JP2006300410A - Ash melting furnace - Google Patents

Ash melting furnace Download PDF

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JP2006300410A
JP2006300410A JP2005122557A JP2005122557A JP2006300410A JP 2006300410 A JP2006300410 A JP 2006300410A JP 2005122557 A JP2005122557 A JP 2005122557A JP 2005122557 A JP2005122557 A JP 2005122557A JP 2006300410 A JP2006300410 A JP 2006300410A
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refractory
furnace
hearth
ash melting
ash
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Japanese (ja)
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Makoto Ozaki
誠 尾崎
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Daido Steel Co Ltd
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Daido Steel Co Ltd
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  • Vertical, Hearth, Or Arc Furnaces (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide an ash melting furnace prevented from erosion, seepage, or the like of a hearth structure such as firebricks or a monolithic refractory in a short period of time in melting ashes under actual circumstances where the variation of composition of the ashes to be melted cannot be predicted. <P>SOLUTION: The ash melting furnace with electrodes inserted in the furnace and with the firebricks laid in inverted arch shape as a whole on the hearth through the monolithic refractory, is constituted to melt the ashes charged in the furnace by applying a current to the electrodes, wherein the monolithic refractory of completely different material from the firebricks is placed further on the upper face of the firebricks laid in inverted arch shape as a whole on the hearth. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は灰溶融炉に関する。都市ごみや産業廃棄物等を焼却処理すると、焼却灰や飛灰等の灰が発生する。かかる灰は、これを減容化及び無害化するため、灰溶融炉を用いて溶融処理する。本発明は、かかる灰溶融炉の改良に関する。   The present invention relates to an ash melting furnace. When municipal waste or industrial waste is incinerated, ash such as incineration ash and fly ash is generated. Such ash is melted using an ash melting furnace in order to reduce the volume and make it harmless. The present invention relates to an improvement of such an ash melting furnace.

従来、前記のような灰溶融炉として、炉内に電極が挿入されており、炉床に不定形耐火物を介し耐火レンガが全体として逆アーチ状に敷設されていて、炉内へ装入した灰を該電極へ通電することにより溶融処理するようにしたものが知られている(例えば特許文献1参照)。かかる従来の灰溶融炉では、炉床に全体として逆アーチ状に敷設された耐火レンガとしてAlを主材とし且つSiCを含有するAl系のもの、例えばAl−SiC系やAl−SiC−C系のものを用いるのが好ましく、またかかる耐火レンガの更に表面を同様にAlを主材とするAl系のもの、例えばAl−Cr系やAl−SiO系の不定形耐火物で保護するのが好ましいこと等も提案されている。 Conventionally, as an ash melting furnace as described above, an electrode is inserted in the furnace, and the refractory bricks are laid in a reverse arch shape as a whole on the hearth via an indeterminate refractory and charged into the furnace. What melt | dissolved the ash by supplying with electricity to this electrode is known (for example, refer patent document 1). In such a conventional ash melting furnace, an Al 2 O 3 -based material containing Al 2 O 3 as a main material and containing SiC, for example, Al 2 O 3 − it is preferred to use those of SiC-based or Al 2 O 3 -SiC-C system, also those of Al 2 O 3 system to further composed primarily Similarly the Al 2 O 3 surface of such refractory bricks, for example Al 2 It has also been proposed that it is preferable to protect with an O 3 —Cr 2 O 3 -based or Al 2 O 3 —SiO 2 -based amorphous refractory.

しかし、前記のような従来の灰溶融炉には、灰の溶融処理に際して、通常は炉床に敷設されている耐火レンガやこれを保護するための不定形耐火物の侵食や浸潤等が少ないものの、その由来に起因する灰の組成の変動によるものと推察されるが、時として炉床に敷設されている耐火レンガやこれを保護するための不定形耐火物が短期間に侵食や浸潤等を受けてしまうことが生じるという問題がある。
特開平5−118522号公報
However, in the conventional ash melting furnace as described above, there is little erosion or infiltration of the refractory bricks usually laid on the hearth or the amorphous refractory for protecting the ash melting process. It is speculated that this is due to fluctuations in the composition of ash due to its origin, but sometimes refractory bricks laid on the hearth and irregular refractories to protect this erode or infiltrate in a short period of time. There is a problem that it may occur.
Japanese Patent Laid-Open No. 5-118522

本発明が解決しようとする課題は、その由来に起因するものと推察されるが、溶融処理の対象である灰の組成の変動が予測できない実情の下で、かかる灰を溶融処理するに際して、耐火レンガや不定形耐火物等の炉床構築物が短期間に侵食や浸潤等を受けてしまうのを防止できる灰溶融炉を提供する処にある。   The problem to be solved by the present invention is presumed to be attributable to its origin, but when the ash is melt-treated under the circumstances where fluctuations in the composition of the ash that is the subject of the melt treatment cannot be predicted, The present invention is to provide an ash melting furnace that can prevent a hearth structure such as a brick or an irregular refractory from being eroded or infiltrated in a short time.

前記の課題を解決する本発明は、炉内に電極が挿入されており、炉床に不定形耐火物を介し耐火レンガが全体として逆アーチ状に敷設されていて、炉内へ装入した灰を該電極へ通電することにより溶融処理するようにした灰溶融炉において、炉床に全体として逆アーチ状に敷設された耐火レンガの更に上面に該耐火レンガとは全く異なる材質の不定形耐火物が打設されて成ることを特徴とする灰溶融炉に係る。   The present invention that solves the above-mentioned problem is that an ash is inserted in the furnace, with electrodes inserted in the furnace, and refractory bricks are laid in a reverse arch shape as a whole on the hearth via an irregular refractory. In an ash melting furnace which is melted by energizing the electrode, an amorphous refractory made of a material completely different from the refractory brick is further provided on the upper surface of the refractory brick laid in a reverse arch shape on the hearth as a whole. The present invention relates to an ash melting furnace.

本発明に係る灰溶融炉も、炉内に電極が挿入されており、炉床に不定形耐火物を介し耐火レンガが全体として逆アーチ状に敷設されていて、炉内へ装入した灰を該電極へ通電することにより溶融処理するようになっている。したがって本発明に係る灰溶融炉は所謂電気炉であり、かかる電気炉としては抵抗炉、アーク炉、プラズマアーク炉、プラズマ炉等が挙げられるが、アーク炉又はプラズマアーク炉が好ましい。   Also in the ash melting furnace according to the present invention, an electrode is inserted in the furnace, and refractory bricks are laid in a reverse arch shape as a whole on the hearth via an irregular refractory, and the ash charged into the furnace is removed. Melting is performed by energizing the electrode. Therefore, the ash melting furnace according to the present invention is a so-called electric furnace, and examples of such an electric furnace include a resistance furnace, an arc furnace, a plasma arc furnace, and a plasma furnace, and an arc furnace or a plasma arc furnace is preferable.

本発明に係る灰溶融炉では、炉床に全体として逆アーチ状に敷設された耐火レンガの更に上面に該耐火レンガとは全く異なる材質の不定形耐火物が打設されている。ここで、全く異なる材質というのは、炉床に全体として逆アーチ状に敷設された耐火レンガと、かかる耐火レンガの更に上面に打設された不定形耐火物との間で、少なくともその主材が異なるという意味である。例えば、炉床に全体として逆アーチ状に敷設された耐火レンガとしてAlを主材とし且つSiCを含有するAl系のもの、より具体的にはAl−SiC系やAl−SiC−C系のものを用いた場合には、かかる耐火レンガの更に上面に打設する不定形耐火物として、同様にAlを主材とする酸化物系のもの、より具体的にはAl−Cr系やAl−SiO系のものを用いるのではなく、MgOを主材とするMgO−Al系やMgO−Cr系のものを用いるのである。炉床に全体として逆アーチ状に敷設された耐火レンガと、かかる耐火レンガの更に上面に打設された不定形耐火物との間で、前記したAlのようにその主材が同じであると、同じ原因でかかる耐火レンガや不定形耐火物が短期間に侵食や浸潤等を受けることとなるため、予測できない灰の組成の変動に対応できなくなるからである。 In the ash melting furnace according to the present invention, an amorphous refractory made of a material completely different from the refractory brick is placed on the upper surface of the refractory brick laid in a reverse arch shape as a whole on the hearth. Here, a completely different material is at least the main material between a refractory brick laid on the hearth in a reverse arch shape as a whole and an irregular refractory placed on the upper surface of the refractory brick. Means different. For example, as a refractory brick laid in a reverse arch shape as a whole on the hearth, an Al 2 O 3 based material containing Al 2 O 3 as a main material and containing SiC, more specifically an Al 2 O 3 —SiC based material When an Al 2 O 3 —SiC—C-based material is used, an amorphous refractory placed on the upper surface of the refractory brick is similarly used as an oxide-based material mainly composed of Al 2 O 3 . Rather than using an Al 2 O 3 —Cr 2 O 3 type or Al 2 O 3 —SiO 2 type, MgO—Al 2 O 3 type or MgO— containing MgO as the main material A Cr 2 O 3 -based material is used. The main material is the same as Al 2 O 3 described above between the refractory brick laid in a reverse arch shape as a whole on the hearth and the irregular refractory placed on the upper surface of the refractory brick. If this is the case, the refractory bricks and irregular refractories for the same reason are subject to erosion, infiltration, etc. in a short period of time, making it impossible to cope with unpredictable variations in ash composition.

本発明に係る灰溶融炉では、以上説明したように、炉床に全体として逆アーチ状に耐火レンガが敷設されており、かかる耐火レンガの更に上面に該耐火レンガとは全く異なる材質の不定形耐火物が打設されている。かかる不定形耐火物に代えて、別に耐火レンガを敷設し、したがっていわば上下2段で全く異なる材質の耐火レンガを積むことも考えられるが、このようにすると、以上説明したような本発明に係る灰溶融炉に比べて、著しく非経済的になるだけでなく、これらの耐火レンガの補修や交替等が著しく厄介になる。   In the ash melting furnace according to the present invention, as described above, refractory bricks are laid in a reverse arch shape as a whole on the hearth, and the refractory bricks are made of a material that is completely different from the refractory bricks on the upper surface of the refractory bricks. Refractories are placed. In place of such an irregular refractory, it is conceivable that a refractory brick is separately laid, so that it is possible to stack refractory bricks of completely different materials in the upper and lower two stages, but in this way, according to the present invention as described above. Compared to ash melting furnaces, not only is it uneconomical, but repair and replacement of these refractory bricks become extremely troublesome.

本発明に係る灰溶融炉によると、溶融処理の対象である灰の組成の変動が予測できない実情の下で、かかる灰を溶融処理するに際して、耐火レンガや不定形耐火物等の炉床構築物が短期間に侵食や浸潤等を受けてしまうのを防止できる。   According to the ash melting furnace according to the present invention, when the ash is melt-processed under a situation where fluctuations in the composition of the ash to be melt-processed cannot be predicted, a hearth structure such as a refractory brick or an amorphous refractory is provided. It is possible to prevent erosion or infiltration in a short time.

図1は本発明に係る灰溶融炉を例示する縦断面図である。ここでは、3相交流アーク炉の場合を例示している。炉本体1の上部に炉蓋2が開閉可能に被着されており、炉蓋2を貫通して炉内に電極3が挿入されている。炉本体1の炉殻4にはその炉床に不定形耐火物5が打設されており、不定形耐火物5の上面は全体として逆アーチ状に形成されている。不定形耐火物5の上面には耐火レンガ6が敷設されており、したがって耐火レンガ6は全体として逆アーチ状になっている。耐火レンガ6の更に上面には耐火レンガ6とは全く異なる材質の不定形耐火物7が打設されており、したがって不定形耐火物7も全体として逆アーチ状になっている。図1に例示した灰溶融炉では、耐火レンガ6はAlを55質量%及びSiCを35質量%含有するAl−SiC系のものを用いており、また不定形耐火物7はMgOを94質量%含有するMgO系のものを用いている。 FIG. 1 is a longitudinal sectional view illustrating an ash melting furnace according to the present invention. Here, the case of a three-phase AC arc furnace is illustrated. A furnace lid 2 is attached to the top of the furnace body 1 so as to be openable and closable, and an electrode 3 is inserted into the furnace through the furnace lid 2. An indeterminate refractory 5 is placed on the hearth 4 of the furnace shell 4 of the furnace body 1, and the upper surface of the indeterminate refractory 5 is formed in a reverse arch shape as a whole. A refractory brick 6 is laid on the upper surface of the irregular refractory 5, and thus the refractory brick 6 has a reverse arch shape as a whole. On the upper surface of the refractory brick 6, an irregular refractory 7 made of a material different from that of the refractory brick 6 is placed. Therefore, the irregular refractory 7 is also formed in a reverse arch shape as a whole. In the ash melting furnace illustrated in FIG. 1, the refractory brick 6 uses an Al 2 O 3 —SiC-based refractory 7 containing 55% by mass of Al 2 O 3 and 35% by mass of SiC. Uses an MgO-based material containing 94% by mass of MgO.

炉殻4の炉壁には耐火レンガ8,9が内張りされており、図示を省略するが、炉蓋2には灰の投入口や排気口等が、また炉本体1には溶融スラグ排出口等が設けられている。図示した灰溶融炉の場合、炉内へ装入した灰を電極3へ通電することにより発生するアークで溶融処理するようになっており、炉内にはかかる溶融処理により生成した溶融メタル層Aと溶融スラグ層Bとが形成されている。   Although the refractory bricks 8 and 9 are lined on the furnace wall of the furnace shell 4, illustration is omitted, but the furnace lid 2 has an ash inlet and an exhaust outlet, and the furnace body 1 has a molten slag outlet. Etc. are provided. In the case of the illustrated ash melting furnace, the ash charged into the furnace is melted by an arc generated by energizing the electrode 3, and the molten metal layer A generated by the melting process is contained in the furnace. And a molten slag layer B are formed.

本発明に係る灰溶融炉を例示する縦断面図。The longitudinal cross-sectional view which illustrates the ash melting furnace which concerns on this invention.

符号の説明Explanation of symbols

1 炉本体
2 炉蓋
3 電極
4 炉殻
5,7 不定形耐火物
6,8,9 耐火レンガ
A 溶融メタル層
B 溶融スラグ層
DESCRIPTION OF SYMBOLS 1 Furnace body 2 Furnace lid 3 Electrode 4 Furnace shell 5,7 Amorphous refractory 6,8,9 Refractory brick A Molten metal layer B Molten slag layer

Claims (2)

炉内に電極が挿入されており、炉床に不定形耐火物を介し耐火レンガが全体として逆アーチ状に敷設されていて、炉内へ装入した灰を該電極へ通電することにより溶融処理するようにした灰溶融炉において、炉床に全体として逆アーチ状に敷設された耐火レンガの更に上面に該耐火レンガとは全く異なる材質の不定形耐火物が打設されて成ることを特徴とする灰溶融炉。   An electrode is inserted in the furnace, and the refractory bricks are laid in a reverse arch shape as a whole via an irregular refractory on the hearth, and the ash charged into the furnace is melted by energizing the electrode. In the ash melting furnace constructed as described above, the refractory brick laid in a reverse arch shape as a whole on the hearth is further provided with an indeterminate refractory made of a material completely different from the refractory brick. Ash melting furnace. 炉床に全体として逆アーチ状に敷設された耐火レンガがAlを主材とし且つSiCを含有するAl系のものであり、該耐火レンガの更に上面に打設された不定形耐火物がMgOを主材とするMgO系のものである請求項1記載の灰溶融炉。
Is of Al 2 O 3 system refractory bricks laid in reverse arch shape as a whole in the hearth and containing SiC as a main material an Al 2 O 3, not being Da設further the upper surface of the refractory bricks 2. The ash melting furnace according to claim 1, wherein the regular refractory is an MgO-based material mainly composed of MgO.
JP2005122557A 2005-04-20 2005-04-20 Ash melting furnace Pending JP2006300410A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010039570A2 (en) * 2008-09-30 2010-04-08 Hemlock Semiconductor Corporation Method of determining an amount of impurities that a contaminating material contributes to high purity silicon and furnace for treating high purity silicon
WO2019140819A1 (en) * 2018-01-19 2019-07-25 东北大学 Method for designing electrode diameter and furnace shell shape of two-phase direct-current (dc) fused magnesia furnace

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010039570A2 (en) * 2008-09-30 2010-04-08 Hemlock Semiconductor Corporation Method of determining an amount of impurities that a contaminating material contributes to high purity silicon and furnace for treating high purity silicon
WO2010039570A3 (en) * 2008-09-30 2010-11-18 Hemlock Semiconductor Corporation Method of determining an amount of impurities that a contaminating material contributes to high purity silicon and furnace for treating high purity silicon
US8895324B2 (en) 2008-09-30 2014-11-25 Hemlock Semiconductor Corporation Method of determining an amount of impurities that a contaminating material contributes to high purity silicon
WO2019140819A1 (en) * 2018-01-19 2019-07-25 东北大学 Method for designing electrode diameter and furnace shell shape of two-phase direct-current (dc) fused magnesia furnace

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