JP2006035009A - Ozone water making apparatus, ozone mist producer and ozone gas making apparatus - Google Patents

Ozone water making apparatus, ozone mist producer and ozone gas making apparatus Download PDF

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JP2006035009A
JP2006035009A JP2004214065A JP2004214065A JP2006035009A JP 2006035009 A JP2006035009 A JP 2006035009A JP 2004214065 A JP2004214065 A JP 2004214065A JP 2004214065 A JP2004214065 A JP 2004214065A JP 2006035009 A JP2006035009 A JP 2006035009A
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ozone
water
liquid feeding
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JP4710270B2 (en
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Kazuyuki Hamada
和幸 濱田
Kahoru Tsujimoto
かほる 辻本
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Panasonic Holdings Corp
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Matsushita Electric Industrial Co Ltd
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  • Water Treatment By Electricity Or Magnetism (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a ozone water, ozone mist or ozone gas making apparatus for stably making ozone water, ozone mist or an ozone gas of low concentration safe to the human body and reduced in ozone smell by a simple structure. <P>SOLUTION: The ozone water ozone mist or ozone gas making apparatus has a water tank 210 for storing water, a ozone producing part 230 arranged in the vicinity of the water tank 210 and a liquid feed means 220 for feeding the water in the water tank 210 outside of the water tank 210 using capillary action. Since the ozone producing part 230 is formed in the water tank 220, the ozone water, the ozone mist or the ozone gas of low concentration safe to the human body and reduced in ozone smell can be made and can be used for removing bacteria, an offensive smell and a harmful substance while ensuring the safety to the human body. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明はオゾン水、オゾンミスト、オゾンガスを除菌、脱臭、有害物質除去に利用したオゾン水の生成装置とオゾンミストの生成装置とオゾンガスの生成装置に関するものがある。   The present invention relates to a device for generating ozone water, a device for generating ozone mist, and a device for generating ozone gas that use ozone water, ozone mist, and ozone gas for sterilization, deodorization, and removal of harmful substances.

従来、この種のオゾン水の生成装置は、放電方式または、紫外線方式のオゾン発生体により、空気中の酸素を分解して生成したオゾンガスを水に混合して、オゾン水を生成しているものである(例えば、特許文献1参照)。また、電解槽中の貯留水を電気分解してオゾン水を生成しているものである。   Conventionally, this type of ozone water generator is a device that generates ozone water by mixing ozone gas generated by decomposing oxygen in the air with water using a discharge type or ultraviolet type ozone generator. (For example, see Patent Document 1). In addition, ozone water is generated by electrolyzing the stored water in the electrolytic cell.

図6は特許文献1に記載された従来のオゾン水の生成装置を示すものである。図6に示すように、沿面放電型のセラミックオゾナイザー(図示せず)を用いたオゾン発生部2と、オゾン水をつくるオゾン溶解部5と原料水を取入れる原料水入口部10とオゾン水出口部11と前記原料水入り口部10とオゾン水出口部11を連通する原料水導入管18とオゾン水の溶存オゾンを除くためのオゾン除去部144とから構成されている。   FIG. 6 shows a conventional ozone water generator described in Patent Document 1. In FIG. As shown in FIG. 6, an ozone generator 2 using a creeping discharge type ceramic ozonizer (not shown), an ozone dissolving part 5 for producing ozone water, a raw water inlet 10 for taking raw water, and an ozone water outlet The raw material water inlet pipe 18 that communicates the part 11, the raw water inlet part 10, and the ozone water outlet part 11, and the ozone removing part 144 for removing dissolved ozone from the ozone water.

以上のように構成されたオゾン水の生成装置について、以下、その動作を説明する。   Hereinafter, the operation of the ozone water generator configured as described above will be described.

まず、沿面放電型のセラミックオゾナイザーを用いたオゾン発生部2を用いて空気中の酸素からオゾンを生成する。一方,原料水は原料水入口部10より取入れ原料水導入管18を介してオゾン溶解部5に導入される。オゾン溶解部5では原料水中に発生したオゾンガスを細かい泡として添加しオゾンを溶解してオゾン水を生成する。またこのオゾン水はオゾン除去部144の活性炭層を通してその溶存オゾンの大部分を除去し、極めて低濃度のオゾン水を生成する。   First, ozone is generated from oxygen in the air using the ozone generator 2 using a creeping discharge type ceramic ozonizer. On the other hand, the raw water is introduced from the raw water inlet 10 into the ozone dissolving part 5 through the raw water introduction pipe 18. In the ozone dissolving part 5, ozone gas generated in the raw material water is added as fine bubbles to dissolve ozone to generate ozone water. Further, this ozone water removes most of the dissolved ozone through the activated carbon layer of the ozone removing unit 144 to generate extremely low concentration ozone water.

さらに、この発明で、オゾンガスを直接装置外に取り出せばオゾンガスを生成することも同時に可能である。
特開平6−144806号公報
Furthermore, in the present invention, ozone gas can be generated at the same time if ozone gas is directly taken out of the apparatus.
JP-A-6-144806

しかしながら、上記従来の構成では、オゾンガスを細かい泡にして水に添加して、オゾンを溶解し、オゾン水を作る方式のため、発生オゾンガスの大半が水中に十分に溶解しきれずに、残存オゾンガスとなり、使用者が人体に危険なオゾン濃度にさらされるという課題を有していた。また、空気清浄機、脱臭器、冷蔵庫などオゾンを利用した家庭電化製品では、オゾン水やオゾンガスの濃度はオゾン臭がしないレベルの低濃度が望まれる。この装置で生成したオゾン水を人体に安全で且つオゾン臭のしない低濃度のオゾン水にするためには、オゾン除去部でオゾン水中の溶存オゾンを再度除去しなければならないという課題を有していた。同じく、残存ガスを人体に安全で且つオゾン臭のしないレベルの低濃度にするためには、新たにオゾン分解手段を設けなければならず、構造が複雑になるという課題を有していた。   However, in the above conventional configuration, ozone gas is added to water as fine bubbles to dissolve ozone and make ozone water. Therefore, most of the generated ozone gas cannot be fully dissolved in water and becomes residual ozone gas. The user has the problem of being exposed to ozone concentrations that are dangerous to the human body. Moreover, in household appliances using ozone such as air purifiers, deodorizers, refrigerators, etc., the concentration of ozone water or ozone gas is desired to be low so as not to cause ozone odor. In order to make ozone water generated by this device into low-concentration ozone water that is safe for the human body and has no ozone odor, there is a problem that dissolved ozone in the ozone water must be removed again by the ozone removal unit. It was. Similarly, in order to make the residual gas low in a level that is safe for the human body and does not generate an ozone odor, a new ozone decomposing means has to be provided, resulting in a complicated structure.

本発明は、上記従来の課題を解決するもので、人体に安全で且つオゾン臭の低い低濃度のオゾン水とオゾンミストとオゾンガスの生成を簡便な構造で行うことのできる生成装置を提供することを目的とする。   The present invention solves the above-mentioned conventional problems, and provides a generating device that is safe for the human body and can generate ozone water, ozone mist, and ozone gas with low concentration and low ozone odor with a simple structure. With the goal.

また、上記従来の構成では発生するオゾンガスは高濃度のため、オゾン臭のレベルが低い低濃度のオゾンガスを安定的に供給することができないという課題を有していた。   Moreover, in the said conventional structure, since ozone gas to generate | occur | produce was high concentration, it had the subject that low concentration ozone gas with a low level of ozone odor cannot be supplied stably.

本発明は、上記従来の課題を解決するもので、オゾン臭の低い低濃度のオゾンガスを安定的に供給することを目的とする。   An object of the present invention is to solve the above-mentioned conventional problems and to stably supply a low-concentration ozone gas having a low ozone odor.

上記課題を解決するために、本発明のオゾン水の生成装置は、貯留水を貯える貯水槽と、一端が前記貯留水中に開口し、他端が前記貯留水の外部に連通するとともに毛細管作用を利用して前記貯水槽の水を前記貯水槽外へ送液する送液手段とを有し、酸素を分解してオゾンを発生させるオゾン発生部を前記送液手段内に構成したものである。   In order to solve the above-described problems, the ozone water generating apparatus of the present invention includes a water storage tank for storing stored water, one end opened in the stored water, the other end communicating with the outside of the stored water, and a capillary action. And an ozone generating section for decomposing oxygen and generating ozone by decomposing oxygen in the liquid feeding means.

これによって、送液手段内の水中の溶存酸素を直接水中で分解することで、発生したオゾン水は微量のオゾンを含む低濃度のオゾン水とすることができる。   Thereby, the generated ozone water can be made into low-concentration ozone water containing a small amount of ozone by directly decomposing dissolved oxygen in water in the liquid feeding means.

また、本発明のオゾンミストの生成装置は、貯留水を貯える貯水槽と、一端が前記貯留水中に開口し、他端が前記貯留水の外部に連通するとともに毛細管作用を利用して前記貯水槽の水を前記貯水槽外へ送液する送液手段と、前記送液手段内に配設され酸素を分解してオゾンを発生させるオゾン発生部と、前記送液手段の前記貯留水外部に連通している下流端近傍に配設された加湿手段とを有し、前記加湿手段が前記送液手段内のオゾン水を霧化するものである。   In addition, the ozone mist generating device of the present invention includes a water storage tank for storing stored water, one end opened in the stored water, the other end communicating with the outside of the stored water, and utilizing the capillary action. A liquid feeding means for feeding the water out of the water storage tank, an ozone generating section disposed in the liquid feeding means for generating oxygen by decomposing oxygen, and communicating outside the stored water of the liquid feeding means Humidifying means disposed in the vicinity of the downstream end, and the humidifying means atomizes ozone water in the liquid feeding means.

これによって、送液手段内の水中の溶存酸素を直接水中で分解することで、発生したオゾン水は微量のオゾンを含む低濃度のオゾン水とすることができ、この低濃度のオゾン水を霧化することで、低濃度のオゾンミストを生成することができる。   As a result, by dissolving the dissolved oxygen in the water in the liquid feeding means directly in the water, the generated ozone water can be converted into low-concentration ozone water containing a small amount of ozone. By making it, low concentration ozone mist can be generated.

また、本発明のオゾンガスの生成装置は、貯留水を貯える貯水槽と、一端が前記貯留水中に開口し、他端が前記貯留水の外部に連通するとともに毛細管作用を利用して前記貯水槽の水を前記貯水槽外へ送液する送液手段と、前記送液手段内に配設され酸素を分解してオゾンを発生させるオゾン発生部と、前記送液手段の前記貯留水外部に連通している下流端近傍に強制対流を与える送風手段とを有し、前記送液手段内のオゾン水が前記送風手段によって蒸散してオゾンガスが発生するものである。   The ozone gas generator of the present invention includes a water storage tank for storing stored water, one end opened in the stored water, the other end communicating with the outside of the stored water, and utilizing the capillary action of the water storage tank. A liquid feeding means for feeding water to the outside of the water storage tank, an ozone generating section disposed in the liquid feeding means for generating oxygen by decomposing oxygen, and communicating with the outside of the stored water of the liquid feeding means And a blowing means for applying forced convection in the vicinity of the downstream end, and ozone water in the liquid feeding means is evaporated by the blowing means to generate ozone gas.

これによって、送液手段内の水中の溶存酸素を直接水中で分解することで、発生したオゾン水は微量のオゾンを含む低濃度のオゾン水とすることができ、この微量のオゾンを含む低濃度のオゾン水から極微量のオゾンガスが安定して発生させることができる。   As a result, by dissolving the dissolved oxygen in the water in the liquid feeding means directly in the water, the generated ozone water can be made into a low concentration ozone water containing a trace amount of ozone, and the low concentration containing this trace amount of ozone A very small amount of ozone gas can be stably generated from the ozone water.

本発明のオゾン水の生成装置は、簡便な構造で低濃度のオゾン水を発生させることで、人体に安全で且つオゾン臭の低いオゾン水が生成できるので、人体への安全性を確保した上で、除菌、脱臭及び有害物質の除去を行うことができる。   The ozone water generating device of the present invention generates ozone water with a simple structure and low concentration, thereby generating ozone water that is safe to the human body and has a low ozone odor, thus ensuring safety to the human body. Thus, sterilization, deodorization and removal of harmful substances can be performed.

また、本発明のオゾンミストの生成装置は、簡便な構造で低濃度のオゾン水を霧化することで、低濃度のオゾンミストを生成することができ、人体に安全で、且つオゾン臭の低い低濃度のオゾンミストを生成することができ、人体への安全性を確保した上で、除菌、脱臭及び有害物質の除去を行うことができる。   Moreover, the ozone mist generating apparatus of the present invention can generate low-concentration ozone mist by atomizing low-concentration ozone water with a simple structure, is safe for the human body, and has a low ozone odor. A low-concentration ozone mist can be generated, and the sterilization, deodorization, and removal of harmful substances can be performed while ensuring safety to the human body.

また、本発明のオゾンガスの生成装置は材料コストを低く抑えられ、かつ低濃度のオゾン水とオゾンガスを安定的に同時に生成することができ、人体への安全性を確保した上で、除菌、脱臭及び有害物質の除去を行うことができる。   In addition, the ozone gas generator of the present invention can keep material costs low and can stably generate low-concentration ozone water and ozone gas at the same time. Deodorization and removal of harmful substances can be performed.

請求項1に記載の発明は、貯留水を貯える貯水槽と、一端が前記貯留水中に開口し、他端が前記貯留水の外部に連通するとともに毛細管作用を利用して前記貯水槽の水を前記貯水槽外へ送液する送液手段とを有し、酸素を分解してオゾンを発生させるオゾン発生部を前記送液手段内に構成したことにより、前記オゾン発生部と大気の接触が大幅に抑制されることで、発生した微量のオゾンを含むオゾン水を前記送液手段内に生成することとなり、特殊材料を必要としない簡便な構造で、人体に安全で且つオゾン臭の低い低濃度のオゾン水を生成することができる。   According to the first aspect of the present invention, there is provided a water storage tank for storing the stored water, one end opening in the stored water, the other end communicating with the outside of the stored water, and utilizing the capillary action to supply the water in the water storage tank. A liquid feeding means for feeding the outside of the water storage tank, and an ozone generating part for decomposing oxygen to generate ozone is configured in the liquid feeding means, so that the contact between the ozone generating part and the atmosphere is greatly increased. Ozone is contained in the liquid feeding means to generate ozone water containing a small amount of generated ozone, and has a simple structure that does not require special materials, is safe for the human body, and has a low concentration of ozone odor. Of ozone water.

請求項2に記載の発明は、貯留水を貯える貯水槽と、一端が前記貯留水中に開口し、他端が前記貯留水の外部に連通するとともに毛細管作用を利用して前記貯水槽の水を前記貯水槽外へ送液する送液手段と、前記送液手段内に配設され酸素を分解してオゾンを発生させるオゾン発生部と、前記送液手段の前記貯留水外部に連通している下流端近傍に配設された加湿手段とを有し、前記加湿手段が前記送液手段内のオゾン水を霧化することにより、オゾンミストを生成することとなり、特殊材料を必要としない簡便な構造で、人体に安全で且つオゾン臭の低い低濃度のオゾンミストを生成することができる。   The invention according to claim 2 is a water storage tank for storing stored water, one end of which opens into the stored water, the other end communicates with the outside of the stored water, and uses the capillary action to supply water from the water storage tank. A liquid feeding means for feeding the liquid outside the water storage tank, an ozone generating section disposed in the liquid feeding means for decomposing oxygen and generating ozone, and communicating with the outside of the stored water of the liquid feeding means. Humidifying means disposed in the vicinity of the downstream end, and the humidifying means atomizes the ozone water in the liquid feeding means to generate ozone mist, which does not require a special material. With the structure, a low concentration ozone mist that is safe for the human body and has a low ozone odor can be generated.

請求項3に記載の発明は、貯留水を貯える貯水槽と、一端が前記貯留水中に開口し、他端が前記貯留水の外部に連通するとともに毛細管作用を利用して前記貯水槽の水を前記貯水槽外へ送液する送液手段と、前記送液手段内に配設され酸素を分解してオゾンを発生させるオゾン発生部と、前記送液手段の前記貯留水外部に連通している下流端近傍に強制対流を与える送風手段とを有し、前記送液手段内のオゾン水が前記送風手段によって蒸散してオゾンガスが発生することにより、オゾンガスが発生することとなり、特殊材料を必要としない簡便な構造で、人体に安全で且つオゾン臭の低い低濃度のオゾンガスを安定的に生成することができる。   The invention according to claim 3 is a water storage tank for storing stored water, one end of which opens into the stored water, the other end communicates with the outside of the stored water, and uses the capillary action to supply water from the water storage tank. A liquid feeding means for feeding the liquid outside the water storage tank, an ozone generating section disposed in the liquid feeding means for decomposing oxygen and generating ozone, and communicating with the outside of the stored water of the liquid feeding means. A blowing means for providing forced convection in the vicinity of the downstream end, ozone gas is generated by the evaporation of ozone water in the liquid feeding means by the blowing means, and ozone gas is generated, and a special material is required. A low-concentration ozone gas that is safe for the human body and has a low ozone odor can be stably generated with a simple structure that does not.

請求項4に記載の発明は、請求項1から3の発明に加えて、前記オゾン発生部は、前記送液手段内の水中の溶存酸素を分解してオゾンを発生させることによりオゾン水を生成することにより、大気中の酸素の分解が略0となり、人体に安全で且つオゾン臭の低い低濃度のオゾンガスを生成することができる。   According to a fourth aspect of the present invention, in addition to the first to third aspects of the invention, the ozone generator generates ozone water by decomposing dissolved oxygen in water in the liquid feeding means to generate ozone. By doing so, the decomposition of oxygen in the atmosphere becomes substantially zero, and a low-concentration ozone gas that is safe to the human body and has a low ozone odor can be generated.

請求項5に記載の発明は、請求項1から4の発明に加えて、前記オゾン発生部のオゾン発生方式は、放電方式または紫外線方式であることにより、水中の溶存酸素を分解してオゾンを生成することとなり、簡便な構造で人体に安全な低濃度のオゾン水を生成することができる。   According to a fifth aspect of the present invention, in addition to the first to fourth aspects of the invention, the ozone generation method of the ozone generation unit is a discharge method or an ultraviolet method, so that dissolved oxygen in water is decomposed to generate ozone. Thus, it is possible to generate low-concentration ozone water that is safe for the human body with a simple structure.

請求項6に記載の発明は、請求項1から4の発明に加えて、前記送液手段は、繊維材料または多孔質セラミックで構成することにより、毛細管作用が生じてオゾン発生体に常時水分が供給されることとなり、ポンプ等の手段を用いず簡便な構造で人体に安全な低濃度のオゾン水を生成することができる。   In addition to the inventions of claims 1 to 4, the invention according to claim 6 is configured such that the liquid feeding means is made of a fiber material or a porous ceramic, so that a capillary action occurs, and moisture is constantly supplied to the ozone generator. Thus, low-concentration ozone water that is safe for the human body can be generated with a simple structure without using a pump or the like.

請求項7に記載の発明は、請求項2の発明に加えて、前記加湿手段は、超音波加湿器であることにより、前記送液手段の下流端内のオゾン水を霧化することとなり、簡便な構造で人体に安全な低濃度のオゾンミストを生成することができる。   In addition to the invention of claim 2, the invention of claim 7 is that the humidifying means is an ultrasonic humidifier, so that the ozone water in the downstream end of the liquid feeding means is atomized, A low-concentration ozone mist that is safe for the human body can be generated with a simple structure.

請求項8に記載の発明は、請求項1から7の発明に加えて、前記送液手段は一端が前記貯留水中に開口するとともに他端が前記貯水槽の外部に開口したものであり、これによって、生成されたオゾン水もしくはオゾンミストもしくはオゾンガスを必要な箇所に直接供給することができ、より確実に除菌、脱臭、有害物質の除去等を行うことができる。   According to an eighth aspect of the invention, in addition to the first to seventh aspects of the invention, the liquid feeding means has one end opened in the stored water and the other end opened outside the water storage tank. Thus, the generated ozone water, ozone mist, or ozone gas can be directly supplied to a necessary place, and sterilization, deodorization, removal of harmful substances, and the like can be performed more reliably.

以下、本発明の実施の形態について、図面を参照しながら説明するが、従来例または先に説明した実施の形態と同一構成については同一符号を付して、その詳細な説明は省略する。   DESCRIPTION OF EMBODIMENTS Hereinafter, embodiments of the present invention will be described with reference to the drawings. The same reference numerals are given to the same configurations as those of the conventional example or the embodiments described above, and detailed descriptions thereof will be omitted.

なお、この実施の形態によってこの発明が限定されるものではない。   The present invention is not limited to the embodiments.

(実施の形態1)
図1は本発明の実施の形態1におけるオゾン水とオゾンミストの生成装置の側断面図である。図2は同実施の形態のオゾン水の生成装置の要部構成図である。
(Embodiment 1)
FIG. 1 is a side sectional view of an apparatus for generating ozone water and ozone mist in Embodiment 1 of the present invention. FIG. 2 is a configuration diagram of a main part of the ozone water generator according to the embodiment.

図1、図2において、オゾン水とオゾンミストの生成装置200には、機器収納区画201と、送風区画202が区画形成されている。   In FIG. 1 and FIG. 2, a device storage section 201 and a blower section 202 are formed in the ozone water and ozone mist generating apparatus 200.

機器収納区画201内には、主に貯水槽210と送液手段220と、オゾン発生部230が配設されている。また、送風区画202内には加湿手段240が配設されている。   In the device storage section 201, a water storage tank 210, a liquid feeding means 220, and an ozone generator 230 are mainly disposed. Further, a humidifying means 240 is disposed in the air blowing section 202.

貯水槽210は、貯留水を貯留するための槽である。貯水槽210には、外部から給水を行うための給水管211が構成されており、給水管211の途中には開閉弁212が構成されている。また、貯水槽210の内部には、水位を検出するフロートスイッチ213が具備されており、貯水槽210の上部には貫通部214が形成されている。   The water storage tank 210 is a tank for storing stored water. A water supply pipe 211 for supplying water from the outside is configured in the water storage tank 210, and an opening / closing valve 212 is configured in the middle of the water supply pipe 211. In addition, a float switch 213 for detecting the water level is provided inside the water storage tank 210, and a penetrating portion 214 is formed in the upper part of the water storage tank 210.

送液手段220は、貯水槽210の水を送風区画へ導くための送液部材であり、毛細管作用により送液することを特徴としており、第一送液部221と、第二送液部222と、第3送液部223とから構成されている。   The liquid feeding means 220 is a liquid feeding member for guiding the water in the water storage tank 210 to the air blowing section, and is fed by capillary action. The first liquid feeding part 221 and the second liquid feeding part 222 are provided. And a third liquid feeding part 223.

第一送液部221は、水の流れの上流に位置し、構成上その下端221aは貫通部214を介して貯水槽210の下部近傍に位置する。第一送液部221の材料としては、フレキシブルに形状が構成できる繊維材料を用いることが望ましい。   The first liquid feeding part 221 is located upstream of the flow of water, and the lower end 221a of the structure is located near the lower part of the water storage tank 210 via the penetration part 214. As a material of the first liquid feeding part 221, it is desirable to use a fiber material that can be configured flexibly.

第二送液部222は、多孔質セラミックを用いることが好ましく、形状としては中空の筒型形状とした。ここで、第二送液部222の一端222aは、第一送液部221の上端221bと接続されており、第二送液部222の他端222bは、第3送液部223の上流端223aと接続されている。   The second liquid feeding part 222 is preferably made of a porous ceramic and has a hollow cylindrical shape. Here, one end 222 a of the second liquid feeding unit 222 is connected to the upper end 221 b of the first liquid feeding unit 221, and the other end 222 b of the second liquid feeding unit 222 is the upstream end of the third liquid feeding unit 223. 223a.

第三送液部223は、貫通部203を介して送風区画202に達しており、第三送液部223の材料としては、フレキシブルに形状が構成できる繊維材料を用いることが望ましい。   The third liquid feeding part 223 reaches the air blowing section 202 via the penetration part 203, and it is desirable to use a fiber material that can be configured flexibly as the material of the third liquid feeding part 223.

オゾン発生部230は、ランプ管231、ランプ管231の両端に電極232とを配したU次型の紫外線ランプを備えている。ここで、ランプ管231は純度の高い石英ガラスを材料としており、ランプ管231内には低圧の水銀蒸気とアルゴン、キセノン等の不活性ガスが封入されている。さらに、オゾン発生部230は、第二送液部222の中空部内壁に、ランプ管231外壁が密接するように挿入されており、ランプ管231の外壁と、第二送液部222の中空部の内壁との間には微小な隙間233が形成されている。さらに、隙間233の開放端は、シール部材234で封止されている。   The ozone generating unit 230 includes a lamp tube 231 and a U-order ultraviolet lamp in which electrodes 232 are arranged at both ends of the lamp tube 231. Here, the lamp tube 231 is made of high-purity quartz glass, and the lamp tube 231 is filled with a low-pressure mercury vapor and an inert gas such as argon or xenon. Further, the ozone generator 230 is inserted so that the outer wall of the lamp tube 231 is in close contact with the inner wall of the hollow portion of the second liquid feeding portion 222, and the outer wall of the lamp tube 231 and the hollow portion of the second liquid feeding portion 222. A minute gap 233 is formed between the inner wall and the inner wall. Further, the open end of the gap 233 is sealed with a seal member 234.

加湿手段240は、送風区画202内に構成された超音波加湿器であり、超音波加湿器の振動子には、第三送液部223の下流端223bが接続されている。   The humidifying means 240 is an ultrasonic humidifier configured in the air blowing section 202, and the downstream end 223b of the third liquid feeding unit 223 is connected to the vibrator of the ultrasonic humidifier.

制御部250は、開閉弁212、フロートスイッチ213、オゾン発生部230、加湿手段240の運転を制御する。   The controller 250 controls the operation of the on-off valve 212, the float switch 213, the ozone generator 230, and the humidifying means 240.

以上のように構成されたオゾン水とオゾンミストの生成装置について、以下その動作、作用を説明する。   The operation and action of the ozone water and ozone mist generator configured as described above will be described below.

まず、貯水槽210の水は、フロートスイッチ213により開閉弁212が開閉し、一定水位になるように設定されている。ここで、貯水槽210の下部近傍には、第一送液部221の下端221aが配設されており、毛細管作用により貯水槽210の水は、第二送液部222へ送液される。   First, the water in the water storage tank 210 is set so that the open / close valve 212 is opened and closed by the float switch 213 and becomes a constant water level. Here, a lower end 221 a of the first liquid feeding unit 221 is disposed near the lower part of the water storage tank 210, and the water in the water storage tank 210 is fed to the second liquid feeding unit 222 by capillary action.

次に、第二送液部222では、第一送液部221から送液された水が他孔質セラミックで形成された第二送液部222全体に満たされることで、微小な隙間233に水が充満することになる。   Next, in the second liquid feeding part 222, the water fed from the first liquid feeding part 221 is filled in the entire second liquid feeding part 222 formed of other porous ceramics, so that the minute gap 233 is formed. It will be full of water.

さらに、オゾン発生部230に通電されると、ランプ管230aより紫外線が発生する。ランプ管230aより発生した紫外線は、オゾン発生部230の周りに充満された水中の溶存酸素を解離してオゾンを生成し、水中に溶存するとともに、酸素原子と水分子の反応によりOHラジカルを生成する。   Further, when the ozone generator 230 is energized, ultraviolet rays are generated from the lamp tube 230a. The ultraviolet rays generated from the lamp tube 230a dissociate dissolved oxygen in the water filled around the ozone generator 230 to generate ozone, and dissolve in the water, and also generate OH radicals by the reaction of oxygen atoms and water molecules. To do.

次に、オゾン発生部230近傍で生成されたオゾン水は、第三送液部223の毛細管作用により、送風区画202に配設された下流端223bへ送液される。ここで、超音波加湿器である加湿手段240が運転されると、加振子に接続された下流端223bに含まれるオゾン水が霧化されて、送風区画202内に拡散することとなる。   Next, the ozone water generated in the vicinity of the ozone generating unit 230 is sent to the downstream end 223 b disposed in the air blowing section 202 by the capillary action of the third liquid feeding unit 223. Here, when the humidifying means 240 that is an ultrasonic humidifier is operated, the ozone water contained in the downstream end 223b connected to the shaker is atomized and diffused into the air blowing section 202.

以上のように本実施の形態では、水を貯える貯水槽210と、貯水槽210の近傍に配設されたオゾン発生部230と、毛細管作用を利用し、貯水槽210の水を貯水槽210外へ送液する送液手段220とを有し、オゾン発生部230は、送液手段220内に構成されていることにより、オゾン発生部230と大気の接触が大幅に抑制されることで、発生した微量のオゾンを含むオゾン水を送液手段220内に生成することとなり、特殊材料を必要としない簡便な構造で、人体に安全で且つオゾン臭の低い低濃度のオゾン水を生成することができる。   As described above, in the present embodiment, the water storage tank 210 that stores water, the ozone generation unit 230 disposed in the vicinity of the water storage tank 210, and the capillary action are used to remove the water in the water storage tank 210 from the water storage tank 210. And the ozone generating unit 230 is configured in the liquid supplying unit 220, so that the contact between the ozone generating unit 230 and the atmosphere is greatly suppressed. Ozone water containing a small amount of ozone is generated in the liquid feeding means 220, and low concentration ozone water that is safe for the human body and has a low ozone odor can be generated with a simple structure that does not require special materials. it can.

さらに、本実施の形態では、送液手段220内のオゾン水を加湿手段240により霧化して拡散させるので、人体に安全で且つオゾン臭の低い低濃度のオゾンミストを生成することができる。   Furthermore, in the present embodiment, since the ozone water in the liquid feeding means 220 is atomized and diffused by the humidifying means 240, a low-concentration ozone mist that is safe for the human body and has a low ozone odor can be generated.

さらに、第二送液部222の中空部内壁に、ランプ管230外壁が密接すように挿入され、この微小な隙間233に充満した水中の溶存酸素を紫外線で解離してオゾンを生成することで、大気中の酸素と紫外線の反応を防止することができるので、人体に安全で且つオゾン臭の低い低濃度のオゾン水を生成することができる。   Further, the outer wall of the lamp tube 230 is inserted into the hollow inner wall of the second liquid feeding unit 222 so that the dissolved oxygen in the water filled in the minute gap 233 is dissociated with ultraviolet rays to generate ozone. Since the reaction between oxygen and ultraviolet rays in the atmosphere can be prevented, low-concentration ozone water that is safe for the human body and has a low ozone odor can be generated.

なお、本実施例においては、オゾン発生部230として、紫外線ランプを用いたが、放電部を耐水処理した放電式のオゾン生成器を用いても同様の効果が期待できる。   In this embodiment, an ultraviolet lamp is used as the ozone generator 230. However, the same effect can be expected by using a discharge type ozone generator in which the discharge part is water-resistant.

(実施の形態2)
図3は本発明の実施の形態2のオゾン水とオゾンガスの生成装置の側断面図である。図4は同実施の形態のオゾン水とオゾンガスの生成装置の要部構成図である。図5は水中放電および空中放電によるオゾン発生量の温度特性図である。
(Embodiment 2)
FIG. 3 is a sectional side view of the ozone water and ozone gas generator according to Embodiment 2 of the present invention. FIG. 4 is a configuration diagram of the main part of the ozone water and ozone gas generator according to the embodiment. FIG. 5 is a temperature characteristic diagram of the amount of ozone generated by underwater discharge and air discharge.

図3、図4において、オゾン水とオゾンガスの生成装置300には、機器収納区画201と送風区画202が区画形成されている。   3 and 4, the device storage section 201 and the air blowing section 202 are formed in the ozone water and ozone gas generation apparatus 300.

送液手段310は、貯水槽210の水を送風区画へ導くための送液部材であり、毛細管作用により送液することを特徴としており、第一送液部311と、第二送液部312と、第3送液部313とから構成されている。   The liquid feeding means 310 is a liquid feeding member for guiding the water in the water storage tank 210 to the air blowing section, and is characterized by feeding liquid by capillary action. The first liquid feeding section 311 and the second liquid feeding section 312 are provided. And a third liquid feeding part 313.

第一送液部311は、水の流れの上流に位置し、構成上その下端311aは貫通部214を介して貯水槽210の下部近傍に位置する。第一送液部311の材料としては、フレキシブルに形状が構成できる繊維材料を用いることが望ましい。   The first liquid feeding unit 311 is located upstream of the flow of water, and the lower end 311a of the configuration is located near the lower part of the water storage tank 210 via the penetration part 214. As a material of the first liquid feeding unit 311, it is desirable to use a fiber material that can be configured flexibly.

第二送液部312は、多孔質セラミックを用いることが好ましく、形状としては中空の筒型形状とした。ここで、第二送液部312の一端312aは、第一送液部221の上端311bと接続されており、第二送液部312の他端312bは、第3送液部313の上流端313aと接続されている。   The second liquid feeding unit 312 is preferably made of a porous ceramic and has a hollow cylindrical shape. Here, one end 312 a of the second liquid feeding unit 312 is connected to the upper end 311 b of the first liquid feeding unit 221, and the other end 312 b of the second liquid feeding unit 312 is the upstream end of the third liquid feeding unit 313. 313a is connected.

第三送液部313は、貫通部203を介して送風区画202に達しており、第三送液部313の材料としては、フレキシブルに形状が構成できる繊維材料を用いることが望ましい。   The third liquid feeding part 313 reaches the air blowing section 202 via the penetration part 203, and it is desirable to use a fiber material that can be configured flexibly as the material of the third liquid feeding part 313.

オゾン発生部320は、高電圧放電方式のオゾン発生体であり、電極部321と電源部322から構成される。ここで、電極部321は電極の周辺の耐水性を高めた仕様とすることが好ましく、電極部321と、第二送液部312の中空部の内壁との間には微小な隙間323が形成されている。さらに、隙間323の開放端は、シール部材324で封止されている。   The ozone generator 320 is a high-voltage discharge type ozone generator, and includes an electrode unit 321 and a power source unit 322. Here, it is preferable that the electrode part 321 has a specification with improved water resistance around the electrode, and a minute gap 323 is formed between the electrode part 321 and the inner wall of the hollow part of the second liquid feeding part 312. Has been. Further, the open end of the gap 323 is sealed with a seal member 324.

電源部322は、オゾン発生のための高電圧発生電源であり、電極部321が内蔵された第二送液部312の近傍に配設されている。   The power supply unit 322 is a high voltage generation power source for generating ozone, and is disposed in the vicinity of the second liquid feeding unit 312 in which the electrode unit 321 is incorporated.

送風手段330は、送風区画202内に構成された送風機であり、送風手段330の運転により、送風区画202内に達した第三送液部313の周辺に強制対流が生じるように構成されている。   The air blowing means 330 is a blower configured in the air blowing section 202, and is configured such that forced convection is generated around the third liquid feeding unit 313 that has reached the air blowing section 202 by the operation of the air blowing means 330. .

以上のように構成されたオゾン水とオゾンガスの生成装置について、以下その動作、作用を説明する。   The operation and action of the ozone water and ozone gas generator configured as described above will be described below.

まず、貯水槽210の下部近傍には、第一送液部311の下端311aが配設されており、毛細管作用により貯水槽210の水は、第二送液部312へ送液される。   First, a lower end 311a of the first liquid feeding unit 311 is disposed near the lower part of the water storage tank 210, and the water in the water storage tank 210 is fed to the second liquid feeding unit 312 by capillary action.

次に、第二送液部312では、第一送液部311から送液された水が他孔質セラミックで形成された第二送液部222全体に満たされることで、微小な隙間323に水が充満することになる。   Next, in the second liquid feeding unit 312, the water fed from the first liquid feeding unit 311 is filled in the entire second liquid feeding unit 222 formed of another porous ceramic, so that the minute gap 323 is formed. It will be full of water.

さらに、オゾン発生部320に通電されると、電極部321からの放電によって、微小な隙間323内の水中の溶存酸素が電子との衝突により酸素原子に解離される。また、酸素原子は溶存酸素分子と結合してオゾンが発生するとともに、水分子と反応してOHラジカルを同時に生成する。さらに、発生したオゾンは隙間323内の水に溶存し、オゾン水が生成される。   Furthermore, when the ozone generator 320 is energized, dissolved oxygen in the water in the minute gap 323 is dissociated into oxygen atoms by collision with electrons due to the discharge from the electrode 321. Also, oxygen atoms combine with dissolved oxygen molecules to generate ozone and react with water molecules to simultaneously generate OH radicals. Furthermore, the generated ozone is dissolved in the water in the gap 323, and ozone water is generated.

次に、オゾン発生部320近傍で生成されたオゾン水は、第三送液部313の毛細管作用により、送風区画202に配設された下流端313bへ送液される。ここで、送風手段330の運転により生じた強制対流により、オゾン水の蒸散が促進される。このとき、水中に溶存したオゾンはオゾンガスとして送風区画202内に拡散することとなる。   Next, the ozone water generated in the vicinity of the ozone generating unit 320 is fed to the downstream end 313 b disposed in the air blowing section 202 by the capillary action of the third liquid feeding unit 313. Here, the convection of ozone water is promoted by the forced convection generated by the operation of the blowing means 330. At this time, ozone dissolved in water diffuses into the air blowing section 202 as ozone gas.

次に図5は一定空間において、本発明の実施の形態2における水中溶存酸素からオゾンを発生する水中放電と従来の空気中の酸素からオゾンを発生する空中放電のオゾン発生量に与える温度の影響を示したものである。従来の空中放電は周囲温度変動の影響が大きく、周囲温度が低いとオゾン発生量が多くなり、逆に周囲温度が高くなるとオゾン発生量が少なくなる特性をもつ。一方、本発明の水中放電は、オゾンガスをオゾン水からの遊離により生成するため、周囲の温度変動の影響が空気に比べ小さく、周囲温度変動によるオゾン発生量の変動幅も小さくなる。したがって、オゾン水からオゾンガスを発生する本発明の実施の形態の方がより安定してオゾンガスを生成することができる。   Next, FIG. 5 shows the influence of temperature on the amount of ozone generated in a constant space, in an underwater discharge in which ozone is generated from dissolved oxygen in water and a conventional air discharge in which ozone is generated from oxygen in the air in Embodiment 2 of the present invention. Is shown. Conventional aerial discharges are greatly affected by ambient temperature fluctuations. When the ambient temperature is low, the amount of ozone generation increases. Conversely, when the ambient temperature increases, the amount of ozone generation decreases. On the other hand, since the underwater discharge of the present invention generates ozone gas by liberation from ozone water, the influence of ambient temperature fluctuation is smaller than that of air, and the fluctuation range of ozone generation amount due to ambient temperature fluctuation is also small. Therefore, the embodiment of the present invention that generates ozone gas from ozone water can generate ozone gas more stably.

以上のように本実施の形態では、水を貯える貯水槽210と、毛細管作用を利用し、貯水槽210の水を貯水槽210外へ送液する送液手段310と、送液手段310内に配設されたオゾン発生部320と、送液手段310の下流端313b近傍に強制対流を与える送風手段330とを有し、送液手段310内の水中の溶存酸素を分解して得られるオゾン水を送風区画202内で再びガス化させるので、通常の空中放電によるオゾンガスの発生量は周囲温度変動の影響が大きく、安定して発生するのが困難であるのに対して、本実施の形態では、周囲の温度変動の影響が、空気に比べ小さいことから、発生するオゾンガス量への影響が小さくなり、人体に安全な低濃度のオゾンガスを安定的に供給することができる。   As described above, in the present embodiment, the water storage tank 210 that stores water, the liquid supply means 310 that supplies water from the water storage tank 210 to the outside of the water storage tank 210 using the capillary action, and the liquid supply means 310 Ozone water obtained by decomposing dissolved oxygen in the water in the liquid feeding means 310, having the ozone generating section 320 disposed, and the air blowing means 330 for giving forced convection in the vicinity of the downstream end 313b of the liquid feeding means 310 In the present embodiment, the amount of ozone gas generated by normal air discharge is greatly affected by ambient temperature fluctuations and is difficult to generate stably. Since the influence of ambient temperature fluctuation is smaller than that of air, the influence on the amount of generated ozone gas is reduced, and a safe low-concentration ozone gas can be stably supplied to the human body.

以上のように、本発明にかかるオゾン水とオゾンミストとオゾンガスの発生装置は、低濃度のオゾン水と低濃度のオゾンミストと低濃度のオゾンガスを安定的に生成し、高性能な脱臭、除菌、有害物質の除去を行なうことができるため、家庭用冷蔵庫、業務用冷蔵庫、食品洗浄器、食器洗浄器、医療器具洗浄器等の用途にも適用できる。   As described above, the ozone water, ozone mist, and ozone gas generator according to the present invention stably generates low-concentration ozone water, low-concentration ozone mist, and low-concentration ozone gas, and performs high-performance deodorization and removal. Since bacteria and harmful substances can be removed, the present invention can be applied to household refrigerators, commercial refrigerators, food cleaners, dishwashers, medical instrument cleaners, and the like.

本発明の実施の形態1におけるオゾン水とオゾンミストの生成装置の側断面図Side sectional view of ozone water and ozone mist generator in Embodiment 1 of the present invention 本発明の実施の形態1におけるオゾン水の生成装置の要部構成図The principal part block diagram of the generator of ozone water in Embodiment 1 of this invention 本発明の実施の形態2におけるオゾン水とオゾンガスの生成装置の側断面図Side sectional view of ozone water and ozone gas generator in Embodiment 2 of the present invention 本発明の実施の形態2におけるオゾン水とオゾンガスの生成装置の要部構成図The principal part block diagram of the production | generation apparatus of the ozone water and ozone gas in Embodiment 2 of this invention 本発明の実施の形態2における水中放電および空中放電によるオゾン発生量の温度特性図Temperature characteristic diagram of ozone generation amount by underwater discharge and air discharge in Embodiment 2 of the present invention 従来のオゾン水の生成装置を示す図A diagram showing a conventional ozone water generator

符号の説明Explanation of symbols

200 オゾン水とオゾンミストの生成装置
210 貯水槽
220,310 送液手段
230 オゾン発生部(紫外線方式)
240 加湿手段
300 オゾン水とオゾンガスの生成装置
320 オゾン発生部(放電方式)
330 送風手段
200 Ozone water and ozone mist generator 210 Water storage tank 220, 310 Liquid feeding means 230 Ozone generator (ultraviolet system)
240 Humidification means 300 Ozone water and ozone gas generator 320 Ozone generator (discharge method)
330 Air blowing means

Claims (8)

貯留水を貯える貯水槽と、一端が前記貯留水中に開口し、毛細管作用を利用して前記貯留水を送液する送液手段とを有し、酸素を分解してオゾンを発生させるオゾン発生部を前記送液手段内に構成したオゾン水の生成装置。   An ozone generator that decomposes oxygen to generate ozone by having a water storage tank for storing stored water, and a liquid feeding means that opens at one end in the stored water and feeds the stored water using a capillary action. A device for generating ozone water in the liquid feeding means. 貯留水を貯える貯水槽と、一端が前記貯留水中に開口し、他端が前記貯留水の外部に連通するとともに毛細管作用を利用して前記貯水槽の水を前記貯水槽外へ送液する送液手段と、前記送液手段内に配設され酸素を分解してオゾンを発生させるオゾン発生部と、前記送液手段の前記貯留水外部に連通している下流端近傍に配設された加湿手段とを有し、前記加湿手段が前記送液手段内のオゾン水を霧化するオゾンミストの生成装置。   A water storage tank that stores the stored water, and one end that opens into the stored water, the other end communicates with the outside of the stored water, and uses the capillary action to send water from the water storage tank to the outside of the water storage tank. A liquid means, an ozone generator disposed in the liquid feed means for generating oxygen by decomposing oxygen, and a humidifier disposed near the downstream end of the liquid feed means communicating with the outside of the stored water And an ozone mist generating device in which the humidifying means atomizes the ozone water in the liquid feeding means. 貯留水を貯える貯水槽と、一端が前記貯留水中に開口し、他端が前記貯留水の外部に連通するとともに毛細管作用を利用して前記貯水槽の水を前記貯水槽外へ送液する送液手段と、前記送液手段内に配設され酸素を分解してオゾンを発生させるオゾン発生部と、前記送液手段の前記貯留水外部に連通している下流端近傍に強制対流を与える送風手段とを有し、前記送液手段内のオゾン水が前記送風手段によって蒸散してオゾンガスが発生するオゾンガスの生成装置。   A water storage tank that stores the stored water, and one end that opens into the stored water, the other end communicates with the outside of the stored water, and uses the capillary action to send water from the water storage tank to the outside of the water storage tank. A liquid means; an ozone generating section disposed in the liquid feeding means for generating ozone by decomposing oxygen; and a blower for applying forced convection to the vicinity of the downstream end of the liquid feeding means communicating with the outside of the stored water Means for generating ozone gas, wherein ozone water in the liquid feeding means is evaporated by the blowing means to generate ozone gas. 前記オゾン発生部は、前記送液手段内の水中の溶存酸素を分解してオゾンを発生させることによりオゾン水を生成する請求項1から3のいずれか一項に記載のオゾン水の生成装置またはオゾンミストの生成装置またはオゾンガスの生成装置。   The ozone water generating device according to any one of claims 1 to 3, wherein the ozone generating section generates ozone water by decomposing dissolved oxygen in water in the liquid feeding means to generate ozone. Ozone mist generator or ozone gas generator. 前記オゾン発生部のオゾン発生方式は、放電方式または紫外線方式である請求項1から4のいずれか一項に記載のオゾン水の生成装置またはオゾンミストの生成装置またはオゾンガスの生成装置。   The ozone generation method of the ozone generation unit is a discharge method or an ultraviolet ray method, The ozone water generation device, the ozone mist generation device, or the ozone gas generation device according to any one of claims 1 to 4. 前記送液手段は、繊維材料または多孔質セラミックで構成されている請求項1から4のいずれか一項に記載のオゾン水の生成装置またはオゾンミストの生成装置またはオゾンガスの生成装置。   5. The ozone water generating device, the ozone mist generating device, or the ozone gas generating device according to claim 1, wherein the liquid feeding unit is made of a fiber material or a porous ceramic. 前記加湿手段は、超音波加湿器である請求項2に記載のオゾンミストの生成装置。   The ozone mist generating apparatus according to claim 2, wherein the humidifying means is an ultrasonic humidifier. 前記送液手段は一端が前記貯留水中に開口するとともに他端が前記貯水槽の外部に開口したものである請求項1から7のいずれか一項に記載のオゾン水の生成装置またはオゾンミストの生成装置またはオゾンガスの生成装置。   8. The apparatus for generating ozone water or ozone mist according to claim 1, wherein one end of the liquid feeding means opens into the stored water and the other end opens to the outside of the water storage tank. Generator or ozone gas generator.
JP2004214065A 2004-07-22 2004-07-22 Ozone water generator, ozone mist generator, and ozone gas generator Expired - Fee Related JP4710270B2 (en)

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JP2009240698A (en) * 2008-03-31 2009-10-22 Osaka Gas Co Ltd Grill deodorant method and grill with deodorant function
JP2012020238A (en) * 2010-07-15 2012-02-02 Adson Corp Ozone mist generator
KR20190011951A (en) * 2017-07-26 2019-02-08 조병옥 Deodorization and sterilization device using ozone mist
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009240698A (en) * 2008-03-31 2009-10-22 Osaka Gas Co Ltd Grill deodorant method and grill with deodorant function
JP2012020238A (en) * 2010-07-15 2012-02-02 Adson Corp Ozone mist generator
KR20190011951A (en) * 2017-07-26 2019-02-08 조병옥 Deodorization and sterilization device using ozone mist
KR102007305B1 (en) 2017-07-26 2019-08-05 조병옥 Deodorization and sterilization device using ozone mist
CN113384725A (en) * 2020-03-11 2021-09-14 上海喜运环保科技有限公司 Method and device for preparing ozone water atomized gas and application

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