JP2005330450A - Apparatus for treating, modifying and reutilizing waste rubber, waste plastic, plastic coating intermediate waste, hydrocarbon and carbon - Google Patents

Apparatus for treating, modifying and reutilizing waste rubber, waste plastic, plastic coating intermediate waste, hydrocarbon and carbon Download PDF

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JP2005330450A
JP2005330450A JP2004174815A JP2004174815A JP2005330450A JP 2005330450 A JP2005330450 A JP 2005330450A JP 2004174815 A JP2004174815 A JP 2004174815A JP 2004174815 A JP2004174815 A JP 2004174815A JP 2005330450 A JP2005330450 A JP 2005330450A
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waste
hydrocarbon
plastic
mica
water
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Shinichiro Kojima
信一郎 小嶋
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/52Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Treating Waste Gases (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To decompose and reutilize waste rubbers, waste plastics or the like, which has been hard to decompose heretofore, causing troubles recently into substances not exerting bad influences to the environments. <P>SOLUTION: The waste rubbers, waste plastics or the like are put in through a crushing machine part of the apparatus and are safely decomposed, gasified and separated by heat rays and α-rays, generated by heating heat storage stones or mica, and by catalytic reactions in the decomposition chamber, and a plurality of pure substances are obtained using a water-cooled condenser, water-cooled direct expansion freezing, a chiller or the like. As harmful substances are treated in a radiant tube helically coated with Ca (calcium) while intermittent discharge is carried out using a carbon electrode, tungsten or the like in the inner flame of the flame from the burner head, the apparatus is almost harmless and friendly to the environments. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

この発明は廃ゴム類、廃プラスチック類、石油中間物質などを分解、炭化及びガス化し油化して再活用しようというものである。  The present invention is intended to decompose, carbonize, gasify, and recycle waste rubbers, waste plastics, petroleum intermediates and the like.

従来、廃ゴム、廃プラスチックまたはその中間物質等の完全な分解は困難であるとされて来た。  Conventionally, it has been considered difficult to completely decompose waste rubber, waste plastic, or an intermediate substance thereof.

今回、雲母に熱を与えて、ある特定のα線を発生させて出たα波と触媒によって、廃ゴム、廃プラスチックまたはその中間物質等を分解できることがわかった。  This time, it was found that waste rubber, waste plastic or its intermediate substances can be decomposed by α-waves and catalyst generated by applying heat to mica to generate a specific α-ray.

課題を解決する為の手段Means to solve the problem

この廃ゴム、廃プラスチックまたはその中間物質等の処理変性再活用装置の構造について説明する。  The structure of the treatment modification / reuse device for waste rubber, waste plastic or intermediate materials thereof will be described.

廃ゴム、廃プラスチックまたはその中間物質等を挿入口から入れる。  Insert waste rubber, waste plastic or its intermediate material from the insertion slot.

小さな物はそのまま大きなものは破砕機1によって廃ゴム、廃プラスチックまたはその中間物質等を細かく破砕し投入する。  As for small things as they are, as for big things, waste rubber, waste plastic or its intermediate substance etc. are crushed finely by the crusher 1 and put in.

バーナーまたは電気ヒーター27によって熱せられたラジアントチューブ3が雲母または雲母石2に特定の熱エネルギーを与えることによって雲母または雲母石2からα線が発生する。この時蓄熱石も同様に熱線を出す。  The radiant tube 3 heated by the burner or the electric heater 27 gives specific heat energy to the mica or mica stone 2 to generate α rays from the mica or mica stone 2. At this time, the heat storage stone also emits heat rays.

このα線と熱と分解室にセットした雰囲気調整バルブ12から吐出される雰囲気調整ガスと熱媒体によって廃ゴム、廃プラスチック及び中間体が分解される。  Waste rubber, waste plastics and intermediates are decomposed by the α-ray, heat, and the atmosphere adjusting gas and heat medium discharged from the atmosphere adjusting valve 12 set in the decomposition chamber.

この熱反応時に雲母及び雲母石2、又はそれに相当する物を、ラジアントチューブ3周辺にセットする為、接触有効面積を大幅に多く取ることが出来ると共に熱放射角度が様々な方向に変わる、またα線放射角度も同様である為、分解反応効率を高めることができる。  Since the mica and mica stone 2 or the equivalent is set around the radiant tube 3 during this thermal reaction, the contact effective area can be greatly increased and the heat radiation angle changes in various directions. Since the radiation angle is the same, the decomposition reaction efficiency can be increased.

廃ゴム、廃プラスチックまたはその中間物質等の中に混入していた残留物等を取る方法は図4の様な分解室でブロー管4によってガスブローして残留物質を排出する。排出中は反応室より集塵機6を通し循環しないように残留物、炭化物及び灰、スラッジ等を取り除く。また2次フィルタを付けるがこれを取り除く場合もある。  A method for removing the residue mixed in the waste rubber, waste plastic, or an intermediate substance thereof is to blow the gas by the blow pipe 4 in the decomposition chamber as shown in FIG. During discharge, residues, carbides, ash, sludge, etc. are removed from the reaction chamber so as not to circulate through the dust collector 6. In some cases, a secondary filter is attached but removed.

但し低温で行う場合は空焼き後行なうようにコントロールする。本操作は発火点以下にて行うが、雰囲気不活性ガスを使用して高温時でも可能にした。  However, if it is performed at a low temperature, it is controlled so that it is performed after baking. This operation was performed below the ignition point, but it was possible even at high temperatures using an inert gas atmosphere.

図4のような構造で砂、泥、各種金属片、水分等の潜入が処理物にあっても問題は無い。  There is no problem even if infiltration of sand, mud, various metal pieces, moisture, and the like is present in the processed object as shown in FIG.

この時、分解されたガスが高熱になるので冷却ジャケット14で装置を冷やし冷却ジャケット14で高温になった水は水蒸気となりコンデンサーに導かれ凝縮せれてボイラー蒸気タンク18を通りタービン17を廻す。  At this time, since the decomposed gas becomes hot, the apparatus is cooled by the cooling jacket 14, and the water heated to the high temperature by the cooling jacket 14 is converted into water vapor, led to the condenser, condensed, and passes through the boiler steam tank 18 and passes through the turbine 17.

タービン17から発電機16によって起電力が生成され、モーター25制御盤などの電力として活用する。  An electromotive force is generated from the turbine 17 by the generator 16 and used as electric power for the motor 25 control panel or the like.

タービン17に入った水蒸気は熱交換器10を通り冷凍機11(チラーの場合も有る)で冷やされ水になり水冷ジャケット14に送って循環させる。  The steam that has entered the turbine 17 passes through the heat exchanger 10, is cooled by a refrigerator 11 (which may be a chiller), becomes water, and is sent to a water cooling jacket 14 for circulation.

ラジアントチューブ3により加熱された蓄熱石、雲母石2から蓄熱石からは熱線、雲母石からはα線が発生し、このα線と熱によって廃ゴム、廃プラスチックその中間物質が分解されガスとなり、断熱物7を通り水冷コンデンサ13によって温度差をつけた断層で軽質油、ナフサ類(燃料)、重質油(A重油・B重油・C重油)酸、塩、炭化物などにわけられる。  Heat storage stones heated by the radiant tube 3, mica stone 2 generate heat rays from the heat storage stone, and mica stones generate α rays, and the α rays and heat decompose the waste rubber, waste plastic and its intermediate substances into gas, It is divided into light oil, naphtha (fuel), heavy oil (A heavy oil / B heavy oil / C heavy oil) acid, salt, carbide, etc. through a fault passing through the insulator 7 and having a temperature difference by the water-cooled condenser 13.

また、この時に残ったガスはブロワーバーナー28で燃やされ熱になる。  Further, the remaining gas at this time is burned by the blower burner 28 and becomes heat.

またここで摂取できた重質油は燃料タンクに戻し燃料として使うこともできる。  The heavy oil that can be consumed here can be returned to the fuel tank and used as fuel.

発明の効果The invention's effect

この装置は発電機16で電力を発生させ変換機23をとおしモーター25制御部などで利用しながら作動するので、電力消費を抑える事が出来ると共に、ほとんど全てのHC(炭化水素構成物)を油化出来る。  This device generates electric power by the generator 16 and operates while using the converter 23 and the motor 25 control unit etc., so that power consumption can be suppressed and almost all HC (hydrocarbon constituent) is oiled. Can be

水冷コンデンサの層からさまざまな物質が採取できるがこの時発生したガスはバーナー28で燃やして利用するが、排気ボイラー24から排気されるガスは、ラジアントチューブ3内にCa(カルシウム)を螺旋状にコーティングすると共に炭素電極によってパルス放電され万が一に有害物質が発生しても処理するので無害である。  Although various substances can be collected from the layer of the water-cooled condenser, the gas generated at this time is burned by the burner 28 and used, but the gas exhausted from the exhaust boiler 24 spirals Ca (calcium) into the radiant tube 3. It is harmless because it is coated and treated even if harmful substances are generated by pulse discharge with a carbon electrode.

又、燃焼させないのでダイオキシン、CO2等の有害物質は出ない。  Moreover, since it is not burned, no harmful substances such as dioxin and CO2 are emitted.

本発明装置の断面全体図(縦書き)Overall cross-sectional view of the device of the present invention (vertical writing) ラジアントチューブ3を上部からみた平面図 内側がCaで出来た外付け信管のラジアントチューブ3を使い、その周りは雲母石2を敷き詰めてある。A plan view of the radiant tube 3 as viewed from the top The radiant tube 3 of an external fusible tube made of Ca on the inside is used, and mica stones 2 are laid around it. 水冷コンデンサ13部分を上部からみた平面図 ガスがここを降りて温度差によりそれぞれ物質ごとにわけられる。The top view which looked at the water-cooled condenser 13 part from the upper part Gas goes down here and is divided for every substance according to a temperature difference, respectively. ラジアントチューブ3及び集塵機6の横断図(分解室のクリ ーナーシステム) ブロー管4、集塵機6によって塵などの混合物を除く事ができる。Cross-sectional view of radiant tube 3 and dust collector 6 (decomposition chamber cleaner system) Mixtures such as dust can be removed by blow tube 4 and dust collector 6. ラジアントチューブ3の拡大図 (a)横断図(b)下から見た図Enlarged view of radiant tube 3 (a) Cross section (b) Viewed from below ブロワー内のバーナー先端の拡大図Enlarged view of the burner tip in the blower

符号の説明Explanation of symbols

1破砕機 2雲母石(花崗岩) 3ラジアントチューブ
4ブロー管 5加圧ポンプ 6集塵機
7断熱物 8炭又は灰分プレス取出し装置
9タンク 10熱交換器(ウォーターキラー)
11冷凍機 12雰囲気整正バルブ
13水冷コンデンサ(耐熱耐酸処理を施している)
14水冷ジャケット 15薬注ポンプ 16発電機
17タービン 18ボイラー蒸気タンク
19バッテリー 20コンデンサ 21トランス
22インバーター 23変換機 24排気ボイラー
25モーター 26燃料タンク 27バーナー
28ブロワー 29 2次フィルター
30チューブ火炎放電プラズマ発生部
1 crusher 2 mica stone (granite) 3 radiant tube 4 blow pipe 5 pressure pump 6 dust collector 7 heat insulator 8 charcoal or ash press takeout device 9 tank 10 heat exchanger (water killer)
11 Refrigerator 12 Atmospheric leveling valve 13 Water-cooled condenser (heat-resistant and acid-resistant)
14 Water Cooling Jacket 15 Chemical Injection Pump 16 Generator 17 Turbine 18 Boiler Steam Tank 19 Battery 20 Capacitor 21 Transformer 22 Inverter 23 Converter 24 Exhaust Boiler 25 Motor 26 Fuel Tank 27 Burner 28 Blower 29 Secondary Filter 30 Tube Flame Discharge Plasma Generator

Claims (13)

雲母から発生するα線による廃ゴム、廃プラスチック、プラスチック中間材の熱化学分解。  Thermochemical decomposition of waste rubber, plastics, and plastic intermediates by alpha rays generated from mica. ブロー管、防爆処置を施した特殊集塵機による炭化物と塵、金属片等の回収と排除。  Collection and elimination of carbides, dust, metal fragments, etc. using a blow tube and special dust collector with explosion-proof treatment. 低温熱分解でガス化した物質と飽和炭化水素に対する磁場通過で活力をつける方式。  A system that energizes a substance gasified by low-temperature pyrolysis and saturated hydrocarbons by passing through a magnetic field. 不活性雰囲気と炭化水素化合物、炭化水素の高いセタン化の重合物と、アルカリ金属を反応室にセットした。  An inert atmosphere, a hydrocarbon compound, a highly cetaneated polymer of hydrocarbons, and an alkali metal were set in the reaction chamber. 炭化水素アルカリ重合物を分解触媒として使用した。  Hydrocarbon alkaline polymer was used as cracking catalyst. 化学アンチミル即ち炭化水素系分解触媒と抑制触媒を熱分解先にした反応。  Chemical antimillyl, a reaction where hydrocarbon cracking catalyst and suppression catalyst are pyrolyzed. 中性電解質を凝縮室より取除くクリーンなウォータークリーナーをセットした分解室。  A decomposition chamber equipped with a clean water cleaner that removes neutral electrolyte from the condensation chamber. 炭化水素回収時にガスと油性体を分離する装置を施した。  A device for separating the gas and the oily substance during hydrocarbon recovery was applied. 臭気汚染を防止する為段階式凝縮装置をセットした。  In order to prevent odor pollution, a staged condenser was set. 臭気公害を阻止する為に排気口に活性炭をセットした。  Activated carbon was set at the exhaust port to prevent odor pollution. 活性炭の再生は、ラジアントチュウーブ排気口より排出される熱により再生を促すようにした。  The regeneration of activated carbon was promoted by the heat discharged from the radiant tube outlet. 処理再生した排熱によりゼネレータを回すタービンによる発電。  Power generation by a turbine that turns a generator by exhaust heat that has been reprocessed. 凝縮層に設けたガス特殊濃縮装置(直接膨張コイル)凝縮層底部マイナス温度まで下げる例。  An example of gas special concentrator (direct expansion coil) provided in the condensate layer to lower the condensate layer bottom minus temperature.
JP2004174815A 2004-05-17 2004-05-17 Apparatus for treating, modifying and reutilizing waste rubber, waste plastic, plastic coating intermediate waste, hydrocarbon and carbon Pending JP2005330450A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2442726A (en) * 2006-10-10 2008-04-16 Pedro A Server Barcelo Process to obtain liquid hydrocarbons by cleavage of carbon and hydrogen molecules
CN106439814A (en) * 2016-11-22 2017-02-22 北京神雾环境能源科技集团股份有限公司 Radiant heater and industrial furnace
CN110549520A (en) * 2019-10-21 2019-12-10 王一飞 Waste crushing and recycling device for PVC (polyvinyl chloride) pipes

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2442726A (en) * 2006-10-10 2008-04-16 Pedro A Server Barcelo Process to obtain liquid hydrocarbons by cleavage of carbon and hydrogen molecules
GB2442726B (en) * 2006-10-10 2011-05-04 Pedro A Server Barcelo A process to obtain liquid hydrocarbons by cleavage of carbon and hydrogen molecules
CN106439814A (en) * 2016-11-22 2017-02-22 北京神雾环境能源科技集团股份有限公司 Radiant heater and industrial furnace
CN110549520A (en) * 2019-10-21 2019-12-10 王一飞 Waste crushing and recycling device for PVC (polyvinyl chloride) pipes
CN110549520B (en) * 2019-10-21 2020-04-14 湖北钟格塑料管有限公司 Waste crushing and recycling device for PVC (polyvinyl chloride) pipes

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