JP2006142136A - Foreign matter removal method and apparatus in slag - Google Patents

Foreign matter removal method and apparatus in slag Download PDF

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JP2006142136A
JP2006142136A JP2004332167A JP2004332167A JP2006142136A JP 2006142136 A JP2006142136 A JP 2006142136A JP 2004332167 A JP2004332167 A JP 2004332167A JP 2004332167 A JP2004332167 A JP 2004332167A JP 2006142136 A JP2006142136 A JP 2006142136A
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slag
specific gravity
foreign matter
dry
dust
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JP4776211B2 (en
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Munetaka Hagitani
宗高 萩谷
Yuichi Tago
祐一 田子
Mikio Mogi
幹夫 茂木
Atsushi Nonomura
敦 野々村
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IHI Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To recover a slag and a foreign matter in the state that a handling property is enhanced. <P>SOLUTION: An indirect heating type drying device 24, a sieve 33, a magnetic sorting machine 37, a sieving device 27 and a dry type specific gravity sorting machine 25 are provided on a downstream side of a receiving hopper 23 for receiving a water-granulated slag 22 recovered by a fusion furnace in the order. After the water-granulated slag 22 in the receiving hopper 23 is subjected to drying treatment by the indirect heating type drying device 24, large metals and the foreign matters 34 are separated by the sieve 33. After a magnetic substance 38 is removed by the magnetic sorting machine 37, an undersize substance 22b of the sieve 33 is applied to the sieving device 27 and a slag particle having a large particle diameter having fear of generating sorting failure is previously separated as an oversize substance 22d by the dry type specific gravity sorting machine 25 at the downstream side and is recovered to a product slag recovery part 40. The undersize substance 22e of the sieving device 27 is applied to the dry type specific gravity sorting machine 25 to separate by specific gravity the foreign matter 26 having smaller specific gravity than that of the slag particle 22f. The slag particle 22f and the foreign matter 26 are recovered to the product slag recovery part 40 and a foreign matter recovery part 47 respectively. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、廃棄物や灰等を溶融して得られるスラグ中に混入する未燃分や未溶融ダスト等の異物を除去するためのスラグ中の異物除去方法及び装置に関するものである。   The present invention relates to a foreign matter removing method and apparatus for removing foreign matter such as unburned matter and unmelted dust mixed in slag obtained by melting waste, ash, and the like.

現在、廃棄物の処理方法としては焼却処理が多く行われてきており、その処理方式の一つとしては、廃棄物の熱分解ガス化溶融方式が知られている。これは、廃棄物を、熱分解炉に装入して低酸素雰囲気下で間接加熱することにより、一旦、熱分解ガスと熱分解残渣に熱分解させて回収し、その後、該熱分解ガスと熱分解残渣を、共に溶融炉、たとえば、表面溶融炉へ供給して高温で燃焼させることにより、不燃物及び灰分を溶融させてスラグ化させるようにしてある。このようにスラグ化することにより、埋立処分の対象となる最終処分物の大幅な減容化並びに安定化(無害化)を図ることができ、更には、この無害化された最終処分物であるスラグを、路盤材等の建設資材として資源化を図ることが可能になる。   At present, incineration is frequently performed as a waste treatment method, and as one of the treatment methods, a thermal decomposition gasification melting method of waste is known. This is because waste is charged into a pyrolysis furnace and indirectly heated in a low-oxygen atmosphere so that it is once thermally decomposed into a pyrolysis gas and a pyrolysis residue and then recovered. Both pyrolysis residues are supplied to a melting furnace, for example, a surface melting furnace, and burned at a high temperature, thereby melting incombustibles and ash to form slag. By making slag in this way, it is possible to achieve a significant volume reduction and stabilization (detoxification) of the final disposal object to be landfilled. It becomes possible to recycle slag as construction materials such as roadbed materials.

又、従来、廃棄物の焼却処理方法として一般に知られている廃棄物を焼却炉に供給して直接的に燃焼させる方式においても、最終処分量の減容化を図ったり、最終処分物の無害化や資源化を図るために、上記焼却炉にて廃棄物を燃焼させることで生じる炉下灰や飛灰等の灰を、灰溶融炉へ供給して、溶融させてスラグ化させることが行なわれるようになってきている。   In addition, in the conventional method of supplying waste to an incinerator and directly combusting it, which is generally known as a method for incineration of waste, the volume of the final disposal is reduced or the final disposal is harmless. In order to promote recycling and resource recycling, ash such as in-furnace ash and fly ash generated by burning waste in the incinerator is supplied to the ash melting furnace and melted to form slag. It is becoming

上記廃棄物の熱分解ガス化溶融方式で用いる溶融炉や、廃棄物の直接燃焼方式で生じる灰を処理するための溶融炉では、図4に示す如く、溶融炉1にて廃棄物や灰を溶融させることにより生じる溶融スラグ2を、該溶融炉1の出滓口1aより、下方に設けてある冷却水槽3へ落下投入させ、これにより上記溶融スラグ2を水冷して、水砕スラグ4として回収することが多く行なわれている。   In a melting furnace used in the above pyrolysis gasification melting method of waste or a melting furnace for treating ash generated in the direct combustion method of waste, as shown in FIG. The molten slag 2 generated by melting is dropped into the cooling water tank 3 provided below from the outlet 1 a of the melting furnace 1, whereby the molten slag 2 is cooled with water to form a granulated slag 4. Many are collected.

ところで、上記溶融炉1では、廃棄物の熱分解残渣や灰等の溶融対象物が変わったり、その量や性状が変化すると、廃棄物の熱分解炉より得られる熱分解残渣中のチャーや、廃棄物の焼却炉にて焼却されずに残っていた可燃物等が、未燃状態のまま出滓口1aより排出されたり、あるいは、燃焼により生じた灰等の灰分が未溶融状態のまま出滓口1aより排出されてしまうことがある。このように、未燃状態のまま排出された可燃物(以下、未燃分という)や、未溶融状態の灰分(以下、未溶融ダストという)が、溶融炉1の出滓口1aより排出されて冷却水槽3へ投入されるようになると、該冷却水槽3より回収される水砕スラグ4に、上記未燃分や未溶融ダストが付着して、回収した水砕スラグ4に未燃分や未溶融ダストが混入する虞がある。この場合、未燃分や未溶融ダストでは、含まれている重金属類等の固定が行われておらず、重金属類が溶出する虞があることから、回収した水砕スラグ4が土壌環境基準に適合しなくなったり、未燃分が混入することに伴って、水砕スラグ4に気泡が生じて路盤材等の建設資材として不適になるため、資源として再利用することが困難になる。   By the way, in the melting furnace 1, when the object to be melted such as the pyrolysis residue or ash of the waste is changed or the amount or property thereof is changed, the char in the pyrolysis residue obtained from the waste pyrolysis furnace, Combustibles left unincinerated in the waste incinerator are discharged from the outlet 1a in an unburned state, or ashes such as ash generated by combustion are left in an unmelted state. It may be discharged from the shed 1a. In this way, combustibles discharged in an unburned state (hereinafter referred to as unburned matter) and unmelted ash (hereinafter referred to as unmelted dust) are discharged from the outlet 1a of the melting furnace 1. Then, when it is put into the cooling water tank 3, the unburned matter and unmelted dust adhere to the granulated slag 4 recovered from the cooling water tank 3, and the unburned slag 4 There is a possibility that unmelted dust may be mixed. In this case, in the unburned matter and unmelted dust, the contained heavy metals are not fixed, and heavy metals may be eluted. Therefore, the recovered granulated slag 4 conforms to the soil environmental standards. Incompatibility or when unburned components are mixed in, bubbles are generated in the granulated slag 4 and become unsuitable as construction materials such as roadbed materials, making it difficult to reuse them as resources.

そのため、回収する水砕スラグ4に対する未燃分や未溶融ダストの混入量を、所要の基準以下に抑える必要がある。このように水砕スラグ4に対する未燃分や未溶融ダストの混入量を抑えるための手法の1つとしては、溶融炉1における燃焼改善等の運転制御を図ることで、溶融スラグ化させる率を向上させるようにすることが行われている。   Therefore, it is necessary to suppress the amount of unburned matter and unmelted dust mixed in the granulated slag 4 to be recovered to a required standard or less. As one of the techniques for suppressing the amount of unburned matter and unmelted dust mixed in the granulated slag 4 as described above, the rate of melting slag can be set by controlling operation such as combustion improvement in the melting furnace 1. It is done to improve.

しかし、上記のように溶融炉の運転条件を最適な条件に整えるようにしていても、溶融炉に供給される溶融対象物の量や性状が変動する場合には、炉の最適な運転条件が変化するため、最適な運転条件にするには、上記溶融対象物の量や性状の変動に合わせて、その都度調整することが必要になるが、あらゆる運転状況において運転条件を調整することは難しく、その結果、溶融炉1より未燃分や未溶融ダストが排出される虞をなくして、回収される水砕スラグ4に上記未燃分や未溶融ダストが混入されないようにすることは困難である。   However, even if the operating conditions of the melting furnace are adjusted to the optimum conditions as described above, the optimum operating conditions of the furnace can be changed if the amount and properties of the object to be melted supplied to the melting furnace fluctuate. In order to achieve optimum operating conditions, it is necessary to adjust each time according to the amount and properties of the melted object, but it is difficult to adjust the operating conditions in all operating conditions. As a result, it is difficult to eliminate the possibility of unburned matter and unmelted dust being discharged from the melting furnace 1 and prevent the unburned matter and unmelted dust from being mixed into the recovered granulated slag 4. is there.

そのために、水砕スラグ4に付着する未燃分や未溶融ダストを洗浄して除去するようにしたものとして、図4に示す如く、上記冷却水槽3より回収される水砕スラグ4を搬送するコンベアの如き搬送装置5の下流側にスラグ洗浄ホッパ6を備えて、水砕スラグ4を搬送装置5により該スラグ洗浄ホッパ6へ搬送して一旦貯留させるようにし、このスラグ洗浄ホッパ6内に貯留している水砕スラグ4に対し、ホッパ上部に設けてある洗浄ノズル7より洗浄水8を噴霧することにより、上記水砕スラグ4に付着している未溶融ダスト等を洗浄して除去するようにしたものが提案されている(たとえば、特許文献1参照)。   Therefore, as shown in FIG. 4, the granulated slag 4 recovered from the cooling water tank 3 is transported, assuming that unburned matter and unmelted dust adhering to the granulated slag 4 are washed and removed. A slag cleaning hopper 6 is provided on the downstream side of the transport device 5 such as a conveyor, and the granulated slag 4 is transported to the slag cleaning hopper 6 by the transport device 5 and temporarily stored, and stored in the slag cleaning hopper 6. The sprayed cleaning water 8 is sprayed from the cleaning nozzle 7 provided in the upper part of the hopper to the water granulated slag 4 so that unmelted dust and the like adhering to the water granulated slag 4 is cleaned and removed. (See, for example, Patent Document 1).

又、上記と同様に水砕スラグ4を洗浄するものとして、図5に示す如く、溶融炉1に付設された冷却水槽3にコンベアの如き搬送装置9を備えて、該冷却水槽3に溶融スラグ2が落下させられて形成された水砕スラグ4を搬送装置9により回収して取出口10より取り出すようにしてある構成において、該取出口10の部分に、洗浄スプレー11を設け、上記取出口10より取り出される水砕スラグ4に対して、洗浄スプレー11より洗浄水12を吹き付けることにより、上記水砕スラグ4に付着している未燃分や未溶融ダストを洗浄して除去するようにしたものも提案されている(たとえば、特許文献2参照)。   In addition, as shown in FIG. 5, the water granulated slag 4 is washed in the same manner as described above. The cooling water tank 3 attached to the melting furnace 1 is provided with a conveying device 9 such as a conveyor, and the molten water slag 3 is provided in the cooling water tank 3. In the configuration in which the granulated slag 4 formed by dropping 2 is collected by the transport device 9 and taken out from the outlet 10, a cleaning spray 11 is provided at the outlet 10, and the outlet By spraying the washing water 12 from the washing spray 11 on the granulated slag 4 taken out from 10, the unburned matter and unmelted dust adhering to the granulated slag 4 are washed and removed. The thing is also proposed (for example, refer patent document 2).

なお、廃棄物を溶融炉において溶融処理してなる廃棄物溶融スラグを、土木建設用骨材や窯業原料化するにあたり、上記廃棄物溶融スラグに混入している金属を除去するための装置として、図6に示す如く、スラグ破砕機14と、所要粒度を基準に分級を行う篩15と、比重分離装置16と、固液分離する水−スラグ分離機17とを順に備えて、製品砂20とするようにしたものが従来提案されている。   As a device for removing the metal mixed in the waste molten slag, when the waste molten slag obtained by melting the waste in the melting furnace is used as an aggregate for civil engineering construction or as a ceramic material, As shown in FIG. 6, a slag crusher 14, a sieve 15 that performs classification based on a required particle size, a specific gravity separator 16, and a water-slag separator 17 that performs solid-liquid separation are provided in order, What has been proposed has been proposed.

詳述すると、上記スラグ破砕機14は、回動する胴体の内部に、原料となるスラグ13を、複数の可動体、及び、緩衝流体である水と共に収納させ、胴体の回動に伴って相互に接近離間し合う可動体の間にて、ガラス質のスラグ粒子の破砕処理を行うと共に、上記原料スラグに混入している金属粒子に対しては圧延作用を及ぼすようにして、スラグ粒子は小径化させる一方、アルミ等の延展性に優れた金属粒子を大径化して薄片とさせることができるようにしてある。   More specifically, the slag crusher 14 stores the slag 13 as a raw material together with a plurality of movable bodies and water as a buffer fluid inside the rotating body, and is mutually associated with the rotation of the body. The glassy slag particles are crushed between the movable bodies approaching and separating from each other, and the metal particles mixed in the raw material slag have a rolling action so that the slag particles have a small diameter. On the other hand, the metal particles having excellent spreadability such as aluminum can be made into a flake by increasing the diameter.

又、上記比重分離装置16は、内周面に螺旋溝が形成してある回転胴内に一端側より他端側へ向けて所要の流速の水流を形成させた状態にて、比重の小さいガラス質の破砕スラグと、比重のより大きい金属成分の破砕スラグ(金属粒子)とを、上流側の篩15によりある程度粒度が揃えられた状態で投入すると、これらの破砕スラグは、両者の比重差に応じて、金属成分の破砕スラグは早期に沈降し、ガラス質の破砕スラグはその上方へ位置するように層状に分離されるようになるため、沈降する金属成分の破砕スラグは、回転胴の内面に形成されている螺旋溝により水流に逆らって搬送させる一方、回転胴の内面との接触が少なく、上記水流の影響を受け易いガラス質の破砕スラグは水流に乗せて搬送させることで、ガラス質の破砕スラグと金属成分の破砕スラグとを分離できるようにしてある。   The specific gravity separator 16 is a glass having a small specific gravity in a state where a water flow having a required flow velocity is formed from one end side to the other end side in a rotating drum having a spiral groove formed on the inner peripheral surface. When crushed slag of high quality and crushed slag (metal particles) of a metal component having a higher specific gravity are introduced in a state in which the particle size is made uniform to some extent by the upstream sieve 15, these crushed slags have a difference in specific gravity between them. Accordingly, the crushed slag of the metal component settles early, and the crushed slag of the vitreous material is separated into layers so as to be positioned above the slag of the metal component. It is conveyed against the water flow by the spiral groove formed in the glass, while the glassy crushed slag that is less affected by the inner surface of the rotating drum and is easily affected by the water flow is carried on the water flow to make it vitreous. Crushing slag And crushing slag metal components are also available separation.

そのため、図6に示した装置において、原料スラグ13を供給すると、先ず、スラグ破砕機14にて上記原料スラグ13中のガラス質のスラグ粒子は破砕されて小径化させられ、一方、混入しているアルミ等の延展性に優れた金属粒子は圧延されて大径化させられる。次に、篩15にて分級することにより、上記スラグ破砕機14にて破砕されて小径化された破砕スラグより、上記大径化されたアルミ等の金属粒子18aが、分離して除去される。次いで、比重分離装置16にて、上記篩15より回収された破砕スラグのうち、ガラス質の破砕スラグより、金属成分の破砕スラグ(鉄、銅、SUS等の金属粒子)18bが分離して除去される。しかる後、水−スラグ分離機17にて、上記比重分離装置16より回収されるガラス質の破砕スラグより水19を分離して除去することにより、上記ガラス質の破砕スラグを製品砂20として回収することができるようにしてある(たとえば、特許文献3参照)。   Therefore, when the raw material slag 13 is supplied in the apparatus shown in FIG. 6, first, the vitreous slag particles in the raw material slag 13 are crushed and reduced in diameter by the slag crusher 14. The metal particles having excellent spreadability such as aluminum are rolled to increase the diameter. Next, by classifying with the sieve 15, the metal particles 18 a such as aluminum having a large diameter are separated and removed from the crushed slag crushed by the slag crusher 14 and reduced in diameter. . Next, among the crushed slag collected from the sieve 15 by the specific gravity separator 16, the crushed slag (metal particles such as iron, copper, SUS, etc.) 18b of the metal component is separated and removed from the vitreous crushed slag. Is done. Thereafter, the water-slag separator 17 separates and removes the water 19 from the glassy crushed slag collected from the specific gravity separator 16, thereby collecting the glassy crushed slag as product sand 20. (See, for example, Patent Document 3).

なお、図6における符号21は、上記水−スラグ分離機17にて製品砂20より分離された水19を処理するための水処理設備であり、該水処理設備21にて処理した処理水は上記スラグ破砕機14へ戻して循環利用するようにしてある。   In addition, the code | symbol 21 in FIG. 6 is the water treatment equipment for processing the water 19 isolate | separated from the product sand 20 with the said water-slag separator 17, and the treated water processed with this water treatment equipment 21 is It is made to return to the slag crusher 14 and circulate.

特開平9−243032号公報JP-A-9-243032 特開2002−122319号公報JP 2002-122319 A 特開2003−211141号公報Japanese Patent Laid-Open No. 2003-211141

ところが、上記図4及び図5に示されているように、水砕スラグ4を洗浄水8や12を用いて洗浄するようにした方式を採用すれば、水砕スラグ4に混入した未燃分や未溶融ダストを除去することは可能であるが、この場合には、莫大な洗浄水量を必要とするため、排水処理を行うための排水処理設備が大規模となり、その設置スペースの確保や設備費用が嵩むという問題が生じる虞がある。   However, as shown in FIG. 4 and FIG. 5 above, if a method in which the granulated slag 4 is washed using the washing water 8 or 12 is used, the unburned component mixed in the granulated slag 4 is used. It is possible to remove the unmelted dust and unmelted dust. In this case, however, an enormous amount of washing water is required. There is a possibility that the problem of increased costs arises.

更に、上記洗浄水8,12により水砕スラグ4の洗浄処理が行われた場合に除去されて洗浄水8,12側に移行する未燃分や未溶融ダストは、排水処理設備にて多量の水分を含むケーキとして回収されるようになるため、必要以上に重量が増してハンドリングが困難になると共に、上記ケーキとして回収される未燃分や未溶融ダストを、再度、燃焼処理や溶融処理を行おうとする場合には、含まれている水分が炉内温度を低下させる要因となってしまうために、無駄な助燃料を必要とするようになるという問題が生じる。   Further, when the granulated slag 4 is washed with the washing water 8 and 12, unburned matter and unmelted dust that are removed and transferred to the washing water 8 and 12 side are a large amount in the waste water treatment facility. Since it will be collected as a cake containing moisture, handling will be difficult due to an increase in weight more than necessary, and the unburned matter and unmelted dust collected as the cake will again be subjected to combustion treatment and melting treatment. When trying to do so, the contained moisture becomes a factor that lowers the temperature in the furnace, so that there arises a problem that unnecessary auxiliary fuel becomes necessary.

更に又、水砕スラグ自体も、水分が含まれた状態で回収されるようになるため、ハンドリング性を向上させるためには、回収後に、水砕スラグに含まれる水分を低減させることが必要とされるという問題もある。   Furthermore, since the granulated slag itself is recovered in a state where moisture is contained, it is necessary to reduce the moisture contained in the granulated slag after the recovery in order to improve handling. There is also the problem of being.

ところで、未燃分や未溶融ダストは、一旦溶融されてガラス化されたスラグに比べ比重が軽い。この点に鑑みて、水砕スラグに混入している未燃分や未溶融ダストを除去するために、図6に記載された比重分離装置16を適用して、上記水砕スラグと、未燃分や未溶融ダストとを、比重差に基づいて分離することが考えられる。この場合、該図6に記載された比重分離装置16は、所要流速の水流中においては、比重差のある粒子はそれぞれの比重差に基づいて沈降し易さが異なるため上下方向に層状に分離され、このために、下層に沈降する比重の大きい粒子は水流の影響を受ける割合が小さいのに対し、上層に分布する比重の小さい粒子は、水流の影響を大きく受けて該水流に乗って搬送され易い、という原理に基づいて各粒子を比重分離するようにしているものであるため、たとえ、該比重分離装置16を用いて上記水砕スラグと、より比重の小さい未燃分や未溶融ダストとを分離できるとしても、回収される水砕スラグは水分を含んだ状態となると共に、該水砕スラグより比重分離される未燃分や未溶融ダストも水分を含んだ状態となる。そのため、上記図4及び図5に記載したものと同様に、回収される水砕スラグや、未燃分及び未溶融ダストのハンドリング性等の問題が生じてしまう。更に、未燃分や未溶融ダストが吸湿した場合、比重が重くなり、スラグと共に沈んでしまうため上手く分離ができなくなる虞も生じる。   By the way, unburned matter and unmelted dust are lighter in specific gravity than slag once melted and vitrified. In view of this point, in order to remove the unburned matter and unmelted dust mixed in the granulated slag, the specific gravity separation device 16 described in FIG. It is conceivable to separate minute and unmelted dust based on the specific gravity difference. In this case, the specific gravity separation device 16 shown in FIG. 6 separates particles having specific gravity differences into layers in the vertical direction because particles having different specific gravity differ in the ease of settling based on the specific gravity differences. For this reason, particles with a large specific gravity that sink to the lower layer are less affected by the water flow, whereas particles with a lower specific gravity distributed in the upper layer are greatly affected by the water flow and are carried on the water flow. Since each particle is subjected to specific gravity separation based on the principle that it is easy to be carried out, even if the above-mentioned granulated slag is used with the specific gravity separation device 16, unburned or unmelted dust having a lower specific gravity. Can be separated, the recovered granulated slag is in a state containing moisture, and unburned matter and unmelted dust separated by specific gravity from the granulated slag are also in a state containing moisture. Therefore, similarly to what was described in FIG. 4 and FIG. 5 above, problems such as recovered granulated slag, unburned matter, and unmelted dust handling properties occur. Furthermore, when unburned matter or unmelted dust absorbs moisture, the specific gravity becomes heavy and sinks with the slag.

そこで、本発明は、スラグに混入する未燃分や未溶融ダスト等の異物を除去できると共に、スラグを含水率が少ない状態で回収できて、ハンドリング性を向上させて再利用し易い状態とすることができ、更に、上記スラグより分離、除去する未燃分や未溶融ダスト等の異物も、ハンドリング性のよい乾燥状態で回収することができるようにするスラグ中の異物除去方法及び装置を提供しようとするものである。   Therefore, the present invention can remove foreign matters such as unburned matter and unmelted dust mixed in the slag, and can recover the slag with a low moisture content, improving handling and making it easy to reuse. Furthermore, a foreign matter removing method and apparatus for removing foreign matter in slag that can collect unburned matter and unmelted dust and other foreign matter separated and removed from the slag in a dry state with good handling properties is provided. It is something to try.

本発明は、上記課題を解決するために、請求項1に係る発明に対応して、溶融炉より排出される溶融スラグを水冷してなる水砕スラグを、乾燥処理した後、該乾燥した水砕スラグを乾式で比重選別処理して、スラグより比重の小さい未燃分や未溶融ダストの如き異物を分離除去するスラグ中の異物除去方法、及び、請求項3に係る発明に対応して、溶融炉より排出される溶融スラグを水冷してなる水砕スラグを受け入れるための受入ホッパの下流側に、乾燥装置と乾式比重選別機とを順に備えてなり、乾燥した水砕スラグを乾式比重選別機でスラグ粒子と異物に分離するようにした構成を有するスラグ中の異物除去装置とする。   In order to solve the above-mentioned problem, the present invention, corresponding to the invention according to claim 1, after drying the granulated slag obtained by water-cooling the molten slag discharged from the melting furnace, the dried water Corresponding to the invention according to claim 3, wherein the crushed slag is subjected to a specific gravity sorting process by a dry method, and the foreign matter removal method in the slag for separating and removing foreign matters such as unburned matter and unmelted dust having a specific gravity smaller than the slag, and In the downstream of the receiving hopper for receiving granulated slag obtained by cooling the molten slag discharged from the melting furnace, a drying device and a dry specific gravity sorter are provided in order, and the dry granulated slag is sorted by dry specific gravity. An apparatus for removing foreign matter in slag having a configuration in which the slag particles and foreign matter are separated by a machine.

又、上記乾燥装置による乾燥処理を、間接加熱方式で行うようにする方法及び装置とする。   Also, a method and apparatus for performing the drying process by the drying apparatus by an indirect heating method.

更に、上記各構成において、乾燥装置と乾式比重選別機との間に、篩分装置を設けて、乾燥した水砕スラグの粒径の小さいものを乾式比重選別機へ導くようにした構成とする。   Furthermore, in each said structure, it is set as the structure which provided the sieving apparatus between the drying apparatus and the dry-type specific gravity sorter, and led the thing with the small particle diameter of the dried granulated slag to a dry-type specific gravity sorter. .

更に又、上記各構成において、乾燥装置と乾式比重選別機との間に、磁選機を設けるようにした構成とする。   Furthermore, in each said structure, it is set as the structure which provided the magnetic separator between the drying apparatus and the dry-type specific gravity sorter.

上述の各構成において、乾燥装置と乾式比重選別機からのダスト状の異物を回収するための集塵装置を設けた構成とする。   In each of the above-described configurations, a dust collector for collecting dust-like foreign matter from the drying device and the dry specific gravity sorter is provided.

本発明によれば、以下の如き優れた効果を発揮する。
(1)溶融炉より排出される溶融スラグを水冷してなる水砕スラグを、乾燥装置にて乾燥処理した後、該乾燥した水砕スラグを乾式比重選別機にて比重選別処理して、スラグより比重の小さい未燃分や未溶融ダストの如き異物を分離除去するスラグ中の異物除去方法及び装置としてあるので、スラグに混入されている未燃分や未溶融ダストの如き異物を比重差を基に容易に分離除去することができて、このような異物の除去された製品スラグを回収することができる。しかも、上記製品スラグとして回収されるものは、含水率が少ない状態となっているため、回収した製品スラグのハンドリング性を向上させることができて、再利用し易い状態とすることができる。
(2)又、スラグより分離させる未燃分や未溶融ダストの如き異物も、乾燥状態で回収できるため、ハンドリング性を向上させることができて、その処理を容易に行なうことができる。したがって、上記異物を再び燃焼処理や溶融処理する場合であっても、無駄な助燃料を必要とすることはない。
(3)更に、製品スラグとして回収される粒子については、スラグとしての高純度化を容易に図ることができるため、溶融炉の運転状態の変動により、該溶融炉より回収される水砕スラグのスラグ性状が悪化したとしても、本発明のスラグ中の異物除去方法及び装置を適用することによりリカバーすることが可能になる。
(4)更に又、従来、水砕スラグに混入している異物を除去するために要していた如き洗浄水を必要としないため、大規模な排水処理設備等を設ける必要をなくすことができ、設備を小スペースにコンパクトに設置することが可能となる。
(5)水砕スラグの乾燥処理を、間接加熱式の乾燥装置で行うようにすることにより、該乾燥処理の際、乾燥処理対象である水砕スラグに未燃分が混入していたとしても、該未燃分が燃焼する虞を未然に防止することができる。更に、スラグに混入されている未燃分や未溶融ダストの如き異物が飛散したり、粉塵化することを防止できる。
(6)乾燥装置と乾式比重選別機との間に、篩分装置を設けて、乾燥した水砕スラグの粒径の小さいものを乾式比重選別機へ導くようにした構成とすることにより、乾式比重選別機へ供給する粒子の粒度をある程度揃えることができるため、該乾式比重選別機にてスラグと異物との選別不良が発生する虞を未然に防止することができる。しかも、篩分処理の対象となる粒子は、上流側の間接加熱式乾燥装置にて予め乾燥処理されているため、付着水の影響を受けることなく粒度選別を行なうことができて、粒径に応じて分離されるそれぞれの成分の純度の向上化を図ることができる。又、篩分装置自体に、篩目の目詰まり等の機械的トラブルが生じる虞を回避することができる。
(7)乾燥装置と乾式比重選別機との間に、磁選機を設けるようにした構成とすることにより、乾燥装置にて予め乾燥処理されたスラグより、未燃分や未溶融ダストの如き異物を混入させることなく、スラグ粒子よりも比重の大きい金属粒子の如き磁性物を容易に分離して除去することができる。
(8)乾燥装置と乾式比重選別機からのダスト状の異物を回収するための集塵装置を設けた構成とすることにより、ダスト状の異物をも乾燥状態で回収することができると共に、上記ダスト状の異物が外部へ排出される虞を防止できる。
According to the present invention, the following excellent effects are exhibited.
(1) Granulated slag obtained by cooling the molten slag discharged from the melting furnace is dried with a drying device, and then the dried granulated slag is subjected to specific gravity sorting with a dry specific gravity sorter. Because it is a foreign matter removal method and device in slag that separates and removes foreign matter such as unburned matter and unmelted dust with a smaller specific gravity, the difference in specific gravity between foreign matter such as unburned matter and unmelted dust mixed in the slag is reduced. Therefore, the product slag from which such foreign matters are removed can be recovered. And since what is collect | recovered as said product slag is in a state with little moisture content, the handleability of the collect | recovered product slag can be improved and it can be made into the state which is easy to reuse.
(2) In addition, since foreign matters such as unburned matter and unmelted dust separated from the slag can be recovered in a dry state, handling properties can be improved and the processing can be easily performed. Therefore, even when the foreign matter is again subjected to combustion treatment or melting treatment, useless auxiliary fuel is not required.
(3) Furthermore, since the particles recovered as product slag can be easily purified as slag, the fluctuation of the granulated slag recovered from the melting furnace due to fluctuations in the operating condition of the melting furnace. Even if the slag property deteriorates, it can be recovered by applying the foreign matter removing method and apparatus in the slag of the present invention.
(4) Furthermore, since there is no need for washing water as conventionally required to remove foreign matters mixed in the granulated slag, it is possible to eliminate the need for providing a large-scale wastewater treatment facility. The equipment can be installed compactly in a small space.
(5) Even if unburned matter is mixed in the granulated slag, which is the subject of the drying treatment, by performing the drying treatment of the granulated slag with an indirect heating type drying device. The risk of burning the unburned component can be prevented beforehand. Furthermore, foreign matters such as unburned matter and unmelted dust mixed in the slag can be prevented from being scattered or dusted.
(6) A sieving device is provided between the drying device and the dry specific gravity sorter so that the dry granulated slag having a small particle size is guided to the dry specific gravity sorter. Since the particle sizes of the particles supplied to the specific gravity sorter can be made uniform to some extent, the dry specific gravity sorter can prevent the occurrence of poor sorting of slag and foreign matters. Moreover, since the particles to be subjected to the sieving treatment are previously dried in the upstream indirect heating type drying apparatus, the particle size can be selected without being affected by the adhering water, and the particle size can be reduced. Accordingly, the purity of each component separated can be improved. Further, it is possible to avoid the possibility that mechanical troubles such as clogging of the sieves occur in the sieving device itself.
(7) By adopting a configuration in which a magnetic separator is provided between the drying device and the dry specific gravity sorter, foreign matters such as unburned matter and unmelted dust from slag previously dried in the drying device. Without mixing, magnetic substances such as metal particles having a specific gravity larger than that of slag particles can be easily separated and removed.
(8) By providing a dust collector for collecting dust-like foreign matter from the drying device and the dry specific gravity sorter, dust-like foreign matter can also be collected in a dry state, and It is possible to prevent the possibility of dusty foreign matter being discharged to the outside.

以下、本発明を実施するための最良の形態を図面を参照して説明する。   The best mode for carrying out the present invention will be described below with reference to the drawings.

図1乃至図3は本発明のスラグ中の異物除去方法及び装置の実施の一形態を示すもので、基本的構成として、従来の水砕スラグ4と同様に、廃棄物の熱分解ガス化溶融処理設備における溶融炉、あるいは、廃棄物の直接燃焼により生じる炉下灰、飛灰等の溶融処理に用いる溶融炉等の溶融炉より排出される溶融スラグを水冷して生成させるようにしてある水砕スラグ22を受け入れて一旦貯留するための受入ホッパ23を設け、該受入ホッパ23の下流側に、間接加熱式乾燥装置24と乾式比重選別機25とを順に備えてなる構成とし、上記受入ホッパ23より供給される水砕スラグ22を、間接加熱式乾燥装置24にて乾燥処理した後、乾燥状態とされた水砕スラグ(乾燥スラグ)22aを、乾式比重選別機25へ供給して、水砕スラグ22と、該水砕スラグ22に混入している未燃分や未溶融ダストの如き異物26とを、乾燥状態の下で、両者の比重差に基づいて選別し、上記水砕スラグ22より異物26を分離、除去できるようにする。   FIG. 1 to FIG. 3 show an embodiment of the method and apparatus for removing foreign matter in slag of the present invention. As a basic configuration, similar to conventional granulated slag 4, pyrolysis gasification and melting of wastes. Water that is produced by water-cooling molten slag discharged from a melting furnace in a processing facility, or a melting furnace such as a melting furnace used for melting treatment of in-furnace ash, fly ash, etc. generated by direct combustion of waste A receiving hopper 23 for receiving and temporarily storing the crushed slag 22 is provided, and an indirect heating type drying device 24 and a dry specific gravity sorter 25 are sequentially provided on the downstream side of the receiving hopper 23, and the receiving hopper After the granulated slag 22 supplied from 23 is dried by the indirect heating type drying device 24, the granulated slag (dried slag) 22a in a dry state is supplied to the dry specific gravity sorter 25, Crushed slag 2 And foreign matter 26 such as unburned matter and unmelted dust mixed in the granulated slag 22 are selected based on the specific gravity difference between the two in a dry state. Can be separated and removed.

更に、上記乾式比重選別機25にて、大粒径の水砕スラグ22が、本来、水砕スラグ22より比重の小さい未燃分や未溶融ダストの如き異物26を選別して排出させるべきライトサイド側(軽量物側)へ転がる等して選別不良を生じるおそれが懸念される場合に、上記間接加熱式乾燥装置24と乾式比重選別機25との間に、間接加熱式乾燥装置24にて乾燥処理された後、乾式比重選別機25へ供給される乾燥スラグ22aより、上記のような選別不良が懸念される所要粒径よりも大きな粒径の粒子を予め分離して回収するための振動篩や円筒バースクリーン、トロンメル等の篩分装置27を設けるようにした構成とする。   Further, in the dry specific gravity sorter 25, the light granulated slag 22 having a large particle size should sort out and discharge foreign matter 26 such as unburned matter or unmelted dust which originally has a smaller specific gravity than the granulated slag 22. When there is a concern that a sorting failure may occur due to rolling to the side (lightweight object side) or the like, the indirect heating type drying device 24 is interposed between the indirect heating type drying device 24 and the dry specific gravity sorter 25. After drying, vibration for separating and recovering particles having a particle size larger than the required particle size, which is likely to cause sorting defects, from the dry slag 22a supplied to the dry specific gravity sorter 25 in advance. A sieving device 27 such as a sieve, a cylindrical bar screen, or a trommel is provided.

詳述すると、上記受入ホッパ23は、下端に定量切出装置(図示せず)を具備した構成としてあり、該定量切出装置の出口側に、上記間接加熱式乾燥装置24の投入口28を接続して、上記受入ホッパ23内の水砕スラグ22を、定量切出装置により上記間接加熱式乾燥装置24へ定量供給できるようにしてある。   More specifically, the receiving hopper 23 has a fixed amount cutting device (not shown) at the lower end, and the inlet 28 of the indirect heating type drying device 24 is provided on the outlet side of the fixed amount cutting device. By connecting, the granulated slag 22 in the receiving hopper 23 can be quantitatively supplied to the indirect heating type drying device 24 by a quantitative cutting device.

上記間接加熱式乾燥装置24は、たとえば、図2(イ)(ロ)に示す如く、長手方向の一端部上方に投入口28を備え、且つ他端側下部に排出口29を備えたトラフ形状の搬送路30を、投入口28側よりも排出口29側の方が低くなるよう所要角度傾斜させて配置すると共に、該搬送路30に図示しない振動装置を取り付け、更に、上記搬送路30の底面に、熱媒体を流通させるための熱媒通路31を埋設するか、あるいは、該熱媒通路31を、上記搬送路30の下面側に取り付けてなる構成とする。これにより、上記振動装置により搬送路30を振動させると共に、上記熱媒通路31に、熱媒体として、たとえば、170℃程度の低圧蒸気32を流通させた状態にて、上記受入ホッパ23の定量切出装置により切り出される水砕スラグ22を、上記投入口28を経て搬送路30の長手方向一端部へ投入させることにより、20%程度の水分を含んだ状態となっている水砕スラグ22を、振動する搬送路30上にて排出口29まで搬送する間に、上記熱媒通路31を流通させる低圧蒸気32により搬送路30の底面を介し間接加熱し、水分量が10%以下程度となるまで乾燥させて、乾燥スラグ22aとして排出口29より回収することができるようにしてある。なお、上記水砕スラグ22を乾燥処理する際、受入ホッパ23より投入される水砕スラグ22に異物として未燃分が混入している場合であっても、上記したように、乾燥処理は間接加熱方式で行うようにしてあるため、上記未燃分が燃焼するような虞を未然に防止することができるようになる。又、水砕スラグ22に混入している未燃分や未溶融ダストの如き異物26が飛散したり、粉塵化する虞も未然に防止できるようになる。上記のように乾燥処理された後に取り出される乾燥スラグ22aの温度が高く、異物として混入している未燃分の発火が懸念される場合には、上記間接加熱式乾燥装置24の排出口29の直後に図示していないが冷却装置を設けるようにすればよい。この冷却装置としては、乾式の直接冷却方式あるいは間接冷却方式のいずれのものでもよく、又、いかなる形式のものを採用してもよい。   For example, as shown in FIGS. 2 (a) and 2 (b), the indirect heating type drying device 24 has a trough shape having an input port 28 above one end in the longitudinal direction and a discharge port 29 at the lower end on the other end side. The transport path 30 is inclined at a required angle so that the discharge port 29 side is lower than the input port 28 side, and a vibration device (not shown) is attached to the transport path 30. A heat medium passage 31 for circulating the heat medium is embedded in the bottom surface, or the heat medium passage 31 is attached to the lower surface side of the transport path 30. As a result, the conveying path 30 is vibrated by the vibration device, and the receiving hopper 23 is fixedly cut in a state where, for example, low-pressure steam 32 of about 170 ° C. is circulated through the heat medium passage 31 as the heat medium. By introducing the granulated slag 22 cut out by the dispensing device into one end in the longitudinal direction of the conveyance path 30 through the inlet 28, the granulated slag 22 that contains about 20% moisture is obtained. While being conveyed to the discharge port 29 on the conveying path 30 that vibrates, it is indirectly heated through the bottom surface of the conveying path 30 by the low-pressure steam 32 that circulates the heating medium path 31 until the water content becomes about 10% or less. It is made to dry and can collect | recover from the discharge port 29 as the dry slag 22a. Note that when the granulated slag 22 is dried, even if unburned matter is mixed as foreign matter in the granulated slag 22 introduced from the receiving hopper 23, the drying process is indirectly performed as described above. Since the heating method is employed, it is possible to prevent the possibility that the unburned portion will burn. Further, it is possible to prevent the possibility that foreign matter 26 such as unburned matter and unmelted dust mixed in the granulated slag 22 is scattered or dusted. When the temperature of the dry slag 22a taken out after the drying process as described above is high and there is a concern about the ignition of the unburned portion mixed as a foreign matter, the outlet 29 of the indirect heating type drying device 24 A cooling device may be provided although not shown immediately after. This cooling device may be either a dry direct cooling method or an indirect cooling method, or any type of cooling device may be employed.

本実施の形態では、図1に示す如く、上記間接加熱式乾燥装置24の排出口29側の端部に、乾燥処理後の乾燥スラグ22aに含まれている粒子を所定粒径、たとえば、粒径30mm以上と30mm未満の粒子に分離するための篩33を、一体に設けた構成としてある。これは、通常、水砕スラグ22は30mm未満の粒径となることから、粒径30mm以上の粒子を、水砕スラグ22に混入している金属類やその他の異物34として分離して、篩上物出口33aより取り出すことができるようにするためである。   In the present embodiment, as shown in FIG. 1, the particles contained in the dried slag 22a after the drying treatment are disposed at the end on the discharge port 29 side of the indirect heating type drying device 24 at a predetermined particle size, for example, The sieve 33 for separating particles having a diameter of 30 mm or more and less than 30 mm is integrally provided. This is because the granulated slag 22 usually has a particle size of less than 30 mm, so that particles having a particle size of 30 mm or more are separated as metals and other foreign matters 34 mixed in the granulated slag 22 and sieved. This is because it can be taken out from the upper product outlet 33a.

上記篩33の篩下物出口33bには、バッファ35、定量切出装置36、磁選機37を順に接続して、上記篩33にて粒径30mm未満の粒子として回収される篩下物22bを、バッファ35に受け入れて一旦貯留した後、定量切出装置36により磁選機37へ定量供給し、該磁選機37にて磁性物38を分離して、該磁選機37の磁性物出口37aより取り出して回収できるようにする。   A buffer 35, a quantitative cutting device 36, and a magnetic separator 37 are connected in order to the under sieve outlet 33b of the sieve 33, and the under sieve 22b recovered as particles having a particle diameter of less than 30 mm by the sieve 33 is obtained. Then, after being received in the buffer 35 and temporarily stored, it is supplied quantitatively to the magnetic separator 37 by the quantitative cutting device 36, the magnetic material 38 is separated by the magnetic separator 37, and taken out from the magnetic material outlet 37 a of the magnetic separator 37. So that it can be recovered.

上記磁選機37の非磁性物出口37bには、スラグ切出装置39と、上記したように、間接加熱式乾燥装置24にて乾燥処理された後、乾式比重選別機25へ供給させる乾燥スラグ22aより、選別不良が懸念される所要粒径よりも大きな粒径の粒子、たとえば、粒径10mm以上の粒子を分離して回収するための篩分装置27とを順に接続して、上記磁選機37より非磁性物として排出されるスラグ粒子22cを、スラグ切出装置39により上記篩分装置27へ供給できるようにする。   The non-magnetic material outlet 37b of the magnetic separator 37 has a slag cutting device 39 and a dry slag 22a that is supplied to the dry specific gravity separator 25 after being dried by the indirect heating type drying device 24 as described above. Thus, the magnetic separator 37 is connected in order with a sieving device 27 for separating and collecting particles having a particle size larger than the required particle size for which poor sorting is a concern, for example, particles having a particle size of 10 mm or more. The slag particles 22c discharged more as non-magnetic materials can be supplied to the sieving device 27 by the slag cutting device 39.

上記篩分装置27の篩上物出口27aは、製品スラグ回収部40に接続して、粒径10mm以上の粒子として分離される篩上物22dを、製品スラグとして回収できるようにする。一方、上記篩分装置27の篩下物出口27bは、上記乾式比重選別機25の投入口41に接続して、上記篩分装置27にて粒径が10mm未満に揃えられた状態で回収される篩下物22eを、乾式比重選別機25へ供給できるようにする。なお、上記篩分装置27における篩分処理の対象となる上記スラグ粒子22cは、予め乾燥状態とされているため、たとえ、供給されるスラグ粒子22cに、未燃分や未溶融ダストの如き異物26が付着していたとしても、該異物26は篩分処理される上記スラグ粒子22cより容易に脱離させられるようになる。このために、上記異物26が上記粒径10mm以上の篩上物22dとして分けられたものに同伴されて製品スラグ回収部40へ回収されてしまう虞を防止できる。   The sieve top outlet 27a of the sieving device 27 is connected to the product slag collection part 40 so that the sieve top 22d separated as particles having a particle size of 10 mm or more can be collected as product slag. On the other hand, the sieving device outlet 27b of the sieving device 27 is connected to the input port 41 of the dry specific gravity sorter 25, and is recovered in a state where the particle size is less than 10 mm by the sieving device 27. The under-sieving material 22e can be supplied to the dry specific gravity sorter 25. In addition, since the slag particles 22c to be subjected to the sieving process in the sieving device 27 are in a dry state in advance, even if foreign matter such as unburned matter or unmelted dust is added to the supplied slag particles 22c. Even if 26 adheres, the foreign matter 26 can be easily detached from the slag particles 22c to be sieved. For this reason, it is possible to prevent the foreign matter 26 from being collected in the product slag collection unit 40 by being accompanied by the sieving material 22d having a particle diameter of 10 mm or more.

上記乾式比重選別機25は、たとえば、図3に示す如く、長手方向一端部に投入口41を備え、且つ他端側を排出口42としたトラフ形状とすると共に、搬送面となる底面を、織線、パンチ穴を備えた板状材、あるいは、布製構造として、該搬送面より上向きにエアー46を噴き出すことができるようにしてあるポーラスデッキ43を、投入口41側よりも排出口42側の方が低くなるよう長手方向に所要角度傾斜したサイドスロープ44と、上記排出口42の幅方向一端側が幅方向他端側よりも低くなるよう幅方向に所要角度傾斜したエンドスロープ45が形成されるように配置する。更に、該ポーラスデッキ43を、図中矢印xで示される幅方向に振動させるための図示しない振動装置を備えてなる構成としてある。これにより、上記ポーラスデッキ43を振動させると共に、該ポーラスデッキ43の搬送面よりエアー46を噴き出させて該搬送面の上側にエアー46による所要速度の上昇流を形成させた状態にて、上記篩分装置27より回収される篩下物22eを、上記ポーラスデッキ43の投入口41より投入すると、該投入された篩下物22eに含まれる各粒子は、その比重に応じて上記エアー46の上昇流の中で層状化され、比重の大きい粒子は下部に、又、比重の小さい粒子は上部に層をなすようになる。このために、上記篩下物22e中に含まれている比重が大きいスラグ粒子22fは、エアー46の上昇流の中にて、下層に位置させられるようになることから、搬送面であるポーラスデッキ43の底面と接触させられて、該ポーラスデッキ43の幅方向の振動の影響を強く受け、これにより、ポーラスデッキ43上を投入口41側より排出口42側へ搬送される間に、エンドスロープ45によって幅方向に傾斜している該ポーラスデッキ43の搬送面を、高所側へ上るよう移動させられて、排出口42の上部側に形成されるヘビーサイド出口42aより排出されるようになる。一方、上記篩分装置27の篩下物22e中に混入されている未燃分や未溶融ダストの如き比重の軽い異物26は、上記エアー46の上昇流の中では、該上昇流に乗せられて上記比重の大きいスラグ粒子22fより分離されて上層に位置させられるようになる。したがって、ポーラスデッキ43の搬送面との接触度が低く、該ポーラスデッキ43の幅方向の振動の影響が弱いことから、上記未燃分や未溶融ダストの如き比重の軽い異物26は、ポーラスデッキ43の傾斜にしたがって搬送されて、エンドスロープ45により幅方向に傾斜している排出口42の下部側に形成されるライトサイド出口42bより排出されるようになる。   For example, as shown in FIG. 3, the dry specific gravity sorter 25 has a trough shape having an inlet 41 at one end in the longitudinal direction and an outlet 42 at the other end, and a bottom surface serving as a conveying surface. As a plate-like material having a woven wire or a punched hole, or a cloth structure, a porous deck 43 that is capable of ejecting air 46 upward from the conveying surface is provided on the outlet 42 side rather than the inlet 41 side. A side slope 44 inclined at a required angle in the longitudinal direction so as to be lower and an end slope 45 inclined at a required angle in the width direction so that one end in the width direction of the discharge port 42 is lower than the other end in the width direction are formed. Arrange so that. Further, the porous deck 43 is provided with a vibration device (not shown) for vibrating in the width direction indicated by an arrow x in the drawing. As a result, the porous deck 43 is vibrated and air 46 is blown out from the conveying surface of the porous deck 43 to form an upward flow at a required speed by the air 46 above the conveying surface. When the sieving material 22e recovered from the sieving device 27 is introduced from the charging port 41 of the porous deck 43, each particle contained in the sieving material 22e that has been introduced is in accordance with the specific gravity of the air 46. Layered in the upward flow, particles with high specific gravity will be layered at the bottom and particles with low specific gravity will be layered at the top. For this reason, the slag particles 22f having a large specific gravity contained in the under sieve 22e are positioned in the lower layer in the upward flow of the air 46, so that the porous deck which is the transport surface 43 is brought into contact with the bottom surface of 43, and is strongly affected by the vibration in the width direction of the porous deck 43, so that the end slope is conveyed while being transported on the porous deck 43 from the inlet 41 side to the outlet 42 side. The transport surface of the porous deck 43 inclined in the width direction by 45 is moved so as to rise to the high place side, and discharged from a heavy side outlet 42a formed on the upper side of the discharge port 42. . On the other hand, the foreign matter 26 having a light specific gravity such as unburned matter or unmelted dust mixed in the under sieve 22e of the sieving device 27 is put on the upward flow in the upward flow of the air 46. Thus, the slag particles 22f having a large specific gravity are separated from the slag particles 22f and positioned in the upper layer. Accordingly, since the degree of contact with the conveying surface of the porous deck 43 is low and the influence of vibration in the width direction of the porous deck 43 is weak, the foreign matter 26 having a low specific gravity such as unburned matter or unmelted dust is It is conveyed according to the inclination of 43 and discharged from the light side outlet 42b formed on the lower side of the outlet 42 inclined in the width direction by the end slope 45.

したがって、上記乾式比重選別機25におけるヘビーサイド出口42aは、上記製品スラグ回収部40に接続して、上記比重の軽い未燃分や未溶融ダストの如き異物26が分離除去されたスラグ粒子22fを、製品スラグとして回収できるようにする。一方、上記ライトサイド出口42bは、異物回収部47に接続して、上記スラグ粒子22fより比重選別されて分離される未燃分や未溶融ダストの如き異物26を回収するようにしてある。なお、図3では、上記ポーラスデッキ43の上方を覆う天井部の記載は省略してある。   Therefore, the heavy side outlet 42a in the dry specific gravity sorter 25 is connected to the product slag collecting section 40 to remove the slag particles 22f from which the foreign matter 26 such as unburned matter and unmelted dust having a low specific gravity is separated and removed. To be collected as product slag. On the other hand, the light side outlet 42b is connected to the foreign matter collecting part 47 so as to collect the foreign matter 26 such as unburned matter and unmelted dust separated and separated by specific gravity from the slag particles 22f. In FIG. 3, the description of the ceiling portion that covers the top of the porous deck 43 is omitted.

更に、上記乾式比重選別機25では、スラグ粒子22fと、異物26との分離を行う際、混入している未燃分や未溶融ダストの如き異物26のうち、粒径が小さく、重量が軽いダスト状のものは、上記ポーラスデッキ43の底面より噴き出させるエアー46の上昇流に同伴される虞がある。そのために、上記乾式比重選別機25の空気出口48には、バグフィルタの如き集塵装置49を接続して、上記乾式比重選別機25にてスラグ粒子22fと異物26との比重選別に供された後のエアー46に同伴されるダスト状の異物26aは、上記集塵装置49にて回収して、外部へ排出される虞が生じないようにしてある。なお、上記集塵装置49にて回収されるダスト状の異物26aは、乾式比重選別機25にてスラグ粒子22fより分離される異物26と同様に、上記異物回収部47へ回収するようにすればよい。   Further, in the dry specific gravity sorter 25, when separating the slag particles 22f from the foreign matter 26, the particle size is small and the weight is light among the foreign matters 26 such as unburned matter and unmelted dust that are mixed. There is a possibility that the dust-like thing will be accompanied by the upward flow of air 46 ejected from the bottom surface of the porous deck 43. For this purpose, a dust collector 49 such as a bag filter is connected to the air outlet 48 of the dry specific gravity sorter 25, and the dry specific gravity sorter 25 is used for specific gravity sorting of the slag particles 22f and the foreign matter 26. The dust-like foreign matter 26a accompanying the air 46 after that is collected by the dust collecting device 49 so as not to be discharged to the outside. The dust-like foreign matter 26a collected by the dust collector 49 is collected by the foreign matter collecting unit 47 in the same manner as the foreign matter 26 separated from the slag particles 22f by the dry specific gravity sorter 25. That's fine.

又、上記間接加熱式乾燥装置24では、水砕スラグ22の乾燥に伴って水蒸気が発生するため、該水蒸気を外部に排出させる必要があるが、この際、上記水砕スラグ22に混入している未燃分や未溶融ダストの如き異物26のうち、比重の軽いダスト状の異物26aが、水蒸気の流れに同伴されて排出される虞がある。そのため、上記間接加熱式乾燥装置24における水蒸気出口50には、ヒータ52と、バグフィルタの如き集塵装置51とを順に接続して、上記水蒸気出口50より排出される水蒸気の如き気体を、上記ヒータ52にて、下流側の集塵装置51の内部で結露が発生しないように予め所要温度まで加熱してから、上記集塵装置51に通すことで、上記水蒸気出口50より排出される気体に、上記ダスト状の異物26aが同伴されたとしても、該ダスト状の異物26aを回収することができるようにしてある。なお、上記集塵装置51で回収されたダスト状の異物26aは、上記乾式比重選別機25に付設した集塵装置49から回収される異物26aと同様に、異物回収部47へ回収するようにすればよい。   Moreover, in the indirect heating type drying device 24, since water vapor is generated as the granulated slag 22 is dried, it is necessary to discharge the water vapor to the outside. Among the foreign matter 26 such as unburned matter and unmelted dust, the dust-like foreign matter 26a having a low specific gravity may be discharged along with the flow of water vapor. Therefore, a heater 52 and a dust collector 51 such as a bag filter are connected in order to the water vapor outlet 50 in the indirect heating type drying device 24 so that a gas such as water vapor discharged from the water vapor outlet 50 The heater 52 is heated in advance to a required temperature so that condensation does not occur inside the dust collector 51 on the downstream side, and is then passed through the dust collector 51 so that the gas discharged from the water vapor outlet 50 Even if the dusty foreign matter 26a is accompanied, the dusty foreign matter 26a can be recovered. The dust-like foreign matter 26a collected by the dust collecting device 51 is collected by the foreign matter collecting unit 47 in the same manner as the foreign matter 26a collected from the dust collecting device 49 attached to the dry specific gravity sorter 25. do it.

以上の構成としてあることにより、本発明のスラグ中の異物除去装置を用いて水砕スラグ22に混入した異物を除去する場合は、先ず、受入ホッパ23に貯留されている水砕スラグ22を、定量切出装置により間接加熱式乾燥装置24へ供給して乾燥させる。この乾燥は、間接加熱により行うようにしてあるため、上記水砕スラグ22に異物26として未燃分が含まれている場合であっても該未燃分が燃焼する虞はない。   When the foreign matter mixed in the granulated slag 22 is removed by using the foreign matter removing device in the slag of the present invention, the granulated slag 22 stored in the receiving hopper 23 is first used. It supplies to the indirect heating type drying apparatus 24 with a fixed quantity cutting device, and it dries. Since this drying is performed by indirect heating, there is no possibility that the unburned matter will burn even if the granulated slag 22 contains unburned matter as foreign matter 26.

次に、上記乾燥処理された乾燥スラグ22aを、篩33に供給して、粒径30mm以上の篩上物33aとして金属類や異物34を分離除去する。次いで、上記篩33より篩下物22bとして回収されるものを、磁選機37にて磁性物38を除去した後、篩分装置27へ供給して、後工程となる乾式比重選別機25における選別工程にて選別不良が懸念される粒径10mm以上の粒子を、篩上物22dとして予め製品スラグ回収部40へ回収するようにする。   Next, the dried slag 22a subjected to the drying process is supplied to the sieve 33, and the metals and foreign matter 34 are separated and removed as the sieve top 33a having a particle diameter of 30 mm or more. Next, after the magnetic material 38 is removed by the magnetic separator 37 after being recovered as the under sieve 22b from the sieve 33, the magnetic material 38 is supplied to the sieving device 27 for selection in the dry specific gravity separator 25 as a subsequent process. Particles having a particle size of 10 mm or more that are likely to be poorly sorted in the process are collected in advance in the product slag collection unit 40 as the sieve top 22d.

その後、上記篩分装置27の篩下物22eを、乾式比重選別機25へ供給して、スラグ粒子22fと、混入していた未燃分や未溶融ダストの如き異物26を、両者の比重差に基づいて乾式で分離して、上記スラグ粒子22fは製品スラグ回収部40へ、又、上記異物26は異物回収部47へそれぞれ回収するようにする。   Thereafter, the sieving material 22e of the sieving device 27 is supplied to the dry specific gravity sorter 25, and the slag particles 22f and the foreign matter 26 such as unburned matter and unmelted dust mixed therein are compared with each other in specific gravity difference. The slag particles 22f are collected in the product slag collection unit 40, and the foreign material 26 is collected in the foreign material collection unit 47.

上記間接加熱式乾燥装置24における乾燥工程で水蒸気の流れに同伴されるダスト状の異物26aや、乾式比重選別機25における比重選別工程でスラグ粒子22fと異物26との比重選別に供された後のエアー46に同伴されるダスト状の異物26aは、各々対応する集塵装置49や51で回収して上記異物26と共に、異物回収部47へ回収するようにする。   After being used for the specific gravity sorting of the slag particles 22f and the foreign matter 26 in the specific gravity sorting process in the dry specific gravity sorter 25 in the dust-like foreign material 26a accompanying the flow of water vapor in the drying process in the indirect heating type drying device 24. The dust-like foreign matter 26 a accompanying the air 46 is collected by the corresponding dust collectors 49 and 51 and collected together with the foreign matter 26 to the foreign matter collecting unit 47.

このように、本発明のスラグ中の異物除去方法及び装置によれば、廃棄物や灰を溶融炉にて溶融処理した溶融スラグを水冷してなる水冷スラグ22より、混入した未燃分や未溶融ダストの如き異物26,26aを容易に分離除去することができて、篩分装置27の篩上物22dや、乾式比重選別機25より回収されるスラグ粒子22fを、製品スラグとして回収することができる。しかも、上記製品スラグとして回収されるもの、すなわち、上記篩分装置27の篩上物22dや、乾式比重選別機25より回収されるスラグ粒子22fは、いずれも含水率が少ない乾燥状態となっているため、ハンドリング性を向上させることができて、再利用し易い状態で回収することができる。   As described above, according to the foreign matter removal method and apparatus in the slag of the present invention, the mixed unburned matter and unburned matter are obtained from the water-cooled slag 22 obtained by water-cooling the molten slag obtained by melting waste and ash in the melting furnace. Foreign matter 26, 26a such as molten dust can be easily separated and removed, and the slag particles 22f collected from the sieve device 27d of the sieving device 27 and the dry specific gravity sorter 25 are collected as product slag. Can do. And what is collect | recovered as the said product slag, ie, the slag particle | grains 22f collect | recovered from the sieve top material 22d of the said sieving apparatus 27, and the dry-type specific gravity sorter 25, becomes a dry state with little moisture content. Therefore, handling property can be improved and it can collect | recover in the state which is easy to reuse.

又、上記製品スラグより分離させる未燃分や未溶融ダストの如き異物26,26aも、乾燥状態で回収できるため、ハンドリング性を向上させることができて、その処理を容易に行なうことができる。上記異物26,26aを再び燃焼処理や溶融処理する場合であっても、無駄な助燃料を必要とすることはない。   In addition, since foreign matter 26 and 26a such as unburned matter and unmelted dust separated from the product slag can be recovered in a dry state, handling property can be improved and the processing can be easily performed. Even when the foreign substances 26 and 26a are subjected to the combustion process or the melting process again, useless auxiliary fuel is not required.

更に、製品スラグとして回収される粒子のスラグとしての高純度化を容易に図ることができるため、溶融炉の運転状態の変動により、該溶融炉より回収される水砕スラグのスラグ性状が悪化したとしても、本発明の方法及び装置を適用することによりリカバーすることが可能になる。   Furthermore, since it is possible to easily purify the particles recovered as product slag as slag, the slag properties of the granulated slag recovered from the melting furnace deteriorated due to fluctuations in the operating condition of the melting furnace. However, it is possible to recover by applying the method and apparatus of the present invention.

更に又、本発明によれば、従来要していた如きスラグの洗浄水を必要としないため、大規模な排水処理設備等を設ける必要をなくすことができ、したがって、設備を小スペースにコンパクトに設置することが可能になる。   Furthermore, according to the present invention, it is not necessary to provide slag washing water as conventionally required, so that it is not necessary to provide a large-scale wastewater treatment facility, etc. Therefore, the facility can be made compact in a small space. It becomes possible to install.

上記した篩33及び篩分装置27は、いずれも間接加熱式乾燥装置24の下流側に設けるようにしてあることから、水砕スラグ22の付着水の影響を受けることなく粒度選別を行なうことができて、粒径に応じて分離されるそれぞれの成分の純度の向上化を図ることができると共に、篩目の目詰まり等の機械的トラブルが生じる虞を回避することが可能となる。   Since both the sieve 33 and the sieving device 27 are provided on the downstream side of the indirect heating type drying device 24, the particle size selection can be performed without being affected by the water adhering to the granulated slag 22. In addition, the purity of each component separated according to the particle size can be improved, and the possibility of mechanical troubles such as clogging of the meshes can be avoided.

同様に、上記磁選機37も間接加熱式乾燥装置37の下流側に設けるようにしてあるため、未燃分や未溶融ダストの如き異物26を混入させることなく、磁性物38を容易に分離して除去することができる。   Similarly, since the magnetic separator 37 is also provided on the downstream side of the indirect heating type drying device 37, the magnetic material 38 can be easily separated without mixing foreign matter 26 such as unburned matter or unmelted dust. Can be removed.

なお、本発明は上記実施の形態のみに限定されるものではなく、以下に述べるようにしたものも含むものである。たとえば、本発明の間接加熱式乾燥装置24は、長手方向に傾斜配置すると共に、振動装置により振動できるようにしてある搬送路30の底面部に設けた熱媒通路31に、熱媒体としての低圧蒸気32を流通させるものとして示したが、供給される水砕スラグ22を間接的に所要温度まで加熱して含まれる水分量を10%以下程度まで低減させることができれば、上記熱媒通路31に流通させる熱媒体として低圧蒸気32以外の熱媒体を流通させるようにしたり、熱源として電気ヒータを用いる等、いかなる形式のものを採用してもよい。又、上下流方向に2段式の乾燥装置とする等、図2に示した以外の形状のものを採用してもよい。更に、上記間接加熱式乾燥装置24は、排出口29側端部に、篩33を一体に設けてなるものとして示したが、該篩33は別体としてもよい。更には、灰溶融炉より排出されるスラグ等、未燃分を含まない水砕スラグを処理対象とする場合には、上記間接加熱式乾燥装置24に代えて直接加熱式の乾燥装置を用いて乾燥処理を行うようにしてもよい。乾式比重選別機25は、振動式のものを例示したが、水砕スラグ22の粒子と、該水砕スラグ22に混入している未燃分や未溶融ダストの如き異物26とを、比重差に基づいて選別できれば、風力選別式等、いかなる形式、形状のものを採用してもよい。混入しているダストの除去処理を行うべき水砕スラグ22の粒度分布範囲が、乾式比重選別機25にて選別不良を生じることなく比重選別できる許容範囲にすべて収まる場合には、篩分装置27を省略するようにしてもよい。乾式比重選別機25の空気出口48と、間接加熱式乾燥装置24の水蒸気出口50の下流側に、個別に集塵装置49、51を接続するものとして示したが、共通の一つの集塵装置に接続するようにしてもよい。廃棄物や灰を溶融するいかなる形式の溶融炉より排出されるスラグの処理にも適用できること、その他本発明の要旨を逸脱しない範囲内において種々変更を加え得ることは勿論である。   In addition, this invention is not limited only to the said embodiment, The thing as described below is also included. For example, the indirect heating type drying device 24 of the present invention is arranged in a slanting manner in the longitudinal direction, and a low pressure as a heat medium is provided in the heat medium passage 31 provided on the bottom surface of the conveyance path 30 that can be vibrated by a vibration device. Although the steam 32 was shown to circulate, if the amount of water contained can be reduced to about 10% or less by indirectly heating the supplied granulated slag 22 to the required temperature, the heating medium passage 31 can be used. A heat medium other than the low-pressure steam 32 may be circulated as a heat medium to be circulated, or an electric heater may be used as the heat source. Further, a shape other than that shown in FIG. 2, such as a two-stage drying device in the upstream and downstream directions, may be employed. Further, although the indirect heating type drying device 24 is shown as having the sieve 33 integrally provided at the end of the discharge port 29, the sieve 33 may be a separate body. Furthermore, when granulated slag that does not contain unburned components, such as slag discharged from an ash melting furnace, is used as a treatment target, a direct heating type drying device is used instead of the indirect heating type drying device 24. You may make it perform a drying process. The dry specific gravity sorter 25 is exemplified by a vibration type, but the specific gravity difference between the particles of the granulated slag 22 and the foreign matter 26 such as unburned matter and unmelted dust mixed in the granulated slag 22 is obtained. As long as it can be sorted based on the above, any type or shape such as a wind sorting type may be adopted. In the case where the particle size distribution range of the granulated slag 22 to be subjected to the removal process of the mixed dust falls within the allowable range in which the specific gravity can be sorted without causing the sorting failure in the dry specific gravity sorter 25, the sieving device 27 May be omitted. Although the dust collectors 49 and 51 are individually connected to the downstream side of the air outlet 48 of the dry specific gravity sorter 25 and the water vapor outlet 50 of the indirect heating type dryer 24, one common dust collector is shown. You may make it connect to. Needless to say, the present invention can be applied to the treatment of slag discharged from any type of melting furnace for melting waste and ash, and various modifications can be made without departing from the scope of the present invention.

本発明のスラグ中の異物除去方法及び装置の実施の一形態を示す概要図である。It is the schematic which shows one Embodiment of the foreign material removal method and apparatus in the slag of this invention. 図1に示す間接加熱式乾燥装置の一例を示すもので、(イ)は概略側面図、(ロ)は(イ)のA−A方向矢視図である。An example of the indirect heating type drying apparatus shown in FIG. 1 is shown, (A) is a schematic side view, (B) is an AA direction arrow view of (A). 図1に示す乾式比重選別機の一例を示す概略斜視図である。It is a schematic perspective view which shows an example of the dry-type specific gravity sorter shown in FIG. 水砕スラグに混入されている未燃分や未溶融ダストの如き異物を除去するために従来提案されている装置の一例を示す概要図である。It is a schematic diagram which shows an example of the apparatus conventionally proposed in order to remove foreign materials, such as the unburned content and unmelted dust which are mixed in the granulated slag. 水砕スラグに混入されている未燃分や未溶融ダストの如き異物を除去するために従来提案されている装置の他の例を示す概要図である。It is a schematic diagram which shows the other example of the apparatus conventionally proposed in order to remove foreign materials, such as the unburned content and unmelted dust which are mixed in the granulated slag. 廃棄物溶融スラグに混入している金属を比重分離して除去するために従来提案されている装置を示す概要図である。It is a schematic diagram which shows the apparatus conventionally proposed in order to isolate | separate and remove the metal mixed in waste molten slag by specific gravity.

符号の説明Explanation of symbols

22 水砕スラグ
22a 乾燥スラグ
22b 篩下物
22c スラグ粒子
22d 篩上物
22e 篩下物
22f スラグ粒子
23 受入ホッパ
24 間接加熱式乾燥装置(乾燥装置)
25 乾式比重選別機
26,26a 異物
27 篩分装置
37 磁選機
49 集塵装置
51 集塵装置
22 Granulated slag 22a Dry slag 22b Under sieve 22c Slag particles 22d Over sieve 22e Under sieve 22f Slag particles 23 Receiving hopper 24 Indirect heating type drying equipment (drying equipment)
25 Dry specific gravity sorter 26, 26a Foreign matter 27 Sieving device 37 Magnetic separator 49 Dust collector 51 Dust collector

Claims (7)

溶融炉より排出される溶融スラグを水冷してなる水砕スラグを、乾燥処理した後、該乾燥した水砕スラグを乾式で比重選別処理して、スラグより比重の小さい未燃分や未溶融ダストの如き異物を分離除去することを特徴とするスラグ中の異物除去方法。   After the granulated slag formed by water-cooling the molten slag discharged from the melting furnace is dried, the dried granulated slag is subjected to a specific gravity selection process by a dry method, and unburned matter and unmelted dust having a specific gravity smaller than that of the slag. A method for removing foreign matter in a slag, wherein the foreign matter is separated and removed. 乾燥処理を間接加熱方式で行うようにする請求項1記載のスラグ中の異物除去方法。   The method for removing foreign matter in slag according to claim 1, wherein the drying process is performed by an indirect heating method. 溶融炉より排出される溶融スラグを水冷してなる水砕スラグを受け入れるための受入ホッパの下流側に、乾燥装置と乾式比重選別機とを順に備えてなり、乾燥した水砕スラグを乾式比重選別機でスラグ粒子と異物に分離するようにした構成を有することを特徴とするスラグ中の異物除去装置。   In the downstream of the receiving hopper for receiving granulated slag obtained by cooling the molten slag discharged from the melting furnace, a drying device and a dry specific gravity sorter are provided in order, and the dry granulated slag is sorted by dry specific gravity. An apparatus for removing foreign matter in slag, characterized by having a configuration in which the slag particles and foreign matter are separated by a machine. 乾燥装置を、間接加熱式の乾燥装置とした請求項3記載のスラグ中の異物除去装置。   The apparatus for removing foreign matter in slag according to claim 3, wherein the drying apparatus is an indirect heating type drying apparatus. 乾燥装置と乾式比重選別機との間に、篩分装置を設けて、乾燥した水砕スラグの粒径の小さいものを乾式比重選別機へ導くようにした請求項3又は4記載のスラグ中の異物除去装置。   The slag in the slag according to claim 3 or 4, wherein a sieving device is provided between the drying device and the dry specific gravity sorter so that the dried granulated slag having a small particle size is led to the dry specific gravity sorter. Foreign matter removal device. 乾燥装置と乾式比重選別機との間に、磁選機を設けるようにした請求項3、4又は5記載のスラグ中の異物除去装置。   The apparatus for removing foreign matter in slag according to claim 3, 4 or 5, wherein a magnetic separator is provided between the drying device and the dry specific gravity sorter. 乾燥装置と乾式比重選別機からのダスト状の異物を回収するための集塵装置を設けた請求項3、4、5又は6記載のスラグ中の異物除去装置。   The apparatus for removing foreign matter in slag according to claim 3, 4, 5, or 6, further comprising a dust collecting device for collecting dust-like foreign matter from the drying device and the dry specific gravity sorter.
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