JP2005529641A - 二重装着可能な手袋 - Google Patents
二重装着可能な手袋 Download PDFInfo
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- JP2005529641A JP2005529641A JP2004503231A JP2004503231A JP2005529641A JP 2005529641 A JP2005529641 A JP 2005529641A JP 2004503231 A JP2004503231 A JP 2004503231A JP 2004503231 A JP2004503231 A JP 2004503231A JP 2005529641 A JP2005529641 A JP 2005529641A
- Authority
- JP
- Japan
- Prior art keywords
- polychloroprene
- article
- polymer
- latex
- glove
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 55
- 229920000642 polymer Polymers 0.000 claims abstract description 40
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 14
- 239000002174 Styrene-butadiene Substances 0.000 claims abstract description 13
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011115 styrene butadiene Substances 0.000 claims abstract description 9
- 239000006185 dispersion Substances 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 4
- 229920001195 polyisoprene Polymers 0.000 claims abstract description 3
- 239000004816 latex Substances 0.000 claims description 33
- 229920000126 latex Polymers 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 22
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 239000000017 hydrogel Substances 0.000 claims description 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 claims description 2
- 239000010409 thin film Substances 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 238000005660 chlorination reaction Methods 0.000 description 12
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 11
- 239000000460 chlorine Substances 0.000 description 11
- 229910052801 chlorine Inorganic materials 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000000463 material Substances 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 5
- 239000005060 rubber Substances 0.000 description 5
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 210000003811 finger Anatomy 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 2
- 229920013645 Europrene Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002981 blocking agent Substances 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- LIFLRQVHKGGNSG-UHFFFAOYSA-N 2,3-dichlorobuta-1,3-diene Chemical compound ClC(=C)C(Cl)=C LIFLRQVHKGGNSG-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000011928 denatured alcohol Substances 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 210000004247 hand Anatomy 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 210000003813 thumb Anatomy 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 210000000707 wrist Anatomy 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/126—Halogenation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/003—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/14—Dipping a core
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
- C08L11/02—Latex
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2400/00—Functions or special features of garments
- A41D2400/44—Donning facilities
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
- B29C71/0009—After-treatment of articles without altering their shape; Apparatus therefor using liquids, e.g. solvents, swelling agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2009/00—Use of rubber derived from conjugated dienes, as moulding material
- B29K2009/06—SB polymers, i.e. butadiene-styrene polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2011/00—Use of rubber derived from chloroprene as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0072—Roughness, e.g. anti-slip
- B29K2995/0073—Roughness, e.g. anti-slip smooth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/48—Wearing apparel
- B29L2031/4842—Outerwear
- B29L2031/4864—Gloves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/753—Medical equipment; Accessories therefor
- B29L2031/7546—Surgical equipment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2311/00—Characterised by the use of homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
- C08L13/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
Landscapes
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Gloves (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Moulding By Coating Moulds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Materials For Medical Uses (AREA)
Abstract
Description
薄い壁のある外科医の手袋は以下のように作られた。手袋形成型は硝酸カルシウム(SG1.10−1.20)に浸され、かつそれから90−110℃で20−30秒間乾燥された。型はそれから、ネオプレン750(2−クロロ−1,3ブタジエンおよび2,3ジクロロ−1,3−ブタジエンのコポリマー;合計固体含有率(TSC)=40−46%)を含むが、追加の塩素処理可能ポリマーは少しも含まない配合ラテックスに浸された。前記ラテックスは、上述の好ましい配合により、促進剤としてRhenocure、DPG(ジフェニルグアニジン)およびZinc BuD(ジブチルジチオカルバミン酸亜鉛)、硫化剤として硫黄および酸化亜鉛、安定剤としてDehydolおよびArylan、抗酸化剤としてWingstay L、および色素としてColanyl blue A2Rを含んでいた。
外科医の手袋は、前記ラテックスが7.5重量%のカルボキシル化されたSBRラテックスを含有するネオプレン750(すなわち、比92.5:7.5でのネオプレン750およびカルボキルシル化されたSBRラテックス)を含む以外、例1の方法に従って作られた。カルボキシル化されたSBRラテックスは、Enichemから入手可能なEuroprene5583であり、かつ40重量%のスチレンを含んでいた。粘着防止剤中の洗浄工程は省略されたが、手袋は以下の手順に従って塩素処理された。
d)手袋が取り除かれ、0.1%Rexanolを含む水でそれから乾燥され、取り除かれ、水で洗浄され、かつ最終的に取り除かれ、かつ乾燥された。
2.0 かなり潤滑
3.0 適度な抗力
4.0 高い抗力および粘着性なし
例1によってネオプレン750のみで作られた標準的なネオプレン手袋は約3.0の評価を有する一方、例2により作られた手袋は1−2の表面摩擦抗力評価を有する。
Claims (15)
- ポリクロロプレンより容易に塩素処理可能なポリマーを含むポリクロロプレン物品。
- 容易に塩素処理可能な表面を有するポリクロロプレン物品の製造方法であって、前記ポリクロロプレンの水分散液または溶液から前記物品を形成することを含み、ポリクロロプレンより容易に塩素処理可能な1つまたはそれ以上のポリマーが前記分散液または溶液に含まれることを特徴とする方法。
- 前記物品を塩素処理する工程をさらに含む請求項2記載のポリクロロプレン物品の製造方法。
- 前記ポリマーは合成エラストマーポリマーである請求項1、2または3記載の物品または方法。
- 前記物品は薄膜物品である請求項1、2、3または4記載の物品または方法。
- 前記物品は手袋、特に外科手術用手袋である請求項1から5のいずれか1項記載の物品または方法。
- 前記ポリマーはポリクロロプレンとある程度の非親和性がある請求項1から6のいずれか1項記載の物品または方法。
- 前記ポリマーは、合成cis−1,4−ポリイソプレンを含む、カルボキシル化したニトリルゴム、カルボキシル化したスチレンブタジエン、またはポリイソプレンである請求項1から7のいずれか1項記載の物品または方法。
- 前記ポリマーは、(重量で)0−5%カルボン酸、40−60%スチレンおよび40−60%ブタジエンを含むカルボキシル化されたスチレンブタジエンである請求項8記載の物品または方法。
- 前記ポリマーはラテックスの形態であり、かつポリクロロプレンラテックスに添加される請求項1から10のいずれか1項記載の物品または方法。
- 前記ポリマーラテックスは、前記ポリクロロプレンラテックスの4から15重量%の量で前記ポリクロロプレンラテックスに添加される請求項10記載の方法。
- ポリマーラテックスの前記量は前記ポリクロロプレンの5から10重量%である請求項11記載の方法。
- 実質的にその使用者接触表面にヒドロゲル層を含む手袋である請求項1から9のいずれか1項記載のポリクロロプレン物品。
- 前記手袋を構成する前記ポリマーはカルボキシル化されたスチレンブタジエンである請求項13記載の手袋。
- 請求項3から12のいずれか1項記載されたような、二重装着可能なポリクロロプレン物品、特に手袋の製造方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0211027.8A GB0211027D0 (en) | 2002-05-14 | 2002-05-14 | Double-donnable glove |
PCT/GB2003/002083 WO2003095172A1 (en) | 2002-05-14 | 2003-05-14 | Double-donnable glove |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2005529641A true JP2005529641A (ja) | 2005-10-06 |
Family
ID=9936644
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004503231A Withdrawn JP2005529641A (ja) | 2002-05-14 | 2003-05-14 | 二重装着可能な手袋 |
Country Status (16)
Country | Link |
---|---|
US (1) | US8187684B2 (ja) |
EP (2) | EP2360001A1 (ja) |
JP (1) | JP2005529641A (ja) |
CN (2) | CN1668438B (ja) |
AT (1) | ATE487582T1 (ja) |
AU (1) | AU2003242825C1 (ja) |
BR (1) | BR0309984A (ja) |
CA (1) | CA2485746C (ja) |
DE (1) | DE60334902D1 (ja) |
DK (1) | DK1511610T3 (ja) |
GB (1) | GB0211027D0 (ja) |
IL (1) | IL165151A0 (ja) |
MX (1) | MXPA04011212A (ja) |
NZ (1) | NZ536724A (ja) |
RU (1) | RU2325278C2 (ja) |
WO (1) | WO2003095172A1 (ja) |
Cited By (1)
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KR20200044451A (ko) * | 2018-10-19 | 2020-04-29 | 아주대학교산학협력단 | 의료용 이중 장갑 |
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US8110266B2 (en) | 2007-02-08 | 2012-02-07 | Allegiance Corporation | Glove coating and manufacturing process |
US7805773B2 (en) * | 2007-03-12 | 2010-10-05 | Joseph Di Lorenzo | Surgical glove |
US20100192295A1 (en) | 2007-06-01 | 2010-08-05 | Liquidbreaker Llc | Drain Cartridge Having Removable Valved System |
US7900288B2 (en) | 2007-06-01 | 2011-03-08 | Liquidbreaker, Llc | Drain cartridge having removable valved system |
US20080306200A1 (en) | 2007-06-11 | 2008-12-11 | Seong Fong Chen | Antistatic gloves and process for making same |
JP5608567B2 (ja) | 2008-03-14 | 2014-10-15 | アレジアンス、コーポレイション | 水性樹脂組成物およびその製品 |
WO2010129531A1 (en) | 2009-05-05 | 2010-11-11 | Liquidbreaker, Llc | Drain cartridge having removable valved system |
GB201021903D0 (en) * | 2010-12-23 | 2011-02-02 | Midas Safety Inc | Elastomeric films |
US8883511B2 (en) * | 2011-03-10 | 2014-11-11 | Denki Kagaku Kogyo Kabushiki Kaisha | Method for evaluating chemical stability of polychloroprene latex |
WO2015004674A1 (en) * | 2013-07-10 | 2015-01-15 | Ttk Protective Devices Limited | A binary process for manufacture of dipped latex products |
CN105492179B (zh) * | 2013-07-16 | 2019-03-08 | 皮肤防护有限公司 | 形成弹性体膜的组合物和由所述弹性体膜制成的制品 |
US10253170B2 (en) | 2014-03-25 | 2019-04-09 | Ansell Limited | Polyisoprene/polychloroprene compositions |
KR20240055870A (ko) * | 2015-10-18 | 2024-04-29 | 얼리젼스 코포레이션 | 수계 히드로겔 블렌드 코팅 및 엘라스토머 물품에의 적용 방법 |
EP3562868A4 (en) * | 2016-12-30 | 2020-09-16 | Skinprotect Corporation SDN BHD | ELASTOMERIC FILM-FORMING COMPOSITIONS AND RELATED ARTICLES AND PROCEDURES |
US10479874B1 (en) * | 2018-02-15 | 2019-11-19 | Shimon Amdur | Latex compositions and antistatic articles manufactured therefrom |
CN117715969A (zh) * | 2021-07-27 | 2024-03-15 | 安塞尔有限公司 | 不含促进剂的高抗撕裂合成手套 |
CN114316395B (zh) * | 2022-01-11 | 2023-06-02 | 星宇医疗科技股份有限公司 | 一种复合胶乳的制备方法和应用 |
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AT409819B (de) * | 1996-09-12 | 2002-11-25 | Semperit Ag Holding | Gegenstand aus einem flexiblen gummi und/oder kunststoff |
CA2303375A1 (en) * | 1997-11-07 | 1999-05-20 | Microflex Corporation | Elastomeric articles from a blend of polychloroprene and acrylonitrile |
CA2227645A1 (en) | 1998-01-21 | 1999-07-21 | Eci Medical Technologies Inc. | Multi-layered thin-walled powder-free articles manufactured from styrene block copolymers |
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US6391409B1 (en) * | 1999-02-12 | 2002-05-21 | Allegiance Corporation | Powder-free nitrile-coated gloves with an intermediate rubber-nitrile layer between the glove and the coating and method of making same |
CA2370505A1 (en) * | 1999-02-12 | 2000-08-17 | Allegiance Corporation | Powder-free nitrile-coated gloves with an intermediate rubber-nitrile layer between the glove and the coating |
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US20080306200A1 (en) * | 2007-06-11 | 2008-12-11 | Seong Fong Chen | Antistatic gloves and process for making same |
-
2002
- 2002-05-14 GB GBGB0211027.8A patent/GB0211027D0/en not_active Ceased
-
2003
- 2003-05-14 MX MXPA04011212A patent/MXPA04011212A/es active IP Right Grant
- 2003-05-14 DK DK03749958.9T patent/DK1511610T3/da active
- 2003-05-14 IL IL16515103A patent/IL165151A0/xx unknown
- 2003-05-14 JP JP2004503231A patent/JP2005529641A/ja not_active Withdrawn
- 2003-05-14 CA CA2485746A patent/CA2485746C/en not_active Expired - Lifetime
- 2003-05-14 AU AU2003242825A patent/AU2003242825C1/en not_active Ceased
- 2003-05-14 BR BR0309984-9A patent/BR0309984A/pt not_active IP Right Cessation
- 2003-05-14 EP EP10184628A patent/EP2360001A1/en not_active Withdrawn
- 2003-05-14 EP EP03749958A patent/EP1511610B1/en not_active Expired - Lifetime
- 2003-05-14 NZ NZ536724A patent/NZ536724A/en not_active IP Right Cessation
- 2003-05-14 DE DE60334902T patent/DE60334902D1/de not_active Expired - Lifetime
- 2003-05-14 AT AT03749958T patent/ATE487582T1/de not_active IP Right Cessation
- 2003-05-14 WO PCT/GB2003/002083 patent/WO2003095172A1/en active Application Filing
- 2003-05-14 US US10/514,020 patent/US8187684B2/en not_active Expired - Fee Related
- 2003-05-14 CN CN03816714XA patent/CN1668438B/zh not_active Expired - Lifetime
- 2003-05-14 RU RU2004136305/04A patent/RU2325278C2/ru not_active IP Right Cessation
- 2003-05-14 CN CN2010105101335A patent/CN102093604A/zh active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20200044451A (ko) * | 2018-10-19 | 2020-04-29 | 아주대학교산학협력단 | 의료용 이중 장갑 |
KR102155169B1 (ko) * | 2018-10-19 | 2020-09-11 | 아주대학교산학협력단 | 의료용 이중 장갑 |
Also Published As
Publication number | Publication date |
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BR0309984A (pt) | 2005-03-01 |
AU2003242825A1 (en) | 2003-11-11 |
CN1668438B (zh) | 2010-12-15 |
EP1511610B1 (en) | 2010-11-10 |
CN102093604A (zh) | 2011-06-15 |
IL165151A0 (en) | 2005-12-18 |
CN1668438A (zh) | 2005-09-14 |
ATE487582T1 (de) | 2010-11-15 |
US20060010565A1 (en) | 2006-01-19 |
NZ536724A (en) | 2007-04-27 |
EP2360001A1 (en) | 2011-08-24 |
GB0211027D0 (en) | 2002-06-26 |
DK1511610T3 (da) | 2011-02-21 |
AU2003242825B2 (en) | 2009-10-29 |
WO2003095172A1 (en) | 2003-11-20 |
DE60334902D1 (de) | 2010-12-23 |
AU2003242825C1 (en) | 2010-03-04 |
EP1511610A1 (en) | 2005-03-09 |
CA2485746A1 (en) | 2003-11-20 |
RU2004136305A (ru) | 2005-05-10 |
US8187684B2 (en) | 2012-05-29 |
CA2485746C (en) | 2011-08-02 |
RU2325278C2 (ru) | 2008-05-27 |
MXPA04011212A (es) | 2005-11-17 |
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