JP4937534B2 - Porous molded body - Google Patents
Porous molded body Download PDFInfo
- Publication number
- JP4937534B2 JP4937534B2 JP2005180581A JP2005180581A JP4937534B2 JP 4937534 B2 JP4937534 B2 JP 4937534B2 JP 2005180581 A JP2005180581 A JP 2005180581A JP 2005180581 A JP2005180581 A JP 2005180581A JP 4937534 B2 JP4937534 B2 JP 4937534B2
- Authority
- JP
- Japan
- Prior art keywords
- molded body
- porous molded
- pores
- titanium oxide
- porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011148 porous material Substances 0.000 claims description 31
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 23
- 238000005192 partition Methods 0.000 claims description 20
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 19
- 239000000919 ceramic Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 241001465754 Metazoa Species 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 239000000843 powder Substances 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- 230000001877 deodorizing effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000000465 moulding Methods 0.000 description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 241000237858 Gastropoda Species 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000013032 photocatalytic reaction Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Catalysts (AREA)
Description
本発明は、多孔成形体に係り、セラミック等の成形体に、多数の細孔を同一方向に向けて貫通形成し、その薄隔壁面に酸化チタン層を形成した、消臭具としての多孔成形体に関する。 The present invention relates to a porous molded body, in which a large number of pores are formed through a molded body such as ceramic in the same direction, and a titanium oxide layer is formed on the surface of the thin partition wall. About the body.
従来、多孔セラミックとして、例えば椰子殻活性炭、木炭などが知られ、消臭材として使用されている。 Conventionally, coconut shell activated carbon, charcoal, and the like are known as porous ceramics, and are used as deodorants.
前記椰子殻活性炭や木炭は、形状が不定形であり、必ずしも気流が前後方向に通過しない。また容易に細片や粉末となり、取扱いが困難である。更に汚れが付着すると、除去しにくいという難点がある。
本発明は、任意の形状にすることができ、消臭・殺菌作用があり、美的に吊支することができ、また水洗をしても、消臭・殺菌効果が変ることのない、多孔成形体を提供することを目的としている。
The coconut shell activated carbon and charcoal have an indefinite shape, and airflow does not necessarily pass in the front-rear direction. Moreover, it becomes a fine piece and powder easily and is difficult to handle. Furthermore, when dirt adheres, there exists a difficulty that it is difficult to remove.
The present invention can be formed into an arbitrary shape, has a deodorizing / sterilizing action, can be aesthetically supported, and does not change its deodorizing / sterilizing effect even after washing with water. The purpose is to provide a body.
本発明の具体的な内容は、次の通りである。 The specific contents of the present invention are as follows.
(1)可塑性物質を押出成形して硬化させた成形板体において、薄隔壁を介して、細孔の配列の中に大きさの異なる細孔を配することにより孔模様を一定方向へ向けて貫通形成し、その薄隔壁面に酸化チタン層を形成した多孔成形体。 (1) In a molded plate obtained by extruding and curing a plastic material, the pore pattern is directed in a certain direction by arranging pores of different sizes in the pore array through thin partition walls. A porous molded body formed by penetrating and forming a titanium oxide layer on the surface of the thin partition wall.
(2)大きさの異なる細孔を網目状に連設した前記(1)に記載の多孔成形体。 ( 2 ) The porous molded body according to ( 1 ), wherein pores having different sizes are continuously arranged in a network.
(3)前記薄隔壁の前面に、陶器用顔料の焼付けにより色模様を形成した前記(1)又は(2)に記載の多孔成形体。 ( 3 ) The porous molded body according to (1) or (2) , wherein a color pattern is formed on the front surface of the thin partition wall by baking a ceramic pigment.
(4)前記成形板体を、内側に格子を有する額枠の各格子の間に嵌装して、掛吊り可能に形成した前記(1)〜(3)のいずれかに記載の多孔成形体。 ( 4 ) The porous molded body according to any one of (1) to ( 3 ), wherein the molded plate body is fitted between each grid of a frame having a grid on the inner side so as to be hung. .
(5)前記成形板体は、動物や、建造物から選択した形状の装飾用置物としてある前記(1)〜(4)のいずれかに記載の多孔成形体。 ( 5 ) The porous molded body according to any one of (1) to ( 4 ), wherein the molded plate body is an ornament for a shape selected from an animal or a building.
本発明によると、次のような効果が奏せられる。 According to the present invention, the following effects can be obtained.
前記(1)に記載の多孔成形体は、成形板体に多数形成された細孔の薄隔壁に、酸化チタン層が形成されており、細孔は同一方向を向いて貫通しているので、空気の流通性に優れ、空気との接触面積が大きく、例えばトイレや犬小屋などに置くと、空気に含まれている臭気は、細孔薄隔壁の酸化チタンの触媒作用によって分解され、短時間で消臭される。また風呂場等に置いて、カビ菌の除菌をすることができる。主たる細孔部分に、大きさの異なる異細孔を配して孔模様状としてあるので、模様が判然として装飾性に優れ、かつ1工程で孔模様を表現することができる。 The porous molded body according to the above (1) has a titanium oxide layer formed on a thin partition wall of pores formed on the molded plate body, and the pores penetrate in the same direction. Excellent air circulation and large contact area with air. For example, when placed in a toilet or kennel, the odor contained in the air is decomposed by the catalytic action of titanium oxide in the fine pore partition walls, and is short in time. Deodorized with. In addition, it can be sterilized by mold in a bathroom. Since different pores having different sizes are arranged in the main pore portion to form a hole pattern, the pattern is clearly excellent in decorativeness and can be expressed in one step .
前記(2)に記載の多孔成形体は、細孔が、大きさの異なる不定形の細孔であり、網目状に連結してあるので、網目模様として柔らかな感じとなる。 The porous molded body described in the above ( 2 ) has irregular pores having different sizes and is connected in a mesh shape, so that it feels soft as a mesh pattern.
前記(3)に記載の多孔成形体は、薄隔壁の前面に、陶器用顔料の焼付けにより色模様を形成してあるので、色落ちがなく、消臭作用があり、装飾品として使用することができる。 The porous molded body according to the above ( 3 ) has a color pattern formed on the front surface of the thin partition wall by baking a ceramic pigment, so there is no color fading and it has a deodorizing action and should be used as a decorative product. Can do.
前記(4)に記載の多孔成形体は、内側に格子を有する額枠の各格子の間に、成形板体をそれぞれ嵌装して、掛吊り可能に形成してあるので、成形板体の面積が小さくても、全体の面積を大として、任意の個所に吊支することができる。 The porous molded body described in ( 4 ) above is formed so that it can be suspended by fitting a molded plate body between each grid of a frame having a grid on the inside. Even if the area is small, the entire area can be made large and can be suspended at an arbitrary position.
前記(5)に記載の多孔成形体は、動物、建造物から選択した形状の装飾用置物としてあるので、室内に飾物として置き、室内の消臭をすることができる。 Since the porous molded body described in ( 5 ) above is a decorative ornament of a shape selected from animals and buildings, it can be placed in a room as a decoration and deodorized indoors.
本発明の実施の形態例を、図面を参照して説明する。 Embodiments of the present invention will be described with reference to the drawings.
図1において、多孔成形体(1)は、可塑性物質の一例である陶土を押出成形することにより、薄隔壁(2)を介して、前後方向を向く多数の大きさを異にする細孔(3)(3a)(3b)を並列配置した棒体を、任意の厚さに切断して、成形板体(6)としたものである。 In FIG. 1, a porous molded body (1) is formed by extruding porcelain, which is an example of a plastic material, to form a plurality of pores having different sizes in the front-rear direction via thin partition walls (2) ( 3) A rod body in which (3a) and (3b) are arranged in parallel is cut into an arbitrary thickness to obtain a molded plate body (6).
成形板体(6)の寸法は、例えば1辺5cm〜20cmなど、成形機の大きさによって選択される。細孔(3)(3a)(3b)は、細かであり多数あるので、その薄隔壁(2)の総面積は大である。成形板体(6)の主たる細孔(3)の配列の中に、大きさの異なる細孔(3a)(3b)を混在させて、孔模様(5)が形成されている。 The dimension of the molded plate body (6) is selected according to the size of the molding machine, for example, 5 cm to 20 cm per side. Since the pores (3), (3a), and (3b) are thin and many, the total area of the thin partition walls (2) is large. A hole pattern (5) is formed by mixing pores (3a) and (3b) having different sizes in the array of main pores (3) of the molded plate body (6).
成形板体(6)の厚さは、用途によって、2mm〜3cm等任意に設定することができる。成形板体(6)の正面形状は、図1では方形であるが、三角形、丸形、動物形、その他の具象形等が任意に選択される。
薄隔壁(2)の厚さは、薄い方が好ましいが、素材が陶土等の可塑性物質であるため、崩れないように、例えば0.5mm〜1mmの範囲で設定する。
The thickness of the molded plate (6) can be arbitrarily set, such as 2 mm to 3 cm, depending on the application. The front shape of the molded plate (6) is a square in FIG. 1, but a triangular shape, a round shape, an animal shape, other concrete shapes, and the like are arbitrarily selected.
The thickness of the thin partition wall (2) is preferably thinner, but is set in the range of 0.5 mm to 1 mm, for example, so that the material is a plastic material such as porcelain.
細孔(3)(3a)(3b)は、表面積を大とするために小さい方が好ましいが、例えば1mm〜2mm等任意に設定される。細孔(3)(3a)(3b)の正面形状は、図1では方形であるが、丸孔、三角形、六角形、ハート形、千鳥形など任意である。 The pores (3), (3a), and (3b) are preferably small in order to increase the surface area, but are arbitrarily set to 1 mm to 2 mm, for example. The front shape of the pores (3), (3a), and (3b) is a square in FIG. 1, but is arbitrary such as a round hole, a triangle, a hexagon, a heart shape, and a staggered shape.
成形板体(6)は、素焼をした後、酸化チタン分散溶液の中に浸して、細孔(3)(3a)(3b)内部の薄隔壁(2)の表面に、図2に示すように、酸化チタン微粉末層(4)を形成し、セラミックの多孔成形体(1)としてある。このままでも使用することができるが、剥離しないようにするためには、2通りの手段が採用される。 The molded plate body (6) is baked and then immersed in a titanium oxide dispersion solution, on the surface of the thin partition walls (2) inside the pores (3) (3a) (3b) as shown in FIG. Further, a titanium oxide fine powder layer (4) is formed to form a ceramic porous molded body (1). Although it can be used as it is, two means are employed in order to prevent peeling.
その1っは、前記酸化チタン微粉末分散溶液を付着させた後、窯炉において180℃〜800℃に加熱する。あるいは、酸化チタン微粉末分散溶液中にアクリル樹脂を添加しておき、付着させてからアクリル樹脂を架橋反応させて、硬化させる。酸化チタン層(4)の厚さは15μ〜20μで十分である。
酸化チタン微粉末を陶土に混合して練り、押出し成形することも出来る。
The first is that after the titanium oxide fine powder dispersion solution is adhered, it is heated to 180 ° C. to 800 ° C. in a kiln. Alternatively, an acrylic resin is added to the titanium oxide fine powder dispersion solution and allowed to adhere, and then the acrylic resin is subjected to a crosslinking reaction and cured. A thickness of 15 to 20 μ is sufficient for the titanium oxide layer (4).
Titanium oxide fine powder can be mixed with porcelain and kneaded and extruded.
酸化チタンは、正方結晶系のアナターゼ型(低温系)とルチル型(高温系)であれば、300nm〜400nmの紫外線によって光触媒反応をし、強い親水性と強い酸化力とを発揮する。この触媒作用により、空気中の臭気の分解や、殺菌、防汚作用が生じる。使用については、アナターゼ型が好ましい。 If titanium oxide is a tetragonal crystal type anatase type (low temperature type) and rutile type (high temperature type), it undergoes a photocatalytic reaction with ultraviolet rays of 300 nm to 400 nm and exhibits strong hydrophilicity and strong oxidizing power. This catalytic action causes decomposition, sterilization, and antifouling action of odors in the air. For use, the anatase type is preferred.
酸化チタン分散液としては、例えばアナターゼ型微粉末を、アルコールと水の溶液中に分散させたものを使用する。酸化チタン分散液は、噴霧器により噴射するか、刷毛塗布や、浸漬等により、多孔成形体(1)に付着させて乾燥させる。 As the titanium oxide dispersion, for example, an anatase type fine powder dispersed in a solution of alcohol and water is used. The titanium oxide dispersion is sprayed by a sprayer or attached to the porous molded body (1) by brush application, immersion, or the like, and dried.
図3は、多孔成形体(1)の周囲に嵌装した額枠(7)の左側面を示す。額枠(7)の、前後枠(7a)(7b)の間に、多孔成形体(1)が細孔(3)を前後に向けて挟装されている。額枠(7)の上部に形成した掛吊部(7c)を、釘等に掛吊ることができる。額枠(7)の背面上下には、突体(7d)が設けられている。 FIG. 3 shows the left side of the frame (7) fitted around the porous molded body (1). The porous molded body (1) is sandwiched between the front and rear frames (7a) and (7b) of the frame (7) with the pores (3) facing front and rear. The hanging part (7c) formed on the upper part of the frame (7) can be hung on a nail or the like. Projections (7d) are provided above and below the back of the frame (7).
図1に示す状態で、多孔成形体(1)を、例えばトイレの壁に掛けると、突体(7d)が壁面に当り、壁面と額枠(7)の間に間隙が生じる。すると、多孔成形体(1)の前面と背面とでは、気圧が異なる(気温の高い方が気圧が低い)ので、気圧の高い方から低い方へと、細孔(3)を通って空気が流通し、気流の中に含まれている臭気物質は、細孔(3)内の薄隔壁(2)における酸化チタンの触媒作用によって分解されて、消臭される。 In the state shown in FIG. 1, when the porous molded body (1) is hung on, for example, a toilet wall, the protrusion (7d) hits the wall surface, and a gap is generated between the wall surface and the frame (7). Then, since the atmospheric pressure is different between the front and back of the porous molded body (1) (the higher the temperature, the lower the atmospheric pressure), the air passes through the pores (3) from the higher pressure to the lower pressure. The odorous substance that flows and is contained in the airflow is decomposed and deodorized by the catalytic action of titanium oxide in the thin partition walls (2) in the pores (3).
酸化チタンは、光エネルギーによって、空気中の水分や酸素から、強力の酸化分解力を持つ働きを作り出し、酸化力で殺菌作用もあるので、空気中に浮遊しているカビ菌、その他の菌も殺菌される。
また空気中のガスなどの汚染物質も、酸化チタンの触媒作用によって分解される。更に、酸化チタンの親水性により、空気中の微細な埃も吸着される。
Titanium oxide creates a function with strong oxidative degradation power from moisture and oxygen in the air by light energy, and also has bactericidal action with oxidizing power, so mold fungi and other bacteria floating in the air Sterilized.
Also, pollutants such as gas in the air are decomposed by the catalytic action of titanium oxide. Furthermore, fine dust in the air is also adsorbed due to the hydrophilic property of titanium oxide.
定期的に多孔成形体(1)を水洗すると、多孔成形体(1)に付着している汚れは、酸化チタンの親水性により水だけで除去されて、元通りに使用することができる。再使用する時には、直射日光に晒して、細孔(3)(3a)(3b)に紫外線を充分に当てる。 When the porous molded body (1) is periodically washed with water, the dirt adhering to the porous molded body (1) is removed only by water due to the hydrophilic property of titanium oxide, and can be used as it is. When reusing it, expose it to direct sunlight and expose the pores (3), (3a), and (3b) to ultraviolet rays.
図4は、多孔成形体(1)の実施例2の正面図である。前例と同じ部位には、同じ符号を付して説明を省略する。この実施例2では、多孔成形体(1)の前面の薄隔壁(2)の表面に、色模様(8)を形成してある。色模様(8)は、例えば陶器用の顔料で、手描き、型使用吹付け、捺染(シルクスクリーンを含む)等で染付けて焼付けられる。 FIG. 4 is a front view of Example 2 of the porous molded body (1). The same parts as those in the previous example are denoted by the same reference numerals and description thereof is omitted. In Example 2, the color pattern (8) is formed on the surface of the thin partition wall (2) on the front surface of the porous molded body (1). The color pattern (8) is, for example, a ceramic pigment, and is printed by hand-drawing, spraying with a mold, printing (including silk screen), or the like.
これによって、多孔成形体(1)をトイレなどの壁に掛けると、飾額となり、和みを与えることができる。ここでいう色模様(8)とは、文字も含むものとする。この色模様(8)は、前記孔模様(5)と組合わせることができる。 Thus, when the porous molded body (1) is hung on a wall such as a toilet, it becomes a decorative amount and can be softened. The color pattern (8) here includes characters. This color pattern (8) can be combined with the hole pattern (5).
図5は、多孔成形体の実施例3の正面図である。前例と同じ部位には、同じ符号を付して説明を省略する。
この実施例3における成形板体(6)では、大きさの異なる細孔(3)(3a)(3b)が、網目状に広がり、かつ前面から後面方向にかけて、途中から大きさの異なる細孔(3)(3a)(3b)が重なって、前後に隣同士の細孔(3)(3a)(3b)が、部分的に連通して、あたかも網を数枚重ねたように見える。
FIG. 5 is a front view of Example 3 of the porous molded body. The same parts as those in the previous example are denoted by the same reference numerals and description thereof is omitted.
In the molded plate (6) in Example 3, the pores (3), (3a), (3b) having different sizes spread in a mesh shape, and the pores having different sizes from the middle from the front surface to the rear surface direction. (3) (3a) (3b) overlaps, and the adjacent pores (3) (3a) (3b) partially communicate with each other in the front and back, and it looks as if several nets are stacked.
これによって、細孔(3)(3a)(3b)の薄隔壁(2)の面積は著しく大となり、薄隔壁(2)に酸化チタン層(4)を形成すると、消臭効果が大きくなる。この実施例3の多孔成形体(1)の成形板体(6)は、正面も凹凸状になるため、踵の垢すり具等に使用することができる。また酸化チタン層(4)の触媒作用により、殺菌性に優れているので不潔になりにくい。 As a result, the area of the thin partition walls (2) of the pores (3), (3a), and (3b) is remarkably increased, and when the titanium oxide layer (4) is formed on the thin partition walls (2), the deodorizing effect is increased. Since the molded plate body (6) of the porous molded body (1) of Example 3 also has an uneven front surface, it can be used as a grime grinder. In addition, due to the catalytic action of the titanium oxide layer (4), it has excellent bactericidal properties and is not easily filthy.
図6は、多孔成形体の実施例4の正面図である。前例と同じ部位には、同じ符号を付して説明を省略する。図6において、額枠(7)の内側には、格子(7e)が設けられている。これによって、小型の成形板体(6)を、各格子(7e)の間に嵌装して用いることが出来る。 FIG. 6 is a front view of Example 4 of the porous molded body. The same parts as those in the previous example are denoted by the same reference numerals and description thereof is omitted. In FIG. 6, a lattice (7e) is provided inside the frame (7). Thus, a small molded plate (6) can be used by being fitted between the lattices (7e).
そのため、成形板体(6)の寸法が小さくても、全体として額枠(7)の面積を大とすることができる。また衝撃が加えられても、割れにくくなる。従って、例えば犬小屋の中に吊ったり、猫の寝床の下に敷いても、破損しにくい。 Therefore, even if the dimension of the molded plate body (6) is small, the area of the frame (7) can be increased as a whole. Even if an impact is applied, it becomes difficult to break. Therefore, for example, even if hung in a kennel or laid under a cat's bed, it is not easily damaged.
図7は、多孔成形体(1)の実施例5の斜視図である。前例と同じ部位には、同じ符号を付して説明を省略する。この実施例では、成形板体(6)を、魚形の置物に形成した多孔成形体(1)である。 FIG. 7 is a perspective view of Example 5 of the porous molded body (1). The same parts as those in the previous example are denoted by the same reference numerals and description thereof is omitted. In this embodiment, the molded plate body (6) is a porous molded body (1) formed into a fish-shaped figurine.
表面には、単色または多彩色模様を形成することができる。あるいは細孔(3)を、大きさの異なるウロコ形の孔模様にすることができる。置物としては、その他の動物形、建造物や乗物形、その他具象物形が選択される。 A single color or multicolor pattern can be formed on the surface. Alternatively, the pores (3) can be formed into a scale-shaped hole pattern having different sizes. As the figurine, other animal shapes, building and vehicle shapes, and other concrete shapes are selected.
多孔成形体(1)を、略サイコロ状として、例えば植木鉢の側に置いてナメクジ、ダンゴ虫などを排除することができ、靴の中に入れると脱臭することができる。
籠や袋に入れて、犬小屋内に吊ったり、下駄箱の中、押入の中、トイレなどに吊ることもできる。また浴槽の中に入れて、湯垢等を除去することができる。
The porous molded body (1) can be formed in a substantially dice shape, for example, placed on the side of a flower pot to eliminate slugs, snails, etc., and deodorized when placed in shoes.
You can hang it in a bag or bag and hang it in a doghouse, in a clog box, in a closet, or in a toilet. Moreover, it can put in a bathtub and can remove scales.
なお、本発明は、前記実施例に限定されるものではなく、目的に沿って適宜設計変更をすることができる。前記可塑性物質として、陶土に代えて、合成樹脂或いは溶融ガラスを使用することができる。成形については、押出成形の他に、型押成形も当然可能である。各実施例の部分を適宜組合わせることができる。 In addition, this invention is not limited to the said Example, A design change can be suitably performed according to the objective. As the plastic material, synthetic resin or molten glass can be used in place of the clay. As for molding, in addition to extrusion molding, embossing molding is naturally possible. The parts of the respective embodiments can be appropriately combined.
本発明による多孔成形体は、ペット用の消臭具としても使用することができる。 The porous molded body according to the present invention can also be used as a deodorizing tool for pets.
(1)多孔成形体
(2)薄隔壁
(3)(3a)(3b)細孔
(4)酸化チタン層
(5)孔模様
(6)成形板体
(7)額枠
(7a)前枠
(7b)後枠
(7c)掛吊部
(7d)突体
(7e)格子
(8)色模様
(1) Porous molded body
(2) Thin partition
(3) (3a) (3b) Pore
(4) Titanium oxide layer
(5) Hole pattern
(6) Molded plate
(7) Frame
(7a) Front frame
(7b) Rear frame
(7c) Hanging part
(7d) Projection
(7e) lattice
(8) Color pattern
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005180581A JP4937534B2 (en) | 2005-06-21 | 2005-06-21 | Porous molded body |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005180581A JP4937534B2 (en) | 2005-06-21 | 2005-06-21 | Porous molded body |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007000696A JP2007000696A (en) | 2007-01-11 |
JP4937534B2 true JP4937534B2 (en) | 2012-05-23 |
Family
ID=37686781
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2005180581A Expired - Fee Related JP4937534B2 (en) | 2005-06-21 | 2005-06-21 | Porous molded body |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4937534B2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5291982B2 (en) * | 2008-05-07 | 2013-09-18 | 国立大学法人三重大学 | Liquid junction and method for manufacturing the same |
JP6923918B2 (en) * | 2016-11-24 | 2021-08-25 | 株式会社 シリコンプラス | Photocatalyst-supported filter and mounted air purifier |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0354912U (en) * | 1989-10-02 | 1991-05-28 | ||
JP3247611B2 (en) * | 1996-04-26 | 2002-01-21 | 石原産業株式会社 | Hazardous substance remover and harmful substance removal method using the same |
JPH10309440A (en) * | 1997-05-12 | 1998-11-24 | Tomoji Sumiya | Purifying apparatus |
JPH11314022A (en) * | 1998-05-07 | 1999-11-16 | Japan Ceramics Kk | Photocatalytic deodorization filter and manufacture thereof |
JP2001046885A (en) * | 1999-08-06 | 2001-02-20 | Mitsubishi Heavy Ind Ltd | Honeycomb type catalyst |
JP2001058002A (en) * | 1999-08-23 | 2001-03-06 | Mitsubishi Paper Mills Ltd | Deodorant sheet and recordable deodorant sheet |
JP2001137661A (en) * | 1999-11-11 | 2001-05-22 | Mitsubishi Paper Mills Ltd | Method of manufacturing photocatalytic filter |
JP2002136811A (en) * | 2000-11-02 | 2002-05-14 | Ishihara Sangyo Kaisha Ltd | Photocatalyst deodorizing filter |
JP2002219316A (en) * | 2001-01-25 | 2002-08-06 | National House Industrial Co Ltd | Air cleaning member and method for manufacturing the same |
US7678439B2 (en) * | 2002-09-05 | 2010-03-16 | Ngk Insulators, Inc. | Honeycomb structure and die for forming honeycomb structure |
JP2004159727A (en) * | 2002-11-11 | 2004-06-10 | Seiji Kuwabara | Hair grooming implement |
JP4564733B2 (en) * | 2003-09-22 | 2010-10-20 | 株式会社フォレスティ峯岸 | Unglazed made of multiple porous clays and titanium dioxide |
-
2005
- 2005-06-21 JP JP2005180581A patent/JP4937534B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2007000696A (en) | 2007-01-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN205180007U (en) | Slidable formula cat lavatory | |
CN103553527B (en) | Diatom ooze powder and method for manufacturing environmental-friendly diatom ooze crafts | |
KR100755242B1 (en) | Prefabricated loess-tile | |
JP4937534B2 (en) | Porous molded body | |
KR100906608B1 (en) | Red Clay Tile for Sticking on The Wall and Manufacturing Method Thereof | |
JP6675500B2 (en) | Functional image tile and method of manufacturing the same | |
KR100539015B1 (en) | A Filter Sheet Having the Function of Sterilization and Deodorization for Electric Fan | |
WO1997032664A1 (en) | Molded product having photocatalytic function | |
JP4189074B2 (en) | Photocatalyst functional body | |
KR100798888B1 (en) | Loess interior decoration and the method | |
CN201019346Y (en) | Mildew resistant tatami mattress | |
KR100885607B1 (en) | Functional charcoal | |
KR20060101943A (en) | Lamp shade for lighting | |
KR102079175B1 (en) | Interior decoration sheet | |
KR200418067Y1 (en) | Functional sheet | |
KR200391918Y1 (en) | Deodorizer and dehumidifier in stalled of an antibacterial and aromatic function | |
KR100794715B1 (en) | Lamp shade for lighting | |
JPH09209208A (en) | Decorative article such as artificial flower bearing deodorizing function | |
JPH08333959A (en) | Fittings | |
JP3197196U (en) | Water absorbent mat | |
KR101121604B1 (en) | Composition for excrement treatment from pet animal | |
JP2003310423A (en) | Metal screen with air cleaning and cooling capacity | |
CN208870317U (en) | A kind of environmental friendly indoor moldproof, anti-odour PVC board | |
JP3102189U (en) | Photocatalyst titanium coating sheet structure | |
KR20140140406A (en) | Antibacterial insect net using hard charcoal |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080612 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20100714 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110802 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110922 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20111129 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120111 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120221 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120222 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150302 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |