JP2006525218A - 有機フィロシリケートナノ複合材料組成物の製造法 - Google Patents
有機フィロシリケートナノ複合材料組成物の製造法 Download PDFInfo
- Publication number
- JP2006525218A JP2006525218A JP2006506534A JP2006506534A JP2006525218A JP 2006525218 A JP2006525218 A JP 2006525218A JP 2006506534 A JP2006506534 A JP 2006506534A JP 2006506534 A JP2006506534 A JP 2006506534A JP 2006525218 A JP2006525218 A JP 2006525218A
- Authority
- JP
- Japan
- Prior art keywords
- organophyllosilicate
- concentrated
- wax
- oligomer
- substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 48
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 36
- 230000008569 process Effects 0.000 title claims abstract description 5
- 229910052615 phyllosilicate Inorganic materials 0.000 claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000000178 monomer Substances 0.000 claims abstract description 39
- 229920000642 polymer Polymers 0.000 claims abstract description 35
- 239000012065 filter cake Substances 0.000 claims abstract description 31
- 239000002002 slurry Substances 0.000 claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- -1 polypropylene Polymers 0.000 claims description 21
- 239000001993 wax Substances 0.000 claims description 19
- 238000001035 drying Methods 0.000 claims description 16
- 239000004743 Polypropylene Substances 0.000 claims description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- 229920001155 polypropylene Polymers 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 229920005862 polyol Polymers 0.000 claims description 8
- 150000003077 polyols Chemical class 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 6
- 238000004132 cross linking Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 238000001694 spray drying Methods 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 claims description 2
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 239000012170 montan wax Substances 0.000 claims description 2
- 229920005672 polyolefin resin Polymers 0.000 claims description 2
- 239000012178 vegetable wax Substances 0.000 claims description 2
- 238000007865 diluting Methods 0.000 claims 2
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- 239000011159 matrix material Substances 0.000 abstract description 6
- 239000004927 clay Substances 0.000 description 39
- 239000010408 film Substances 0.000 description 13
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 12
- 239000006185 dispersion Substances 0.000 description 12
- 239000012141 concentrate Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 10
- 229920000098 polyolefin Polymers 0.000 description 9
- 238000011010 flushing procedure Methods 0.000 description 7
- 230000002209 hydrophobic effect Effects 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 235000019270 ammonium chloride Nutrition 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 229920001684 low density polyethylene Polymers 0.000 description 6
- 239000004702 low-density polyethylene Substances 0.000 description 6
- 239000003760 tallow Substances 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 4
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 229910052901 montmorillonite Inorganic materials 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- XQRLCLUYWUNEEH-UHFFFAOYSA-L diphosphonate(2-) Chemical compound [O-]P(=O)OP([O-])=O XQRLCLUYWUNEEH-UHFFFAOYSA-L 0.000 description 3
- 210000004907 gland Anatomy 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 235000019809 paraffin wax Nutrition 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 235000019271 petrolatum Nutrition 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910021647 smectite Inorganic materials 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 229920005606 polypropylene copolymer Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920001054 Poly(ethylene‐co‐vinyl acetate) Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229920000362 Polyethylene-block-poly(ethylene glycol) Polymers 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- UYANAUSDHIFLFQ-UHFFFAOYSA-N borinic acid Chemical compound OB UYANAUSDHIFLFQ-UHFFFAOYSA-N 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 125000006182 dimethyl benzyl group Chemical group 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229940094522 laponite Drugs 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000006178 methyl benzyl group Chemical group 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920006113 non-polar polymer Polymers 0.000 description 1
- 229910000273 nontronite Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000004010 onium ions Chemical group 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 230000037050 permeability transition Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001713 poly(ethylene-co-vinyl alcohol) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polymerisation Methods In General (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/428,348 US7163972B2 (en) | 2003-05-02 | 2003-05-02 | Preparation of a concentrated organophyllosilicate and nanocomposite composition |
| PCT/IB2004/001275 WO2004096736A2 (en) | 2003-05-02 | 2004-04-28 | Preparation of organophyllosilicate nanocomposite compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006525218A true JP2006525218A (ja) | 2006-11-09 |
| JP2006525218A5 JP2006525218A5 (enExample) | 2007-06-21 |
Family
ID=33310383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006506534A Pending JP2006525218A (ja) | 2003-05-02 | 2004-04-28 | 有機フィロシリケートナノ複合材料組成物の製造法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7163972B2 (enExample) |
| EP (1) | EP1620503A4 (enExample) |
| JP (1) | JP2006525218A (enExample) |
| CN (1) | CN1780879A (enExample) |
| CA (1) | CA2523828A1 (enExample) |
| WO (1) | WO2004096736A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009534284A (ja) * | 2006-04-19 | 2009-09-24 | ザ・プロヴォスト，フェローズ・アンド・スカラーズ・オブ・ザ・カレッジ・オブ・ザ・ホーリー・アンド・アンディヴァイデッド・トリニティー・オブ・クイーン・エリザベス，ニア・ダブリン | 変性オルガノクレー |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060041048A1 (en) * | 2004-08-19 | 2006-02-23 | Kung-Hwa Wei | Method for manufacturing polymer-silicate nanocomposite material |
| BRPI0503777A (pt) * | 2005-07-15 | 2007-03-06 | Braskem Sa | processo para o preparo de nanocompósitos, e, nanocompósitos |
| US20090048381A1 (en) * | 2007-08-16 | 2009-02-19 | Nova Chemical Inc. | Process for making polyolefin clay nanocomposites |
| EP2217527B1 (en) * | 2007-11-21 | 2014-03-12 | LG Chem, Ltd. | Nanocomposites, polymer compositions comprising the same and preparation methods thereof |
| WO2011011899A2 (es) * | 2009-07-29 | 2011-02-03 | Universidad De Chile | Nanopartículas híbridas con morfología controlada y su uso en nanocompuestos con matriz de polímero termoplástico |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS649202A (en) * | 1987-03-26 | 1989-01-12 | Toyota Central Res & Dev | Manufacture of composite material |
| JPH10259016A (ja) * | 1997-03-18 | 1998-09-29 | Kanegafuchi Chem Ind Co Ltd | 粘土層間化合物、粘土層間化合物と熱可塑性樹脂からなる熱可塑性樹脂組成物、およびそれらの製法 |
| JP2001518122A (ja) * | 1995-06-23 | 2001-10-09 | エクソン リサーチ アンド エンジニアリング カンパニー | 乳化合成によって形成されたナノコンポジットポリマー |
| WO2002024759A2 (en) * | 2000-09-21 | 2002-03-28 | Rohm And Haas Company | Improved nanocomposite compositions and methods for making and using same |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3977894A (en) * | 1975-09-19 | 1976-08-31 | Nl Industries, Inc. | Rheological agent for non-aqueous fluid systems |
| US4235751A (en) * | 1979-04-30 | 1980-11-25 | E. I. Du Pont De Nemours And Company | Modified montmorillonite clay catalyst |
| US4816517A (en) * | 1982-09-29 | 1989-03-28 | Vulkor, Incorporated | Crosslinked polymer interdispersions containing polyolefin and method of making |
| DE3806548C2 (de) * | 1987-03-04 | 1996-10-02 | Toyoda Chuo Kenkyusho Kk | Verbundmaterial und Verfahren zu dessen Herstellung |
| US5837763A (en) | 1995-06-07 | 1998-11-17 | Amcol International Corporation | Compositions and methods for manufacturing waxes filled with intercalates and exfoliates formed with oligomers and polymers |
| US6380295B1 (en) * | 1998-04-22 | 2002-04-30 | Rheox Inc. | Clay/organic chemical compositions useful as additives to polymer, plastic and resin matrices to produce nanocomposites and nanocomposites containing such compositions |
| US6033736A (en) | 1998-06-29 | 2000-03-07 | Brandeis University | Aqueous wax emulsion as paint primer and paint repair adhesive |
| AU1837000A (en) * | 1998-12-07 | 2000-06-26 | Eastman Chemical Company | A polymer/clay nanocomposite comprising a clay mixture and process for making same |
| EP1155079B1 (en) * | 1998-12-07 | 2003-08-20 | University of South Carolina Research Foundation | Polymer/clay nanocomposite and process for making same |
| AU1836600A (en) * | 1998-12-07 | 2000-06-26 | Eastman Chemical Company | A polymer/clay nanocomposite having improved gas barrier comprising a clay material with a mixture of two or more organic cations and a process for preparing same |
| US6262162B1 (en) * | 1999-03-19 | 2001-07-17 | Amcol International Corporation | Layered compositions with multi-charged onium ions as exchange cations, and their application to prepare monomer, oligomer, and polymer intercalates and nanocomposites prepared with the layered compositions of the intercalates |
| US6271298B1 (en) * | 1999-04-28 | 2001-08-07 | Southern Clay Products, Inc. | Process for treating smectite clays to facilitate exfoliation |
| US6225394B1 (en) * | 1999-06-01 | 2001-05-01 | Amcol International Corporation | Intercalates formed by co-intercalation of onium ion spacing/coupling agents and monomer, oligomer or polymer ethylene vinyl alcohol (EVOH) intercalants and nanocomposites prepared with the intercalates |
| US6407155B1 (en) * | 2000-03-01 | 2002-06-18 | Amcol International Corporation | Intercalates formed via coupling agent-reaction and onium ion-intercalation pre-treatment of layered material for polymer intercalation |
| BR0106751A (pt) * | 2000-06-16 | 2002-04-16 | Basell Technology Co Bv | Material de argila intercalada útil para preparar nanocompósitos poliméricos de alfa-olefinas e composto intercalante usado na mesma |
| AU2001291024B2 (en) * | 2000-09-21 | 2006-11-23 | Rohm And Haas Company | Hydrophobically modified clay polymer nanocomposites |
| CN100475854C (zh) * | 2000-09-21 | 2009-04-08 | 罗姆和哈斯公司 | 纳米复合材料高酸水分散体 |
| EP1373372A1 (fr) * | 2001-03-13 | 2004-01-02 | Pechiney Emballage Flexible Europe | Procede de preparation d'une dispersion fluide nanocomposite pour enduction |
| US6841226B2 (en) * | 2001-11-13 | 2005-01-11 | Eastman Kodak Company | Ethoxylated alcohol intercalated smectite materials and method |
| US6790896B2 (en) * | 2002-03-18 | 2004-09-14 | The University Of Chicago | Composite materials with improved phyllosilicate dispersion |
| US6822035B2 (en) * | 2002-02-20 | 2004-11-23 | The University Of Chicago | Process for the preparation of organoclays |
| US6864308B2 (en) * | 2002-06-13 | 2005-03-08 | Basell Poliolefine Italia S.P.A. | Method for making polyolefin nanocomposites |
| WO2004078839A1 (en) * | 2003-03-03 | 2004-09-16 | Ciba Specialty Chemicals Holding Inc. | Process for intercalating natural or sznthetic clays with block or comb copolymers |
-
2003
- 2003-05-02 US US10/428,348 patent/US7163972B2/en not_active Expired - Fee Related
-
2004
- 2004-04-28 JP JP2006506534A patent/JP2006525218A/ja active Pending
- 2004-04-28 EP EP04729933A patent/EP1620503A4/en not_active Withdrawn
- 2004-04-28 CN CNA2004800117984A patent/CN1780879A/zh active Pending
- 2004-04-28 CA CA002523828A patent/CA2523828A1/en not_active Abandoned
- 2004-04-28 WO PCT/IB2004/001275 patent/WO2004096736A2/en not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS649202A (en) * | 1987-03-26 | 1989-01-12 | Toyota Central Res & Dev | Manufacture of composite material |
| JP2001518122A (ja) * | 1995-06-23 | 2001-10-09 | エクソン リサーチ アンド エンジニアリング カンパニー | 乳化合成によって形成されたナノコンポジットポリマー |
| JPH10259016A (ja) * | 1997-03-18 | 1998-09-29 | Kanegafuchi Chem Ind Co Ltd | 粘土層間化合物、粘土層間化合物と熱可塑性樹脂からなる熱可塑性樹脂組成物、およびそれらの製法 |
| WO2002024759A2 (en) * | 2000-09-21 | 2002-03-28 | Rohm And Haas Company | Improved nanocomposite compositions and methods for making and using same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009534284A (ja) * | 2006-04-19 | 2009-09-24 | ザ・プロヴォスト，フェローズ・アンド・スカラーズ・オブ・ザ・カレッジ・オブ・ザ・ホーリー・アンド・アンディヴァイデッド・トリニティー・オブ・クイーン・エリザベス，ニア・ダブリン | 変性オルガノクレー |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1780879A (zh) | 2006-05-31 |
| EP1620503A2 (en) | 2006-02-01 |
| WO2004096736A3 (en) | 2005-05-06 |
| WO2004096736A2 (en) | 2004-11-11 |
| US20040220305A1 (en) | 2004-11-04 |
| CA2523828A1 (en) | 2004-11-11 |
| EP1620503A4 (en) | 2006-11-29 |
| US7163972B2 (en) | 2007-01-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6790896B2 (en) | Composite materials with improved phyllosilicate dispersion | |
| US7157516B2 (en) | Polyolefin nanocomposites | |
| US6822035B2 (en) | Process for the preparation of organoclays | |
| US7223359B2 (en) | Method of producing an exfoliated polymer-clay nanocomposite through solid-state shear pulverization | |
| Someya et al. | Nanocomposites based on poly (butylene adipate‐co‐terephthalate) and montmorillonite | |
| US7919185B2 (en) | Polymer composites, polymer nanocomposites and methods | |
| US7709569B2 (en) | Flame retardant and UV absorptive polymethylmethacrylate nanocomposites | |
| US7160942B2 (en) | Polymer-phyllosilicate nanocomposites and their preparation | |
| Moncada et al. | Use of PP grafted with itaconic acid as a new compatibilizer for PP/clay nanocomposites | |
| JP2006525218A (ja) | 有機フィロシリケートナノ複合材料組成物の製造法 | |
| Abu-Zurayk et al. | Biaxial deformation behavior and mechanical properties of a polypropylene/clay nanocomposite | |
| US20080207801A1 (en) | Compatibilization of Polymer Clay Nanocomposites | |
| US20090209694A1 (en) | Process for Nanocomposites Preparation, and Nanocomposites | |
| KR20010100279A (ko) | 삽입형 나노복합재 제조 방법 | |
| EP1553136A1 (en) | Polyolefin resin composition | |
| Abdelaal et al. | An overview on polysulphone/clay nanocomposites | |
| WO2004026952A1 (en) | Shear modification of hdpe-clay nanocomposites | |
| KR102025136B1 (ko) | 이성분계를 활용한 나노클레이 분산 방법 | |
| US20140377562A1 (en) | Natural nanoreinforcement that comprises a laminar silicate from volcanic sources useful to manufacture polymeric nanocomposites and manufacture process thereof | |
| JP4865941B2 (ja) | ポリオレフィン系複合材料及びその製造方法 | |
| JP2004352779A (ja) | 熱可塑性ポリオレフィン及びポリビニル系樹脂組成物 | |
| Leite et al. | Mechanical and thermomechanical properties of polyamide 6/Brazilian organoclay nanocomposites |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070426 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070426 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100609 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20101215 |