JP2006255915A - Embossed decorative paper, its manufacturing method and paper container using embossed decorative paper - Google Patents
Embossed decorative paper, its manufacturing method and paper container using embossed decorative paper Download PDFInfo
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本発明は、板紙等紙基材の表面にエンボス加工で微細な凹凸を付けて加飾し、その商品価値を高めるエンボス加飾紙およびその製造方法、それを用いたエンボス加飾紙製容器に関するものであり、特に、高級清酒等の紙箱用として、その表面にアルミニウム箔等で金属光沢を施し、その上に微細な凹凸パターンを施した美麗なエンボス加飾紙及びその製造方法並びにそれを用いた紙製容器に関する。 TECHNICAL FIELD The present invention relates to an embossed decorative paper that embellishes the surface of a paper substrate such as paperboard by embossing and decorates it, increases its commercial value, a manufacturing method thereof, and an embossed decorative paper container using the embossed decorative paper Especially for paper boxes for high-quality sake, etc., a beautiful embossed decorative paper with its surface glossy with aluminum foil etc. and a fine uneven pattern on it, its manufacturing method and its use It relates to a paper container.
従来、例えば高級清酒やウイスキーなどの紙箱として、その側壁面にエンボス加工で模様状の微細な凹凸を施し、その紙箱の商品価値を高めたものが知られ、さらにそれを美麗化するため、紙基材の表面にアルミニウム箔などで金属光沢を施し、それに印刷とエンボス加工で模様状の微細な凹凸とが見当が合った状態で施されたものがある(例えば、特許文献1参照。)。 Conventionally, for example, a high-quality sake or whiskey paper box, which has been embossed with fine pattern irregularities on its side wall surface to increase the commercial value of the paper box, and to make it even more beautiful, There is one in which a metallic luster is applied to the surface of the base material with an aluminum foil or the like, and fine pattern unevenness is registered by printing and embossing (for example, refer to Patent Document 1).
また一方、上記美麗化のためのエンボス加工の模様(デザインなど)として、基材の表面の金属箔(アルミニウム箔)層に万線方向が異なる万線状凹凸パターン群が複数集合したエンボスパターンを形成したもので、見る角度を変化させると万線状凹凸パターン群の濃淡や輝きが動的に変化する所謂オパール効果を有する「オパール像」がある(例えば、特許文献2参照。)。 On the other hand, as an embossing pattern (design etc.) for the above-mentioned beautification, an emboss pattern in which a plurality of line-shaped uneven pattern groups having different line directions are gathered on the metal foil (aluminum foil) layer on the surface of the base material. There is an “opal image” that has a so-called opal effect in which the shading and brightness of the line-shaped uneven pattern group dynamically changes when the viewing angle is changed (see, for example, Patent Document 2).
以下に、上記先行技術文献を示す。
しかしながら、上記の従来技術、すなわち紙基材の表面にアルミニウム箔などで金属光沢層が施された金属光沢原紙にエンボス加工により模様状(万線状等)の微細な凹凸パターンを施したものは、紙基材の密度のムラ(紙基材の繊維間の隙間等に基づく表面粗さなどによる)が金属光沢層面にもろに現れ、その濃淡の鮮明さ(シャープ性)や輝きに欠けるようになり、所謂「オパール効果」に欠け、本来の美麗さが失われるという問題点があった。 However, the above-mentioned conventional technology, that is, a metal glossy base paper with a metallic gloss layer made of aluminum foil or the like on the surface of a paper base material, has been subjected to embossing to give a fine concavo-convex pattern such as a line shape. , Uneven density of the paper base material (due to surface roughness based on gaps between fibers of the paper base material) appears on the surface of the metallic luster layer, and lacks the sharpness and brightness of the light and shade Thus, there was a problem that the so-called “opal effect” was lacking and the original beauty was lost.
本発明は、かかる従来技術の問題点を解決するものであり、その課題とするところは、紙基材上に金属光沢層が施された金属光沢原紙にエンボス加工で万線状パターン群でなる模様状の微細な凹凸を施したエンボス加飾紙において、紙基材の密度のムラ等が金属光沢層に現れることがなく本来の美麗さを有するエンボス加飾紙およびその製造方法並びにそれを用いた紙製容器を提供することにある。 The present invention solves the problems of the prior art, and the problem is that the metallic gloss base paper having a metallic gloss layer on a paper base material is formed by a line pattern group by embossing. In embossed decorative paper with fine pattern irregularities, the embossed decorative paper has its original beauty without unevenness of density of the paper base material appearing in the metallic luster layer, its manufacturing method and its use It is to provide a paper container.
本発明に於いて上記課題を達成するために、まず請求項1の発明では、紙基材上に熱成形性樹脂層を介して金属光沢層が施された金属光沢原紙に、加熱エンボス加工による万線状パターン群でなる微細な凹凸部が施されていることを特徴とするエンボス加飾紙としたものである。
In order to achieve the above object in the present invention, first, in the invention of
また、請求項2の発明では、前記加熱エンボス加工による万線状パターン群でなる微細な凹凸部は、その高度差が0.003〜0.1mmの範囲でなり、そのピッチが0.005〜0.3mmの範囲でなることを特徴とする請求項1記載のエンボス加飾紙としたものである。
Further, in the invention of claim 2, the fine irregularities formed by the line-shaped pattern group by the heat embossing have a height difference in a range of 0.003 to 0.1 mm, and a pitch of 0.005 to 0.005. The embossed decorative paper according to
また、請求項3の発明では、紙基材と金属光沢層とを熱成形性を有する樹脂でサンドウイッチラミネートして金属光沢原紙を作製し、該金属光沢原紙の金属光沢層面上に、万線状パターン群でなる微細な凹凸部が施された平板タイプのエンボス版を、加熱し上下動せしめて加圧することを特徴とするエンボス加飾紙の製造方法としたものである。
In the invention of
また、請求項4の発明では、紙基材に熱成形性を有する樹脂を溶融押出しで熱成形性樹脂層を形成し、該熱成形性樹脂層面に金属蒸着薄膜の蒸着もしくは転写によって金属光沢層を施して金属光沢原紙を作製し、該金属光沢原紙の金属光沢層面上に、万線状パターン群でなる微細な凹凸部が施された平板タイプのエンボス版を、加熱し上下動せしめて加圧することを特徴とするエンボス加飾紙の製造方法としたものである。 According to a fourth aspect of the present invention, a thermoforming resin layer is formed by melt-extruding a resin having thermoformability on a paper substrate, and a metallic gloss layer is formed on the surface of the thermoformable resin layer by vapor deposition or transfer of a metal vapor deposition thin film. To produce a metallic glossy base paper, and heat the plate-type embossed plate with fine irregularities made of line-shaped patterns on the surface of the metallic glossy base paper. It is set as the manufacturing method of the embossed decorative paper characterized by pressing.
また、請求項5の発明では、紙基材に熱成形性を有する樹脂を溶融押出しで熱成形性樹脂層を形成し、該熱成形性樹脂層面にアルミニウムペーストインキによる印刷で金属光沢層を施して金属光沢原紙を作製し、該金属光沢原紙の金属光沢層面上に、万線状パターン群でなる微細な凹凸部が施された平板タイプのエンボス版を、加熱し上下動せしめて加圧することを特徴とするエンボス加飾紙の製造方法としたものである。 In the invention of claim 5, a thermoformable resin layer is formed by melt extrusion of a resin having a thermoformability on a paper substrate, and a metallic luster layer is applied to the surface of the thermoformable resin layer by printing with an aluminum paste ink. To produce a metallic glossy base paper, and heat and move the plate-type embossed plate with fine irregularities made of line-shaped patterns on the metallic glossy layer surface of the metallic glossy base paper to pressurize it. It is set as the manufacturing method of the embossed decorative paper characterized by these.
また、請求項6の発明では、前記平板タイプのエンボス版に施された万線状パターン群でなる微細な凹凸部は、その深さが0.003〜0.1mmの範囲でなり、そのピッチが0.005〜0.3mmの範囲でなることを特徴とする請求項3乃至5のいずれか1項記載のエンボス加飾紙の製造方法としたものである。
Further, in the invention of claim 6, the fine irregularities formed by the line-shaped pattern group applied to the flat plate type embossed plate have a depth in the range of 0.003 to 0.1 mm and the pitch. Is in the range of 0.005 to 0.3 mm, the embossed decorative paper manufacturing method according to any one of
さらにまた、請求項7の発明では、上記請求項1または2記載のエンボス加飾紙を用いた紙製容器としたものである。
Furthermore, in invention of Claim 7, it is set as the paper container using the embossed decorative paper of the said
本発明は以上の構成であるから、下記に示す如き効果がある。 Since this invention is the above structure, there exist the following effects.
即ち、上記請求項1に係る発明によれば、紙基材上に熱成形性樹脂層を介して金属光沢層が施された金属光沢原紙に、加熱、加圧するエンボス加工で万線状パターン群でなる微細な凹凸部を施しているので、この熱成形性樹脂層が紙基材の密度のムラ(紙基材の繊維間の隙間等に基づく表面粗さなどによる)を吸収し、かつ表面に切れの良いシャープな万線状の凹凸パターンが得られ、従来のように紙基材の密度のムラなどが金属光沢層面に現出されず、よって表面の金属光沢層に濃淡の鮮明さ(シャープ性)や輝きが増すようになり、本来の美麗さを有する所謂「オパール効果」に優れるエンボス加飾紙とすることができる。 That is, according to the first aspect of the present invention, a line pattern group is formed by embossing heat and pressure applied to a metallic glossy base paper having a metallic glossy layer provided on a paper base via a thermoformable resin layer. This thermoformable resin layer absorbs unevenness in the density of the paper base material (due to surface roughness based on gaps between fibers of the paper base material) and the surface. A sharp line-shaped uneven pattern with a sharp edge is obtained, and uneven density of the paper base material does not appear on the surface of the metallic luster layer as in the past. (Sharpness) and brightness increase, and embossed decorative paper having an original beauty and excellent in so-called “opal effect” can be obtained.
また、上記請求項2に係る発明によれば、前記加熱エンボス加工で万線状パターン群でなる微細な凹凸部の高度差を0.003〜0.1mmの範囲とし、その(万線状パターン群の凹凸部の)ピッチを0.005〜0.3mmの範囲とすることによって、表面の金属光沢層に濃淡の鮮明さ(シャープ性)や輝きに優れる所謂「オパール効果」に優れたオパール画像が形成されたエンボス加飾紙とすることができる。 According to the second aspect of the present invention, the difference in altitude of the fine irregularities formed by the line-shaped pattern group in the heating embossing is set to a range of 0.003 to 0.1 mm, An opal image with excellent so-called “opal effect”, which is excellent in contrast (sharpness) and brightness of the metallic luster layer on the surface by setting the pitch of the concavo-convex portion of the group to a range of 0.005 to 0.3 mm. Can be used as embossed decorative paper.
上記万線状パターン群でなる微細な凹凸部の高度差が0.003mmに満たなく、その(万線状パターン群の凹凸部の)ピッチが0.005mmに満たないと、微細な凹凸部が
浅くかつ細か過ぎて表面の金属光沢層の濃淡や輝きが不鮮明になり、本来の美麗さのないエンボス加飾紙となり、逆に万線状パターン群でなる微細な凹凸部の高度差が0.1mmを越え、そのピッチが0.3mmを越えると、微細な凹凸部が深くかつ粗過ぎて表面の金属光沢層の濃淡や輝きが無くなり、所謂「オパール効果」に欠けるようになるので好ましくない。
If the height difference of the fine irregularities formed by the above-mentioned line-shaped pattern group is less than 0.003 mm and the pitch (of the irregularities of the line-shaped pattern group) is less than 0.005 mm, the fine irregularities are The depth and brightness of the metallic luster layer on the surface is too shallow and too fine, resulting in embossed decorative paper with no original beauty. If the pitch exceeds 1 mm and the pitch exceeds 0.3 mm, the fine uneven portions are too deep and rough, and the surface metallic luster layer loses light and shade, so that the so-called “opal effect” is lost.
また、上記請求項3に係る発明によれば、紙基材と金属光沢層とを熱成形性を有する樹脂でサンドウイッチラミネートして金属光沢原紙を作製し、該金属光沢原紙の金属光沢層面上に、万線状パターン群でなる微細な凹凸部が施された平板タイプのエンボス版を、加熱し上下動せしめて加圧することによって、熱成形性を有する樹脂でなるサンドウイッチラミネート層が紙基材の密度のムラ(紙基材の繊維間の隙間等に基づく表面粗さなどによる)を吸収し、かつ金属光沢原紙上に切れの良いシャープな万線状凹凸パターン群を形成し、従来のように紙基材の密度のムラなどが金属光沢層面に現出することがなく、よって表面の金属光沢層に濃淡の鮮明さ(シャープ性)や輝きを増さしめ、所謂「オパール効果」に優れた本来の美麗さを有するエンボス加飾紙の製造方法とすることができる。 According to the third aspect of the present invention, the paper base and the metallic gloss layer are sandwich-laminated with a resin having thermoformability to produce a metallic gloss base paper. In addition, a sandwich-type laminate layer made of a resin having thermoformability is formed by heating a flat-plate type embossed plate with fine irregularities made of a line-shaped pattern group by heating, moving up and down, and applying pressure. Absorbs uneven density of materials (due to surface roughness based on gaps between fibers of paper base material) and forms sharp sharp line-shaped uneven patterns on metallic glossy base paper. In this way, the density unevenness of the paper base material does not appear on the surface of the metallic luster layer, thus increasing the sharpness and brightness of the surface metallic luster layer, so-called "opal effect" Excellent natural beauty It can be a method for producing embossed decorative paper.
また、上記請求項4に係る発明によれば、紙基材に熱成形性を有する樹脂を溶融押出しで熱成形性樹脂層を形成し、該熱成形性樹脂層面に金属蒸着薄膜の蒸着もしくは転写によって金属光沢層を施して金属光沢原紙を作製し、該金属光沢原紙の金属光沢層面上に、万線状パターン群でなる微細な凹凸部が施された平板タイプのエンボス版を、加熱し上下動せしめて加圧することによって、熱成形性を有する樹脂でなる溶融押出し樹脂層が紙基材の密度のムラ(紙基材の繊維間の隙間等に基づく表面粗さなどによる)などを吸収し、かつ金属光沢原紙上に切れの良いシャープな万線状凹凸パターン群を形成し、従来のように紙基材の密度のムラなどが金属光沢層面に現出することがなく、よって表面金属光沢層に濃淡の鮮明さ(シャープ性)や輝きを増さしめ、所謂「オパール効果」に優れた本来の美麗さを有するエンボス加飾紙の製造方法とすることができる。 According to the invention of claim 4 above, a thermoformable resin layer is formed by melt extrusion of a resin having thermoformability on a paper substrate, and vapor deposition or transfer of a metal vapor-deposited thin film is formed on the thermoformable resin layer surface. A metallic glossy base paper is prepared by applying a metallic glossy layer, and a flat type embossed plate with fine irregularities made of line-shaped patterns on the metallic glossy layer surface of the metallic glossy base paper is heated to By moving and applying pressure, the melt-extruded resin layer made of a resin having thermoformability absorbs uneven density of the paper base material (due to surface roughness based on gaps between fibers of the paper base material). In addition, a sharp and sharp line-shaped uneven pattern group is formed on the metallic gloss base paper, and the density unevenness of the paper base material does not appear on the metallic gloss layer surface as in the past, so the surface metallic gloss In the layer, sharpness and sharpness Tighten Masa to come, it can be a method for producing embossed decorative paper having the original beautiful is excellent in so-called "opal effect."
また、上記請求項5に係る発明によれば、紙基材に熱成形性を有する樹脂を溶融押出しで熱成形性樹脂層を形成し、該熱成形性樹脂層面にアルミニウムペーストインキによる印刷で金属光沢層を施して金属光沢原紙を作製し、該金属光沢原紙の金属光沢層面上に、万線状パターン群でなる微細な凹凸部が施された平板タイプのエンボス版を、加熱し上下動せしめて加圧することによって、熱成形性を有する樹脂でなる溶融押出し樹脂層が紙基材の密度のムラ(紙基材の繊維間の隙間等に基づく表面粗さなどによる)などを吸収し、かつ金属光沢原紙上に切れの良いシャープな万線状凹凸パターン群を形成し、従来のように紙基材の密度のムラなどが金属光沢層面に現出することがなく、よって表面の金属光沢層に濃淡の鮮明さ(シャープ性)や輝きを増さしめ、所謂「オパール効果」に優れた本来の美麗さを有するエンボス加飾紙の製造方法とすることができる。 According to the fifth aspect of the present invention, a thermoformable resin layer is formed by melt-extruding a resin having thermoformability on a paper base, and the surface of the thermoformable resin layer is printed with aluminum paste ink. A metallic glossy base paper is prepared by applying a glossy layer, and a flat plate type embossed plate with fine irregularities made of line-shaped patterns on the metallic glossy layer surface of the metallic glossy base paper is heated and moved up and down. And pressurizing, the melt-extruded resin layer made of a resin having thermoformability absorbs uneven density of the paper base material (due to surface roughness based on gaps between fibers of the paper base material) and the like, and A sharp and sharp line-shaped uneven pattern group is formed on the metallic glossy base paper, and unevenness of the density of the paper base material does not appear on the metallic glossy layer surface as in the past. In sharpness (sharpness) Tighten Masa shine can be a method for producing embossed decorative paper having the original beautiful is excellent in so-called "opal effect."
また、上記請求項6に係る発明によれば、上記平板タイプのエンボス版に施された万線状パターン群でなる微細な凹凸部の深さを0.003〜0.1mmの範囲とし、そのピッチを0.005〜0.3mmの範囲とすることによって、金属光沢原紙上に切れの良いシャープな万線状凹凸パターン群を形成し、よって表面の金属光沢層に濃淡の鮮明さ(シャープ性)や輝きを増さしめ、所謂「オパール効果」に優れた本来の美麗さを有するエンボス加飾紙の製造方法とすることができる。 Further, according to the invention of claim 6, the depth of the fine irregularities formed by the line-shaped pattern group applied to the flat plate type embossed plate is in the range of 0.003 to 0.1 mm, By setting the pitch in the range of 0.005 to 0.3 mm, a sharp sharp line-shaped uneven pattern group is formed on the metallic glossy base paper, and thus the sharpness (sharpness of the shading) is formed on the metallic glossy layer on the surface. And embossed decorative paper having an original beauty excellent in so-called “opal effect”.
上記平板タイプのエンボス版に施された万線状パターン群でなる微細な凹凸部の深さが0.003mmに満たなく、その(万線状パターン群の微細な凹部の)ピッチが0.005mmに満たないと、微細な凹凸部が細か過ぎて、金属を腐食せしめて凹凸部を形成するエンボス版の画線精度が得られず、よってこのエンボス版の加熱エンボスで得られるエンボス加飾紙が切れの悪いぼやけた万線状凹凸パターン群となり、逆にエンボス版を形成す
る万線状パターン群でなる微細な凹凸部の深さが0.1mmを越え、そのピッチが0.3mmを越えると、エンボス版の微細な凹凸部が深く粗過ぎて、このエンボス版による加熱エンボス加工で得られるエンボス加飾紙の金属光沢層に濃淡の鮮明さや輝きが無くなり、所謂「オパール効果」に欠けるようになるので好ましくない。
The depth of the fine concavo-convex portion formed by the line-shaped pattern group applied to the flat plate type embossed plate is less than 0.003 mm, and the pitch (of the fine concave portion of the line-shaped pattern group) is 0.005 mm. Otherwise, the fine embossed portion is too fine to corrode the metal and the embossed plate that forms the uneven portion cannot be drawn, so the embossed decorative paper obtained by heating embossing of this embossed plate is not If the depth of the fine irregularities formed by the line-shaped pattern group forming the embossed plate exceeds 0.1 mm and the pitch exceeds 0.3 mm. The embossed plate's fine irregularities are too deep and rough, and the metallic luster layer of embossed decorative paper obtained by heat embossing with this embossed plate loses the sharpness and brightness of the shading and lacks the so-called "opal effect" Is not preferable because Uninaru.
さらにまた、上記請求項7に係る発明によれば、上記請求項1または2記載のエンボス加飾紙を用いた紙製容器とすることによって、得られたエンボス加飾の紙製容器は、その側壁等の表面に、切れの良いシャープな万線状凹凸パターン群が形成され、表面の金属光沢層に濃淡の鮮明さ(シャープ性)や輝きに優れる所謂「オパール効果」に優れるオパール画像が形成された紙製容器とすることができる。
Furthermore, according to the invention which concerns on the said Claim 7, the paper container of the embossed decoration obtained by setting it as the paper container using the embossed decorative paper of the
上記でいう「オパール効果」とは、金属光沢を有する表面に微細な万線状凹凸パターン群を各画素ごとに万線の方向を少しづつ変えて複数群形成した(オパール)画像を、見る角度や方向を変化させると、各万線状凹凸パターン群の濃淡や輝きが動的に変化し、オパールのような極めて華麗な光沢を現出する効果をいう。 The “opal effect” mentioned above refers to the angle at which an image is formed by forming a plurality of fine line-shaped uneven patterns on the surface with metallic luster by changing the direction of the line for each pixel little by little (opal). When the direction is changed, the shading and brightness of each line-shaped uneven pattern group dynamically changes, which means the effect of producing an extremely brilliant gloss like opal.
以下本発明を実施するための最良の形態を図面を用いて詳細に説明する。 The best mode for carrying out the present invention will be described below in detail with reference to the drawings.
図1は、本発明のエンボス加飾紙の一部を拡大した斜視図であり、図2は、本発明のエンボス加飾紙の製造方法の一工程を説明する側断面図である。また、図3は、本発明のエンボス加飾紙の製造方法に使用するエンボス版の説明図であり、図4は、その製造の一事例である転写箔の側断面図である。さらにまた、図5は、本発明のエンボス加飾紙を用いた紙製容器の説明図である。 FIG. 1 is an enlarged perspective view of a part of the embossed decorative paper of the present invention, and FIG. 2 is a side sectional view for explaining one step of the method for producing the embossed decorative paper of the present invention. Moreover, FIG. 3 is explanatory drawing of the embossing plate used for the manufacturing method of the embossed decorative paper of this invention, FIG. 4 is a sectional side view of the transfer foil which is an example of the manufacture. Furthermore, FIG. 5 is explanatory drawing of the paper-made containers using the embossed decorative paper of this invention.
本発明は、例えば、図1の一部拡大斜視図に示すように、基材(10)上に熱成形性樹脂層(14)を介して金属光沢層(12)が施された金属光沢原紙(20)に、加熱エンボス加工による微細な万線状凹凸パターン群(30)が3画素集合したエンボスパターンでなるエンボス加飾紙(1)、およびこの製造方法、並びに例えば、これらエンボス加飾紙(1)およびこの製造方法を用いて、図5の斜視図に示すように、胴部側壁面に加熱エンボス加工による微細な万線状凹凸パターン群(30)が複数画素集合したエンボスパターンが施されたオパール様の極めて美麗な光沢を現出する紙製容器(5)に関するものである。 In the present invention, for example, as shown in a partially enlarged perspective view of FIG. 1, a metallic glossy base paper in which a metallic glossy layer (12) is provided on a substrate (10) via a thermoformable resin layer (14). (20), embossed decorative paper (1) comprising an embossed pattern in which three fine line-shaped uneven pattern groups (30) obtained by heat embossing are assembled, and the manufacturing method thereof, for example, these embossed decorative paper (1) and this manufacturing method, as shown in the perspective view of FIG. 5, an emboss pattern in which a plurality of fine line-shaped concavo-convex pattern groups (30) by heat embossing are assembled on the side wall surface of the trunk is applied. The present invention relates to a paper container (5) that exhibits a very beautiful gloss of opal.
上記請求項1に係る発明は、例えば、図1に示すように、コートボール等板紙を基材(10)とし、その上にポリエチレン等の低温で熱成形性に優れる熱成形性樹脂層(14)を介してアルミニウム箔等でなる金属光沢層(12)が施されている金属光沢原紙(20)の表面に、加熱エンボス加工による微細な万線状凹凸パターン群(30)が3画素集合してエンボスパターンを形成してなるエンボス加飾紙(1)である。
In the invention according to
上記のように、板紙等の基材(10)とアルミニウム箔等でなる金属光沢層(12)との間にポリエチレン等の低温で熱成形性に優れる熱成形性樹脂層(14)を施した金属光沢原紙(20)とすることによって、この熱成形性樹脂層(14)が板紙等表面の粗い基材(10)の密度のムラを吸収し、かつこの金属光沢原紙(20)の表面に、加熱エンボス加工で万線状凹凸パターン群(30)を3画素集合して施しているので、その表面に切れの良いシャープな万線状凹凸パターン群(30)が得られ、よって表面の金属光沢層(12)に濃淡の鮮明さ(シャープ性)や輝きが増し、本来の美麗さ所謂「オパール効果」に優れるエンボス加飾紙(1)を得ることができる。 As described above, a thermoformable resin layer (14) excellent in thermoformability at a low temperature such as polyethylene was applied between a substrate (10) such as paperboard and a metallic luster layer (12) made of aluminum foil or the like. By using the metallic glossy base paper (20), the thermoformable resin layer (14) absorbs uneven density of the rough base material (10) such as paperboard, and on the surface of the metallic glossy base paper (20). Since the line-shaped uneven pattern group (30) is formed by gathering three pixels by heat embossing, a sharp line-shaped uneven pattern group (30) with a good cut is obtained on the surface, and thus the surface metal The embossed decorative paper (1) can be obtained in which the brightness (sharpness) and brightness of the gloss layer (12) are increased, and the original beauty is so-called “opal effect”.
上記万線状凹凸パターン群(30)は1画素のみでもよいが、図1に示すように複数画
素が集合したものとすることによって、見る角度や方向の変化で動きや立体性が出るようなオパール画像とすることもできる。
The line-shaped concavo-convex pattern group (30) may be composed of only one pixel. However, when a plurality of pixels are assembled as shown in FIG. It can also be an opal image.
また、上記請求項2に係る発明では、例えば、図1に示すように、加熱エンボス加工による微細な万線状凹凸パターン群(10)は、その高度差(H)が0.003〜0.1mmの範囲で、そのピッチ(P)が0.005〜0.3mmの範囲でなるエンボス加飾紙(1)とするものである。 In the invention according to claim 2, for example, as shown in FIG. 1, the fine line-shaped uneven pattern group (10) by heat embossing has an altitude difference (H) of 0.003 to 0.00. The embossed decorative paper (1) has a pitch (P) in the range of 0.005 to 0.3 mm within a range of 1 mm.
このように、加熱エンボス加工でなる微細な万線状凹凸パターン群(30)の高度差(H)を0.003〜0.1mmの範囲とし、そのピッチ(P)を0.005〜0.3mmの範囲とすることによって、表面の金属光沢層(12)に濃淡の鮮明さ(シャープ性)や輝きに優れ、見る方向や角度を変化させると、表面の金属光沢層(12)に濃淡の鮮明さ(シャープ性)や輝きに優れ、所謂「オパール効果」に優れた極めて美麗なエンボス加飾紙(1)とすることができる。 Thus, the height difference (H) of the fine line-shaped uneven pattern group (30) formed by heat embossing is in the range of 0.003 to 0.1 mm, and the pitch (P) is 0.005 to 0.00. By setting the range to 3 mm, the surface metallic luster layer (12) is excellent in contrast and sharpness (sharpness) and brightness, and when the viewing direction and angle are changed, the surface metallic luster layer (12) is dark and light. It is possible to obtain a very beautiful embossed decorative paper (1) which is excellent in sharpness (sharpness) and brightness and excellent in so-called “opal effect”.
上記微細な万線状凹凸パターン群(30)の高度差(H)が0.003mmに満たなく、そのピッチ(P)が0.005mmに満たないと、微細な凹凸部が浅くかつ細か過ぎて表面の金属光沢層(12)の濃淡や輝きが不鮮明になり、本来の美麗さのないぼやけたパール画像のエンボス加飾紙(1)となり、逆に微細な万線状凹凸パターン群(30)の高度差(H)が0.1mmを越え、そのピッチ(P)が0.3mmを越えると、微細な万線状凹凸パターン群(30)が深くかつ粗過ぎて表面の金属光沢層(12)の濃淡や輝きが無くなり、所謂「オパール効果」に欠けるエンボス加飾紙(1)となる。 If the height difference (H) of the fine line-shaped uneven pattern group (30) is less than 0.003 mm and the pitch (P) is less than 0.005 mm, the fine uneven parts are shallow and too fine. The metallic luster layer (12) on the surface is not clear and bright, and it becomes embossed decorative paper (1) with a blurred pearl image without the original beauty. Conversely, the fine line-shaped uneven pattern group (30) When the height difference (H) exceeds 0.1 mm and the pitch (P) exceeds 0.3 mm, the fine line-shaped uneven pattern group (30) is too deep and rough, and the metallic gloss layer (12 ), The embossed decorative paper (1) lacks the so-called “opal effect”.
上記金属光沢原紙(20)を構成する金属光沢層(12)の表面に透明性に優れる印刷インキで絵柄等の印刷層(図示せず)を施してデザイン効果を向上させることもでき、さらにこの金属光沢層(12)の表面に、アクリル、ポリエステル樹脂等耐熱性と堅牢性に優れる樹脂を主成分としたオーバーコート層(図示せず)を設け金属光沢層(12)を保護することもできる。 The surface of the metallic gloss layer (12) constituting the metallic glossy base paper (20) can be provided with a printing layer (not shown) such as a pattern with a printing ink having excellent transparency to improve the design effect. An overcoat layer (not shown) composed mainly of a resin having excellent heat resistance and fastness such as acrylic and polyester resin can be provided on the surface of the metallic gloss layer (12) to protect the metallic gloss layer (12). .
上記エンボス加飾紙(1)を構成する基材(10)としては、例えば、坪量210g/m2 〜500g/m2 程度のコートボール、ノーコートボール、アイボリーやカード紙のマニラボール、特殊マニラボール、あるいは黄ボールやチップボール等表面の粗い低級板紙も使用できる。 Base material constituting the embossed decorative paper (1) as (10), for example, basis weight 210g / m 2 ~500g / m 2 about coated board, no coated cardboard, ivory or card paper manila board, special A low-grade paperboard with a rough surface such as a Manila ball or a yellow ball or a chip ball can also be used.
また、上記エンボス加飾紙(1)を構成する熱成形性樹脂層(14)としては、例えば、直鎖状低密度ポリエチレン(LLDPE)、低密度ポリエチレン(LDPE)、中密度ポリエチレン(MDPE)、アイオノマー(IO)や無延伸ポリプロピレン(CPP)などの比較的低温で熱成形性に優れ、厚み10〜50μm、好ましくは15μm程度の薄い膜厚の樹脂層が挙げられ、その形成は、下記のエンボス加飾紙の製造方法で述べる。 Moreover, as the thermoformable resin layer (14) constituting the embossed decorative paper (1), for example, linear low density polyethylene (LLDPE), low density polyethylene (LDPE), medium density polyethylene (MDPE), The resin layer is excellent in thermoformability at a relatively low temperature, such as ionomer (IO) and unstretched polypropylene (CPP), and has a thin film thickness of 10 to 50 μm, preferably about 15 μm. The method for producing decorative paper will be described.
また、上記エンボス加飾紙(1)を構成する金属光沢層(12)としては、例えば、厚み10μm程度のアルミニウム箔、厚み12μm程度のポリエチレンテレフタレートフィルムにアルミニウム蒸着層を施したアルミニウム蒸着フィルム、あるいは金属ペーストインキで印刷されたものなどが挙げられる。 Moreover, as a metallic luster layer (12) which comprises the said embossed decorative paper (1), for example, the aluminum vapor deposition film which gave the aluminum vapor deposition layer to the aluminum foil about 10 micrometers thick, the polyethylene terephthalate film about 12 micrometers thick, or Examples thereof include those printed with metal paste ink.
また、上記請求項3に係る発明は、例えば、図1に示すような金属光沢原紙(20)の表面に微細な万線状凹凸パターン群(30)を設けるエンボス加飾紙(1)の製造方法であり、例えば、図2の側断面積層図に示すように、板紙等でなる基材(10)とアルミニウム蒸着フィルム等でなる金属光沢層(12)との間に低密度ポリエチレン等の熱成形性に優れる樹脂を押出してラミネートする所謂サンドウイッチラミネートで金属光沢原紙(
20)を作製する。
Further, the invention according to
20).
続いて上記で得られた金属光沢原紙(20)の金属光沢層(12)面上に、例えば、図3(a)の上面図およびそのB−B面を示す図3(b)の断面図に示すように、3画素でなる微細な万線状凹凸パターン群(32)が施された平板タイプのエンボス版(3)を加熱し、上下動せしめて加圧して図1に示すようなエンボス加飾紙(1)とするエンボス加飾紙の製造方法である。 Subsequently, on the surface of the metallic glossy layer (12) of the metallic glossy base paper (20) obtained above, for example, a top view of FIG. 3 (a) and a cross-sectional view of FIG. As shown in FIG. 1, a flat plate-type embossed plate (3) provided with a fine line-shaped concavo-convex pattern group (32) of 3 pixels is heated, moved up and down, and pressurized to give an emboss as shown in FIG. It is a manufacturing method of embossed decorative paper made into decorative paper (1).
上記平板タイプのエンボス版(3)は、例えば、証券印刷に用いられる凹版の製版方法すなわち手または機械彫刻腐食法により平面の銅板に万線状の凹凸パターン群(32)を形成して得られ、さらに、この銅板原版をもとに電胎法にて銅板実用版(実用エンボス版)とすることができる。 The flat plate type embossed plate (3) is obtained, for example, by forming a line-shaped concavo-convex pattern group (32) on a flat copper plate by an intaglio plate making method used for securities printing, that is, by hand or mechanical engraving corrosion method. Furthermore, a copper plate practical plate (practical embossed plate) can be obtained by the electroconcentration method based on this copper plate original plate.
また、上記請求項4に係る発明は、例えば、図1に示すようなエンボス加飾紙(1)の製造方法であって、例えば、図2の側断面積層図に示すように、板紙等でなる基材(10)に、溶融された低密度ポリエチレン等の熱成形性に優れる樹脂を押出して熱成形性樹脂層(14)を形成し、さらにこの熱成形性樹脂層(14)面に、例えばアルミニウムを蒸着して金属光沢層(12)を施して金属光沢原紙(20)を作製する。 In addition, the invention according to claim 4 is a method for producing embossed decorative paper (1) as shown in FIG. 1, for example, as shown in the side sectional laminate diagram of FIG. Extruded resin having excellent thermoformability such as melted low density polyethylene to the base material (10) to form a thermoformable resin layer (14), and further on the surface of the thermoformable resin layer (14), For example, aluminum is vapor-deposited and a metallic luster layer (12) is applied to produce a metallic luster base paper (20).
続いて上記で得られた金属光沢原紙(20)の金属光沢層(12)面上に、例えば、図3(a)の上面図およびそのB−B面を示す図3(b)の断面図に示すように、3画素でなる微細な万線状凹凸パターン群(32)が施された平板タイプのエンボス版(3)を加熱し、上下動せしめて加圧して図1に示すようなエンボス加飾紙(1)とするエンボス加飾紙の製造方法である。 Subsequently, on the surface of the metallic glossy layer (12) of the metallic glossy base paper (20) obtained above, for example, a top view of FIG. 3 (a) and a cross-sectional view of FIG. As shown in FIG. 1, a flat plate-type embossed plate (3) provided with a fine line-shaped concavo-convex pattern group (32) of 3 pixels is heated, moved up and down, and pressurized to give an emboss as shown in FIG. It is a manufacturing method of embossed decorative paper made into decorative paper (1).
また、上記請求項4に係る発明では、上記熱成形性樹脂層(14)面に形成する金属光沢層(12)を、例えば、図4の側断面図に示すように、厚み12μm程度のポリエチレンテレフタレートフィルム(41)に易剥離層(42)、保護層(43)、アルミニウム蒸着層(44)、接着層(45)が順に積層されている金属蒸着転写箔(40)を用い、易剥離層(42)から保護層(43)付のアルミニウム蒸着層(44)を接着層(45)で接着させて転写して設けることもできる。 In the invention according to claim 4, the metallic luster layer (12) formed on the surface of the thermoformable resin layer (14) is made of, for example, polyethylene having a thickness of about 12 μm as shown in the side sectional view of FIG. Using a metal vapor-deposited transfer foil (40) in which an easy-peeling layer (42), a protective layer (43), an aluminum vapor-deposited layer (44), and an adhesive layer (45) are laminated in this order on a terephthalate film (41), an easy-peelable layer The aluminum vapor deposition layer (44) with the protective layer (43) from (42) may be adhered and transferred by the adhesive layer (45).
このように、金属光沢層(12)をアルミニウム蒸着層(44)の転写によって得られるので、必要な部分にのみ部分転写が可能になり、より経済的でかつデザイン上でも好適なエンボス加飾紙(1)を得ることができる。 Thus, since the metallic luster layer (12) is obtained by transferring the aluminum vapor deposition layer (44), partial transfer is possible only on necessary portions, and the embossed decorative paper is more economical and suitable for design. (1) can be obtained.
さらにまた、上記請求項5に係る発明は、例えば、図1に示すようなエンボス加飾紙(1)の製造方法であって、例えば、図2の側断面積層図に示すように、板紙等でなる基材(10)に、溶融された低密度ポリエチレン等の熱成形性に優れる樹脂を押出して熱成形性樹脂層(14)を形成し、さらにこの熱成形性樹脂層(14)面に、例えばアルミニウムペーストインキによる印刷で金属光沢層(12)を施して金属光沢原紙(20)を作製する。 Furthermore, the invention according to claim 5 is a method for producing embossed decorative paper (1) as shown in FIG. 1, for example, as shown in the side sectional laminate diagram of FIG. The base material (10) is extruded with a resin having excellent thermoformability, such as molten low density polyethylene, to form a thermoformable resin layer (14), and further on the surface of the thermoformable resin layer (14). For example, a metallic gloss base paper (20) is produced by applying a metallic gloss layer (12) by printing with aluminum paste ink.
続いて上記で得られた金属光沢原紙(20)の金属光沢層(12)面上に、例えば、図3(a)の上面図およびそのB−B面を示す図3(b)の断面図に示すように、3画素でなる微細な万線状凹凸パターン群(32)が施された平板タイプのエンボス版(3)を加熱し、上下動せしめて加圧して図1に示すようなエンボス加飾紙(1)とするエンボス加飾紙の製造方法である。 Subsequently, on the surface of the metallic glossy layer (12) of the metallic glossy base paper (20) obtained above, for example, a top view of FIG. 3 (a) and a cross-sectional view of FIG. As shown in FIG. 1, a flat plate-type embossed plate (3) provided with a fine line-shaped concavo-convex pattern group (32) of 3 pixels is heated, moved up and down, and pressurized to give an emboss as shown in FIG. It is a manufacturing method of embossed decorative paper made into decorative paper (1).
また、上記請求項6に係る発明では、例えば、図3(a)およびそのB−B面を表す図
3(b)に示すように、平板タイプのエンボス版(3)に施された万線状凹凸パターン群(32)の深さ(ED)を、0.003〜0.1mmの範囲とし、そのピッチ(EP)を0.005〜0.3mmの範囲としたエンボス加飾紙の製造方法である。
Moreover, in the invention which concerns on the said Claim 6, as shown in FIG.3 (a) and FIG.3 (b) showing the BB surface, for example, the line applied to the flat plate type embossed plate (3) Of embossed decorative paper, wherein the depth (ED) of the concavo-convex pattern group (32) is in the range of 0.003 to 0.1 mm, and the pitch (EP) is in the range of 0.005 to 0.3 mm. It is.
上記のようなエンボス版(3)に施された万線状凹凸パターン群(32)の深さ(ED)とピッチ(EP)とすることによって、図1に示すように、金属光沢原紙(20)上に切れの良いシャープな万線状凹凸パターン群(30)を形成し、その結果表面の金属光沢層(12)に濃淡の鮮明さ(シャープ性)や輝きを増さしめ、細か過ぎたり、粗過ぎたりしない所謂「オパール効果」に優れた本来の美麗さを有するエンボス加飾紙の製造方法とすることができる。 By setting the depth (ED) and pitch (EP) of the line-shaped uneven pattern group (32) applied to the embossed plate (3) as described above, as shown in FIG. ) A sharp and sharp line-shaped uneven pattern group (30) is formed on the surface, and as a result, the surface of the metallic luster layer (12) is increased in sharpness and brightness and is too fine. Thus, it can be a method for producing embossed decorative paper having an original beauty excellent in so-called “opal effect” which is not too rough.
上記エンボス加飾紙の製造方法における平板タイプのエンボス版(3)の加熱温度は、75℃〜250℃程度で、熱成形性樹脂層(14)の厚みや樹脂の種類などによって適宜選定するものであり、この温度が75℃に満たないと熱成形性樹脂層(14)に十分な万線状凹凸パターン群(30)が形成されず、逆に250℃を越えると熱成形性樹脂層(14)が溶け出して十分な万線状凹凸パターン群(30)が形成されなくなるので好ましくない。 The heating temperature of the flat plate type embossed plate (3) in the method for producing embossed decorative paper is about 75 ° C. to 250 ° C., and is appropriately selected depending on the thickness of the thermoformable resin layer (14), the type of resin, and the like. If this temperature is less than 75 ° C., sufficient line-shaped uneven pattern group (30) is not formed on the thermoformable resin layer (14), and conversely if it exceeds 250 ° C, the thermoformable resin layer ( 14) melts and a sufficient line-shaped uneven pattern group (30) is not formed, which is not preferable.
また、上記平板タイプのエンボス版(3)の上下動による加圧は、0.5MPa〜400MPa程度の高圧でかつ短時間でエンボスするもので、この圧力が0.5MPaに満たないと熱成形性樹脂層(14)に十分な万線状凹凸パターン群(30)が形成されず、逆に400MPaを越えるとエンボス版(3)の万線状凹凸パターン群(32)などが潰れたりするので好ましくない。 Further, the pressurization by the vertical movement of the flat plate type embossing plate (3) is embossed in a short time at a high pressure of about 0.5 MPa to 400 MPa, and if this pressure is less than 0.5 MPa, thermoformability is achieved. A sufficient line-shaped uneven pattern group (30) is not formed on the resin layer (14). On the contrary, if the pressure exceeds 400 MPa, the line-shaped uneven pattern group (32) of the embossed plate (3) may be crushed. Absent.
さらにまた、上記請求項7に係る発明は、例えば、図5の斜視図に示すように、上記のようなエンボス加飾紙の製造方法で得られたエンボス加飾紙(1)を用いて、エンボス加飾された紙製容器(5)とするもので、この紙製容器(5)の胴部側壁に万線状凹凸パターン群(30)が施され、「オパール効果」に優れた美粧性の紙製容器(5)とするものである。 Furthermore, as shown in the perspective view of FIG. 5, for example, the invention according to claim 7 uses an embossed decorative paper (1) obtained by the above-described embossed decorative paper manufacturing method, The embossed decorative paper container (5) is provided with a line-shaped uneven pattern group (30) on the body side wall of the paper container (5), and has an excellent opal effect. The paper container (5).
以下に、本発明の具体的実施例について説明する。 Specific examples of the present invention will be described below.
基材として坪量310g/m2 のコートボールを用い、金属光沢層として12μmのPETフィルムにアルミニウムを蒸着したアルミニウム蒸着フィルムを用い、これら基材と金属光沢層との間に低密度ポリエチレンを主体とした熱成形性樹脂を溶融押出して厚み15μmの熱成形性樹脂層でラミネートして金属光沢原紙を得た。 A coated ball having a basis weight of 310 g / m 2 is used as a base material, and an aluminum vapor-deposited film in which aluminum is vapor-deposited on a 12 μm PET film is used as a metallic gloss layer. The thermoformable resin thus obtained was melt extruded and laminated with a thermoformable resin layer having a thickness of 15 μm to obtain a metallic glossy base paper.
一方万線状凹凸パターン群の深さが0.04mmで、そのピッチが0.08mmのエンボス版を準備した。 On the other hand, an embossed plate having a line-shaped uneven pattern group depth of 0.04 mm and a pitch of 0.08 mm was prepared.
上記エンボス版を箔押し機:SP102−BMA型(ボブスト社製)に取付け、版圧;34MPa、版温度;110℃、加圧速度;3200ショット/時間で金属光沢原紙の金属光沢層面にエンボス加工してエンボス加飾紙を得た。 The embossed plate is attached to a foil stamping machine: SP102-BMA type (manufactured by Bobst), and the plate pressure: 34 MPa, plate temperature; To get embossed decorative paper.
以下に、本発明の比較例について説明する。 Below, the comparative example of this invention is demonstrated.
基材にポリウレタン系のドライラミネーション用接着剤を介して金属光沢層をラミネートして金属光沢原紙とし、エンボス版を加熱せず常温とした以外は、実施例1と同様にし
てエンボス加飾紙を得た。
The embossed decorative paper was prepared in the same manner as in Example 1 except that the substrate was laminated with a metallic gloss layer via a polyurethane-based dry lamination adhesive to obtain a metallic glossy base paper, and the embossed plate was not heated to room temperature. Obtained.
上記実施例1で得られたエンボス加飾紙は、その表面に切れの良いシャープな万線状の凹凸パターンが得られ、よって表面の金属光沢層に濃淡の鮮明さ(シャープ性)や輝きが増し、本来の美麗さ所謂「オパール効果」に優れたものであった。これに対し比較のための実施例2で得られたエンボス加飾紙は、コートボール紙の密度のムラが金属光沢層にもろに現れ、その濃淡の鮮明さ(シャープ性)や輝きに欠け、本来の美麗さ即ち「オパール効果」が失われたものであった。 The embossed decorative paper obtained in Example 1 has a sharp, sharp, line-like uneven pattern on its surface, and thus the surface of the metallic luster layer has sharpness (sharpness) and brightness. The original beauty was excellent in the so-called “opal effect”. On the other hand, the embossed decorative paper obtained in Example 2 for comparison shows uneven density of the coated cardboard in the metallic luster layer, lacking its sharpness and sharpness, The original beauty, that is, the “opal effect” was lost.
1‥‥エンボス加飾紙
3‥‥エンボス版
5‥‥エンボス加飾の紙製容器
10‥‥基材
12‥‥金属光沢層
14‥‥熱成形性樹脂層
20‥‥金属光沢原紙
30‥‥万線状凹凸パターン群
32‥‥エンボス版に施された万線状凹凸パターン群
40‥‥アルミニウム蒸着転写箔
41‥‥ポリエチレンテレフタレートフィルム
42‥‥易剥離層
43‥‥保護層
44‥‥アルミニウム蒸着層
45‥‥接着層
ED‥‥エンボス版の万線状凹凸パターン群の深さ
EP‥‥エンボス版の万線状凹凸パターン群のピッチ
H‥‥エンボス加飾紙の万線状凹凸パターン群の深さ
P‥‥エンボス加飾紙の万線状凹凸パターン群のピッチ
DESCRIPTION OF
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JP2008110558A (en) * | 2006-10-31 | 2008-05-15 | Toppan Printing Co Ltd | Embossed decorative plate and manufacturing method thereof |
WO2012077245A1 (en) * | 2010-12-06 | 2012-06-14 | 株式会社サカイヤ | Microfabricated synthetic resin sheet synthetic resin molded product using same |
WO2012176921A1 (en) * | 2011-06-24 | 2012-12-27 | 日本写真印刷株式会社 | Hairline transfer sheet |
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