JP2006315149A - Surface coated cermet cutting tool having hard coating layer exhibiting excellent wear resistance in high-speed cutting - Google Patents

Surface coated cermet cutting tool having hard coating layer exhibiting excellent wear resistance in high-speed cutting Download PDF

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JP2006315149A
JP2006315149A JP2005142016A JP2005142016A JP2006315149A JP 2006315149 A JP2006315149 A JP 2006315149A JP 2005142016 A JP2005142016 A JP 2005142016A JP 2005142016 A JP2005142016 A JP 2005142016A JP 2006315149 A JP2006315149 A JP 2006315149A
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inclination angle
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Hiroshi Hara
央 原
Tetsuhiko Honma
哲彦 本間
Kazuhiro Kono
和弘 河野
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Mitsubishi Materials Corp
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<P>PROBLEM TO BE SOLVED: To provide a surface coated cermet cutting tool having a hard coating layer exhibiting excellent wear resistance in high-speed cutting. <P>SOLUTION: In a coated cermet tool, the hard coating layer composed of (a) Ti compound layer having total average layer thickness of 3 to 20 μm as a lower layer and (b) α type Al<SB>2</SB>O<SB>3</SB>layer having an average layer thickness of 2 to 15 μm as an upper layer is formed by chemical vapor deposition. The α type Al<SB>2</SB>O<SB>3</SB>layer is made to be upper and lower double-layer structure composed of a reformed layer occupying 55 to 80% by the ratio with respect to an average layer thickness of whole Al<SB>2</SB>O<SB>3</SB>layer and a residual standard layer. When the inclination angle formed by a normal line of (0001) surface of crystal grains is measured by using a field emission type scanning electron microscope and an inclination angle frequency distribution graph is made by adding up the frequency existing in each division, the double-layer α type Al<SB>2</SB>O<SB>3</SB>layer shows a specific inclination angle frequency distribution graph. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

この発明は、特に硬質被覆層の上部層である酸化アルミニウム層(以下、Al23層で示す)が、各種の鋼や鋳鉄などの切削加工を、高速で行った場合にも、すぐれた耐摩耗性を発揮する表面被覆サーメット製切削工具(以下、被覆サーメット工具という)に関するものである。 The present invention is particularly excellent when an aluminum oxide layer (hereinafter referred to as an Al 2 O 3 layer), which is an upper layer of a hard coating layer, is used to cut various types of steel and cast iron at high speed. The present invention relates to a surface-coated cermet cutting tool that exhibits wear resistance (hereinafter referred to as a coated cermet tool).

従来、一般に、炭化タングステン(以下、WCで示す)基超硬合金または炭窒化チタン(以下、TiCNで示す)基サーメットで構成された基体(以下、これらを総称して工具基体という)の表面に、
(a)下部層として、Tiの炭化物(以下、TiCで示す)層、窒化物(以下、同じくTiNで示す)層、炭窒化物(以下、TiCNで示す)層、炭酸化物(以下、TiCOで示す)層、および炭窒酸化物(以下、TiCNOで示す)層のうちの1層または2層以上からなり、かつ3〜20μmの全体平均層厚を有するTi化合物層、
(b)上部層として、2〜15μmの平均層厚を有し、かつ化学蒸着した状態でα型の結晶構造を有する酸化アルミニウム層(以下、α型Al23層で示す)、
以上(a)および(b)で構成された硬質被覆層を化学蒸着形成してなる被覆サーメット工具が知られており、この被覆サーメット工具が、例えば各種の鋼や鋳鉄などの連続切削や断続切削に用いられることは良く知られている。
Conventionally, generally on the surface of a substrate (hereinafter collectively referred to as a tool substrate) composed of a tungsten carbide (hereinafter referred to as WC) -based cemented carbide or titanium carbonitride (hereinafter referred to as TiCN) -based cermet. ,
(A) As a lower layer, Ti carbide (hereinafter referred to as TiC) layer, nitride (hereinafter also referred to as TiN) layer, carbonitride (hereinafter referred to as TiCN) layer, carbon oxide (hereinafter referred to as TiCO) A Ti compound layer consisting of one or two or more layers of carbonitride oxide (hereinafter referred to as TiCNO) layers and having an overall average layer thickness of 3 to 20 μm,
(B) As an upper layer, an aluminum oxide layer (hereinafter referred to as an α-type Al 2 O 3 layer) having an average layer thickness of 2 to 15 μm and having an α-type crystal structure in a state of chemical vapor deposition,
A coated cermet tool formed by chemical vapor deposition of the hard coating layer composed of (a) and (b) above is known, and this coated cermet tool is used for continuous cutting and intermittent cutting of various steels and cast irons, for example. It is well known to be used in

また、一般に、上記の被覆サーメット工具の硬質被覆層を構成するTi化合物層やα型Al23層が粒状結晶組織を有し、さらに、前記Ti化合物層を構成するTiCN層を、層自身の強度向上を目的として、通常の化学蒸着装置にて、反応ガスとして有機炭窒化物を含む混合ガスを使用し、700〜950℃の中温温度域で化学蒸着することにより形成して縦長成長結晶組織をもつようにすることも知られている。
特開平6−31503号公報 特開平6−8010号公報
In general, the Ti compound layer and the α-type Al 2 O 3 layer constituting the hard coating layer of the above-mentioned coated cermet tool have a granular crystal structure, and further, the TiCN layer constituting the Ti compound layer is the layer itself. For the purpose of improving the strength of the crystal, a vertically grown crystal formed by chemical vapor deposition at a medium temperature range of 700 to 950 ° C. using a mixed gas containing an organic carbonitride as a reaction gas in a normal chemical vapor deposition apparatus. It is also known to have an organization.
Japanese Unexamined Patent Publication No. 6-31503 Japanese Patent Laid-Open No. 6-8010

近年の切削装置の高性能化はめざましく、一方で切削加工に対する省力化および省エネ化、さらに低コスト化の要求は強く、これに伴い、切削加工は一段と高速化する傾向にあるが、上記の従来被覆サーメット工具においては、これを鋼や鋳鉄などの通常の条件での連続切削や断続切削に用いた場合には問題はないが、特にこれを高速切削条件で用いた場合には、硬質被覆層を構成するα型Al23層の耐摩耗性が不十分であることから、摩耗が急速に進行するようになり、比較的短時間で使用寿命に至るのが現状である。 In recent years, the performance of cutting machines has been remarkable. On the other hand, there is a strong demand for labor saving and energy saving and further cost reduction for cutting work, and along with this, cutting work tends to be further accelerated. For coated cermet tools, there is no problem when this is used for continuous cutting or intermittent cutting under normal conditions such as steel or cast iron, but especially when this is used under high-speed cutting conditions, a hard coating layer Since the α-type Al 2 O 3 layer constituting the layer has insufficient wear resistance, the wear progresses rapidly, and the service life is reached in a relatively short time.

そこで、本発明者等は、上述のような観点から、上記のα型Al23層が硬質被覆層の上部層を構成する被覆サーメット工具に着目し、特に前記α型Al23層の耐摩耗性向上を図るべく研究を行った結果、
(a)上記の従来被覆サーメット工具の硬質被覆層としてのα型Al23層は、一般に、通常の化学蒸着装置にて、
反応ガス組成:容量%で、AlCl3:1〜5%、CO2:3〜7%、HCl:0.3〜3%、H2S:0.02〜0.4%、H2:残り、
反応雰囲気温度:950〜1100℃、
反応雰囲気圧力:6〜13kPa、
の条件(以下、通常条件という)で形成されるが、この通常条件形成のα型Al23層(以下、標準層という)について、電界放出型走査電子顕微鏡を用い、図1(a),(b)に概略説明図で示される通り、表面研磨面の測定範囲内に存在する六方晶結晶格子を有する結晶粒個々に電子線を照射して、前記表面研磨面の法線に対して、前記結晶粒の結晶面である(0001)面の法線がなす傾斜角を測定し、前記測定傾斜角のうちの45〜90度の範囲内にある測定傾斜角を0.25度のピッチ毎に区分すると共に、各区分内に存在する度数を集計してなる傾斜角度数分布グラフを作成すると、図3に例示される通り、(0001)面の測定傾斜角の分布が45〜90度の範囲内で不偏的な傾斜角度数分布グラフを示すこと。
The present inventors have, from the viewpoint as described above, focuses on coated cermet tool α type the Al 2 O 3 layer described above constituting the upper layer of the hard coating layer, in particular the α-type the Al 2 O 3 layer As a result of research to improve wear resistance,
(A) The α-type Al 2 O 3 layer as a hard coating layer of the above-described conventional coated cermet tool is generally a normal chemical vapor deposition apparatus,
Reaction gas composition: by volume%, AlCl 3: 1~5%, CO 2: 3~7%, HCl: 0.3~3%, H 2 S: 0.02~0.4%, H 2: remainder ,
Reaction atmosphere temperature: 950-1100 ° C.
Reaction atmosphere pressure: 6-13 kPa,
The α-type Al 2 O 3 layer (hereinafter referred to as the standard layer) formed under the normal conditions is subjected to a field emission scanning electron microscope as shown in FIG. As shown in the schematic explanatory diagram in (b), each crystal grain having a hexagonal crystal lattice existing within the measurement range of the surface polished surface is irradiated with an electron beam, and the normal line of the surface polished surface is obtained. The inclination angle formed by the normal line of the (0001) plane, which is the crystal plane of the crystal grain, is measured, and the measurement inclination angle within the range of 45 to 90 degrees of the measurement inclination angle is set to a pitch of 0.25 degrees. When an inclination angle number distribution graph is created, which is divided for each of the areas and the frequencies existing in the respective areas are totaled, the distribution of measured inclination angles on the (0001) plane is 45 to 90 degrees as illustrated in FIG. An unbiased inclination angle number distribution graph within the range of.

(b)一方、α型Al23層を、同じく通常の化学蒸着装置を用い、

反応ガス組成:容量%で、AlCl3:1〜5%、CO2:3〜7%、HCl:0.3〜3%、H2S:0.02〜0.4%、H2:残り、
反応雰囲気温度:750〜900℃、
反応雰囲気圧力:20〜30kPa、
の相対的に低温高圧条件(反応ガス組成は上記の通常条件と同じ)で形成すると、この結果形成されたα型Al23層(以下、改質層という)は、同じく電界放出型走査電子顕微鏡を用い、図1(a),(b)に示される通り、表面研磨面の測定範囲内に存在する六方晶結晶格子を有する結晶粒個々に電子線を照射して、前記表面研磨面の法線に対して、前記結晶粒の結晶面である(0001)面の法線がなす傾斜角を測定し、前記測定傾斜角のうち、45〜90度の範囲内にある測定傾斜角を0.25度のピッチ毎に区分すると共に、各区分内に存在する度数を集計してなる傾斜角度数分布グラフで表した場合、図2に例示される通り、傾斜角区分の特定位置にシャープな最高ピークが現れ、試験結果によれば、化学蒸着装置における反応雰囲気圧力を、上記の通り20〜30kPaの範囲内で変化させると、上記シャープな最高ピークの現れる位置が傾斜角区分の75〜85度の範囲内で変化すると共に、前記75〜85度の範囲内に存在する度数の合計が、傾斜角度数分布グラフにおける度数全体の45〜65%の割合を占めるようになり、この結果の傾斜角度数分布グラフにおいて75〜85度の範囲内に傾斜角区分の最高ピークが現れる改質層は、上記の通常条件形成の標準層に比して、一段とすぐれた耐摩耗性を示すこと。
(B) On the other hand, the α-type Al 2 O 3 layer was similarly used with a normal chemical vapor deposition apparatus,

Reaction gas composition: by volume%, AlCl 3: 1~5%, CO 2: 3~7%, HCl: 0.3~3%, H 2 S: 0.02~0.4%, H 2: remainder ,
Reaction atmosphere temperature: 750 to 900 ° C.
Reaction atmosphere pressure: 20-30 kPa,
When formed under relatively low temperature and high pressure conditions (reaction gas composition is the same as the above normal conditions), the resulting α-type Al 2 O 3 layer (hereinafter referred to as a modified layer) is also subjected to field emission scanning. Using an electron microscope, as shown in FIGS. 1A and 1B, the surface polished surface is irradiated with an electron beam on each crystal grain having a hexagonal crystal lattice existing within the measurement range of the surface polished surface. The inclination angle formed by the normal line of the (0001) plane which is the crystal plane of the crystal grain is measured, and the measurement inclination angle within the range of 45 to 90 degrees is measured among the measurement inclination angles. When divided into pitches of 0.25 degrees and represented by an inclination angle number distribution graph obtained by summing up the frequencies existing in each of the divisions, as shown in FIG. The highest peak appears, and according to the test results, the reaction in chemical vapor deposition equipment When the atmospheric pressure is changed within the range of 20 to 30 kPa as described above, the position at which the sharpest peak appears changes within the range of 75 to 85 degrees of the inclination angle section, and the range of 75 to 85 degrees. The total number of frequencies existing in the graph occupies 45 to 65% of the total frequency in the tilt angle frequency distribution graph, and the tilt angle section falls within the range of 75 to 85 degrees in the resulting tilt angle frequency distribution graph. The modified layer in which the highest peak of shows a better abrasion resistance than the standard layer formed under the normal conditions described above.

(c)したがって、下部層がTi化合物層からなる硬質被覆層の上部層であるα型Al23層を、Al23層全体の平均層厚に占める割合で55〜80%の上記改質層と、残りの上記標準層からなる上下2重層構造とし、表面研磨面の測定で、前記改質層を、75〜85度の範囲内の傾斜角区分に最高ピークが存在すると共に、前記75〜85度の範囲内に存在する度数の合計が、傾斜角度数分布グラフにおける度数全体の45〜65%の割合を占める傾斜角度数分布グラフを示し、前記標準層を、45〜90度の範囲の測定傾斜角区分全体に亘ってピークが存在せず、測定傾斜角の分布が不偏的な傾斜角度数分布グラフを示す2重層α型Al23層で構成してなる被覆サーメット工具は、前記2重層α型Al23層が、相対的にすぐれた耐摩耗性を有する改質層と高温硬さを有する標準層からなることから、層全体の特性としてすぐれた耐摩耗性と高温硬さを兼ね備えるようになるので、特に高速切削条件で切削加工を行っても、上記の硬質被覆層の上部層全体が、上記標準層に相当する(0001)面の測定傾斜角の分布が45〜90度の範囲内で不偏的な傾斜角度数分布グラフを示す単層α型Al23層で構成された従来被覆サーメット工具に比して、一段とすぐれた耐摩耗性を長期に亘って発揮するようになること。
以上(a)〜(c)に示される研究結果を得たのである。
(C) Therefore, the α-type Al 2 O 3 layer, which is the upper layer of the hard coating layer whose lower layer is a Ti compound layer, is 55 to 80% of the total layer thickness of the Al 2 O 3 layer. The upper and lower layers are composed of a modified layer and the remaining standard layer, and the surface is polished, and the modified layer has the highest peak in the tilt angle section within the range of 75 to 85 degrees. The inclination angle number distribution graph in which the total of the frequencies existing in the range of 75 to 85 degrees occupies a ratio of 45 to 65% of the entire degrees in the inclination angle number distribution graph is shown, and the standard layer is 45 to 90 degrees. Coated cermet tool composed of a double-layer α-type Al 2 O 3 layer showing no inclination angle distribution graph in which there is no peak over the entire measured inclination angle range in the range of , the 2-layer α type the Al 2 O 3 layer is relatively superior Since it consists of a modified layer with wear resistance and a standard layer with high temperature hardness, it has excellent wear resistance and high temperature hardness as the overall characteristics of the layer, so cutting is performed especially under high speed cutting conditions. Even if it goes, the whole upper layer of the hard coating layer shows an unbiased inclination angle number distribution graph within the range of the measured inclination angle of the (0001) plane corresponding to the standard layer in the range of 45 to 90 degrees. Compared to conventional coated cermet tools composed of a single-layer α-type Al 2 O 3 layer, the wear resistance should be improved over a long period of time.
The research results shown in (a) to (c) above were obtained.

この発明は、上記の研究結果に基づいてなされたものであって、工具基体の表面に、
(a)下部層として、TiC層、TiN層、TiCN層、TiCO層、およびTiCNO層のうちの1層または2層以上からなり、かつ3〜20μmの全体平均層厚を有するTi化合物層、
(b)上部層として、2〜15μmの平均層厚を有するα型Al23層、
以上(a)および(b)で構成された硬質被覆層を化学蒸着形成してなる被覆サーメット工具において、
上記α型Al23層を、Al23層全体の平均層厚に占める割合で55〜80%の改質層と、残りの標準層からなる上下2重層構造とし、さらに電界放出型走査電子顕微鏡を用い、上記表面研磨面の測定範囲内に存在する六方晶結晶格子を有する結晶粒個々に電子線を照射して、前記表面研磨面の法線に対して、前記結晶粒の結晶面である(0001)面の法線がなす傾斜角を測定し、前記測定傾斜角のうちの45〜90度の範囲内にある測定傾斜角を0.25度のピッチ毎に区分すると共に、各区分内に存在する度数を集計してなる傾斜角度数分布グラフで現した場合、
(A)上記α型Al23層の改質層は、75〜85度の範囲内の傾斜角区分に最高ピークが存在すると共に、前記75〜85度の範囲内に存在する度数の合計が、傾斜角度数分布グラフにおける度数全体の45〜65%の割合を占める傾斜角度数分布グラフを示し、
(B)上記α型Al23層の標準層は、45〜90度の範囲の測定傾斜角区分全体に亘ってピークが存在せず、測定傾斜角の分布が不偏的な傾斜角度数分布グラフを示す、
以上(A)および(B)からなる2重層α型Al23層で構成してなる、硬質被覆層が高速切削ですぐれた耐摩耗性を発揮する被覆サーメット工具に特徴を有するものである。
This invention was made based on the above research results, and on the surface of the tool base,
(A) As a lower layer, a Ti compound layer composed of one or more of a TiC layer, a TiN layer, a TiCN layer, a TiCO layer, and a TiCNO layer and having an overall average layer thickness of 3 to 20 μm,
(B) an α-type Al 2 O 3 layer having an average layer thickness of 2 to 15 μm as an upper layer;
In the coated cermet tool formed by chemical vapor deposition of the hard coating layer composed of (a) and (b) above,
The α-type Al 2 O 3 layer has an upper and lower double layer structure consisting of 55 to 80% of the modified layer and the remaining standard layer in the ratio of the average layer thickness of the entire Al 2 O 3 layer, and a field emission type Using a scanning electron microscope, each crystal grain having a hexagonal crystal lattice existing within the measurement range of the surface polished surface is irradiated with an electron beam, and the crystal of the crystal grain is normal to the surface polished surface. Measuring the tilt angle formed by the normal line of the (0001) plane, and dividing the measured tilt angle within the range of 45 to 90 degrees of the measured tilt angles into pitches of 0.25 degrees, When expressed in the slope angle distribution graph, which is the sum of the frequencies existing in each category,
(A) In the modified layer of the α-type Al 2 O 3 layer, the highest peak exists in the tilt angle section within the range of 75 to 85 degrees, and the total number of frequencies existing within the range of 75 to 85 degrees. Shows an inclination angle number distribution graph occupying a proportion of 45 to 65% of the entire frequency in the inclination angle number distribution graph,
(B) In the standard layer of the α-type Al 2 O 3 layer, there is no peak over the entire measurement inclination angle range of 45 to 90 degrees, and the inclination angle number distribution in which the distribution of the measurement inclination angles is unbiased. Showing the graph,
The hard coating layer composed of the double layer α-type Al 2 O 3 layer composed of the above (A) and (B) is characterized by a coated cermet tool that exhibits excellent wear resistance in high-speed cutting. .

以下に、この発明の被覆サーメット工具の硬質被覆層の構成層に関し、上記の通りに数値限定した理由を説明する。
(a)Ti化合物層(下部層)
Ti化合物層は、基本的には2重層α型Al23層の下部層として存在し、自身の具備するすぐれた高温強度によって硬質被覆層全体の高温強度向上に寄与するほか、工具基体と2重層α型Al23層のいずれにも強固に密着し、よって硬質被覆層の工具基体に対する密着性を向上させる作用を有するが、その平均層厚が3μm未満では、前記作用を十分に発揮させることができず、一方その平均層厚が20μmを越えると、特に高熱発生を伴なう高速切削では熱塑性変形を起し易くなり、これが偏摩耗の原因となることから、その平均層厚を3〜20μmと定めた。
The reason why the numerical values of the constituent layers of the hard coating layer of the coated cermet tool of the present invention are limited as described above will be described below.
(A) Ti compound layer (lower layer)
The Ti compound layer basically exists as a lower layer of the double-layer α-type Al 2 O 3 layer and contributes to improving the high-temperature strength of the entire hard coating layer by its excellent high-temperature strength. The double-layer α-type Al 2 O 3 layer has a function of firmly adhering to any of the two layers, thereby improving the adhesion of the hard coating layer to the tool substrate. On the other hand, if the average layer thickness exceeds 20 μm, it becomes easy to cause thermoplastic deformation especially in high-speed cutting with high heat generation, which causes uneven wear. Was determined to be 3 to 20 μm.

(b)2重層α型Al23層(上部層)
上記の通り、2重層α型Al23層の改質層の傾斜角度数分布グラフにおける測定傾斜角の最高ピーク位置は、化学蒸着装置における反応雰囲気圧力を、上記の通り20〜30kPaの範囲内で変化させると、傾斜角区分の75〜85度の範囲内で変化すると共に、前記75〜85度の範囲内に存在する度数の合計が、傾斜角度数分布グラフにおける度数全体の45〜65%の割合を占める傾斜角度数分布グラフを示すようになるものであり(この場合前記反応雰囲気圧力を調整しても65%以上の度数割合を占めるようにすることはできない)、したがって、前記反応雰囲気圧力が前記範囲から低い方に外れても、また高い方に外れても、測定傾斜角の最高ピーク位置は75〜85度の範囲から外れてしまうと共に、これに対応して傾斜角度数分布グラフにおける前記75〜85度の範囲内に存在する度数の割合も度数全体の45%未満となってしまい、所望のすぐれた耐摩耗性を確保することができないものとなる。
また、2重層α型Al23層は、改質層のすぐれた耐摩耗性と標準層のすぐれた高温硬さによって、すぐれた耐摩耗性と高温硬さを具備するようになるが、前記改質層の層厚がAl23層全体の平均層厚に占める割合で55%未満では、所望のすぐれた耐摩耗性を確保することができず、一方同層厚が同じく80%を越えると、高温硬さが急激に低下し、摩耗進行が加速するようになることから、前記改質層の層厚をAl23層全体の平均層厚に占める割合で55〜80%と定め、残りを前記標準層(上記従来α型Al23層に相当)で占める上下2重層構造とした。
さらに、2重層α型Al23層全体の平均層厚が2μm未満では、これのもつすぐれた特性を十分に発揮させることができず、一方その平均層厚が15μmを越えて厚くなりすぎると、切刃部にチッピング(微少欠け)が発生し易くなることから、その全体平均層厚を2〜15μmと定めた。
(B) Double layer α-type Al 2 O 3 layer (upper layer)
As described above, the highest peak position of the measured inclination angle in the inclination angle number distribution graph of the modified layer of the double layer α-type Al 2 O 3 layer is the reaction atmosphere pressure in the chemical vapor deposition apparatus, as described above, in the range of 20 to 30 kPa. When the angle is changed within the range of 75 to 85 degrees of the inclination angle section, the total of the frequencies existing in the range of 75 to 85 degrees is 45 to 65 of the entire degrees in the inclination angle distribution graph. % Of the inclination angle number distribution graph (in this case, even if the reaction atmosphere pressure is adjusted, it is not possible to occupy a frequency ratio of 65% or more). Regardless of whether the atmospheric pressure is out of the range or low, the maximum peak position of the measurement inclination angle is out of the range of 75 to 85 degrees, and the inclination angle is corresponding to this. The ratio of the frequencies existing in the range of 75 to 85 degrees in the frequency distribution graph is also less than 45% of the entire frequencies, and the desired excellent wear resistance cannot be ensured.
The double layer α-type Al 2 O 3 layer has excellent wear resistance and high temperature hardness due to the excellent wear resistance of the modified layer and the high temperature hardness of the standard layer. If the layer thickness of the modified layer is less than 55% in the average layer thickness of the entire Al 2 O 3 layer, the desired excellent wear resistance cannot be ensured, while the layer thickness is also 80%. If it exceeds 1, the high-temperature hardness will rapidly decrease and the progress of wear will accelerate, so the layer thickness of the modified layer is 55-80% of the average layer thickness of the entire Al 2 O 3 layer. The remainder was a double-layered structure occupying the standard layer (corresponding to the conventional α-type Al 2 O 3 layer).
Furthermore, if the average layer thickness of the entire double-layer α-type Al 2 O 3 layer is less than 2 μm, the excellent characteristics of the double layer α-type Al 2 O 3 layer cannot be exhibited sufficiently, while the average layer thickness exceeds 15 μm and becomes too thick. Then, since chipping (slight chipping) is likely to occur in the cutting edge portion, the overall average layer thickness is set to 2 to 15 μm.

なお、切削工具の使用前後の識別を目的として、黄金色の色調を有するTiN層を、必要に応じて硬質被覆層の最表面層として蒸着形成してもよいが、この場合の平均層厚は0.1〜1μmでよく、これは0.1μm未満では、十分な識別効果が得られず、一方前記TiN層による前記識別効果は1μmまでの平均層厚で十分であるという理由からである。   In addition, for the purpose of identification before and after the use of the cutting tool, a TiN layer having a golden color tone may be vapor-deposited as the outermost surface layer of the hard coating layer as necessary, but the average layer thickness in this case is It may be 0.1 to 1 μm, and if it is less than 0.1 μm, a sufficient discrimination effect cannot be obtained, while the discrimination effect by the TiN layer is sufficient for an average layer thickness of up to 1 μm.

この発明の被覆サーメット工具は、硬質被覆層の上部層を構成する2重層α型Al23層が、各種の鋼や鋳鉄などの切削加工を高速で行っても、前記2重層α型Al23層が、すぐれた耐摩耗性と高温硬さを有することから、すぐれた耐摩耗性を発揮し、使用寿命の一層の延命化を可能とするものである。 In the coated cermet tool of the present invention, even if the double layer α-type Al 2 O 3 layer constituting the upper layer of the hard coating layer is subjected to cutting of various types of steel and cast iron at high speed, the double layer α-type Al Since the 2 O 3 layer has excellent wear resistance and high temperature hardness, it exhibits excellent wear resistance and enables further extension of the service life.

つぎに、この発明の被覆サーメット工具を実施例により具体的に説明する。   Next, the coated cermet tool of the present invention will be specifically described with reference to examples.

原料粉末として、いずれも1〜3μmの平均粒径を有するWC粉末、TiC粉末、ZrC粉末、VC粉末、TaC粉末、NbC粉末、Cr32粉末、TiN粉末、およびCo粉末を用意し、これら原料粉末を、表1に示される配合組成に配合し、さらにワックスを加えてアセトン中で24時間ボールミル混合し、減圧乾燥した後、98MPaの圧力で所定形状の圧粉体にプレス成形し、この圧粉体を5Paの真空中、1370〜1470℃の範囲内の所定の温度に1時間保持の条件で真空焼結し、焼結後、切刃部にR:0.07mmのホーニング加工を施すことによりISO・CNMG120408に規定するスローアウエイチップ形状をもったWC基超硬合金製の工具基体A〜Fをそれぞれ製造した。 As raw material powders, WC powder, TiC powder, ZrC powder, VC powder, TaC powder, NbC powder, Cr 3 C 2 powder, TiN powder, and Co powder each having an average particle diameter of 1 to 3 μm are prepared. The raw material powder is blended in the blending composition shown in Table 1, added with wax, ball mill mixed in acetone for 24 hours, dried under reduced pressure, and press-molded into a green compact of a predetermined shape at a pressure of 98 MPa. The green compact is vacuum-sintered in a vacuum of 5 Pa at a predetermined temperature within a range of 1370 to 1470 ° C. for 1 hour. After sintering, the cutting edge is subjected to a honing process of R: 0.07 mm. Thus, tool bases A to F made of a WC-based cemented carbide having a throwaway tip shape specified in ISO · CNMG120408 were manufactured.

また、原料粉末として、いずれも0.5〜2μmの平均粒径を有するTiCN(質量比で、TiC/TiN=50/50)粉末、Mo2 C粉末、ZrC粉末、NbC粉末、TaC粉末、WC粉末、Co粉末、およびNi粉末を用意し、これら原料粉末を、表2に示される配合組成に配合し、ボールミルで24時間湿式混合し、乾燥した後、98MPaの圧力で圧粉体にプレス成形し、この圧粉体を1.3kPaの窒素雰囲気中、温度:1540℃に1時間保持の条件で焼結し、焼結後、切刃部分にR:0.07mmのホーニング加工を施すことによりISO規格・CNMG120412のチップ形状をもったTiCN基サーメット製の工具基体a〜fを形成した。 Further, as raw material powders, TiCN (mass ratio, TiC / TiN = 50/50) powder, Mo 2 C powder, ZrC powder, NbC powder, TaC powder, WC, all having an average particle diameter of 0.5 to 2 μm. Prepare powder, Co powder, and Ni powder, blend these raw material powders into the composition shown in Table 2, wet mix with a ball mill for 24 hours, dry, and press-mold into a green compact at 98 MPa pressure The green compact is sintered in a nitrogen atmosphere of 1.3 kPa at a temperature of 1540 ° C. for 1 hour, and after sintering, the cutting edge portion is subjected to a honing process of R: 0.07 mm. Tool bases a to f made of TiCN-based cermet having a chip shape conforming to ISO standards / CNMG 120212 were formed.

ついで、これらの工具基体A〜Fおよび工具基体a〜fのそれぞれを、通常の化学蒸着装置に装入し、
(a)まず、表3(表3中のl−TiCNは特開平6−8010号公報に記載される縦長成長結晶組織をもつTiCN層の形成条件を示すものであり、これ以外は通常の粒状結晶組織の形成条件を示すものである)に示される条件にて、表5,6に示される組み合わせおよび目標層厚で、Ti化合物層を硬質被覆層の下部層として蒸着形成し、
(b)ついで、表4に示される条件にて、表5,6に示される組み合わせよび目標層厚で、改質層(a)〜(j)のいずれかと標準層(1)〜(8)のいずれかからなる2重層α型Al23層を硬質被覆層の上部層として蒸着形成することにより本発明被覆サーメット工具1〜13をそれぞれ製造した。
Then, each of these tool bases A to F and tool bases a to f is charged into a normal chemical vapor deposition apparatus,
(A) First, Table 3 (l-TiCN in Table 3 indicates the conditions for forming a TiCN layer having a vertically elongated crystal structure described in JP-A-6-8010, and the other conditions are ordinary granularity. Under the conditions shown in Table 5 and 6 and the target layer thickness, the Ti compound layer is deposited as a lower layer of the hard coating layer under the conditions shown in Table 5).
(B) Next, under the conditions shown in Table 4, any one of the modified layers (a) to (j) and the standard layers (1) to (8) with the combinations and target layer thicknesses shown in Tables 5 and 6 The coated cermet tools 1 to 13 of the present invention were respectively produced by vapor-depositing a double layer α-type Al 2 O 3 layer made of any of the above as an upper layer of the hard coating layer.

また、比較の目的で、硬質被覆層の上部層である単層α型Al23層を、表4に示される標準層(1)〜(8)の形成条件(上記の通り、前記標準層(1)〜(8)の形成条件は単層α型Al23層の形成条件と同一である)にて、表7に示される組み合わせよび目標層厚で形成する以外は、上記の本発明被覆サーメット工具1〜13と同一の条件で従来被覆サーメット工具1〜13をそれぞれ製造した。 For comparison purposes, the single layer α-type Al 2 O 3 layer, which is the upper layer of the hard coating layer, is formed on the formation conditions of the standard layers (1) to (8) shown in Table 4 (as described above, the standard The formation conditions of the layers (1) to (8) are the same as the formation conditions of the single-layer α-type Al 2 O 3 layer), except for the combinations shown in Table 7 and the target layer thickness. Conventional coated cermet tools 1 to 13 were produced under the same conditions as the coated cermet tools 1 to 13 of the present invention.

ついで、上記の本発明被覆サーメット工具1〜13と従来被覆サーメット工具1〜13の硬質被覆層の上部層を構成する2重層α型Al23層および単層α型Al23層について、電界放出型走査電子顕微鏡を用いて、傾斜角度数分布グラフをそれぞれ作成した。
すなわち、上記傾斜角度数分布グラフは、上記の本発明被覆サーメット工具1〜13の2重層α型Al23層の改質層および標準層について、それぞれの表面をそれぞれ研磨面とした状態で、電界放出型走査電子顕微鏡の鏡筒内にセットし、前記研磨面に70度の入射角度で15kVの加速電圧の電子線を1nAの照射電流で、それぞれの前記表面研磨面の測定範囲内に存在する六方晶結晶格子を有する結晶粒個々に照射して、電子後方散乱回折像装置を用い、30×50μmの領域を0.1μm/stepの間隔で、前記研磨面の法線に対して、前記結晶粒の結晶面である(0001)面の法線がなす傾斜角を測定し、この測定結果に基づいて、前記測定傾斜角のうちの45〜90度の範囲内にある測定傾斜角を0.25度のピッチ毎に区分すると共に、各区分内に存在する度数を集計することにより作成した。
また、従来被覆サーメット工具1〜13の単層α型Al23層(上記の通り上記標準層(1)〜(8)のいずれかに相当)についても、表面研磨面を同一の条件で観察し、同一な条件で傾斜角度数分布グラフを作成した。
Subsequently, the double-layer α-type Al 2 O 3 layer and the single-layer α-type Al 2 O 3 layer constituting the upper layer of the hard coating layer of the above-described coated cermet tool 1 to 13 of the present invention and the conventional coated cermet tool 1 to 13 Using the field emission type scanning electron microscope, an inclination angle number distribution graph was prepared.
That is, the inclination angle number distribution graph shows the modified layer of the double layer α-type Al 2 O 3 layer and the standard layer of the above-described coated cermet tools 1 to 13 in a state where each surface is a polished surface. Set in a lens barrel of a field emission scanning electron microscope, and an electron beam with an acceleration voltage of 15 kV at an incident angle of 70 degrees on the polished surface is irradiated with 1 nA within the measurement range of each polished surface. By irradiating each crystal grain having an existing hexagonal crystal lattice and using an electron backscatter diffraction image apparatus, a region of 30 × 50 μm is spaced at a spacing of 0.1 μm / step with respect to the normal line of the polished surface. The inclination angle formed by the normal line of the (0001) plane which is the crystal plane of the crystal grain is measured, and based on the measurement result, the measurement inclination angle within the range of 45 to 90 degrees of the measurement inclination angle is calculated. Divided every 0.25 degree pitch In addition, it was created by counting the frequencies existing in each category.
Further, the surface polished surfaces of the conventional coated cermet tools 1 to 13 of the single layer α-type Al 2 O 3 layer (corresponding to any one of the standard layers (1) to (8) as described above) are also subjected to the same conditions. Observed and created a tilt angle number distribution graph under the same conditions.

この結果得られた各種のα型Al23層の傾斜角度数分布グラフにおいて、表5〜8にそれぞれ示される通り、本発明被覆サーメット工具1〜13の2重層α型Al23層の改質層は、(0001)面の測定傾斜角の分布が、それぞれ75〜85度の範囲内の傾斜角区分に最高ピークが現れる傾斜角度数分布グラフを示すのに対して、本発明被覆サーメット工具1〜13の2重層α型Al23層の標準層、並びに従来被覆サーメット工具1〜13の単層α型Al23層は、(0001)面の測定傾斜角の分布が45〜90度の範囲内で不偏的で、最高ピークが存在しない傾斜角度数分布グラフを示すものであった。
また表5〜7には、上記の各種のα型Al23層の傾斜角度数分布グラフにおいて、それぞれ75〜85囲内の傾斜角区分に存在する全傾斜角度数の傾斜角度数分布グラフ全体に占める割合を示した。
なお、図2,3は、本発明被覆サーメット工具2の2重層α型Al23層の改質層および標準層の傾斜角度数分布グラフ、図4は従来被覆サーメット工具5の単層α型Al23層の傾斜角度数分布グラフである。
In the gradient angle distribution graphs of the various α-type Al 2 O 3 layers obtained as a result, as shown in Tables 5 to 8, double-layer α-type Al 2 O 3 layers of the coated cermet tools 1 to 13 of the present invention, respectively. The modified layer of the present invention shows a gradient angle distribution graph in which the distribution of the measured inclination angle of the (0001) plane shows the highest peak in the inclination angle section within the range of 75 to 85 degrees, respectively. The standard layer of the double-layer α-type Al 2 O 3 layer of the cermet tools 1 to 13 and the single-layer α-type Al 2 O 3 layer of the conventional coated cermet tools 1 to 13 have a distribution of measured inclination angles on the (0001) plane. An inclination angle number distribution graph that is unbiased within the range of 45 to 90 degrees and does not have the highest peak is shown.
Tables 5 to 7 show the entire inclination angle distribution graphs of all inclination angle numbers existing in the inclination angle sections within 75 to 85 in the inclination angle distribution graphs of the various α-type Al 2 O 3 layers. The percentage of
2 and 3 are graphs showing the distribution of inclination angles of the double layer α-type Al 2 O 3 layer and the standard layer of the coated cermet tool 2 of the present invention, and FIG. 4 is a single layer α of the conventional coated cermet tool 5. the inclination angle frequency distribution graph of the mold the Al 2 O 3 layer.

また、この結果得られた本発明被覆サーメット工具1〜13および従来被覆サーメット工具1〜13の硬質被覆層の構成層の厚さを、走査型電子顕微鏡を用いて測定(縦断面測定)したところ、いずれも目標層厚と実質的に同じ平均層厚(5点測定の平均値)を示した。   Moreover, when the thickness of the constituent layer of the hard coating layer of the present invention coated cermet tools 1 to 13 and the conventional coated cermet tools 1 to 13 obtained as a result was measured using a scanning electron microscope (longitudinal section measurement) , Each showed an average layer thickness (average value of 5-point measurement) substantially the same as the target layer thickness.

つぎに、上記の本発明被覆サーメット工具1〜13および従来被覆サーメット工具1〜13各種の被覆サーメット工具について、いずれも工具鋼製バイトの先端部に固定治具にてネジ止めした状態で、
被削材:JIS・S45Cの丸棒、
切削速度:400m/min.、
切り込み:1.0mm、
送り: 0.2mm/rev.、
切削時間: 12分、
の条件(切削条件Aという)での炭素鋼の乾式連続高速切削試験(通常の切削速度は200m/min.)、
被削材:JIS・SNCM439の丸棒、
切削速度:350m/min.、
切り込み:1.0mm、
送り: 0.3mm/rev.、
切削時間: 9分、
の条件(切削条件Bという)での合金鋼の乾式連続高速切削試験(通常の切削速度は150m/min.)、さらに、
被削材:JIS・FC250の丸棒、
切削速度:450m/min.、
切り込み:1.0mm、
送り: 0.25mm/rev.、
切削時間: 8分、
の条件(切削条件Cという)での鋳鉄の乾式連続高速切削試験(通常の切削速度は200m/min.)を行い、いずれの切削試験でも切刃の逃げ面摩耗幅を測定した。この測定結果を表8に示した。
Next, for the various coated cermet tools of the present invention coated cermet tool 1-13 and the conventional coated cermet tool 1-13, all of them are screwed with a fixing jig to the tip of the tool steel tool,
Work material: JIS / S45C round bar,
Cutting speed: 400 m / min. ,
Cutting depth: 1.0 mm,
Feed: 0.2 mm / rev. ,
Cutting time: 12 minutes,
Dry continuous high-speed cutting test of carbon steel under the conditions (cutting condition A) (normal cutting speed is 200 m / min.),
Work material: JIS / SNCM439 round bar,
Cutting speed: 350 m / min. ,
Cutting depth: 1.0 mm,
Feed: 0.3 mm / rev. ,
Cutting time: 9 minutes
Dry continuous high-speed cutting test (normal cutting speed is 150 m / min.) Of alloy steel under the following conditions (referred to as cutting conditions B),
Work material: JIS / FC250 round bar,
Cutting speed: 450 m / min. ,
Cutting depth: 1.0 mm,
Feed: 0.25 mm / rev. ,
Cutting time: 8 minutes,
The dry continuous high-speed cutting test (normal cutting speed is 200 m / min.) Of cast iron under the above conditions (referred to as cutting condition C), and the flank wear width of the cutting edge was measured in any cutting test. The measurement results are shown in Table 8.

Figure 2006315149
Figure 2006315149

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Figure 2006315149
Figure 2006315149

Figure 2006315149
Figure 2006315149

表5〜8に示される結果から、本発明被覆サーメット工具1〜13は、いずれも硬質被覆層の上部層である2重層α型Al23層の上下2重層構造の改質層が、(0001)面の傾斜角度数分布グラフで75〜85度の範囲内の傾斜角区分で最高ピークを示し、この結果として相対的にすぐれた耐摩耗性を有し、一方同標準層が相対的にすぐれた高温硬さを保持することから、鋼や鋳鉄の切削加工を、高速で行っても、すぐれた耐摩耗性を示すのに対して、硬質被覆層の上部層全体が、(0001)面の測定傾斜角の分布が45〜90度の範囲内で不偏的で、最高ピークが存在しない傾斜角度数分布グラフを示し、前記標準層(a)〜(h)のいずれかに相当する単層α型Al23層で構成された従来被覆サーメット工具1〜13においては、いずれも前記単層α型Al23層の耐摩耗性不足が原因で、高速切削条件では硬質被覆層の磨耗が著しく促進され、比較的短時間で使用寿命に至ることが明らかである。 From the results shown in Tables 5 to 8, the coated cermet tools 1 to 13 of the present invention each have a double layer α-type Al 2 O 3 layer upper and lower double layer structure modified layer, which is the upper layer of the hard coating layer. The (0001) plane tilt angle number distribution graph shows the highest peak in the tilt angle section in the range of 75 to 85 degrees, and as a result, it has relatively good wear resistance, while the standard layer is relatively Because it retains excellent high-temperature hardness, it exhibits excellent wear resistance even when cutting steel and cast iron at high speed, whereas the entire upper layer of the hard coating layer is (0001) The distribution of the measured inclination angle of the surface is unbiased within the range of 45 to 90 degrees, and shows an inclination angle number distribution graph in which the highest peak does not exist, and corresponds to any one of the standard layers (a) to (h). in the conventional coated cermet tools 1 to 13 that comprises a layer α type the Al 2 O 3 layer Both because of the wear resistance shortage of the single layer α type the Al 2 O 3 layer, a high-speed cutting conditions abrasion of the hard coating layer is accelerated significantly, it is apparent that lead to a relatively short time using life .

上述のように、この発明の被覆サーメット工具は、各種鋼や鋳鉄などの通常の条件での連続切削や断続切削は勿論のこと、特に高速切削でもチッピングの発生なく、すぐれた耐摩耗性を示し、長期に亘ってすぐれた切削性能を発揮するものであるから、切削装置の高性能化並びに切削加工の省力化および省エネ化、さらに低コスト化に十分満足に対応できるものである。   As described above, the coated cermet tool of the present invention exhibits excellent wear resistance without occurrence of chipping even in continuous cutting and intermittent cutting under normal conditions such as various steels and cast irons, especially in high-speed cutting. Since it exhibits excellent cutting performance over a long period of time, it can satisfactorily respond to higher performance of the cutting device, labor saving and energy saving of cutting, and further cost reduction.

硬質被覆層を構成するα型Al23層における結晶粒の(0001)面を測定する場合の傾斜角の測定範囲を示す概略説明図である。It is a schematic diagram illustrating a measurement range of the inclination angle of the case of measuring the crystal grain of the α-type the Al 2 O 3 layer constituting the hard coating layer (0001) plane. 本発明被覆サーメット工具2の硬質被覆層を構成する2重層α型Al23層の改質層の(0001)面の傾斜角度数分布グラフである。It is an inclination angle number distribution graph of the (0001) plane of the modified layer of the double layer α-type Al 2 O 3 layer constituting the hard coating layer of the coated cermet tool 2 of the present invention. 本発明被覆サーメット工具2の硬質被覆層を構成する2重層α型Al23層の標準層の(0001)面の傾斜角度数分布グラフである。It is an inclination angle number distribution graph of the (0001) plane of the standard layer of the double layer α-type Al 2 O 3 layer constituting the hard coating layer of the coated cermet tool 2 of the present invention. 従来被覆サーメット工具5の硬質被覆層を構成する単層α型Al23層(標準層に相当)の(0001)面の傾斜角度数分布グラフである。6 is a graph showing the distribution of the number of inclination angles on the (0001) plane of a single-layer α-type Al 2 O 3 layer (corresponding to a standard layer) constituting a hard coating layer of a conventional coated cermet tool 5.

Claims (1)

炭化タングステン基超硬合金または炭窒化チタン基サーメットで構成された工具基体の表面に、
(a)下部層として、Tiの炭化物層、窒化物層、炭窒化物層、炭酸化物層、および炭窒酸化物層のうちの1層または2層以上からなり、かつ3〜20μmの全体平均層厚を有するTi化合物層、
(b)上部層として、化学蒸着した状態でα型の結晶構造を有し、かつ2〜15μmの平均層厚を有する酸化アルミニウム層、
以上(a)および(b)で構成された硬質被覆層を化学蒸着形成してなる表面被覆サーメット製切削工具において、
上記α型酸化アルミニウム層を、酸化アルミニウム層全体の平均層厚に占める割合で55〜80%の改質層と、残りの標準層からなる上下2重層構造とし、さらに電界放出型走査電子顕微鏡を用い、表面研磨面の測定範囲内に存在する六方晶結晶格子を有する結晶粒個々に電子線を照射して、前記表面研磨面の法線に対して、前記結晶粒の結晶面である(0001)面の法線がなす傾斜角を測定し、前記測定傾斜角のうちの45〜90度の範囲内にある測定傾斜角を0.25度のピッチ毎に区分すると共に、各区分内に存在する度数を集計してなる傾斜角度数分布グラフで表した場合、
(A)上記酸化アルミニウム層の改質層は、75〜85度の範囲内の傾斜角区分に最高ピークが存在すると共に、前記75〜85度の範囲内に存在する度数の合計が、傾斜角度数分布グラフにおける度数全体の45〜65%の割合を占める傾斜角度数分布グラフを示し、
(B)上記酸化アルミニウム層の標準層は、45〜90度の範囲の測定傾斜角区分全体に亘ってピークが存在せず、測定傾斜角の分布が45〜90度のいずれの範囲内でも不偏的な傾斜角度数分布グラフを示す、
以上(A)および(B)からなる2重層α型酸化アルミニウム層で構成したことを特徴とする硬質被覆層が高速切削ですぐれた耐摩耗性を発揮する表面被覆サーメット製切削工具。
On the surface of the tool base composed of tungsten carbide based cemented carbide or titanium carbonitride based cermet,
(A) As a lower layer, it consists of one or more of Ti carbide layer, nitride layer, carbonitride layer, carbonate layer, and carbonitride oxide layer, and has an overall average of 3 to 20 μm A Ti compound layer having a layer thickness,
(B) As an upper layer, an aluminum oxide layer having an α-type crystal structure in a chemical vapor deposited state and an average layer thickness of 2 to 15 μm,
In the surface-coated cermet cutting tool formed by chemical vapor deposition of the hard coating layer composed of (a) and (b) above,
The α-type aluminum oxide layer has an upper and lower double layer structure consisting of 55 to 80% of the modified layer and the remaining standard layer in the ratio of the average thickness of the entire aluminum oxide layer, and a field emission scanning electron microscope. The crystal grain of the crystal grain is used with respect to the normal of the surface polished surface by irradiating each crystal grain having a hexagonal crystal lattice existing within the measurement range of the surface polished surface with an electron beam (0001 ) Measure the tilt angle formed by the normal of the surface, and divide the measured tilt angle within the range of 45-90 degrees of the measured tilt angle by pitch of 0.25 degrees and exist in each section When it is represented by a tilt angle frequency distribution graph that is a sum of the frequencies to be
(A) The modified layer of the aluminum oxide layer has the highest peak in the inclination angle section within the range of 75 to 85 degrees, and the sum of the frequencies existing in the range of 75 to 85 degrees is the inclination angle. The inclination angle frequency distribution graph which occupies the ratio of 45 to 65% of the whole frequency in the number distribution graph is shown.
(B) The standard layer of the aluminum oxide layer has no peak over the entire measurement inclination angle range in the range of 45 to 90 degrees, and the distribution of the measurement inclination angle is unbiased even in any range of 45 to 90 degrees. Showing a typical inclination angle number distribution graph,
A surface-coated cermet cutting tool in which a hard coating layer characterized by comprising a double-layer α-type aluminum oxide layer comprising the above (A) and (B) exhibits excellent wear resistance in high-speed cutting.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8404366B2 (en) * 2007-01-02 2013-03-26 Taegutec, Ltd. Surface treating method for cutting tools

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8404366B2 (en) * 2007-01-02 2013-03-26 Taegutec, Ltd. Surface treating method for cutting tools

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