JP2006172742A - Collector member for fuel cell, and fuel cell stack using it, and fuel cell - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a collector member for a fuel cell in which a contact area with a fuel cell cell is fully securable and which is excellent in linking reliability. <P>SOLUTION: The collector member for the fuel cell is a collector member for connecting adjacent fuel cell cells electrically, and divided according to a slit 11 formed in an interior. A plurality of thin plate-like members 1 configured from a plurality of strips of rectangular parts 14 mutually joined at first ends 12 and second ends 13 are connected in series on the identical side through a connector 2 so that the first ends 12 and the second ends 13 are arranged on the same rank in parallel, and the adjacent strips of the rectangular parts can extend inversely mutually at a thickness direction. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a current collecting member for a fuel cell for electrically connecting adjacent fuel cells, a fuel cell stack using the same, and a fuel cell.

  In recent years, various fuel cells in which a fuel cell stack is accommodated in a storage container have been proposed as next-generation energy.

  The fuel cell stack described above is obtained by electrically connecting a plurality of adjacent fuel cells via a current collecting member. As such a current collecting member, a metal having high conductivity is employed, and since it is used at a high temperature, a heat resistant metal is preferably employed.

As for the shape of the current collecting member, a plurality of slits 81 are formed substantially in parallel at one end of the rectangular plate as shown in FIG. 11A, and between the slits 81 as shown in FIG. The current collecting pieces 82 are alternately projected on both sides of the plate-like current collecting member, and a plurality of current collecting pieces 82 are formed at one end of the base, and the cross-sectional U-shaped comb blade shape is used. As shown in FIG. 12, a plurality of slits are formed substantially in parallel, and current collecting pieces 91 formed between the slits alternately projecting on both sides of the plate-like current collecting member are arranged at predetermined intervals in the length direction. A structure in which the base 92 and the current collecting pieces 91 are alternately formed is known. (See Patent Document 1)
JP 2003-282101 A

  However, the fuel cell often warps or tilts, and there is a problem that the distance between adjacent fuel cells (the dimension between fuel cells) is not constant and varies depending on the position. .

  At this time, since the current collecting member having a U-shaped cross section shown in FIG. 11 is basically a cantilever structure, as shown in FIG. 13, when the dimension between fuel cells becomes excessively small, When the U-shaped tip is separated from the fuel cell, and the dimension between the fuel cells is increased, the U-shaped central portion is separated from the fuel cell, and the contact area of the current collecting member is reduced. There was a problem that connection reliability was lowered. That is, it is difficult to adjust the dimension between the fuel cells and the optimum dimension of the current collecting member.

  Further, when the current collecting member having the shape shown in FIG. 12 is arranged so that the slit and the longitudinal direction of the fuel cell are parallel, the contact area is not sufficient, and the slit and the longitudinal direction of the fuel cell are Is arranged so that the current collecting pieces are fixed on both sides, the degree of freedom is small, and the change in the dimension between the fuel cells cannot be followed. There is a problem that the connection reliability is lowered.

  An object of the present invention is to provide a fuel cell current collecting member that can sufficiently secure a contact area with a fuel battery cell and is excellent in connection reliability.

  As a result of intensive studies on the shape of the current collecting member, the present inventors have found that the following shape achieves the above object, and have reached the present invention.

  That is, the present invention is a current collecting member for electrically connecting adjacent fuel cells, partitioned by a slit formed inside, and joined to each other at a first end and a second end. In addition, the thin plate-like member composed of a plurality of strip-shaped portions has a connecting portion so that the strip-shaped portions are parallel and the first end portion and the second end portion are arranged on the same line. A fuel cell current collecting member, wherein a plurality of the strip-shaped portions adjacent to each other in series are pushed and spread in opposite directions in the thickness direction. As a result, it is possible to obtain a current collecting member for a fuel cell that can secure a sufficient contact area with the fuel cell and is excellent in connection reliability.

  Here, a connection portion is formed to be bent so as to connect the first end portion and the second end portion, a first region parallel to the strip-shaped portion, and the first end portion, It consists of the first region and the second region connecting the second end and the first region, and the first region is expanded in the thickness direction like the strip-shaped portion. Preferably it is. Thus, by comprising so that a 1st edge part and a 2nd edge part may be connected, it can spread like a strip-shaped part, and can increase a contact area with a fuel cell. .

  At this time, the thin plate-like member was formed in any one of a letter shape having two strip-shaped portions, a Japanese character shape having three strip-shaped portions, and a mark shape having four strip-shaped portions. A member is preferred. With this number, twisting is less likely to occur due to the restraint from the first end and the second end. The binding by the end portion and the second end portion becomes stronger, and it is possible to make the twist less likely to occur.

  Further, the present invention is the current collector for a fuel cell, wherein the thin plate-like member includes at least five strip-like portions, and the connection portions are arranged along a central axis in the connection direction. Thereby, a strip-shaped part can be spread on the reverse side in a substantially balanced manner.

  In the fuel cell current collecting member, it is preferable that at least three thin plate-like members are connected. This is because the restraint by the first end or the second end is weakened, and it becomes possible to follow the dimensional variation between the fuel cells. In addition, although the constraint by the first end and the second end is necessary for eliminating the twist, it becomes impossible to follow the dimensional variation between the fuel cells when this constraint extends over the entire connection direction (longitudinal direction). Adjusting the number of strip-shaped members and the number of connected thin plate-shaped members provides a more effective shape of a current collecting member for a fuel cell.

  Furthermore, the present invention is a fuel cell stack formed by interposing the fuel cell current collecting member between adjacent fuel cells and electrically connecting a plurality of fuel cells in series. Moreover, this invention is a fuel cell by which this fuel cell stack is accommodated in a storage container. By such a fuel cell stack and a fuel cell, a fuel cell excellent in long-term reliability with little voltage drop can be obtained.

  According to the present invention, it is possible to obtain a current collecting member for a fuel cell that can secure a sufficient contact area with the fuel cell and is excellent in connection reliability, so that the contact area with the fuel cell is not easily reduced. The electrical connection between the cells can be performed stably.

  Hereinafter, embodiments of the present invention will be described with reference to the drawings.

  As shown in FIGS. 1 and 2, the current collector for a fuel cell according to the present invention is partitioned by a slit 11 formed inside and joined to each other at a first end 12 and a second end 13. The thin plate-like member 1 composed of a plurality of strip-like portions 14 has a connecting portion so that the strip-like portions 14 are parallel and the first end portion 12 and the second end portion 13 are arranged in the same row. A plurality of strip-shaped portions 14 connected in series on the same surface through 2 are spread in opposite directions in the thickness direction.

  The thin plate-like member 1 is represented by a region surrounded by a dotted line shown in FIGS. 1 and 2. The thin plate-like member 1 has a slit 11 formed therein. The slit 11 is formed along the direction orthogonal to the connecting direction of the thin plate-like member 1. Here, that the slit 11 is formed inside means that the slit 11 does not reach the outer edge of the thin plate member 1. Further, in the thin plate-like member 1, two strip-shaped portions 14 partitioned by the slits 11 are formed. The two strip-shaped portions 14 are formed by the first end portion 12 and the second end portion 13. Are joined together. In other words, the strip-shaped part 14 extends in a direction orthogonal to the connection direction of the thin plate-like member 1, and the first end 12 and the second end that connect both sides in the length direction of the plurality of strip-shaped parts 14. A portion 13 is formed. Here, the 1st edge part 12 and the 2nd edge part 13 are the area | regions where the slit 11 has not reached | attained, Comprising: It represents with the area | region enclosed with the dashed-dotted line of FIG. With such a configuration, the thin plate-like member 1 has a so-called mouth shape in the drawing.

  A plurality of the thin plate-like members 1 are connected in series on the same surface via the connection portion 2. At this time, the adjacent thin plate-like members 1 are arranged so that the respective strip-like portions 14 are parallel to each other, and the first end portions 12 of the adjacent thin plate-like members 1 are arranged in the same row. Two end portions 13 are arranged on the same line.

  The connecting portion 2 is for connecting adjacent thin plate-like members 1, and connects the first end portion 12 of one thin plate-like member 1 and the second end portion 13 of the other thin plate-like member 1. It is formed so as to be bent. Specifically, as shown in FIG. 2, the first region 21 parallel to the strip-shaped portion 14 of the thin plate member 1, the first end 12 and the first region 21 of one thin plate member 1. The second region 22 for connecting the first region 21, the second end portion 13 of the other thin plate-like member 1, and the second region 22 for connecting the first region 21. Since the connection portion 2 is configured to connect the first end portion and the second end portion in this manner, the connection portion 2 can be expanded in the same manner as the strip-shaped portion, and the contact area with the fuel cell unit Can earn a lot.

  The structure composed of the thin plate-like member 1 and the connecting portion 2 described above has the thin plate-like member 1 (shown in the region surrounded by the dotted line in FIG. 2 as the region 3 surrounded by the dotted line in the meandering shape (meander shape) shown in FIG. The shape is such that it is replaced with a thin plate-like member in the shape of a character. In addition, since this example is a shape that has been replaced in this way, all of the connecting portions 2 shown in FIGS. 1 and 2 are bent downward to the right. However, the shape is not limited to the replaced shape. The structure may be such that the lower right and the lower left are mixed.

  In the current collecting member of the present invention, the adjacent strip-like portions 14 are spread in opposite directions in the thickness direction of the thin plate-like member 1, in other words, the strip-like portions 14 are on both sides in the thickness direction of the thin-plate-like member 1. As shown in FIG. 1 (b), the cross section is such that the strip-like portion 14 swells flat with the first end portion 12 and the second end portion 13 as both ends. It has a shape. Such a shape is a mold in which a slit is formed as shown in FIG. 1 (a), and a mold having a concavo-convex shape formed in accordance with the strip-shaped portion, and the concavo-convex of the upper mold and the lower mold are reversed. It can obtain by pressing from the up-down direction using the metal mold | die formed.

  Here, with respect to the shape shown in FIG. 3, as shown in FIG. 1, adjacent strips are spread out in the thickness direction in opposite directions to produce a current collecting member, as shown in FIG. When the current collecting member is sandwiched between the fuel cells and the interval between the fuel cells is reduced, the current collecting member is twisted. 4 (a) shows a state in which the intervals between the fuel cells are wide, FIG. 4 (b) shows a state in which the intervals between the fuel cells are appropriate, and FIG. 4 (c) shows a state in which the intervals between the fuel cells are reduced. FIG. 4D shows a state where the current collecting member is finally twisted and the contact area between the current collecting member and the fuel cell is reduced. On the other hand, in a region 3 surrounded by a dotted line in FIG. 3, a thin plate formed by joining two strip-like portions 14 as shown in FIGS. 1 and 2 at the first end portion 12 and the second end portion 13. By replacing the strip-shaped member 1 with each other, the adjacent strip-shaped portions 14 are subjected to a certain degree of restraint, so that twisting is not easily generated, and a sufficient contact area can be secured.

  As a thin plate-like member used corresponding to the connecting portion 2 shown in FIGS. 1 and 2, the letter-like member as shown in FIG. 5 is used in addition to the square-shaped thin plate member 1 shown in FIGS. The thin plate-like member 4, and further, a plate-like thin plate-like member (not shown) can be employed. The binding of the first end portion 12 and the second end portion 13 is stronger in the case of the Japanese character shape than the character shape, and the shape of the character character than the character shape, so that twisting can be made more difficult to occur.

  Further, the width L1 of the strip-shaped portion 14 is preferably 0.5 to 2.0 mm, and the width L2 of the first end portion 12 and the second end portion 13 is 1.5 to 3.0 mm. Is preferred.

  Note that the number of the thin plate-like members 1 connected in this shape is appropriately determined according to the length of the fuel cell, the width of the strip-like portion 14, the number of the like, and the like.

  As other embodiments, the forms shown in FIGS. 6 and 7 can also be preferably employed. Whereas the connecting portion 2 described above is formed to be bent so as to connect the first end portion 12 of one thin plate-like member 1 and the second end portion 13 of the other thin plate-like member 1. 6 and 7 connect the adjacent thin plate-like members 5 so as to constrain the strip-like portions 51 located at both ends of each connection direction, exhibit a linear shape, and connect in the connection direction. Arranged along the central axis. Note that the position of this arrangement is not limited to that along the central axis, and may be slightly shifted. In addition, the length and width of the connecting portion 6 are determined in consideration of the followability to changes in dimensions between fuel cells, the contact area with the fuel cells, etc., but the length is 2 to 4 mm and the width is Is preferably 0.5 to 2 mm.

  And the thin plate-shaped member 5 shown in FIG.6 and FIG.7 has comprised the seven strip-shaped parts 51. FIG. Here, the connection part 6 restrains the strip-like part 51 located in the connection direction both ends of the adjacent thin plate-like member 5, and when the strip-like part is spread, the restrained strip-like part 51 is on the same side. In view of balance, the number of the strip-like portions 51 in the thin plate-like member 5 is preferably at least 5 and more preferably an odd number. However, since the interval between the fuel cells varies depending on the warp or inclination of the fuel cells, the number of the strip-shaped portions of the thin plate member is preferably less than 20 so that the dimensional variation between the fuel cells can be followed. .

  Further, it is preferable that at least three thin plate members are connected. In other words, it is preferable that two or more connection portions are provided. Connecting at least three or more thin plate-like members weakens the binding by the first end 52 or the second end 53 of the strip-like portion 51, and can follow the dimensional variation between the fuel cells. Because it becomes. In particular, it is preferable to connect 5 to 10 pieces.

  In addition, the binding by the first end and the second end in the strip-shaped portion is necessary for eliminating the twist, but this constraint follows the dimensional variation between the fuel cells when the entire connection direction (longitudinal direction) is applied. Since it becomes impossible, adjusting the number of strip-shaped members and the number of thin plate-shaped members will provide a more effective shape of the current collecting member for the fuel cell. That is, by determining the width and number of the strip-shaped portions of the thin plate-like member and the number of thin plate-like members to be connected in a well-balanced manner, a fuel cell that can sufficiently secure a contact area with the fuel cell and has excellent connection reliability A current collecting member can be obtained.

  Here, the width of the strip-shaped portion 51 is appropriately determined depending on the number of the thin plate-like members 5, the number of the strip-shaped portions 51, the length of the fuel cell, and the like, but usually the same as in the previous embodiment. Is adopted.

  Further, in the thin plate member 5 shown in FIGS. 6 and 7, slits 54 having a predetermined gap are formed inside the thin plate member 5, but as shown in FIG. A slit 55 that is not formed, that is, a thin plate-like member 7 in which a so-called cut is formed can also be preferably used. The internal slit 54 shown in FIG. 6 and FIG. 7 was formed by etching or punching this portion, but the slit 55 shown in FIG. Since shearing can be performed at the same time, the material can be used without waste.

  In the present invention, there is a thin plate-like member composed of a plurality of strip-like portions that are partitioned by slits formed inside and joined to each other at the first end portion and the second end portion. Although the expression that adjacent strip-shaped portions are spread out in the thickness direction opposite to each other is used, it also includes those formed by simultaneously forming the slit and expanding as described above. Further, in the present invention, the expressions of a thin plate member and a connection portion are used, but these are usually provided integrally with the same material, and obtained by processing a single metal plate member. Means. The material is preferably a heat-resistant alloy such as Fe—Cr or Fe—Ni, and the thickness is preferably 0.3 to 0.6 mm, but is not particularly limited.

Next, a fuel cell, a fuel cell stack, and a fuel cell in which the fuel cell current collector of the present invention is used will be described.
As shown in FIG. 9, the fuel battery cell 10 according to the present invention includes a flat plate-like support substrate 101 in which a plurality of fuel gas passages 101 a are formed at appropriate intervals. Various types of fuel cell cells 101 are provided on the support substrate 101. It has a structure in which members are provided.

  The support substrate 101 is composed of a flat portion and arcuate portions at both ends of the flat portion. A fuel electrode layer 102 is provided so as to cover one of a pair of opposed surfaces of the flat portion and arcuate portions on both sides thereof. Further, a dense solid electrolyte layer 103 is formed so as to cover the fuel electrode layer 102. The air electrode 104 is laminated on the solid electrolyte layer 103 so as to correspond to the fuel electrode layer 102. An interconnector 105 is formed on the other surface of the flat portion where the fuel electrode layer 102 and the solid electrode layer 103 are not stacked. As is clear from FIG. 9, the fuel electrode layer 102 and the solid electrolyte layer 103 extend to both sides of the interconnector 105 and are configured so that the surface of the support substrate 101 is not exposed to the outside.

  In the fuel cell 10 having such a structure, the portion of the fuel electrode layer 102 facing the air electrode 104 operates as a fuel electrode to generate electric power. That is, by flowing an oxygen-containing gas such as air outside the air electrode 104 and flowing a fuel gas (hydrogen) through the fuel gas passage 101a in the support substrate 101 and heating it to a predetermined operating temperature, the air electrode 104 Electricity is generated by generating an electrode reaction of the following formula (1) and generating an electrode reaction of the following formula (2), for example, in the portion of the fuel electrode layer 102 that becomes the fuel electrode.

Air electrode: 1 / 2O ₂ + 2e ⁻ → O ²⁻ (solid electrolyte) (1)
Fuel electrode: O ²⁻ (solid electrolyte) + H ₂ → H ₂ O + 2e ⁻ (2)
The current generated by such power generation is collected via the interconnector 105 attached to the support substrate 101.

  Here, the support substrate 101 is required to be gas permeable to allow the fuel gas to permeate to the fuel electrode and to be conductive to collect current via the interconnector 105. In order to satisfy such requirements and to avoid the disadvantages caused by simultaneous firing, the support substrate 101 is composed of an iron group metal component and a specific rare earth oxide.

  The iron group metal component is for imparting conductivity to the support substrate 101, and may be a single iron group metal, or an iron group metal oxide, an iron group metal alloy or an alloy oxide. May be. The iron group metals include iron, nickel, and cobalt. In the present invention, any of them can be used, but Ni and / or NiO is changed to iron group because it is inexpensive and stable in fuel gas. It is preferable to contain as a component.

The rare earth oxide component is used to approximate the thermal expansion coefficient of the support substrate 101 to the stabilized zirconia forming the solid electrolyte layer 103, and maintains a high conductivity and is a solid electrolyte layer. In order to prevent diffusion to 3 etc., oxides Y ₂ O ₃ and Yb ₂ O ₃ containing rare earth elements are used in combination with the iron group component.

  In particular, the iron group component described above is contained in the support substrate 101 in an amount of 35 to 65% by volume in terms of approximating the thermal expansion coefficient of the support substrate 101 to stabilized zirconia, and the rare earth oxide is included in the support substrate 101. It is preferably contained in an amount of 35 to 65% by volume.

  Since the support substrate 101 composed of the iron group metal component and the rare earth oxide as described above needs to have fuel gas permeability, the open porosity is usually 30% or more, particularly 35. It is preferable to be in the range of up to 50%. Further, the conductivity of the support substrate 101 is preferably 300 S / cm or more, and particularly preferably 440 S / cm or more.

  Further, the length of the flat portion of the support substrate 101 is usually 15 to 35 mm, the length of the arc-shaped portion (arc length) is about 3 to 8 mm, and the thickness of the support substrate 101 is (both surfaces of the flat portion). Is preferably about 2.5 to 5 mm.

The fuel electrode layer 102 causes the electrode reaction of the above-described formula (2), and is formed of a known porous conductive ceramic. For example, it is formed from ZrO ₂ in which a rare earth element is dissolved, and Ni and / or NiO. As ZrO ₂ (stabilized zirconia) in which the rare earth element is dissolved, the same one used for forming the solid electrolyte layer 103 described below is preferably used.

In the example of FIG. 9, the fuel electrode layer 102 extends to both sides of the interconnector 105, but it is sufficient that the fuel electrode is formed in a position facing the air electrode 104, For example, the fuel electrode layer 102 may be formed only on the flat portion on the side where the air electrode 104 is provided.

The solid electrolyte layer 103 provided on the fuel electrode layer 102 is generally formed of a dense ceramic called ZrO ₂ (usually stabilized zirconia) in which 3 to 15 mol% of a rare earth element is dissolved. . Examples of rare earth elements include Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu, but they are inexpensive. From the point, Y and Yb are desirable.

The air electrode 104 is formed of a conductive ceramic made of a so-called ABO ₃ type perovskite oxide. As such a perovskite oxide, at least one of transition metal perovskite oxides, particularly LaMnO ₃ oxides, LaFeO ₃ oxides, and LaCoO ₃ oxides having La at the A site is preferable. LaFeO ₃ -based oxides are particularly suitable because they have high electrical conductivity at an operating temperature of about 1000 ° C. In the perovskite oxide, Sr and the like may exist together with La at the A site, and Co and Mn may exist together with Fe at the B site.

The interconnector 105 provided on the support substrate 101 is generally made of a lanthanum chromite perovskite oxide (LaCrO ₃ oxide). Further, in order to prevent leakage of the fuel gas passing through the inside of the support substrate 101 and the oxygen-containing gas passing through the outside of the support substrate 101, such conductive ceramics must be dense, for example, 93% or more, particularly 95%. It is preferable to have the above relative density.

  A P-type semiconductor layer 106 is preferably provided on the outer surface (upper surface) of the interconnector 105. The fuel cell current collector of the present invention is connected to the interconnector 105. However, if the fuel cell current collector is directly connected to the interconnector 105, the potential drop increases due to non-ohmic contact. The current collecting performance will be reduced. As such a P-type semiconductor, a transition metal perovskite oxide can be exemplified.

  As shown in FIG. 10, the fuel cell stack includes a fuel cell current collecting member interposed between the fuel cell 10 and the fuel cell 10 to electrically connect the plurality of fuel cells 10 in series. Can be obtained. At this time, the elongated strip-shaped portion of the current collecting member for the fuel cell is in contact with the air electrode of one fuel cell of the adjacent fuel cells, and the other fuel of the adjacent fuel cells. It is in contact with the P-type semiconductor of the battery cell. FIG. 10 shows a state viewed from above when the fuel battery cell 10 shown in FIG. 9 is arranged upright. The fuel cell can be obtained by storing the fuel cell stack in a storage container. By such a fuel cell stack and a fuel cell, a fuel cell excellent in long-term reliability with little voltage drop can be obtained.

Here, the manufacturing method of a fuel cell is demonstrated.
First, a slurry is prepared by mixing an iron group metal such as Ni or its oxide powder, a rare earth oxide powder such as Y ₂ O ₃ , an organic binder, and a solvent, and extrusion using this slurry. A support substrate molded body is produced by molding and dried.

  Next, a fuel electrode layer forming material (Ni or NiO powder and stabilized zirconia powder), an organic binder, and a solvent are mixed to prepare a slurry, and a sheet for the fuel electrode layer is prepared using this slurry. Further, instead of producing a sheet for the fuel electrode layer, a paste in which the fuel electrode forming material is dispersed in a solvent is applied to a predetermined position of the formed support substrate and dried, and then the fuel electrode layer is formed. A coating layer may be formed.

Furthermore, a stabilized zirconia powder, an organic binder, and a solvent are mixed to prepare a slurry, and a solid electrolyte layer sheet is prepared using this slurry.

  The support substrate molded body, the fuel electrode sheet and the solid electrolyte layer sheet formed as described above are laminated so as to have a layer structure as shown in FIG. 9, for example, and dried. In this case, when the coating layer for the fuel electrode layer is formed on the surface of the support substrate molded body, only the solid electrolyte layer sheet may be laminated on the support substrate molded body and dried.

Thereafter, the interconnector material (e.g., LaCrO ₃ based oxide powder), an organic binder and a solvent were mixed to prepare a slurry, to produce the interconnector sheet.

  This interconnector sheet is further laminated at a predetermined position of the laminate obtained above to produce a firing laminate.

  Next, the above laminate for firing is subjected to binder removal treatment, and co-fired at 1300 to 1600 ° C. in an oxygen-containing atmosphere to obtain a sintered body.

Next, a paste containing an air electrode forming material (for example, LaFeO ₃ -based oxide powder) and a solvent and, if necessary, a P-type semiconductor layer forming material (for example, LaFeO ₃ -based) at a predetermined position of the sintered body. Oxide powder) and a solvent-containing paste were applied by dipping or the like, and an air electrode coating layer was provided on the surface of the solid electrolyte layer. At the same time, the paste is applied to the outer surface of the interconnector formed in the sintered body, a P-type semiconductor coating layer is provided, and baking is performed at 1000 to 1300 ° C.
A fuel cell is produced through the above steps.

  Then, using a Fe-Cr heat-resistant alloy plate having a thickness of 0.3 to 0.6 mm, a current collecting member processed into the aforementioned shape is prepared, and the current collecting member and the aforementioned fuel cell are electrically connected. In addition, a paste prepared by mixing a powder composed of the transition metal perovskite oxide, which is the P-type semiconductor, an organic binder, and a solvent for mechanical bonding, is used as the air electrode and the interconnector surface of the fuel cell. And after apply | coating to a current collection member, a fuel cell and a current collection member are laminated | stacked alternately, and it bakes at 1000-1300 degreeC. Further, the stacked fuel cell and the current collecting member are disposed in a manifold, and the fuel cell and the manifold are sealed with glass or the like, thereby producing a fuel cell stack.

  The fuel cell is manufactured by arranging the plurality of cell stacks in a storage container and piping a fuel gas introduction tube and an air introduction tube for sending the fuel cell to the fuel cell for use in power generation.

BRIEF DESCRIPTION OF THE DRAWINGS It is explanatory drawing which shows one Embodiment of the current collection member for fuel cells of this invention, (a) is a front view before an adjacent strip-shaped part is spread in the thickness direction mutually oppositely, (b) is adjacent. It is an AA line cross-sectional view shown to (a) after the strip-shaped part which fits was expanded in the thickness direction in the opposite direction mutually. FIG. 2 is a partially enlarged view of a fuel cell current collecting member shown in FIG. 1. It is explanatory drawing which shows the meander-shaped member for demonstrating the current collection member for fuel cells of this invention. It is explanatory drawing of the problem of the meander-shaped member shown in FIG. 3, (a) is a state with a wide space | interval of a fuel cell, (b) is a state with a suitable space | interval of a fuel cell, (c) is a fuel cell. FIG. 4D shows a state in which the cell interval is narrow, and FIG. 4D shows a state in which the current collecting member is twisted and the contact area between the current collecting member and the fuel cell is reduced. It is explanatory drawing which shows other embodiment of the current collection member for fuel cells of this invention. It is explanatory drawing which shows further another embodiment of the current collection member for fuel cells of this invention, (a) is a front view before the strip-shaped part which adjoins is pushed apart mutually in the thickness direction, (b) [Fig. 5] Fig. 5 is a cross-sectional view taken along line B-B shown in (a) after adjacent strip-shaped portions are spread in opposite directions in the thickness direction. FIG. 7 is a partially enlarged view of the fuel cell current collecting member shown in FIG. 6. It is explanatory drawing which shows other embodiment of the current collection member for fuel cells of this invention. It is explanatory drawing of the fuel cell used together with the current collection member for fuel cells of this invention. It is explanatory drawing of the fuel cell stack of this invention, and has shown the state seen from the upper side when the fuel cell 10 shown in FIG. 9 is arrange | positioned upright. It is explanatory drawing which shows an example of the conventional current collection member for fuel cells, (a) is a front view, (b) is a cross-sectional view. It is explanatory drawing which shows the other example of the conventional collector member for fuel cells. It is explanatory drawing of the problem of the current collection member for fuel cells shown in FIG. 10, (a) is the state where the space | interval of the fuel cell expanded, (b) is the state where the space | interval of a fuel cell is optimal, (c). Indicates a state in which the interval between the fuel cells is reduced.

Explanation of symbols

1, 4, 5, 7... Thin plate members 11, 54, 55... Slit 12, 52... First end 13, 53. Strip-shaped part 2, 6 ... connection part 21 ... 1st area | region 22 ... 2nd area | region

Claims (7)

A current collecting member for electrically connecting adjacent fuel cells,
A thin plate-like member composed of a plurality of strip-shaped portions that are partitioned by slits formed inside and joined to each other at the first end and the second end, the strip-shaped portions are parallel and the first A plurality of one end portion and the second end portion are connected in series via the connecting portion so that they are arranged on the same line,
A current collecting member for a fuel cell, wherein the adjacent strip-shaped portions are spread in opposite directions in the thickness direction. A connection portion is formed by bending so as to connect the first end portion and the second end portion, a first region parallel to the strip-like portion, the first end portion and the first end And a second region connecting the second end and the first region,
The current collecting member for a fuel cell according to claim 1, wherein the first region is expanded in the thickness direction like the strip-shaped portion. The thin plate-like member is a member formed in any one of a letter shape having two strip-shaped portions, a Japanese character shape having three strip-shaped portions, and a character shape having four strip-shaped portions. The current collecting member for a fuel cell according to claim 2. 2. The fuel cell current collecting member according to claim 1, wherein the thin plate-like member comprises at least five or more strip-like portions, and the connecting portions are arranged along a central axis in a connecting direction. The current collecting member for a fuel cell according to any one of claims 1 to 4, wherein at least three thin plate-like members are connected. A current collecting member for a fuel cell according to any one of claims 1 to 5 is interposed between the adjacent fuel cells, and a plurality of fuel cells are electrically connected in series. Fuel cell stack. 7. A fuel cell comprising the fuel cell stack according to claim 6 housed in a housing container.

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