JP2006234788A5 - - Google Patents

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JP2006234788A5
JP2006234788A5 JP2005211849A JP2005211849A JP2006234788A5 JP 2006234788 A5 JP2006234788 A5 JP 2006234788A5 JP 2005211849 A JP2005211849 A JP 2005211849A JP 2005211849 A JP2005211849 A JP 2005211849A JP 2006234788 A5 JP2006234788 A5 JP 2006234788A5
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enzyme
electrode
conductive member
enzyme electrode
porous structure
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JP2005211849A
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JP2006234788A (en
JP4632437B2 (en
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Claims (11)

導電性部材及び酵素を有する酵素電極であって、
前記導電性部材は、多孔質構造を備え、且つ
前記酵素が、前記多孔質構造を構成する孔内に、担体を介して固定されており、
前記導電性部材が、互いに対向する2つの作用面を少なくとも有し、かつこれらの一方の面から他方の面に前記多数の空隙を介して液体が透過可能である酵素電極
An enzyme electrode having a conductive member and an enzyme,
The conductive member has a porous structure, and the enzyme is fixed in a hole constituting the porous structure via a carrier ,
The enzyme electrode, wherein the conductive member has at least two working surfaces opposed to each other, and a liquid can pass from one surface to the other surface through the plurality of voids .
請求項に記載の酵素電極と、該酵素電極の有する導電性部材に接続した配線と、を有する酵素電極デバイス。 An enzyme electrode device comprising: the enzyme electrode according to claim 1; and a wiring connected to a conductive member of the enzyme electrode. 前記酵素電極の複数を、各々の作用面を対向させて積層した構造を有する請求項に記載の酵素電極デバイス。 The enzyme electrode device according to claim 2 , wherein the enzyme electrode device has a structure in which a plurality of the enzyme electrodes are stacked with their working surfaces facing each other. 請求項またはに記載の酵素電極デバイスを物質を検知するための検知部位として用いることを特徴とするセンサ。 A sensor using the enzyme electrode device according to claim 2 or 3 as a detection site for detecting a substance. アノード電極とカソード電極との間に電解液を保持し得る領域を設けた燃料電池において、これらのアノード電極とカソード電極の少なくとも一方が、請求項またはに記載の酵素電極デバイスからなることを特徴とする燃料電池。 A fuel cell provided with a region capable of holding an electrolyte solution between an anode electrode and a cathode electrode, wherein at least one of the anode electrode and the cathode electrode comprises the enzyme electrode device according to claim 2 or 3. A fuel cell. 反応領域と、該反応領域に導入された原料に電気化学的反応を生じさせて目的とする生成物を得るための電極と、を有する電気化学的反応装置において、
前記電極が、請求項またはに記載の酵素電極デバイスであることを特徴とする電気化学的反応装置。
A reaction region, in the product that electrical chemical reactor Yusuke and electrodes, the for obtaining of interest by causing electrochemical reactions in the starting materials introduced into the reaction region,
An electrochemical reaction apparatus, wherein the electrode is the enzyme electrode device according to claim 2 or 3 .
導電性部材及び酵素を有する酵素電極であって、
前記導電性部材は、多孔質構造を備え、且つ
前記酵素が、前記多孔質構造を構成する孔内に、担体を介して固定されており、
前記導電性部材の表面側における孔径は、該導電性部材の内部における孔径よりも大きいことを特徴とする酵素電極。
An enzyme electrode having a conductive member and an enzyme,
The conductive member has a porous structure, and
The enzyme is immobilized in a pore constituting the porous structure via a carrier;
Pore size, enzyme electrodes you being greater than the diameter in the interior of the conductive member on the surface side of the conductive member.
前記酵素と前記導電性部材との電子の受け渡しを促進させるためのメディエータを有することを特徴とする請求項に記載の酵素電極。 The enzyme electrode according to claim 7 , further comprising a mediator for facilitating transfer of electrons between the enzyme and the conductive member. 前記導電性部材は、金属、導電性高分子、金属酸化物及び炭素材料から選択される材料の少なくとも1種からなることを特徴とする請求項7または8に記載の酵素電極。 The enzyme electrode according to claim 7 or 8 , wherein the conductive member is made of at least one material selected from metals, conductive polymers, metal oxides, and carbon materials. 前記酵素が酸化還元酵素である請求項7〜9のいずれかに記載の酵素電極。 The enzyme electrode according to any one of claims 7 to 9 , wherein the enzyme is an oxidoreductase. 燃料電池であって、
アノード電極及びカソード電極が多孔質構造を有し、前記アノード電極とカソード電極の少なくとも一方が、前記多孔質構造を構成する孔内に酵素を保持している酵素電極であり、
前記酵素電極の表面側における孔径は、該導電性部材の内部における孔径よりも大きいことを特徴とする燃料電池。
A fuel cell,
Anode and cathode electrodes has a porous structure, at least one of the anode electrode and the cathode electrode, Ri enzyme electrode der holding the enzyme in the pores constituting the porous structure,
The fuel cell according to claim 1, wherein a pore diameter on the surface side of the enzyme electrode is larger than a pore diameter inside the conductive member .
JP2005211849A 2004-07-23 2005-07-21 Enzyme electrode, device having enzyme electrode, sensor, fuel cell, electrochemical reaction device Expired - Fee Related JP4632437B2 (en)

Priority Applications (1)

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JP2005211849A JP4632437B2 (en) 2004-07-23 2005-07-21 Enzyme electrode, device having enzyme electrode, sensor, fuel cell, electrochemical reaction device

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JP2004216287 2004-07-23
JP2005023520 2005-01-31
JP2005211849A JP4632437B2 (en) 2004-07-23 2005-07-21 Enzyme electrode, device having enzyme electrode, sensor, fuel cell, electrochemical reaction device

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JP2010181906A Division JP4891429B2 (en) 2004-07-23 2010-08-16 Enzyme electrode, device having enzyme electrode, sensor, fuel cell, electrochemical reaction device

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JP2006234788A JP2006234788A (en) 2006-09-07
JP2006234788A5 true JP2006234788A5 (en) 2008-09-04
JP4632437B2 JP4632437B2 (en) 2011-02-16

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JP5022657B2 (en) * 2005-09-30 2012-09-12 キヤノン株式会社 Enzyme electrode and manufacturing method thereof
JP2008071584A (en) * 2006-09-13 2008-03-27 Toyota Motor Corp Electron transfer mediator modification enzyme electrode, and biological fuel cell equipped with this
JP2009009815A (en) 2007-06-28 2009-01-15 Toyota Central R&D Labs Inc Electrode catalyst substrate, its manufacturing method, and solid polymer fuel cell
JP5181576B2 (en) * 2007-08-17 2013-04-10 ソニー株式会社 FUEL CELL MANUFACTURING METHOD, FUEL CELL, AND ELECTRONIC DEVICE
JP2009272179A (en) 2008-05-08 2009-11-19 Sony Corp New enzyme electrode and fuel cell using the same
JP5481822B2 (en) * 2008-10-06 2014-04-23 ソニー株式会社 Enzyme electrode and fuel cell using the enzyme electrode
CN102171880A (en) 2008-10-06 2011-08-31 索尼公司 Fuel cell and enzyme electrode
JP5899885B2 (en) * 2011-01-31 2016-04-06 ソニー株式会社 Fuel cell, fuel cell production method, electronic device, nicotinamide adenine dinucleotide-immobilized electrode, nicotinamide adenine dinucleotide-immobilized carrier, enzyme reaction utilization apparatus, protein-immobilized electrode, and protein-immobilized carrier
JP5930810B2 (en) 2011-04-26 2016-06-08 アークレイ株式会社 Analysis tool
WO2013005814A1 (en) * 2011-07-06 2013-01-10 ソニー株式会社 Biofuel battery
JP2013243012A (en) * 2012-05-18 2013-12-05 Toyota Motor Corp Method of manufacturing electrode for biofuel cell
CN104520700B (en) 2012-06-25 2016-08-17 日本生物工程研究所有限责任公司 Enzyme electrode
TWI481498B (en) * 2013-12-27 2015-04-21 Plastics Industry Dev Ct Fruit and Vegetable fresh packing material and producing method thereof
WO2018074551A1 (en) * 2016-10-19 2018-04-26 キッコーマン株式会社 Glucose redox reaction using flavin compound and composition for glucose measurement
JP6931915B2 (en) * 2017-05-02 2021-09-08 国立研究開発法人農業・食品産業技術総合研究機構 Electrodes for bioelectrochemical systems and bioelectrochemical systems
KR20210057471A (en) 2019-11-12 2021-05-21 엘지디스플레이 주식회사 Conductive film and display device comprising the same
CN114235923A (en) * 2021-12-09 2022-03-25 清华大学 Bioelectrochemical sensing electrode, device and electrode preparation method

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JPH0612352B2 (en) * 1984-12-17 1994-02-16 株式会社島津製作所 Enzyme functional electrode
JPH061252B2 (en) * 1984-08-31 1994-01-05 株式会社島津製作所 Oxidase electrode
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JP3477511B2 (en) * 1998-03-25 2003-12-10 国立身体障害者リハビリテーションセンター総長 Biosensor using gold platinum electrode
US7018518B2 (en) * 2002-02-04 2006-03-28 Yissum Research Development Company Of The Hebrew University Of Jerusalem Biosensor carrying redox enzymes

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