JP2006207302A - Fire-resistant panel, fire-resistant segment for tunnel, using the same, and highly fire-resistant tunnel - Google Patents

Fire-resistant panel, fire-resistant segment for tunnel, using the same, and highly fire-resistant tunnel Download PDF

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JP2006207302A
JP2006207302A JP2005022353A JP2005022353A JP2006207302A JP 2006207302 A JP2006207302 A JP 2006207302A JP 2005022353 A JP2005022353 A JP 2005022353A JP 2005022353 A JP2005022353 A JP 2005022353A JP 2006207302 A JP2006207302 A JP 2006207302A
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fire
resistant
tunnel
fireproof
panel
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Koji Nishimuta
幸治 西牟田
Tamotsu Hashimoto
保 橋本
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Taiheiyo Materials Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a fire-resistant panel which dispenses with a complicated structure, and exerts excellent fire resistance even if it is arranged with low installation accuracy, and to provide a fire-resistant segment for a tunnel, using the fire-resistant panel, and a highly fire-resistant tunnel. <P>SOLUTION: The fire-resistant panel has a fire-resistant high-temperature expanding layer containing a phosphate compound as a main ingredient on each side surface of a fire-resistant substrate. Preferably the high-temperature expanding layer has an expansion ratio of 2 to 30 times under high temperature conditions of 200 to 400°C. The fire-resistant segment for a tunnel is formed by setting the fire-resistant panel on a surface of the segment such that an interval between the side surfaces of the fire-resistant panels is reduced to less than 3 mm after high-temperature expanding. The highly fire-resistant tunnel has an internal surface thereof covered with the segments. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、耐火性に優れた耐火パネルと、これを用いたトンネル用耐火セグメントと高耐火性トンネルに関する。より詳しくは、本発明は、複雑な構造を必要とせずに、設置精度が低くても優れた耐火性を有する耐火パネルと、これを用いたトンネル用耐火セグメントおよび高耐火性トンネルに関する。 The present invention relates to a fire resistant panel having excellent fire resistance, a fire resistant segment for a tunnel using the fire resistant panel, and a high fire resistant tunnel. More specifically, the present invention relates to a fire-resistant panel having excellent fire resistance even when installation accuracy is low without requiring a complicated structure, and a fire-resistant segment for a tunnel and a high fire-resistant tunnel using the fire-resistant panel.

道路トンネル、鉄道トンネル等のトンネルの主な材質は、コンクリート、鋳鉄、鋼材又はこれらの2種以上を組み合わせたものである。特に、都市部においては、セグメントを組立て、リング構造体としてトンネルを支保するシールド工法により構築されるシールドトンネルが多く採用されている。トンネル内で火災が発生すると、火災により発生する熱によりトンネル構造体の強度が低下する虞があり、場合によっては長期間トンネルの使用ができなくなる虞もある。このため、トンネル内表面に多数の耐火パネルを設置することが提案されている。 The main material of tunnels such as road tunnels and railway tunnels is concrete, cast iron, steel, or a combination of two or more of these. Particularly in urban areas, shield tunnels constructed by a shield construction method in which segments are assembled and the tunnel is supported as a ring structure are often employed. When a fire occurs in the tunnel, the strength of the tunnel structure may be reduced by heat generated by the fire, and in some cases, the tunnel may not be used for a long time. For this reason, it has been proposed to install a large number of fireproof panels on the inner surface of the tunnel.

しかし、耐火パネルを相互に突き合わせた隙間が3mm以上であると、この隙間から火炎が侵入して耐火性が大幅に低下するため、耐火パネル相互の隙間が3mm未満となる高い精度で設置することが求められる。ところが、トンネル内表面は一般に平面のみからなることは少なく湾曲面が多いために、このような精度で耐火パネルを設置するには手間がかかり、施工効率が大幅に低下する。 However, if the gap between the refractory panels is 3 mm or more, the flame will enter through this gap and the fire resistance will be greatly reduced. Is required. However, since the inner surface of the tunnel is generally not composed of only a flat surface and has many curved surfaces, it takes time to install the fireproof panel with such accuracy, and the construction efficiency is greatly reduced.

そこで、耐火パネル相互の隙間を耐火性目地材で閉塞ないし覆う方法が知られている(特許文献1、2)。しかし、耐火板相互の隙間を目地材で覆う方法も手間がかかり、施工効率が低く経済性も悪い。一方、耐火パネルの側面に段差を形成して、耐火パネルの側面が相互に重なるようにして隙間ができないようにする方法もあるが、耐火パネル側面の加工が面倒であり、コスト高になる。 Then, the method of block | closing or covering the clearance gap between fireproof panels with a fireproof joint material is known (patent documents 1, 2). However, the method of covering the gaps between the refractory plates with joint materials is also troublesome, and the construction efficiency is low and the economic efficiency is poor. On the other hand, there is a method of forming a step on the side surface of the refractory panel so that the side surfaces of the refractory panel overlap each other so that there is no gap, but the processing of the side surface of the refractory panel is cumbersome and costly.

また、パネルや管などの端面に、未焼成バーミキュライト、ホウ酸塩類、およびケイ酸塩類の一種または二種以上からなる熱膨張耐熱材を設けた耐熱建材が知られている(特許文献3)。しかし、200〜350℃程度の加熱下では未焼成バーミキュライトの膨張は小さく耐火性は乏しい。また、未焼成バーミキュライトなどは水ガラスや酢酸ビニル樹脂などの結着剤によって付着されるが、高温下で結着性が失われて未焼成バーミキュライトなどが脱落するなどの致命的な問題を生じる場合がある。
特開2002−349196号公報 特開2002−309897号公報 特公昭56−40225号公報
In addition, a heat-resistant building material is known in which a thermal expansion heat-resistant material composed of one or more of unfired vermiculite, borates, and silicates is provided on an end face of a panel or a tube (Patent Document 3). However, under heating at about 200 to 350 ° C., the unburned vermiculite has a small expansion and poor fire resistance. In addition, unburned vermiculite is attached by a binder such as water glass or vinyl acetate resin, but when the fatality such as loss of unburnt vermiculite is lost due to loss of binding property at high temperature. There is.
JP 2002-349196 A JP 2002-309897 A Japanese Patent Publication No.56-40225

本発明は、従来のトンネルなどに用いる耐火パネルおよびその施工方法における上記問題を解決したものであり、複雑な構造を必要とせずに、設置精度が低くても優れた耐火性を有する耐火パネルと、これを用いたトンネル耐火性セグメントおよび耐火性トンネルを提供することを目的とする。 The present invention solves the above-described problems in fireproof panels used in conventional tunnels and the like and construction methods thereof, and does not require a complicated structure, and has a fireproof panel having excellent fire resistance even when installation accuracy is low, and An object is to provide a tunnel refractory segment and a refractory tunnel using the same.

本発明は以下の構成を有する耐火パネルおよびこれを用いたトンネル用耐火セグメントおよび高耐火性トンネルに関する。
(1)耐火性基板の側面にリン酸化合物を主成分とする耐火性の高温膨張層を有することを特徴とする耐火パネル。
(2)耐火性の高温膨張層が200〜400℃の高温下で2〜30倍に膨張する上記(1)の耐火パネル。
(3)耐火性の高温膨張層がリン酸化合物を主成分とする耐火塗料および/または耐火シートによって形成されている上記(1)または(2)の耐火パネル。
(4)上記(1)〜(3)の何れかに記載する耐火パネルを、耐火パネル側面相互の間隙が高温膨張後に3mm未満になるように、セグメント表面に設置したことを特徴とするトンネル用耐火セグメント。
(5)上記(4)のトンネル用耐火セグメントにおいて、耐火パネル側面相互の設置間隙が30mm以内であり、高温膨張後の耐火パネル側面相互の間隙が3mm未満になる耐火性の高温膨張層を有する耐火パネルを用いたトンネル用耐火セグメント。
(6)上記(1)〜(3)の何れかに記載する耐火パネルをトンネル内表面に設けたことを特徴とする高耐火性トンネル。
(7)上記(4)または(5)のトンネル用耐火セグメントによってトンネル内表面を形成した高耐火性トンネル。
The present invention relates to a fireproof panel having the following configuration, a fireproof segment for a tunnel using the fireproof panel, and a high fireproof tunnel.
(1) A fire-resistant panel comprising a fire-resistant high-temperature expansion layer mainly composed of a phosphoric acid compound on a side surface of a fire-resistant substrate.
(2) The fire-resistant panel according to (1), wherein the fire-resistant high-temperature expansion layer expands 2 to 30 times at a high temperature of 200 to 400 ° C.
(3) The fire-resistant panel according to (1) or (2), wherein the fire-resistant high-temperature expansion layer is formed of a fire-resistant paint and / or a fire-resistant sheet mainly composed of a phosphoric acid compound.
(4) For tunnels characterized in that the fireproof panels described in any of (1) to (3) above are installed on the segment surface so that the gap between the fireproof panel side surfaces is less than 3 mm after high-temperature expansion. Refractory segment.
(5) The tunnel fireproof segment of (4) above has a fireproof high temperature expansion layer in which the installation gap between the fireproof panel side surfaces is within 30 mm and the gap between the fireproof panel side surfaces after high temperature expansion is less than 3 mm. Fireproof segment for tunnels using fireproof panels.
(6) A highly fire-resistant tunnel characterized in that the fire-resistant panel described in any one of (1) to (3) above is provided on the inner surface of the tunnel.
(7) A highly fire-resistant tunnel in which the tunnel inner surface is formed by the tunnel fire-resistant segment of (4) or (5) above.

本発明の耐火パネルは、耐火性基板の側面に耐火性の高温膨張層を有するので、高温下で耐火パネルの側面が膨張して耐火パネル相互の側面の隙間を3mm未満に閉塞し、耐火性を高める。また、この高温膨張層はリン酸化合物を主成分とし、耐火性基板の側面に設けられているので、高温下で脱落するトラブルを生じる虞がなく、安定かつ効果的に膨張するので、信頼性の高い耐火効果を得ることができる。 Since the fireproof panel of the present invention has a fireproof high-temperature expansion layer on the side surface of the fireproof substrate, the side surfaces of the fireproof panel expand at high temperatures to close the gap between the side surfaces of the fireproof panels to less than 3 mm. To increase. In addition, this high-temperature expansion layer is mainly composed of a phosphoric acid compound and is provided on the side of the refractory substrate, so there is no risk of dropping off at high temperatures and the expansion is stable and effective. High fire resistance can be obtained.

さらに、本発明の耐火パネルは耐火性基板の側面に高温膨張層を有するので、施工時の耐火パネル相互の隙間が大きくても、基板側面部が高温膨張して耐火パネル相互の側面の間隙を3mm未満に閉塞することができるので、耐火パネルの施工精度を緩和することができ、施工が容易である。 Furthermore, since the fireproof panel of the present invention has a high temperature expansion layer on the side surface of the fireproof substrate, even if the gap between the fireproof panels at the time of construction is large, the side surface portion of the substrate expands at a high temperature and the gap between the fireproof panels is increased. Since it can be closed to less than 3 mm, the construction accuracy of the fireproof panel can be relaxed and the construction is easy.

本発明の耐火パネルは、複雑な構造を必要とせず、かつ耐火パネル相互の側面の隙間が3mm以上の低い施工精度で設置しても高い耐火性能を発揮するので、トンネル用の耐火パネルとして好適である。具体的には、本発明の耐火パネルはトンネル内表面を形成するセグメント表面に設置して用いればよい。本発明の耐火パネルを用いた耐火セグメントおよび高耐火性トンネルは、施工および構築が容易かつ安価であり、またトンネル内で火災が発生しても高い耐火性能を有するので、早期に復旧可能である。 The fireproof panel of the present invention does not require a complicated structure, and exhibits high fireproof performance even when installed with low construction accuracy with a clearance of 3 mm or more between the fireproof panels, so it is suitable as a fireproof panel for tunnels It is. Specifically, the fireproof panel of the present invention may be used by being installed on the segment surface forming the inner surface of the tunnel. The fire-resistant segment and the high fire-resistant tunnel using the fire-resistant panel of the present invention are easy and inexpensive to construct and construct, and have high fire resistance even if a fire occurs in the tunnel. .

さらに、本発明の耐火パネルはパネル相互間に隙間を有しているので、地震等によりトンネルが多少変形しても耐火パネル相互間に応力が負荷し難く、耐火パネルが損傷し難い。このため、耐震性も高い高耐火性トンネルを構築することができる。 Furthermore, since the fireproof panels of the present invention have gaps between the panels, even if the tunnel is slightly deformed due to an earthquake or the like, stress is not easily applied between the fireproof panels, and the fireproof panels are not easily damaged. For this reason, it is possible to construct a highly fire-resistant tunnel with high earthquake resistance.

以下、本発明を実施例と共に具体的に説明する。
本発明の耐火パネルは、耐火性基板の側面にリン酸化合物を主成分とする耐火性の高温膨張層を有することを特徴とする。この耐火パネルの模式的な断面図を図1に示す。図中、1は耐火性基板、2は高温膨張層、3は取付金具、4はトンネル構造体(セグメント)、5はセグメント内表面(トンネル内表面)、6はセグメントの地山側表面、7は耐火パネル側面相互の隙間(目地の開き)、10は耐火パネルである。
Hereinafter, the present invention will be specifically described together with examples.
The fireproof panel of the present invention is characterized by having a fireproof high-temperature expansion layer mainly composed of a phosphoric acid compound on the side surface of a fireproof substrate. A schematic cross-sectional view of this fireproof panel is shown in FIG. In the figure, 1 is a refractory substrate, 2 is a high-temperature expansion layer, 3 is a mounting bracket, 4 is a tunnel structure (segment), 5 is an inner surface of the segment (inner surface of the tunnel), 6 is a surface on the ground side of the segment, 7 is The gap between the sides of the fireproof panel (opening of joints), 10 is a fireproof panel.

耐火パネル10の高温膨張層2はリン酸化合物を主成分として含む。リン酸化合物は火炎に曝されたときなどの高温下で発泡膨張し、この発泡により形成される耐火層が強固であり、火炎による損傷を受け難く、耐火性を長時間保持できる。リン酸化合物としては、例えば、第一リン酸アンモニウム、第二リン酸アンモニウム、リン酸アンモニウム、ポリリン酸アンモニウム、ポリリン酸アミド、リン酸メラミンなどを用いることができる。上記高温膨張層は、リン酸化合物以外に、エポキシ樹脂,アクリル樹脂,メラミン樹脂や酢酸ビニル樹脂等のビヒクル、アクリル,メラミン,尿素,酢酸ビニル等のビヒクルの原材料、炭水化物、多価アルコール、顔料、染料、消泡剤、増粘剤、繊維等から選ばれる一種又は二種以上を、本発明の効果を損なわない範囲で含有することができる。 The high temperature expansion layer 2 of the refractory panel 10 contains a phosphoric acid compound as a main component. The phosphoric acid compound expands and expands at a high temperature such as when exposed to a flame, and the fireproof layer formed by the foaming is strong, hardly damaged by the flame, and can maintain the fire resistance for a long time. As the phosphoric acid compound, for example, primary ammonium phosphate, secondary ammonium phosphate, ammonium phosphate, ammonium polyphosphate, polyphosphate amide, melamine phosphate and the like can be used. In addition to the phosphoric acid compound, the high-temperature expansion layer is composed of a vehicle such as an epoxy resin, an acrylic resin, a melamine resin or a vinyl acetate resin, a raw material for a vehicle such as acrylic, melamine, urea or vinyl acetate, a carbohydrate, a polyhydric alcohol, a pigment, One type or two or more types selected from dyes, antifoaming agents, thickeners, fibers and the like can be contained within a range that does not impair the effects of the present invention.

本発明の耐火パネル10について、火災などによる高温下でパネル側面の上記高温膨張層2が膨張した態様を図2に示す。図示するように、本発明の耐火パネル10は、パネル側面の耐火性高温膨張層2が高温下で膨張し、耐火パネル相互の側面の隙間7を3mm未満に閉塞することができるので、火炎が耐火パネル10の裏側に入り込まず、従って、優れた耐火性を発揮する。 About the fireproof panel 10 of this invention, the aspect which the said high temperature expansion layer 2 of the panel side surface expanded under high temperature by a fire etc. is shown in FIG. As shown in the figure, in the fireproof panel 10 of the present invention, the fireproof high temperature expansion layer 2 on the side surface of the panel expands at a high temperature, and the gap 7 on the side surface between the fireproof panels can be closed to less than 3 mm. It does not enter the back side of the refractory panel 10 and thus exhibits excellent fire resistance.

リン酸化合物を主成分とする上記高温膨張層2は、200〜400℃の高温下で、加熱前の体積に対する加熱後の体積比率(以下「発泡倍率」と云う)が、2〜30倍となるものが好ましく、5〜20倍となるものがより好ましい。発泡倍率が2倍未満では耐火パネルの設置精度を高くする必要があり、発泡倍率が30倍より大きいと発泡後の内部空隙の割合が過剰になるので、火炎によって損傷を受け易くなり、耐火性を長時間保持するのが難しくなる。 The high-temperature expansion layer 2 containing a phosphoric acid compound as a main component has a volume ratio after heating to a volume before heating (hereinafter referred to as “foaming ratio”) of 2 to 30 times at a high temperature of 200 to 400 ° C. What becomes is preferable, and what becomes 5 to 20 times is more preferable. If the expansion ratio is less than 2 times, it is necessary to increase the installation accuracy of the fireproof panel. If the expansion ratio is greater than 30 times, the ratio of the internal voids after foaming becomes excessive, so that it is easy to be damaged by the flame, and the fire resistance Is difficult to hold for a long time.

上記耐火性高温膨張層2は耐火塗料および/または耐火シートによって形成することができる。具体的には、例えば、リン酸化合物を含む耐火塗料を耐火パネルの側面に所定の層厚になるように塗布し、あるいはリン酸化合物を含む所定厚さの耐火シートを耐火パネルの側面に貼り付けて上記高温膨張層2を形成する。 The fire resistant high temperature expansion layer 2 can be formed of a fire resistant paint and / or a fire resistant sheet. Specifically, for example, a fireproof paint containing a phosphoric acid compound is applied to the side surface of the fireproof panel so as to have a predetermined layer thickness, or a fireproof sheet having a predetermined thickness containing a phosphoric acid compound is applied to the side surface of the fireproof panel. In addition, the high temperature expansion layer 2 is formed.

上記高温膨張層2の厚みは、その発泡倍率、耐火パネルの設置精度などに応じて定めれば良い。また、上記高温膨張層2は必ずしも耐火パネル側面の全面に設けなくても良く、発泡膨張の程度に応じて耐火パネルの側面の一部に設けても良い。 What is necessary is just to determine the thickness of the said high temperature expansion layer 2 according to the foaming magnification, the installation precision of a fireproof panel, etc. The high-temperature expansion layer 2 does not necessarily have to be provided on the entire side surface of the refractory panel, and may be provided on a part of the side surface of the refractory panel depending on the degree of foam expansion.

本発明の耐火パネル10の基板1は、耐火性を有するものであれば良く、組成、形状、大きさなどは限定されない。例えば、珪酸カルシウム板、セラミックス製耐火板、不燃性石膏ボード、耐火繊維成形板、無定形耐火材成形板、これら二種以上からなる板材などを用いることができる。また、これらに金属板や仕上げ材を積層したものでも良い。上記無定形耐火材の成形板としては、例えば、太平洋マテリアル社製「フェンドライト」(商品名)等の無定形の耐火被覆材に鉄筋や金属性網等を内在させた板を用いることができる。 The board | substrate 1 of the fireproof panel 10 of this invention should just have fire resistance, and a composition, a shape, a magnitude | size, etc. are not limited. For example, a calcium silicate board, a ceramic fireproof board, a non-combustible gypsum board, a fireproof fiber molded board, an amorphous fireproof material molded board, a board made of two or more of these, and the like can be used. Moreover, what laminated | stacked the metal plate and finishing material on these may be used. As the molded plate of the above-mentioned amorphous refractory material, for example, a plate in which reinforcing bars, metal nets, etc. are incorporated in an amorphous fire-resistant coating material such as “Fendrite” (trade name) manufactured by Taiheiyo Material Co., Ltd. can be used. .

上記耐火パネル10を、耐火パネル側面相互の間隙7が高温膨張後に3mm未満になるように、セグメント内表面5に設置することによって、耐火性に優れたトンネル用耐火セグメントを形成することができる。具体的には、高温膨張層2の発泡倍率に従って、高温膨張後の耐火パネル側面相互の間隙7が3mm未満になるように、耐火パネル側面相互の設置間隙を定めれば良い。例えば、高温膨張層2の発泡倍率が2〜30倍であるとき、耐火パネル10を30mm以内の設置間隔で耐火セグメント10に取り付ければ良い。 By installing the fireproof panel 10 on the inner surface 5 of the segment so that the gap 7 between the fireproof panel side surfaces is less than 3 mm after high temperature expansion, a fireproof segment for tunnels having excellent fire resistance can be formed. Specifically, according to the expansion ratio of the high-temperature expansion layer 2, the installation gap between the refractory panel side faces may be determined so that the gap 7 between the refractory panel side faces after the high-temperature expansion is less than 3 mm. For example, when the expansion ratio of the high-temperature expansion layer 2 is 2 to 30 times, the fireproof panel 10 may be attached to the fireproof segment 10 at an installation interval of 30 mm or less.

本発明の耐火パネル10を、耐火パネル側面相互の間隙7が高温膨張後に3mm未満になるように、トンネル内表面に設けることによって高耐火性のトンネルを構築することができる。トンネル内表面に耐火パネルを設置する手段としては、トンネル内表面を形成するコンクリート表面に耐火パネルをセメントやモルタル、その他の耐熱性接着剤によって貼り付けても良く、または取付金具やセラミックス製取付具を用いてコンクリート面に固定しても良い。あるいは、セグメント表面に本発明の耐火パネルを設置した上記トンネル用耐火セグメント4を用いてトンネル内表面を形成しても良い。耐火パネル10をセグメント4に取り付ける手段は限定されない。取付金具3やセラミックス製取付具を用いても良く、耐熱性接着剤で貼り付けても良い。また、トンネル内表面に設置する時期も特に限定されない。トンネル構築後にトンネル内表面に設置しても良く、セグメントの内表面側に予め耐火パネルを装着しておいても良い。 By providing the refractory panel 10 of the present invention on the inner surface of the tunnel such that the gap 7 between the refractory panel side surfaces is less than 3 mm after high temperature expansion, a highly refractory tunnel can be constructed. As a means of installing a fireproof panel on the inner surface of the tunnel, the fireproof panel may be attached to the concrete surface forming the inner surface of the tunnel with cement, mortar, or other heat-resistant adhesive, or a mounting bracket or ceramic fixture You may fix to the concrete surface using. Or you may form a tunnel inner surface using the said fireproof segment 4 for tunnels which installed the fireproof panel of this invention in the segment surface. The means for attaching the fireproof panel 10 to the segment 4 is not limited. The mounting bracket 3 or a ceramic mounting tool may be used, or a heat resistant adhesive may be used. Moreover, the time to install on the inner surface of the tunnel is not particularly limited. After the tunnel construction, it may be installed on the inner surface of the tunnel, or a fireproof panel may be attached in advance to the inner surface side of the segment.

耐火パネル側面相互の間隙が高温膨張後に3mm未満になるように本発明の耐火パネルを内表面に設けたトンネルは、火災などの高温下において、耐火パネル側面が膨張して耐火パネル相互の間隙を閉塞するので、火炎が耐火パネルの裏側に入り込まず、従って、優れた耐火性を発揮する。 Tunnels provided with the fireproof panel of the present invention on the inner surface so that the gap between the fireproof panel side surfaces is less than 3 mm after high temperature expansion, the fireproof panel side surfaces expand under high temperatures such as a fire, and the gap between fireproof panels is increased. Since it is closed, the flame does not enter the back side of the refractory panel and therefore exhibits excellent fire resistance.

以下、本発明の実施例を比較例と共に示す。
〔実施例〕
耐火性基板の側面に、リン酸化合物を主成分とする組成物を塗布して耐火性の高温膨張層を有する耐火パネルを製造した。この耐火パネルをコンクリート製模擬セグメント接合部の内表面側に設置した試験体を作製した。作製した試験体を、加熱曲線としてトンネル内火災を想定したRABT加熱曲線(最高温度までの到達時間;発火5分後,最高温度1200℃で60分間保持)に基づいて耐火試験を行い、火炎に曝して耐火性を調べた。この結果を耐火パネルの製造条件、設置条件と共に表1に示した。このとき用いた高温膨張層は、ポリリン酸アンモニウム、多価アルコール及びアニリンを含有し、400℃における発泡倍率が20倍の耐火塗料を塗布することにより形成した。なお、表1中の「フェンドライト+セメント板」、「フェンドライト+石膏ボード」と記載したA5およびA6は、それぞれ耐火性基板として、無定形の耐火被覆材(太平洋マテリアル社製品、商品名フェンドライト)と、セメント板または石膏ボードとを積層した板を用いた。
Examples of the present invention are shown below together with comparative examples.
〔Example〕
A composition having a phosphoric acid compound as a main component was applied to the side surface of the refractory substrate to produce a refractory panel having a refractory high-temperature expansion layer. A test body was prepared in which this fireproof panel was installed on the inner surface side of a concrete simulated segment joint. The fired test was performed on the prepared specimen based on the RABT heating curve assuming a fire in the tunnel as the heating curve (time to reach the maximum temperature; after 5 minutes of ignition, held at the maximum temperature of 1200 ° C for 60 minutes). The fire resistance was examined by exposure. The results are shown in Table 1 together with the manufacturing conditions and installation conditions of the fireproof panel. The high-temperature expansion layer used at this time was formed by applying a fire resistant paint containing ammonium polyphosphate, polyhydric alcohol and aniline and having an expansion ratio of 20 times at 400 ° C. In Table 1, A5 and A6 described as “fendrite + cement board” and “fendrite + gypsum board” are amorphous fireproof coatings (Pacific Materials Co., Ltd. Drite) and a board laminated with cement board or gypsum board were used.

〔比較例〕
高温膨張層の材料として、未焼成バーミキュライト、ホウ酸塩、ケイ酸塩を用いた以外は実施例と同様の条件下で耐火パネルを製造し、コンクリート製セグメント模擬接合部の内表面側に設置し、その耐火性を調べた。この結果を表1に示した。このとき用いた高温膨張層は、以下のものを塗布することにより形成した。
B1:未焼成バーミュキライトとエポキシ樹脂の混合物。
B2:四ホウ酸ナトリウムとエポキシ樹脂の混合物。
B3:水ガラス(珪酸ナトリウム水溶液)と普通ポルトランドセメント(主成分;珪酸カルシウム)の混合物。
B4:高温膨張層は無し。
[Comparative Example]
A fireproof panel was manufactured under the same conditions as in the examples except that unfired vermiculite, borate, and silicate were used as the material for the high-temperature expansion layer, and installed on the inner surface side of the concrete segment simulated joint. The fire resistance was investigated. The results are shown in Table 1. The high temperature expansion layer used at this time was formed by applying the following.
B1: Mixture of unfired vermiculite and epoxy resin.
B2: A mixture of sodium tetraborate and epoxy resin.
B3: A mixture of water glass (sodium silicate aqueous solution) and ordinary Portland cement (main component: calcium silicate).
B4: No high temperature expansion layer.

表1に示すように、ポリリン酸アンモニウム、多価アルコール及びアニリンを含有し、400℃における発泡倍率が20倍の耐火塗料を塗布することにより形成した高温膨張層を耐火性基板の側面に有する耐火パネルを用いた本発明の実施例A1〜A6は何れも耐火パネル側面部分が火炎高温下において膨張し、耐火パネル側面相互の間隙が閉塞された。この結果、模擬セグメント接合部の内表面側の表面温度は350℃未満であり、優れた耐火性を示した。一方、従来の耐火パネルを用いた比較例は何れもパネル側面相互の隙間が閉塞されず、従って、模擬セグメント接合部付近の内表面側の表面に火炎が入り込み、表面温度が350℃以上になり、耐火性が不充分であった。 As shown in Table 1, a fire-resistant substrate having a high-temperature expansion layer formed on a side surface of a fire-resistant substrate formed by applying a fire-resistant paint containing ammonium polyphosphate, polyhydric alcohol and aniline and having an expansion ratio of 20 times at 400 ° C. In Examples A1 to A6 of the present invention using panels, the side portions of the refractory panel expanded at high flame temperatures, and the gaps between the refractory panel sides were closed. As a result, the surface temperature on the inner surface side of the simulated segment joint was less than 350 ° C., indicating excellent fire resistance. On the other hand, in the comparative examples using the conventional fireproof panels, the gaps between the panel side surfaces are not closed, so that a flame enters the surface on the inner surface side near the simulated segment joint and the surface temperature becomes 350 ° C. or higher. The fire resistance was insufficient.

Figure 2006207302
Figure 2006207302

本発明の耐火パネルの設置状態を示す模式断面図(火災前)Schematic sectional view showing the installation state of the fireproof panel of the present invention (before fire) 本発明の耐火パネルの設置状態を示す模式断面図(火災後)Schematic sectional view showing the installation state of the fireproof panel of the present invention (after fire)

符号の説明Explanation of symbols

1−耐火性基板、2−高温膨張層、3−取付金具、4−トンネル構造体(セグメント)、5−セグメント内表面(トンネル内表面)、6−セグメントの地山側表面、7−耐火パネル側面相互の隙間(目地の開き)、10−耐火パネル
1-fireproof substrate, 2-high temperature expansion layer, 3-mounting bracket, 4-tunnel structure (segment), 5-segment inner surface (tunnel inner surface), 6-segment ground surface, 7-fireproof panel side Mutual gap (open joint), 10-fireproof panel

Claims (7)

耐火性基板の側面にリン酸化合物を主成分とする耐火性の高温膨張層を有することを特徴とする耐火パネル。 A fire-resistant panel comprising a fire-resistant high-temperature expansion layer mainly composed of a phosphoric acid compound on a side surface of a fire-resistant substrate. 耐火性の高温膨張層が200〜400℃の高温下で2〜30倍に膨張する請求項1の耐火パネル。 The fire-resistant panel according to claim 1, wherein the fire-resistant high-temperature expansion layer expands 2 to 30 times at a high temperature of 200 to 400 ° C. 耐火性の高温膨張層がリン酸化合物を主成分とする耐火塗料および/または耐火シートによって形成されている請求項1または2の耐火パネル。 The fire-resistant panel according to claim 1 or 2, wherein the fire-resistant high-temperature expansion layer is formed of a fire-resistant paint and / or a fire-resistant sheet mainly composed of a phosphoric acid compound. 請求項1〜3の何れかに記載する耐火パネルを、耐火パネル側面相互の間隙が高温膨張後に3mm未満になるように、セグメント表面に設置したことを特徴とするトンネル用耐火セグメント。 A fireproof segment for tunnels, characterized in that the fireproof panel according to any one of claims 1 to 3 is installed on the surface of a segment so that a gap between side surfaces of the fireproof panel is less than 3 mm after high-temperature expansion. 請求項4のトンネル用耐火セグメントにおいて、耐火パネル側面相互の設置間隙が30mm以内であり、高温膨張後の耐火パネル側面相互の間隙が3mm未満になる耐火性の高温膨張層を有する耐火パネルを用いたトンネル用耐火セグメント。 5. The fireproof segment for a tunnel according to claim 4, wherein a fireproof panel having a fireproof high temperature expansion layer in which a space between the fireproof panel side surfaces is within 30 mm and a space between the fireproof panel side surfaces after high temperature expansion is less than 3 mm is used. There was a fireproof segment for tunnels. 請求項1〜3の何れかに記載する耐火パネルをトンネル内表面に設けたことを特徴とする高耐火性トンネル。 A high fire-resistant tunnel comprising the fire-resistant panel according to claim 1 provided on an inner surface of the tunnel. 請求項4または5のトンネル用耐火セグメントによってトンネル内表面を形成した高耐火性トンネル。 A high fire resistant tunnel in which the tunnel inner surface is formed by the fire resistant segment for a tunnel according to claim 4 or 5.
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JP2007262862A (en) * 2006-03-30 2007-10-11 Taiheiyo Material Kk Metallic fire resistant decorative panel and fire resistant covering structure using the panel
JP2008286593A (en) * 2007-05-16 2008-11-27 Shimizu Corp Method and device for testing fire resistance of lining segment, and method of designing lining segment
CN109650917A (en) * 2019-01-24 2019-04-19 陕西拓新节能环保科技发展有限公司 A kind of ceramic coating and its preparation method and application of high emissivity high-temperature corrosion resistance dirt-resistant slagging

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JP2003269098A (en) * 2002-03-18 2003-09-25 Taiheiyo Cement Corp Joint structure of tunnel fire-resisting material

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JPH0874497A (en) * 1994-09-01 1996-03-19 Kyoritsu Kagaku Sangyo Kk Internal wall forming method for tunnel structure
JPH09296537A (en) * 1996-03-08 1997-11-18 Nisshin Steel Co Ltd Sealing method of refractory panel end part
JPH11294098A (en) * 1998-04-07 1999-10-26 Hiroaki Ando Fire resistant tunnel structure
JP2002029807A (en) * 2000-07-06 2002-01-29 Daiho Constr Co Ltd Refractory material, tunnel, refractory lining worked body for tunnel and method for forming refractory lining worked body for tunnel
JP2003269098A (en) * 2002-03-18 2003-09-25 Taiheiyo Cement Corp Joint structure of tunnel fire-resisting material

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007262862A (en) * 2006-03-30 2007-10-11 Taiheiyo Material Kk Metallic fire resistant decorative panel and fire resistant covering structure using the panel
JP2008286593A (en) * 2007-05-16 2008-11-27 Shimizu Corp Method and device for testing fire resistance of lining segment, and method of designing lining segment
CN109650917A (en) * 2019-01-24 2019-04-19 陕西拓新节能环保科技发展有限公司 A kind of ceramic coating and its preparation method and application of high emissivity high-temperature corrosion resistance dirt-resistant slagging

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