are denoted by the same reference numerals and description thereof is omitted.
In the molded body (5) in Example 8, the pores (3) having different sizes spread in a network shape, and the pores (3) having different sizes overlap from the front to the rear, and penetrated in the front-rear direction. As a result, the adjacent pores (3) partially communicate with each other, and the pores (3) are formed to penetrate in the horizontal and vertical directions as if several nets are stacked.
これによって、細孔(3)の薄隔壁(2)の面積は著しく広くなり、薄隔壁(2)に酸化チタン層(4)が形成されるとき、消臭効果が大きくなる。この実施例８の多孔成形体(1)は、正面も凹凸になるため、楕円形などにするとき、踵用の垢すり具にすることができ、酸化チタン層(4)の触媒作用により、殺菌性に優れて、不潔になりにくい。 As a result, the area of the thin partition walls (2) of the pores (3) is remarkably wide, and the deodorizing effect is increased when the titanium oxide layer (4) is formed on the thin partition walls (2). Since the front surface of the porous molded body (1) of Example 8 is also uneven, it can be used as an agate grinder when it is formed into an oval shape, etc., by the catalytic action of the titanium oxide layer (4), Excellent bactericidal properties and less filthy.
前記各実施例は可塑性物として、セラミックについて説明したが、陶土に変えて、合成樹脂による押出成形で多孔の成形体を形成し、細孔中に酸化チタン層を形成することができる。この場合、樹脂に酸化チタン粉末を混入して、細孔内に付着させて硬化させることができる。 In each of the above embodiments, ceramic was described as a plastic material, but instead of porcelain clay, a porous molded body can be formed by extrusion molding with a synthetic resin, and a titanium oxide layer can be formed in the pores. In this case, the titanium oxide powder can be mixed into the resin and adhered to the pores and cured.
なおこの発明は、前記実施例に限定されるものではなく、目的に沿って適宜設計変更をすることができる。可塑性物として、溶融ガラスを使用することができる。成形について、押出成形の他に型押成形も当然にできる。各実施例の部分を適宜組合わせることができる。 The present invention is not limited to the above-described embodiment, and can be appropriately changed in design according to the purpose. Molten glass can be used as the plastic material. As for molding, in addition to extrusion molding, embossing can naturally be performed. The parts of the respective embodiments can be appropriately combined.
本発明は、ペット用の消臭具としても使用することができる。 The present invention can also be used as a deodorizing tool for pets.
(1)多孔成形体
(2)薄隔壁
(3)細孔
(4)酸化チタン層
(5)成形体
(6)額枠
(6a)前枠
(6b)後枠
(6c)掛吊部
(6d)突体
(6e)格子
(7)色模様
(8)孔模様
(1) Porous molded body
(2) Thin partition
(3) Pore
(4) Titanium oxide layer
(5) Molded body
(6) Frame
(6a) Front frame
(6b) Rear frame
(6c) Hanging part
(6d) Projection
(6e) lattice
(7) Color pattern
(8) Hole pattern
Claims (11)
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| Application Number | Priority Date | Filing Date | Title |
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| JP2005180581A JP4937534B2 (en) | 2005-06-21 | 2005-06-21 | Porous molded body |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005180581A JP4937534B2 (en) | 2005-06-21 | 2005-06-21 | Porous molded body |
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| Publication Number | Publication Date |
|---|---|
| JP2007000696A true JP2007000696A (en) | 2007-01-11 |
| JP4937534B2 JP4937534B2 (en) | 2012-05-23 |
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| Application Number | Title | Priority Date | Filing Date |
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| JP2005180581A Expired - Fee Related JP4937534B2 (en) | 2005-06-21 | 2005-06-21 | Porous molded body |
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| JP2018086263A (en) * | 2016-11-24 | 2018-06-07 | 株式会社 シリコンプラス | Photocatalysis carrier filter and fitting type air purifier |
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| JP4937534B2 (en) | 2012-05-23 |
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