JP2006504784A - Ｉｔｑ−１３による芳香族化合物の転化 - Google Patents
Ｉｔｑ−１３による芳香族化合物の転化 Download PDFInfo
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- JP2006504784A JP2006504784A JP2004550038A JP2004550038A JP2006504784A JP 2006504784 A JP2006504784 A JP 2006504784A JP 2004550038 A JP2004550038 A JP 2004550038A JP 2004550038 A JP2004550038 A JP 2004550038A JP 2006504784 A JP2006504784 A JP 2006504784A
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- conversion
- aromatic compound
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- xylene
- aromatic
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- 238000006243 chemical reaction Methods 0.000 title claims abstract description 92
- 150000001491 aromatic compounds Chemical class 0.000 title claims abstract description 88
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- 238000000034 method Methods 0.000 claims abstract description 85
- 239000003054 catalyst Substances 0.000 claims abstract description 65
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 63
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 61
- 239000008096 xylene Substances 0.000 claims abstract description 49
- -1 olefin aromatic compounds Chemical class 0.000 claims abstract description 30
- 238000006317 isomerization reaction Methods 0.000 claims abstract description 23
- 238000007323 disproportionation reaction Methods 0.000 claims abstract description 18
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 16
- 125000003118 aryl group Chemical group 0.000 claims abstract description 9
- 230000029936 alkylation Effects 0.000 claims abstract description 8
- 238000005804 alkylation reaction Methods 0.000 claims abstract description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012188 paraffin wax Substances 0.000 claims abstract description 3
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- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 claims description 32
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
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- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 claims description 8
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- WWGUMAYGTYQSGA-UHFFFAOYSA-N 2,3-dimethylnaphthalene Chemical compound C1=CC=C2C=C(C)C(C)=CC2=C1 WWGUMAYGTYQSGA-UHFFFAOYSA-N 0.000 claims description 4
- QIMMUPPBPVKWKM-UHFFFAOYSA-N 2-methylnaphthalene Chemical compound C1=CC=CC2=CC(C)=CC=C21 QIMMUPPBPVKWKM-UHFFFAOYSA-N 0.000 claims description 4
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 4
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- 239000011135 tin Chemical group 0.000 claims description 3
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- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 claims description 2
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- YQZBFMJOASEONC-UHFFFAOYSA-N 1-Methyl-2-propylbenzene Chemical compound CCCC1=CC=CC=C1C YQZBFMJOASEONC-UHFFFAOYSA-N 0.000 claims description 2
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- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
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Images
Classifications
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
- C07C5/2732—Catalytic processes
- C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Luminescent Compositions (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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| US10/285,917 US7081556B2 (en) | 2002-11-01 | 2002-11-01 | Aromatics conversion with ITQ-13 |
| PCT/US2003/032969 WO2004041756A1 (en) | 2002-11-01 | 2003-10-17 | Aromatics conversion with itq-13 |
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| JP2006504784A true JP2006504784A (ja) | 2006-02-09 |
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| JP (1) | JP2006504784A (enExample) |
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Cited By (1)
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| JP2016512788A (ja) * | 2013-03-15 | 2016-05-09 | ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド | ボロアルミノシリケートモレキュラーシーブおよびそれをキシレンの異性化に用いる方法 |
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| US7238636B2 (en) * | 2003-07-23 | 2007-07-03 | Exxonmobil Chemical Patents Inc. | High temperature calcination of selectivated molecular sieve catalysts for activity and diffusional modification |
| US7060644B2 (en) * | 2004-01-08 | 2006-06-13 | Saudi Basic Industries Corporation | Aromatic alkylation catalyst and method |
| ES2244345B1 (es) * | 2004-05-28 | 2007-03-01 | Universidad Politecnica De Valencia | Procedimiento y catalizador para transalquilacion/dealquilacion de compuestos organicos. |
| ES2302442B1 (es) * | 2006-07-31 | 2009-06-08 | Universidad Politecnica De Valencia | Aquilacion de compuestos aromaticos utilizando la zeolita itq-33. |
| US8846559B2 (en) | 2008-11-03 | 2014-09-30 | Saudi Basic Industries Corporation | Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing |
| US8062987B2 (en) * | 2009-10-05 | 2011-11-22 | Saudi Basic Industries Corporation | Phosphorus-containing zeolite catalysts and their method of preparation |
| US9090525B2 (en) | 2009-12-11 | 2015-07-28 | Exxonmobil Research And Engineering Company | Process and system to convert methanol to light olefin, gasoline and distillate |
| US20110147263A1 (en) | 2009-12-18 | 2011-06-23 | Exxonmobil Research And Engineering Company | Process and system to convert olefins to diesel and other distillates |
| US8598395B2 (en) * | 2010-01-19 | 2013-12-03 | Uop Llc | Process for increasing a mole ratio of methyl to phenyl |
| US8609917B2 (en) * | 2010-01-19 | 2013-12-17 | Uop Llc | Process for increasing methyl to phenyl mole ratios and reducing benzene content in a motor fuel product |
| US8563795B2 (en) * | 2010-01-19 | 2013-10-22 | Uop Llc | Aromatic aklylating agent and an aromatic production apparatus |
| US9278342B2 (en) | 2012-07-02 | 2016-03-08 | Saudi Basic Industries Corporation | Method of modifying a phosphorus-containing zeolite catalyst |
| US20160032047A1 (en) | 2013-03-14 | 2016-02-04 | John L. Murphy | Peg-based adhesive phenylic derivatives and methods of synthesis and use |
| CN104528756B (zh) * | 2014-12-08 | 2016-06-08 | 中国石油天然气股份有限公司 | 一种含稀土的Al-ITQ-13沸石及其合成方法 |
| CA3001358A1 (en) | 2015-10-28 | 2017-05-04 | Exxonmobil Research And Engineering Company | Methods and apparatus for converting oxygenate-containing feedstocks to gasoline and distillates |
| US20190300801A1 (en) | 2018-03-30 | 2019-10-03 | Exxonmobil Research And Engineering Company | Staged removal of aromatics in naphtha reforming |
| RU2676704C1 (ru) * | 2018-06-28 | 2019-01-10 | федеральное государственное автономное образовательное учреждение высшего образования "Российский государственный университет нефти и газа (национальный исследовательский университет) имени И.М. Губкина" | Катализатор для изомеризации ароматических углеводородов с-8 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0981406A4 (en) | 1997-05-12 | 2002-02-27 | Phillips Petroleum Co | IMPROVED CATALYTIC COMPOSITION SUITABLE FOR CONVERSION OF NON-AROMATIC HYDROCARBONS TO LIGHT AROMATES AND OLEFINS |
| US6281406B1 (en) | 2000-03-31 | 2001-08-28 | Chevron Corporation | Adsorption process for paraxylene purifacation using Cs SSZ-25 adsorbent with benzene desorbent |
| US7411101B2 (en) | 2001-02-07 | 2008-08-12 | Exxonmobil Chemical Patents Inc. | Production of alkylaromatic compounds |
| US6471941B1 (en) | 2001-05-29 | 2002-10-29 | Exxonmobil Research And Engineering Company | Synthetic porous crystalline material ITQ-13, its synthesis and use |
| US6709572B2 (en) * | 2002-03-05 | 2004-03-23 | Exxonmobil Research And Engineering Company | Catalytic cracking process |
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2002
- 2002-11-01 US US10/285,917 patent/US7081556B2/en not_active Expired - Fee Related
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2003
- 2003-10-17 DE DE60312024T patent/DE60312024D1/de not_active Expired - Lifetime
- 2003-10-17 EP EP03776453A patent/EP1558550B1/en not_active Expired - Lifetime
- 2003-10-17 AT AT03776453T patent/ATE354556T1/de not_active IP Right Cessation
- 2003-10-17 KR KR1020057007625A patent/KR20050070107A/ko not_active Withdrawn
- 2003-10-17 CN CNA2003801048578A patent/CN1720207A/zh active Pending
- 2003-10-17 JP JP2004550038A patent/JP2006504784A/ja active Pending
- 2003-10-17 AU AU2003284273A patent/AU2003284273A1/en not_active Abandoned
- 2003-10-17 WO PCT/US2003/032969 patent/WO2004041756A1/en not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016512788A (ja) * | 2013-03-15 | 2016-05-09 | ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド | ボロアルミノシリケートモレキュラーシーブおよびそれをキシレンの異性化に用いる方法 |
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|---|---|
| CN1720207A (zh) | 2006-01-11 |
| EP1558550A1 (en) | 2005-08-03 |
| WO2004041756A1 (en) | 2004-05-21 |
| US20040087822A1 (en) | 2004-05-06 |
| ATE354556T1 (de) | 2007-03-15 |
| DE60312024D1 (de) | 2007-04-05 |
| US7081556B2 (en) | 2006-07-25 |
| EP1558550B1 (en) | 2007-02-21 |
| KR20050070107A (ko) | 2005-07-05 |
| AU2003284273A1 (en) | 2004-06-07 |
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